基于GIS的农业面源硝酸盐地下水污染动态风险评价

地下水中的硝酸盐污染具有全球性,这不仅是一个环境问题,也是一个经济和人类健康问题。DRASTIC方法可以进行地下水污染的脆弱性评价,但是却没有涵盖风险的概念,也忽视了污染物随地表水流运动的动态特性。因此,所得结果可能有碍于“欧洲水管理框架指南”在地下水水质管理中的执行。笔者基于DRASTIC方法开发了一个动态风险评价方法,并将其运用于英国北爱尔兰Upper Bann流域中的一个小流域。研究区地下水硝酸盐污染风险评价结果表明,此方法将有效地帮助决策者在流域范围内开展农业面源地下水污染预防措施。“非常高风险”和“高风险”区分别占研究区面积的5.1%和10.5%。此结果可帮助当地政府针对流域内这些“非常高风险”和“高风险”区的特点制订地下水质保护政策。此方法同样适用于任何面源可溶性污染物的地下水污染动态风险评价。     

Nitrate pollution from agriculture in different hydrogeological zones of the regional groundwater flow system in the North China Plain

A survey of the quality of groundwater across a broad area of the North China Plain, undertaken in 1998 to 2000, indicates that nitrate pollution is a serious problem affecting the drinking water for a vast population. The use of nitrogen (N)-fertilizer in agriculture has greatly increased over the past 20 years to meet the food needs of the rapidly expanding population. During the study, 295 water samples were collected from wells and springs to determine the water chemistry and the extent of nitrate pollution. High concentrations of nitrate, especially in a recharge area along the western side, but also in the vicinity of Beijing and locally in other parts of the plain, pose a serious problem for the drinking water supply. In places, the nitrate concentration exceeds the maximum for safe drinking water of 45 mg/L. The intense use of N-fertilizer and the widespread use of untreated groundwater for crop irrigation contribute greatly to the problem, but no doubt the disposal of industrial and municipal waste into streams and infiltrating the aquifer also contribute to the problem; however, the lack of data prevents evaluation of those sources. In the recharge area, nitrate is found at depths of as much as 50 m. Near Beijing, relatively high concentrations of nitrate occur at depths of as much as 80 m. In the discharge area, in the vicinity of the Yellow River, high concentrations of nitrate occur at depths of <8 m.

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Electronic Supplementary Material Supplementary Material is available in the online version of this article at

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Resumen Contaminacíon de nitratos a causa de prácticas agrícolas en diferentes zonas hidrogeológicas del sistema de flujo regional de aguas subterráneas en la planice del norte de China. Un estudio de la calidad del agua subterránea en una zona amplia de la planice del norte de China se llevó a cabo entre 1998 y el año 2000. Este estudio indica que la contaminación de nitratos es un problema grave que afecta el agua potable de una vasta población. El uso de fertilizantes a base de nitratos en la agricultura ha aumentado considerablemente durante los últimos 20 años para satisfacer las necesidades alimentices de la creciente población. Durante el estudio, se tomaron 295 muestras de pozos de agua y manantiales para determinar la química de las aguas y el grado de contaminación por nitratos. Altas concentraciones de nitratos, especialmente en una zona de recarga a lo largo del lado oeste, asì como en la cercanía a Pekín y en zonas locales en otras partes de la planicie, presentan un problema serio al sumunistro de agua potable. En ciertos lugares, la concentracióon de nitratos excede el nivel máximo de seguridad para el agua potable 45 mg NO₃/L. El intenso uso de fertilizantes de nitratos y el abundante uso de agua subterránea sin tratamiento para la irrigación de cultivos contribuyen sustancialmente al problema. Sin embargo, sin lugar a dudas, la descarga de deshechos industriales y municipales en arroyos y en el acuífero también contribuyen al problema. La falta de datos impide la evalución de dichas fuentes. En la zona de recarga se encuentran nitratos hasta los 50 m de profundidad. Cerca a Pekín, concentraciones relativamente altas de nitrato ocurren hasta los 80 m de profunidad. En las zonas de descarga afectadas por el Río Amarillo las concentraciones altas de nitrato se encuentran solamente a menos de 8m de profundidad.

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Resumé Une campagne dévaluation de la qualité de leau souterraine entreprise entre 1998 et 2000 à travers une vaste étendue de la plaine du nord en Chine indique que la pollution par les nitrates est un problème sérieux qui affecte la qualité de leau souterraine pour une abondante population. Lutilisation de fertilisants azotés pour lagriculture a augmenté considérablement durant les 20 dernières années afin de rencontrer les besoins alimentaires dune population à forte croissance. Lors de cette étude, 295 échantillons deau ont été prélevés dans des puits et sources naturelles afin de déterminer la composition chimique de leau souterraine ainsi que létendue de la pollution par les nitrates. Des concentrations élevées de nitrates, en particulier dans une zone de recharge le long de la limite ouest de la plaine, mais aussi dans la région de Beijing et sporadiquement dans la plaine, posent de sérieux problèmes à la consommation de leau souterraine. A certains endroits, la concentration en nitrates excède la valeur maximale acceptée pour la consommation qui est de 45 mg NO₃/L. Lutilisation intensive de fertilisants azotés ainsi que lutilisation répandue deau souterraine non traitée pour lirrigation contribuent pour beaucoup au problème, mais il ne fait pas de doute que le rejet des déchets municipaux et industriels dans les rivières et aquifères y est aussi pour quelque chose. Par contre, le manque de donnés ne permet pas dévaluer la contribution de chacune de ces sources. Dans la zone de recharge, les nitrates se retrouvent à des profondeurs allant jusquà 50 m. Près de Beijing, des concentrations relativement élevées de nitrate ont été mesurées à des profondeurs allant jusquà 80 m. Enfin, dans la zone démergence affectée par la rivière Jaune, les fortes concentrations se retrouvent à une profondeur maximale de 8 m.

     

非点源污染空间连续分布模型研究

非点源污染负荷的离散型分布不利于深入研究非点源污染与社会、环境等因素的关系,因此非常必要对其进行空间连续分布处理,但在对离散变量连续化过程中应注意尺度和信息增减等问题.以非点源污染中人畜产污为例,通过构建空间连续分布模型模拟计算人畜产污的数量及其分布.从验证的结果来看,这种非点源污染空间连续分布处理方法不但是必要的,也是可行的.     

Current status and cause analysis of microplastic pollution in sea areas in China

As a new type of pollutants in the marine environment,microplastics have attracted increasing attention from scientific researchers and environmental protection workers in China and abroad.However,for the microplastic pollution in sea areas in China,there are a very limited number of studies on its current status and few reviews of research on the microplastics.This paper reviews the surveys and researches of microplastics in the Bohai Sea,the Yellow Sea,the East China Sea,the South China Sea,and main estuaries in China carried out in recent years and proposes an outlook for future work,aiming to provide research suggestions and solutions for ecological protection against microplastic pollution in sea areas in China.Previous studies have shown that microplastics are widely distributed in water bodies and sediments in sea areas and major estuaries in China.The Pearl River Estuary,in the South China Sea suffers the most serious microplastic pollution,followed by the Bohai Sea.In contrast,the microplastic pollution in the Yellow Sea and the East China Sea is comparatively slight.Microplastics in sea areas in China are mainly fibrous and are concentrated in offshore areas with developed industry and a dense population(especially around estuaries and bays).In addition,they are widely affected by human activities,such as shipping,aquaculture,industry,and sewage discharge.Here the authors suggest unifying measurement units and research methods and developing related standard systems to carry out researches related to microplastics.Furthermore,this paper also suggests further deepening researches on both the source-sink process of microplastics and nanoscale microplastics while enhancing the development and implementation of related policies,aiming to promote researches and control of microplastics in sea areas in China.     

Duration of soil cadmium and lead pollution from shale-based alum production

The scope of this study is to assess the present impact from an historical emission source, in order to provide information on the duration of this metal pollution problem.The present distribution of cadmium and lead, emitted from a Swedish alumworks between 1726–1840, was studied in soils, sediments and ground water. The soil data imply that cadmium has disappeared from the surface soils during the 150 to 250 years that have passed since the emissions ceased. Lead concentrations of the soil are elevated only within 200 m from the site of the works. Further away, the lead concentrations are almost at background level. A possible explanation for this pattern, is that lead dispersed in large particles has not yet fully disintegrated and leached down the soil profile, in contrast to the smaller particles deposited further away.The metal concentrations in the ground water wells are slightly higher than the Swedish average but probably governed by the pH of the water, rather than the occurrence of large amounts of metals. Elevated lead concentrations were found in a few sediment samples in the river mouth downstream from the works. These elevated concentrations coincided with the abundant occurrence of small particles of used shale, indicating their origin.Cadmium is not found, at present, in the soil around the alumworks in concentrations substantially above background levels. Consequently, it is likely that the cadmium deposited in the area, has leached through the upper layers of the soil profile on its way to the sea sediments. Likewise, the lead concentrations in the soil beyond 200 m from the alumworks are not above background levels which indicate that losses through leaching have occurred at a rate of 0.5 to 1.5% yr⁻¹.Finally, comparisons with other long-term perspective studies give an opportunity to discuss the rate for the disappearance of an environmental problem.     

中国北方岩溶地下水污染分析

近年来,受气候变化和强烈人类活动的影响,环境物质及能量多频次、大范围的输入,极大程度上改变着岩溶水系统的水环境质量,岩溶水生态环境遭受不同程度的威胁和破坏,岩溶水水质日趋恶化。本文归纳分析了我国北方岩溶水系统水质特征、污染现状、污染来源及污染途径。我国北方岩溶水水质类型中硫酸盐型水和氯化物型水的分布逐渐增加,主要污染组分为总硬度、SO42-、F-、NO3-和TDS等。其中硫酸盐和硝酸盐污染强度和范围最大,呈现出显著的人类活动影响特征。依据我国北方岩溶系统结构及水力学特征,将岩溶水污染途径概括为：①连续入渗型——主要包括岩溶区地表水（河流、水库等）渗漏污染,城镇污水渠或排污管道破损引起的污水渗漏污染;②越流型污染——污染孔/裂隙水（含矿坑水/老窑积水等）越流污染岩溶水;③间歇入渗型——固废淋溶入渗和污水灌溉渗漏污染等。据此提出了推进岩溶水水资源保护和污染防治的合理化建议。     

农畜产品虚拟水研究的背景、方法及意义

虚拟水是近年出现在水资源管理领域的新概念,随着全球贸易的增加,虚拟水已成为影响区域水资源管理的重要因素。分析了虚拟水概念出现的经济背景,总结介绍了与农作物和畜产品相关的虚拟水含量的计算方法,以及国际上虚拟水贸易的基本情况,揭示了虚拟水在提高水资源效率、制定水资源战略的作用,以及对社会经济、水资源管理等方面的重要影响。     

Households’ willingness to reduce pollution threats in the Poyang Lake region,southern China

Environmental threats to wetland ecosystems are increasing, and these ecosystems are becoming increasingly sensitive to human impacts, leading to deterioration of these already fragile ecosystems. Poyang Lake is the largest freshwater lake in China and one of the most important wetlands in the world. However, water pollution and related environmental changes have increasingly drawn the scientific community's attention. The goal of this paper is to provide insights into the environmental threats to the Poyang Lake region as perceived from the households’ perspective, and to investigate their willingness to pay for conservation of the lake's environment. We collected both primary and secondary data through a questionnaire delivered to 270 households and analysis of existing water monitoring data. The major threat confronting the Poyang lake region is water pollution; water quality, as represented by the total nitrogen (TN) and total phosphorus (TP) concentrations and by chemical oxygen demand (COD), suggests a moderate to severe degree of eutrophication. The situation has worsened in recent years, particularly due to high TN and TP in agricultural drainage water caused by increasingly intensive use of chemical fertilizers by local farmers. Most households were willing to pay to mitigate these threats, but the magnitude of the payment was related to a farmer's dependence on the lake for their production and daily life. The results of our analysis will help managers develop more effective environmental management policies.     

An approach to studying heavy metal pollution caused by modern city development in Nanjing, China

 Nanjing is currently one of the fastest developing regions in terms of construction and economy in China. Heavy metal pollution is becoming more serious with the expansion of production and life scales. Four environmental units (highway, refinery, rubbish dumps associated with human daily life, and shoal of the Yangtse River) were selected from the region according to the geneses of the pollution to study and evaluate the distribution and mechanism of the contamination, the speciations of the polluting elements, and the geneses of the pollution in the soils and sediments. The purposes of the study are to understand generally the current situation and the cause of the pollution, and to provide a scientific basis to prevent and solve the pollution problem. At the same time, it would be helpful to probe the effective way of studying heavy metal pollution resulting from the development of modern cities and to accumulate data. It is indicated by the study that the heavy metals contained in the soil of the environmental unit of the highway are Pb, Co and Cr; in the soil of the refinery Cr, V, Pb, Ni, and Co; in the soil of the rubbish plot Co, Cu, and Sb; in the sediments of the shoal Pb, Co, Cu, and Ni. Fe-Mn oxide is given the first place to the speciations in polluting heavy metals transmitted by air. Carbonate is more in speciations of polluting heavy metals transmitted by water than in speciations of the metals transmitted by air. In the ten elements studied, Pb is most directly poisonous to the plants in the region; Co and Cu are the next, and Ni is the least. Heavy metal pollution has been occurring in the soils and sediments of the region and the situation will worsen if some effective measures are not taken. Received: 18 October 1997 · Accepted: 3 February 1998     

Microplastic pollution in Yellow River,China: Current status and research progress of biotoxicological effects

This study aims to comprehensively assess the environmental risks of microplastics in the Yellow River, achieving the following results through comprehensive research. The average microplastic abundances in the river waters and sediments are 5358–654000 n/m³ and 43.57–615 items/kg, respectively, and there are fewer microplastics in water samples than in sediments. Microplastics in the study area can be divided into five types according to their occurrence morphologies, namely fragments, foams, films, fibers, and particles. The most widely distributed pollution types in sediments include debris, fibers, and particles. In contrast, fibers are the dominant type in water samples, accounting for 68.18% –98.93%. The chemical components of the microplastics include polyethylene, polypropylene, polystyrene, polyethylene terephthalate, and polyvinyl chloride. The microplastics are in four colors, with white accounting for a higher proportion. The grain size of the microplastics in tributaries or lakes of the Yellow River is less than 2 mm, which makes them liable to enter organisms for enrichment. Furthermore, the sources of the microplastics are closely related to agricultural and industrial production and biological activities in habitats and exhibit seasonal and hydrological characteristics. The microplastics in the study area show the adsorption of metals and nonmetals to different degrees, which increases the pollution risks of heavy metals combined with microplastics. In addition, microplastics can accumulate in organisms in the Yellow River and cause physical, biochemical, and other damage to aquatic organisms, thus further posing carcinogenic risks to human beings. Therefore, it is necessary to study, monitor, and control the pollution and effects of microplastics in the Yellow River, in order to provide theoretical references for the control of pollution and ecological risk of microplastics in the river.©2021 China Geology Editorial Office.     

Trace-element variations in an annually layered stalagmite as recorders of climatic changes and anthropogenic pollution in Central China

We analyzed variations in the Sr/Ca, Ba/Ca, REE/Ca (REE: rare earth element), Zn/Ca, and Pb/Ca ratios preserved in an annually layered stalagmite, XL21, from central China. The stalagmite record spans the 95 year period AD 1914–2008. The Sr/Ca and Ba/Ca ratios have a significant positive correlation with the stalagmite's growth rate, suggesting that they were primarily controlled by growth-rate variations. Variations in REE/Ca ratios are consistent with local temperature changes, suggesting temperature influenced REE concentrations in the stalagmite over decadal to annual timescales. Higher temperature in this humid area can increase vegetation cover, microbial activity, and organic decomposition in the soil, resulting in enhanced pCO₂, organic matter concentration and reduced pH, and consequently increased REE mobilization from the overlying soil layer and host rock. Higher temperatures may also increase the natural Zn mobilization from the overlying soil mediated by organic matter and consequently may have led to increased Zn retention in XL21. An increasing trend is seen in the Pb/Ca ratios from XL21 since 1985, which is consistent with increased lead production in this area, and indicates an increase in mine-derived lead pollution in the local environment over the past 30 years.     

Export upgrading and environmental performance: Evidence from China

This study argues that export upgrading can, but does not necessarily, lead to environmental improvement. A synergy between global and local linkage determines the likely disjuncture between export upgrading and environmental improvement. On the basis of the panel data covering 261 prefectural-level cities in China during 2003–2011, this study applies the decomposition of export sophistication to quantify diverse upgrading types. It also divides the sample cities into groups and uses the fixed-effect regression by groups to investigate the role of local linkages. Empirical findings indicate that environmental improvement associated with export upgrading in China has largely relied on changing product mix to avoid environmental costs, exhibiting a significant displacement effect. The role of efficiency promotion of production process is still insignificant. Local linkage may alter the environmental effects of export upgrading. Specialisation in polluting production can help cities to change product mix through the agglomeration of related firms. Stringent environmental regulation protects cities from the export–environment disjuncture through imposing additional costs. These findings suggest that the greening efforts of China should take one step further from export restructuring to efficiency promoting.     

中国非点源污染负荷计算研究现状与存在问题

非点源污染负荷计算对水污染总量控制具有重要意义,为分析中国非点源污染负荷计算研究的现状与问题,在系统调研相关文献的基础上,将中国常用的非点源污染负荷计算方法总结为三大类:输出系数模型、实证模型和机理模型,阐述了各种模型的特点及其在中国的研究和应用情况;从非点源污染的界定、产污量和排污量的区别、国内和国外非点源污染产生环境的差异以及平原河网地区非点源污染负荷的计算4个方面分析了中国非点源污染负荷计算研究存在的主要问题;认为模型和计算方法适应研究区的环境特征是研究工作取得成功的关键,今后要加强实证研究、理论研究与模型开发的结合,逐步建立适应中国环境特点的非点源污染负荷计算方法体系。     

Elements pollution in the extremely high tumor risk residents in Chaoshan littoral, southern China

Background ＆ aim： To investigate and analyze the elements pollution in the extremely high tumor risks residents in the Chaoshan littoral, southern China. Methods： 19 elements including Cr, Mn, Ni, Sr, Pb, Zn, Co, Sn, Th, Tl, Se, Hg, Cu, Mo, Cd, Sb, U, Ge, As, and Al were measured from 145 hair samples of residents from the high-risk Nanao Island （mortality of cancer 173-156/106 in recent 30 years）, Shantou high-risk village （mortality of cancer 230.4/106 in recent three years）, and two controls Shanwei （mortality of cancer 32/106 in 1970s） and Meizhou Hakka （incidence of cancer 103/106 ） using AAS, AFS, ICP-MS methods collaborated with Beijing University. And 21 samples of water, 18 samples office from the Nanao Island, Shantou high-risk village, and other low-risk controls were measured using the same methods. Results： The element analysis showed that levels of CD, PB in the Shantou high-risk village were the highest, Hg, MN, SR, SB, TH, U on the Nanao Island were the highest in hairs. Conclusions： It is indicated that there occurred elements pollution among the local high-risk population.     

矿山水土污染与防治对策研究

矿山水土环境污染是采矿活动引发的主要环境地质问题之一。我国矿山数量众多,水土污染比较普遍,尤以金属矿山最为严重,矿山水土污染防治是今后开展国土空间生态保护修复的重要内容。基于全国矿山地质环境摸底调查成果资料,对矿业活动不同阶段的水土污染风险以及不同矿山的水土污染类型、特征和污染物迁移演化规律等进行了研究。分析指出:矿业活动过程包括勘探、建矿、开采、洗选、冶炼等多个阶段,而水土污染风险贯穿于矿业活动全过程,不同阶段的污染风险不同;矿产资源开发造成的水土污染物类型、特征因开采的矿产类型不同而不同,呈现出特征污染物与矿体母岩的高度相关性;矿山及其周边污染物的迁移作用受污染物自身的物理化学性质和外界环境条件的影响,在矿山长期持续开采条件下矿山水土污染物存在累积效应,而矿产资源集中开采区的污染物扩散表现出叠加效应。通过对某典型水土环境污染案例的分析研究,初步证实了上述推断。根据我国矿山水土环境污染多发性和复杂性的特点,建议今后开展矿山水土污染防治工作应区分不同类型矿山、不同地质环境条件、不同污染物特征、不同污染程度,采取分类施策、系统修复、标本兼治的对策,以实现矿山环境明显改善。     

陕北风沙滩地区包气带抗污能力试验研究

为了研究陕北风沙滩地区包气带风积沙的抗污能力,在榆林煤化工厂厂区及其周边地区选择4个试验点,采用双环入渗法,选择渣场炉渣浸出液（Cd、Cr、Cu、Mn、Ni和Pb重金属污染物溶液）进行渣场污水入渗试验,采用人工配置污染物溶液（COD、氨氮、F、石油类和挥发酚）进行了配污试点试验。渣场污水入渗试验过程中,由于水流的冲刷作用,剖面上大部分污染物的含量都小于入渗前的含量;而渗后样的测定结果则表明包气带风积沙对污水中Cr、Cu、Mn、Ni和Pb的净化能力较强。配污试点试验表明包气带对无机污染物的阻滞作用会延缓其对地下水的污染,石油类在包气带中的运移速度缓慢,难以在水流的作用下到达含水层,而COD容易造成地下水污染,挥发酚对含水层的污染能力要小于COD。应考虑采取适当方式降低地下水位,增大包气带厚度,以加强包气带对地下水的保护能力。     

Dynamic assessment of pollution risk of groundwater source area in Northern China

Based on the dynamic analysis and research of pollution risk of groundwater sources, this paper creates the dynamic assessment method of pollution risk of groundwater source area under the theory of “source-pathway-receptor”, and applies this method to one typical fissure karst groundwater source area in northern China. Following the 30-year petroleum pollutant migration simulation and pollution risk assessment of groundwater source area, this study finds that the very high risk zone is mainly located in Q Petrochemical Company and the surrounding area and the area adjacent to River Z. Within this period of thirty years, the pollution risk of groundwater source area has showed a dynamic trend that features an inverted “V” shape. The ratio of very high risk zone to the total area will be 18.1%, 17.47% and 16.62% during the tenth year, the twentieth year and the thirtieth year separately, and will reach the highest level of 19.45% during the fifteenth year. Meanwhile, the vertical migration distance of pollutant centre concentration changed from the surface soil at the outset to the deepest point of about 250 meters underground during the tenth year. The results of this risk assessment indicate the dynamic feature of pollution risk. The dilution, degradation and migration of petroleum pollutants in groundwater system contribute to an ultimate decline in pollution risk.     

Influence of transboundary air pollution on air quality in southwestern China

Air pollution is a grand challenge of our time due to its multitude of adverse impacts on environment and society,with the scale of impacts more severe in developing countries,including China.Thus,China has initiated and implemented strict air pollution control measures over last several years to reduce impacts of air pollution.Monitoring data from Jan 2015 to Dec 2019 on six criteria air pollutants(SO2,NO2,CO,O3,PM2.5,and PM1o)at eight sites in southwestern China were investigated to understand the situation and analyze the impacts of transboundary air pollutants in this region.In terms of seasonal variation,the maximum concentrations of air pollutants at these sites were observed in winter or spring season depending on individual site.For diurnal variation,surface ozone peaked in the afternoon while the other pollutants had a bimodal pattern with peaks in the morning and late afternoon.There was limited trans-port of domestic emissions of air pollutants in China to these sites.Local emissions enhanced the concen-trations of air pollutants during some pollution events.Mostly,the transboundary transport of air pollution from South Asia and Southeast Asia was associated with high concentrations of most air pollu-tants observed in southwestern China.Since air pollutants can be transported to southwestern China over long distances from the source regions,it is necessary to conduct more research to properly attribute and quantify transboundary transport of air pollutants,which will provide more solid scientific guidance for air pollution management in southwestern China.     

利用漫反射光谱鉴定红粘土中针铁矿和赤铁矿

针铁矿(Gt)和赤铁矿(Hm)是广泛存在于土壤和沉积物中的重要铁矿物。这两种矿物在土壤和沉积物中含量很低,常规的测试手段很难有效地测定其含量。利用反射光谱联合加热处理的方法,可对土壤及沉积物样品中针铁矿和赤铁矿进行定性或半定量测定。实验结果显示,样品加热到300℃后,针铁矿的反射光谱的一阶导数特征峰发生了变化,赤铁矿的一阶导数特征峰却没有明显的变化。因此加热前后样品反射光谱一阶导数的变化取决于针铁矿和赤铁矿的含量。利用这种方法估计黄土高原第三纪红粘土样品中的赤铁矿含量约为0.3%～0.4%,针铁矿含量约为0.5%～1%。