Geochemistry of Cretaceous mafic rocks from the Lower Yangtze region, eastern China: Characteristics and evolution of the lithospheric mantle

Geochemical and isotopic data for Cretaceous mafic rocks (basalt, gabbro, and diorite) from the Lower Yangtze region, northern Yangtze block, constrain the evolution of the lithospheric mantle. The mafic rocks, separated into the northeast and southwest groups, are alkaline and evolved, with low Mg# values (44–58) and variable SiO₂ contents (47.6–57.4 wt%). Enriched LREEs, LILEs, and Pb, together with depleted Nb, Zr, and Ti, suggest that the mantle sources were metasomatized by slab-derived fluid/melt. All samples show high radiogenic ²⁰⁷Pb/²⁰⁴Pb(t) (15.41–15.65) and ²⁰⁸Pb/²⁰⁴Pb(t) (37.66–38.51) ratios at given ²⁰⁶Pb/²⁰⁴Pb(t) (17.65–19.00) ratios, consistent with the mantle sources having been metasomatized by ancient slab-derived material. Mafic rocks of the southwest group show enriched Sr–Nd isotopic characteristics, with ⁸⁷Sr/⁸⁶Sr(t) ranging from 0.7056 to 0.7071 and ε_Nd(t) ranging from −5.3 to −8.3, indicating an origin from enriched lithospheric mantle. Mafic rocks of the northeast group, which record ⁸⁷Sr/⁸⁶Sr(t) ratios of between 0.7044 and 0.7050 and ε_Nd(t) of −2.8 to −0.7, possibly formed by the mixing of melts from isotopically enriched lithospheric mantle and isotopically depleted asthenospheric mantle. Taking into consideration the geochemical and isotopic characteristics of Cretaceous mafic rocks, Cenozoic basalts, and basalt-hosted peridotite xenoliths from the Lower Yangtze region, we propose that an isotopically enriched, subduction-modified lithospheric mantle was replaced by or transformed into an isotopically depleted “oceanic-type” mantle. Such a process appears to have occurred in the eastern North China Craton as well as the eastern Yangtze block, probably in response to subduction of the paleo-Pacific plate beneath East Asia.     

大别-苏鲁地区晚中生代镁铁质岩地球化学对造山带岩石圈地幔性质的约束

来自大别-苏鲁地区晚中生代镁铁质岩石表现出类似于岛弧火山岩的富集大离子亲石元素（LILE）、轻稀土元素（LREE）和相对亏损高场强元素（HFSE）的微量元素地球化学特征,和高度富集的放射成因Sr（ISr：0．7065～0．7090）和低放射成因Nd（εNd（t）=-19～-10）的同位素组成;同时它们显示出一定程度的Nb／Ta和Zr／Hf内部分馏特征,反映其地慢源区曾受到了相对富金红石和CO2的熔体交代作用。我们倾向认为深俯冲陆壳在俯冲或折返过程中发生部分熔融作用形成的熔体与地幔反应是形成大别-苏鲁地区造山带富集岩石圈地幔的重要机制。     

Geochemistry of mafic igneous rocks of the northern Prince Charles Mountains,Antarctica

Rare mafic dykes, which intrude 1000 Ma high‐grade metamorphic rocks of the northern Prince Charles Mountains‐Mawson Coast area, are compositionally distinct from abundant early to middle Proterozoic tholeiite dykes, which are confined to Archaean or early Proterozoic terrains in the southern Prince Charles Mountains and elsewhere in East Antarctica, and which have therefore proved useful as stratigraphic markers. The younger dykes (and extrusive rocks) are a composition‐ally heterogeneous group with a wide range of ages (at least Cambrian to Eocene), although most are of K‐rich alkaline composition or have alkaline affinites. Their strong enrichment in highly incompatible elements (Rb, Ba, Th, Nb, K, Pb, Th and U) relative to less incompatible elements (La, Ce and P) suggests derivation by partial melting of more enriched mantle source regions than those of most of the Proterozoic tholeiite suites. However, unlike the latter, many incompatible element ratios have been significantly affected by fractional crystallisation and possibly also by the presence of residual minor phases during low degrees of melting.     

Geochemistry of peridotites and mafic igneous rocks from the Central Dinaric Ophiolite Belt,Yugoslavia

In the Central Dinaric Ophiolite Belt (CDOB) peridotites and associated metamorphic rocks of various grades tectonically overlie an olistostrome melange of middle to late Jurassic age. Peridotites and underlying slices of mafic granulites (partially transformed to gamet amphibolites) are intruded by doleritic dikes which do not occur in the melange. The melange contains blocks of subgreywackes and cherts as well as those of pillow lavas and massive diabase (spilites). CDOB peridotites are in the spinel peridotite facies, but locally spinel-plagioclase peridotites occur as well. All peridotites have lherzolitic compositions showing several significant element correlations: Al₂O₃, CaO, TiO₂, Na₂O and Cu are negatively correlated and Ni is positively correlated with MgO. Recent estimates of primitive mantle compositions lie near the low-MgO end point of each correlation trend. Al/Ti and Ca/Al ratios of CDOB lherzolites are for the most part higher than the range observed in chondrites. However, when a few samples with extreme compositions are excluded, Al/Ti and Ca/Al are positively correlated with MgO, and the samples at the low-MgO end have near-chondritic Ca/Al but slightly higher than chondritic Al/Ti ratios. Chondrite-normalized REE patterns of CDOB lherzolites show extreme depletions in LREE providing strong evidence for the absence of any metasomatic renrichment. The lack of correlation between highly incompatible elements (LREE) and moderately incompatible elements (HREE, Ti, Na, Al, Ca) together with the extremely low La/Sm ratios suggest that fractional or very small increment melt removal played a role in the genesis of these lherzolites. Four out of five lherzolites yield and apparent Sm-Nd isochron age of 136±15 Ma with an Nb of 6.0±1.1 (bulk rocks and clinopyroxene separates). One sample has an exceptionally high Nd of about 23. The mafic igneous rocks scatter around the lower end of the 136 Ma reference isochron allowing, but not proving, a genetic relationship with a mantle having a Nd isotopic composition which is similar to that of CDOB lherzolites. LIL element abundances of spilites and doleritic dike rocks suggest some hydrothermal alteration. In primitive mantle-normalized concentration diagrams none of these mafic igneous rocks shows a significant negative Nb-Ta anomaly. Chondrite-normalized REE patterns of both rock types are essentially flat. Whereas the inferred primary compositions of the spilites compare well with those of E-type MORBs, the doleritic dike rocks show elemental ratios similar to those normally found in back-arc basin tholeiites.     

Geochemistry and geochronology of mafic rocks from the Spanish Central System:Constraints on the mantle evolution beneath central Spain

The Spanish Central System(SCS) contains several suites of Palaeozoic mafic igneous intrusions with contrasting geochemical affinity:Ordovician tholeiitic metabasites,Variscan calc-alkaline gabbros(Gb1) and microdiorites(Gb2),shoshonitic monzogabbros(Gb3) and alkaline diabases and lamprophyres(Gb4).Not all of these rocks are accurately dated,and several aspects of their genesis are still poorly understood.We present new whole-rock geochemical data(major and trace elements,and Sr-Nd isotopes),U-Pb and Lu-Hf isotopic ratios on magmatic zircons and 40 Ar/~(39)Ar amphibole geochronology results in order to establish a precise chronology for the successive events of magmatism in the SCS,and discuss the nature of their mantle sources.Accurate ages have been determined for the Variscan gabbros(305-294 Ma),the microdiorites(299 Ma) and the accompanying felsic porphyries(292 Ma),the shoshonitic monzogabbros(285 Ma),and the alkaline diabases(274 Ma) and monzosyenites(271-264 Ma).According to this information,the Variscan mafic magmatism would be mainly concentrated in the range of 305-294 Ma,with a final manifestation represented by the minor shoshonitic dykes.The alkaline magmatism proved to be slightly older than previously thought and yielded at least two distinct pulses:diabases and lamprophyres-monzosyenites.Zircon Hf isotopes evidence the involvement of depleted and slightly enriched mantle sources.The bulk of the eHf values are in the broad range of-8 to+11,indicative of melting both depleted and enriched mantle regions.The high within-sample Hf isotope variation(up to-11 epsilon units) shown by samples from the Variscan series(gabbros,microdiorites and monzogabbros) could be explained mainly by hybridisation of magmas derived from heterogeneous lithospheric mantle sources.Pressure estimates indicate that the Variscan mafic magmas were extracted from the lithosphere.The Nd-Hf isotopic composition of these suites of rocks suggests the recycling of pelitic sediments during the Cadomian orogeny.Deeper(asthenospheric) mantle levels were involved in the generation of the alkaline suite,whose anomalous negative eHf values(moderately decoupled with respect to radiogenic Nd) could be associated with subducted oceanic components raised by mantle upwelling associated with lithosphere thinning and extension during the Permian.     

吉林晚古生代榆木川基性岩的地球化学特征及其岩石成因

位于兴蒙造山带张广才岭块体的榆木川辉绿玢岩,K—AT年龄测定表明其形成年龄为262～264Ma,主微量元素研究表明,辉绿玢岩SiO2含量为47.02％～52.60％,贫K2O（0.13％～0.47％）,Na2O〉K2O,属于低钾拉斑系列,稀土分布模式属于轻稀土略亏损的平坦型,微量元素原始地幔标准化图解中大离子亲石元素（Rh、Ba、Sr）较为富集,但不存在高场强元素（Nb、Ta）的亏损,同位素组成显示Sr同位素初始比值在0.704958～0.705631之间,εNd（t）值（72～81）较高且变化较小,表明其来源于亏损地幔的部分熔融且成岩过程中未受到地壳物质的混染。基性岩形成于造山后的伸展拉张背景,并结合前人的研究成果,认为晚古生代（约270Ma）兴蒙造山带已经进入晚期,此时加厚的岩石圈由于重力不稳定发生拆沉减薄作用,导致软流圈的大量上涌和岩石圈拉张,从而引起先存亏损岩石圈地幔的部分熔融,最后侵入地壳深部形成研究区辉绿玢岩。     

新疆西准噶尔达拉布特蛇绿岩E-MORB型镁铁质岩的地球化学、年代学及其地质意义

新疆西准噶尔地区是古生代经过俯冲-增生形成的复合造山带,该地区分布有多条蛇绿岩带,其中之一的西准噶尔达拉布特蛇绿岩被认为是最大的一条蛇绿岩带,可能代表了古亚洲洋壳的残余。本文的资料显示蛇绿岩带内的镁铁质岩呈现出N-MORB、E-MORB和似OIB的地球化学特征,通过对阿克巴斯套岩体中的浅色辉长岩LA-ICP-MS锆石年龄测定,获得达拉布特蛇绿岩E-MORB型镁铁质岩的年龄为302±1.7Ma。鉴于达拉布特蛇绿岩中E-MORB和似OIB型镁铁质岩成因的复杂性,结合前人研究成果,对辉长岩锆石U-Pb年龄所代表的意义存在两种可能性：（1）E-MORB型和似OIB型镁铁质岩可能是弧后盆地扩张后期的产物,代表蛇绿岩的年龄,其表明西准噶尔地区可能晚石炭纪还有洋盆存在;（2）E-MORB型镁铁质岩是蛇绿岩消亡阶段由于扩张脊和俯冲带碰撞作用而形成的弧前海山,形成时代晚于达拉布特主体蛇绿岩,但其成因与蛇绿岩的演化密切相关。本文侵向于第二种可能性,认为新疆北部晚石炭-早二叠可能仍存在活动陆缘,俯冲作用仍然存在,扩张脊俯冲形成的板片窗效应导致地幔楔、俯冲板片和沉积物等熔融促使基性岩浆向长英质酸性岩浆转变,从而引发了二叠纪大规模玄武质岩浆底侵,导致了该时期的构造-岩浆-成矿-造山作用的发生。     

巴楚辉绿岩墙的岩石成因及其对塔里木大火成岩省岩浆演化的启示

早二叠世塔里木大火成岩省主要有两期岩浆活动:以柯坪玄武岩为代表的喷出岩形成较早(~290Ma),以巴楚超基性-基性-长英质侵入体和岩墙为代表的侵入岩形成较晚(~280Ma)。本研究选取代表晚期岩浆活动的巴楚辉绿岩墙为研究对象,旨在为认识塔里木地幔柱活动及与岩石圈的相互作用提供更多信息。巴楚辉绿岩XHZ-10样品中的锆石均为继承性锆石,不能用来限定其侵位时代。然而,野外关系表明巴楚辉绿岩墙属于塔里木大火成岩省的第二期岩浆活动。巴楚辉绿岩墙经历了橄榄石、辉石和磁铁矿的分离结晶。Nd同位素比值与SiO₂和La/Nb比值的相关性以及继承性锆石年龄(2480~717Ma,主要集中在~800Ma)表明,新元古代基底的同化混染作用可以解释其ε_Nd具有较大的变化范围(-2.6~+5.1)。受混染程度最小的样品具有与洋岛玄武岩(OIB)极其相似的微量元素特征,并且具有亏损的Nd同位素组成(ε_Nd=~+5),暗示其来源于富集的对流地幔源区,与早期(~290Ma)具有岩石圈地幔源区特征的玄武岩形成鲜明对比。本文提出地幔柱侧向流动模型以解释两期岩浆的时空分布和地球化学差异:当地幔柱上升至塔里木岩石圈底部时,巨厚的岩石圈地幔(>140km)会阻碍其减压熔融;但不断积累在岩石圈底部的地幔柱物质提供足够的热,促使早期富集交代的岩石圈地幔发生部分熔融,形成~290Ma的玄武岩;地幔柱物质将向岩石圈厚度较薄的边缘地区侧向流动,发生减压熔融,形成的熔体侵位到地壳中形成超基性-基性-长英质侵入岩和辉绿岩墙,并诱发地壳的熔融形成长英质火山岩。     

Geochemistry of peridotites from the Yap Trench,Western Pacific: implications for subduction zone mantle evolution

ABSTRACT

This study examines the major and trace elements of peridotites from the Yap Trench in the western Pacific to investigate mantle evolution beneath a subduction zone. Major element results show that the peridotites are low in Al₂O₃ (0.31–0.65 wt.%) and CaO (0.04–0.07 wt.%) contents and high in Mg# (Mg/(Mg+Fe)) (0.91–0.92) and have spinels with Cr# (Cr/(Cr+Al)) higher than 0.6 (0.61–0.73). Trace element results show that the peridotites have extremely low heavy rare earth element (HREE) contents compared with abyssal peridotites but have U-shaped chondrite-normalized rare earth element (REE) patterns. The degree of mantle melting estimated based on the major elements, HREEs, and spinel Cr# range from 19% to 25%, indicating that the Yap Trench peridotites may be residues of melting associated with the presence of water in the mantle source. In addition to light rare earth element (LREE) enrichment, the peridotites are characterized by high contents of highly incompatible elements, positive U and Sr anomalies, negative Ti anomalies, and high Zr/Hf ratios. The correlations between these elements and both the degree of serpentinization and high field strength element (HFSE) contents suggest that fluid alteration alone cannot account for the enrichment of the peridotites and that at least the enrichment of LREEs was likely caused by melt–mantle interaction. Comparison between the peridotites and the depletion trend defined by the primitive mantle (PM) and the depleted mantle (DM) suggests that the Yap Trench mantle was modified by subduction-related melt characterized by high contents of incompatible elements, high Zr/Hf ratios, and low HFSE contents. Hydrous melting may have been enhanced by tectonic erosion of the subducting Caroline Plate with complex tectonic morphostructures at the earliest stages of subduction initiation.     

Geochronology, geochemistry and petrogenesis of mafic and ultramafic rocks from Southern Beishan area, NW China: Implications for crust–mantle interaction

The Liuyuan mafic and ultramafic rocks are exposed in Southern Beishan, which is along the southern branch of the Central Asian Orogenic Belt (CAOB). Zircon SHRIMP U–Pb dating showed that Liuyuan gabbros intruded during the early Permian (~ 270–295 Ma) coeval with the basalts and the ultramafic rocks were emplaced at about 250 Ma. The basalts are within–plate tholeiites with slight enrichment in light rare earth elements (LREE) relative to heavy rare earths (HREE) and small negative anomalies of Nb and Ta. Gabbros including olivine gabbros, olivine gabbronorites and troctolites are grouped into two: the cumulate gabbros are depleted in LREE and show small negative Nb and Ta anomalies but distinct positive Sr and Eu anomalies; non–cumulate gabbros resemble tholeiitic basalts. Lamprophyres and cumulate ultramafic rocks are characterized by large enrichment of LREE relative to HREE with depletion in Nb and Ta. The enriched Sr–Nd isotopic trend from DM towards the EM II end member component implies that the lithospheric mantle was progressively enriched with depth by the involvement of subducted crustal material due to the delamination of thickened mantle lithosphere after collision. The digestion of subducted crustal material into the mantle resulting in the metasomatized and enriched mantle is inferred to be an important process during crust–mantle interaction.     

Geochemistry of mafic dikes in the Adirondack mountains: implications for late Proterozoic continental rifting

Mafic dikes of late Proterozoic age which cut Grenvillian crust in the northeastern Adirondack Mountains are mostly mildly alkaline basalts except for a few tholeiitic examples. All dikes are high in Ti, P, K, Zr, Y, and LREE, and plot in within-plate fields on tectonic discriminant diagrams. The dikes are similar in composition to Hudson Highland dikes in southern New York and New Jersey and to the Bakersville dike swarm in the southern Appalachians. They differ from the Grenville dike swarm in Ontario and Quebec in being alkaline and having higher Ti and P contents. Mesozoic alkaline dikes in the same geographic area as the Proterozoic ones are strongly enriched in Ba, K, Rb and LREE, and approach lamprophyre in composition. The Proterozoic dikes have low La/Nb and La/Ta ratios, suggesting that subduction-modified mantle lithosphere was not substantially involved in their genesis. This contrasts with certain Mesozoic tholeiitic dikes, associated with the opening of the Atlantic, which show sharp negative Nb or Ta anomalies relative to La indicating they were derived from subduction-modified lithospheric mantle. The trace element chemistry suggests that the source for the Proterozoic dikes was trace element-enriched asthenosphere (OIB-like source), as postulated for certain basalts erupted in the East African Rift system, and in parts of the Basin and Range Province of the southwestern United States of America. Finally, the Proterozoic dikes are chemically similar to rift volcanics from the western Vermont Appalachians, and thus they are thought to represent magmatism associated with extension of the Grenvillian crust prior to opening of the Iapetus ocean.     

Platinum-group element geochemistry of mafic rocks from the Dongchuan area,southwestern China

Mafic intrusions and dykes are well preserved in the Yinmin and Lanniping districts, located within the western margin of the Yangtze Block, SW China. Although these mafic rocks from the two areas formed during different periods, they share similar ranges of PGE concentration. Most of the Yinmin gabbroic dykes contain relatively high PGE concentrations (PGEs = 13.9–87.0 ppb) and low S contents (0.003 %–0.020 %), higher than the maximum PGE concentrations of mafic magmas melting from the mantle. Two exceptional Yinmin samples are characterized by relatively low PGE (PGEs = 0.31–0.37 ppb) and high S (0.114 %–0.257 %) contents. In contrast, most samples from the Lanniping gabbroic intrusion have low PGE concentrations (PGEs = 0.12–1.02 ppb) and high S contents (0.130 %–0.360 %), except that the three samples exhibit relatively high PGE (PGEs = 16.3–34.8 ppb) and low S concentrations (0.014 %–0.070 %). All the Yinmin and Lanniping samples are characterized by the enrichment of PPGE relative to IPGE in the primitive-mantle normalized diagrams, and the high-PGE samples exhibit obvious Ru anomalies. This study suggests that during the ascent of the parental magma, removal of Os–Ir–Ru alloys and/or chromite/spinel leads to high Pd/Ir ratios and Ru anomalies for the Yinmin high-PGE samples and relatively lower Pd/Ir ratios and Ru anomalies for the Lanniping low-PGE samples. We propose that the magmas parental to the Yinmin gabbroic dykes are initially S-unsaturated, and subsequently, minor evolved magma reached sulfur saturation and led to sulfide segregation. Although the Lanniping parental magmas are originally not saturated in S, the high Cu/Pd ratios (3.8 × 10⁴ to 3.2 × 10⁶) for most of the Lanniping samples indicate the S-saturated state and sulfide segregation. A calculation shows that the PGE-poor magmas might have experienced 0.01 %–0.1 % sulfide segregation in the magma chamber. Therefore, our study provides a possible opportunity to discover PGE-enriched sulfide mineralization somewhere near or within the Lanniping mafic intrusion.     

新疆阿舍勒盆地泥盆纪火成岩与构造-岩浆演化

阿舍勒泥盆纪火山盆地是阿尔泰西南缘重要的矿集区,产出我国著名的火山成因块状硫化物型(VMS)矿床——阿舍勒铜矿.其内部发育的火山岩和侵入岩地球化学特征记录了阿舍勒盆地的构造岩浆演化和成岩、成矿作用过程,但其形成构造背景和成岩成矿机制一直存在争论.本文报道了阿舍勒矿集区萨尔朔克铜金多金属矿区深部英云闪长岩的LA-MC-I...     

Geological Implications for the Deep-Derived Mafic Enclaves from Cenozoic Shoshonitic Rocks in Jianchuan-Dali Area,West Yunnan

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新疆三塘湖盆地古生代晚期火山岩地球化学特征及其构造-岩浆演化意义

三塘湖盆地早石炭世安山岩（ECA）、早二叠世粗面岩类（EPT）以及中二叠世玄武岩（MPB）样品都具有大离子亲石元素（LILE）相对于高场强元素（HFSE）富集，Nb和Ta强烈亏损，轻稀土元素（LREE）相对于重稀土元素（HREE）富集，类似于和俯冲带相关的岩浆特征。ECA具有高的Zr／Nb（4．67～12．39），低的Nb／La（0．27～0．30），Ce／Ce＊=0．63～0．89，Sr／Sr＊=1．32．2．49，并具有Ti的负异常，另外（^87Sr／^86Sr）i=0．70408～0．70451，εNd（t）=＋7．42-＋7．88。与ECA相比，EPT大离子亲石元素更为富集，Ti和P的负异常明显，特别是Ce／Ce＊=0．72—1．64，Sr／Sr＊=0．38～1．87，相对较低的Al2O3和CaO含量以及（^87Sr／^86Sr）；=0．70414～0.70481和εNd（t）=＋4．93～＋6．13而区别于ECA。MPB与ECA相比具有较低的大离子亲石元素含量和较高的Nb、Ta含量，Ce／Ce＊=0．69～0．84，Sr／Sr＊=1、44～2．13，未有明显的Ti负异常，（^87St／^86Sr）i=0．70388～0．70396，εNd（t）=＋7．10-＋7．99。所有的地球化学特征表明：早石炭世或更早，三塘湖盆地为与俯冲带相关的构造背景，ECA是典型的弧火山岩，其岩浆主要源于被流体或沉积物交待改造的亏损地幔楔。早石炭世以后，三塘湖地区逐渐进入碰撞后伸展拉张阶段，EPT和MPB都为后造山火山岩。EPT岩浆主要源于亏损软流圈底侵前二叠纪形成的造山组分的部分熔融；MPB的岩浆主要源于亏损地幔的部分熔融，并被前二叠纪形成的造山组分或是年轻地壳混染。三塘湖地区二叠纪伸展拉张的动力学机制主要是由于造山带增厚的岩石圈大范围拆沉而导致的大范围亏损地幔部分熔融岩浆和上部造山组分或是年轻地壳的相互作用，这种造山组分或是年轻地壳具有低的（^87Sr／^86Sr），比值和正的εNd（t）值。火山岩地球化学特征指示没有明显地幔柱的作用特征。     

Secular evolution of the lithospheric mantle beneath the eastern North China craton: evidence from peridotitic xenoliths from Late Cretaceous mafic rocks in the Jiaodong region,east-central China

The Mesozoic lithospheric mantle beneath the North China craton remains poorly constrained relative to its Palaeozoic and Cenozoic counterparts due to a lack of mantle xenoliths in volcanic rocks. Available data show that the Mesozoic lithospheric mantle was distinctive in terms of its major, trace element, and isotopic compositions. The recent discovery of mantle peridotitic xenoliths in Late Cretaceous mafic rocks in the Jiaodong region provides an opportunity to further quantify the nature and secular evolution of the Mesozoic lithospheric mantle beneath the region. These peridotitic xenoliths are all spinel-facies nodules and two groups, high-Mg# and low-Mg# types, can be distinguished based on textural and mineralogical features. High-Mg# peridotites have inequigranular textures, high Mg# (up to 92.2) in olivines, and high Cr# (up to 55) in spinels. Clinopyroxenes in the high-Mg# peridotites are generally LREE-enriched ((La/Yb)_N>1) with variable REE concentrations, and have enriched Sr–Nd isotopic compositions (⁸⁷Sr/⁸⁶Sr = 0.7046–0.7087; ¹⁴³Nd/¹⁴⁴Nd = 0.5121–0.5126). We suggest that the high-Mg# peridotites are fragments of the Archaean and/or Proterozoic lithospheric mantle that underwent extensive interaction with both carbonatitic and silicate melts prior to or during Mesozoic time. The low-Mg# peridotites are equigranular, are typified by low Mg# ( < 90) in olivines, and by low Cr# ( < 12) in spinels. Clinopyroxenes from low-Mg# peridotites have low REE abundances (ΣREE = 12 ppm), LREE-depleted REE patterns ((La/Yb)_N < 1), and depleted Sr–Nd isotopic features, in contrast to the high-Mg# peridotites. These geochemical characteristics suggest that the low-Mg# peridotites represent samples from the newly accreted lithospheric mantle. Combined with the data of mantle xenoliths from the Junan and Daxizhuang areas, a highly heterogeneous, secular evolution of the lithosphere is inferred for the region in Late Cretaceous time.     

Geochronology and geochemistry of igneous rocks in the Bailingshan area: Implications for the tectonic setting of late Paleozoic magmatism and iron skarn mineralization in the eastern Tianshan,NW China

The late Paleozoic Bailingshan intrusions and volcanic rocks are located in the Aqishan–Yamansu arc belt in the southern part of the eastern Tianshan and are associated with an important group of iron skarn deposits. The exposed intrusive rocks are mainly granodiorite, monzonitic granite, and granite. Zircon U–Pb dating of the Tugutublak Formation tuffaceous dacitic lava yields an age of 324 Ma, whereas dates of the Bailingshan granodiorite, monzonitic granite, and granite yields ages of 317 Ma, 313 Ma, and 307 Ma, respectively. The results indicate that the Bailingshan granitoids were emplaced soon after the eruption of the Tugutublak dacite. All these rocks studied show calc-alkaline to high-K calc-alkaline and metaluminous affinities, with A/CNK values ranging 0.83–1.10. They are enriched in Rb, K, and Pb, depleted in Nb, Ta, Ti, and P, and contain low Sr/Y (4.16–23.7) and Sr (109.0–347.0 ppm) values, displaying typical arc geochemical affinities. The tuffaceous dacitic lava has low Nb/Ta (10.3–14.1) values, a wide range of Mg^# (6–64), positive zircon ε_Hf(t) (3.2–7.5) values, and elevated whole-rock ε_Nd(t) (2.03–4.41), but low I_Sr values (0.70427–0.70530), indicating that the source magma may have been derived from the juvenile lower crust with minor mantle input. The Bailingshan I-type intrusions also exhibit a mixed source signal, as constrained by Nb/Ta ratios, Mg^#, and isotopes characteristics. Because the granodiorite, monzonitic granite, and granite intrusions have higher zircon ε_Hf(t) (3.3–7.5, 11.8–13.5, and 10.2–14.4, respectively) and ε_Nd(t) (3.90, 5.78, and 5.94, respectively) values than those of the tuffaceous dacitic lava, it is suggested that mantle-derived materials may have played a more prominent role with their petrogenetic evolution. Integrating our new geological, age, geochemical and isotopic data we propose that the Aqishan–Yamansu iron skarn belt may have formed in a back-arc position or within an intra-arc basin generated by the southward subduction of the Kanggur oceanic plate beneath the Yili–Central Tianshan block during the late Paleozoic, with felsic-intermediate magmatism occurring during the basin inversion.     

新疆博格达造山带晚古生代构造-岩浆演化过程:火山岩组合及地球化学证据

最近,笔者在博格达山东段北部的西地-伊齐-小红柳峡一带的地质调查中发现,该区发育有大量晚石炭世柳树沟组双峰式火山岩及早二叠世卡拉岗组酸性火山岩建造,但双峰式火山岩性质及成因有别于其南侧七角井早石炭世双峰式火山岩。玄武岩富钠贫钾(K_2O=0.18%～0.45%,Na_2O=2.24%～3.63%),属拉斑系列;TiO_2=1.6%～1.7%,略高于MORB,较高的Al(Al_2O_3=16.2%～16.7%)、高Mg(MgO=8.12%～9.54%,Mg~#=61～64),以及低K_2O/TiO_2和K_2O/P_2O_5比值(分别为0.1～0.27、0.63～1.68),反映了在岩浆演化过程中分离结晶作用不明显;Rb/Sr比值0.01～0.02,Zr/Nb=21.6～39.7,Zr/Y=5.38～7.47,以及不相容元素Ba、Zr、Hf相对略富集、Nb-Ta和Th相对亏损,显示岩石具有板内玄武岩的特点;稀土元素球粒陨石标准化配分图上整体接近于平坦型,(La/Yb)_N=1.8～1.9,Eu无异常至轻微正异常(δEu=1.07～1.12),正ε_(Nd)(t)值(+5.63～+5.89),(~(143)Nd/~(144)Nd)_I=0.512927～0.512944,Th/Yb0.2,Ta/Yb=0.1,表明玄武岩浆源于亏损软流圈地幔,且在演化过程中不曾发生过斜长石的分离结晶作用,并暗示当时的大陆地壳可能由于拉张而变得较薄,玄武岩浆形成后快速上升至地表喷发。双峰式火山岩中的流纹岩Rb-Sr等时线年龄为296±2Ma(1σ),具高Si(SiO_2=76%～80%),富钾贫钠(K_2O=5.1%～5.7%,Na_2O=0.94%～2.03%);低Al(Al_2O_3=7.9%～10.4%);低Ti、Ca和P含量,属高钾钙碱性系列;微量元素Rb、Th、Zr、Hf、K相对富集,Ba、Sr、P、Ti、Nb、Ta为显著亏损;轻稀土元素适度富集且轻、重稀土分馏程度低,(La/Yb)_N=5.1～7.1,(La/Sm)_N=2、(Gd/Yb)_N=1.6～2.2,以及强烈的负Eu异常(δEu=0.17～0.2),(~(87)Sr/~(86)Sr)_I=0.7051～0.7052,δ~(18)O=11.6‰,指示岩石源于地壳物质的部分熔融,源区存在有斜长石残留,形成于大陆裂谷环境。早二叠世末流纹岩(Rb-sr等时线年龄为278±2Ma)具高Si(SiO_2=74%),富钾贫钠(K_2O/Na_2O2),低Al(Al_2O_3=11.0%)以及较低的Ti和P含量的特征,岩石为高钾钙碱性系列;微量元素PM标准化图解上表现为Rb、Ba、Th、U、K、La、Ce不相容元素相对富集,高场强元素Nb、Ta、P、Ti以及Sr为明显的负异常;轻稀土轻度富集,(La/Yb)_N=5～6,(La/Sm)_N=3,(Gd/Yb)_N=1.3～1.4,以及强烈的负Eu异常(δEu=0.31～0.39),(~(87)Sr/~(86)Sr)_I为0.7069,δ~(18)O=11.97‰,指示源于地壳物质部分熔融的产物,形成于伸展垮塌的构造环境。综合研究结果表明,博格达山前身裂谷岩浆作用始于早石炭世,结束于晚石炭世末期,早二叠世末进入后造山伸展的演化阶段。     

Geochemistry and tectonic setting of mafic rocks from the Othris Ophiolite,Greece

We present new geochemical analyses of minerals and whole rocks for a suite of mafic rocks from the crustal section of the Othris Ophiolite in central Greece. The mafic rocks form three chemically distinct groups. Group 1 is characterized by N-MORB-type basalt and basaltic andesite with Na- and Ti-rich clinopyroxenes. These rocks show mild LREE depletion and no HFSE anomalies, consistent with moderate degrees (~15%) of anhydrous partial melting of depleted mantle followed by 30–50% crystal fractionation. Group 2 is represented by E-MORB-type basalt with clinopyroxenes with higher Ti contents than Group 1 basalts. Group 2 basalts also have higher concentrations of incompatible trace elements with slightly lower HREE contents than Group 1 basalts. These chemical features can be explained by ~10% partial melting of an enriched mantle source. Group 3 includes high MgO cumulates with Na- and Ti-poor clinopyroxene, forsteritic olivine, and Cr-rich spinel. The cumulates show strong depletion of HFSE, low HREE contents, and LREE enrichments. These rocks may have formed by olivine accumulation from boninitic magmas. The petrogenesis of the N-MORB-type basalts and basaltic andesites is in excellent agreement with the melting conditions inferred from the MOR-type peridotites in Othris. The occurrence of both N- and E-MORB-type lavas suggests that the mantle generating the lavas of the Othris Ophiolite must have been heterogeneous on a comparatively fine scale. Furthermore, the inferred parental magmas of the SSZ-type cumulates are broadly complementary to the SSZ-type peridotites found in Othris. These results suggest that the crustal section may be genetically related to the mantle section. In the Othris Ophiolite mafic rocks recording magmatic processes characteristic both of mid-ocean ridges and subduction zones occur within close spatial association. These observations are consistent with the formation of the Othris Ophiolite in the upper plate of a newly created intra-oceanic subduction zone. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.