Sedimentary facies of the subaqueous Changjiang River delta since the late Pleistocene

The sedimentary facies of the subaqueous Changjiang(Yangtze) River delta since the late Pleistocene was studied based on lithology and foraminifera analysis for two boreholes,CJK07 and CJK11,along with14C dating.Four sedimentary facies were identified,namely fluvial,tidal flat,offshore,and prodelta facies.The fluvial sedimentary facies is comprised of fluvial channel lag deposits,fluvial point bar deposits,and floodplain deposits,showing a fining-upward sequence in general with no benthic foraminifera.A layer of stiff clay overlies the fluvial deposits in core CJK07,indicating a long-term exposure environment during the Last Glacial Maximum(LGM).During the postglacial sea-level rise around 13-7.5 cal ka BP,the tidal flat facies was deposited in core CJK11,characterized by abundant silt-clay couplets.Euryhaline species dominate the subtidal flat foraminiferal assemblages,while almost no foraminifera was found in the intertidal flat.The offshore environment was the major sedimentary environment when the sea level reached its highest level around 7.5 cal ka BP,with a maximum accumulation rate of 10 mm/a found in core CJK11.Prodelta sediments have been deposited in core CJK11 since ~3 cal ka BP,after the formation of the Changjiang River delta.The difference in sedimentary facies between core CJK07 and CJK11 is due to their location: core CJK07 was in an interfluve while core CJK11 was in an incised valley during the LGM.Furthermore,AMS14C dating of core CJK07 shows poor chronological order,indicating that the sediments were reworked by strong tidal currents and that sediment deposited since ~7.7 cal ka BP in core CJK07 was eroded away by modern hydrodynamic forces caused by the southward shift of the Changjiang River delta depocenter.     

辽河群孔达岩系原岩建造及沉积环境分析

辽宁省辽河群孔达岩系分在于营口－草河口复向斜南北两翼，主要由各类片岩、变粒岩、片麻岩夹斜长角闪岩、大理岩组成，为高绿片岩相和低角闪岩相，原岩属碳酸盐岩富碳的陆源碎屑－粘土沉积建造。孔达岩系中石墨稳定同位素研究表明，石墨与有机墨有关，可能来源于低等生物；沉积时期的古气候为温湿－亚热带，沉积物质来源于海底火山喷发和陆源碎屑，沉积环境为浅海微淡化水体，低能、强还原环境的泻湖相。     

Grain-size characteristics and climate variability in TMS5e sequence of Tumen section in southern Tengger Desert, northwestern China

The TMS5e sequence from the Tumen section,at the southern edge of Tengger Desert in the northwestern China,is synchronous with Marine Isotope Stage 5e(MIS5e).It consists of 16 layers of aeolian dune sands,11 layers of lacustrine loess-like facies,and 5 layers of lacustrine facies.The results of grain-size analysis shows that the palaeo-mobile dune sands,palaeo-fixed to semi-fixed dune sands and loess-like sandy loams are mainly composed of sands,ranging from 70% to 96%;their silt contents ranged from 4% to 20%,and their clay contents ranged from 1% to 5%;the climate under which the aeolian dune sands were deposited is similar to that under which modern mobile dune sands form,which is caused by the dominance of the cold,dry East Asian winter monsoon.In contrast,the lacustrine loess-like facies and lacustrine facies had a lower sand contents than those of the three aeolian dune sands,but have higher silt and clay contents,most of their sand content ranged from 30% to 60%,their silt contents ranged from 35% to 55%,and their clay contents ranged from 6% to 20%.The lacustrine loess-like facies and lacustrine facies formed under the influence of the warm,humid East Asian summer monsoon based on their similarity with modern sediments.The grain-size indicator Mz(mean grain diameter) and the SC/D value in the TMS5e sequence indicate climatic insta-bility at the southern edge of the Tengger Desert during MIS5e,with at least 14 fluctuations between a warm,humid climate and a cold,dry climate,divided into five stages:TMS5e5(139 kyr to 129.3 kyr B.P.),TMS5e4(129.3 kyr to 124 kyr B.P.),TMS5e3(124 kyr to 119.5 kyr B.P.),TMS5e2(119.5 kyr to 116.5 kyr B.P.),and TMS5e1(116.5 kyr to 113.7 kyr B.P.).These correspond roughly to MIS5e5,MIS5e4,MIS5e3,MIS5e2,and MIS5e1,respectively,in the GRIP ice core data.     

The Sources and Transport Patterns of Modern Sediments in Hangzhou Bay: Evidence from Clay Minerals

Clay mineral compositions of 199 offshore surface sediment samples collected from the Hangzhou Bay have been analyzed. The clay minerals in the sediments from the Hangzhou Bay are dominated by illite(58.7%, on average), followed by chlorite(20.3%), kaolinite(16.9%) and smectite(4.1%). Two provinces were classified by Q-mode cluster analysis. Class Ⅰ with relatively low amounts of illite and smectite is widely distributed in the Hangzhou Bay, especially concentrated in the top and mouth of the bay, and the northern and southern nearshore areas. Class Ⅱ with comparatively high amounts of illite and smectite is mainly concentrated in the central part of the bay with the water depth of 8–10 m. By comparing clay mineral compositions with the neighbouring regions, we can find that the sediments in the Hangzhou Bay are mainly influenced by the resuspension and repeated deposition of particles from the Yangtze River due to the strong dynamic environment. In particular, the clay fraction of Class Ⅰ is mainly supplied by the Yangtze River, while the sediments of Class Ⅱ are mixture of the clay minerals carried by the Yangtze River and Qiantang River. In general, the distributions of clay minerals in the northern bay are affected by Yangtze River runoff, coastal current and flood tide together, and in the southern they are mainly affected by the Qiantang River runoff and ebb tide.     

Statistical analysis of the material source and the modern sedimentary environment of the ferromanganese nodules enriched area of the North Pacific region

The source of elements and the modern sedimentary environment of the ferromanganese nodules enriched area of the North Pacific region were analysed statistically and discussed in detail. Cluster analysis shows the area's surface sediments are mainly brown clay and biogenic calcareous, calcsiliceous and siliceous ooze. Factor (principal component) analysis shows that the area's trace elements (Fe, Mn, Cu, Co, Ni, Zn, Cr, etc.) mainly come through adsorption of clay minerals and secondarily from authigenic sediments related to biochemical processes. Bao Gende, 1990. Characteristics of element geochemistry in sediments in the ferromanganese nodules enriched area of the North Pacific region.Acta Sedimentologica Sinica. (in press, in Chinese)     

沉积物中硬质粘土层的研究进展

大量的钻孔资料表明,平原地区及其海域沉积物中普遍有硬质粘土层的存在。硬质粘土层在工程地质、地理学研究等方面具有重要的价值,它不仅是高层建筑的持力层,而且是研究全球环境变化事件、古气候演变的良好载体。该文阐述了硬质粘土层的一般特征、成因以及在粒度、地球化学元素、年代学、沉积环境等方面的研究进展,并展望了硬质粘土层在年代、物质来源和沉积环境等方面的研究方向,认为黄河三角洲硬质粘土层研究较少,需要开展大范围的、系统深入的、多学科的宏观和微观综合分析,挖掘硬质粘土层蕴含的古环境意义和应用价值。     

ORIGIN OF CARBONATE MATERIALS IN THE NORTHERN BASIN OF LAKE BAIKAL AND ITS RELATIONSHIP TO HOLOCENE PALEOCLIMATE

Fine-grained disseminated carbonate was found in Holocene sediments in a core taken from the northern basin of Lake Baikal. The core had two distinct facies. a terrigenous blue-clay overlain by a diatomaceous silt. Oxygen and carbon stable isotope analyses, combined with SEM , X-ray diffraction and .palynology, show that the carbonate in the blue-clay layer is pedogenic in origin, rather than biogenic or authigenic . The S C values in the blue clay suggest that the carbonate is derived from a single source , while the carbonate in the diatom-rich layer might be transported by winds from different sources. On the assumption that the carbonate was formed during the post-glacial age and was transported primarily by river runoff, the 18O isotopic values suggest that the annual temperature in the northern Baikal drainage area was about 3℃ warmer during the middle Holocene (8500-7000 a, B. P.) than during the early Holocene (11 000-8 500a, B.P.) when the blue clay was being deposited . This interpretation is     

青藏高原东北缘尖扎盆地沉积物矿物特征及其古环境意义

应用X射线衍射对青藏髙原东北缘尖扎盆地加让剖面11.8~5.8 Ma的地层沉积物进行矿物分析,结果表明加让剖面沉积物矿物组分主要包括碎屑矿物、碳酸盐矿物和黏土矿物。其中,以碎屑矿物居多,主要是石英、斜长石、云母类矿物(白云母、黑云母),及少量尖晶石、辉石类矿物(普通辉石、锰钙辉石及顽火辉石等)、金红石、刚玉、磁铁矿、钛磁铁矿、榍石、霞石,偶见锆石、石榴子石、锐钛矿;碳酸盐矿物以方解石居为主,白云石占比较少;黏土矿物中,绿泥石占比最高,还有少量赤铁矿、蛭石和沸石。以全岩矿物指标研究为主,结合加让剖面沉积相演化特点,并以磁化率变化为参考,进行系统的矿物学研究,获得了尖扎盆地在11.8~5.8 Ma蕴含的古气候环境演化大致可分为4个阶段:11.8~10.0 Ma,气候干冷期;10.0~8.6 Ma,气候暖湿波动期;8.6~6.2 Ma,气候温暖湿润期;6.2~5.8 Ma,气候干冷期。在约10.0、8.6、7.2 Ma附近,主要矿物占比及组合特征有明显改变,当时的古环境状况发生急剧变化,可能揭示青藏高原东北缘在10~8 Ma期间广泛发生了一系列较强烈的构造运动,来源于周边山脉的剥蚀使得研究区沉积的近源物质增多,约7.2 Ma之后的古环境演化过程主要受青藏高原构造隆升以及全球气候变冷协同影响。     

高邮凹陷古近系戴南组扇三角洲沉积体系及其沉积相模式

扇三角洲是苏北盆地高邮凹陷戴南组较为发育的一种沉积类型,集中分布在凹陷南部陡坡带一侧,是该区一个重要的勘探领域。根据岩芯、测井、地震、粒度等资料,对高邮凹陷古近系戴南组扇三角洲的沉积特征进行了研究,建立了高邮凹陷戴南组的沉积相模式。根据单井沉积相、连井沉积相分析以及地震剖面反射特征和砂地比图综合分析,确定了戴南组各亚段沉积相的平面展布,编制了戴南组各亚段沉积相分布图。结果表明:高邮凹陷南部陡坡带地形陡,存在扇三角洲发育的条件,也存在反映浅水环境的岩性特点,成分成熟度和结构成熟度低反映了近物源的条件,还发现反映牵引流和重力流共存的沉积构造特点;从地震反射特征上看,反射结构不稳定,并发现向盆地边缘加厚的楔形地震相。在此基础上,重点对戴南组扇三角洲相各微相进行了分析,共划分出扇三角洲平原、扇三角洲前缘和前扇三角洲亚相,并进一步划分出水上分流河道、漫滩沼泽、水下分流河道、分流河道间和席状砂等微相,最后详细阐述了各微相的沉积特征。     

青州市马家庄地区黏土矿成矿地质特征研究

青州市马家庄地区黏土矿主要赋存于第四纪中-上更新统大站组及全新统临沂组,赋矿层系分布面积较广,整体自南向北微有倾斜,呈等轴状展布,其厚度与古地形密切相关,古地形凹陷处矿体厚度较大,隆起区则较小,平均厚度12.61 m,厚度变化系数27.79％.经差热分析可知,黏土矿石主要由蒙脱石+水云母+石英组成.属于陆相残—坡积混合...     

Sedimentary Characteristics of the Second Marine Layer During the Late Marine Isotope Stage 3 in Southern Yellow Sea and Their Response to the East Asian Monsoon

We use the particle size of sediments in core YS01 A to study the sedimentary environment of the mud deposit in the central South Yellow Sea of China during late Marine Isotope Stages 3(MIS3;40.5 kyr–31.3 kyr).In addition,the East Asian Monsoon and its relationship with the North Atlantic Ocean climate change are discussed based on the sensitive grain-size calculation and the spectrum analysis.The results show that during late MIS3,the muddy area in the central South Yellow Sea experienced the evolution of coastal facies,shallow marine facies,coastal facies,and continental facies,with weak hydrodynamic conditions.Compared with other climate indicators,we found that there were many century to millennium-scale climate signals documented in the muddy area sediments in the central South Yellow Sea.According to our particle size results,three strong winter monsoon events occurred at 37.6 kyr,35.6 kyr and 32.2 kyr.The East Asian Winter Monsoon records in core YS01 A are consistent with the Greenland ice core and the Hulu cave stalagmite δ~(18)O.The millennial and centennial scale cycles,which are 55 yr,72 yr,115 yr,262 yr respectively,correspond to solar activity cycles,while the 1049 yr and 2941 yr cycles correspond to the Dansgaard-Oeschger cycles.These cycles indicate that the paleoclimate evolution of the area was controlled by the solar activities,with the high-latitude driving thermohaline circulation as the main energy conveyor belt,followed by the sea-air-land amplification of the winter monsoon variation in the central Yellow Sea in the late MIS3.     

Properties and organic activation of ocean clay in the East Pacific

In order to make use of ocean clay reasonably and excavate its potential applications the properties of ocean clay in Chinese investigating area of the East Pacific have been tested with the chemical analysis, XRFS, ICP/MAS, granulometry and SSA, etc. The results show that the clay sediments of this area are rich in clay minerals, fine granularity, bigger SSA, bigger water absorbability and lower ion changing ability etc. To improve the adaptability of ocean clay and macromolecule materials, using the dry milling method with silane, aluminate, stearic acid coupling agents etc the properties of ocean clay are improved. The effect has been evaluated by testing the water absorbing of the modified ocean clay and their dispersing in paraffin liquid. The result is that KH550 is better than any other active reagents, and the best activation technics is that 1.5 % （volume） of KH550 quantity, 20min of milling time. The DTA, XRD, SEM and IR analyses and SSA testing show that the organic activation can not change the mineral structure but can densify the structure of clay, and activation mechanism is chemical covered mainly and chemical combined secondly.     

Properties and organic activation of ocean clay in the East Pacific

In order to make use of ocean clay reasonably and excavate its potential applications the properties of ocean clay in Chinese investigating area of the East Pacific have been tested with the chemical analysis, XRFS, ICP/MAS, granulometry and SSA, etc. The results show that the clay sediments of this area are rich in clay minerals, fine granularity, bigger SSA, bigger water absorbability and lower ion changing ability etc. To improve the adaptability of ocean clay and macromolecule materials, using the dry milling method with silane, aluminate, stearic acid coupling agents etc the properties of ocean clay are improved. The effect has been evaluated by testing the water absorbing of the modified ocean clay and their dispersing in paraffin liquid. The result is that KH550 is better than any other active reagents, and the best activation technics is that 1.5% (volume) of KH550 quantity, 20min of milling time. The DTA, XRD, SEM and IR analyses and SSA testing show that the organic activation can not change the mineral structure but can densify the structure of clay, and activation mechanism is chemical covered mainly and chemical combined secondly.     

微生物参与下高氟区沉积物中氟的迁移行为

氟是自然界广泛分布的非金属元素,也是人体必须的微量元素之一。环境微生物作为自然界中物质迁移的主动力之一,积极地参与着多种元素的水文生物地球化学循环。研究微生物参与下沉积物中氟的释出行为,对深入理解环境氟迁移行为具有重要意义。以山西运城高氟区沉积物样品为代表,采用野外沉积物调查采集、室内环境地球化学分析和微宇宙培养实验等研究手段,从环境生物地球化学作用的角度探讨了微生物介导下沉积物中氟的迁移释出行为。研究证明,高氟区沉积物总氟质量分数介于206.2~781.0 mg/kg之间,主要含氟矿物为长石、云母、方解石、绿泥石、角闪石等。培养条件下,溶液中的氟质量浓度与微生物生长曲线呈现良好的一致性;在培养初期,溶液中的氟质量浓度迅速上升,而后逐渐缓和,14 d后呈下降趋势。其中,黏土类沉积物的释氟量较大,砂土类沉积物释氟量较小。有、无碳源对照培养说明,沉积物中一定量的碳源可被微生物代谢利用,但碳源不是影响微生物在此环境中作用的主要因素。研究证明,原生微生物代谢活动可以显著促进沉积物中氟的迁移释出,微生物作用下不同岩性沉积物中氟的释出特征也有显著的差异,本研究工作有助于进一步丰富环境氟循环的理论认识。      

Shear Wave Speed Dispersion Characteristics of Seafloor Sediments in the Northern South China Sea

To accurately characterize the shear wave speed dispersion of seafloor sediments in the northern South China Sea,five types of sediments including silty clay,clayey silt,sandy silt,silty sand,and clayey sand were selected,on which the measurements of the shear wave speed at 0.5-2.0 kHz and related physical properties were performed.Results reveal that the shear wave speed of sediments increases as the frequency increases,and the dispersion enhanced in the sediments in the order of silty clay,clayey silt,sandy silt,silty sand,and clayey sand,at a linear change rate of 0.727,0.787,3.32,4.893,and 6.967 m s?1 kHz?1,respectively.Through regression analysis,linear and logarithmic regression equations for the correlation between shear wave speed and frequency were established for each sediment type and the determination coefficients of regression equations indicate that the correlation is closer to a logarithmic relationship.The Grain-Shearing(GS)and Biot-Stoll models were used to calculate the shear wave speed dispersion of the five sediment types,and the comparison between theoretical prediction and measured results of shear wave speeds shows that the GS model can more accurately describe the shear wave speed dispersion characteristics of these sediments in the frequency band of 0.5-2.0 kHz.In the same band,the predictions obtained by using the Biot-Stoll model are significantly different from the measured data.     

Sedimentary evolution of the Holocene subaqueous clinoform off the southern Shandong Peninsula in the Western South Yellow Sea

Based on the stratigraphic sequence formed since the last glaciation and revealed by 3000 km long high-resolution shallow seismic profiles and the core QDZ03 acquired recently off the southern Shandong Peninsula, we addressed the sedimentary characteristics of a Holocene subaqueous clinoform in this paper. Integrated analyses were made on the core QDZ03, including sedimentary facies, sediment grain sizes, clay minerals, geochemistry, micro paleontology, and AMS 14 C dating. The result indicates that there exists a Holocene subaqueous clinoform, whose bottom boundary generally lies at 15–40 m below the present sea level with its depth contours roughly parallel to the coast and getting deeper seawards. The maximum thickness of the clinoform is up to 22.5 m on the coast side, and the thickness contours generally spread in a banded way along the coastline and becomes thinner towards the sea. At the mouths of some bays along the coast, the clinoform stretches in the shape of a fan and its thickness is evidently larger than that of the surrounding sediments. This clinoform came into being in the early Holocene(about 11.2 cal kyr BP) and can be divided into the lower and upper depositional units(DU 2 and DU 1, respectively). The unit DU 2, being usually less than 3 m in thickness and formed under a low sedimentation rate, is located between the bottom boundary and the Holocene maximum flooding surface(MFS), and represents the sediment of a post-glacial transgressive systems tract; whereas the unit DU 1, the main body of the clinoform, sits on the MFS, belonging to the sediment of a highstand systems tract from middle Holocene(about 7–6 cal kyr BP) to the present. The provenance of the clinoform differs from that of the typical sediments of the Yellow River and can be considered as the results of the joint contribution from both the Yellow River and the proximal coastal sediments of the Shandong Peninsula, as evidenced by the sediment geochemistry of the core. As is controlled mainly by coactions of multiple factors such as the Holocene sea-level changes, sediment supplies and coastal dynamic conditions, the development of the clinoform is genetically related with the synchronous clinoform or subaqueous deltas around the northeastern Shandong Peninsula and in the northern South Yellow Sea in the spatial distribution and sediment provenance, as previously reported, with all of them being formed from the initial stage of the Holocene up to the present.     

Features of clay minerals in the YSDP102 core on the continental shelf of the southeast Yellow Sea

Ninety-eight clay mineral samples from the YSDP102 core were analyzed by x-ray diffractometer to study the four clay minerals: illite, chlorite, kaolinite and smectite. Twenty-eight samples had been analyzed on the laser particle-siz eanalyzer to reveal the particle features of the sediments. Distribution of the clay minerals and the particle characteristics in the YSDP102 core show that the core experienced three different depositional periods and formed three different sedimentary intervals due to different sediment sources and different depositional environments. Features of the clay minerals and the heavy minerals in the YSDP102 core indicate that coarse-grained sediments and fine-grained sediments result from different sources. The Yellow Sea Warm Current has greatly influenced the sedimentary framework of this region since the current‘s formation.     

鲁北平原高氟深层地下水的探究

在山东省北部(鲁北)地区,当地群众由于长期饮用高氟深层地下水,极易导致地氟病,严重影响当地群众的身体健康。根据取样分析,研究区深层地下水氟离子含量大致呈现由南向北、由东向西依次增大的趋势,并且同一地段不同深度、不同岩性的氟离子含量也不尽相同,粘土中氟离子含量普遍大于粉砂层中的含量,高氟地下水多为弱碱性水,高氟地下水Na/Ca比高,高氟水与Na/Ca呈对数相关,相关性较好;高氟水水化学类型一般为HCO_3·Cl-Na型。从地质环境、水文地质环境、水文地球化学角度初探了鲁北平原深层高氟地下水的水文地球化学成因,认为鲁北深层高氟水的形成及分布规律主要受沉积环境、径流条件以及开采量的影响。由于沉积物来源的不同、水化学特征的迥异以及深层地下水的大量开采,粘土层压密释水过多补给,同时由于粘土层由南向北厚度逐渐增大,地下水径流进一步变缓,造成氟离子含量逐步增高,形成了南北部相差较大的氟离子分布特征。     

Difference in organic carbon contents and distributions in particle-size fractions between soil and sediment on the Southern Loess Plateau,China

The purpose of this study was to assess the effect of long-term cultivation and water erosion on the soil organic carbon （OC） in particle-size fractions. The study site is located at Nihegou Watershed in the Southern Loess Plateau, China. The soil at this site is loess with loose and silty structure, and contains macropores. The results showed that the OC concentrations in sediments and in the particle-size fractions of sediments were higher than those in soils and in the particle-size fractions of soils. The OC concentration was highest in the clay particles and was lowest in the sand particles. Clay particles possessed higher OC enrichment ability than silt and sand particles. The proportions of OC in the silt fractions of soil and sediment were the highest （mean value of 53.87% and 58.48%, respectively）, and the total proportion of OC in the clay and silt fractions accounted for 96% and 98% of the total OC in the soil and sediment, respectively. The loss of OC was highest in silt particles, with an average value of 0.16 Mg ha^-1 y^-1, and was lowest in the sand （0.003 Mg ha^-1 y^-l）. This result suggests that the fine particle-size fraction in the removed sediment may be an important indicator to assess soil OC losses.     

Clay minerals and geochemistry of the bottom sediments in the northwestern East China Sea

Clay minerals of 34 sediments collected from the northwestern continental shelf of the East China Sea have been determined by X-ray diffraction analysis. The clay mineral distribution is mainly controlled by the sediment source and the dominant circulation pattern. The predominant clay mineral in our study area is illite comprising more than 67% of the whole clay fraction. The highest concentration of illite (>68%) is found in the southeastern offshore parts beyond the reach of terrigenous input from the Jeju Island. It means that these illites are largely transported by the Kuroshio Current from the South China Sea (SCS). Smectite is highly concentrated in the northwest middle part and in the outer-shelf mud patch. It seems to be due to the high supply of smectite transported from China where fine-grained sediments are discharged from modern and ancient Huanghe (Yellow) River. The relatively high abundant kaolinite is likely derived from the Changjiang (Yangtze) River via the Taiwan Warm Current. In contrast, large amounts of chlorite and high chlorite/kaolinite ratios occur in the northwestern area, reflecting the transportation by the Yellow Sea Coastal Current from the southern Yellow Sea. The discrimination diagrams clearly show that the sediments in the northwestern East China Sea are ultimately sourced from Chinese rivers, especially from the Huanghe River, whereas the sediment in the northeast part might come from the Jeju Island. The muddy sediments of the Changjiang River’s submerged delta have much lower 87Sr/86Sr ratios (0.716 2–0.718 0) than those of the Shandong Peninsular mud wedge (0.721 6–0.724 9), which are supposed to be originated from the Huanghe River, suggesting the distribution pattern of 87Sr/86Sr ratios as a new tracer to discriminate the provenance of shelf sediments in the study area. The 87Sr/86Sr ratios of the outer-shelf muddy sediments ranged from 0.7169 to 0.7216 in a wide range and was between those of the Huanghe River and Changjiang River sediments, suggesting multiple sources of the sediment in the area.