Impressions of the turbulence variability in a weakly stratified,flat-bottom deep-sea ‘boundary layer’

The character of turbulent overturns in a weakly stratified deep-sea is investigated in some detail using 144 high-resolution temperature sensors at 0.7 m intervals, starting 5 m above the bottom. A 9-day, 1 Hz sampled record from the 912 m depth flat-bottom (<0.5% bottom-slope) mooring site in the central-north Alboran Sea (W-Mediterranean) demonstrates an overall conservative temperature range of only 0.05 °C, a typical mean buoyancy period as large as 3 h and a 1 Hz-profile-vertically-averaged turbulence dissipation rate maximum of only 10⁻⁸ m² s⁻³. Nonetheless, this ‘boundary layer’ varies in height between <6 and >104 m above the bottom and is thus not homogeneous throughout; the temperature variations are seldom quiescent and are generally turbulent in appearance, well exceeding noise levels. The turbulence character is associated with small-scale internal waves; examples are found of both shear- and convection-driven turbulence; particular association, although not phase-locked, is found between turbulence variations and tidal rather than with inertial motions; the mean buoyancy frequency of a few times the inertial frequency implies the importance of ‘slantwise convection’ in the direction of the earth rotational vector rather than in the direction of gravity. Such convection is observed both in near-homogeneous and weakly stratified form.     

Below-cloud rain scavenging of atmospheric aerosols for aerosol deposition models

Below-cloud aerosol scavenging is generally estimated from field measurements using advanced instruments that measure changes in aerosol distributions with respect to rainfall. In this study, we discuss various scavenging mechanisms and scavenging coefficients from past laboratory and field measurements. Scavenging coefficients derived from field measurements (representing natural aerosols scavenging) are two orders higher than that of theoretical ones for smaller particles (D_p < 2 μm). Measured size-resolved scavenging coefficients can be served as a better option to the default scavenging coefficient (e.g. a constant of 10^?4 s^?1 for all size of aerosols, as used in the CALPUFF model) for representing below-cloud aerosol scavenging. We propose scavenging correction parameter (C_R) as an exponential function of size-resolved scavenging coefficients, winds and width in the downwind of the source–receptor system. For a wind speed of 3 m s^?1, C_R decrease with the width in the downwind for particles of diameters D_p < 0.1 μm but C_R does not vary much for particles in the accumulation mode (0.1 < D_p < 2 μm). For a typical urban aerosol distribution, assuming 3 m s^?1 air-flow in the source–receptor system, 10 km downwind width, 2.84 mm h^?1 of rainfall and using aerosol size dependent scavenging coefficients in the C_R, scavenging of aerosols is found to be 16% in number and 24% in volume of total aerosols. Using the default scavenging coefficient (10^?4 s^?1) in the CALPUFF model, it is found to be 64% in both number and volume of total aerosols.     

Exploring the vertical extent of breaking internal wave turbulence above deep-sea topography

A mooring equipped with 200 high-resolution temperature sensors between 6 and 404 m above the bottom was moored in 1890 m water depth above a steep, about 10° slope of Mount Josephine, NE-Atlantic. The sensors have a precision of less than 0.5 mK. They are synchronized via induction every 4 h so that the 400 m range is measured to within 0.02 s, every 1 s. Thin cables and elliptical buoyancy assured vertical mooring motions to be smaller than 0.1 m under maximum 0.2 m s⁻¹ current speeds. The local bottom slope is supercritical for semidiurnal internal tides by a factor of two. Exploring a one-month record in detail, the observations show: 1/semidiurnal tidal dominance in variations of dissipation rate ε, eddy diffusivity K_z and temperature, but no significant correlation between the records of ε and total kinetic energy, 2/a variation with time over four orders of magnitude of 100-m vertically averaged ε, 3/a local minimum in density stratification between 50 and 100 m above the bottom, 4/a gradual decrease in daily or longer averaged ε and K_z by one order of magnitude over a vertical distance of 250 m, upwards from 150 m above the bottom, 5/monthly mean values of <[ε]> = 2 ± 0.5 × 10⁻⁷ m² s⁻³, <[K_z]> = 8 ± 3 × 10⁻³ m² s⁻¹ averaged over the lower 150 m above the bottom.     

Distribution of CO2 parameters in the Western Tropical Atlantic Ocean

The variability of sea surface Total Alkalinity (TA) and sea surface Total Inorganic Carbon (C_T) is examined using all available data in the western tropical Atlantic (WTA: 20°S-20°N, 60°W-20°W). Lowest TA and C_T are observed for the region located between 0°N-15°N/60°W-50°W and are explained by the influence of the Amazon plume during boreal summer. In the southern part of the area, 20°S-10°S/40°W-60°W, the highest values of TA and C_T are linked to the CO₂–rich waters due to the equatorial upwelling, which are transported by the South Equatorial Current (SEC) flowing from the African coast to the Brazilian shore. An increase of C_T of 0.9 ± 0.3 μmol kg⁻¹yr⁻¹ has been observed in the SEC region and is consistent with previous published estimates. A revised C_T-Sea Surface Salinity (SSS) relationship is proposed for the WTA to take into account the variability of C_T at low salinities. This new C_T-SSS relationship together with a published TA-SSS relationship allow to calculate pCO₂ values that compare well with observed pCO₂ (R² = 0.90).     

One year measurements of aerosol optical properties over an urban coastal site: Effect on local direct radiative forcing

We present results of direct aerosol radiative forcing over a French Mediterranean coastal zone based on one year of continuous observations of aerosol optical properties during 2005–2006. Monthly-mean aerosol optical depth at 440 nm ranged between 0.1 and 0.34, with high Angstrom coefficient (α > 1.2). The single scattering albedo (at 525 nm) estimated at the surface ranged between 0.7 and 0.8, indicating significant absorption. The presence of aerosols over the Mediterranean zone during summer decreases the shortwave radiation reaching the surface by as much as 26 ± 3.9 W m^− 2, and increases the top of the atmosphere reflected radiation by as much as 5.2 ± 1.0 W m^− 2. The shortwave atmospheric absorption translates to an atmospheric heating of 2.5 to 4.6 K day^− 1. Concerted efforts are needed for investigating the possible impact of the increase in heating rate on the maintenance of heat-waves frequently occurring over this coastal region during summer time.     

Size-resolved aerosol chemical concentrations at rural and urban sites in Central California,USA

Aerosol size distributions were measured with Micro Orifice Uniform Deposit Impactor (MOUDI) cascade impactors at the rural Angiola and urban Fresno Supersites in California's San Joaquin Valley during the California Regional PM₁₀/PM_2.5 Air Quality Study (CRPAQS) winter campaign from December 15, 2000 to February 3, 2001. PM_2.5 filter samples were collected concurrently at both sites with Sequential Filter Samplers (SFS). MOUDI nitrate (NO₃⁻) concentrations reached 66 μg/m³ on January 6, 2001 during the 1000–1600 PST (GMT-8) period. Pair-wise comparisons between PM_2.5 MOUDI and SFS concentrations revealed high correlations at the Angiola site (r > 0.93) but more variability (r < 0.85) at the Fresno site for NO₃⁻, sulfate (SO₄⁼), and ammonium (NH₄⁺). Correlations were higher at Fresno (r > 0.87) than at Angiola (r < 0.7) for organic carbon (OC), elemental carbon (EC), and total carbon (TC). NO₃⁻ and SO₄⁼ size distributions in Fresno were multi-modal and wider than the uni-modal distributions observed at Angiola. Geometric mean diameters (GMD) were smaller for OC and EC than for NO₃⁻ and SO₄⁼ at both sites. OC and EC were more concentrated on the lowest MOUDI stage (0.056 µm) at Angiola than at Fresno. The NO₃⁻ GMD increased from 0.97 to 1.02 µm as the NO₃⁻ concentration at Angiola increased from 43 to 66 µg m^− 3 during a PM_2.5 episode from January 4–7, 2001. There was a direct relationship between GMD and NO₃⁻ and SO₄⁼ concentrations at Angiola but no such relationships for OC or EC. This demonstrates that secondary aerosol formation increases both concentration and particle size for the rural California environment.     

The origin of sub-surface source waters define the sea–air flux of methane in the Mauritanian Upwelling,NW Africa

Concentrations and flux densities of methane were determined during a Lagrangian study of an advective filament in the permanent upwelling region off western Mauritania. Newly upwelled waters were dominated by the presence of North Atlantic Central Water and surface CH₄ concentrations of 2.2 ± 0.3 nmol L⁻¹ were largely in equilibrium with atmospheric values, with surface saturations of 101.7 ± 14%. As the upwelling filament aged and was advected offshore, CH₄ enriched South Atlantic Central Water from intermediate depths of 100–350 m was entrained into the surface mixed layer of the filament following intense mixing associated with the shelf break. Surface saturations increased to 198.9 ± 15% and flux densities increased from a mean value over the shelf of 2.0 ± 1.1 μmol m⁻² d⁻¹ to a maximum of 22.6 μmol m⁻² d⁻¹. Annual CH₄ emissions for this persistent filament were estimated at 0.77 ± 0.64 Gg which equates to a maximum of 0.35% of the global oceanic budget. This raises the known outgassing intensity of this area and highlights the importance of advecting filaments from upwelling waters as efficient vehicles for air-sea exchange.     

A method for determining thermophysical properties of organic material in aqueous solutions: Succinic acid

A method for determining evaporation rates and thermodynamic properties of aqueous solution droplets is introduced. The method combines evaporation rate measurements using modified TDMA technique with data evaluation using an accurate evaporation model. The first set of data has been collected and evaluated for succinic acid aqueous solution droplets.Evaporation rates of succinic acid solution droplets have been measured using a TDMA system at controlled relative humidity (65%) and temperature (298 K). A temperature-dependent expression for the saturation vapour pressure of pure liquid phase succinic acid at atmospheric temperatures has been derived by analysing the evaporation rate data with a numerical model. The obtained saturation vapour pressure of liquid phase succinic acid is ln(p) = 118.41 − 16204.8/T − 12.452ln(T). The vapour pressure is in unit of Pascal and the temperature in Kelvin. A linear expression for the enthalpy of vaporization for liquid state succinic acid is also presented.According to the results presented in the following, a literature expression for the vapour pressure of liquid phase succinic acid defined for temperatures higher than 461 K [Yaws, C.L., 2003. Yaws' Handbook of Thermodynamic and Physical Properties of Chemical Compounds, Knovel] can be extrapolated to atmospheric temperatures with very good accuracy. The results also suggest that at 298 K the mass accommodation coefficient of succinic acid is unity or very close to unity.     

Evidence of high PM2.5 strong acidity in ammonia-rich atmosphere of Guangzhou,China: Transition in pathways of ambient ammonia to form aerosol ammonium at [NH4+]/[SO42–] = 1.5

In this study, 24-h PM_2.5 samples were collected using Harvard Honeycomb denuder/filter-pack system during different seasons in 2006 and 2007 at an urban site in Guangzhou, China. The particles collected in this study were generally acidic (average strong acidity ([H⁺]) ~ 70 nmol m^? 3). Interestingly, aerosol sulfate was not fully neutralized in the ammonia-rich atmosphere (NH₃ ~ 30 ppb) and even when NH₄⁺]/[SO₄^2?] was larger than 2. Consequently, strong acidity ([H⁺]) as high as 170 nmol m^? 3 was observed in these samples. The kinetic rate of neutralization of acidity (acidic sulfate) by ambient ammonia was significantly higher than the rate of formation of ammonium nitrate involving HNO₃ and NH₃ for [NH₄⁺]/[SO₄^2?] ≤ 1.5 and much lower for NH₄⁺]/[SO₄^2?] > 1.5. Therefore, higher nitrate principally formed via homogeneous gas phase reactions involving ammonia and nitric acid were observed for [NH₄⁺]/[SO₄^2?] > 1.5. However, little nitrate, probably formed via heterogeneous processes e.g. reaction of HNO₃ with sea salt or crustal species, was observed for [NH₄⁺]/[SO₄^2?] ≤ 1.5. These demonstrate a clear transition in the pathways of ambient ammonia to form aerosol ammonium at [NH₄⁺]/[SO₄^2?] = 1.5 and evidently explain the observed high acidity due to the unneutralized sulfate in the ammonium-rich aerosol (NH₄⁺]/[SO₄^2?] > 1.5). In fact, the measured acidity was almost similar to the excess acid defined as the acid that remains at [NH₄⁺]/[SO₄^2?] = 1.5 due to the un-neutralized fraction of sulfate ([H⁺] = 0.5[SO₄^2?]). The presence of high excess acid and ammonium nitrate significantly lowered the deliquescence relative humidity of ammonium sulfate (from 80% to 40%) in the ammonium-rich samples.     

Nitrate in groundwater of China: Sources and driving forces

Identifying the sources of reactive nitrogen (N) and quantifying their contributions to groundwater nitrate concentrations are critical to understanding the dynamics of groundwater nitrate contamination. Here we assessed groundwater nitrate contamination in China using literature analysis and N balance calculation in coupled human and natural systems. The source appointment via N balance was well validated by field data via literature analysis. Nitrate was detected in 96% of groundwater samples based on a common detection threshold of 0.2 mg N L^?1, and 28% of groundwater samples exceeded WHO's maximum contaminant level (10 mg N L^?1). Groundwater nitrate concentrations were the highest beneath industrial land (median: 34.6 mg N L^?1), followed by urban land (10.2 mg N L^?1), cropland (4.8 mg N L^?1), and rural human settlement (4.0 mg N L^?1), with the lowest found beneath natural land (0.8 mg N L^?1). During the period 1980–2008, total reactive N leakage to groundwater increased about 1.5 times, from 2.0 to 5.0 Tg N year^?1, in China. Despite that the contribution of cropland to the total amount of reactive N leakage to groundwater was reduced from 50 to 40% during the past three decades, cropland still was the single largest source, while the contribution from landfill rapidly increased from 10 to 34%. High reactive N leakage mainly occurred in relatively developed agricultural or urbanized regions with a large population. The amount of reactive N leakage to groundwater was mainly driven by anthropogenic factors (population, gross domestic product, urbanization rate and land use type). We constructed a high resolution map of reactive N source appointment and this could be the basis for future modeling of groundwater nitrate dynamics and for policy development on mitigation of groundwater contamination.     

Influence of regional pollution and sandstorms on the chemical composition of cloud/fog at the summit of Mt. Taishan in northern China

Cloud/fog samples were collected during spring of 2007 in the highly polluted North China Plain in order to examine the impact of pollution and dust particles on cloud water chemistry. The volume weighted mean pH of cloud water was 3.68. The cloud acidity was shown to be associated with air mass origins. Cloud water with its air mass trajectories originating from the southern part of China was more acidic than those from northern China. Anthropogenic source and dust had obvious impact on cloud water composition as indicated by the very high mean concentrations of SO₄^2? (1331.65 μeq L^? 1), NO₃^? (772.44 μeq L^? 1), NH₄⁺ (1375.92 μeq L^? 1) and Ca²⁺ (625.81 μeq L^? 1) in the observation periods. During sandstorm days, cloud pH values were relatively high, and the concentrations of all the ions in cloud water reached unusual high levels. Significant decreases in the mass concentrations of PM_2.5 and PM₁₀ were observed during cloud events. The average scavenging ratio for PM_2.5 and PM₁₀ was 52.0% and 55.7%, respectively. Among the soluble ions in fine particles, NO₃^?, K⁺ and NH₄⁺ tend to be more easily scavenged than Ca²⁺ and Na⁺.     

An operational MODIS aerosol retrieval algorithm at high spatial resolution,and its application over a complex urban region

Aerosol retrieval algorithms for the MODerate Resolution Imaging Spectroradiometer (MODIS) have been developed to estimate aerosol and microphysical properties of the atmosphere, which help to address aerosol climatic issues at global scale. However, higher spatial resolution aerosol products for urban areas have not been well-researched mainly due to the difficulty of differentiating aerosols from bright surfaces in urban areas. Here, an aerosol retrieval algorithm using the MODIS 500-m resolution bands is described, to retrieve aerosol properties over Hong Kong and the Pearl River Delta region. The rationale of our technique is to first estimate the aerosol reflectances by decomposing the top-of-atmosphere reflectances from surface reflectances and Rayleigh path reflectances. For the determination of surface reflectances, a Minimum Reflectance Technique (MRT) is used, and MRT images are computed for different seasons. For conversion of aerosol reflectance to aerosol optical thickness (AOT), comprehensive Look Up Tables specific to the local region are constructed, which consider aerosol properties and sun-viewing geometry in the radiative transfer calculations. Four local aerosol types, namely coastal urban, polluted urban, dust, and heavy pollution, were derived using cluster analysis on 3 years of AERONET measurements in Hong Kong. The resulting 500 m AOT images were found to be highly correlated with ground measurements from the AERONET (r² = 0.767) and Microtops II sunphotometers (r² = 0.760) in Hong Kong. This study further demonstrates the application of the fine resolution AOT images for monitoring inter-urban and intra-urban aerosol distributions and the influence of trans-boundary flows. These applications include characterization of spatial patterns of AOT within the city, and detection of regional biomass burning sources.     

Vortex Rossby waves on smooth circular vortices: Part I. Theory

A complete theory of the linear initial-value problem for Rossby waves on a class of smooth circular vortices in both f-plane and polar-region geometries is presented in the limit of small and large Rossby deformation radius. Although restricted to the interior region of barotropically stable circular vortices possessing a single extrema in tangential wind, the theory covers all azimuthal wavenumbers. The non-dimensional evolution equation for perturbation potential vorticity is shown to depend on only one parameter, G, involving the azimuthal wavenumber, the basic state radial potential vorticity gradient, the interior deformation radius, and the interior Rossby number.In Hankel transform space the problem admits a Schrödinger’s equation formulation which permits a qualitative and quantitative discussion of the interaction between vortex Rossby wave disturbances and the mean vortex. New conservation laws are developed which give exact time-evolving bounds for disturbance kinetic energy. Using results from the theory of Lie groups a nontrivial separation of variables can be achieved to obtain an exact solution for asymmetric balanced disturbances covering a wide range of geophysical vortex applications including tropical cyclone, polar vortex, and cyclone/anticyclone interiors in barotropic dynamics. The expansion for square summable potential vorticity comprises a discrete basis of radially propagating sheared vortex Rossby wave packets with nontrivial transient behavior. The solution representation is new, and for this class of swirling flows gives deeper physical insight into the dynamics of perturbed vortex interiors than the more traditional approach of Laplace transform or continuous-spectrum normal-mode representations. In general, initial disturbances are shown to excite two regions of wave activity. At the extrema of these barotropically stable vortices and for a certain range of wavenumbers, the Rossby wave dynamics are shown to become nonlinear for all initial conditions. Extensions of the theory are proposed.     

Characterization of water-soluble inorganic ions in size-segregated aerosols in coastal city,Xiamen

The samples of water-soluble inorganic ions (WSIs), including anions (F^?, Cl^?, SO₄^2?, NO₃^?) and cations (NH₄⁺, K⁺, Na⁺, Ca²⁺, Mg²⁺) in 8 size-segregated particle matter (PM), were collected using a sampler (with 8 nominal cut-sizes ranged from 0.43 to 9.0 μm) from October 2008 to September 2009 at five sites in both polluted and background regions of a coastal city, Xiamen. The results showed that particulate matters in the fine mode (PM_2.1, Dp < 2.1 μm) comprised large part of mass concentrations of aerosols, which accounted for 45.56–51.27%, 40.04–60.81%, 42.02–60.81%, and 40.46–57.07% of the total particulate mass in spring, summer, autumn, and winter, respectively. The water-soluble ionic species in the fine mode at five sampling sites varied from 15.33 to 33.82 (spring), 14.03 to 28.06 (summer), 33.47 to 72.52 (autumn), and 48.39 to 69.75 μg m^? 3 (winter), respectively, which accounted for 57.30 ± 6.51% of the PM_2.1 mass concentrations. Secondary pollutants of NH₄⁺, SO₄^2? and NO₃^? were the dominant contributors of WSIs, which suggested that pollutants from anthropogenic activities, such as SO₂, NOx were formed in aerosols by photochemical reactions. The size distributions of Na⁺, Cl^?, SO₄^2? and NO₃^? were bimodal, peaking at 0.43–0.65 μm and 3.3–5.8 μm. Although some ions, such as NH₄⁺ presented bimodal distributions, the coarse mode was insignificant compared to the fine mode. Ca²⁺ and Mg²⁺ exhibited unimodal distributions at all sampling sites, peaking at 2.1–3.3 μm, while K⁺ having a bimodal distributions with a major peak at 0.43–0.65 μm and a minor one at 3.3–4.7 μm, were used in most of samples. Seasonal and spatial variations in the size-distribution profiles suggested that meteorological conditions (seasonal patterns) and sampling locations (geographical patterns) were the main factors determining the formation of secondary aerosols and characteristics of size distributions for WSIs.     

Kinematic metrics of the Loop Current in the Gulf of Mexico from satellite altimetry

We analyzed a 20-year time series (January 1st, 1993 through December 31st, 2012) of Loop Current (LC) surface area derived from satellite altimetry in the eastern Gulf of Mexico to estimate kinematical metrics of this potent flow. On average the LC intrudes to its maximum northward position about 216 ± 126 days after the previous eddy separation; and ∼30 ± 31 days later sheds a large anticyclonic eddy. When the northern extent of the LC intrusion following the previous eddy separation is greater than 27°N, the current retreats very quickly until it sheds another eddy with the entire separation process occurring on the order of 30 days. To first order the change in areal extent of the LC during intrusion into the Gulf occurs at an average rate of 225 km² day⁻¹, which corresponds to an intrusion velocity of 1.7 cm s⁻¹ of the LC front, and adds Caribbean water to the Gulf at a rate of 2.6 ± 0.7 Sv.     

Distribution of inorganic nitrogen-containing species in atmospheric particles from an island in the Yellow Sea

In this study, total suspended particles (TSP) and size-segregated atmospheric aerosol samples were measured on Qianliyan Island in the Yellow Sea in spring (April–May), summer (July–August) and fall (October–November) of 2006 and in water (January–February) of 2007. The mass concentration of the TSP varied from 75.6 to 132.0 μg/m³. The average concentration were 9.37 ± 7.56 μg/m³ and 5.32 ± 4.25 μg/m³ for nitrate and ammonium in the TSP, respectively. TSP concentration showed a significant correlation with those of nitrate (n = 27, r = 0.73) and ammonium (n = 27, r = 0.60). The mass-size distribution of atmospheric particles exhibited two modes with an accumulation mode at 0.43–1.1 μm and a coarse mode at 3.3–4.7 μm throughout the sampling months. A bi-modal size distribution of nitrate in concentration occurred in the April–May, October–November and January–February, but a uni-modal size distribution occurred in the August. The uni-modal size distribution of ammonium at 0.43–0.65 μm was observed throughout the sampling months. The average of inorganic nitrogen in mass concentration accounted for 4.0% of the total mass of aerosol particles while ammonium-N was the dominant fraction of TIN (Total Inorganic Nitrogen), contributing to 62–71% of the TIN.     

Climate change impacts on ecosystems and the terrestrial carbon sink: a new assessment

Climate output from the UK Hadley Centre's HadCM2 and HadCM3 experiments for the period 1860 to 2100, with IS92a greenhouse gas forcing, together with predicted patterns of N deposition and increasing CO₂, were input (offline) to the dynamic vegetation model, Hybrid v4.1 (Friend et al., 1997; Friend and White, 1999). This model represents biogeochemical, biophysical and biogeographical processes, coupling the carbon, nitrogen and water cycles on a sub-daily timestep, simulating potential vegetation and transient changes in annual growth and competition between eight generalized plant types in response to climate.Global vegetation carbon was predicted to rise from about 600 to 800 PgC (or to 650 PgC for HadCM3) while the soil carbon pool of about 1100 PgC decreased by about 8%. By the 2080s, climate change caused a partial loss of Amazonian rainforest, C₄ grasslands and temperate forest in areas of southern Europe and eastern USA, but an expansion in the boreal forest area. These changes were accompanied by a decrease in net primary productivity (NPP) of vegetation in many tropical areas, southern Europe and eastern USA (in response to warming and a decrease in rainfall), but an increase in NPP of boreal forests. Global NPP increased from 45 to 50 PgC y⁻¹ in the 1990s to about 65 PgC y⁻¹ in the 2080s (about 58 PgC y⁻¹ for HadCM3). Global net ecosystem productivity (NEP) increased from about 1.3 PgC y⁻¹ in the 1990s to about 3.6 PgC y⁻¹ in the 2030s and then declined to zero by 2100 owing to a loss of carbon from declining forests in the tropics and at warm temperate latitudes — despite strengthening of the carbon sink at northern high latitudes. HadCM3 gave a more erratic temporal evolution of NEP than HadCM2, with a dramatic collapse in NEP in the 2050s.     

Intraurban variability of PM10 and PM2.5 in an Eastern Mediterranean city

The results of the first large scale chemical characterization of PM10 and PM2.5 at three different sites in the urban city of Beirut, Lebanon, are presented. Between May 2009 and April 2010 a total of 304 PM10 and PM2.5 samples were collected by sampling every sixth day at three different sites in Beirut. Observed mass concentrations varied between 19.7 and 521.2 μg m^? 3 for PM10 and between 8.4 and 72.2 μg m^? 3 for PM2.5, respectively. Inorganic concentrations accounted for 29.7–35.6 μg m^? 3 and 46.0–53.5 μg m^? 3 of the total mass of PM10 and PM2.5, respectively. Intra-city temporal and spatial variations were assessed based on the study of three factors: correlation coefficients (R) for PM and chemical components, coefficient of divergence (CODs), and source apportionment using positive matrix factorization (PMF). Based on R and COD of PM concentrations, the three sites appear homogeneous. However, when individual elements were compared, heterogeneity among sites was found. This latter was attributed to the variability in the percent contribution of biogenic and local anthropogenic source factors such as traffic related sources and dust resuspension. Other factors included the proximity to the Mediterranean sea, the population density and the topographical structure of the city. Hence, despite its small size (20.8 km²), one PM monitoring site does not reflect an accurate PM level in Beirut.     

Influence of drizzle on Z–M relationships in warm clouds

This paper addresses the sensitivity of the relationships between radar reflectivity (Z) and liquid water content (M) for liquid water clouds to microphysical drizzle parameters by means of simulated radar observation at a frequency of 3 GHz of modeled cumulus clouds. A power law relationship for non drizzling clouds with water content as high as 3 gm^− 3: Z_c = 0.026 M_c^1.61 is numerically derived and agreed with previous empirical relationships relative to cumulus and stratocumulus. This relationship is then used to explore the influence of drizzle on the correlation between radar reflectively and water content. Due to their large diameters with respect to cloud droplets, drizzle sized drops dominate radar reflectivity but do not carry the cloud water content so that reflectivity and liquid water content are expected to be not correlated in clouds containing drizzle. It is shown that for congestus or extreme congestus cumuli, microphysical conditions for which the Z_c–M_c relationship can be used with a tolerance of 5 and 10% are provided whereas for humilis or mediocris cumuli, the presence of drizzle breaks down the Z_c–M_c relationship whatever the situations.     

A review of ground-based,mobile, W-band Doppler-radar observations of tornadoes and dust devils

A ground-based, mobile, W-band Doppler-radar has been used in the U.S. during the last decade to obtain high-spatial resolution maps of the radar reflectivity and wind fields in tornadoes and dust devils. This radar is one of the best tools available for studying the substructure of intense, small-scale vortices in the boundary layer. The most significant findings to date are summarized.In one case, it was found that just prior to tornadogenesis in a supercell, a 100–200 m scale cyclonic vortex formed at the leading edge of a bulge in the rear–flank gust front. This vortex appeared to interact with a larger-scale (500 m to 1 km wide) cyclonic vortex, just as the tornado formed. Other small-scale cyclonic vortices were present along the rear–flank gust, but they did not develop into tornadoes. The mature tornado-vortex was dominated by quasi-stationary wavenumber-two disturbances, while the mean vortex resembled a two-celled, Rankine combined vortex. The diameter of the mean vortex narrowed as it intensified and widened as it weakened, even though the tornado condensation funnel narrowed as the tornado was dissipating. Evidence was also found of short-term, inertial-like oscillations in vortex diameter and intensity. Spiral bands and eyes were ubiquitous. The eye in one well-documented case was broader in the lowest few hundred meters than it was aloft. Multiple vortices and “umbilical” cords of very narrow bands of reflectivity have also been found.Both cyclonic and anticyclonic dust devils have been documented. Some dust devils resemble a relatively narrow, Rankine combined vortex, while others are wider and have a broad, calm eye and a narrow annulus of intense vorticity just within the radius of maximum wind (RMW), and rising motion just inside the RMW and sinking motion well inside the RMW. Multiple-vortex structure, Rossby-like wave motion, and the Fujiwhara effect have also been documented.