首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 15 毫秒
1.
Distribution of colloidal trace metals in the San Francisco Bay estuary   总被引:11,自引:0,他引:11  
The size distribution of trace metals (Al, Ag, Cd, Cu, Fe, Mn, Ni, Sr, and Zn) was examined in surface waters of the San Francisco Bay estuary. Water samples were collected in January 1994 across the whole salinity gradient and fractionated into total dissolved (<0.2 μm colloidal (10 KDa–0.2 μm) and < 10 kDa molecular weight phases. In the low salinity region of the estuary, concentrations of colloidal A1, Ag, and Fe accounted for ≥84% of the total dissolved fraction, and colloidal Cu and Mn accounted for 16–20% of the total. At high salinities, while colloidal Fe was still relatively high (40% of the dissolved), very little colloidal Al, Mn, and Cu (<10%) and no colloidal Ag was detectable. Colloidal Zn accounted for <3% of the total dissolved along the estuary, and colloidal Ni was only detectable (<2%) at the river endmember. All of the total dissolved Cd and Sr throughout the estuary consisted of relatively low molecular weight (<10 kDa) species. The relative affinity of metals for humic substances and their reactivity with particle surfaces appear to determine the amounts of metal associated with colloids. The mixing behavior of metals along the estuary appears to be determined by the relative contribution of the colloidal phase to the total dissolved pool. Metals with a small or undetectable colloidal fraction showed a nonconservative excess (Cd, Cu, Ni, and Mn) or conservative mixing (Sr) in the total dissolved fraction, relative to ideal dilution of river water and seawater along the estuary.

The salt-induced coagulation of colloidal A1, Fe, and Cu is indicated by their highly nonconservative removal along the salinity gradient. However, colloidal metals with low affinity for humic substances (Mn and Zn) showed conservative mixing behavior, indicating that some riverine colloids are not effectively aggregated during their transport to the sea. While colloidal metal concentrations correlated with dissolved organic carbon, they also covaried with colloidal Al, suggesting that colloids are a mixture of organic and inorganic components. Furthermore, the similarity between the colloidal metal:A1 ratios with the crustal ratios indicated that colloids could be the product of weathering processes or particle resuspension. Distribution coefficients for colloidal particles (Kc) and for large, filter-retained particles (Kd) were of the same magnitude, suggesting similar binding strength for the two types of particles. Also, the dependence of the distribution coefficients on the amount of suspended particulate matter (the so-called particle concentration effect) was still evident for the colloids-corrected distribution coefficient (Kp+c) and for metals (e.g., Ni) without affinity for colloidal particles.  相似文献   


2.
The annual salt budget of the Zuari is examined. The characteristics of the estuary differ markedly from the low run off season during November–May to the heavy run off period of the southwest monsoon from June to October. During November–May the estuary is vertically mixed and the two processes controlling the transport of salt are run off induced advective transport out of the estuary, and tidally induced diffusive transport into the estuary. The magnitude of the latter is about 20% larger, leading to a salinity rise in the estuary. The diffusion coefficient has been estimated to be 233 ± 101 m2/sec. With the onset of the southwest monsoon, the run off increases dramatically, and the estuary loses about 75% of its salt during the first two months of the season. About 2/3 of this loss is recovered in the next two months when the run off decreases. Because the estuary is partially stratified during June–October, gravitational circulation is expected to play a role in addition to tidal diffusion and run off. The magnitude of its contribution has, however, not yet been determined.  相似文献   

3.
Seasonal and interannual patterns in the spatial distribution of bluefish (Pomatomus saltatrix) within a Middle Atlantic Bight estuary were examined using multipanel gillnets fished biweekly at 14 fixeds stations in the Sandy Hook Bay-N avesink River estuary during May–November of 1998 and 1999. To characterize habitats along the estuarine gradient, we measured several abiotic and biotic variables concurrently with gillnet sampling. Juvenile (age-0 and age-1+) bluefish were captured regularly during both years along with large numbers of Atlantic menhaden (Brevoortia tyrannus), which were confirmed by diet analyses to be bluefish’s primary forage species. The date of initial appearance of age-0 bluefish and menhaden in the estuary varied between years and may have been related to interannual differences in seawater temperatures on the continental shelf during spring. Delayed estuarine arrival of prey fishes may have contributed to variability in bluefish diets between years. Within the estuary, bluefish spatial distribution were consistent across seasons and years: bluefish were most common in areas associated with high concentrations of suspended materials and the presence of menhaden. Community analyses also indicated habitat overlap between bluefish and menhaden. Spatial distribution patterns revealed the consistent occurrence of piscivorous bluefish in shallow estuarine habitats that retained suspended materials and aggregated prey fishes. Foraging success of bluefish and other estuarine piscivores may be closely linked with the availability of these productive habitat, highlighting the need for future study of biological interactions and the governing physical processes.  相似文献   

4.
Variation of temperature and salinity in the lower 22 km stretch of the Gautami-Godavari estuary are reported during four different seasons; hot-weather, south-west monsoon, post-monsoon and winter seasons. The seasonal variation in temperature is small, with a high of about 30°C during hot-weather season and a low of about 26°C during winter season. Unlike temperatures, the salinities in the estuary show large seasonal fluctuations. During south-west monsoon surface salinities were low (0 to 8‰) due to high fresh water run off into the estuary. During hot-weather season surface salinities of 25 to 30‰ were observed due to negligible fresh water run off.  相似文献   

5.
Significant coherence among time series of environmental and biological production variables suggested mechanistic pathways through which climate contributed to the downward shift in estuarine production (biomass) in northern San Francisco Bay estuary, 1975–1993. Climate directly and indirectly affected physical processes in the estuary through precipitation and its subsequent impact on streamflow and physical variables affected by streamflow. Climate also directly influenced air temperature and wind velocity. The influence if climate was evaluated through a climate index based on sea level pressure. A shift in this climate index in the early 1980s coincided with changes in many environmental variables including water transparency, water temperature, wind velocity, and rainfall. These physical changes were accompanied by a decrease in diatom, total zooplankton, andNeomysis mercedis carbon at the base of the food web throughout the estuary. Box-Jenkins time series coherence analysis was used to quantify associations among these physical, chemical, and biological time series for nine regions of the estuary. These associations were used to develop a conceptual model of mechanistic pathways that directly linked food web carbon production to climate. Strong coherence among diatom, zooplankton, andN. mercedis carbon time series suggested climate also had an indirect impact on food web production through trophic cascade. Differing mechanistic pathways among the nine regions of the estuary suggested climate was an important contributor to the spatial variability in total food web production and trophic structure.  相似文献   

6.
Phytoplankton chlorophyll a concentration, biovolume, cell diameter, and species composition differed across the narrow, low salinity zone between 0.6‰ to 4‰ and may influence copepod food availability in the northern San Francisco Bay Estuary. The highest chlorophyll a concentrations (range 3.2–12.3 μg 1?1), widest cell diameters (>5 μm diam), highest diatom densities and highest production rates of >10 μm diam cells occurred at the landward edge of the salinity zone in April during a strong spring tide and May during a strong neap tide. Near optimum predator/prey ratios, large prey estimated spherical diameters, and high chlorophyll a concentrations suggest these phytoplankton communities provided good food quantity and quality for the most abundant copepods, Eurytemora affinis, Sinocalanus doerrii, and Pseudodiaptomus forbesi. At the center of the zone, chlorophyll a concentrations, diatom densities, and production rates of >10 μm diam cells were lower and cell diameters were smaller than upstream. Downstream transport was accompanied by accumulation of phytoplankton with depth and tide; maximum biomass occurred on spring tide. The lowest chlorophyll a concentrations (1.4–3.6 μg 1?) and consistently high densities (3,000–4,000 cells ml?1) of <5 μm diam cells occurred at the seaward edge of the zone, where the green alga Nannochloris spp. and the bluegreen alga Synechococcus spp. were the most abundant phytoplankton. Low chlorophyll a concentrations and production rates of >10 μm diam cells, small prey estimated spherical diameters, and high predator/prey ratios suggested the seaward edge of the zone had poor phytoplankton food for copepodids and adult copepods. The seaward decrease in phytoplankton chlorophyll a concentration and cell diameter and shift in species composition in the low salinity zone were probably a function of an estuary-wide decrease in chlorophyll a concentration, cell diameter, and diatom density since the early 1980s that was enhanced in the low salinity zone by clam herbivory after 1987. *** DIRECT SUPPORT *** A01BY090 00008  相似文献   

7.
Four polymorphic loci in seven natural oyster (Crassostrea virginica Gmelin) populations of the Chesapeake Bay were analyzed by protein-gel electrophoresis for genetic variation. Samples of about 100 each were taken in 1977 along environmental gradients from stations in the James and Potomac rivers. The distribution of genotypes at four loci for each of the stations was nog significantly different from Hardy-Weinberg expectations. At two loci (Pgi andLap-2), a pool of all seven stations was also in equilibrium. Significant genetic differentiation between rivers was detected for two other loci (Pgm-1 andLap-1), and frequency of one genotype (Lap-1 95/95) was significantly correlated with mean temperature over the water monitoring period (1972–1977).  相似文献   

8.
Records of stable carbon isotopes (δ13C) are presented from cores collected from four San Francisco Bay marshes and used as a proxy for changes in estuary salinity. The δ13C value of organic marsh sediments are a reflection of the relative proportion of C3 vs. C4 plants occupying the surface, and can thus be used as a proxy for vegetation change on the marsh surface. The four marshes included in this study are located along a natural salinity gradient that exists in the San Francisco Bay, and records of vegetation change at all four sites can be used to infer changes in overall estuary paleosalinity. The δ13C values complement pollen data from the same marsh sites producing a paleoclimate record for the late Holocene period in the San Francisco Bay estuary. The data indicate that there have been periods of higher-than-average salinity in the Bay estuary (reduced fresh water inflow), including 1600-1300 cal yr B.P., 1000-800 cal yr B.P., 300-200 cal yr B.P., and ca. A.D. 1950 to the present. Periods of lower-than-average salinity (increased fresh water inflow) occurred before 2000 cal yr B.P., from 1300 to 1200 cal yr B.P. and ca. 150 cal yr B.P. to A.D. 1950. A comparison of the timing of these events with records from the California coast, watershed, and beyond the larger drainage of the Bay reveals that the paleosalinity variations reflected regional precipitation.  相似文献   

9.
Egg production of planktonic copepods, is commonly measured as a proxy for secondary production in population dynamics studies and for quantifying food limitation. Although limitation of copepod egg production by food quantity or quality is common in natural waters, it appears less common or severe in estuaries where food concentrations are often high. San Francisco Estuary, California, has unusually low concentrations of chlorophyll compared to other estuaries. We measured egg production rates of three species ofAcartia, with dominate the zooplankton biomass at salinity above 15 psu, on 36 occasions during 1999–2002. Egg production was determined by incubating up to 40 freshly collected individual copepods for 24 h in 140 ml of ambient water. Egg production was less than 10 eggs female−1 d−1 most of the year, but as high as 52 eggs female−1 d−1 during month-long spring phytoplankton blooms. Egg production was a saturating function of total chlorophyll concentration with a mean of 30 eggs female−1 d−1 above a chlorophyll concentration of 12±6 mg chl m−3. We take chlorophyll to be a proxy for total food ofAcartia, known to feed on microzooplankton as well as phytoplankton. These findings, together with long-term records of chlorophyll, concentration and earlier studies of abundance of nauplius larvae in the estuary, imply chronic food limitation ofAcartia species, with sufficient food for maximum egg production <10% of the time over the last 25 yr. These results may show the most extreme example of food limitation of copepod reproduction in any temperate estuary. They further support the idea that estuaries may provide suitable habitat forAcartia species by virtue of other factors than high food concentration.  相似文献   

10.
A monthly trace element sampling of the lower Mississippi River, utilizing ultra-clean methods, was conducted from October 1991 to December 1993. Dissolved concentrations were determined for Fe, Mn, Zn, Ph, V, Mo, U, Cu, Ni, Cd, Rb, and Ba. The results show significant seasonal dissolved concentration changes for a number of elements. Specifically, dissolved Mn and Fe are found to increase rapidly in the fall and then decrease in the spring. Zn and Pb follow a similar seasonal trend, though with lower percentage concentration changes. V, Mo, and U follow an opposite seasonal trend to Mn and Fe. The data do not allow a complete determination of the causes of this variability. However, changes in the adsorption process do not appear to play an important role. Hydrologic factors are also of minimal importance for most elements, with the probable exception of Ba and U. I suggest here that redox processes, occurring both in-stream and in source regions, play an important role in determining seasonal variations in dissolved trace elements.No evidence was found of significant dissolved trace element concentration changes over the past decade and interannual variability in mean concentrations was generally small. The time series also encompassed a period of extreme flooding in the U.S. Midwest. However, the flooding did not significantly influence dissolved trace element concentrations in the lower Mississippi River.  相似文献   

11.
Lomnitz  Cinna 《Natural Hazards》1997,16(2-3):287-296
Some analogies in the distribution of damage in the 1985 Mexico, 1989 Loma Prieta, and 1995 Kobe earthquakes may be attributable to similarities in the history of reclamation of bayshore or lakeshore environments by emplacing artificial fill on soft mud. In all three cases, a transitional environment has generated similar soil types and analogous forms of human settlement. These similarities may translate into hazardous situations because of amplification of seismic waves in wedge-shaped low-velocity layers; nonlinearity of seismic wave propagation in soft water-saturated soils; transitions from solid-like to liquid-like behavior, including liquefaction and the emergence of prograde surface waves; and other unforeseen conditions arising from surface geology. Severe stability problems may arise in tall, top-heavy structures and in structures with horizontal spans of the order of the wavelength of surface waves. Effective strategies of hazard reduction include a recognition of the many unanticipated ways in which earthquake hazard may become an emergent property of complex nature-society systems.  相似文献   

12.
W. Chen  R. J. Arculus 《Lithos》1995,36(3-4):203-225
A wide variety of xenoliths has been entrained in Miocene-to-Recent alkali olivine and hypersthene-normative basalts in the San Francisco Volcanic Field (SFVF), northern Arizona, U.S.A. Based on petrography, mineralogy, bulk rock chemistry and Sr-Nd isotopic characteristics, SFVF xenoliths can be divided into two major groups: cumulates and granulites. The cumulates are genetically related to the Cenozoic volcanic rocks and represent under- and/or intraplated additions to the crust of the Colorado Plateau. Assemblages are mafic to ultramafic and are dominated by clinopyroxene-orthopyroxene-plagioclase-spinel-amphibole-olivine. The granulites are probably Proterozoic in age, mafic-to-intermediate/felsic in bulk composition, either two pyroxene-plagioclase-spinel or plagioclase-alkali feldspar-quartz-magnetite-amphibole-biotite assemblages. Many of the granulites show evidence of partial melting. Some high SiO2, very high Rb/Sr glasses are close in composition to erupted rhyolites, and probably represent end-member melts that have interacted with basalt to produce a variety of hybrid intermediate lavas. The major element, trace element and Sr-Nd isotope geochemistry is highly variable in the SFVF xenoliths. Extremely high Ba contents and Ba/Nb of a number of the granulites are equivalent to values characteristics of modern supra-subduction zone magmas. The considerable variation of chemical and isotopic composition depends upon mineral proportions, assemblages and chemistry. Isotopically, three end-members can be identified within the granulites: (i) lowest 87Sr/86Sr (0.702870) with low 143Nd/144Nd (0.511541, εNd-21.4); (ii) high 87Sr/86Sr (0.711069) with the lowest 143Nd/144Nd (0.511434, εNd-23.5); (iii) highest 87Sr/{86}Sr (0.715306) with low 143Nd/144Nd (0.511793, εNd-16.5). Two important age ranges deduced from the isotopic data probably relate to episodes of crustal-growth beneath the SFVF (1.88 ± 0.33 Ga and Cenozoic). Thermobarometric calculations assuming equilibrium show that the xenoliths are derived from the lower crust (0.6–1.3 GPa, 850–1050 °C). The average SFVF lower crust is mafic in composition. In the absence of partial lithospheric delamination, the lower crust may become mafic with time due to under- and intraplating of continental crust by mafic magmas derived from the mantle.  相似文献   

13.
Five stations on the lower Saint John River, a complex multibasin estuary, were sampled semiquantitatively for zooplankton at biweekly intervals for one year, and qualitatively over a 4-year period. Planktonic Crustacea were dominated by the true estuarine copepods,Acartia tonsa andEurytemora affinis and the euryhaline marine copepodsOithona similis andPseudocalanus minutus. Atypical estuarine forms, confined to a lower fiord-like basin with salinity of 20‰, were the amphipod,Parathemisto abyssorum and the mysidErythrops erythrophthalma. River flows were highly variable from year to year. Certain basins function as lakes in some years and estuaries in other years, causing extreme zooplankton community fluctuations, and succession patterns dependent on salinity rather than season. On occasion freshwater zooplankters maintained viable populations at unusually high salinities (ca. 5‰). Vertical and horizontal distributions of zooplankters indicate that the estuary in fact comprises two systems: a true estuary in the upper reaches and the surface waters at the lower end, and a fiord in a subsidiary basin in the lower end.  相似文献   

14.
Freshwater flow is the principal cause of physical variability in estuaries and a focus of conflict in estuaries where a substantial fraction of the freshwater is diverted. Variation in freshwater flow can have many effects: inundation of flood plains, increase loading and advective transport of materials and organisms, dilution or mobilization of contaminants, compression of the estuarine salinity field and density gradient, increase in stratification, and decrease in residence time for water while increasing it for some particles and biota. In the San Francisco Estuary, freshwater flow is highly variable, and has been altered by shifts in seasonal patterns of river flow and increases in diversions from tidal and nontidal regions, entraining fish of several species of concern. Abundance or survival of several estuarine-dependent species also increases with freshwater outflow. These relationships to flow may be due to several potential mechanisms, each with its own locus and period of effectiveness, but no mechanism has been conclusively shown to underlie the flow relationship of any species. Several flow-based management actions were established in the mid-1990s, including a salinity standard based on these flow effects, as well as reductions in diversion pumping during critical periods for listed species of fish. The effectiveness of these actions has not been established. To make the salinity standard more effective and more applicable to future estuarine conditions will require investigation to determine the underlying mechanisms. Effects of entrainment at diversion facilities are more straightforward conceptually but difficult to quatify, and resolving these may require experimental manipulations of diversion flow.  相似文献   

15.
Trace contaminants enter major estuaries such as San Francisco Bay from a variety of point and nonpoint sources and may then be repartitioned between solid and aqueous phases or altered in chemical speciation. Chemical speciation affects the bioavailability of metals as well as organic ligands to planktonic and benthic organisms, and the partitioning of these solutes between phases. Our previous, work in south San Francisco Bay indicated that sulfide complexation with metals may be of particular importance because of the thermodynamic stability of these complexes. Although the water column of the bay is consistently well-oxygenated and typically unstratified with respect to dissolved oxygen, the kinetics of sulfide oxidation could exert at least transient controls on metal speciation. Our initial data on dissolved sulfides in the main channel of both the northern and southern components of the bay consistently indicate submicromolar concenrations (from <1 nM to 162 nM), as one would expect in an oxidizing environment. However, chemical speciation calculations over the range of observed sulfide concentrations indicate that these trace concentrations in the bay water column can markedly affect chemical speciation of ecologically significant trace metals such as cadmium, copper, and zinc.  相似文献   

16.
Microbial mercury (Hg) methylation and methylmercury (MeHg) degradation processes were examined using radiolabled model Hg compounds in San Francisco Bay-Delta surface sediments during three seasonal periods: late winter, spring, and fall. Strong seasonal and spatial differences were evident for both processes. MeHg production rates were positively correlated with microbial sulfate reduction rates during late winter only. MeHg production potential was also greatest during this period and decreased during spring and fall. This temporal trend was related both to an increase in gross MeHg degradation, driven by increasing temperature, and to a build-up in pore water sulfide and solid phase reduced sulfur driven by increased sulfate reduction during the warmer seasons. MeHg production decreased sharply with depth at two of three sites, both of which exhibited a corresponding increase in reduced sulfur compounds with depth. One site that was comparatively oxidized and alkaline exhibited little propensity for net MeHg production. These results support the hypothesis that net MeHg production is greatest when and where gross MeHg degradation rates are low and dissolved and solid phase reduced sulfur concentrations are low.  相似文献   

17.
Selenium behavior in North San Francisco Bay, the largest estuary on the US Pacific coast, is simulated using a numerical model. This work builds upon a previously published application for simulating selenium in the bay and considers point and non-point sources, transport and mixing of selenium, transformations between different species of selenium, and biological uptake by phytoplankton, bivalves, and higher organisms. An evaluation of the calibrated model suggests that it is able to represent salinity, suspended material, and chlorophyll a under different flow conditions beyond the calibration period, through comparison against long-term data, and the distribution of different species of dissolved and particulate selenium. Model-calculated selenium concentrations in bivalves compared well to a long-term dataset, capturing the annual and seasonal variations over a 15-year period. In particular, the observed lower bivalve concentrations in the wet flow periods, corresponding to lower average particulate selenium concentrations in the bay, are well represented by the model, demonstrating the role of loading and hydrology in affecting clam concentrations. Simulated selenium concentrations in higher organisms including white sturgeon and greater scaup also compared well to the observed data in the bay. Finally, a simulation of changing riverine inflows into the bay that might occur as a consequence of proposed hydrologic modifications indicated significant increases in dissolved and particulate selenium concentrations in the bay. The modeling framework allows an examination of the relationship between selenium loads, variations in inflow, in-bay concentrations, and biota concentrations to support management for limiting wildlife impacts.  相似文献   

18.
Specific conductance and concentrations of alkalinity, dissolved silica, nitrate, and ammonium were measured daily in the Sacramento River flow to northern San Francisco Bay during the rainfall seasons of 1983 and 1984 (high flow) and during late summer and early fall of 1984 (low flow). Flow and concentrations of chemical species varied in response to storm events during high flow, but flow was more variable than concentrations of chemical species. Runoff from agriculturally developed areas appeared to increase specific conductance and concentrations of alkalinity during high flow. During low flow, inputs of agricultural tailwaters caused variations in concentrations of alkalinity and dissolved silica. Dilution of municipal waste by river flow caused variability in concentrations of ammonium during both high flow and low flow. Distributions of alkalinity, dissolved silica, nitrate, and ammonium were measured in northern San Francisco Bay during late summer and fall of 1984. Changes in distributions of alkalinity in the estuary were caused by variations in alkalinity in the Sacramento River. Changes in distributions of dissolved silica, nitrate, and ammonium appeared to be primarily related to variations in supply by the river and removal by phytoplankton. Effects of removal by phytoplankton were large for ammonium and dissolved silica, but appeared relatively small for nitrate.  相似文献   

19.
The species composition and relative abundance of ichthyoplankton were investigated during summer 1986 at four stations along the salinity gradient in the Manicouagan River estuary, a tributary of the lower St. Lawrence estuary. Physical characteristics of water masses indicated the presence of a strong saline front (>10‰ per km) delineating the freshwater and marine section of the Manicouagan estuary. The estuary supports a depauperate ichthyoplankton community, including four species of pelagic fish eggs and eight species of fish larvae. Species richness increased with salinity. The ichthyoplankton fauna can be divided into two distinct groups: freshwater and marine. These two groups result initially from spawning preferences exhibited by the different species abundance of freshwater larvae was maximal at the head of the estuary and marine larvae were most abundant at the most saline station. The length frequency distribution suggests that marine larvae are not effectively retained within the estuary. The Manicouagan estuary cannot be considered as a major spawning site nor an important nursery zone for any fish found in this area.  相似文献   

20.
Laguerre  Michel S. 《GeoJournal》2005,64(1):41-49
This paper briefly reviews the sociological literature on the “New” Chinatown phenomenon stressing its structural location vis-à-vis the “Old” Chinatown and the homeland. It defines the New Chinatown as a panethnopolis, that is a global neighborhood with a majority population of Chinese immigrants and of other ethnic groups of mostly Asian descent. It analyzes more particularly the formation, development, and integration of San Francisco’s Richmond District’s New Chinatown into both the city where it is located and the network of transglobal sites to which it belongs. It provides an interpretation of the New Chinatown as a cultural enclave within the context of globalization theory.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号