Heavy metal contamination and ecological risk in Spartina alterniflora marsh in intertidal sediments of Bohai Bay,China

To investigate the effects of Spartina alterniflora on heavy metals pollution of intertidal sediments, sediment cores of a S. alterniflora salt marsh and a mudflat in Bohai Bay, China were analyzed. The results showed that S. alterniflora caused higher total C and P, but lower bulk density and electrical conductivity. The levels of Cd, Cu and Pb were higher in S. alterniflora sediment. Both Cd and Zn were higher than the probable effect level at both sites, indicating their toxicological importance. The geo-accumulation and potential ecological risk indexes revealed higher metal contamination in S. alterniflora sediment. Multivariate analysis implied that anthropogenic activities altered mobility and bioavailability of heavy metals. The percentage of mobile heavy metals was higher in S. alterniflora sediment, indicating improvement of conversion from the immobilized fraction to the mobilized fraction. These findings indicate that S. alterniflora may facilitate accumulation of heavy metals and increase their bioavailability and mobility.     

Heavy metals in surface sediments from nine estuaries along the coast of Bohai Bay,Northern China

Concentrations of heavy metals in river water and sediment were investigated in nine estuaries along the coast of Bohai Bay, Northern China. Multivariate statistical techniques such as principal component analysis and cluster analysis, in combination with metal concentration analysis and correlation analysis, were used to identify the possible sources of the metals and the pollution pattern in nine estuaries along the coast of Bohai Bay. The environmental risks of metals, evaluated by sediment quality guidelines and background values, revealed Hg contamination in the estuaries. However, levels of Cd in estuarine sediments were low, and they were less than those levels in river sediments, partly due to the high mobility and dilution of river or seawater. Cd did not contribute to sediment deposits in estuaries. High organic matter from effluents from large municipal sewage treatment plants was predominantly responsible for restricting Hg mobility from the river to Bohai Bay.     

最小二乘逆时偏移中黏弹性和各向异性的校正:以渤海湾地区地震数据为例

地下介质中存在黏弹性和各向异性,在应用最小二乘逆时偏移时,如果没有对黏弹性和各向异性的影响进行校正,在观测数据和模拟数据的匹配过程中就会发生错误,最终使得最小二乘逆时偏移无法得到准确的成像结果.因此,本论文首先对最小二乘逆时偏移的黏弹性和各向异性进行分别校正,然后对两种影响进行同时校正.在实际资料试算部分,通过对渤海湾数据进行测试,分别采用常规声波最小二乘逆时偏移、补偿黏弹性的最小二乘逆时偏移、校正各向异性的最小二乘逆时偏移及同时校正两种性质的最小二乘逆时偏移进行比较测试,证明了在同时校正了黏弹性和各向异性影响之后,最小二乘逆时偏移得到了更高质量的成像结果,具体表现在低频噪音压制、震源效应压制、深部能量改善、分辨率提升、目的层刻画等方面都明显优于其他三种最小二乘逆时偏移的成像结果,同时也证明了同时校正黏弹性和各向异性最小二乘逆时偏移方法的正确性及在实际资料处理中的适用性.

     

Total petroleum hydrocarbons and heavy metals in the surface sediments of Bohai Bay,China: Long-term variations in pollution status and adverse biological risk

Surface sediments collected from 2001 to 2011 were analyzed for total petroleum hydrocarbons (TPH) and five heavy metals. The sediment concentration ranges of TPH, Zn, Cu, Pb, Cd and Hg were 6.3–535 μg/g, 58–332 μg/g, 7.2–63 μg/g, 4.3–138 μg/g, 0–0.98 μg/g, and 0.10–0.68 μg/g, respectively. These results met the highest marine sediment quality standards in China, indicating that the sediment was fairly clean. However, based on the effects range-median (ERM) quotient method, the calculated values for all of the sampling sites were higher than 0.10, suggesting that there was a potential adverse biological risk in Bohai Bay. According to the calculated results, the biological risk decreased from 2001 to 2007 and increased afterwards. High-risk sites were mainly distributed along the coast. This study suggests that anthropogenic influences might be responsible for the potential risk of adverse biological effects from TPH and heavy metals in Bohai Bay.     

A detailed receiver function image of the sedimentary structure in the Bohai Bay Basin

If the site at which receiver functions are constructed is filled by sediments, then the waveforms from these receiver functions are dominantly controlled by the sedimentary structures within the first few seconds after the direct P arrival. Based on this observation, waveform data collected at 44 temporary seismic stations have been used to image the sedimentary structure of the Bohai Bay Basin, a major continental petroliferous basin in Eastern China. An adapted hybrid global waveform inversion method was applied to the receiver functions to extract structural information beneath each of the stations. The derived S-velocity structure provides for the first time, a basin-scale seismic image of detailed sedimentary stratification. The sedimentary cover of the basin is about 2-12 km thick, consisting of Cenozoic, Mesozoic, and Paleozoic strata from top to bottom. The structural features presented in the S-velocity image coincide quite well with the depression-uplift type of tectonic system in the Bohai Bay Basin. The reconstructed morphology of the sedimentary layers provides seismological evidence for the two-stage evolution of the intracontinental basin that were caused by an intensive tectonic regime transition in late Mesozoic immediately following the lithospheric reforming of the Eastern China continent.     

华北渤海湾盆地大震的构造特征

渤海湾盆地是地震活动强烈的地区，记载有7级以上大地震6次。前人对几次大震的具体构造条件已做过大量研究。笔者基于已有的工作，通过对盆地构造发育早第三纪断陷和晚第三纪以来拗陷两个阶段的不同构造后性和区域地震构造格局的分析，以及大震区构造的剖析，综合研究了大震的构造特征。其中最根本的是，盆地发育的断陷阶段因北西—南东向水平拉张作用，于地壳上部形成了由北北东—北东向太行山山前断裂带等大型拆离断裂拉张滑脱控制的伸展断裂系统；拗陷阶段受北东东—南西西向水平挤压，正发育着一套地壳共轭剪切破裂系统。前者与地震关系不大，后者对地震孕育和发生有着重要的控制作用。     

Distribution of heavy metals in water and sediment of an urban river in a developing country: A probabilistic risk assessment

River water and sediment embody environmental characteristics that give valuable eco-environmental information.Due to rapid industrialization,the aquatic environment of any urban river can be seriously polluted by heavy metals（HMs）.The global concern is caused by heavy metal pollution because of its potential harm to aquatic ecosystems and human health.In the Bhairab River,Bangladesh,surface sediment concentrations of globally alarming toxic metals such as arsenic（As）,chromium（Cr）,cadmium（Cd）,an...     

Seismic tomography of the crust and upper mantle in the Bohai Bay Basin and its adjacent regions

In the Bohai Bay Basin and its adjacent regions(112°―124°E,34°―42°N),there exists abundant gas-petroleum while modern inter-plate seismic activity is robust.Although the tectonic structure of this region is very complicated,plenty of geological,geophysical and geochemical data and results are obtained through previous researches.On the basis of absorbing previous results,especially various kinds of geological and geophysical results,we collect and process the arrival time of P-wave phases of local events and tele-seismic events recorded by the station within this region from 1978 to 2004,build the responding initial model,and image the velocity structure of the crust and upper mantle of this region via tomography.The perturbation images of various depths and velocity profiles imply that the velocity structure of the crust and upper mantle in the Bohai Bay Basin and its adjacent regions is mainly influenced by the surface tectonic units,and is characterized by "Stripped along east-west,and zoned along south-north";some large-scaled faults penetrate Moho and lithosphere,and provide the channels for the basic lava or hot mass upwelling from the mantle.     

The response of benthic macrofauna to anthropogenic stress in Narragansett Bay, Rhode Island: a review of human stressors and assessment of community conditions

The present state of knowledge regarding the input of anthropogenic pollutants into Narragansett Bay, Rhode Island was reviewed and benthic infaunal communities present at four depositional environments within the upper Bay were characterized. Inter-station differences in species composition and abundance of these assemblages were examined in relation to established pollution gradients.Using diversity curves and multivariate statistics, evidence of significant anthropogenic impact on the structure of benthic macrofaunal communities in Narragansett Bay was identified. The magnitude of this impact was greatest at stations closest to the Bay’s urban centers, where exposure to multiple stressors had resulted in communities of opportunistic taxa which persisted in a state of low faunal diversity characteristic of early stages of species succession. As was expected based on historic models of faunal succession; the apparent maturity of benthic assemblages in Narragansett Bay increased along the north-south gradient of decreasing anthropogenic stress.     

渤海湾盆地北西盆山边界地区泊松比分布

泊松比做为了解地球内部介质一个非常重要的参数,在地震学上可以通过P波和S波速度的比值来确定.利用远震P波波形记录中包含的壳-幔速度间断面的Ps转换波及其多次反射/转换波信息,采用在地壳厚度－波速比平面上对接收函数转换波能量的叠加搜索方法,可以测定台站下方区域内地壳的平均厚度和泊松比.我们对渤海湾盆地北西盆山边界地区68个宽频带台站近两年的远震记录资料进行了处理研究,得到了该区域的地壳厚度以及泊松比分布.结果表明,渤海湾盆地北西盆山边界的泊松比值分布横向变化复杂, 山区侧与盆地侧存在明显差异;山区侧泊松比值分布相对均匀,盆地侧变化剧烈,但存在小区域范围内(100～200km)的一致性,与地表出露岩石的对比表明:形成渤海湾盆地的新生代伸展作用在下地壳深度有明显的响应,从地震学上获得的泊松比分布对于了解该地区地壳物质组成可起到很好的约束作用.     

渤海湾地区前第三系构造样式分布特征研究

通过渤海湾盆地内黄骅坳陷等潜山地震剖面的精细解释,结合周缘隆起区露头区野外构造考察,对渤海湾地区前第三系主要发育的拉张构造、挤压构造、走滑构造、负反转构造、重力滑动构造等5种进行了研究,这些构造在南北向上大致以沧东断裂、北西西向上大致以张家口-蓬莱断裂和齐河-广饶断裂为界分为六个区,不同区之间的构造线走向及构造样式组合存在较大差异.渤海湾地区前第三系的这种构造样式分布格局可能是印支期华北板块与北部的西伯利亚板块、南部的扬子板块先后闭合碰撞以及燕山中、晚期滨太平洋构造域影响作用不断增强和深部岩石圈的大规模减薄作用的结果.     

Assessing metal toxicity in sediments using the equilibrium partitioning model and empirical sediment quality guidelines: A case study in the nearshore zone of the Bohai Sea,China

Surface sediments were collected from five nearshore (wastewater discharges, aquaculture facilities and a seaport) sites in Bohai Bay and Laizhou Bay, China. The equilibrium partitioning (EqP) model and empirical sediment quality guidelines (SQGs) were applied to assess the potential metal toxicity in the collected sediments. The results show that, based on the EqP model, 35% of stations exhibited potential metal toxicity. Several metals (Cu, Ni and Cr) exceeded the empirical SQGs (9–93% of the time), however these guidelines may not be suitable for use in the Bohai Sea owing to the background concentrations. The EqP model is a more useful method for assessing potential metal toxicity in Bohai Sea sediment than the empirical SQGs. Additionally, we have provided new understanding about methods for assessing sediment metal toxicity in the Bohai Sea that may be useful in other coastal areas in China.     

Temporal and spatial trends of total petroleum hydrocarbons in the seawater of Bohai Bay, China from 1996 to 2005

The temporal and spatial distribution of total petroleum hydrocarbons (TPH) in the seawater of Tianjin Bohai Bay during 1996-2005 was investigated for the first time. TPH concentrations in 480 seawater samples collected from 16 stations during a 10-year span were quantified by ultra-violet fluorescence spectroscopy. Petroleum hydrocarbons were ubiquitous in the seawater, and their concentrations were highly variable, ranging from 23.7 to 508 μg L⁻¹. TPH concentrations in the seawater varied with seasons, showing a decreasing order of winter > spring > summer. Over the 10-year period, TPH at all stations steadily decreased. The highest values obtained were at stations near the port areas and Dagu outfall where shipping activities and land-based waste water discharges were the major sources of pollution. Our results provided the background information on the extent of TPH contamination in the seawater and highlighted the need to further control TPH pollution in Tianjin Bohai Bay.     

Metal concentrations, fluxes, inventories and chronologies in sediments from Sepetiba and Ribeira Bays: A comparative study

Three sediment cores were sampled at Sepetiba Bay and four cores at Ribeira Bay, Rio de Janeiro State, Brazil. Sediment accumulation rates and chronologies were obtained from ²¹⁰Pb activity-depth profiles. Sediment accumulation rates in Ribera Bay ranged from 1.2 mm y⁻¹ in the inner bay to 2.6 mm y⁻¹ close to its entrance. In Sepetiba Bay two sediment accumulation rates were observed: a lower rate of 0.35 cm y⁻¹ before the 1960s and 0.76 cm y⁻¹ since then. The cause of this change is due to the construction of the Santa Cecília impoundment (1955) that brings water from the Paraíba do Sul Basin into the Guandu River, which increased its flow from the original 20 m³ s⁻¹ to 160 m³ s⁻¹. Concentration of 44 elements was obtained by ICP-MS after total dissolution of samples from two selected cores. The relative differences between the concentrations of crustal elements, such as Al, Fe and Ti are only about 20% (p < 0.05). Cd and Zn are 15 and four times larger in Sepetiba Bay than in Ribeira Bay, respectively. Other major and minor elements show lower statistically significant differences. The enrichment factors and metal inventories show that Sepetiba Bay can be considered polluted with Bi, Cd, Cr, Cu, Sb and Zn. Particularly, Cd and Zn present concentrations three and four times higher than the Brazilian existing limits.     

渤海湾盆地冀中坳陷现今地热特征

渤海湾盆地冀中坳陷是我国最典型的潜山油气藏富集区.本文借助117口钻井地层测温资料和45块实测岩石热导率数据系统研究了冀中坳陷现今地温梯度、大地热流、热岩石圈厚度、岩石圈热结构等地热特征参数.研究表明,冀中坳陷0~3000 m统一深度现今地温梯度为20.8~41.0℃·km-1,平均值为31.6℃·km-1,比未校正值减小1~3℃·km-1;现今大地热流介于48.7~79.7 mW·m-2,平均值为59.2 mW·m-2.平面上,冀中坳陷现今地温梯度和热流由西向东(从盆地边缘向内部)逐渐增大,并且凸起区地温梯度和热流相对较高,而凹陷区则偏低,与基底地形起伏具有很好的对应关系.同时,冀中坳陷腹部高热流凸起区广泛分布地热田.冀中坳陷现今热岩石圈厚度为98~109 km,其岩石圈热结构为一典型的"冷壳热幔"型.本研究不仅对冀中坳陷油气勘探与地热能开发具有重要的指导意义,而且为深部岩石圈研究(华北克拉通破坏科学问题)提供了新依据.     

A review of ecological risk assessment and associated health risks with heavy metals in sediment from India

Heavy metal (HM) pollution in sediment is a serious concern particularly in developing nations, warranting an extensive survey to understand the current situation and propose possible remedial measures. This paper compiles the data of HMs cadmium (Cd), iron (Fe), cobalt (Co), manganese (Mn), arsenic (As), lead (Pb), chromium (Cr), copper (Cu), zinc (Zn) and nickel (Ni) in aquatic sediment from India from 1979 to 2017. It was found that mean values of Cu, Co, Zn, Pb, As, and Cr in Indian sediment were high in comparison to the Australian Interim Sediment Quality Guidelines, World Surface Rock Average, and the Threshold Effect Level for freshwater ecosystems. Anthropogenic activities, lithogenic factors, and sand intrusion are the main factors associated with HM pollution as observed using cluster analysis and principal component analysis. The results of contamination indices indicate that HM contamination ranged from average to high, in the sediment. The ecological risk assessment results showed that 11% HMs present very high risk. The cancer risk, due to the high contents of Cd, As, and Cr the ingestion pathway, showed high risk of cancer through food/water contaminated with sediment. At source reduction of HMs in industrial effluents by effluent treatment plants, and plantation of phytoremediating rooted macrophytes in sediment may help in HM mitigation of the sediment.     

Spatial distribution,fractionation and ecological risk assessment of potentially toxic metals in bottom sediments of the Zarivar freshwater Lake (Northwestern Iran)

Freshwater lakes are one of the most vulnerable ecosystems to environmental contamination. This study was initiated to assess the spatial distribution, fractionation, ecological risk of selected potentially toxic metals (Pb, Zn, Cu, Cr, and Ni) in bottom sediments of the Zarivar lake, the second largest freshwater lake in Iran. The results revealed that Pb, Zn and Cu had the high spatial variability (coefficient of variation >50) across the sampling sites and their maximum concentrations (197.5 for Pb, 198.7 for Zn and 185.6 mg/kg for Cu) were observed in sampling sites from the northern, western and eastern margins of the lake. Cr and Ni with average concentrations of 28.3 and 31.38 mg/kg respectively, exhibited low spatial variability (coefficient of variation <20) and their concentrations did not vary significantly among the sampling sites. Based on the redundancy analysis (RDA), sediment organic matter was strongly correlated with Pb, Zn and Cu while Fe₂O₃ and Al₂O₃ showed a positive correlation with Ni and Cr. The calculated average enrichment factor (EF) and geoaccumulation index (I_geo) showed that the contamination level of metals can be arranged in the following order of Pb> Cu > Zn > Cr > Ni. Results from the modified five-step sequential extraction analysis indicated that 40 % of total Pb and Zn were associated with the reducible fraction, 45 % of Cu with the oxidizable fraction and more than 80 % of total Ni and Cr were retrieved from the residual fraction. It was also noticed that Pb, Zn and Cu were more incorporated into the non-residual fractions in the sites with a higher total concentration of these metals, suggesting that both total concentration and fractionation behavior of metals were influenced by their potential sources in the study area. Ecological risk assessment using the potential ecological risk index (PERI) and the modified potential ecological risk index (MPERI) showed that sediments from the eight sampling sites pose a moderate to considerable risk whereas the other sites had low ecological risk level. In comparison to sediment quality guidelines (SQGs), the effects range low (ERL) and probable effect level (PEL) values for Pb, Cu and Zn were exceeded at some sampling sites while Ni and Cr concentrations were found to be below or close to their SQGs values at all the sampling sites. Pb was generally identified as the contaminant of most concern in the study area. Taking into account the results obtained from the fractionation study and the source contribution estimate, it can be inferred that the Pb, Zn and Cu with the average contribution of 79, 54 and 64 % respectively, were mainly derived from anthropogenic sources whereas Ni and Cr with the estimated contribution of 80 and 89 % were predominately from the lithogenic source.     

中国渤海湾盆地上地壳岩石成分模型(英文)

许多地震属性,比如地震的纵横波速度,泊松比,声波阻抗,都能用来区分不同的岩石类型,利用拉梅阻抗作为进一步的约束来代替声波阻抗能更好的降低结果的非唯一性。我们用这种方法构建了渤海湾地区一条剖面的岩石成分模型。我们简要介绍了区分岩石类型的地震参数,重点在于不同的参数组合对于分辨岩石类型的敏感性。为了与室温常压条件下测得的有代表性的岩石的地震波速度和密度进行对比,我们首先需要做温度和压力的校正。接着,我们需要用已知资料和实验测得的各种岩石样品做对比,来确定研究区的岩石类型。我们收集了渤中凹陷一条剖面的纵波速度资料。该剖面10km深范围内的属于同种岩石类型的不同岩石最终通过地震波速度、泊松比、密度、声波阻抗、以及拉梅阻抗综合约束。     

太湖不同生态类型湖区浮游甲壳动物群落结构季节变化比较

水体富营养化会对整个水生态系统产生重要影响.为了解太湖富营养化对浮游甲壳动物群落结构的影响,于2012年3月至2013年2月对太湖3个典型湖区——藻型湖区(梅梁湾)、草型湖区(胥口湾)和强扰动湖区(湖心区)开展浮游甲壳动物群落结构季节变化比较研究.3个湖区中,湖心区营养水平最高,胥口湾最低.梅梁湾浮游甲壳动物密度和生物量最高,其次是湖心区,胥口湾最低.梅梁湾、湖心区和胥口湾的浮游甲壳动物年平均密度分别为199、150和91 ind./L,年平均生物量分别为1.950、1.557和0.743 mg/L.在整个研究期间,梅梁湾、胥口湾和湖心区的浮游甲壳动物种类数分别为13、11和11;3个湖区的浮游甲壳动物优势种均为中华窄腹剑水蚤和简弧象鼻溞,其中中华窄腹剑水蚤在梅梁湾、胥口湾和湖心区的年平均密度分别为57、25和36 ind./L,简弧象鼻溞在3个湖区的年平均密度分别为40、22和32 ind./L.胥口湾浮游甲壳动物生物多样性指数显著低于梅梁湾和湖心区.相关分析表明,浮游甲壳动物密度与叶绿素a浓度呈极显著正相关.研究表明,同一湖泊不同生态类型湖区浮游甲壳动物会对水体富营养化产生不同的生态响应.     

Development of a benthic index to assess sediment quality in the Tampa Bay Estuary

The identification, remedial treatment, and monitoring of contaminated sediments are among the priorities for managers of the Tampa Bay Estuary. Tampa Bay, as an urbanized estuary, is subject to the input of watershed sources of chemical contaminants, including metals, pesticides, and organic chemicals. Although the use of biological indicators and their incorporation into multi-metric indices is not new, the refinement and applications of such techniques for determining environmental condition still require further development and exploration. We present a single Tampa Bay Benthic Index (TBBI) that was developed specifically for Tampa Bay. Stepwise discriminant analysis was applied to a comprehensive list of potential benthic metrics. Results from the stepwise procedure identified the metrics that best discriminated between "healthy" and "degraded" conditions, as defined by sediment contaminant effect levels and dissolved oxygen. Discriminant analysis was then applied to the resultant three variables to determine the linear combination for the index.