Stable Isotopic Composition of Hydration Water in Carnallite of Late Cretaceous Potash Deposits on Khorat Plateau

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Mineralization Characteristics and Structural Controls of Hydrothermal Deposits in the Gyeongsang Basin, South Korea

Abstract. Hydrothermal deposits in the Gyeongsang Basin show the genetic relationship with igneous activity from Late Cretaceous to Early Tertiary in the spatial and temporal viewpoints. Many hydrothermal Au-Ag-Cu-Pb-Zn and clay deposits are dominantly distributed within the Gyeongsang Basin. The Gyeongsang Basin is divided into seven metallogenic provinces by spatial distribution. The age ranges of igneous activity and mineralization are 140∼40 Ma and 100∼40 Ma, respectively, and the most dominant age ranges of the both activities are from 90 Ma (Coniacian) to 50 Ma (Eocene). The age consistency between igneous activity and mineralization suggests that this age range is the climactic period of the hydrothermal activity of the Gyeongsang Basin. The metallogenic epochs in the Gyeongsang Basin are divided into three epochs of 100∼80 Ma (western part of the Gyeongsang Basin), 80∼60 Ma (central part of the Gyeongsang Basin), and 60∼40 Ma (eastern part of the Gyeongsang Basin). The mineralization and igneous activity tend to become young eastward in the Gyeongsang Basin.
NNW-SSE mineralized veins from 100 to 80 Ma in the western part of the Gyeongsang Basin are interpreted as the control of the parallel tensional fissures caused by NNW-SSE compressional stress. NW-SE mineralized veins from 80 to 60 Ma in the central part of the Gyeongsang Basin seem to have been formed under the same stress as that of the Gaeum and Yangsan Fault Systems. Namely, NW-SE tensional stress is associated with a conjugate set of fracturing of the WNW-ESE Gaeum Fault System and NNE-SSW Yangsan Fault System. Also NE-SW mineralized veins from 60 to 40 Ma in the eastern part of the Gyeongsang Basin seem to be controlled by the NE-SW fractures. The fractures are related with NE-SW compressional stress and are developed as secondary fractures within the dextral strike slip Yangsan Fault System.     

湘南两类铅锌矿床的铅同位素组成特征

一、前言湘南的两类铅锌矿床,主要指的是东坡、香花岭矿田的铅锌、锡铅锌矿床和产于泥盆纪的层控铅锌矿床。前一类矿床的形成,不仅与燕山期花岗岩类小岩体密切有关,而且具有明显的地层效应,集中产于中上泥盆统棋梓桥组、佘田桥组碳酸盐岩中。如香花岭矿田的铅锌矿床约有80％的矿床(点)都集中产于棋梓桥组上段下部的白云岩和白云岩化灰岩内,同时还受到断裂构造的控制。以往的多数研究者认为,东坡、香花岭矿田的铅锌矿床,其成因属于典型的岩浆期后热液     

医巫闾山变质核杂岩中金矿的稳定同位素特征

医巫闾山变质核杂岩中金矿及相关岩石的氢、氧、铅、硅、碳、硫稳定同位素测试结果为:成矿流体δD为-97‰~-72‰,δ18O为0.3‰~3.8‰,在δ18O-δD分布图上,位于变质水、岩浆水与当地雨水之间;其他稳定同位素数据及综合资料均说明,以排山楼金矿为代表的该区金矿成矿具有长期性、复杂性和多源性;医巫闾山变质核杂岩构造系统对区内金矿有一定控制作用.     

兰坪盆地三类主要铜银多金属矿床的稳定同位素地球化学

通过对兰坪盆地内三种主要成因类型（沉积-热液改造型、热水沉积-热液改造型和热液脉型）的铜银多金属矿床硫、碳、氢、氧同位素的研究,揭示了成矿作用过程的某些重要信息：矿石中的硫主要来自细菌还原的海水硫酸盐,但在沉积-热液改造型矿床中可能还有部分有机生物硫和深源火山硫的贡献;碳主要来自不同比值水/岩反应体系中碳酸盐岩地层的溶解结果,但在沉积-热液改造型矿床中还可能有深部地幔去气作用带来的CO2.成矿流体系以大气降水为主要补给源的盆地建造水,盆地建造水的运移成矿过程中可能伴有较为明显的蒸发作用.     

西藏东南缘早二叠世长英质凝灰岩锆石U-b年龄和Hf同位素特征

西藏东南缘记录的唐加-松多古特提斯增生杂岩带对认识古特提斯洋晚古生代的构造演化提供了新的证据.针对该杂岩带中新发现的长英质凝灰岩开展了全岩主、微量元素,锆石LA-ICP-MS U-Pb定年和锆石Hf同位素组成的研究.结果显示冲尼凝灰岩喷发于278~275 Ma,具有较高的SiO₂含量（63.47%~72.65%）、Al₂O₃含量（14.53%~21.31%）,较低的K₂O含量（1.30%~2.51%）和TiO₂含量（0.50%~1.17%）,MgO含量较低,介于0.92%~2.00%,Mg#范围在19.9~34.2（均低于40）.富集大离子亲石元素（LILE）、亏损高场强元素（HFSE）.锆石具有较高的ε_Hf（t）值（+10.2~+14.4）和相对年轻的地壳模式年龄T_DMc=351~621 Ma,认为冲尼凝灰岩是唐加-松多古特提斯洋向北俯冲背景下的新生地壳部分熔融的产物,洋盆俯冲消减的开始时代不晚于早二叠世,并且在早二叠世拉萨地体东南缘存在新生地壳生长事件.      

个旧锡矿花岗岩的氧氢碳稳定同位素研究

个旧锡矿是世界闻名的特大型锡多金属矿床,大量工程揭示,锡矿与花岗岩在时空分布上有着密切的联系,本文试图通过对矿区岩石、矿物及其流体包裹体的氧氢碳稳定同位素的测试研究,进一步揭示锡矿化与花岗岩之间的内在联系和探索成岩成矿物质来源。     

Geochemical Evolution of Hydrothermal Fluids at the Daejang Cu–Zn–Pb Vein Deposit, Korea

Abstract: The Daejang mine is located within the Cretaceous Gyeongsang basin. Mineral paragenesis can be divided into four stages (stages I, II, III and IV) by major tectonic fracturing. Stages I, III and IV are economically barren. Stage II, at which the precipitation of major ore minerals occurred, is further divided into three substages with paragenetic time based on minor fractures and discernible mineral assemblages: substage IIa, marked by deposition of quartz and Fe–sulfides; substage IIb, by introduction of base-metal sulfides within carbonates and some quartz; substage IIc, by quartz and carbonates with various sulfosalts. Fluid inclusion data indicate a complex geochemical evolution of hydrothermal fluids. Both CO₂–rich and H₂O–rich fluids were trapped in fluid inclusions at stage I and substage IIa. It is suggested that a compositionally heterogeneous fluid was formed by fluid boiling and CO₂ immiscibility at temperatures of about 400° to 300°C. Composite lodes of base-metal sul–fides, carbonates and quartz at substage IIb were deposited in open spaces created by fracturing. The fracturing event prompted rapid decreases in pressure and temperature of residual fluids and resulted in retrograde fluid boiling at about 200 bars and 300°–250°C during substage IIb. The progressive loss of CO₂ by CO₂ effervescence and retrograde boiling from substage IIa and IIb fluids resulted in pH increase and related increase in carbonate activity, causing deposition of abundant carbonates. The change in pH also caused the decrease of stability of hydrogen sulfide with Cu, Zn and Pb chloride complexes (as main transporting agents at Daejang) and resulted in the pricipitation of base-metal minerals. Deposition of Ag– and Sb-bearing sul–fides and sulfosalts of substage IIc occurred at temperatures of about 250° to 150°C from a dominantly aqueous fluid with low salinity (down to 3. 0 equiv. wt % NaCl). At this substage, aqueous fluid formed by mixing with cooler and less saline meteoric groundwater. There is a systematic decrease in caculated δ¹⁸O_water values with the mineralization stage (and decreasing temperature) in the Daejang hydrothermal system, from values of about 11% for stage I, through about 4% for stages II and III, to about –3 per mil for stage IV. The result of stable isotope and fluid inclusion studies are interpreted to indicate progressive less evolved and/or unexchanged meteoric water influx of an early hydrothermal system formed by highly evolved meteoric waters.     

矿床地球化学应用

稳定同位素方法已成为现代地球科学研究的重要手段之一，稳定同位素体系的理论模式及其地球化学应用是国际上地球化学研究的前沿方向之一。本文概括了热液体系内成矿地球化学过程引起稳定同位素组成变化的定量理论模式，包括热液矿物之间的同位素平衡的判断、热液去气和矿物沉淀的储库效应、二元混合与矿床成因等。这些模型对于确定成矿温度、鉴定成矿流体源区和推测成矿地球化学机理提供了更为合理的同位素数据定量解释基础。     

浙江主要金银（铅、锌）矿床同位素地球化学研究

应用Rb-Sr等时线法测定了浙江不同类型金、银矿床（璜山金矿、治岭头金银矿、毫石银矿及拔茅、大岭口含银铅锌矿）的成矿时代。不同类型矿床的Sr、Pb同位素组成有显著的差别表明其成矿物质有不同的来源和成因。特征的Pb同位素组成还可以作为不同类型矿床的找矿标志。     

黔西罐子窑铅锌矿床Pb同位素研究及地质意义

罐子窑铅锌矿床位于川、滇、黔铅锌成矿区东缘,矿体赋存于上泥盆统-下石炭统的白云质灰岩和白云岩中,呈似层状或陡倾斜脉状产出。在分析该矿床成矿地质条件的基础上,系统研究了矿石和围岩的Pb同位素组成特征,探讨了成矿时代与成矿物质来源。研究结果表明,该矿床矿石Pb同位素组成稳定,属于正常普通铅,利用H-H法计算获得了矿脉铅的主模式年龄150~169 Ma。研究表明该矿石Pb模式年龄应该代表矿床成矿年龄,反映Pb主成矿期在燕山期,燕山期NE向断裂(带)控制着本区铅锌矿体(点)的分布。同位素示踪结果显示本区矿石Pb同位素具有多来源特征,不同时代的碳酸盐岩围岩和基底岩石均为罐子窑铅锌矿床提供了成矿物质。综合研究认为,川、滇、黔铅锌成矿区内铅锌成矿具有多阶段、多旋回性,构造与同位素年代学均揭示,该成矿区存在较大规模的燕山期铅锌成矿作用,在今后的找矿研究工作中应当充分重视。     

大兴安岭南段热液脉状矿床的流体包裹体和稳定同位素特征:对矿床成因的启示

大兴安岭南段发育大井、双尖子山、布金黑、拜仁达坝、维拉斯托等多个具有典型后生特征的热液脉状铅锌银锡多金属矿床。为了查明上述矿床在成矿流体、成矿物质等方面的特征与差异,进而总结大兴安岭南段热液脉状矿床成矿作用特点,本次研究在野外地质调研的基础上,对上述矿床进行了流体包裹体、激光拉曼和氢氧硫同位素的研究,并取得了如下主要的认识:(1)双尖子山银多金属矿床成矿流体属简单盐水体系热液,维拉斯托和布金黑矿床成矿流体属富碳质盐水体系热液,而大井铜矿成矿流体则为含子矿物的不均匀盐水体系热液;(2)大井、布金黑、拜仁达坝和维拉斯托等矿床早期成矿流体均来自于岩浆热液,但布金黑、拜仁达坝和维拉斯托矿床成矿流体在运移过程中明显地受到了大气降水和地层中有机质的影响;(3)大兴安岭南段多数热液脉状多金属矿床矿石硫同位素δ34S值具有岩浆来源特点,个别矿床硫同位素δ34S值偏高可能是由复杂的岩浆源区性质及地层硫混入所引起。总的来说,大兴安岭南段不同热液脉状矿床在物质来源和流体演化方面的差异明显,而这也体现了该区中生代热液成矿作用的多样性和复杂性特点。     

南京汤山洞穴石笋稳定同位素指示的气候与环境意义

对南京汤山葫芦洞南壁钙板上一支长８２ｍｍ石笋进行了高精度热电离质谱（ＴＩＭＳ）定年及氧碳同位素分析。结果表明,该支短石笋生长时段长达３００ｋａ左或（距今４６３～１５９ｋａ）,其底部年龄进一步证实南京直立人生存时代早于４５０ｋａＢＰ。δ＾１３Ｃ值在ＭＩＳ６／７界线上的显著漂移揭示了一次土壤侵蚀事件,结束了洞穴文化层的堆积历史。     

我国热液金矿中黄铁矿的载金性研究

黄铁矿是热液金矿主要的载金矿物。单个金矿中黄铁矿的载金已有不少研究,并积累了相关经验,但综合研究和相对定量的分析鲜见,对热液金矿中黄铁矿含金性的普遍认识非常重要。以我国数十个重要的卡林/类卡林型、造山型、岩浆热液型以及浅成低温热液型金矿中载金黄铁矿的矿物学及元素组成为基础,相对全面和定量地开展了黄铁矿粒径、自形程度和As含量与其载金性之间相关性的研究。结果表明:黄铁矿的载金性与其粒径大小多呈负相关(相关系数为-0.049～-0.783),与其自形程度多呈负相关(相关系数为-0.049～-0.989),与其As含量多呈正相关(相关系数为0.189～0.998),即细晶、它形、高As黄铁矿载金性优于粗晶、自形、低As的黄铁矿。相较于粗晶自形的黄铁矿,中细晶它形黄铁矿晶体,由于非理想的生长条件,使其内部晶格缺陷常见,从而更易包裹自然金;As以类质同象的形式置换S进入黄铁矿,由于As与S的晶体化学性质差异,导致高As黄铁矿内部出现更多晶格缺陷而捕获金。这些可能都是导致细晶、它形、高As黄铁矿载金性优于粗粒、自形、低As黄铁矿的原因。热液金矿成矿早阶段形成黄铁矿中的不可见金,很可能在热液系统中通...     

Stable Isotopic Evidence for Fluid-Rock Interactions in the Ivrea Zone, Italy

Stable isotope compositions of Ivrea Zone marbles and associatedlithologies are in general heterogeneous. The oxygen isotopecomposition of quartz in pelites ranges from ¹⁸O +9 to + 17(SMOW) and does not vary systematically with metamorphic grade.Peridotites retain oxygen isotope signatures close to mantlevalues. Marble calcites vary in isotopic composition from ¹³C + 2(PDB),¹⁸0 +24(SMOW)to ¹³C –6(PDB), ¹⁸O + 13 (SMOW).Depletions in ¹⁸O and ¹³C may be explained dominantly by interactionwith fluids derived from within the observed metasedimentarysequence during prograde metamorphism. ¹⁸O and ¹³C show gradients of greater than 5/m across marblemargins and within marbles. The preservation of such isotopicgradients is not consistent with the long-term presence of grain-boundary-scaleinterconnected fluid films in and around marbles. There is ageneral lowering of ¹⁸O within individual marble bodies althoughlarge carbon and oxygen isotopic gradients are present. Calcitein marbles may attain oxygen isotope equilibrium, but rarelycarbon isotope equilibrium, with surrounding metapelites. Infiltrationof marbles must involve a component of channelized fluid flow. The general lack of isotopic equilibration within the sequencerequires channelized fluid flow and limited fluid-rock ratios.Large pervasive mantle to crust fluid fluxes are not consistentwith the observations. ^*Present address: Natural Environment Research Council, Polaris House, North Star Avenue, Swindon SN2 1EU, England     

与侵入岩有关的脉型金矿:类型、构造岩浆背景及与造山带金矿的区别

一些金矿化类型表明它们与侵入岩有关。这些矿床产于侵入岩内部、附近或环绕单个侵入体 ,包括斑岩型、角砾岩型、矽卡岩型、交代型和脉型。其中由于脉型金矿多为中温热液金矿而使其在生成模式上最有争议 ,这就是由 Groves等 (1998)提出的造山带金矿。由于缺少任何与侵入岩有直接联系的流体证据 ,普遍认为造山带金矿是在挤压变形和区域变质作用期间或之后生成的。据矿脉矿物学及金属元素组合特征 ,可将与侵入岩有关的脉型金矿分为 5种类型及相应的金属元素组合 :Au Fe氧化物 Cu,Au CuMo Zn,Au As Pb Zn Cu,Au Te Pb Zn Cu和 Cu As BiSb类型。     

Chemical, Isotopic, and Fluid Inclusion Evidence for the Hydrothermal Alteration of the Footwall Rocks of the BIF-Hosted Iron Ore Deposits in the Hamersley District, Western Australia

Abstract. The petrography, chemical, fluid inclusion and isotope analyses (O, Rb-Sr) were conducted for the shale samples of the Mount McRae Shale collected from the Tom Price, Newman, and Paraburdoo mines in the Hamersley Basin, Western Australia. The Mount McRae Shale at these mines occurs as a footwall unit of the secondary, hematite-rich iron ores derived from the Brockman Iron Formation, one of the largest banded iron formations (BIFs) in the world. Unusually low contents of Na, Ca, and Sr in the shales suggest that these elements were leached away from the shale after deposition. The δ¹⁸O (SMOW) values fall in the range of + 15.0 to +17.9 per mil and show the positive correlation with calculated quartz/sericite ratios of the shale samples. This suggests that the oxygen isotopic compositions of shale samples were homogenized and equilibrated by postdepositional event. The pyrite nodules hosted by shales are often rimmed by thin layers of silica of varying crystallinity. Fluid inclusions in quartz crystals rimming a pyrite nodule show homogenization temperatures ranging from 100 to 240C for 47 inclusions and salinities ranging from 0.4 to 12.3 wt% NaCl equivalent for 18 inclusions. These fluid inclusion data give direct evidence for the hydrothermal activity and are comparable to those of the vein quartz collected from the BIF-derived secondary iron ores (Taylor et al, 2001). The Rb-Sr age for the Mount McRae Shale is 1,952 ± 289 Ma and at least 200 million years younger than the depositional age of the Brockman Iron Formation of ∼ 2.5 Ga in age. All the data obtained in this study are consistent with the suggestion that high temperature hydrothermal fluids were responsible for both the secondary iron ore formation and the alteration of the Mount McRae Shale.     

黔西南灰家堡金矿田热液方解石稀土元素与C-O-Sr同位素地球化学特征

为探讨灰家堡金矿田矿化剂和成矿物质来源,系统开展了热液方解石的稀土元素和C-O-Sr 同位素研究.结果表明,热液方解石的稀土元素具有"上凸型"配分模式,低的(La/Sm)N值(0.003～0.580),较高的(Gd/Yb)N值(1.21～15.73),Eu正异常,显示成矿流体的壳源特征;产于龙潭组(P3l)的矿体中的方...     

Geology and Genesis of Orogenic Gold Deposits,Xiaoqinling District,Southeastern China

Orogenic gold vein deposits in the Xiaoqinling district are situated in a basement-cored uplift along the southern margin of the North China craton. The deposits are hosted by Late Archean to Paleoproterozoic amphibolite-facies country rocks, varying in lithology from clastic and chemical sedimentary units to felsic and mafic volcanic rocks and plutons. Absolute and relative age relationships indicate a late Mesozoic emplacement of the lodes, which is subsequent to the deformation associated with the Middle to Late Triassic Qinling orogen along the craton margin. All auriferous quartz veins are hosted in faults. The ores are generally composed of quartz veins with various amounts of pyrite, galena, chalcopyrite, sphalerite, and carbonates. Mineralization can be separated into three distinct stages.

Ore fluids are H₂O dominant, with approximately 20 to 30 and 10 to 20 mole% CO₂ for gold-bearing stage I and II veins, respectively. Vein formation pressures and temperatures were 2.2 kbar and 300 to 370°C for stage I and 1.6 kbar and 250 to 320°C for stage II. The narrow range of δ¹⁸O values for ore fluids from the deposits throughout the Xiaoqinling district indicate a common deep fluid source, most likely of magmatic origin. The ³⁴S data suggest sulfur originated from a magmatic fluid of approximately 2 ± 2%, with significant local sulfur contributions leading to large variations in the ore-stage sulfide minerals. The most probable mechanism for the deposition of gold is phase separation caused by the partial loss of volatiles such as CO₂ and CH₄.