Multiscale analysis of Asian Monsoon over the past 640 ka

The empirical mode decomposition(EMD) method is used to re-analyse the high-resolution and precisely-dated stalagmite record from Chinese caves over the past 640 ka. Results show that(1) the variation in the Asian Monsoon can be completely decomposed into ten quasiperiod oscillations, among which the precession and semiprecession band oscillations are the most prominent periodicities, with contribution rates of 31.1% and 30.7%, respectively;(2) the cross-spectrum analysis of the semiprecession component and bi-hemisphere insolation(BHI) are strongly correlated, indicating an amplified response of precipitation and temperature variability to the interhemispheric insolation in the low-latitude regions, thus further affecting the intensity of the Asian Monsoon;(3) on millennial timescales, obvious oscillations at the 5 ka and 1–2 ka bands roughly correspond to the classical Bond and Dansgaard-Oeschger(DO) cycles. Additionally, a strong correlation is found between the detrended stalagmite δ18 O records and Ca/Sr sequence from the North Atlantic(especially at the 5 ka band). This result means that the 5 ka cycle is characteristic of the glacial-interglacial cycle since the middle and late Pleistocene and may imply that climate change on the millennial timescale is the result of an interaction between global ice volume and insolation.     

Climatic variations in the past 140 ka recorded in core RM, east Qinghai-Xizang Plateau

The sequences of climatic evolution are reconstructed by the analyses of δ¹³C and δ¹⁸O of carbonate from core RM in the Zoige Basin since 140 kaB. P. During the Last Glaciation there existed at least seven warm climatic fluctuations and five cold events correlated with the records of ice core and deep sea, and during the preceding last interglacial period there were two cold climatic variations coinciding with the record of ice core GRIP. These results de-pict climatic instability in east Qinghai-Xizang Plateau over the last interglacial period. In addition, the environmental proxies of the carbonate content and pigments indicate the similar results to the stable isotope record from core RM. Project supported by the Chinese Climbing Project (85-029-02-01).     

Temperature and methane records over the last 2 ka in Dasuopu ice core

High resolution δ¹⁸O and methane records over the last 2ka have been reconstructed from Dasuopu ice core recovered from the Himalayas. Analysis shows that the δ¹⁸O record correlates well with the Northern Hemispheric temperature, Dunde ice core record, and with temperature record in eastern China. The warming trend detected in δ¹⁸O record from the last century is similar to that during the Medieval warm period. There is a dramatic increasing in methane concentration in the Dasuopu ice core, which reached 1031 nmol ⋅ mol^-1 in 1997. Moreover, methane concentration in the Dasuopu ice core is about 15%-20% higher than that in Antarctica and Greenland. There is a positive correlation between methane concentration and δ¹⁸O in Dasuopu ice core.     

Chronostratigraphy and morphological changes in Cerion land snail shells over the past 130 ka on Long Island,Bahamas

Despite the nearly 600 named species of the land snail Cerion, studies of the geological and paleontological framework of modern species are few. To address this deficiency, the biostratigraphic succession of Cerion was investigated at several areas on Long Island, Bahamas. A chronostratigraphic framework was developed through whole-rock and Cerion land snail aminostratigraphies. About 175 individual Cerion shells from last interglacial and Holocene deposits were age-ranked using stratigraphic position and amino acid racemization (AAR) geochronology. AAR ages were generated using an existing AAR-¹⁴C age model for Cerion from the central Bahamas. The age structure of Cerion fossils in sediments was determined with AAR ages, and the magnitude of “dead carbon” anomalies was evaluated using this chronological approach.Temporal changes in gross shell morphology were examined from four study areas. The last interglacial, marine isotope stage/substage (MIS) 5e (Aminozone E) is characterized by generally large shells and in some cases, bimodal sets of very small (α shells) and very large forms (β shells) coexisting in the same stratigraphic levels (primarily soils), which may encompass the transition from between MIS 5e and 5d/c. Similar bimodality of nearly identical α and β shell forms and sizes is observed at other late MIS 5e sites from the furthest reaches of Great Bahama Bank (including Long, Exumas, Eleuthera, and New Providence Islands). The widespread distribution of α and β forms in soils capping MIS 5e marine and eolian deposits implies that there may have been a synchronous, regional morphological convergence on Great Bahama Bank. None of these forms are observed in Holocene deposits of Aminozone A.The earliest MIS 1 Cerion appear in a oolite deposited 6500 a BP, and are of intermediate size compared to the Pleistocene α and β forms. As MIS 1 progressed, the diversity of shell sizes and shapes increased into modern times. The greater variety of shell forms over the past 1000–2000 a suggests that humans may have played a role in the introduction and redistribution of Cerion across the region. The potential for frequent and widespread human introductions, combined with the propensity of Cerion to hybridise freely may explain the farrago of shell sizes and shapes in the recent snail faunas of Long Island and other Bahama islands.     

Ice core record of Be over the past millennium from Dome Fuji, Antarctica: A new proxy record of past solar activity and a powerful tool for stratigraphic dating

The cosmogenic nuclide ¹⁰Be was analyzed by using accelerator mass spectrometry on an ice core drilled at the Dome Fuji station, inland Antarctica, for 700–1900 yr CE. The measured concentration of ¹⁰Be in the Dome Fuji ice core and the derived ¹⁰Be flux show similar fluctuations, with both increasing at known solar-activity minima over the last millennium in agreement with earlier observations of ¹⁰Be and ¹⁴C. Based on the similar nature of the ¹⁰Be flux to the reconstructed ¹⁴C production rate patterns, a ¹⁰Be–¹⁴C correlation age model for the Dome Fuji ice core was successfully constructed. This age model agrees well with the initial version of the tephrochronology of the core. The ¹⁰Be-flux record contains information on variability in the amount of cosmic radiation incident on the atmosphere, which is mainly attributable to high-frequency change in solar activity and low-frequency background intensity adjustment of the geomagnetic field. High-resolution ¹⁰Be analyses of the Dome Fuji ice cores promise to provide potentially important information on the history of cosmic radiation intensity over the past several hundred thousand years.     

Dasuopu ice core record of atmospheric methane over the past 2000 years

The concentrations of CH₄ in the atmosphere over the past 2000 years have been deduced by extracting and analyzing the air in bubbles embedded in the Dasuopu ice core, Qing-hai-Tibetan Plateau. Upon analyzing 57 ice core samples we found that the concentration of CH₄ 200 years ago and earlier was 0.85 μ mol· mol^-1 or about 40% of present atmospheric CH₄ levels over Qinghai-Tibetan Plateau. A rapid and significant increase of atmospheric CH₄ started about 200–250 a ago. For a given age before 19th century, the Dasuopu CH₄ concentrations were about 15%-20% higher than those in Antarctic and Greenland references. It was also found that the Dasuopu CH₄ concentrations changed more frequently, and its fluctuations could reflect the temperature change sensitively.     

Regional Be production rate calibration for the past 12 ka deduced from the radiocarbon-dated Grøtlandsura and Russenes rock avalanches at 69° N, Norway

Two rock avalanches in Troms County – the Grøtlandsura and Russenes – were selected as CRONUS-EU natural cosmogenic ¹⁰Be production-rate calibration sites because they (a) preserve large boulders that have been continuously exposed to cosmic irradiation since their emplacement; (b) contain boulders with abundant quartz phenocrysts and veins with low concentrations of naturally-occurring ⁹Be (typically < 1.5 ppb); and (c) have reliable minimum radiocarbon ages of 11,424 ± 108 cal yr BP and 10,942 ± 77 cal yr BP (1σ), respectively. Quartz samples (n = 6) from these two sites contained between 4.28 × 10⁴ and 5.06 × 10⁴ at ¹⁰Be/g using the 1.387 Myr ¹⁰Be half-life. Determination of these concentrations accounts for topographic and self-shielding, and effects on nuclide production due to isostatic rebound are shown to be negligible. Persistent, constant snow and moss cover cannot be proven, but if taken into consideration they may have reduced ¹⁰Be concentrations by 10%. Using the ¹⁰Be half-life of 1.387 Myr and the Stone scaling scheme, and accounting for snow- and moss-cover, we calculate an error-weighted mean total ¹⁰Be production rate of 4.12 ± 0.19 at/g/yr (1σ). A corresponding error-weighted mean spallogenic ¹⁰Be production rate is 3.96 ± 0.16 at/g/yr (1σ), respectively. These are in agreement within uncertainty with other ¹⁰Be production rates in the literature, but are significantly, statistically lower than the global average ¹⁰Be production rate. This research indicates, like other recent studies, that the production of cosmogenic ¹⁰Be in quartz is lower than previously established by other production-rate calibration projects. Similarly, our findings indicate that regional cosmogenic production rates should be used for determining exposure ages of landforms in order to increase the accuracy of those ages. As such, using the total ¹⁰Be production rate from our study, we determine an error-weighted mean surface-exposure age of a third rock avalanche in Troms County (the Hølen avalanche) to be 7.5 ± 0.3 kyr (1σ). This age suggests that the rock avalanche occurred shortly after the 8.2 kyr cooling event, just as the radiocarbon ages of the Grøtlandsura and Russenes avalanches confirm field evidence that those rock-slope failures occurred shortly after deglaciation.     

Land use changes and their relations with carbon cycles over the past 300 a in China

Land use and land cover in China have changed greatly during the past 300 a, indicated by the rapid abrupt decrease of forest land area and the rapid increase of cropland area, which can affect terrestrial carbon cycle greatly. The first-hand materials are used to analyze main characteristics for land use and land cover changes in China during the study period. The following conclusions can be drawn from this study. The cropland area in China kept increasing from 60.78×106 hm2 in 1661 to 96.09×106 hm2 in 1998. Correspondingly, the forest land area decreased from 248.13×106 hm2 in 1700 to 109.01×106 hm2 in 1949. Affected by such changes, the terrestrial ecosystem carbon storage decreased in the mean time. Car-bon lost from land use and land cover changes mainly consist of the loss from vegetation biomass and soil. In the past 300 a, about 3.70 PgC was lost from vegetation biomass, and emissions from soil ranged from 0.80 to 5.84 PgC. The moderate evaluation of soil losses was 2.48 PgC. The total loss from vegetation and soil was between 4.50 and 9.54 PgC. The moderate and optimum evaluation was 6.18 PgC. Such carbon losses distribution varied spatially from region to region. Carbon lost more significantly in Northeast China and Southwest China than in other regions, because losses of forest land in these two regions were far greater than in the other regions during the past 300 a. And losses of carbon in the other regions were also definite, such as Inner Mongolia, the western part of South China, the Xinjiang Uygur Autonomous Region, and the Qinghai-Tibet Plateau. But the carbon lost very little from the traditional agricultural regions in China, such as North China and East China. Studies on the relationship between land use and land cover change and carbon cycle in China show that the land use activities, especially those related to agriculture and forest management, began to affect terrestrial carbon storage positively in recent years.     

Details of magnetic polarity transitions recorded in a high deposition rate deep-sea core

Concentrations of the (n, γ)-produced radionuclide⁶⁰Co were measured in lunar samples at various depths from the surface down to 360 g/cm². By comparing the data obtained to calculated production rates (based on the work of Lingenfelter et al. [8]) we determined the present day lunar neutron production rate, which was found to be (12 ± 3)neutrons/cm²sec (E < 10MeV).     

Sea-level changes and shelf break prograding sequences during the last 400 ka in the Aegean margins: Subsidence rates and palaeogeographic implications

The subsidence rates of the Aegean margins during the Middle-Upper Pleistocene were evaluated based on new and historical seismic profiling data. High-resolution seismic profiling (AirGun, Sparker and 3.5 kHz) have shown that (at least) four major oblique prograding sequences can be traced below the Aegean marginal slopes at increasing subbottom depths. These palaeo-shelf break glacial delta sediments have been developed during successive low sea-level stands (LST prograding sequences), suggesting continuous and gradual subsidence of the Aegean margins during the last 400 ka. Subsidence rates of the Aegean margins were calculated from the vertical displacement of successive topset-to-foreset transitions (palaeo-shelf break) of the LST prograding sediment sequences.The estimated subsidence rates that were calculated in the active boundaries of the Aegean microplate (North Aegean margins, Gulfs of Patras and Corinth) are high and range from 0.7 to 1.88 m ka^?1, while the lowest values (0.34–0.60 m ka^?1) are related to the low tectonic and seismic activity margins like the margin of Cyclades plateau. Lower subsidence rates (0.34–0.90 m ka^?1) were estimated for the period 146–18 ka BP (oxygen isotopic stages 6–2) and higher (1.46–1.88 m ka^?1) for the period from 425 to 250 ka BP (oxygen isotopic stages 12/10–8). A decrease of about 50% of the subduction rates in the Aegean margins was observed during the last 400 ka.During the isotopic stages 8, 10, 11 and 12, almost the 50–60% of the present Aegean Sea was land with extensive drainage systems and delta plains and large lakes in the central and North Aegean. Marine transgression in the North Aegean was rather occurred during the isotopic 9 interglacial period. The estimated palaeomorphology should imply fan delta development and sediment failures in the steep escarpments of the North Aegean margins and high sedimentation rates and turbidite sediment accumulation in the basins. It is deduced that the Black Sea was isolated from the Mediterranean during the Pleistocene prior oxygen isotopic stage 5.     

柴达木盆地东部尕海短钻岩芯记录的过去近400 a区域环境变化

干旱区湖泊沉积可以有效记录区域湿度变化及粉尘活动历史,位于柴达木盆地德令哈南部的咸水封闭湖泊尕海具有恢复区域环境变化的潜力.该地区的长序列环境演变研究已开展了较多的工作,但缺乏短尺度、高分辨率的近代以来的环境变化湖泊记录.通过对尕海深水区短钻岩芯放射性核素210Pb和137Cs的年代测定和沉积物各指标分析,认为尕海沉积物碳酸盐含量可以反映区域湿度变化;而粗颗粒组分(66.9μm)主要由风力搬运入湖,其含量可以指示区域粉尘活动历史.区域近400 a的环境变化可划分为3个阶段:1633 1750 AD:各指标出现大幅度波动,表现出该时期气候环境的不稳定和干湿交替,其中1650 1720 AD的变化波动尤为显著,这与太阳活动进入Maunder极小期存在一定的联系.1750 1950 AD:区域气候环境无明显波动,碳酸盐含量逐渐降低,湿度增加.1950 2010 AD:各指标变动剧烈,区域虽降水增多,但由于蒸发加强,湿度降低;1974 AD以后粗颗粒组分含量急剧上升,表现出高强度尘暴事件.     

Solar modulation of cosmogenic nuclide production over the last millennium: comparison between C and Be records

For about the last 30 years it has been recognized that the high frequency component of the tree rings ¹⁴C/¹²C record is dominated by the modulation of the cosmic ray flux by the solar wind. In particular, it has been demonstrated that the three most recent periods of low sunspot occurrence were characterized by high values of atmospheric ¹⁴C/¹²C. During the last millennium other periods of high ¹⁴C/¹²C values were observed but their solar origin is still debatable. In the present work we compare these fluctuations with an independent record of cosmogenic ¹⁰Be measured in ice from the South Pole to check the solar origin of the observed ¹⁴C/¹²C variations. In order to compare quantitatively the results obtained on ¹⁰Be and ¹⁴C, it is necessary to take into account the different behaviour of these two cosmogenic isotopes, and especially the damping effect of the carbon cycle in the case of ¹⁴C. As an input to a 12-box numerical model we used the relative fluctuations of the ¹⁰Be concentrations record measured in South Pole ice and converted it into a synthetic ¹⁴C record. We took into account the fact that ¹⁰Be modulation is enhanced in polar regions due to the orientation of the geomagnetic field. As expected, the fluctuations of the modelled ¹⁴C record are much smaller (a factor of 20) than those observed for the raw ¹⁰Be record. In addition, the variations are smoother and shifted in time by a few decades. The ¹⁰Be-based ¹⁴C variations closely resemble the ¹⁴C measurements obtained on tree rings (R = 0.81). In particular, it is easy to identify periods of maximal ¹⁴C/¹²C which correspond to solar activity minima centred at about 1060, 1320 (Wolf), 1500 (Spörer), 1690 (Maunder) and 1820 (Dalton) yr A.D. Cross-correlation calculations suggest that there is no significant lag between the ¹⁰Be-based ¹⁴C and the tree-ring ¹⁴C records. Our study strongly suggests the dominance of the solar modulation on the cosmonuclide production variations during the last millennium.     

江汉平原江陵地区9ka以来古气候演化的沉积记录

从一起自然发病的中华绒螯蟹(Eriocheir sinensis H．Milne-Edwards)肝胰腺中,分离做纯培养的6株(HQ010516A-1至HQ010516A-6)鳗利斯顿氏菌(Listonella anguillarum),进行了形态特征、主要理化特性等方面的检验．同时择代表菌株(HQ010516A-1)测定了16S rRNA基因序列、构建了系统发育树．另外,以代表菌株(HQ010516A-1)对健康蟹进行了人工感染试验,结果表明了该菌株在所检病例的病原学意义;用37种抗菌类药物对3株菌所做的药敏试验,结果均表现对头孢噻肟等29种药物呈现敏感或高度敏感(抑菌圈直径在16-40 mm)、对头孢唑啉等3种药物呈低度敏感(抑菌圈直径在10-12 mm)、对青霉素G等5种药物耐药(无抑菌圈形成)．     

Responses of infaunal composition, biomass and production to discharges from a marine outfall over the past decade

The largest municipal outfall on the west coast of Canada discharges into the southeastern Strait of Georgia, where high sedimentation from the Fraser River has maintained stable sediment geochemical and contaminant conditions from 2001 to 2011. Outfall exposure has not affected trophic structure or diversity (H'), but has significantly affected faunal composition and species richness, resulting in loss of crustaceans and echinoderms near-field. Organic biomass and production have mostly remained within expected background ranges for the Strait, due to recent increases in a low oxygen tolerant polychaete in the high deposition zone. A significant regional shift in faunal composition occurred after 2003, followed by gradual declines in richness, abundance, calcareous organisms and production. This cannot be attributed to changes in outfall exposure, but is exaggerated by it. We hypothesize that changing river flow, extreme events and shifts in offshore upwelling water temperature, oxygen and pH may be increasing geochemical stress in benthos.     

白令海岩芯记录的冰消期14 ka以来地磁场强度和方向

对白令海北部陆坡B5-4孔进行了古地磁和岩石磁学研究,尝试获得该岩芯的地磁场相对强度和方向变化信息.结果表明:(1)除0~0.44 m沉积物的磁性矿物粒度比其余沉积物细以外,岩芯的磁学性质总体均一,其记录的地磁场相对强度可以与北大西洋ODP983孔相应记录进行高度对比.(2)根据B5-4孔与ODP983孔地磁场相对强度记录对比结果,并结合该孔4.54~4.56 m处有孔虫AMS14C测年结果,可以确定3个深度-年龄对比点,并据此初步建立了B5-4孔的年龄模型.(3)B5-4孔磁偏角和磁倾角记录与贝加尔湖、北美、欧洲全新世以来的记录和当地地磁场球谐模型结果一致,其对比点丰富了强度对比点年龄模型,揭示了14 cal ka B.P.以来近线性的沉积模式.(4)根据与中国东部陆架两个钻孔的磁倾角对比,我们推测B5-4孔9~14 ka之间两段浅化的磁倾角可能是哥德堡极性事件的记录,但是受到早期成岩或者沉积物平滑效应的影响.以上结果足以证明,地磁场相对强度和方向变化可以从适宜的白令海沉积物中获得,它可以为确定该海区沉积物年龄提供相关辅助信息,有助于解决北极、亚北极古环境和古海洋研究中由于有孔虫等钙质生物壳体缺乏导致的年龄信息匮乏问题.     

近三百年来洪泽湖演变过程及其原因分析

洪泽湖是淮河水系中最重要的湖泊之一,是我国的第四大淡水湖,它在防洪、灌溉、航运、跨流域调水以及水资源与水环境保护等方面发挥着重要作用.过去300年来,由于黄淮关系的演变和人类活动的影响,洪泽湖水域面积发生剧烈变化.研究湖泊水域空间变化有助于认识流域环境变化与人类活动影响.本文利用18世纪初以来的古地图、历史文献资料及1981-2016年期间的7期遥感影像数据,采用遥感和地理信息系统技术相结合的方法,分析了近300年来洪泽湖水域时空演变过程及其原因.研究结果表明：过去300年来,洪泽湖面积总体呈减少趋势,年际缩减速率为0.17%,且湖域范围总体表现为由四周向中心缩小的趋势,其中西南湖域的形态变化最为显著.具体而言,清中期以前,黄河多次夺泗入淮,洪泽湖面积变化受黄淮关系、高家堰等水利枢纽的修建以及降水等因素影响.至清末,洪泽湖面积由3078.78 km²下降至2335.73 km²,共减少743.05 km²,其空间形态也发生了剧烈变化,该时期黄河改道、降水以及人口增长导致的湖滨围垦是影响洪泽湖演变的主要原因.建国以来（1949-2016年）,洪泽湖面积进一步缩小,由1757.60 km²下降至1488.43 km²,共减少了269.17 km²,其中1995-2000年间湖泊面积下降最为显著,共减少了281.43 km²,湖泊动态变化度达到2.78%,该时期自然因素对湖泊水域面积的影响减弱,而人口增长、围垦及水利工程的修建等人类活动逐渐成为影响洪泽湖演化的主导因素.     

过去40年太湖剧烈的湖泊物理环境变化及其潜在生态环境意义

过去40年,全球气候变暖、辐射变暗和变亮、风速减弱、气候异常波动等自然环境变化以及筑坝建闸、岸堤硬质化和调水引流等强烈人类活动势必会深刻改变太湖湖泊物理环境和过程,驱动湖泊生态系统演化.基于历史文献、档案数据以及气象水文和透明度等长期观测数据,本文系统梳理了太湖气温、水温、风速、水位和透明度等物理环境空间分布和长期变化特征,探讨了气温和风速、水位和透明度相互协同作用机制及其潜在生态环境意义.受全球变化和城市化等影响,过去40年太湖气温和水温呈现显著升高趋势,而近地面风速则表现为持续下降,湖泊增温和风速下降有利于藻类生长和蓝藻水华漂浮聚集,某种程度上增加了蓝藻水华出现频次和集聚的面积.为防洪和满足流域日益增长的水资源需求,闸坝管控和调水引流使太湖水位呈现缓慢增加趋势,而入湖污染物增加和富营养化则造成水体透明度逐渐下降,致使透明度与水位(水深)的比值明显降低,减少了湖底可利用光强,恶化水下光环境,在一定程度上驱动了太湖水生植被和草型生态系统退化.湖泊物理环境长期变化逐渐拓展了太湖藻型生境空间而压缩了草型生境空间,加剧了草型生态系统向藻型生态系统转化和增强了藻型生态系统的自我长期维持.太湖湖...     

近40年台特玛-康拉克湖泊群水域变化遥感监测

车尔臣河下游自1989年改道以来,河道北边形成若干小湖,使台特玛湖-康拉克地区的水域格局发生了很大变化.干涸30多年的台特玛湖,随着自2000年起塔里木河下游应急生态输水工程的实施开始形成大片水域,且水域面积呈扩大趋势.2002年车尔臣河改道结束后康拉克地区的湖泊格局基本形成,而台特玛湖地区的水域则继续大幅变化.本文在1972-2012年102期遥感影像及其相关辅助数据基础上进行各项定量分析,详细描述台特玛湖-康拉克地区的水域变化过程,总结变化趋势,试图找出变化主导因素.笔者认为台特玛湖-康拉克地区的湖泊水域景观格局变化自1970s-2000年主要受车尔臣河径流量年际变化的控制,而21世纪以来则主要受塔里木河下游应急生态输水工程措施的影响.     

亚高山湿地摇蚊亚化石记录的近两百年来环境演化——以重庆葱坪湿地为例

偏远的亚高山湿地受人为活动直接干扰较小,是追踪气候变化和大气沉降双重影响下湿地生态系统演化的理想研究地.本研究以位于巫山的葱坪湿地为研究对象,基于一根50 cm沉积岩芯的²¹⁰Pb和¹³⁷Cs测年、摇蚊亚化石和元素序列,探讨该湿地近200年来环境演化历史.结果表明,摇蚊种群由1910年之前的Chironomus anthracinus-type、Limnophyes sp.、Cladotanytarsus mancus-type 1变为1910-1925年的C.mancus-type 1、C.anthracinus-type、Procladius sp.和Endochironomus impar-type的优势组合,这些优势种均指示浅水环境.此后,耐营养种E.impar-type、Polypedilum nubeculosum-type和C.anthracinus-type逐渐成为优势种.冗余分析表明,总磷、总碳和钙是解释摇蚊组合变化的显著环境因子.20世纪30年代以前摇蚊种群可能与进入湿地的径流量小、水位较低相关,而20世纪中叶以来摇蚊组合变化指示大气沉降增长背景下湿地营养富集过程.在大气沉降和气候变化的双重影响下,耐营养属种增加和生物多样性降低表明葱坪湿地生态环境正发生退化.     

Water isotopic variability in Mallorca: a path to understanding past changes in hydroclimate

This paper reports the first results on δ¹⁸O and δ²H analysis of precipitations, cave drip waters, and groundwaters from sites in Mallorca (Balearic Islands, western Mediterranean), a key region for paleoclimate studies. Understanding the isotopic variability and the sources of moisture in modern climate systems is required to develop speleothem isotope‐based climate reconstructions. The stable isotopic composition of precipitation was analysed in samples collected between March 2012 and March 2013. The values are in the range reported by GNIP Palma station. Based on these results, the local meteoric water line (LMWL) δ²H = 7.9 (±0.3) δ¹⁸O + 10.8 (±2.5) was derived, with slightly lower slope than Global Meteoric Water Line. The results help tracking two main sources of air masses affecting the study sites: rain events with the highest δ¹⁸O values (> ?5‰) originate over the Mediterranean Sea, whereas the more depleted samples (< ?8‰) are sourced in the North Atlantic region. The back trajectory analysis and deuterium excess values, ranging from 0.4 to 18.4‰, further support our findings. To assess the isotopic variation across the island, water samples from eight caves were collected. The δ¹⁸O values range between ?6.9 and ?1.6‰. With one exception (Artà), the isotopic composition of waters in caves located along the coast (Drac, Vallgornera, Cala Varques, Tancada, and Son Sant Martí) indicates Mediterranean‐sourced moisture masses. By contrast, the drip water δ¹⁸O values for inland caves (Campanet, ses Rates Pinyades) or developed under a thick (>50 m) limestone cap (Artà) exhibit more negative values. A well‐homogenized aquifer supplied by rainwaters of both origins is clearly indicated by groundwater δ¹⁸O values, which show to be within 2.4‰ of the unweighted arithmetic mean of ?7.4‰. Although limited, the isotopic data presented here constitute the baseline for future studies using speleothem δ¹⁸O records for western Mediterranean paleoclimate reconstructions. Copyright © 2016 John Wiley & Sons, Ltd.