Chemical differentiation of the Earth: the relationship between mantle, continental crust, and oceanic crust

The average chemical compositions of the continental crust and the oceanic crust (represented by MORB), normalized to primitive mantle values and plotted as functions of the apparent bulk partition coefficient of each element, form surprisingly simple, complementary concentration patterns. In the continental crust, the maximum concentrations are on the order of 50 to 100 times the primitive-mantle values, and these are attained by the most highly incompatible elements Cs, Rb, Ba, and Th. In the average oceanic crust, the maximum concentrations are only about 10 times the primitive mantle values, and they are attained by the moderately incompatible elements Na, Ti, Zr, Hf, Y and the intermediate to heavy REE.This relationship is explained by a simple, two-stage model of extracting first continental and then oceanic crust from the initially primitive mantle. This model reproduces the characteristic concentration maximum in MORB. It yields quantitative constraints about the effective aggregate melt fractions extracted during both stages. These amount to about 1.5% for the continental crust and about 8–10% for the oceanic crust.The comparatively low degrees of melting inferred for average MORB are consistent with the correlation of Na₂O concentration with depth of extrusion [1], and with the normalized concentrations of Ca, Sc, and Al ( 3) in MORB, which are much lower than those of Zr, Hf, and the HREE ( 10). Ca, Al and Sc are compatible with clinopyroxene and are preferentially retained in the residual mantle by this mineral. This is possible only if the aggregate melt fraction is low enough for the clinopyroxene not to be consumed.A sequence of increasing compatibility of lithophile elements may be defined in two independent ways: (1) the order of decreasing normalized concentrations in the continental crust; or (2) by concentration correlations in oceanic basalts. The results are surprisingly similar except for Nb, Ta, and Pb, which yield inconsistent bulk partition coefficients as well as anomalous concentrations and standard deviations.The anomalies can be explained if Nb and Ta have relatively large partition coefficients during continental crust production and smaller coefficients during oceanic crust production. In contrast, Pb has a very small coefficient during continental crust production and a larger coefficient during oceanic crust production. This is the reason why these elements are useful in geochemical discrimination diagrams for distinguishing MORB and OIB on the one hand from island arc and most intracontinental volcanics on the other.The results are consistent with the crust-mantle differentiation model proposed previously [2]. Nb and Ta are preferentially retained and enriched in the residual mantle during formation of continental crust. After separation of the bulk of the continental crust, the residual portion of the mantle was rehomogenized, and the present-day internal heterogeneities between MORB and OIB sources were generated subsequently by processes involving only oceanic crust and mantle. During this second stage, Nb and Ta are highly incompatible, and their abundances are anomalously high in both OIB and MORB.The anomalous behavior of Pb causes the so-called “lead paradox”, namely the elevated U/Pb and Th/Pb ratios (inferred from Pb isotopes) in the present-day, depleted mantle, even though U and Th are more incompatible than Pb in oceanic basalts. This is explained if Pb is in fact more incompatible than U and Th during formation of the continental crust, and less incompatible than U and Th during formation of oceanic crust.     

Isotopic inferences on the chemical structure of the mantle

Variations in the isotopic composition of rocks derived from the upper mantle can be used to infer the chemical history and structure of the Earth's interior. The most prominent material in the upper mantle is the source of mid-ocean ridge basalts (MORB). The MORB source is characterized by a general depletion in incompatible elements caused by the extraction of the continental crust from the mantle. At least three other isotopically distinct components are recognized in the suboceanic mantle. All three could be generated by the recycling of near surface materials (oceanic crust, pelagic sediments, continental lithospheric mantle) into the mantle by subduction. Therefore, the isotope data do not require a compositionally layered mantle, but neither do they deny the existence of such layering. Correlations between the volumetric output of plume volcanism with the reversal frequency of the Earth's magnetic field, and between the geographic distribution of isotopic variability in oceanic volcanism with seismic tomography suggest input of deep mantle material to surface volcanism in the form of deep mantle plumes. Volcanism on the continents shows a much wider range in isotopic composition than does oceanic volcanism. The extreme isotopic compositions observed for some continental magmas and mantle xenoliths indicate long-term (up to 3.3 Gyr) preservation of compositionally distinct material in thick (>200 km) sections of continental lithospheric mantle.     

Geochemistry of late Cenozoic lavas on Kunashir Island, Kurile Arc

Middle Miocene to Quaternary lavas on Kunashir Island in the southern zone of the Kurile Arc were examined for major, trace, and Sr–Nd–Pb isotope compositions. The lavas range from basalt through to rhyolite and the mafic lavas show typical oceanic island arc signatures without significant crustal or sub-continental lithosphere contamination. The lavas exhibit across-arc variation, with increasingly greater fluid-immobile incompatible element contents from the volcanic front to the rear-arc; this pattern, however, does not apply to some other incompatible elements such as B, Sb, and halogens. All Sr–Nd–Pb isotope compositions reflect a depleted source with Indian Ocean mantle domain characteristics. The Nd and Pb isotope ratios are radiogenic in the volcanic front, whereas Sr isotope ratios are less radiogenic. These Nd isotope ratios covary with incompatible element ratios such as Th/Nd and Nb/Zr, indicating involvement of a slab-derived sediment component by addition of melt or supercritical fluid capable of mobilizing these high field-strength elements and rare earth elements from the slab. Fluid mobile elements, such as Ba, are also elevated in all basalt suites, suggesting involvement of slab fluid derived from altered oceanic crust. The Kurile Arc lavas are thus affected both by slab sediment and altered basaltic crust components. This magma plumbing system has been continuously active from the Middle Miocene to the present.     

Origin of Icelandic basalts: A review of their petrology and geochemistry

The petrology and geochemistry of Icelandic basalts have been studied for more than a century. The results reveal that the Holocene basalts belong to three magma series: two sub-alkaline series (tholeiitic and transitional alkaline) and an alkali one. The alkali and the transitional basalts, which occupy the off-rift volcanic zones, are enriched in incompatible trace elements compared to the tholeiites, and have more radiogenic Sr, Pb and He isotope compositions. Compared to the tholeiites, they are most likely formed by partial melting of a lithologically heterogeneous mantle with higher proportions of melts derived from recycled oceanic crust in the form of garnet pyroxenites compared to the tholeiites. The tholeiitic basalts characterise the mid-Atlantic rift zone that transects the island, and their most enriched compositions and highest primordial (least radiogenic) He isotope signature are observed close to the centre of the presumed mantle plume. High-MgO basalts are found scattered along the rift zone and probably represent partial melting of refractory mantle already depleted of initial water-rich melts. Higher mantle temperature in the centre of the Iceland mantle plume explains the combination of higher magma productivity and diluted signatures of garnet pyroxenites in basalts from Central Iceland. A crustal component, derived from altered basalts, is evident in evolved tholeiites and indeed in most basalts; however, distinguishing between contamination by the present hydrothermally altered crust, and melting of recycled oceanic crust, remains non-trivial. Constraints from radiogenic isotope ratios suggest the presence of three principal mantle components beneath Iceland: a depleted upper mantle source, enriched mantle plume, and recycled oceanic crust.The study of glass inclusions in primitive phenocrysts is still in its infancy but already shows results unattainable by other methods. Such studies reveal the existence of mantle melts with highly variable compositions, such as calcium-rich melts and a low-¹⁸O mantle component, probably recycled oceanic crust. Future high-resolution seismic studies may help to identify and reveal the relative proportions of different lithologies in the mantle.     

Chemical heterogeneity of the Archaean mantle,composition of the earth and mantle evolution

New rare earth element (REE) data for Archaean basalts and spinifex-textured peridotites (STP) show a range of La/Sm ratios (chondrite-normalized) from 0.36 to 3.5, with the bulk of the data in the range 0.7–1.3. This supports the hypothesis, based on Sr isotope initial ratios, that the Archaean mantle was chemically heterogeneous. We suggest that the bulk mantle source for Archaean basaltic magmas was close to an undepleted earth material. An average chemical composition of the Archaean mantle is estimated using chemical regularities observed in Archaean STP and high-magnesian basalts. TiO₂ and MgO data show an inverse correlation which intersects the MgO axis at about 50% MgO (Fo₉₂). TiO₂ abundance in the mantle source is measured on this plot by assigning anMgO= 38% for the mantle. Concentrations of other elements are also estimated and these data are then used to obtain a composition for the bulk earth. We suggest an earth model with about 1.35 times ordinary chondrite abundances of refractory lithophile elements and about 0.2 times carbonaceous type 1 chondrite abundances of moderately volatile elements (such as Na, Rb, K, Mn). P shows severe depletion in the model earth relative to carbonaceous chondrites, a feature either due to volatilization or core formation (preferred). Our data support the hypothesis of Ringwood that the source material for the earth is a carbonaceous chondrite-like material.The generation of mid-ocean ridge basalts (MORB) is examined in the light of the model earth composition and Al₂O₃/TiO₂, CaO/TiO₂ ratios. It is suggested that for primitive basalts, these values can be used to predict the residual phases in their source. Comparison of chemical characteristics of inferred sources for 2.7-b.y. Archaean basalts and modern “normal” MORB indicates that the MORB source is severely depleted in highly incompatible elements such as Cs, Ba, Rb, U, Th, K, La and Nb, but has comparable abundances of less incompatible elements such as Ti, Zr, Y, Yb. The cause of the depletion in the MORB source is examined in terms of crust formation and extraction of silica-undersaturated melts. The latter seems to be a more likely explanation, since the degree of enrichment of highly incompatible elements in the crust only accounts for up to 40% of their abundances in the bulk earth and cannot match the depletion pattern in normal MORB. A large volume of material, less depleted than the source for normal MORB must therefore exist in the mantle and can serve as the source for the ocean island basalts and “normal” MORB.Three different mantle evolution models are examined and each suggests that the mantle is stratified with respect to abundances of incompatible trace elements. We suggest that no satisfactory model is available to fully explain the spectrum of geochemical and geophysical data. In particular the Pb and Sr isotope data on oceanic basalts, the depletion patterns of MORB and the balance between lithophile abundances in the crust and mantle, are important geochemical constraints to mantle models. Further modelling of the mantle evolution will be dependent on firmer information on the role of subduction, mantle convection pattern, and basalt production through geologic time together with a better understanding of the nature of Archaean crustal genesis.     

Transition from platemargin to intraplate environment: Geochemistry of basalts in Paleogene Liaohe basin,northeastern China

Mesozoic and Cenozoic volcanic rocks are widely distributed in the circum-Pacific area of eastern China. These rocks have long been genetically linked to westward subduction of the paleo-Pacific oceanic plate to the eastern Asia continent[1,2]. Research in re-cent years[3―6] has attained conclusions that a simple paleo-Pacific subduction model does not work well in interpreting all the volcanic rocks in eastern China, although some of them could be attributed to circum-Pacific interaction …     

The origin of ocean island basalt end-member compositions: trace element and isotopic constraints

Ocean island basalt (OIB) suites display a wide diversity of major element, trace element, and isotopic compositions. The incompatible trace element and isotopic ratios of OIB reflect considerable heterogeneity in the mantle source regions. In addition to the distinctive Sr, Nd and Pb isotopic signatures of the HIMU, EMI and EMII OIB end-members, differences in incompatible trace element ratios among these end-members are of great help in identifying the nature and origin of their sources. Examination of trace element and isotopic constraints for the three OIB end-members suggests a relatively simple model for their origin. The dominant component in all OIB is ancient recycled basaltic oceanic crust which has been processed through a subduction zone, and which carries the trace element and isotopic signature of a dehydration residue (enrichment in HFSE relative to LILE and LREE, low Rb/Sr, but high U/Pb and Th/Pb ratios leading to the development of radiogenic Pb isotope compositions). HIMU OIB are derived from such a source, with little contamination from other components. Both the EMI and EMII OIB end-members are also dominantly derived from this source, but they contain significant proportions (up to 5–10%) of sedimentary components derived from the continental crust. In the case of EMI OIB, ancient pelagic sediment with high LILE/HFSE, LREE/HFSE, Ba/Th and Ba/La ratios, and low U/Pb ratios, is the contaminant. EMII OIB are also contaminated by a sedimentary component, in the form of ancient terrigenous sediment with high LILE/HFSE and LREE/HFSE ratios, but lacking relative Ba enrichment, and with higher U/Pb and Rb/Sr ratios. A model whereby the source for all OIB is ancient (1–2 Ga old) subducted oceanic crust ± entrained sediment (pelagic and/or terrigenous) is therefore consistent with the trace element and isotopic data. Although subducted oceanic lithosphere will accumulate and be dominantly concentrated within the mesosphere boundary layer, forming the source for hot-spots, such material may also become convectively dispersed within the depleted upper mantle as blobs or streaks, giving rise to small-scale chemical heterogeneities in the upper mantle.     

U-Pb isotopic geochemistry of the post-collisional mafic-ultramafic rocks from the Dabie Mountains——Crust-mantle interaction and LOMU component

Geochronological studies of mafic-ultramafic intrusions occurrence in the northern Dabie zone (NDZ) suggest that these pyroxenite-gabbro intrusions formed 120—130 Ma ago should be post-collisional magmatic rocks[1—4]. These mafic-ultramafic rocks provid…     

Aleutian magnesian andesites: Melts from subducted Pacific ocean crust

Several diagnostic chemical characteristics of an uncommon Aleutian magma type support a proposed origin that involves a small amount of partial melting of subducted Pacific ocean crust (basalt) consisting mainly of garnet and clinopyroxene (eclogite or garnet websterite). Among the characteristics are high La/Yb ratios and Sr contents and low ratios of radiogenic to non-radiogenic Sr and Pb. The major element composition of the andesites resembles that of hydrous melts in equilibrium with peridotite: a low ratio of total Fe to Mg is distinctive. These disparate observations can be reconciled if large ion lithophile (LIL)- element-rich hydrous melt from the subducted oceanic crust equilibrates with olivine and orthopyroxene in overlying LIL-element-depleted mantle and then erupts without interacting with the island are crust. The compositional dissimilarity of the magnesian andesites and most other andesites from the Aleutian island arc precludes application of this model to island are magmatism in general.     

Geochemistry of early Paleozoic alkali dyke swarms in south Qinling and its geological significance

The abundant research achievements about Qinling orogeny going through central China were obtained in the last decade[1—3]. However, there is a debate about the early Paleozoic tectonic evolution of south Qinling. Thus, it is undoubted that the systemati…     

Oxygen isotope evidence for the origin of enriched mantle beneath the mid-Atlantic ridge

Geochemical variations in mid-ocean ridge basalts have been attributed to differing proportions of compositionally distinct mantle components in their sources, some of which may be recycled crust. Oxygen isotopes are strongly fractionated by near-surface interactions of rocks with the hydrosphere, and thus provide a tracer of near-surface materials that have been recycled into the mantle. We present here oxygen isotope analyses of basaltic glasses from the mid-Atlantic ridge south of and across the Azores platform. Variations in δ¹⁸O in these samples are subtle (range of 0.47‰) and may partly reflect shallow fractional crystallization; we present a method to correct for these effects. Relatively high fractionation-corrected δ¹⁸O in these samples is associated with geochemical indices of enrichment, including high La/Sm, Ce/Pb, and ⁸⁷Sr/⁸⁶Sr and low ¹⁴³Nd/¹⁴⁴Nd. Our results suggest two first-order conclusions about these enriched materials: (1) they are derived (directly or indirectly) from recycled upper oceanic crustal rocks and/or sediments; and (2) these materials are present in the north Atlantic MORB sources in abundances of less than 10% (average 2–5%). Modeling of variations of δ¹⁸O with other geochemical variables further indicates that the enriched component is not derived from incorporation of sediment or bulk altered oceanic crust, from metasomatism of the mantle by hydrous or carbonate-rich fluids, or from partial melting of subducted sediment. Instead, the data appear to require a model in which the enriched component is depleted mantle that has been metasomatized by small-degree partial melts of subducted, dehydrated, altered oceanic crust. The age of this partial melting is broadly constrained to 250 Ma. Reconstructed plate motions suggest that the enriched component in the north Atlantic mantle may have originated by subduction along the western margin of Pangea.     

U-Pb isotopic geochemistry of the post-collisional mafic-ultramafic rocks from the Dabie Mountains

The U-Pb isotope geochemical study of the pyroxenite-gabbro intrusion in the Dabie Mountains shows that the post-collisional mafic-ultramafic rocks of the Dabie Mountains are characterized by relative high Pb contents, low U contents and low U/Pb ratios. These characters may be results of interaction between lithosphere or depleted asthenospheric mantle (DMM) and lower crust, but have nothing to do with mantle plume and subducted continental crust. It was first observed that some samples with lower ²⁰⁶Pb/²⁰⁴Pb and higher ²⁰⁷Pb/²⁰⁴Pb ratios show typical characters of the LOMU component. The Pb, Sr, and Nd isotopic tracing shows that three components are needed in the source of the Zhujiapu pyroxenite-gabbro intrusion. They could be old enriched sub-continental lithospheric mantle (LOMU component), lower crust and depleted asthenospheric mantle. The crust-mantle interaction process producing primitive magma of post-collisional mafic-ultramafic rocks in the Dabie Mountains could be described by a lithospheric delamination and magma underplating model. After continent-continent collision, delamination of the thickened lithosphere induced the upwelling of depleted asthenospheric mantle, which caused partial melting of asthenospheric mantle and residual sub-continental lithospheric mantle. The basaltic magma produced in this process underplated in the boundary between the crust and mantle and interacted with lower crust resulting in the geochemical characters of both enriched lithospheric mantle and lower crust.     

Correlated Nd,Sr and Pb isotope variation in Walvis Ridge basalts and implications for the evolution of their mantle source

Basement intersected in DSDP holes 525A, 528 and 527 on the Walvis Ridge consists of submarine basalt flows and pillows with minor intercalated sediments. These holes are situated on the crest and mid and lower northwest flank of a NNW-SSE-trending ridge block which would have closely paralleled the paleo mid-ocean ridge [13, 14]. The basalts were erupted approximately 70 m.y. ago, an age equivalent to that of immediately adjacent oceanic crust in the Angola Basin and consistent with formation at the paleo mid-ocean ridge [14]. The basalt types vary from aphyric quartz tholeiites on the ridge crest to highly plagioclase phyric olivine tholeiites on the ridge flank. These show systematic differences in incompatible trace element and isotopic composition. Many element and isotope ratio pairs form systematic trends with the ridge crest basalts at one end and the highly phyric ridge flank basalts at the other.The low ¹⁴³Nd/¹⁴⁴Nd (0.51238), ²⁰⁶Pb/²⁰⁴Pb (17.54), ²⁰⁸Pb/²⁰⁴Pb (15.47), ²⁰⁸Pb/²⁰⁴Pb (38.14) and high⁸⁷Sr/⁸⁶Sr (0.70512) ratios of the ridge crest basalts suggest derivation from an old Nd/Sm-, Rb/Sr- and Pb/U-enriched mantle source. This isotopic signature is similar to that of alkaline basalts on Tristan de Cunha but offset to significantly lower Nd and Pb isotopic ratios. The isotopic ratio trends may be extrapolated beyond the ridge flank basalts with higher¹⁴³Nd/¹⁴⁴Nd (0.51270), ²⁰⁶Pb/²⁰⁴Pb (18.32), ²⁰⁷Pb/²⁰⁴Pb (15.52), ²⁰⁸Pb/²⁰⁴Pb (38.77) and lower ⁸⁷Sr/⁸⁶Sr (0.70417) ratios in the direction of increasingly Nd/Sm-, Rb/Sr- and Pb/U-depleted source compositions. These isotopic correlations are equally consistent with mixing od depleted and enriched end member melts or partial melting of an inhomogenous, variably enriched mantle source. However, observe ZrBaNbY interelement relationships are inconsistent with any simple two-component model of magma mixing, as might result from the rise of a lower mantle plume through the upper mantle. Incompatible element and Pb isotopic systematics also preclude extensive involvement of depleted (N-type) MORB material or its mantle sources. In our preferred petrogenetic model the Walvis Ridge basalts were derived by partial melting of mantle similar to an enriched (E-type) MORB source which had become heterogeneous on a small scale due to the introduction of small-volume melts and metasomatic fluids.     

Major and trace element and Sr–Nd isotope signatures of lavas from the Central Lau Basin: Implications for the nature and influence of subduction components in the back-arc mantle

New major and trace element and Sr–Nd isotope data are presented for basaltic glasses from active spreading centers (Central Lau Spreading Center (CLSC), Relay Zone (RZ) and Eastern Lau Spreading Center (ELSC)) in the Central Lau Basin, SW Pacific. Basaltic lavas from the Central Lau Basin are mainly tholeiitic and are broadly similar in composition to mid-ocean ridge basalts (MORB). Their generally high ⁸⁷Sr/⁸⁶Sr ratios, combined with relatively low ¹⁴³Nd/¹⁴⁴Nd ratios are more akin to MORB from the Indian rather than Pacific Ocean. In detail, the CLSC, RZ and ELSC lavas are generally more enriched in large ion lithophile elements (Rb, Ba, Sr, and K) than average normal-MORB, which suggests that the mantle beneath the Central Lau Basin was modified by subducted slab-derived components. Fluid mobile/immobile trace element and Sr – Nd isotope ratios suggest that the subduction components were essentially transferred into the mantle via hydrous fluids derived from the subducted oceanic crust; contributions coming from the subducted sediments are minor. Compared to CLSC lavas, ELSC and RZ lavas show greater enrichment in fluid mobile elements and depletion in high field strength elements, especially Nb. Thus, with increasing distance away from the arc, the influence of subduction components in the mantle source of Lau Basin lavas diminishes. The amount of hydrous fluids also influences the degree of partial melting of the mantle beneath the Central Lau Basin, and hence the degree of melting also decreases with increasing distance from the arc.     

岩浆与构造作用对洋壳厚度的影响——以西北印度洋为例

洋中脊及邻区洋盆的洋壳厚度能很好地反映区域岩浆补给特征,对于研究洋中脊内部及周缘岩浆活动和构造演化过程具有很好的指示意义.西北印度洋中脊作为典型的慢速扩张洋中脊,其扩张过程与周缘构造活动具有很强的时空关系.本文利用剩余地幔布格重力异常反演了西北印度洋洋壳厚度,由此分析区域内洋壳厚度分布和岩浆补给特征.研究发现,西北印度洋洋壳平均厚度为7.8 km,受区域构造背景影响厚度变化较大.根据洋壳厚度的统计学分布特征,将区域内洋壳分为三种类型:薄洋壳(小于4.5 km)、正常洋壳(4.5~6.5 km)和厚洋壳(大于6.5 km),根据西北印度洋中脊周缘(~40 Ma内)洋壳厚度变化特征可将洋中脊划分为5段,发现洋中脊洋壳厚度受区域构造活动和地幔温度所控制,其中薄洋壳主要受转换断层影响造成区域洋壳厚度减薄,而厚洋壳主要受地幔温度和地幔柱作用影响,并在S4洋中脊段显示出较强的热点与洋中脊相互作用,同时微陆块的裂解和漂移也可能是导致洋壳厚度差异的原因之一.     

Chemical composition of Archaean komatiites: Implications for early history of the earth and mantle evolution

Estimates of the chemical composition of the Archaean mantle, derived from elemental abundance ratios in komatiites combined with ultramafic xenolith data, support a model of a multistage heterogeneous accretion history of the Earth and synchronous core formation, 4.6 Ga ago.Most refractory lithophile element abundance ratios in komatiites and xenoliths are close to chondritic except for V/Ti and Ca/Al. Depletion of vanadium is likely due to its partial incorporation into the iron core; whereas fractionation of Ca/Al observed in Archaean Al-undepleted komatiites (1.20 times chondrites) and in some modern fertile spinel lherzolite xenoliths (1.15 times chondrites) could be due to small amounts of garnet (rich in Al but poor in Ca) segregation into the lower mantle during partial or complete melting of the upper mantle in the very early history of the Earth. However, this process may have had only a small effect on the overall chemical composition of the upper mantle.Simultaneous occurrence of early Archaean Al-undepleted (Al/Ti chondrites) and Al-depleted (Al/Ti 0.5 chondrites, and depletion of Sc and heavy REE) peridotitic komatiites in the Barberton area, S. Africa, and late Archaean Newton Township, Canada, argue against derivation of peridotitic komatiites from a circum-global magma ocean. Garnet separation from a mantle diapir which intersects the solidus at great depth ( 200 km) in a hotter early Archaean mantle could explain the chemical characteristics of Al-depleted komatiites. Alternatively, these two types of komatiites could have been derived from different layers in a fractionated mantle. A limited amount of Hf isotope data for Archaean komatiites seems to suggest that both mechanisms are important. This chemically and minerallogically layered mantle, if it existed, was homogenized by mantle convection after early Archaean times.Constant P₂O₅/TiO₂, Ni/Mg, Co/Mg, Fe/Mg ratios (siderophile/lithophile) and PGE abundances, estimated for the mantle sources of komatiites from Archaean to modern times, strongly argue against continuous growth of the Earth's core since the early Archaean.Extensive crustal contamination might have been involved in the generation of Archaean-early Proterozoic siliceous high magnesian basalts with “boninite affinity”. However, involvement of chemically modified ancient continental lithosphere may also be important in the generation of these basalts.     

Lithophile elements in Huronian low-Ti continental tholeiites from Canada, and evolution of the Precambrian mantle

Huronian basalts from central Ontario, Canada, dated at about 2450 Ma and associated with an early rifting episode, are classified as siliceous, low-TiNb tholeiites. They display strong enrichment in large-ion lithophile (LILE) and light rare earth (LREE) elements compared to modern oceanic lavas. The tectonic setting and geochemistry resemble Mesozoic rift-related low-Ti flood basalts, including the Ferrar Group of Antarctica, and the Parana and equivalent Etendeka volcanics of south Brazil and Namibia, respectively. High LILE/LREE ratios are also similar to subduction-related island arc tholeiites, and it is suggested that enrichment of the Huronian lithospheric mantle source occurred through ancient subduction of crustal material, probably during formation and consolidation of the Archean continental crust.Melting models suggest that Huronian subcontinental mantle source compositions, derived from least contaminated, aphyric, mafic end-members, had already undergone a complex evolution, including withdrawal of Archean basalts and hydrous enrichment in incompatible components. Despite several subsequent melting episodes and a second, probably magmatic, enrichment event, however, many aspects of the Huronian source signature were preserved, and appeared in later basaltic products of this mantle mass. Keweenawan volcanics, for example, dated at about 1100 Ma, preserve low P, Zr, Ti and HREE abundances.     

Osmium-strontium-neodymium-lead isotopic covariations in mid-ocean ridge basalt glasses and the heterogeneity of the upper mantle

Osmium, strontium, neodymium, and lead isotopic data have been obtained for 30 hand picked samples of basaltic glass from the Pacific, Atlantic and Indian mid-oceanic ridges. Large variations in Os isotopic ratios exist in the glasses, from abyssal peridotite-like values to radiogenic compositions similar to oceanic island basalts (¹⁸⁷Os/¹⁸⁶Os and ¹⁸⁷Os/¹⁸⁸Os ratios range from 1.06 to 1.36 and from 0.128 to 0.163, respectively). Os isotopic and elemental data suggest the existence of mixing correlations. This relationship might be ascribed to secondary contamination processes; however, such a hypothesis cannot account for the negative correlation observed between Os and Nd isotopes and the existence of complementary covariations between Os and SrPb isotopes. In this case, OsSrNdPb isotopic variations are unrelated to late post-eruption or shallow level contamination. These relationships provide strong evidence that the Os isotopic composition of the samples are derived from the mantle and thus implies a global chemical heterogeneity of the oceanic upper mantle. The results are consistent with the presence of recycled oceanic crust in the mantle sources of mid-ocean ridge basalts, and indicate that the unique composition of the upper mantle below the Indian ocean results from its contamination by a mantle component characterized by radiogenic Os and particularly unradiogenic Nd and Pb isotopic compositions.     

Trace elements in ocean ridge basalts

A correlary of sea floor spreading is that the production rate of ocean ridge basalts exceeds that of all other volcanic rocks on the earth combined. Basalts of the ocean ridges bring with them a continuous record in space and time of the chemical characteristics of the underlying mantle. The chemical record is once removed, due to chemical fractionation during partial melting. Chemical fractionations can be evaluated by assuming that peridotite melting has proceeded to an olivine-orthopyroxene stage, in which case the ratios of a number of magmaphile elements in the extracted melt closely match the ratios in the mantle. Comparison of ocean ridge basalts and chondritic meteorites reveals systematic patterns of element fractionation, and what is probably a double depletion in some elements. The first depletion is in volatile elements and is due to high accretion temperatures of a large percentage of the earth from the solar nebula. The second depletion is in the largest, most highly charged lithophile elements (“incompatible elements”), probably because the mantle source of the basalts was melted previously, and the melt, enriched in these elements, was removed. Migration of melt relative to solid under ocean ridges and oceanic plates, element fractionation at subduction zones, and fractional melting of amphibolite in the Precambrian are possible mechanisms for depleting the mantle in incompatible elements. Ratios of transition metals in the mantle source of ocean ridge basalts are close to chondritic, and contrast to the extreme depletion of refractory siderophile elements, the reason for which remains uncertain. Variation of ocean ridge basalt chemistry along the length of the ridge has been correlated with ridge elevation. Thus chemically anomalous ridge segments up to 1000 km long appear to broadly coincide with regions of high magma production (plumes, hot spots). Basalt heterogeneity at a single location indicates mantle heterogeneity on a smaller scale. Variation of ocean ridge basalt chemistry with time has not been established, in fact, criteria for recognizing old oceanic crust in ophiolite terrains are currently under debate. The similarity of rare earth element patterns in basalt from ocean ridges, back-arc basins, some young island arcs, and some continental flood basalts illustrates the dangers of tectonic labeling by rare earth element pattern.     

Early Archaean rocks and geochemical evolution of the earth's crust

Remnants of Early Archaean rocks (>FX3000 m.y. old) are reported from most continents. A critical review of the radiometric data shows that few of these are well authenticated and most are very limited in extent. The oldest are predominantly plutonic gneisses of tonalitic-to-granitic composition (e.g., the basement gneisses of West Greenland, Labrador, Rhodesia and South Africa). In all cases there are inclusions of meta-volcanic and sedimentary rocks with greenstone belt affinities which probably represent crust into which the igneous parents of the gneisses were intruded.The trace element chemistry of these very old rocks is reviewed in an attempt to establish the mechanism of formation of early crust and place constraints on the chemical evolution of the earth's mantle. “Mantle-type” Sr isotope compositions show that the sialic members of both early gneisses and greenstone belts were not derived from much older crustal differentiates, either at 3800 or at 2800 m.y. ago. However, trace element ratios such as K/Rb and Sr/Ba, and rare earth element abundances, are not consistent with direct derivation of the plutonic suite from the upper mantle and also rule out a common parentage for the tonalites and granites. An origin by partial melting of metamorphosed juvenile crust with a composition range equivalent to that represented by the greenstone belts is preferred. Tonalites resulted from high-pressure melting of mafic garnet-amphibolite and at least some of the granites from low-pressure melting of more felsic (possibly even sedimentary) material.The trace element chemistry of the greenstone belt volcanics is thought to characterize the composition of early mantle melts, although the best preserved and best documented cases are about 500–1000 m.y. younger than the oldest known gneisses. The dominant type is tholeiite with low incompatible element contents and light-depleted or essentially flat rare earth patterns, features even more marked in the ultramafic komatiites which represent large degrees of melting. More evolved calc-alkaline rocks with relative incompatible and light rare earth element enrichment are also important. With the exception of the ultramafic lavas, all these types can be matched by the chemistry of present-day oceanic volcanism.It is concluded that the range of trace element variations in the earth's mantle was comparable in early Archaean times to that at the present. This is supported by mass balance calculations for the lithophile elements which have been preferentially extracted into the crust. Thus the isotope and trace element evidence of the oldest rocks argues against primary differentiation of the crust either during accretion of the earth or during its first 500 m.y. as a solid body. Crust formation has probably occurred continuously, although worldwide evidence for magmatism at around 2800 m.y. ago probably marks a particularly active period.