Hydrocarbon gases (C1–C5) and organic matter in bottom sediments of the Ivankovo Reservoir on the Volga River

The results of studying the composition of hydrocarbon gases (C₁–C₅) and organic matter in bottom sediments of the Ivankovo Reservoir in 1995, 2004, and 2005 are given. The methods used in the study include vapor-phase gas chromatography, instrumental pyrolysis gas chromatography, and mass-spectrometry for determining organic carbon δ ¹³C_org. The gas field of bottom sediments in different regions of the reservoir varies widely in terms of gas saturation and the spectrum of hydrocarbon gases. This suggests the heterogeneous composition of organic matter in the sediments and different conditions of its input and transformation processes. The gases were found to contain saturated hydrocarbons from methane to pentane C₁–C₅, including isomers i-C₄ and i-C₅ and unsaturated compounds C₂–C₄. A correlation was found to exist between methane distribution and the distribution of its more high-molecular homologues, which confirms their genetic relationship in bottom sediments. The obtained results show an increase in the rate of microbiological processes and organic matter transformation for most regions in the Ivankovo Reservoir. The only exceptions are the zones of Moshkovichskii Bay and the sections at Gorodnya and Konakovo, where technogenic organic matter is being accumulated. The high information value of hydrocarbon gases as biogeochemical markers of the sources of organic matter and the rates of its transformation is demonstrated. The isotopic composition of organic-matter carbon in the bottom sediments of the Ivankovo Reservoir δ ¹³C varies from ?26.21 to ?30.86‰.     

Dynamics of microelement concentrations in bottom sediments of the marginal filter (Razdol’naya R.–Amur Bay)—Result of biogeochemical processes

Atomic-emission spectroscopy was used to determine the concentrations of Be, Ga, Nb, Ta, Y, Zr, Hf, Sc, Mo, U, and Th in subcolloidal, medium-pelite, coarse-pelite, fine-aleurite, and coarse-aleurite fractions of bottom sediments of Razdol’naya R. marginal filter. The concentrations of examined elements are maximal for the subcolloidal sediment fraction. The average concentration (n = 10) of elements in the soil and fluvial sediments (upstream of the mixing zone) were calculated and taken as background concentrations. The highest concentrations of Y, Be, U was shown to correspond to sediments in the zone of fresh and sea water mixing, which is accompanied by flocculation and sorption on Fe and Mn hydroxides and clay minerals (hydromica in fluvial sediments, and smectite in marine sediments).     

Temporal trend of the suspended sediment transport of the Amazon River (1984–2016)

ABSTRACT

We discuss the claim that the Amazon River has been subjected to a noticeable increase in suspended sediment transport (SST) in response to both climate and land-use changes. To study this, both satellite imagery and in situ data were compiled to produce a 32-year time series (1984–2016) of suspended sediment concentration. Both parametric and nonparametric statistics were applied to examine the SST time trend. The results indicate that there has been no statistically significant increase in SST in the last 32 years, independent of the statistical approach. The results indicate that, over the last 32 years at the Óbidos station, in Brazil, a recurring pattern of increase and decrease in SST has occurred, rather than a unidirectional systematic trend. This further explains the increasing trend reported in the literature and indicates that short time series are not recommended for time trend analyses due to the large inter-annual variability.     

Lateral Inhomogeneity of Basement Layer in Three Gorges Region of Changjiang River (Yangtze River)

Seismic tomography from the Pg wave data along the non-longitudinal profile in the Three Gorges Region is presented in this paper.The seismic tomography method,and the acquisition and analysis of seismic travel time are broadly outlined.The tomography of basement reveals a great amount of significant information and shows that the low-velocity zone is due to the lithologic difference and the fault fracture zone.It also demonstrates that there exist three high-velocity zones with v>6.4 km/s at the basement; the largest of zones which strikes north-south is located at the southwestern side of Huangling Anticlinorium and extends into the anticlinorium northward.The other two high-velocity zones are,respectively,situated at the eastern side of the anticlinorium and the western side of the profile.The high-velocity zones are inferred to originate from the upwelling of material with high-velocity from deep crust.     

The July–August 2001 eruption of Mt. Etna (Sicily)

The July–August 2001 eruption of Mt. Etna stimulated widespread public and media interest, caused significant damage to tourist facilities, and for several days threatened the town of Nicolosi on the S flank of the volcano. Seven eruptive fissures were active, five on the S flank between 3,050 and 2,100 m altitude, and two on the NE flank between 3,080 and 2,600 m elevation. All produced lava flows over various periods during the eruption, the most voluminous of which reached a length of 6.9 km. Mineralogically, the 2001 lavas fall into two distinct groups, indicating that magma was supplied through two different and largely independent pathways, one extending laterally from the central conduit system through radial fissures, the other being a vertically ascending eccentric dike. Furthermore, one of the eccentric vents, at 2,570 m elevation, was the site of vigorous phreatomagmatic activity as the dike cut through a shallow aquifer, during both the initial and closing stages of the eruption. For 6 days the magma column feeding this vent was more or less effectively sealed from the aquifer, permitting powerful explosive and effusive magmatic activity. While the eruption was characterized by a highly dynamic evolution, complex interactions between some of the eruptive fissures, and changing eruptive styles, its total volume (~25×10 ⁶ m ³ of lava and 5–10×10 ⁶ m ³ of pyroclastics) was relatively small in comparison with other recent eruptions of Etna. Effusion rates were calculated on a daily basis and reached peaks of 14–16 m ³ s ^-1, while the average effusion rate at all fissures was about 11 m ³ s ^-1, which is not exceptionally high. The eruption showed a number of peculiar features, but none of these (except the contemporaneous lateral and eccentric activity) represented a significant deviation from Etna's eruptive behavior in the long term. However, the 2001 eruption could be but the first in a series of flank eruptions, some of which might be more voluminous and hazardous. Placed in a long-term context, the eruption confirms a distinct trend, initiated during the past 50 years, toward higher production rates and more frequent eruptions, which might bring Etna back to similar levels of activity as during the early to mid seventeenth century.     

Phosphorus forms and bioavailability of lake sediments in the middle and lower reaches of Yangtze River

Forms of phosphorus in sediments from 25 lakes in the middle and lower reaches of Yangtze River were analyzed by the sequential extraction procedure. Contents and spatial distrubution of algal available phosphorus (AAP) in sediments of Lake Taihu, the third largest freshwater lake of China, were also studied. Relationships between phosphorus forms in sediment and macrophytes coverage in sample sites, as well as phosphorus forms in sediments and chlorophyal contents in lake water were discussed. Exchangeable form of phosphorus (Ex-P) in surface sediments was significantly positive correlative to total phosphorus (IP), dissolved total phosphorus (DTP) and soluble reactive phosphorus (SRP) contents in the lake water. Bioavailable phosphorus (Bio-P) contents in sediments from macrophytes dominant sites were significantly lower than that in no macrophyte sites. In Lake Taihu, Ex-P content in top 3 cm sediment was highest. However, content of ferric fraction phosphorus (Fe-P) was highest in 4 - 10 cm. Bioavalilble phosphorus (Bio-P) contents in surface sediments positively correlated to Chlorophyll a contents in water of Lake Taihu with significant difference. Therefore, contents of Bio-P and AAP could be acted as the indicators of risks of internal release of phosphorus in the shallow lakes. It was estimated that there were 268.6 ton AAP in top 1 cm sediments in Lake Taihu. Sediment suspension caused by strong wind-induced wave disturbance could carry plenty of AAP into water in large shallow lakes like Lake Taihu.     

Sorption–Desorption Transformation of the Runoff of Dissolved Microelements at River–Sea Geochemical Barrier (Based on Data of Experimental Laboratory Simulation)

Water Resources - A new method was used for experimental simulation of the sorption–desorption transformation of microelement composition of the adsorbed complex of solid substances of river...     

Source characterization and spatio–temporal evolution of the metal pollution in the sediments of the Basque estuaries (Bay of Biscay)

According to Water Framework Directive requirements, Member States must identify and analyze effects derived from human pressures in aquatic systems. As different kind of pressures can impact water bodies at different scales, analyses of spatio-temporal evolution of water bodies becomes essential in order to understand ecosystem responses. In this investigation, an analysis of spatio-temporal evolution of sedimentary metal pollution (Cd, Cr, Cu, Hg, Ni, Pb, Zn) in 12 Basque estuaries (Bay of Biscay) is presented. Data collected in extensive sampling surveys is the basis for the GIS-based statistical approach used. The implementation of pollution abatement measures is reflected in a long-term decontamination process, mostly evident in estuaries with highest historical sediment pollution levels. Spatial evolution is determined by either naturally occurring or human driven processes. Such spatial processes are more obviously being reflected in estuaries with lower historical sediment pollution levels.     

Seismicity of the Baikal rift zone for the digital recording period of earthquake observation (2001–2006)

Some characteristics of the seismic regime of the Baikal rift zone for the analogue (1960–2000) and digital (2001–2006) registration modes are considered. It was ascertained that the general number of seismic events recorded by digital equipment increased by two times in comparison with the analogue observation period and the catalog completeness level was lowered to K _P = 7.0 as well. The focal mechanisms of 110 earth-quakes with K _P ≥ 8.0 were examined. The overwhelming majority of them during 2001–2006 were due to normal faulting and normal faulting with strike-slip components. Special attention was given to study of the strong events (K _P ≥ 13.5 and MPSP ≥ 4.7), whose focal solutions reveal the regional stress field.     

Fluctuations of floods of the River Morava (Czech Republic) in the 1691–2009 period: interactions of natural and anthropogenic factors

Abstract

Floods from the middle part of the River Morava (eastern Czech Republic) are considered over the course of the past three centuries, the study being based on data derived from documentary evidence (1691–1880), measured peak water stages, H_k (1881–1920) and peak discharges, Q_k (1916–2009), evaluated with respect to their N-year return period (H_N and Q_N ). Changes in land use and water management (water reservoirs, channel modifications) are discussed, as are factors influencing runoff conditions in the Morava catchment. Decadal synthesis of flood series identifies the highest flood activity in the decades of 1911–1920 and 1961–1970 (11 floods each), 1831–1840, 1891–1900, 1901–1910 and 1931–1940 (10 floods each). Uncertainty in this series is related to some incompleteness of documentary data in the pre-1881 period. Very low flood frequency occurred in the 1990s–2000s, although the most disastrous floods were recorded in this particular period (July 1997 at Q ₁₀₀ and March/April 2006 at Q ₂₀–Q ₅₀). Changes in flood frequency correspond partly to long-term changes in temperature and precipitation patterns.

Citation Brázdil, R., ?ezní?ková, L., Valá?ek, H., Havlí?ek, M., Dobrovolný, P., Soukalová, E., ?ehánek, T. & Skokanová, H. (2011) Fluctuations of floods of the River Morava (Czech Republic) in the 1691–2009 period: interactions of natural and anthropogenic factors. Hydrol. Sci. J. 56(3), 468–485.     

Palaeomagnetism of some Cenozoic sediments,Cairo–Fayum area,Egypt

The palaeomagnetic and rock magnetic characteristics of some Cenozoic rocks from the Cairo–Fayum area have been investigated. A total number of 259 oriented core samples were collected at 32 sites located in rocks of Eocene (13 sites), Oligocene (11 sites) and Pliocene (9 sites) ages. Most of these rocks carry a weak but stable remanent magnetisation that is principally carried by hematite. Goethite and magnetite are also found in some samples as subordinate constituents. Careful thermal demagnetisation successfully enabled the isolation of the characteristic remanent magnetisation. Normal and reversed polarities that passed a reversal test have been recorded in the three age groups. This magnetisation is probably of primary origin and reflects the ages of the rocks. The resultant palaeomagnetic poles are considered reliable and represent a good contribution to the African palaeomagnetic database and should help in further refining of the Cenozoic APWP for Africa.     

Reassessment of flood frequency using historical information for the River Ouse at York,UK (1200–2000)

Abstract

The reassessment of flood risk at York, UK, is pertinent in light of major flooding in November 2000, and heightened concerns of a perceived increase in flooding nationally. Systematic flood level readings from 1877 and a wealth of documentary records dating back as far as 1263 AD give the City of York a long and rich history of flood records. This extended flood record provides an opportunity to reassess estimates of flood frequency over a time scale not normally possible within flood frequency analysis. This paper re-evaluates flood frequency at York, considering the strengths and weaknesses in estimates resulting from four contrasting methods of analysis and their corresponding data: (a) single-site analysis of gauged annual maxima; (b) pooled analysis of multi-site gauged annual maxima; (c) combined analysis of systematic annual maxima augmented with historical peaks, and (d) analysis of only the very largest peaks using a Generalized Pareto Distribution. Use of the historical information was found to yield risk estimates which were lower and considered to be more credible than those achieved using gauged records alone.

Citation Macdonald, N. & Black, A. R. (2010) Reassessment of flood frequency using historical information for the River Ouse at York, UK (1200–2000). Hydrol. Sci. J. 55(7), 1152–1162.     

Rainfall–runoff modelling for estimating Latonyanda River flow contributions to Luvuvhu River downstream of Albasini Dam

Rainfall–runoff modelling was conducted to estimate the flows that Latonyanda River contribute to Luvuvhu River downstream of Albasini Dam. The confluence of Latonyanda and Luvuvhu Rivers is ungauged. The contributed flows compensate for upstream water abstractions and periodic lack of releases from Albasini Dam. The flow contributions from tributaries to Luvuvhu River are important for ecosystem sustenance, meeting downstream domestic and agricultural water demand and ecological water requirements particularly in Kruger National Park. The upper Latonyanda River Quaternary Catchment (LRQC), with streamflow gauging station number A9H027 was delineated and used for rainfall–runoff modelling. The simulation was done using Mike 11 NAM rainfall–runoff model. Calibration and verification runs of Mike 11 NAM rainfall–runoff model were carried out using data for periods of 4 and 2 years, respectively. The model was calibrated using shuffled complex evolution optimizer. The model efficiency was tested using coefficient of determination (R²), root mean square error (RMSE), overall water balance error (OWBE) and percentage bias (PBIAS). The model parameters obtained from the upper LRQC were transferred and used together with rainfall and evaporation data for 40 years period in the simulation of runoff for the LRQC. The flows that Latonyanda River contribute to Luvuvhu River were computed by subtracting irrigation abstractions and runoff drained to Tshakhuma Dam from the simulated runoff time series of the LRQC. The observed and the simulated runoff showed similar trends and measures of performances for both calibration and verification runs fell within acceptable ranges. The pairs of values obtained for R², RMSE, OWBE and PBIAS for calibration and verification were 0.86 and 0.73, 0.21 and 0.2, 2.1 and 1.3, and 4.1 and 3.4, respectively. The simulated runoff for LRQC correlated well with the areal rainfall showing that the results are reasonable. The mean and maximum daily flow contributions from the Latonyanda River are 0.91 and 49 m³/s respectively. The estimation of these ungauged flows makes it possible to plan and manage the water requirements for the downstream users.     

Don·L·安德森(1933-2014)

<正>美国地球物理联合会前主席安德森(Don L.Anderson)(http://srl.geoscienceworld.org/content/85/1/91.full),于2014年12月2日逝世,享年81岁。唐堪称地球和行星科学领域复兴的真正领军人物。在他于1958年到2014年间发表的350多篇论文中,他试图解决在矿物物理学、地震学、热流、地球化学、构造物理     

Seismic response of deep Quaternary sediments in historical center of L’Aquila City (central Italy)

On 6 April 2009 a M_w=6.1 earthquake produced severe destruction and damage over the historic center of L’Aquila City (central Italy), in which the accelerometer stations AQK and AQU recorded a large amount of near-fault ground motion data. This paper analyzes the recorded ground motions and compares the observed peak accelerations and the horizontal to vertical response spectral ratios with those revealed from numerical simulations. The finite element method is considered herein to perform dynamic modeling on the soil profile underlying the seismic station AQU. The subsurface model, which is based on the reviewed surveys that were carried out in previous studies, consists of 200–400 m of Quaternary sediments overlying a Meso-Cenozoic carbonate bedrock. The Martin-Finn-Seed's pore-water pressure model is used in the simulations. The horizontal to vertical response spectral ratio that is observed during the weak seismic events shows three predominant frequencies at about 14 Hz, 3 Hz and 0.6 Hz, which may be related to the computed seismic motion amplification occurring at the shallow colluvium, at the top and base of the fluvial-lacustrine sequence, respectively. During the 2009 L’Aquila main shock the predominant frequency of 14 Hz shifts to lower values probably due to a peculiar wave-field incidence angle. The predominant frequency of 3 Hz shifts to lower values when the earthquake magnitude increases, which may be associated to the progressive softening of soil due to the excess pore-water pressure generation that reaches a maximum value of about 350 kPa in the top of fluvial-lacustrine sequence. The computed vertical peak acceleration underestimates the experimental value and the horizontal to vertical peak acceleration ratio that is observed at station AQU decreases when the earthquake magnitude increases, which reveals amplification of the vertical component of ground motion probably due to near-source effects.     

Recovery of the early period of long instrumental time series of air temperature in Padua,Italy (1716–2007)

The longest series of instrumental observations have a number of problems in the early period. This paper is focused on the recovery of early indoor and outdoor observations in Padua and their transformation in terms of a modern series. The Padua series was started by Giovanni Poleni with outdoor observations in 1716–1718, but soon, the readings passed indoors (1725–1764) to join the directives of the Royal Society, London. The indoor readings were recovered within the EU project IMPROVE, but it was necessary to transform indoor observations into outdoor ones, and this was possible thanks to the presence of simultaneous indoor and outdoor observations by Morgagni in Padua and Beccari in Bologna. These parallel series were also useful to fill a short gap. Another problem was to reconstruct the calibration of the Amontons thermometer, which changed when Poleni moved to a new house. Also the problem of the use of variable and/or different sampling times was solved making reference to the trend of the daily cycles in the different seasons and under diverse weather conditions. The data analysis has shown a trend that appears similar to the well-known results (IPCC 2007) for the last 160 yr but a less marked recent warming for winter and autumn. The 18th century was characterized by cold winters (culminated 1709 and 1740) and springs, and warm summers and autumns. A well-marked Bruckner cycle (35.8 yr), continually repeated and attenuated, is visible for the period 1716–1930. The wide time scale and the repetition of warmer and colder periods over two-thirds of the series noted in Padua and other Mediterranean stations may induce us to suppose that such cycles could continue in the future, at least on the local scale.     

Paleosecular variations 12–20 Kyr as recorded by sediments from Lake Moreno (Southern Argentina)

We present results of paleomagnetic and sedimentological studies carried out on three cores Lmor1, Lmo98-1, Lmor98-2 from bottom sediments of Lake Moreno (south-western Argentina), and integrate them with data from our previous studies. Measurements of directions (declination D and inclination I) and mass specific intensity of natural remanent magnetization (NRM intensity), magnetic susceptibility (specific, χ and volumetric, κ), isothermal remanent magnetization (IRM), saturation of isothermal remanent magnetization (SIRM), and back field remanent coercivity (B_0CR) were performed. The stability of the NRM was investigated using alternating-field demagnetization. The results show that these sediments meet the criteria required to construct a reliable paleomagnetic record. The cores were correlated very well based on magnetic parameters, such as χ and NRM intensity, as well as with lithological features. Tephra layers were identified from the lithological profiles and magnetic susceptibility logs. We obtained the D and I logs of the characteristic remanent magnetization for the cores as a function of shortened depth. The data from the three cores were combined to form a composite record using the Fisher method. A comparison between stacked inclination and declination records of Lake Moreno and those obtained in previous works on Lake Escondido and Lake El Trébol shows good agreement. This agreement made it possible to transform the stacked curves into time series spanning the interval 12–20 kyr. The results obtained improved our knowledge of SV and the behaviour of the geomagnetic field and also allowed us to determine the range of past inclination variations from −70° to −45° for the southern hemisphere, where data are scarce.     

Land–ocean distribution of allochthonous organic matter in surface sediments of the Chiloé and Aysén interior seas (Chilean Northern Patagonia)

We investigated the relative distribution of allochthonous (i.e., terrigenous) organic matter in the complex, continuous, river–fjord–sound–channel–gulf system of Chile’s North Patagonia (41.5–46.5°S) in order to establish whether this organic matter can reach the open ocean or whether it is largely retained near its fluvial sources. Grain size distribution, total organic carbon and total nitrogen contents, and carbon stable isotope contents (δ¹³C) were quantified in 53 surface sediment samples collected during the CIMAR Fiordos cruises 1, 4, 8, and 10, as were salinity and silicic acid concentrations in the surface waters. A principal component analysis segregated the Chiloé and Aysén interior seas into two zones: (i) the continental fjords, with sediment enriched in allochthonous organic matter, having higher C:N molar ratios (10–14) and lower δ¹³C composition (?23‰ to ?27‰); and (ii) the channels and gulfs, with a prevalent autochthonous marine source, having lower C:N values (6–10) and higher δ¹³C composition (?20‰ to ?23‰). Estuarine waters with low salinity (2–30) and high silicic acid (10–90 μM) were associated with high C:N ratios and low δ¹³C in surface sediments, meaning that terrestrial organic matter was transported up to the mouth of the continental fjords. A two-source mixing model confirmed that allochthonous (terrestrial) organic matter contents (50–90%) associated with local river discharges were present within the continental fjords. On the contrary, autochthonous (marine) organic matter was prevalent (50–90%) at the sites in the marine influenced channels, sounds, and gulfs.     

Projected streamflow in the Huaihe River Basin (2010–2100) using artificial neural network

Climate projections for the Huaihe River Basin, China, for the years 2001–2100 are derived from the ECHAM5/MPI-OM model based on observed precipitation and temperature data covering 1964–2007. Streamflow for the Huaihe River under three emission scenarios (SRES-A2, A1B, B1) from 2010 to 2100 is then projected by applying artificial neural networks (ANN). The results show that annual streamflow will change significantly under the three scenarios from 2010 to 2100. The interannual fluctuations cover a significant increasing streamflow trend under the SRES-A2 scenario (2051–2085). The streamflow trend declines gradually under the SRES-A1B scenario (2024–2037), and shows no obvious trend under the SRES-B1 scenario. From 2010 to 2100, the correlation coefficient between the observed and modeled streamflow in SRES-A2 scenario is the best of the three scenarios. Combining SRES-A2 scenario of the ECHAM5 model and ANN might therefore be the best approach for assessing and projecting future water resources in the Huaihe basin and other catchments. Compared to the observed period of streamflows, the projected periodicity of streamflows shows significant changes under different emission scenarios. Under A2 scenario and A1B scenario, the period would delay to about 32–33a and 27–28a, respectively, but under B1 scenario, the period would not change, as it is about 5–6a and the observed period is about 7–8a. All this might affect drought/flood management, water supply and irrigation projects in the Huaihe River basin.     

From drought to flood: A water balance analysis of the Tuolumne River basin during extreme conditions (2015–2017)

The degree to which the hydrologic water balance in a snow-dominated headwater catchment is affected by annual climate variations is difficult to quantify, primarily due to uncertainties in measuring precipitation inputs and evapotranspiration (ET) losses. Over a recent three-year period, the snowpack in California's Sierra Nevada fluctuated from the lightest in recorded history (2015) to historically heaviest (2017), with a relatively average year in between (2016). This large dynamic range in climatic conditions presents a unique opportunity to investigate correlations between annual water availability and runoff in a snow-dominated catchment. Here, we estimate ET using a water balance approach where the water inputs to the system are spatially constrained using a combination of remote sensing, physically based modelling, and in-situ observations. For all 3 years of this study, the NASA Airborne Snow Observatory (ASO) combined periodic high-resolution snow depths from airborne Lidar with snow density estimates from an energy and mass balance model to produce spatial estimates of snow water equivalent over the Tuolumne headwater catchment at 50-m resolution. Using observed reservoir inflow at the basin outlet and the well-quantified snowmelt model results that benefit from periodic ASO snow depth updates, we estimate annual ET, runoff efficiency (RE), and the associated uncertainty across these three dissimilar water years. Throughout the study period, estimated annual ET magnitudes remained steady (222 mm in 2015, 151 mm in 2016, and 299 mm in 2017) relative to the large differences in basin input precipitation (547 mm in 2015, 1,060 mm in 2016, and 2,211 mm in 2017). These values compare well with independent satellite-derived ET estimates and previously published studies in this basin. Results reveal that ET in the Tuolumne does not scale linearly with the amount of available water to the basin, and that RE primarily depends on total annual snowfall proportion of precipitation.