The Infrared Spectrum of Comet Hele–Bopp as Seen by the Infrared Space Observatory

Spectra of comet C/1995 O1 (Hale-Bopp) were obtained with the Infrared Space Observatory (ISO) at medium resolution with the grating spectrometer in the photometer (PHT-S) and/or at high resolution with the short wavelength spectrometer (SWS) and long wavelength spectrometer (LWS) in April 1996 (Crovisier et al., 1996), September–October 1996 (Crovisier et al., 1997a, b) and December 1997, at distances from the Sun of 4.6, 2.9 and 3.9 AU, respectively. For the first time, high-resolution spectra of a comet covering the entire 2.4 to 200 μm spectral range were obtained. The vibrational bands of H₂O, CO₂ and CO are detected in emission with PHT-S. Relative production rates of 100:22:70 are derived for H₂O:CO₂:CO at 3 AU pre-perihelion. H₂O is observed at high spectral resolution in the ν₃ group of bands around 2.7 μm and the ν₂ group around 6 μm with SWS, and in several rotational lines in the 100–180 μm region with LWS. The high signal-to-noise ratio of the ν₃ band observed on September–October 1996 allows accurate determinations of the water rotational temperature (28 K) and of its ortho-to-para ratio(2.45 ± 0.10, which significantly differs from the high temperature limit and corresponds to a spin temperature of 25 K). Longward of 6 μm the spectrum is dominated by dust thermal continuum emission, upon which broad emission features are superimposed. The wavelengths of the emission peaks correspond to those of Mg-rich crystalline olivine (forsterite). In the September–October 1996 spectra, emission features at 45 and 65 μm and possible absorption at 2.9–3.2 μm suggest that grains of water ice were present at 3 AU from the Sun. The observations made post-perihelion in late December 1997 led to the detections of H₂O, CO₂ and CO at 3.9 AU from the Sun (Figures 1 and 2). The production rates were ≈3.0 × 10²⁸,3.5 × 10²⁸ and ≈1.5 × 10²⁹ s^-1, respectively. This corresponds to H₂O:CO₂:CO = 100:110:500 and confirms that at such distances from the Sun, cometary activity is dominated by sublimation of CO and CO₂ rather than by H₂O. This revised version was published online in July 2006 with corrections to the Cover Date.     

Infrared measurements of the chemical composition of C/2006 P1 McNaught

C/2006 P1 McNaught is a dynamically new comet from the Oort cloud that passed very close to the Sun, driving overall volatile production rates up to about 10³¹ molecules s⁻¹. Post-perihelion observations were obtained in a target-of-opportunity campaign using the CSHELL instrument at the NASA Infrared Telescope Facility atop Mauna Kea, Hawaii, on UT 2007 January 27 and 28. Eight parent volatiles (H₂O, CH₄, C₂H₂, C₂H₆, HCN, CO, NH₃, H₂CO) and two daughter fragments (OH and NH₂) were detected, enabling the determination of a rotational temperature and production rate for H₂O on UT January 27 and absolute and relative production rates for all the detected parent species on UT January 28. The chemical composition measured in the coma suggests that this close perihelion passage stripped off processed outer surface layers, likely exposing relatively fresh primordial material during these observations. The post-perihelion abundances we measure for CO and CH₄ (relative to H₂O) are slightly depleted while C₂H₂, NH₂ and possibly NH₃ are enhanced when compared to the overall comet population. Measured abundances for other detected molecular species were within the range typically observed in comets.     

Spectroscopy of Comet Hale-Bopp in the infrared

High resolution infrared spectra of Comet C/1995 O1 (Hale-Bopp) were obtained during 2-5 March 1997 UT from the NASA Infrared Telescope Facility on Mauna Kea, Hawaii, when the comet was at r≈1.0 AU from the Sun pre-perihelion. Emission lines of CH₄, C₂H₆, HCN, C₂H₂, CH₃OH, H₂O, CO, and OH were detected. The rotational temperature of CH₄ in the inner coma was T_rot=110±20 K. Spatial profiles of CH₄, C₂H₆, and H₂O were consistent with release solely from the nucleus. The centroid of the CO emission was offset from that of the dust continuum and H₂O. Spatial profiles of the CO lines were much broader than those of the other molecules and asymmetric. We estimate the CO production rate using a simplified outflow model: constant, symmetric outflow from the peak position. A model of the excitation of CO that includes optical depth effects using an escape probability method is presented. Optical depth effects are not sufficient to explain the broad spatial extent. Using a parent+extended-source model, the broad extent of the CO lines can be explained by CO being produced mostly (∼90% on 5 March) from an extended source in the coma. The CO rotational temperature was near 100 K. Abundances relative to H₂O (in percent) were 1.1±0.3 (CH₄), 0.39±0.10 (C₂H₆), 0.18±0.04 (HCN), 0.17±0.04 (C₂H₂), 1.7±0.5 (CH₃OH), and 37-41 (CO, parent+extended source). These are roughly comparable to those obtained for other long-period comets also observed in the infrared, though CO appears to vary.     

Optical Spectroscopy of Comet C/2000 WM1 (LINEAR) at the Guillermo Harro Astrophysical Observatory in Mexico

We present a preliminary analysis of medium resolution optical spectra of comet C/2000 WM1 (LINEAR) obtained on 22 November 2001. Theemission lines of the molecules C₂, C₃, CN, NH₂,H₂O⁺ and presumably CO (Asundi and triplet bands) and C₂ ^-were identified in these spectra. By analysing the brightnessdistributions of the C₂, C₃, CN emission lines along theslit of the spectrograph we determined some physical parameters of theseneutrals, such as their lifetimes and expansion velocities inthe coma. The Franck–Condon factors for the CO Asundi bands and C₂ ^- bands were calculated using a Morse potential model.     

Monte Carlo modeling of neutral gas and dust in the coma of Comet 1P/Halley

The neutral gas environment of a comet is largely influenced by dissociation of parent molecules created at the surface of the comet and collisions of all the involved species. We compare the results from a kinetic model of the neutral cometary environment with measurements from the Neutral Mass Spectrometer and the Dust Impact Detection System onboard the Giotto spacecraft taken during the fly-by at Comet 1P/Halley in 1986. We also show that our model is in good agreement with contemporaneous measurements obtained by the International Ultraviolet Explorer, sounding rocket experiments, and various ground based observations.The model solves the Boltzmann equation with a Direct Simulation Monte Carlo technique (Tenishev, V., Combi, M., Davidsson, B. [2008]. Astrophys. J. 685, 659-677) by tracking trajectories of gas molecules and dust grains under the influence of the comet’s weak gravity field with momentum exchange among particles modeled in a probabilistic manner. The cometary nucleus is considered to be the source of dust and the parent species (in our model: H₂O, CO, H₂CO, CO₂, CH₃OH, C₂H₆, C₂H₄, C₂H₂, HCN, NH₃, and CH₄) in the coma. Subsequently our model also tracks the corresponding dissociation products (H, H₂, O, OH, C, CH, CH₂, CH₃, N, NH, NH₂, C₂, C₂H, C₂H₅, CN, and HCO) from the comet’s surface all the way out to 10⁶ km.As a result we are able to further constrain cometary the gas production rates of CO (13%), CO₂ (2.5%), and H₂CO (1.5%) relative to water without invoking unknown extended sources.     

Studies of proton-irradiated cometary-type ice mixtures

Radiation synthesis has been proposed as a mechanism for changing the nature of the outer few meters of ice in a comet stored 4.6 billion years in the Oort cloud and may explain some of the differences observed between new and more evolved comets. Cometary-type ice mixtures were studied in a laboratory experiment designed to approximately simulate the expected temperature, pressure, and radiation environment of the interstellar Oort cloud region. The 2.5- to 15-μm infrared absorption features of thin ice films were analyzed near 20°K before and after 1 MeV proton irradiation. Various ice mixtures included the molecules H₂O, NH₃, CH₄, N₂, C₃H₈, CO, and CO₂. All experiments confirm the synthesis of new molecular species in solid phase mixtures at 20°K. The synthesized molecules, identified by their infrared signatures, are C₂H₆, CO₂, CO, N₂O, NO, and CH₄ (weak). Synthesized molecules, identified by gas chromatographic (GC) analysis of the volatile fraction of the warmed irradiated ice mixture, are C₂H₄ or C₂H₆, and C₃H₈. When CH₄ is present in the irradiated ice mixture, long-chained volatile hydrocarbons and CO₂ are synthesized along with high-molecular-weight carbon compounds present in the room temperature residue. Irradiated mixtures containing CO and H₂O synthesize CO₂ and those CO₂ and H₂O synthesize CO. Due to radiation synthesis, ～1% of the ice was converted into a nonvolatile residue containing complicated carbon compounds not present in blank samples. These results suggest that irrespective of the composition of newly accreted comets, initial molecular abundances can be altered and new species created as a result of radiation synthesis. Irradiated mixtures exhibited thermoluminescence and pressure enhancements during warming; these phenomena suggest irradiation synthesis of reactive species. Ourbursts in new comets resulting from similar radiation induced exothermic activity would be expected to occur beginning at distances of the order of 100 AU.     

Infrared Observations Of Volatile Molecules In Comet Hale-Bopp

Infrared observations of comets C/1996 B2 (Hyakutake) and C/1995 O1 (Hale-Bopp) benefited from the high spectral resolution and sensitivity of échelle spectrometers now equipping ground-based telescopes and from the availability of the Infrared Space Observatory (ISO). From the ground, several hydrocarbons were unambiguously detected for the first time: CH₄, C₂H₂, C₂H₆. Water was observed through several of its hot vibrational bands, escaping telluric absorption. CO, HCN, NH₃ and OCS were also observed, as well as several radicals. This permitted the evaluation of molecular production rates, of rotational temperature, and — taking advantage of the 1-D imaging of long-slit spectroscopy — of the space distribution of these species. With ISO, carbon dioxide was directly observed for the second time in a comet (after its detection from the Vega probes in P/Halley). The spectrum of water was investigated in detail (several bands of vibration and far-infrared rotational lines), permitting the evaluation of the rotational temperature of water, and of it spin temperature from the ortho-to-para ratio. Water ice was identified in the grains of Hale-Bopp as far as 7 AU from the ground and possibly at 3 AU with ISO. The composition of cometary volatiles appears to be strikingly similar to that of interstellar ices. This revised version was published online in July 2006 with corrections to the Cover Date.     

Photopolarimetric studies of comet Austin

Photopolarimetric observations of comet Austin with the IAU/IHW filter system were obtained on the 2.34 m Vainu Bappu Telescope (VBT) of the Indian Institute of Astrophysics, at Kavalur, India, during pre-perihelion phase on February 20,1990 and on the 1.2 m telescope of the Physical Research Laboratory at Gurusikhar, Mount Abu during postperihelion phase on May 2 and 4, 1990. The comet appeared bluer than a solar analog during post-perihelion phase on May 2 and 4. The percent polarization shows a sharp increase towards the red on May 2 and 4. The dominant sizes of the dust particles appear to lie in a narrow range of 0.1 to 0.5 Μm. Regarding the molecular band emission, CN and C₂ bands are quite strong; C₃ emission was also found to be strong though the observations on May 2 and 4 show significant variation as compared to C₂ emission. Molecular band polarization for CN, C₃, C₂ and H₂ O+ have been calculated. It has been found that emission polarization in CN, C₂ and C₃ is between 1–7% (phase angle between 107.4–109 degrees). For CN and C₂ the polarization values are close to the theoretically predicted values, but for C₃ the polarization value falls much below the theoretically predicted value. A similar result was found for comet Halley.     

The organic composition of Comet C/2001 A2 (LINEAR): I. Evidence for an unusual organic chemistry

We used the NIRSPEC instrument on the Keck-2 telescope atop Mauna Kea, HI to observe Comet C/2001 A2 (LINEAR) in a Target of Opportunity campaign on UT 2001 July 9.5, 10.5 August 4.4, 10.5. We measured seven organic parent volatiles (C₂H₆, C₂H₂, HCN, CH₄, CO, CH₃OH, H₂CO) simultaneously with H₂O. We obtained absolute production rates and relative abundances for parent volatiles, and also measured rotational temperatures for several of these species. The chemical composition of C/2001 A2 differs substantially from any comet we have observed to date. The abundances we measure (relative to H₂O) for C₂H₆, C₂H₂, HCN, and CH₃OH are enriched by a factor of ∼2 to 3 in C/2001 A2 compared with most comets in our database. Other molecular species were detected within the typical range of measured abundances. C/2001 A2 presented a unique opportunity to study the chemistry of a fragmenting comet where pristine areas are exposed to the Sun.     

Methane in Oort cloud comets

We detected CH₄ in eight Oort cloud comets using high-dispersion (λ/Δλ∼2×10⁴) infrared spectra acquired with CSHELL at NASA's IRTF and NIRSPEC at the W.M. Keck Observatory. The observed comets were C/1995 O1 (Hale-Bopp), C/1996 B2 (Hyakutake), C/1999 H1 (Lee), C/1999 T1 (McNaught-Hartley), C/1999 S4 (LINEAR), C/2000 WM₁ (LINEAR), C/2001 A2 (LINEAR), and 153/P Ikeya-Zhang (C/2002 C1). We detected the R0 and R1 lines of the ν₃ vibrational band of CH₄ near 3.3 μm in each comet, with the exception of McNaught-Hartley where only the R0 line was measured. In order to obtain production rates, a fluorescence model has been developed for this band of CH₄. We report g-factors for the R0 and R1 transitions at several rotational temperatures typically found in comet comae and relevant to our observations. Using g-factors appropriate to T_rot as determined from HCN, CO and/or H₂O and C₂H₆, CH₄ production rates and mixing ratios are presented. Abundances of CH₄/H₂O are compared among our existing sample of comets, in the context of establishing their place of origin. In addition, CH₄ is compared to native CO, another hypervolatile species, and no correlation is found among the comets observed.     

Narrowband photometry of comet Okazaki-Levy-Rudenko 1989r

The results of the photoelectric photometry with the narrowband CN, C₃, C₂ and Blue Continuum (BC) IHW interference filters are presented. Observations were carried out with a set of diaphragms of different effective radii. On the base of the Haser model the production rates of the radicals have been obtained. The CN and C₂ molecules scale lengths (3.4 × 10⁵ km and 8.5 × 10⁴ km respectively for 1.0 AU heliocentric distance) have been also derived. The dust continuum spectrum is negligibly low in comparison with the molecular one, which stay in agreement with the results of other observations of comet Okazaki-Levy-Rudenko.     

C/1995 O1 (Hale-Bopp): Gas Production Curves And Their Interpretation

The discovery of C/1995 O1 (Hale-Bopp) at 7 AU from the Sun provided the first opportunity to follow the activity of a bright comet over a large range of heliocentric distances r_h. Production rates of a number of parent molecules and daughter species have been monitored both pre- and postperihelion. CO was found to be the major driver of the activity far from the Sun, surpassed by water within 3 AU whose production rate reached 10³¹ s⁻¹ at perihelion. Gas production curves obtained for various species show several behaviours with r_h. Gas production curves contain important information concerning the physical state of cometary ices, the structure of the nucleus and all the processes taking place inside the nucleus leading to outgassing. They are relevant to the study of several other phenomena such as the sublimation from icy grains, dust mantling or seasonal effects. For some species, such as H₂CO or HNC, they permit to constrain their origin in the coma. We discuss models of subsurface gas production in distant comets and predictions of how such a source may vary as the comet moves along its orbit, approaching perihelion and receding again. Features in the observed gas production curves of comet Hale-Bopp are generally interpretable in terms of either subsurface production (typical example: CO at large r_h) or free sublimation (typical example: H₂O). Possible implications for the vertical stratification of the cometary ices are reviewed, and preference is found for a model with crystallization of amorphous ice close to the nuclear surface. This revised version was published online in July 2006 with corrections to the Cover Date.     

Long-term Evolution of the Outgassing of Comet Hale-Bopp From Radio Observations

C/1995 O1 (Hale-Bopp) has been observed on a regular basis since August 1995 at millimetre and submillimetre wavelengths using IRAM, JCMT, CSO and SEST radio telescopes. The production rates of eight molecular species (CO, HCN, CH₃OH, H₂CO,H₂S, CS, CH₃CN,HNC) have been monitored as a function of heliocentric distance(r_h from 7 AU pre-perihelion to 4 AU post-perihelion. As comet Hale-Bopp approached and receded from the Sun, these species displayed different behaviours. Far from the Sun, the most volatile species were found in general relatively more abundant in the coma. In comparison to other species, HNC, H₂CO and CS showed a much steeper increase of the production rate with decreasing r_h. Less than 1.5 AU from the Sun, the relative abundances were fairly stable and approached those found in other comets near 1 AU. The kinetic temperature of the coma, estimated from the relative intensities of the CH₃OH and CO lines, increased with decreasing r_h, from about10 K at 7 AU to 110 K around perihelion. The expansion velocity of the gaseous species, derived from the line shapes, also increased with a law close tor_h ³. This revised version was published online in July 2006 with corrections to the Cover Date.     

Exploring morphological correlations among H2CO, 12CO, MSX and continuum mappings

There are relatively few H₂CO mappings of large-area giant molecular cloud (GMCs). H₂CO absorption lines are good tracers for low-temperature molecular clouds towards star formation regions. Thus, the aim of the study was to identify H₂CO distributions in ambient molecular clouds. We investigated morphologic relations among 6-cm continuum brightness temperature (CBT) data and H₂CO (1₁₁−1₁₀; Nanshan 25-m radio telescope), ¹²CO (1–0; 1.2-m CfA telescope) and midcourse space experiment (MSX) data, and considered the impact of background components on foreground clouds. We report simultaneous 6-cm H₂CO absorption lines and H110α radio recombination line observations and give several large-area mappings at 4.8 GHz toward W49 (50′×50′), W3 (70′×90′), DR21/W75 (60′×90′) and NGC2024/NGC2023 (50′×100′) GMCs. By superimposing H₂CO and ¹²CO contours onto the MSX color map, we can compare correlations. The resolution for H₂CO, ¹²CO and MSX data was ∼10′, ∼8′ and ∼18.3″, respectively. Comparison of H₂CO and ¹²CO contours, 8.28-μm MSX colorscale and CBT data revealed great morphological correlation in the large area, although there are some discrepancies between ¹²CO and H₂CO peaks in small areas. The NGC2024/NGC2023 GMC is a large area of HII regions with a high CBT, but a H₂CO cloud to the north is possible against the cosmic microwave background. A statistical diagram shows that 85.21% of H₂CO absorption lines are distributed in the intensity range from −1.0 to 0 Jy and the ΔV range from 1.206 to 5 km s⁻¹.     

Water production and release in Comet 153P/Ikeya-Zhang (C/2002 C1): accurate rotational temperature retrievals from hot-band lines near 2.9-μm

Multiple non-resonance fluorescence lines of water (H₂O) were detected in Comet 153/P Ikeya-Zhang (2002 C1) between UT 2002 March 21.9 (R_h=0.51 AU) and April 13.9 (R_h=0.78 AU), using the Cryogenic Echelle Spectrometer (CSHELL) at the NASA Infrared Telescope Facility. Analysis of 2.9-μm water lines enabled accurate determination of rotational temperatures on three dates. The derived H₂O rotational temperatures were 138⁺⁶₋₅, 141⁺¹⁰₋₉, and 94±3 K on UT 2002 March 22.0, March 23.0, and April 13.8, respectively. Water production rates were retrieved from spectral lines measured in nineteen separate grating settings over seven observing periods. The derived heliocentric dependence of the water production rate was Q=(9.2±1.1)×10²⁸[R_h^{(−3.21±0.26)}] molecules s⁻¹. The spatial distribution of H₂O in the coma was consistent with its release directly from the nucleus (as a native source) on all dates.     

Spectrophotometry of P/Halley (1982i)

Spectral scans of the head of periodic Comet Halley (1982i) have been presented in the optical region (3200–7000 Å) for six nights. Emission features due to NH, CN, CH, C₃, C₂ and NH₂ molecules have been identified. It is found that the comet exhibits night-to-night variation of emission bands. The abundances and production rates of CN and C₂ species have been derived.     

Two new LBV candidates in the M 33 galaxy

We present two new luminous blue variable (LBV) candidate stars discovered in the M33 galaxy. We identified these stars as massive star candidates at the final stages of evolution, presumably with a notable interstellar extinction. The candidates were selected from the Massey et al. catalog based on the following criteria: emission in H _α , V<18^./m 5 and 0_.^m 35 < (B - V) < 1_.^m 2. The spectra of both stars reveal a broad and strong H _α emission with extended wings (770 and 1000 kms⁻¹). Based on the spectra we estimated the main parameters of the stars. Object N45901 has a bolometric luminosity log(L/L_⊙) = 6.0–6.2 with the value of interstellar extinction A _V = 2.3 ± 0.1. The temperature of the star’s photosphere is estimated as T⋆ ∼ 13000–15000 K, its probable mass on the Zero Age Main Sequence is M∼ 60–80 M_⊙. The infrared excess in N 45901 corresponds to the emission of warm dust with the temperature Twarm ∼ 1000 K, and amounts to 0.1%of the bolometric luminosity. A comparison of stellar magnitude estimates from different catalogs points to the probable variability of the object N45901. Bolometric luminosity of the second object, N125093, is log(L/L_⊙) = 6.3 − 6.6, the value of interstellar extinction is A _V = 2.75 ± 0.15. We estimate its photosphere’s temperature as T⋆∼ 13000–16000K, the initial mass as M ∼ 90–120 M_⊙. The infrared excess in N125093 amounts to 5–6% of the bolometric luminosity. Its spectral energy distribution reveals two thermal components with the temperatures T_warm ∼ 1000K and T_cold ∼ 480 K. The [Ca II] λλ7291, 7323 lines, observed in LBV-like stars Var A and N93351 in M33 are also present in the spectrum of N 125093. These lines indicate relatively recent gas eruptions and dust activity linked with them. High bolometric luminosity of these stars and broad H α emissions allow classifying the studied objects as LBV candidates.     

Absolute spectrophotometry of Comet kohoutek 1973f during post-perihelion passage

Absolute spectrophotometry of the coma of Comet Kohoutek 1973f during post-perihelion period has been presented for seven nights in January 1984. Moderately wide range of heliocentric distance (0.436–0.799 AU) covered during observations allowed us to study the flux variation of emission bands with heliocentric distance. The emission features of CN, CH, C₂, C₃, and NaI have been identified in this comet. The abundances of CN and C₂ have been estimated and the production rates of CN, C₂ and C₃ have been derived. Production rates of CN and C₂ seem to vary as r ^–0.33 and r ^–3.50 respectively. The continuum of the comet became more and more redder as the heliocentric distance of the comet increased and phase angle decreased.     

A Molecular Survey of Comet C/1995 O1 (Hale-Bopp) at the IRAM Telescopes

Spectroscopic observations of comet Hale-Boppwere undertaken near perihelion at millimetre wavelengths with the Institut de Radioastronomie Millimétrique (IRAM) telescopes at Plateau de Bure (France)and Pico Veleta (Spain). They resulted in the first detections of HCOOH,SO₂, NH₂CHO and HCOOCH₃ in a comet. HDO was detected through its3₁₂–2₂₁ line at 225.897 GHz,complementing the observation of the 1₀₁–0₀₀ line at 464.925 GHz at the James Clerk Maxwell Telescope (Meier et al., 1998,Science 279, 842).Several unidentified lines are present in the spectra. Observations of HC₃N, HNCO, OCS, SO, CN, CO₊, HCO₊, in addition to more ‘classical’species CO, HCN, HNC, CH₃CN, CH₃OH, H₂CO, CS and H₂S (Biveret al., this issue) permit us to make out an extensive inventory of the composition of the coma of comet Hale-Bopp at its perihelion. It presents strong analogies with gas-phase abundances measured in interstellar hot cores and bipolar flows, which are believed to reflect the composition of interstellar grains. This revised version was published online in July 2006 with corrections to the Cover Date.     

The molecular composition of Comet C/2007 W1 (Boattini): Evidence of a peculiar outgassing and a rich chemistry

We measured the chemical composition of Comet C/2007 W1 (Boattini) using the long-slit echelle grating spectrograph at Keck-2 (NIRSPEC) on 2008 July 9 and 10. We sampled 11 volatile species (H₂O, OH^∗, C₂H₆, CH₃OH, H₂CO, CH₄, HCN, C₂H₂, NH₃, NH₂, and CO), and retrieved three important cosmogonic indicators: the ortho-para ratios of H₂O and CH₄, and an upper-limit for the D/H ratio in water. The abundance ratios of almost all trace volatiles (relative to water) are among the highest ever observed in a comet. The comet also revealed a complex outgassing pattern, with some volatiles (the polar species H₂O and CH₃OH) presenting very asymmetric spatial profiles (extended in the anti-sunward hemisphere), while others (e.g., C₂H₆ and HCN) showed particularly symmetric profiles. We present emission profiles measured along the Sun-comet line for all observed volatiles, and discuss different production scenarios needed to explain them. We interpret the emission profiles in terms of release from two distinct moieties of ice, the first being clumps of mixed ice and dust released from the nucleus into the sunward hemisphere. The second moiety considered is very small grains of nearly pure polar ice (water and methanol, without dark material or apolar volatiles). Such grains would sublimate only very slowly, and could be swept into the anti-sunward hemisphere by radiation pressure and solar-actuated non-gravitational jet forces, thus providing an extended source in the anti-sunward hemisphere.