Zeolitic diagenesis of late Quaternary fluviolacustrine sediments and associated calcrete formation in the Lake Bogoria Basin, Kenya Rift Valley

Late Quaternary fluviolacustrine siltstones, mudstones and claystones (Loboi Silts) on the northern margins of the saline, alkaline Lake Bogoria in the Kenya Rift Valley contain up to c. 40% authigenic analcime and minor natrolite. The zeolitic sediments are reddish brown and up to 1 m thick. The amount of analcime increases upward in the profile, but decreases with distance from the lake. The altered sediments show many pedogenic features including zeolitic root mats, rootmarks, concretions and carbonate rhizoliths. Residual patches of calcrete locally cap the zeolitic rocks. The profile is interpreted as an exhumed palaeosol and land surface on the former margins of the lake. The analcime occurs as submicroscopic (0–5–2–5 μ.m) subhedral and euhedral crystals, which have an average Si/A 1 ratio of 2–33 (as determined by X-ray microanalysis) or 2–18 (d-value of 639 analcime peak). The analcime formed in lake marginal sediments (soils) by reaction of silicate detritus with Na₂CO₃ rich pore waters concentrated close to the land surface by evaporative pumping and evapotranspiration. Poorly ordered clay minerals were probably the main reactants. Authigenic illite may have been a by-product of the reactions. Chemical analyses suggest that pore waters supplied some of Na⁺, and possibly K⁺ and SiO₂. The associated calcrete and rhizoliths were formed during or shortly after the main period of zeolitic alteration. The Ca²⁺ may have originated from infiltrating dilute runoff and groundwater. Authigenic smectite was precipitated in open porosity following analcime formation. The zeolitic alteration at Lake Bogoria provides a relatively recent analogue for lake marginal zeolites found in many ancient saline, alkaline lake sediments.     

Late Quaternary primary tephras in Sacred Lake sediments, northeast Mount Kenya, Kenya

In this paper, a sequence of five Late Quaternary tephras occurring as discrete, well-preserved horizons in lake sediments on the northeastern flank of Mount Kenya are characterised and their ages determined by a combination of high-resolution indirect radiocarbon dating and direct dating. The grain size characteristics suggest that the tephras are of fairly local origin. These Na---K-rich alkali pyroclasts with a trachytic chemical composition have a highly correlated chemistry and mineralogy, suggesting that they were probably derived from the same genetic series and possibly erupted from a single source vent. Morphological differences are attributed to the peculiar characteristics of each eruption episode. The magma source was probably a small, highly differentiated magma chamber following the olivine basalt-trachyandesite-trachyte-phonolite series, which broadly reflects the Quaternary rock suite of Mount Kenya.     

塔中地区良里塔格组碳酸盐岩储层特征及成岩作用

塔中地区良里塔格组发育巨厚的礁滩相碳酸盐岩,为碳酸盐岩储层的形成提供了有利条件。通过对钻井岩心和薄片分析,系统研究了研究区良里塔格组碳酸盐岩的储层岩石学、成岩作用类型和特征,总结了各类成岩作用的识别标志、发育规律及对储集体形成的影响。研究区碳酸盐岩储层的成岩作用包括泥晶化作用、白云石化作用、方解石胶结作用、溶蚀作用、硅化和硅质充填作用,以及压实、压溶作用、破裂作用和自生黄铁矿作用。在此基础上,总结了良里塔格组碳酸盐岩成岩序列及储层孔隙演化规律,认为早期强烈的方解石胶结作用和压实压溶作用降低了储层的孔隙度和渗透率,而溶蚀作用和构造破裂作用对良里塔格组礁滩相碳酸盐岩优质储层的形成具有明显控制作用。     

Origin and diagenesis of Quaternary travertine shrub fabrics, Rapolano Terme, central Italy

Millimetre to centimetre sized arborescent shrub-like calcite precipitates are common constituents of hot water travertine shallow pool deposits of Quaternary age at Rapolano Terme, Tuscany, Italy. In the presently forming travertines, the shrubs consist of apparently random associations of (i) micrite aggregates and (ii) subhedral to euhedral rhombic spar crystal aggregates. In thin section, the micrite aggregates appear dark and the spar-rhomb aggregates light, giving the shrubs a mottled appearance. Travertines are basically produced by CaCO₃ precipitation due to degassing and evaporation of the spring waters, although biological influence may also stimulate precipitation. The formation of masses of erect shrubs, rather than dense crystal crusts that form on slopes, is probably due to limited water flow in the pool environments. Microbes, including bacteria and diatoms, are important influences on shrub microfabric and external shape. The micrite aggregates are associated with bacteriform bodies, seen as tiny rods and spheres. The micrite precipitates around these bodies and in adjacent biofilm. Spar-rhomb precipitation appears to be external to the biofilm, and may be related to the presence of diatoms which are locally closely associated with the spar-rhombs, although an essentially inorganic origin, particularly for the more euhedral rhombs, cannot be ruled out. In the older Quaternary travertines, the original microfabric of the shrubs has been diagenetically altered. The original mottled appearance of the shrubs has become uniformly dark and micritic, and the evidence for the dual micritic and spar-rhomb origin of the shrubs is obscured or destroyed. Spar-micritization of the shrubs is probably due to abiotic, and locally biotic, dissolution. Previous studies did not recognize the diagenetic micritization and attributed shrub formation entirely to bacterial activity.     

安徽无为-巢湖地区中下二叠统碳酸盐岩成岩作用

成岩作用控制孔隙演化,对油气开采具有重要的指示作用.安徽无为-巢湖地区中下二叠统碳酸盐岩广泛发育,有机质丰富,多年来主要集中在地层、古生物及沉积相方面的研究,成岩作用的工作较少.镜下鉴定显示研究区发育溶解作用、去白云化作用、压溶作用、破裂作用4种主要的建设性成岩作用和泥晶化作用、压实作用、胶结作用、白云化作用、硅化作用...     

Loess sedimentation in Tibet: provenance,processes, and link with Quaternary glaciations

Well-preserved loess deposits are found on the foothills of mountains along the middle reaches of the Yarlung Zangbo River in southern Tibet. Optically stimulated luminescence (OSL) dating is used to determine loess ages by applying the single-aliquot regeneration technique. Geochemical, mineralogical, and granulometric measurements were carried out to allow a comparison between loess from Tibet and the Chinese Loess Plateau. Our results demonstrate that (i) the loess deposits have a basal age of 13–11 ka, suggesting they accumulated after the last deglaciation, (ii) loess in southern Tibet has a “glacial” origin, resulting from eolian sorting of glaciofluvial outwash deposits from braided river channels or alluvial fans by local near-surface winds, and (iii) the present loess in the interior of Tibet has accumulated since the last deglaciation when increased monsoonal circulation provided an increased vegetation cover that was sufficient for trapping eolian silt. The lack of full-glacial loess is either due to minimal vegetation cover or possibly due to the erosion of loess as glaciofluvial outwash during the beginning of each interglacial. Such processes would have been repeated during each glacial–interglacial cycle of the Quaternary.     

碳酸盐岩成岩作用与层序地层学关系研究--以鄂尔多斯盆地寒武系为例

本文从准同生成岩作用、成岩作用类型及其强度、成岩环境演化等方面探讨了成岩作用与海平面升降、层序地层学的关系。研究指出,准同生期成岩作用反映海平面升降、层序界面的形成最敏感;成岩作用的类型及其成岩强度反映了海平面升降幅度、层序边界的类型：体系域的演化控制了成岩环境的演化,不同的体系域其成岩作用类型及其组合不同。成岩作用研究在白云岩地层中对层序边界及其类型的识别、体系域的划分具有重要的意义。     

Carbonate deposition in a fluvial tufa system: processes and products (Corvino Valley – southern Italy)

In a multi‐scale approach to the study of the organic and mineral components in an active barrage‐type tufa system of southern Italy, neo‐formed deposits, in both natural depositional sites and on inorganic substrates placed in the stream for this study, were observed and compared through one year of monitoring. Dams and lobes representing the basic morpho‐facies of the deposits are composed of two depositional facies: vacuolar tufa (a mixture of phytoclastic and framestone tufa) and stromatolitic tufa (phytoherm boundstone tufa). Three petrographic components comprise both facies: micrite and microsparite, often forming peloidal to aphanitc, laminar and dendrolitic fabrics, and sparite, which occurs as isolated to coalescent fan‐shaped crystals forming botryoids or continuous crusts. All fabrics occurring in all depositional facies are organized into layers with a more or less well‐developed cyclicity, which has its best expression in stromatolitic lamination. The precipitation of all types of calcite (with Mg 1·0 to 3·2 mole % and Sr 0·5 to 0·8 mole %) takes place more or less constantly during all seasons, in spite of the low saturation state of the water (the saturation index range is 0·75 to 0·89) within the active depositional zone; the latter extends for a few hundred microns through the external surface of the deposit. The active depositional zone has a particular micro‐morphology composed of porous micro‐columns (50 to 150 μm in size), separated by interstitial channels. Mineral precipitation occurs upon both external surfaces and within internal cavities of the micro‐columns, while further point sites of precipitation occur suspended within the masses of cyanobacterial tufts. Sub‐spherical mineral units, ‘nano‐spheres’ (10 to 20 nm in diameter) are the basic biotic neo‐precipitate; they commonly form by replacing non‐living degrading organic matter and at point sites along the external surface of living cyanobacterial sheaths. Nano‐spheres agglutinate to form first rod‐shaped aggregates (100 to 200 nm) which then evolve into triads of fibres or polyhedral structures. Successively, both triads and polyhedral solids coalesce to form larger calcite crystals (mainly tetrahedrons tens of microns in size) that represent the fundamental bricks for the construction of the micro‐columns in the active depositional zone. Precipitation is attributed to the presence of a widespread biofilm that occurs in the active depositional zone; this is composed of a heterogeneous community comprising epilithic and endolithic filamentous cyanobacteria, green algae, unicellular prokaryotes, actinobacteria and fungi, with a variable amount of extracellular polymeric substances. No precipitation takes place where the biofilm is absent, indicating that the biological activities of the biofilm are crucial, with its living organisms and non‐living organic matter. Basic aggregates of neo‐precipitates do not form in association with any one particular type of organic matter substrate, but appear to be related to the seasonal temperature variation: polyhedral micro‐crystals mainly precipitate in the colder season, short triads in the intermediate seasons, and long triads in the warmest conditions. These three basic crystal aggregates have a petrographic counterpart, respectively, in the spar, microspar and micrite.     

Australian dust deposits: modern processes and the Quaternary record

Dust raising and transport are common and important processes in Australia today. The aridity of the Australian continent and high climatic variability result in widespread dust raising in the arid and semi-arid areas and transport to the humid margins and surrounding oceans. The supply of erodible particles appears to be the greatest limitation on total flux of transported dust. Dust raising is greatest in the Lake Eyre Basin, including the Simpson Desert, and Murray-Darling Basin where internal drainage renews supplies of fine particles to the arid zone. In the west and northwest dust entrainment is low, despite considerable aridity. The marine record of dust flux shows at least a threefold increase in dust flux, compared with the Holocene, in the last glacial maximum in both tropical and temperate Australia, driven by weakened Australian monsoon rains and drier westerly circulation, respectively. Despite the widespread confirmation of aeolian dust deposits in southeastern and southwestern Australia, dated or quantified records are extremely rare. The dominant model of Australian dust deposits, the clay-rich ‘parna’, is shown to be poorly substantiated while modern and ancient dust deposits examined in detail are shown to bear a strong similarity to conventional definitions of loess.     

Effects of differential tectonic uplift on Late Quaternary coral reef diagenesis,Huon Peninsula,Papua New Guinea

Mineralogical, petrological and geochemical analyses of corals and associated skeletal limestones taken from three transects across the Late Quaternary raised coral reefs of the Huon Peninsula, Papua New Guinea, show that tectonic uplift can be related to the degree of subaerial diagenesis of the reefs. Where the uplift rate is high, Pleistocene corals frequently retain their aragonite mineralogy, even though the annual rainfall is relatively high. In contrast, similar age corals from low‐uplift areas are consistently altered neomorphically to calcite. The transformation of reef skeletal limestones shows a similar, but less pronounced, trend to the corals. Chemical analysis shows that the neomorphic calcite crystals of coral skeletons from the low‐uplift areas have relatively higher Sr and Mg concentrations, compared with those in high‐uplift areas. This may indicate that neomorphism of corals in the low‐uplift terraces takes place at a relatively higher rate and an earlier stage than that in the high‐uplift areas. The pattern of diagenesis of the Huon reefs can be explained by the effects of tectonic uplift on the regional hydrological regime. First, lower uplift rates allow a raised reef or any part of it to remain in the meteoric phreatic zone for a relatively long time. Second, river gorge slopes from low‐uplift regions have lower gradients and reef terraces in these areas have more extensive raised lagoon depressions than in high‐uplift areas. Thus, there is less runoff and consequently more extensive vadose percolation in the former areas. Third, the resulting low‐relief topography in low‐uplift areas prompts formation of soils on the terraces, and further increases the ability of interaction between coral reefs and formation water.     

Relative ages of loess and till in two Quaternary palaeosols in Gorges Valley,Mount Kenya,East Africa

Two compound palaeosol profiles formed in loess and till were studied in the oldest early Quaternary end moraine (Gorges age) system on Mount Kenya. Although both tills appear to have similar weathering histories, the overlying loessic sediments, serving as secondary parent materials for the palaeosols, are considered to have different ages on the basis of colour, presence or absence of clay films, and field texture (especially percentage of silt). Palaeomagnetic determinations showed both tills to have reversed remanent magnetism, suggesting that they were emplaced during the Matuyama Chron. The overlying loessic sediments in profiles GOR55 and GOR58 show normal magnetism and grade upward into the lower zone of bioturbation in the A horizon complex. However, in GOR58 the surface loessic sediments have normal remanent magnetism with considerable secular variations, suggesting it was emplaced over a longer time frame during the Brunhes Chron (i.e. < 0.78 Ma). Profile GOR55 contains larger amounts of gibbsite, indicating more aggressive leaching over time, and an absence of secular magnetic variations suggests deposition over a shorter time interval. The study of volcanic feldspars and ash, using scanning electron microscopy, in the two profiles, shows that sand grain (63–250 μm) weathering is slightly different in the two tills; relative weathering effects (e.g. corrosion of grain surfaces and neoformation of clay minerals) are greater in profile GOR55 than in profile GOR58. Overall the data indicate that some sites in the lower tropical Afroalpine timberline environment may have aeolian covers that are considerably younger than the deposits they overlie. © 1997 by John Wiley & Sons, Ltd.     

Quaternary slope processes and morphologies in the upper Sehonghong Valley, eastern Lesotho

Several high south-facing slopes in the southern Drakensberg were glaciated during the Late Quaternary, yet little is known about the slope geomorphic history on equally high slopes that appear not to have been glaciated. To this end, we examine evidence for Late Quaternary slope dynamics in a high alpine valley of eastern Lesotho, with particular attention given to palaeo-environmental signatures offered by deep colluvial mantles along the flanks of the Sehonghong River and pronival ramparts along the upper southerly-facing slopes of the adjoining Thabana-Ntlenyana. Sedimentary exposures were mapped and sampled for clast fabric, clast shape, organic matter content, granulometry and ¹⁴C age determination. Similarly, a pronival rampart was mapped and clast size, shape and fabric determined for various micro-topographic settings. A palaeosol beneath the rampart was also Radiocarbon dated. Findings suggest that the deep and extensive debris mantles on lower south-facing slopes are a product of prolonged colluviation, whilst the more stratified sequences on north-facing slopes indicate greater slope geomorphic-process variability over time. Radiocarbon ages suggest sediment accumulation along the north-facing exposure from at least ∼43 ka. It is proposed that snowcreep and snowpush on high (>3400 m a.s.l.) southeast-facing slopes during a relatively cold, yet moist period at ∼AD 300-1000 initiated boulder movement to form the pronival ramparts.     

Micro-environmental controls on biomineralization: superficial processes of apatite and calcite precipitation in Quaternary soils, Roussillon, France

Calcium hydroxyapatite and calcite precipitates around bacteria were observed in 2-week-old alluvial topsoil (Roussillon area, SE France). This observation prompted a laboratory study of Ca²⁺ and PO₄³⁻ incorporation into hydroxyapatite and Ca²⁺ into calcite mediated by bacteria using similar topsoil material, but free from apatite and calcite. Subsamples were prepared using three different grain sizes, and experiments were undertaken using sucrose and different contents of Ca²⁺ and PO₄³⁻. Mineralization experiments proceeded over 5 days. Calcium and PO₄³⁻ sorption onto clay influenced the Ca/P ratio in the solutions. Hydroxyapatite and calcite precipitation only occurred in unsterilized samples. The presence of clay minerals promoted biomineralization.     

西沙群岛晚第四纪碳酸盐岩淡水成岩作用

基于西沙永兴岛上最新钻孔（SSZK1）取得的55.92 m岩芯的 U?Th定年、矿物、薄片、主微量元素及碳氧稳定同位素等资料,开展了西沙群岛晚第四纪碳酸盐岩沉积相和淡水成岩作用的研究。根据不同的矿物组成特征,可将SSZK1钻孔岩芯分为上、中、下三段: 下 段（33.89~55.92 m,主要为低镁方解石）、中 段（18.39~33.89 m,主要为文石和低镁方解石）、上段（0~18.39 m,主要为文石、高镁方解石和低镁方解石）。由于下段碳酸盐岩几乎全为稳定的低镁方解石组成,碳氧同位素值的严重负偏和小幅度变化,可推断其经历了程度较大的淡水成岩作用。中段和上段还存在不稳定的文石和高镁方解石,碳氧同位素值相对下段正偏和高幅高频变化,推测其淡水成岩作用的程度比下段要小。中段碳氧同位素值高幅高频变化同时也说明该段的矿物纵向变化较复杂。这种矿物组成的复杂变化可能是由于晚第四纪海平面频繁变化,该段被大气水渗流带和潜流带交替占据引起的。主微量元素的变化同时受到淡水成岩作用和沉积环境的影响。在中段、下段中可识别出sq1、sq2、sq3、sq4四个完整的相旋回。Na₂O,S,Sr 和碳氧同位素受到的淡水成岩作用而被消耗和负偏,且由于老一期的旋回经历了更长时间的淡水成岩作用,新、老旋回间的 Na₂O,S,Sr含量值和碳氧同位素值有明显差异。利用新、老时期形成的旋回间淡水成岩作用剩余Na₂O,S,Sr含量和碳氧同位素值的差别可以将新、老两个旋回区分开来。     

五大连池第四纪火山岩层序划分及其构造与生态意义

大量前人成果和1:5万区调钻孔资料证实,五大连池第四纪火山地层属于水平岩层.因此,该地区第四纪火山地层的划分,是在地表岩石层序与钻孔岩石层序充分划分与对比的基础上进行的.从沉积角度看,五大连池火山地层属于松嫩盆地连续沉积过程中的第四纪短暂幕式火山喷发所形成的水平岩层.本文结合K-Ar同位素测年新资料,将该区第四纪岩石地层重新划分为11个组级地层单位.其中的火山岩石地层可以自下而上划分为:下更新统焦得布玄武岩(1.214—1.113 Ma);中更新统尾山玄武岩(0.62—0.285 Ma);中更新统笔架山玄武岩(0.24—0.132 Ma)和全新统老黑山玄武岩(距今290～288 a),对夹于其间的正常沉积地层也进行了相应的划分.对层状火山岩层序的层位划分和空间分布研究对于理解五大连池火山群的构造背景和生态环境具有特别重要的意义,五大连池火山群处于中国大陆内部的大同—大兴安岭火山岩带的最北东端,是地幔流体向北东方向流动的最前缘;这类富钾的碱性玄武岩的火山喷发活动对东北富饶的黑土地的形成具有重要贡献,火山岩在嫩江平原上塑造的台地和火山锥地形地貌对生态多样性和优质地下水的生态要素具有重要影响.     

Distribution of arsenic and mercury in subtropical coastal beachrock,Gulf of Mannar,India

An assessment of coastal pollution was made on the basis of trace element concentrations (arsenic — As, mercury — Hg) in the Gulf of Mannar. The beachrock samples were collected along the coastal tracts between Rameswaram and Kanyakumari. The samples were dried and digested to determine the As and Hg using atomic absorption spectrophotometer (AAS-air-acetylene and nitrous oxide method). The As and Hg accumulation status of the beachrock was assessed using geo-accumulation index values (I _geo). The accumulation of As and Hg in the beachrock ranges from 2.75 to 20.72 μg g⁻¹ and from 0.06 to 0.31 μg g⁻¹, respectively. The As and Hg concentrations in the beachrocks are compared with crustal average values and average of other region sediments. The possible source of the contamination is from atmospheric deposition and anthropogenic activities.     

天山托木尔河流域第四纪冰川沉积序列及其初步年代学

谷冰川,规模最盛时冰川长分别为47 km、60 km、≥70 km.     

Quaternary sediment dynamics in the Belgica mound province,Porcupine Seabight: ice-rafting events and contour current processes

The Belgica cold-water coral banks on the eastern slope of the Porcupine Seabight are closely associated with bottom currents. In order to better understand the local temporal and spatial characteristics, as well as the palaeoclimatologic influences, a 26 m long core, taken on a small contourite drift, was studied. This sediment record of approximately 100 ka BP reveals new insights into the regional glacial and sedimentary processes, which are intrinsically linked to several geological, climatological, biological and hydrodynamic variables. The glacial sequences in the core contain six ice-rafting events (IRE). They are comparable with the North Atlantic Heinrich Events, although their characteristics show dominant influences from the proximal British–Irish Ice Sheet (BIIS). These IRE have a low magnetic susceptibility and are deposited during two or three ice-rafting pulses. The record of ice-rafting suggests a millennial-scaled BIIS destabilisation and confirms the start of a final retreat about 25 ka ago. Additionally, the glacial sequence corresponds to a muddy contourite, influenced by bottom-current strength variations during interstadials, possibly triggered by sporadic reintroductions of Mediterranean Outflow Water in a glacial North Atlantic Ocean. The interglacial sequence features an 11-m thick deep-water massive sand unit, probably deposited under a high-energy bottom-current regime.