Geochemistry of waters in the Valley of Ten Thousand Smokes region, Alaska

Meteoric waters from cold springs and streams outside of the 1912 eruptive deposits filling the Valley of Ten Thousand Smokes (VTTS) and in the upper parts of the two major rivers draining the 1912 deposits have similar chemical trends. Thermal springs issue in the mid-valley area along a 300-m lateral section of ash-flow tuff, and range in temperature from 21 to 29.8°C in early summer and from 15 to 17°C in mid-summer. Concentrations of major and minor chemical constituents in the thermal waters are nearly identical regardless of temperature. Waters in the downvalley parts of the rivers draining the 1912 deposits are mainly mixtures of cold meteoric waters and thermal waters of which the mid-valley thermal spring waters are representative. The weathering reactions of cold waters with the 1912 deposits appear to have stabilized and add only subordinate amounts of chemical constituents to the rivers relative to those contributed by the thermal waters. Isotopic data indicate that the mid-valley thermal spring waters are meteoric, but data is inconclusive regarding the heat source. The thermal waters could be either from a shallow part of a hydrothermal system beneath the 1912 vent region or from an incompletely cooled, welded tuff lens deep in the 1912 ash-flow sheet of the upper River Lethe area.Bicarbonate-sulfate waters resulting from interaction of near-surface waters and the cooling 1953–1968 southwest Trident plug issue from thermal springs south of Katmai Pass and near Mageik Creek, although the Mageik Creek spring waters are from a well-established, more deeply circulating hydrothermal system. Katmai caldera lake waters are a result of acid gases from vigorous drowned fumaroles dissolving in lake waters composed of snowmelt and precipitation.     

18O/16O studies of fossil fissure fumaroles from the Valley of Ten Thousand Smokes, Alaska

At three sample sites where there are good exposures of the upper 15 m of the 1912 ash-flow sheet in the Valley of Ten Thousand Smokes (VTTS), Alaska, ¹⁸O/¹⁶O studies indicate that fumarolic activity produced a very wide range of δ¹⁸O values (?0.1 to +12.6; n=32) in the groundmass adjacent to fossil fissure fumaroles. This contrasts sharply with the uniformity of δ¹⁸O in the groundmass away from fumarolic conduits (δ¹⁸O=+5.9 to +7.1; n=7) and in all of the feldspar phenocrysts (δ¹⁸O=+6.11 to +7.5 1 for 11 samples from this study and Hildreth 1987), independent of whether these were collected from fossil fumaroles or from unaltered tuff. Only one sample contained feldspars that were even slightly ¹⁸O-enriched relative to the others (cloudy plagioclase δ¹⁸O=+8.45). and this sample also contained the most ¹⁸0-enriched groundmass of any of those analyzed (δ¹⁸O=+12.6). This preservation of primary magmatic δ¹⁸O values in the VTTS feldspar phenocrysts is clearly a consequence of the extremely short time span (i.e., 1912 to ≈1923) of vigorous, high-temperature, fumarolic activity in the 1912 ash-flow sheet. These ¹⁸O/^l6O systematica are strikingly similar to those discovered in the 2.8-Ma intracaldera Chegem Tuff (Gazis et al. 1996) and in the fossil fumaroles in the outflow sheet of the 0.76 Ma Bishop Tuff (Holt and Taylor 1998), thus confirming that a similar type of fumarolic meteoric-hydro-thermal activity occurred above the zone of intense welding in all three of these ash-flow tuffs. This is particularly important, because it provides a direct linkage between the older tuffs and the actual observations at the VTTS of steam chemistry, water/rock interaction, circulation geometry, flow velocities, and fumarolic temperatures (up to 645°C). The ¹⁸O/^l6O effects in the VTTS can all be explained in terms of a two-stage history: (a) an early, 10- to 15-year-long, high-temperature (τ;450°C), fumarolic ¹⁸O-depletion event (groundmass δ¹⁸O=?0.1 to +4.8); and (b) a subsequent, much longer-lived, low-temperature (<150°C), ¹⁸O-enrichment episode (groundmass as high as δ¹⁸O=+12.6). Steam in these low-temperature fumaroles probably passed through various parts of the same hydrothermal system associated with the earlier, higher-temperature, fumarolic activity, and a weakened form of this low-temperature hydrothermal circulation continues to the present day (Keith et al. 1992; Lowell and Keith 1991). This low-temperature ¹⁸O/¹⁶O exchange probably occurred in combination with mineralogical alteration of both the groundmass and the calcium-rich portions of feldspar phenocrysts during the waning (<150°C) stages of fumarolic activity (Spilde et al. 1993). The slight ¹⁸O enrichment of apparently pristine, transparent feldspar phenocrysts (δ¹⁸O=+7.51) in one of the ¹⁸O-depleted, meteoric-hydrothermally altered fumarolic samples (whole-rock δ¹⁸O=+4.8) probably indicates that this sample was incipiently altered at low temperatures as fumarolic activity waned, and thus may have had a whole-rock δ¹⁸O value much lower than +4.87‰ prior to 1923.     

Guagua pichincha volcano, Ecuador: fluid geochemistry in volcanic surveillance

The densely populated metropolitan area of Quito is located on the slopes of the active Guagua Pichincha volcano at only 10 km from the crater. Recently, the Italian Ministry of Foreign Affairs sponsored a project for the mitigation of volcanic hazard in this area. The geochemical study carried out as part of this project was aimed at constructing a geochemical model of the zone for use in volcanic surveillance.According to this geochemical model, a hydrothermal aquifer (T = 200–240°C), fed both by meteoric waters and by fluids released by a magma body, lies at shallow levels beneath Guagua Pichincha crater. The crater fumaroles are essentially fed by steam boiled off from the hydrothermal aquifer. The high flow rate fumaroles located in the dome area show significant SO₂ contents, which suggest a relatively high contribution of magmatic fluids in the zone of the aquifer feeding them. The absence of SO₂ in the fumarolic discharges near the southern crater wall indicates instead that the magmatic fluids dissolve entirely into the aquifer here. The hot springs located at the western end of the crater represent the lateral discharge of the hydrothermal aquifer.On the basis of this model, it is likely that an increment in the flux of both the magmatic fluids and the heat from a magma body produces an increase, albeit small, of the pressure-temperature conditions of the hydrothermal system and consequent changes in flow rate and fluid chemistry of the fumarolic vents. In particular, total sulphur and possibly hydrochloric acid may increase in all the vents and sulphur dioxide may appear in other fumarolic discharges. The varying thermodynamic conditions in the hydrothermal aquifer can be evaluated on the basis of the equilibria among carbon species and hydrogen. Only minor delayed changes are expected in the physical-chemical characteristics of the springs located at the western end of the crater.     

Incremental growth of a large volume,chemically zoned magma body: a study of the tephra sequence beneath the Rainier Mesa ash flow sheet of the Timber Mountain Tuff

The Rainier Mesa ash-flow is a large (1200 km³), 11.6 My old, chemically zoned unit that ranges in composition from 55 to 76% SiO₂ — one of the largest chemical ranges ever observed in a large volume ash-flow sheet. Two chemical trends occur in this sheet, a low silica (55–66% SiO₂) and a high silica (>66% SiO₂) trend. Ninety per cent of the Rainier Mesa sheet occurs in the high silica trend. Immediately beneath the Rainier Mesa sheet is a thick tephra sequence. The chemical variation of this sequence is nearly equivalent to the high silica portion of the Rainier Mesa ash-flow sheet (about 66–78% SiO₂). Throughout the tephra sequence numerous small ash-flow layers occur, and each ash-flow layer is chemically zoned from more evolved at the base to less evolved at the top. This is consistent with having been erupted from a zoned magma body. The lowest silica tephra units are at the base of the sequence and the highest silica units are at the top — that is, the large-scale chemical trend of the entire sequence is opposite to that of the individual ash-flow layers. These ash-flow layers are of very small volume. The tephra sequence provides a unique record of the incremental development of the zoned, high silica portion of the Rainier Mesa magma body.     

A resurgent cauldron in the early Paleozoic of Wales, U.K.

The paper presents a controversial interpretation of a mid-Ordovician volcano-sedimentary complex. It deals with the cyclic interdependence of intrusive, volcanic, and sedimentary processes, due to the development of a nearshore resurgent cauldron in the Caledonian fold belt of North Wales. Deformed volcanotectonic features include a resurgent dome and apical graben, surrounded by a moat and peripheral crescentic ring-fault, constituting a caldera 20 km in diameter. The resurgent Snowdon caldera developed through three cycles of ash-flow volcanism resulting from the continuous supply of magma into a shallow magma chamber emplaced beneath the floor of a marine basin. Each ash-flow cycle was preceded by the emergence, above sea level, of a geotumour that subsequently collapsed following eruption and evacuation of the magma chamber. Localized unconformities at the base of individual ash-flow cycles are compared with caldera margin and associated collapse features. Deeper-seated effects of caldera collapse are expressed as gaps in the Ordovician sequence due to normal faulting along the structural boundary of the caldera. Major ash-flow fissure vents were located at points of maximum unloading of the magma chamber by distention faults in its roof. Explosive mechanisms were triggered by rapid pressure release due to tectonic erosion.The presence of a resurgent cauldron implies that the Ordovician succession of North Wales is more complete than recorded in the literature, and that Caledonian structures were largely predetermined by Caradocian volcano-tectonics.     

Geochemical and isotopic evidence for seawater contamination of the hydrothermal system of Taal Volcano, Luzon, the Philippines

 The hydrologic structure of Taal Volcano has favored development of an extensive hydrothermal system whose prominent feature is the acidic Main Crater Lake (pH<3) lying in the center of an active vent complex, which is surrounded by a slightly alkaline caldera lake (Lake Taal). This peculiar situation makes Taal prone to frequent, and sometimes catastrophic, hydrovolcanic eruptions. Fumaroles, hot springs, and lake waters were sampled in 1991, 1992, and 1995 in order to develop a geochemical model for the hydrothermal system. The low-temperature fumarole compositions indicate strong interaction of magmatic vapors with the hydrothermal system under relatively oxidizing conditions. The thermal waters consist of highly, moderately, and weakly mineralized solutions, but none of them corresponds to either water–rock equilibrium or rock dissolution. The concentrated discharges have high Na contents (>3500 mg/kg) and low SO₄/Cl ratios (<0.3). The Br/Cl ratio of most samples suggests incorporation of seawater into the hydrothermal system. Water and dissolved sulfate isotopic compositions reveal that the Main Crater Lake and spring discharges are derived from a deep parent fluid (T≈300  °C), which is a mixture of seawater, volcanic water, and Lake Taal water. The volcanic end member is probably produced in the magmatic-hydrothermal environment during absorption of high-temperature gases into groundwater. Boiling and mixing of the parent water give rise to the range of chemical and isotopic characteristics observed in the thermal discharges. Incursion of seawater from the coastal region to the central part of the volcano is supported by the low water levels of the lakes and by the fact that Lake Taal was directly connected to the China sea until the sixteenth century. The depth to the seawater-meteoric water interface is calculated to be 80 and 160 m for the Main Crater Lake and Lake Taal, respectively. Additional data are required to infer the hydrologic structure of Taal. Geochemical surveillance of the Main Crater Lake using the SO₄/Cl, Na/K, or Mg/Cl ratio cannot be applied straightforwardly due to the presence of seawater in the hydrothermal system. Received: 12 February 1997 / Accepted: 26 January 1998     

Geochemistry of the thermal springs and fumaroles of Basse-Terre Island,Guadeloupe, Lesser Antilles

 The purpose of this work was to study jointly the volcanic-hydrothermal system of the high-risk volcano La Soufrière, in the southern part of Basse-Terre, and the geothermal area of Bouillante, on its western coast, to derive an all-embracing and coherent conceptual geochemical model that provides the necessary basis for adequate volcanic surveillance and further geothermal exploration. The active andesitic dome of La Soufrière has erupted eight times since 1660, most recently in 1976–1977. All these historic eruptions have been phreatic. High-salinity, Na–Cl geothermal liquids circulate in the Bouillante geothermal reservoir, at temperatures close to 250  °C. These Na–Cl solutions rise toward the surface, undergo boiling and mixing with groundwater and/or seawater, and feed most Na–Cl thermal springs in the central Bouillante area. The Na–Cl thermal springs are surrounded by Na–HCO₃ thermal springs and by the Na–Cl thermal spring of Anse à la Barque (a groundwater slightly mixed with seawater), which are all heated through conductive transfer. The two main fumarolic fields of La Soufrière area discharge vapors formed through boiling of hydrothermal aqueous solutions at temperatures of 190–215  °C below the "Ty" fault area and close to 260  °C below the dome summit. The boiling liquid producing the vapors of the Ty fault area has δD and δ¹⁸O values relatively similar to those of the Na–Cl liquids of the Bouillante geothermal reservoir, whereas the liquid originating the vapors of the summit fumaroles is strongly enriched in ¹⁸O, due to input of magmatic fluids from below. This process is also responsible for the paucity of CH₄ in the fumaroles. The thermal features around La Soufrière dome include: (a) Ca–SO₄ springs, produced through absorption of hydrothermal vapors in shallow groundwaters; (b) conductively heated, Ca–Na–HCO₃ springs; and (c) two Ca–Na–Cl springs produced through mixing of shallow Ca–SO₄ waters and deep Na–Cl hydrothermal liquids. The geographical distribution of the different thermal features of La Soufrière area indicates the presence of: (a) a central zone dominated by the ascent of steam, which either discharges at the surface in the fumarolic fields or is absorbed in shallow groundwaters; and (b) an outer zone, where the shallow groundwaters are heated through conduction or addition of Na–Cl liquids coming from hydrothermal aquifer(s). Received: 9 November 1998 / Accepted: 15 July 1999     

The hydrothermal system of the Calabozos caldera,central Chilean Andes

Active thermal springs associated with the late Pleistocene Calabozos caldera complex occur in two groups: the Colorado group which issues along structures related to caldera collapse and resurgence, and the Puesto Calabozos group, a nearby cluster that is chemically distinct and probably unrelated to the Colorado springs. Most of the Colorado group can be related to a hypothetical parent water containing ∼400 ppm Cl at ∼250°C by dilution with ≥50% of cold meteoric water. The thermal springs in the most deeply eroded part of the caldera were derived from the same parent water by boiling.The hydrothermal system has probably been active for at least as long as 300,000 years, based on geologic evidence and calculations of paleo-heat flow. There is no evidence for economic mineralization at shallow depth. The Calabozos hydrothermal system would be an attractive geothermal prospect were its location not so remote.     

The hydrothermal system of Nevado del Ruiz volcano,Colombia

Hot springs and steam vents on the slopes of Nevado del Ruiz volcano provide evidence regarding the nature of hydrothermal activity within the summit and flanks of the volcano. At elevations below 3000 m, alkali-chloride water is discharged from two groups of boiling springs and several isolated warm springs on the western slope of Nevado del Ruiz. Chemical and isotopic geothermometers suggest that the boiling springs are fed by an aquifer having a subsurface equilibration temperature of at least 175°C, and the sampled warm spring is fed by an aquifer having a subsurface equilibration temperature near 150°C. Similarities in conservative solute ratios (e.g., B/Cl) indicate that the alkali-chloride waters may be related to a single reservoir at depth. Isotopic ratios of hydrogen and oxygen indicate that recharge for the alkali-chloride aquifers comes mostly from higher elevations on the volcano. Steam vents and steam-heated bicarbonate-sulfate springs at higher elevations, along a linear structural trend with the alkali-chloride springs, may be derived partly from the alkali-chloride water at depth by boiling. Steam from the vents (84°C) yields a gas geothermometer temperature of 209°C. Acid-sulfate-chloride and acid-sulfate waters are discharged widely from warm springs above 3000 m on the northern and eastern slopes of Nevado del Ruiz. Similarities in B/Cl and SO₄/Cl ratios suggest that the acid waters are mixtures of water from an acid-sulfate-chloride reservoir with various proportions of shallow, dilute groundwater. The major source of sulfate, halogens, and acidity for the acid waters may be high-temperature magmatic gases. Available data on hot spring temperatures and compositions indicate that they have remained fairly stable since 1968. However, the eruption of November 13, 1985 apparently caused an increase in sulfate concentration in some of the acid springs that peaked about a year after the eruption. Long-term monitoring of hot spring compositions over many years will be required to better define the effects of volcanic activity on the Nevado del Ruiz hydrothermal system.     

The Oka hydrothermal system, East Sayan mountains

The western flank of the Baikal Rift Zone contains the Oka hydrothermal system of the “volcanogenic type,” which is related to the occurrence of basaltic volcanism. It consists of springs for the discharge of thermal and subthermal waters confined to the intersections of faults of various settings at the boundary of two major lithospheric blocks. Helium isotope data were used to find heat flow for all springs of the hydrothermal system; this heat flow is comparable with that across the bottom of the Baikal southern basin. Predicted hydrotherm temperatures were calculated at the depths of their generation using silica and cation thermometers. The average depth of generation of the springs that form the Oka hydrothermal system is 2.8 km, which is 1.1 km nearer to the ground surface than the h of the hydrothermal occurrences around Lake Baikal. The spatial coincidence between the location of the hydrothermal system and the area of young volcanism provides evidence of a common source of heat, while the thermal parameters of the system, its gas and chemical compositions, correlate with the age of the volcanism.     

Origin of silicic volcanic rocks in Central Costa Rica: a study of a chemically variable ash-flow sheet in the Tiribí Tuff

Chemical heterogeneities of pumice clasts in an ash-flow sheet can be used to determine processes that occur in the magma chamber because they represent samples of magma that were erupted at the same time. The dominant ash-flow sheet in the Tiribí Tuff contains pumice clasts that range in composition from 55.1 to 69.2 wt% SiO₂. It covers about 820 km² and has a volume of about 25 km³ dense-rock equivalent (DRE). Based on pumice clast compositions, the sheet can be divided into three distinct chemical groupings: a low-silica group (55.1-65.6 wt% SiO₂), a silicic group (66.2-69.2 wt% SiO₂), and a mingled group (58.6-67.7 wt% SiO₂; all compositions calculated 100% anhydrous). Major and trace element modeling indicates that the low-silica magma represents a mantle melt that has undergone fractional crystallization, creating a continuous range of silica content from 55.1-65.6 wt% SiO₂. Eu/Eu*, MREE, and HREE differences between the two groups are not consistent with crystal fractionation of the low-silica magma to produce the silicic magma. The low-silica group and the silicic group represent two distinct magmas, which did not evolve in the same magma chamber. We suggest that the silicic melts resulted from partial melting of relatively hot, evolved calc-alkaline rocks that were previously emplaced and ponded at the base of an over-thickened basaltic crust. The mingled group represents mingling of the two magmas shortly before eruption. Electronic supplementary material to this paper can be obtained by using the Springer LINK server located at http://dx.doi.org/10.1007/s00445-001-0188-8.     

Evolution of tholeiitic diabase sheet systems in the eastern United States: examples from the Culpeper Basin, Virginia-Maryland, and the Gettysburg Basin, Pennsylvania

High-TiO₂, quartz-normative (HTQ) tholeiite sheets of Early Jurassic age have intruded mainly Late Triassic sedimentary rocks in several early Mesozoic basins in the eastern United States. Field observations, petrographic study, geochemical analyses and stable isotope data from three HTQ sheet systems in the Culpeper basin of Virginia and Maryland and the Gettysburg basin of Pennsylvania were used to develop a general model of magmatic differentiation and magmatic-hydrothermal interaction for HTQ sheets. The three sheet systems have remarkably similar major-oxide and trace-element compositions. Cumulus and evolved diabase in comagmatic sheets separated by tens of kilometers are related by igneous differentiation. Differentiated diabase in all three sheets have petrographic and geochemical signatures and fluid inclusions indicating hydrothermal alteration beginning near magmatic temperatures and continuing to relatively low temperatures. Sulfur and oxygen isotope data are consistent with a magmatic origin for the hydrothermal fluid.The three sheet systems examined apparently all had a similar style of crystal-liquid fractionation that requires significant lateral migration of residual magmatic liquid. The proposed magmatic model for HTQ sheets suggests that bronzite-laden magma was intruded in an upper crustal magma chamber, with bronzite phenocrysts collecting in the lower part of the magma chamber near the feeder dike. Early crystallization of augite and Ca-poor pyroxene before significant plagioclase crystallization resulted in density-driven migration of lighter residual magmatic liquids along lateral and vertical pressure gradients towards the upper part of the sheet. The influence of water on the physical properties of the residual liquid, including density, viscosity and liquidus temperature, may have facilitated the lateral movement more than 15 km up dip in the sheets. Exsolution of a Cl- and S-rich metal-bearing aqueous fluid from residual magma resulted in concentration and redistribution of incompatible and aqueoussoluble elements in late-stage differentiated rocks. This proposed hydrothermal mechanism has important economic implications as it exerts a strong control on the final distribution of noble metals in these types of diabase sheets.     

The imprint of basalt on the geochemistry of silicic magmas

We propose that the fluid mechanics of magma chamber replenishment leads to a novel process whereby silicic magmas can acquire an important part of their chemical signatures. When flows of basaltic magma enter silicic magma chambers, they assume a ‘fingered' morphology that creates a large surface area of contact between the two magmas. This large surface area provides an opportunity for significant chemical exchange between the magmas by diffusion that is enhanced by continuous flow of silicic liquid traversing the basalt through thin veins. A quantitative analysis shows that a basaltic magma may thereby impart its trace-element and isotopic characteristics to a silicic magma. Depending on concentration differences and diffusion coefficients for the given components, this new mechanism may be as important as crystal fractionation and assimilation in producing the compositional diversity of silicic magmas. It may explain concentration gradients in silicic ash-flow tuffs and should be considered when interpreting the isotopic signatures of silicic rocks, even in the overt absence of mixing. For example, we show that, for several well studied, compositionally graded ash-flow tuffs, the concentrations and isotopic ratios of important geochemical tracers such as strontium could be largely due to this flow-enhanced diffusion process.     

The Christmas Mountains caldera complex,Trans-Pecos Texas

The Christmas Mountains caldera complex developed approximately 42 Ma ago over an elliptical (8×5 km) laccolithic dome that formed during emplacement of the caldera magma body. Rocks of the caldera complex consist of tuffs, lavas, and volcaniclastic deposits, divided into five sequences. Three of the sequences contain major ash-flow tuffs whose eruption led to collapse of four calderas, all 1–1.5 km in diameter, over the dome. The oldest caldera-related rocks are sparsely porphyritic, rhyolitic, air-fall and ash-flow tuffs that record formation and collapse of a Plinian-type eruption column. Eruption of these tuffs induced collapse of a wedge along the western margin of the dome. A second, more abundantly porphyritic tuff led to collapse of a second caldera that partly overlapped the first. The last major eruptions were abundantly porphyritic, peralkaline quartz-trachyte ash-flow tuffs that ponded within two calderas over the crest of the dome. The tuffs are interbedded with coarse breccias that resulted from failure of the caldera walls. The Christmas Mountains caldera complex and two similar structures in Trans-Pecos Texas constitute a newly recognized caldera type, here termed a laccocaldera. They differ from more conventional calderas by having developed over thin laccolithic magma chambers rather than more deep-seated bodies, by their extreme precaldera doming and by their small size. However, they are similar to other calderas in having initial Plinian-type air-fall eruption followed by column collapse and ash-flow generation, multiple cycles of eruption, contemporaneous eruption and collapse, apparent pistonlike subsidence of the calderas, and compositional zoning within the magma chamber. Laccocalderas could occur else-where, particularly in alkalic magma belts in areas of undeformed sedimentary rocks.     

Geochemistry of the magmatic–hydrothermal system of Kawah Ijen volcano, East Java, Indonesia

Samples from Kawah Ijen crater lake, spring and fumarole discharges were collected between 1990 and 1996 for chemical and isotopic analysis. An extremely low pH (<0.3) lake contains SO₄–Cl waters produced during absorption of magmatic volatiles into shallow ground water. The acidic waters dissolve the rock isochemically to produce “immature” solutions. The strong D and ¹⁸O enrichment of the lake is mainly due to enhanced evaporation at elevated temperature, but involvement of a magmatic component with heavy isotopic ratios also modifies the lake D and ¹⁸O content. The large Δ_SO4–S⁰ (23.8–26.4‰) measured in the lake suggest that dissolved SO₄ forms during disproportionation of magmatic SO₂ in the hydrothermal conduit at temperatures of 250280°C. The lake δ¹⁸O_SO4 and δ¹⁸O_H2O values may reflect equilibration during subsurface circulation of the water at temperatures near 150°C. Significant variations in the lake's bulk composition from 1990 to 1996 were not detected. However, we interpret a change in the distribution and concentration of polythionate species in 1996 as a result of increased SO₂-rich gas input to the lake system.Thermal springs at Kawah Ijen consist of acidic SO₄–Cl waters on the lakeshore and neutral pH HCO₃–SO₄–Cl–Na waters in Blawan village, 17 km from the crater. The cation contents of these discharges are diluted compared to the crater lake but still do not represent equilibrium with the rock. The SO₄/Cl ratios and water and sulfur isotopic compositions support the idea that these springs are mixtures of summit acidic SO₄–Cl water and ground water.The lakeshore fumarole discharges (T=170245°C) have both a magmatic and a hydrothermal component and are supersaturated with respect to elemental sulfur. The apparent equilibrium temperature of the gas is 260°C. The proportions of the oxidized, SO₂-dominated magmatic vapor and of the reduced, H₂S-dominated hydrothermal vapor in the fumaroles varied between 1979 and 1996. This may be the result of interaction of SO₂-bearing magmatic vapors with the summit acidic hydrothermal reservoir. This idea is supported by the lower H₂S/SO₂ ratio deduced for the gas producing the SO₄–Cl reservoir feeding the lake compared with that observed in the subaerial gas discharges. The condensing gas may have equilibrated in a liquid–vapor zone at about 350°C.Elemental sulfur occurs in the crater lake environment as banded sediments exposed on the lakeshore and as a subaqueous molten body on the crater floor. The sediments were precipitated in the past during inorganic oxidation of H₂S in the lake water. This process was not continuous, but was interrupted by periods of massive silica (poorly crystallized) precipitation, similar to the present-day lake conditions. We suggest that the factor controlling the type of deposition is related to whether H₂S- or silica-rich volcanic discharges enter the lake. This could depend on the efficiency with which the lake water circulates in the hydrothermal cell beneath the crater. Quenched liquid sulfur products show δ³⁴S values similar to those found in the banded deposits, suggesting that the subaqueous molten body simply consists of melted sediments previously accumulated at the lake bottom.     

Geothermal data analysis at the high-temperature hydrothermal area in Western Sichuan

The western Sichuan hydrothermal area is located at the northeastern margin of the eastern syntaxis of the Qinghai-Tibet Plateau, which is also the eastern end of the Mediterranean-Himalayan geothermal activity zone. There are 248 warm or hot springs in this area, and 11 have temperatures beyond the local boiling temperature. Most of these hot springs are distributed along the Jinshajiang, Dege-Xiangcheng, Ganzi-Litang, and Xianshuihe faults, forming a NW-SE hydrothermal belt. A geothermal analysis of this high-temperature hydrothermal area is an important basis for understanding the deep geodynamic process of the eastern syntaxis of the Qinghai-Tibet Plateau. In addition, this study offers an a priori view to utilize geothermal resources, which is important in both scientific research and application. We use gravity, magnetic, seismic, and helium isotope data to analyze the crust-mantle heat flow ratio and deep geothermal structure. The results show that the background terrestrial heat flow descends from southwest to northeast. The crustal heat ratio is not more than 60%. The high temperature hydrothermal active is related to crustal dynamics processes. Along the Batang-Litang-Kangding line, the Moho depth increases eastward, which is consistent with the changing Qc/Qm(crustal/mantle heat flow) ratio trend. The geoid in the hydrothermal zone is 4–6 km higher than the surroundings, forming a local "platform". The NW-SE striking local tensile stress zone and uplift structure in the upper and middle crust corresponds with the surface hydrothermal active zone. There is an average Curie Point Depth(CPD) of 19.5–22.5 km in Batang, Litang, and Kangding. The local shear-wave(S-wave) velocity is relatively low in the middle and lower crust. The S-wave shows a low velocity trap(Vs3.2 km s.1) at 15–30 km, which is considered a high-temperature partial melting magma, the crustal source of the hydrothermal active zone. We conclude that the hydrothermal system in this area can be divided into Batang-type and Kangding-type, both of which rely on a crustal heating cycle of atmospheric precipitation and surface water along the fracture zone. The heat is derived from the middle and lower crust: groundwater penetrates the deep faults bringing geothermal energy back to the surface and forming high-temperature springs.     

Surface mercury geochemistry as a guide to volcanic vent structure and zones of high heat flow in the valley of ten thousand smokes, Katmai National Park, Alaska

A reconnaissance survey of Hg° was designed to model the 1912 Novarupta vent structure and delineate zones of near-surface high heat flow. Statistical analysis of 294 regolith samples collected at 127 sites from fossil/active fumaroles and relatively unaltered ash-flow tuff and air-fall ejecta indicates two Hg° sample populations; one associated with fumarole deposits and the other corresponding to the relatively unaltered regolith. Measured Hg° concentrations range from 12 to 6913 ppb. Sample threshold (upper limit of background Hg° concentrations; fumarole deposits: 351 ppb, unaltered regolith: 110 ppb) and contrast (sample value/threshold) determinations enable differentiation between relict and actively accumulating Hg° contents.All significant Hg° anomalies (contrast values > 1.5) occur within Novarupta Basin. High-magnitude, active Hg² enrichment was found on the Turtle, a dome-like feature northeast of the Novarupta extrusive dome. The Hg° data, coupled with available geologic and geophysical evidence, suggest a shallow intrusion beneath the Turtle. Results from two Novarupta Basin sample traverses do not support the presence of a near-surface magma feeder dike connecting the proposed intrusion beneath the Turtle with the Novarupta dome. Based on the Hg° data, the preferred vent model is one generated by collapse of supporting walls after the major eruptive phase into a cored-out explosive vent. Collapse of vent walls is initiated along a series of deep-extending faults which subsequently serve as migration pathways for Hg° to the surface. The overall vent morphology is funnel-like with subsidence concentrated in the narrow funnel center. Results of this study show that Hg° surveys can further constrain the morphology of the 1912 vent and aid in delineating zones of near-surface high heat flow in this region.     

Steady-state operation of Stromboli volcano,Italy: constraints on the feeding system

Stromboli volcano has been in continuous eruption for several thousand years without major changes in the geometry and feeding system. The thermal structure of its upper part is therefore expected to be close to steady state. In order to mantaim explosive activity, magma must release both gas and heat. It is shown that the thermal and gas budgets of the volcano lead to consistent conclusions. The thermal budget of the volcano is studied by means of a finite-element numerical model under the assumption of conduction heat transfer. It is found that the heat loss through the walls of an eruption conduit is weakly sensitive to the dimensions of underlying magma reservoirs and depends mostly on the radius and length of the conduit. In steady state, this heat loss must be balanced by the cooling of magma which flows through the system. For the magma flux of about 1 kg s^-1 corresponding to normal Strombolian activity, this requires that the conduits are a few meters wide and not deeper than a few hundred meters. This implies the existence of a magma chamber at shallow depth within the volcanic edifice. This conclusion is shown to be consistent with considerations on the thermal effects of degassing. In a Strombolian explosion, the mass ratio of gas to lava is very large, commonly exceeding two, which implies that the thermal evolution of the erupting mixture is dominated by that of the gas phase. The large energy loss due to decompression of the gas phase leads to decreased eruption temperatures. The fact that lava is molten upon eruption implies that the mixture does not rise from more than about 200 m depth. To sustain the magmatic and volcanic activity of Stromboli, a mass flux of magma of a few hundred kilograms per second must be supplied to the upper parts of the edifice. This represents either the rate of magma production from the mantle source feeding the volcano or the rate of magma overturn in the interior of a large chamber.     

Temporal geochemical variations in volatile emissions from Mount St. Helens, USA, 1980–1994

Fumarole discharges (95–560°C) collected from the dacite dome inside Mount St. Helens crater show temporal changes in their isotopic and chemical compositions. A δD vs. δ¹⁸O plot shows that condensed waters from the gases are mixtures of meteoric and magmatic components, but that the apparent magmatic end-member in 1994 was depleted by about 7‰ in δD relative to the apparent end-member in 1980. Based on δD modeling, approximately 63% of shallow, post-1980 magma has yet to degas. Surprisingly, Cl and F contents in the 1994 samples were only 0.47 and 3.8%, respectively, of the concentrations determined for end-member magmatic fluid in 1980. The data indicate that Cl (and F and B) is degassed from magma relatively quickly compared to water and/or that most of the Cl degassed in later years is dissolved into the shallow Mount St. Helens hydrothermal system. Because metals are often transported in magmatic and hydrothermal fluids as Cl complexes, rapid changes in surface volatile compositions may have implications for the timing and location of metals transport and deposition in some volcanoes.     

Simultaneous crystallization and melting at both the roof and floor of crustal magma chambers: Experimental study using NH4Cl–H2O binary eutectic system

Thermal and compositional evolution of magmas after emplacement of basalt into continental crust has been investigated by means of fluid dynamic experiments using a cold solid mixture with eutectic composition and a hot liquid with higher salinity in the NH₄Cl–H₂O binary eutectic system. The experiments were designed to simulate cases where crystallization of a basalt magma is accompanied by melting at both the roof and floor of a crustal magma chamber. The results show that thermal and compositional convection occur simultaneously in the solution; the thermal convection is driven by cooling at the roof and the compositional convection is driven by melting and crystallization at the floor. The roof was rapidly melted by the convective heat flux, which resulted in formation of a separate eutectic melt layer (the upper liquid layer) with negligible mixing of the underlying liquid (the lower liquid layer). On the other hand, a mushy layer formed at the floor. The compositional convection at the floor carried a low heat flux, so that the heat transfer at the floor was basically explained by simple heat conduction. The thermal boundary layer in the lower liquid layer at the interface with the upper liquid layer became thicker with time and subsequently temperature decreased upward throughout the lower liquid layer. Compositional gradient with NH₄Cl content decreasing upward formed by compositional convection in the lower liquid layer. The formation of these gradients resulted in formation of double-diffusive convecting layers in the lower liquid layer. The upward heat transfer was suppressed when compared with the case where the liquid region is homogenized by vigorous convection.These experimental results imply that, when a basalt magma is emplaced in continental crust, floor melting does not always enhance the cooling of the magma, but it may even reduce the total heat loss from the magma to the crusts due to suppression of convection by formation of a stabilizing compositional gradient.