WATER POLLUTION IN THE RIVER MOUTHS AROUND BOHAI BAY

Twelve water samples were collected and analyzed. The samples were taken from the river mouths around Bohai Bay including the Jiyun. New Yongding, Haihe, Dagu, Duliujian, Qingjinghuang, Qikou, Dakou, and Yellow Rivers, and tested for concentrations of heavy metals, arsenic, total nitrogen (TN) and total phosphorus (TP). The results show that the river mouths are polluted and the water quality exceeds Class V of the Environmental Quality Standard for Surface Water (EQSSW). The main pollutants are Hg, nitrogen (N) and phosphorus (P). The concentrations of the other pollutants are within Class II of the Standard. The Hg content in the Haihe River mouth is now 10 times higher than it was 20 years ago, indicating that the accelerating water pollution has reached an alarming level. The high concentrations of N and P cause eutrophication of the waters. Analysis indicates that the terrestrial pollutants and nutrients are the main cause of frequently occurring red tides in the Bohai Sea.     

Toxicity assessment of metals in sediment from the lower reaches of the Haihe River Basin in China

The aqueous environmental quality of the Haihe River Basin is crucial for the ecological health of local catchments and the Bohai Sea. For the routine management neglected sediment tests and no legitimate tool supported the toxicity evaluation yet, one supplementary monitoring was implemented to examine the occurrence and toxic level of sediment metals in the lower reaches of the Haihe River Basin in 2009. Both world-widely used consensus-based sediment quality guidelines and China's environmental quality standard for soils (EQSS) were used as assessment tools. Cu, Zn, As, Hg, Cd, and Pb were detected in all 24 samples, while Cr was detected in 18 samples. Assessment results showed 9 samples were toxic and the most dominant toxic element was As. Although the river water quality is getting better, sediment metals have accumulated over thirty years due to continuous industrial development, with toxicity far beyond safety limitations. The highest toxicity levels were encountered in Binhai New Area, suggesting three rivers should be given priority for restoration. It is found that EQSS is also applicable for sediment toxicity assessment until a dedicated tool for Haihe River Basin is available, except for that EQSS is too conservative for Pb.     

PRINCIPLES OF RIVER TRAINING AND MANAGEMENT

River regulation and river training have been performed for various purposes and negative effects have been shown in numerous cases. In some cases the negative effects are so serious that humans have to consider to "renaturalize" the regulated rivers. Only by using the strategy of integrated river management the diverse river uses and natural fluvial processes and ecological systems may be harmonized. Based on analysis of case studies and data collected from literatures this paper presents the concept of integrated river management and four principles of river training. The integrated river management comprises: 1) taking the watershed, upper stream basin including the tributaries, middle and lower reaches and the estuary as an integrated entity in the planning, design and management; and 2) mitigating or controlling the negative impacts on hydrology, erosion and sedimentation, fluvial processes, land use and river use, environment and ecology while in achieving economic benefit from water resources development, flood safety management and hydropower exploitation. River training and management should be in accordance with the four principles: 1) extending the duration of river water flowing on the continent, which may be achieved by extending the river course or reducing the flow velocity; 2) controlling various patterns of erosions and reducing the sediment transportation in the rivers; 3) increasing the diversity of habitat and enhancing the connectivity between the river and riparian waters; and 4) restoring natural landscapes.     

Effect of Resuspension on the Release of Heavy Metals and Water Chemistry in Anoxic and Oxic Sediments

Two types of river sediments with contrasting characteristics (anoxic or oxic) were resuspended and the release of heavy metals and changes in water chemistry were investigated. During resuspension of the anoxic sediment, the dissolved oxygen (DO) concentration and redox potential of the water layer decreased abruptly within the first 1 min, followed by increases toward the end of the resuspension period. Heavy metals were released rapidly in the first 6 h, probably due to the oxidation of acid volatile sulfide (AVS) of the anoxic sediment, and then the aqueous phase concentrations of the heavy metals decreased due to resorption onto the sediment until the 12‐h point. During resuspension of the oxic sediment, the DO concentration and redox potential remained relatively constant in the oxic ranges. The heavy metals were released from the oxic sediment gradually during a 24‐h resuspension period. The temporal maximum concentrations of Ni, Cu, Zn, and Cd in the aqueous phases in both experiments frequently exceeded the USEPA water quality criteria or the water quality guidelines of Australia and New Zealand. This suggests that a resuspension event could bring about temporal water quality deterioration in the two sediment environments.     

Anthropogenic influences on heavy metals across marine habitats in the western coast of Venezuela

Concentrations of ten metals were measured in waters and sediments at 14 sites during four sampling periods (1996–1997). These sites include various marine ecosystems that are highly influenced by industry, tourism and river discharges, nine of which are within the Morrocoy National Park. Spatially, metal concentrations in water were homogenous, whereas in sediments their distributions were related to grain size. Maximum concentrations of cadmium (Cd) and mean concentrations of copper (Cu), nickel (Ni), lead (Pb) and zinc (Zn) in water were above the guideline values proposed by NOAA, indicating the potential of these metals for producing chronic effects in marine biota. Sheltered sites showed the highest metal concentrations in sediments; with Cd and Zn above these guidelines. Enrichment factors and geo-accumulation indexes suggested that metals in sediments were largely of natural origin except for Pb, Cd and vanadium (V), which were apparently associated with industrial effluents. A disruption of the spatial distribution of metals after heavy rainfall, when exposed sites reached concentrations as high as those in sheltered sites, showed the influence of nearby rivers. The potential increase of such climatic events could represent additional stress for natural protected areas in the Caribbean.     

Review: The International Sediment Initiative case studies of sediment problems in river basins and their management

Management of sediment in river basins and waterways has been an important issue for water managers throughout history. The changing nature of sediment issues has meant that water managers today face many complex technical and environmental challenges in relation to sediment management. UNESCO's International Hydrological Programme(IHP) launched the International Sediment Initiative(ISI) in 2002.ISI aims to further advance sustainable sediment management on a global scale. This is achieved through the delivery of a decision support framework for sediment management that provides guidance on legislative and institutional solutions, applicable across a range of socio-economic and physiographic settings in the context of global change. ISI mobilizes international experience on sediment problems and their management through the compilation of a series of case studies representative of a broad range of physiographic and socio-economic conditions, which are made available as guidance for policy makers dealing with water and river basin management. Case studies prepared to date include the basins of the Nile, Mississippi, Rhine, Volga, Yellow, and Haihe and Liaohe rivers. Available in full from the ISI website,these detailed case studies are briefly introduced in this review articles.     

阳澄湖入湖河道分类、污染特征分析及治理策略

为进一步揭示阳澄湖入湖河道的污染物来源,提出相应的治理对策,以2017—2021年阳澄湖入湖河道水质监测数据为基础进行分析讨论。依据入湖水量选取10条主要入湖河道进行分析,其中位于阳澄湖东岸的白曲港在七浦塘拓浚工程建成之前主导流向为出湖,工程建成后,通过Pearson相关分析证实了其流向与七浦塘引水时的水力关系,因此白曲港被选为主要入湖河道。采用距平系数法、系统聚类法和物元分析法将阳澄湖主要入湖河道分为3个类别:第1类别包括白荡、蠡塘河、北河泾、永昌泾4条河道,第2类别包括渭泾塘、界泾和施家斗港3条河道,第3类别包括南消泾、七浦塘和白曲港3条河道。使用因子分析法进行因子分析,第1类别河道的因子为高锰酸盐指数(CODMn)、氨氮(NH3-N)、溶解氧(DO)和总磷(TP),第2类别河道的污染因子为NH3-N、总氮(TN)、pH、TP和DO,第3类别河道的污染因子为pH、TP、TN和DO。通过对上游河道水质情况分析、文件研究以及实地调查等方式得出第1类别河道区域的污染源主要为工业污染源和生活污染源,第2类别河道区域污染源主要为工业污染源与种植业污染源,第3类别河道污染源主要为陆地水产养殖污...     

Hydrological and morphological processes at river mouths of the Caspian Sea Region as possible analogs of expected changes of mouths of other rivers in Russia and the world

Present changes in the regime and structure of mouths of rivers, which empty into the Caspian Sea, are discussed. The similarities and differences of these processes at the mouths of different rivers of the Caspian Region were revealed. Assessment was made of the impact of changes in river water runoff and sediment load and in the Caspian Sea level as well as the nearshore zone relief and local hydraulic engineering activities on the processes under study. Anomalous features of the processes occurring at the mouths of the Volga and Terek rivers were revealed and explained. Hydrological and morphological processes typical of the present mouths of the rivers of Ural, Sulak, and Kura were revealed; these processes could be accepted as universal and possible analogs in assessing the expected changes at the mouths of other rivers in Russia and the world in the XXI century.     

The response of river mouths to large-scale variations in sea level and river runoff: Case study of rivers flowing into the Caspian Sea

Regularities in the response of the mouths of major rivers, flowing into the Caspian Sea, to large-scale variations in its level and river water runoff and sediment yield are considered. Changes in the morphological structure and hydrological regime of the Volga, Terek, Sulak, Ural, and Kura mouths have been analyzed in both geological past and separately for three modern periods: a considerable drop in Caspian Sea level before 1978, its abrupt rise in 1978–1995, and a relative stabilization in the subsequent years. Specific features were identified in the hydrological-morphological processes in different mouths, caused by the differences in river sediment yields, and the slopes of delta surface and mouth nearshore beds. Some theoretical and methodological approaches were verified in the analysis and evaluation of the processes under consideration. The obtained results of studies of the mouths of rivers flowing into the Caspian Sea can be regarded as examples and analogues in the assessment of processes, which take place at the mouths of other Russian and world rivers at present and can take place in the future under anticipated natural and anthropogenic variations in sea level and river runoff.     

考虑空间尺度效应的云南异龙湖流域主要入湖河流污染源解析

定量解析污染源对水质影响的贡献是水环境精细化管理的重要基础。目前多通过水质和土地利用类型的关系以解析水体污染源的研究,忽略了空间尺度的差异性,引发景观配置不合理的后果。为此,本研究依据考虑空间尺度效应的污染源解析方法,基于异龙湖流域3条主要入湖河流的入湖口监测断面对雨季和旱季的水质数据进行研究。同时利用绝对主成分—多元线性回归模型(APCS-MLR)和bioenv分析揭示河道不同尺度缓冲区的土地利用变化对水质的影响并解析河流主要污染源。研究结果表明:(1)异龙湖主要入湖河流水质表现出季节性差异,旱季期间3条主要入湖河流的浊度、化学需氧量(COD_Cr)、氨氮(NH₃-N)、总磷(TP)和总氮(TN)浓度平均值相比于雨季减幅分别为39.53%、39.93%、94.48%、38.29%和1.72%。其中,入湖河流水体中的TN在旱季和雨季的超标率分别为58%和74%,成为首要污染物;(2)在旱季,20 m缓冲区尺度内河流水质受耕地和裸地占比影响较大,随着空间尺度的扩大,至50～300 m缓冲区尺度时建设用地、林地及水体占比对水质的影响增加;在雨季,C...     

环太湖江苏段入湖河道污染物通量与湖区水质的响应关系

基于2008-2018年环太湖江苏段入湖河道污染物通量及湖区水质数据,从时空变化及相关关系两个方面探讨了入湖污染物通量与湖区水质的响应关系,并分析了污染物进入湖体影响水质的主要因子.结果表明:太湖污染减排已见成效,氨氮、总氮、高锰酸盐指数和化学需氧量入湖污染物通量整体呈下降趋势,年均下降率分别为8.0%、2.0%、1.6%和2.2%,湖体氨氮和总氮时间格局响应较好,年均下降率分别为2.1%和2.3%.湖体氨氮、总氮、总磷、高锰酸盐指数和化学需氧量与入湖污染物通量整体由西北部、西部湖区向东南部、东部湖区递减,空间格局上响应基本一致.全湖区年尺度总氮、氨氮浓度与入湖河道污染物通量分别呈显著正相关、极显著正相关关系;影响湖区总氮、氨氮的主要因子为入湖河道的总氮、氨氮浓度,其次为入湖河道浓度与原湖区水质差值,因此亟需加强入湖河道水质浓度的控制.     

Dissolved oxygen--a target indicator in determining use of the Gulf of Kachchh waters

Spatial and temporal variations of Dissolved Oxygen (DO) and Biochemical Oxygen Demand (BOD) in the Gulf of Kachchh (GoK), India are assessed based on data collected since 1976. DO concentrations in the interior GoK vary within a narrow range (6.05-6.86 mg l(-1)), whereas near-shore waters show wider variations (3.5-7.8 mg l(-1)). The DO concentration levels in the Gulf waters are close to saturation, varying from 75.4% to 108.6%, which is much higher than the 60% saturation level set for the SW-1 waters. BOD-DO simulation shows that when effluents containing a BOD concentration of 50.0 mg l(-1) are introduced at three select locations, DO reduces from 5.1 mg l(-1) to 3.1, 5.0 and 3.8 mg l(-1), respectively, indicating a strong sensitivity to effluent load. Based on the DO analysis, BOD assimilation capacity of coastal waters around the Marine National Park (MNP) and Marine Sanctuary (MS) in the Gulf is determined. DO available for utilization for various categories of water use is illustrated, keeping in mind the ecology of MNP and MS areas. The significance of DO as a target indicator to zone the Gulf for different water use, is highlighted in this study.     

Morphodynamic research challenges for braided river environments: Lessons from the iconic case of New Zealand

Pressures on braided river systems in New Zealand are increasing due to anthropogenic stresses such as demand for irrigation water, braidplain conversion to farmland and invasive vegetation, as well as extreme natural events associated with earthquakes and climate change. These pressures create issues around preserving braided river physical environments and associated ecosystems, and managing hazards such as floods, aggradation and erosion. A need for more robust understanding and quantification of braided river morphodynamic processes underpins many of these issues. Here, we present eight morphodynamic research challenges to service this need. The first four research challenges relate to managing aggradation-related flooding hazards; the last four address issues stem largely from recent dairy expansion, which has created huge pressure to take land and irrigation water from the alp-fed braided rivers and to alter flow regimes at their mouths. Hāpua, the freshwater lagoons found where most braided rivers meet the coast, show complex morphodynamic behaviour in response to the interplay of river and coastal processes, and their special ecosystems are sensitive to river flow and sediment load changes. We discuss how physical laboratory experiments and novel numerical modelling can help to understand the morphological processes braided rivers undergo, and we show how those research advances could inform planning and legal decisions to regulate land rights and irrigation water allocation on New Zealand's braidplains. We illustrate these environmental and engineering issues and research challenges with examples from the Kowhai, Waiho, Waiau, Rangitata and Hurunui Rivers. © 2020 John Wiley & Sons, Ltd.     

Key drivers of changes in the sediment loads of Chinese rivers discharging to the oceans

The magnitude and variation of the sediment loads transported by rivers have important implications for the functioning of river systems and changes in the sediment loads of rivers are driven by numerous factors. In this paper, the key drivers of changes in the sediment loads of the major rivers of China are identified by reviewing recent studies of changes in their sediment loads. Except for the Songhua River, which presents no clear tendency of change in runoff or sediment load, nearly all the major rivers of China are characterized by an apparent decline in annual sediment load. The total annual sediment load of major Chinese rivers transported to the coast decreased from 2.03 billion t/yr during the period 1955–1968 to 0.50 billion t/yr during the period 1997–2010. The primary drivers of changes in the sediment loads of the rivers are dam construction, implementation of soil and water conservation measures, catchment disturbance, agricultural practices, sand mining and climate change. Examples drawn from Chinese rivers are used to demonstrate the importance of these drivers. Construction of a large number of reservoirs in the Yangtze River basin represents the primary driver for the reduced sediment load of the Yangtze River. The implementation of soil and water conservation programmes is one of the key drivers for the sharp decline in the sediment load of the Yellow River. Catchment disturbance explains why the reduction of the sediment load of the Lancang-Mekong River at the Chiang Saen gauging station was much less than that at the Gajiu gauging station upstream. A reduction in sediment load resulting from the expansion of agricultural production may be the main driver for the reduced sediment load of the Huaihe River. The decrease in the sediment load of the Pearl River has been influenced by sand mining activities. Climate change is one of the key drivers responsible for the greatly reduced sediment load of the rivers in the Haihe River Basin.     

Madagascar

Untreated domestic and industrial wastes are discharged into Tolo Harbour via several major streams entering the harbour. These untreated wastes will cause a harmful effect because Tolo Harbour is a land-locked sea with only a narrow outlet and an ever-decreasing volume caused by the construction of Plover Cove Reservoir and the reclamation of Shatin New Town. In order to study the effect of polluted water discharged into the harbour, water samples and sediments near the mouths of the major rivers were collected. The analysis of the total organic carbon, total nitrogen, and water soluble phosphate contents of the samples showed that Lam Tsuen River, Tai Po Kau River, and Shing Mon River were grossly polluted by organic and inorganic wastes. Blue Snake River which passes through the iron ore tailings accumulated high contents of metal contaminants.     

Evaluation of River Water Quality Simulations at a Daily Time Step – Experience with SWAT in the Axe Catchment,UK

The Water Framework Directive (WFD) was established for the protection of surface waters (rivers, lakes, transitional and coastal waters) and ground waters in the European Union. The main environmental objective is to achieve and maintain a good status for all waters by the target date of 2015. Models which are able to address the majority of environmental objectives are proposed within the WFD to inform the management changes required to meet current water policy goals. The use of the Soil and Water Assessment Tool (SWAT) catchment model is widespread throughout the world, especially to support river basin management as required by the WFD. This paper provides a critical evaluation of the use of the model by placing model performance in the Axe catchment, UK, in the context of international performance of the model. Within the constraints of the available data, SWAT represents hydrology, sediment and ortho‐phosphorus concentration well for this heterogeneous catchment, but the representation of daily nitrogen concentration dynamics is poor. Temporal aggregation of model outputs from daily to monthly improved the performance metrics for all the river outputs, including nitrate. Wider review of SWAT studies showed widespread reporting of monthly performance metrics within the SWAT studies, despite the model operating at a daily time step. Poor performance for nitrate identified in this current study may be a significant factor in the choice to not report daily results. This demonstrates the importance of ascertaining the reasons for the use of temporal aggregation in modelling studies.     

On sediment pollution in selected german coastal waters of the Baltic Sea

In order to determine and assess their status sediments from the German coastal waters of the baltic sea were analyzed for structural parameters and for several groups of harmful substances. Regarding all groups of harmful substances, i.e. nutrients, heavy metals and organic toxicants the sediments of the eastern sections investigated (Strelasund, Peenestrom and Stettin Lagoon) are generally more polluted than the sediments of the other ones.The sediments of the examined sections of the Baltic coast compare with North Sea sediments by factors of between 0.05 and 4 with regard to heavy metals.Because of the variability of the concentration of harmful substances in the various coastal sections, it is imperative to make a differentiated assessment of the polluted sediments and to set district-related targets for the various sections of the Baltic coast.     

Sediment pollution and its effect on fish through food chain in the Yangtze River

Suspended sediment adsorbs pollutants from flowing water in rivers and deposits onto the bed. However, the pollutants accumulated in the river bed sediment may affect the bio-community through food chain for a long period of time. To study the problem the concentration of heavy metals （Cr, Cd, Hg, Cu, Fe, Zn, Pb and As） in water, sediment, and fish/invertebrate were investigated in the middle and lower reaches of the Yangtze River during 2006-2007. The concentrations of heavy metals were 100-10,000 times higher in the sediment than in the water. Benthic invertebrates had relatively high concentrations of heavy metals in their tissues due to their proximity to contaminated sediments. Benthic invertivore fish had moderately high concentrations of heavy metals whereas phytoplanktivore fish, such as the silver carp, accumulated the lowest concentration of heavy metals. The concentrations of Cu, Zn, and Fe were higher than Hg, Pb, Cd, Cr, and As in the tissue samples. The concentration of heavy metals was lower in the river sediments than in the lake sediments. Conversely, the concentration of heavy metals was higher in river water than in lake water. While a pollution event into a water body is often transitory, the effects of the pollutants may be long-lived due to their tendency to be absorbed in the sediments and then released into the food chain. The heavy metals were concentrated in the following order： bottom material 〉 demersal fish and benthic fauna 〉 middle-lower layer fish 〉 upper-middle layer fish 〉 water.     

The behaviors and sources of dissolved arsenic and antimony in Bohai Bay

In this paper, we determined the concentrations of antimony species (antimonite (Sb(III)), antimonate (Sb(V)) and dissolved inorganic antimony (DISb)) and arsenic, in Bohai Bay seawaters, as well as the relationships of the analytes with environmental factors such as seawater characteristics (e.g., suspended particulate material (SPM), salinity and total organic carbon (TOC)), heavy metals, nutrients and phytoplankton species, and evaluated the sources of arsenic and antimony. Dissolved arsenic and antimony concentrations in the surface waters were ranging spatially from 1.03 to 1.26 ng/ml and 0.386 to 1.075 ng/ml, with mean values of 1.18 and 0.562 ng/ml, respectively. Sb(V) as the prominent chemical species constituted about 89%. Regarding arsenic concentrations in the surface waters, there was a tendency for a small variation. However, antimony species concentrations were much variable than arsenic. The highest arsenic and antimony concentrations were found near the Haihe Estuary. These distribution patterns were controlled mainly by environmental factors, biological activities and sources. In this region, DISb and Sb(V) negatively correlated with salinity. Besides, arsenic and antimony correlated well with the nutrients, chlorophyll a and phytoplankton, implying that arsenic and antimony had been involved in biological cycling. In addition, according to our estimate, about 333.5×10⁸ mg/year of arsenic and 454.2×10⁸ mg/year of antimony reached Bohai Bay via rivers.