南黄海北部晚第四纪底栖有孔虫群落 分布特征及对古冷水团的指示

底栖有孔虫和粒度分析结果表明,南黄海北部DLC70 3孔（36°38′15″ N,123°32′56″ E,水深7200 m）7120 m长的柱状样保存了130 ka以来的沉积记录。依据349个样品的底栖有孔虫丰度和特征种的分布,结合岩性粒度变化,可识别9个底栖有孔虫组合,对应5个海相层和4个陆相至过渡相层;结合AMS14C和OSL测年数据建立了钻孔晚更新世以来的年代地层,可以与南黄海其他钻孔的地层进行对比。应用属种组合和不同生态种的丰度变化,探讨了研究区末次间冰期以来的古环境变化,认为海平面频繁波动是该地区不同成因类型地层从陆相、潮间、滨岸、滨海、近岸浅海、到浅海反复演替的关键。孔段2040~2780 m（MIS3早期）和5500~7120 m（MIS5e）的底栖有孔虫优势种是 Buccella frigida和Protelphidium tuberculatum,代表了与目前相似的冷涡边缘的冷水环境,指示南黄海古冷水团在MIS5e和MIS3早期高海平面时期已经存在。     

渤海东部和黄海北部表层沉积物稀土元素的分布特征与物源判别

为了探讨渤海东部和黄海北部稀土元素分布特征及其影响因素,对渤海东部和黄海北部138个表层沉积物样品进行电感耦合等离子体质谱法分析.结果表明:渤海东部和黄海北部沉积物的配分模式与中国黄土的接近,与周边的鸭绿江、黄河等河流输入物质也有相似性,表明研究区沉积物主要来自于周边大陆.沉积物物源判别结果显示:山东半岛近岸及其西南部沉积物主要来源于黄河,该区域沉积物分布受山东半岛沿岸流及近岸潮流影响;研究区东部沉积物稀土元素组成特征与鸭绿江沉积物组成相近,表明研究区东部沉积物可能由鸭绿江供应;研究区西北部沉积物主要来源于黄河及辽宁沿岸物质输入,局部有滦河、六股河物质存在;研究区东南部物质主要来源于黄河.对沉积物稀土元素百分含量及参数特征值进行了Q型聚类分析,将研究海域沉积物划分为4个不同的区域,分别为北黄海东部区域(Ⅰ)、山东半岛近岸周边区域(Ⅱ)、渤海东部中部区域(Ⅲ)及研究区的西北部与东南部分布区(Ⅳ).      

南黄海中部海水中多环芳烃的分布特征

2007年9月进行了2007南黄海海洋环境调查,并采集各个调查站位的表层、中层、底层海水及表层沉积物。利用液-液萃取法对采集到的样品进行前处理,并用气相色谱-质谱法检测海水中的多环芳烃。结果显示,监测站位中表层海水中总多环芳烃的含量范围是15.76~233.39ng/L,南黄海中部海水中多环芳烃的组成以2环的萘为优势组分;各种多环芳烃的含量与国际生物学组织或国家制定的评价水生生物暴露于水体的安全食用标准相比虽未超标,但个别组分如荧蒽的含量已达到生态毒理评价标准。     

Preliminary Research on the Center's Location and Interseasonal variabilities of the Cold Eddy in East China Sea

To determine the center location of the Cold Eddy in East China Sea(CEECS)′s center, we analyzed typical sections of temperature fields in the sea area around the eddy and improved the proper method to acquire the eddy′s center based on the temperature data of SODA from 1958 to 2001. Results show that the CEECS′s mean center was located at 32.0°N, 125.7°E at the depth of 35 meters during 44 years, while the center was not fixed in one place. From summer to winter, the center of the eddy moves from north to south gradually while it moves from south to north gradually from winter to summer in the longitudinal direction. In the latitudinal direction, the center is obviously in the west only in winter, while in the other seasons it is in the east and the latitude of it changes lightly. The main factor should be Tsushima Current and the Yellow Sea Coastal Current which control the variance of the center′s location. The eddy′s center is not obvious in early fall, late winter and early spring, which should be associated with the seasonality of the current fields.

     

南黄海中部隆起海相中-古生界科学钻探CSDP-2井选址

2014年,大陆架科学钻探项目（CSDP）确定采用自主研发的轻便型海洋钻井平台"探海1号"在南黄海盆地中部隆起上实施首口科学钻探井（CSDP-2井）,其科学目标是探查中部隆起的中-古生界地质结构和油气地质条件,解决南黄海中部隆起海相残留盆地长期悬而未决的地层属性问题,同时为区域地质、海陆演化与海相油气资源前景研究和评价提供基础资料。据此确定钻孔的选址原则为：钻探海域水深不超过30 m,在预定2 800 m的钻探深度范围内钻遇多套完整的中-古生界海相地层。根据钻探目标和选址原则,针对中部隆起没有钻探资料的状况,以区域地质特征和周边钻井对比为参考,以地震资料多属性解释为手段,标定了地震反射层位,解释并编制了反射层构造图,拟定了钻探井位,预测了钻探层位;采用地震储层预测技术预测了有利储层。上述工作形成了无井勘探区的钻探井位部署技术流程和方法,经钻探厘定了三叠纪-奥陶纪海相沉积层,并发现了多个油气显示层,达到了预定钻探目标。     

黄河口及邻近渤海海域悬浮体和沉积物中有机碳、氮的分布特征及其影响因素

利用元素分析仪对2007年获取的黄河口及邻近渤海海域悬浮体和沉积物进行了有机碳、氮含量分析.结果表明,在同一站位有机碳大体上的分布为,表层沉积物中TOC含量≤底层悬浮体中POC含量<表层悬浮体中POC含量;依据表层沉积物中TOC、TN含量和悬浮体中POC的分布,研究区可划分为5个区,依次为莱州湾西部靠近黄河口区(Ⅰ和Ⅱ...     

北黄海东部次盆地层序地层格架中烃源岩发育特征与影响因素

北黄海东部次盆地是我国海域勘探程度较低的一个盆地,钻探已发现该盆地发育中、上侏罗统巨厚暗色泥岩,但目前对该盆地烃源岩的研究尚较薄弱,精细评价该盆地的烃源岩对后续勘探部署具有重要意义。本文利用多口钻井实测数据和地震、测井资料,在层序地层学研究的基础上,应用有机地球化学和有机岩石学等方法,对中、上侏罗统不同层序和同一层序不同体系域中的烃源岩特征进行综合研究,并探讨烃源岩的分布规律及影响因素。东部次盆地烃源岩非均质性特征明显：中侏罗统J₂SQ1和J₂SQ2层序均以半深湖-深湖相、滨浅湖相暗色泥岩为主,烃源岩有机碳质量分数总体较高（w（TOC）>1.0%）,但生烃潜力指数（w（S₁+S₂））和氢指数（I_H）均很低,且有机质类型差,表明研究区有机质丰度高的烃源岩并非都是生烃能力高的烃源岩,整体为中等-差烃源岩。上侏罗统J₃SQ1层序中的烃源岩主要为三角洲前缘和滨浅湖相泥岩,有机质丰度较低,不同体系域发育的均是中等-差烃源岩;J₃SQ2层序主要为半深湖-深湖相暗色泥岩,具有厚度大、质纯和横向分布广的特点,但不同体系域中烃源岩的w（TOC）变化很大（0.5%~5.3%）,其中优质烃源岩主要发育在J₃SQ2层序中的高位体系域和湖侵体系域中,厚度0~104 m,而低位体系域中发育的则是中等烃源岩,该套优质烃源岩是东部次盆地内最主要的一套油源岩。研究认为,层序地层格架和沉积相控制了东部次盆地烃源岩的空间展布范围,陆源有机质的输入与湖盆原位生物生产力的匹配关系控制了烃源岩的质量,湖盆水体的含氧量与盐度在一定程度上控制了有机质的保存。综上所述,北黄海东部次盆地属于中低丰度的含油气盆地,应在优质烃源岩发育区及其邻区寻找有利勘探目标。     

Chemical and Isotopic Characters of the Water and Suspended Particulate Materials in the Yellow River and Their Geological and Environmental Implications

The chemical and isotopic characteristics of the water and suspended particulate materials(SPM)in the Yellow River were investigated on the samples collected from 29 hydrological monitoring stations in the mainstem and several major tributaries during 2004 to 2007.TheδD andδ~(18)O values of the Yellow River water vary in large ranges from-32‰to-91‰and from-3.1‰to-12.5‰,respectively.The characters of H and O isotope variations indicate that the major sources of the Yellow River water are meteoric water and snow melting water,and water cycle in the Yellow River basin is affected strongly by evaporation process and human activity.The average SPM content(9.635g/L)of the Yellow River is the highest among the world large rivers.Compared with the Yangtze River,the Yellow River SPM has much lower clay content and significantly higher contents of clastic silicates and carbonates.In comparison to the upper crust rocks,the Yellow River SPM contains less SiO_2,CaO,K_2O and Na_2O,but more TFe_2O_3,Co,Ni,Cu,Zn,Pb and Cd.The abnormal high Cd contents found in some sample may be related to local industrial activity.The REE contents and distribution pattern of the Yellow River SPM are very close to the average value of the global shale.The averageδ~(30)Si_(SPM)in the Yellow River(-0.11‰)is slightly higher than the average value(-0.22‰)of the Yangtze River SPM.The major factors controlling theδ~(30)Si_(SPM)of the Yellow River are the soil supply,the isotopic composition of the soil and the climate conditions.The TDS in the Yellow River are the highest among those of world large rivers.Fair correlations are observed among Cl~-,Na~+,K~+,and Mg~(2+)contents of the Yellow River water,indicating the effect of evaporation.The Ca~(2+)and Sr~(2+)concentrations show good correlation to the SO_4~(2-)concentration rather than HCO_3~-concentration,reflecting its origin from evaporates.The NO_3~-contents are affected by farmland fertilization.The Cu,Zn and Cd contents in dissolved load of the Yellow River water are all higher than those of average world large rivers,reflecting the effect of human activity.The dissolved load in the Yellow River water generally shows a REE distribution pattern parallel to those for the Yangtze River and the Xijiang River.Theδ~(30)Si values of the dissolved silicon vary in a range from 0.4‰to 2.9‰,averaging1.34‰.The major processes controlling the D_(Si)andδ~(30)Si_(Diss)of the Yellow River water are the weathering process of silicate rocks,growth of phytolith in plants,evaporation,dissolution of phytolith in soil,growth of fresh water diatom,adsorption and desorption of aqueous monosilicic acid on iron oxide and human activities.The averageδ~(30)Si_(Diss)value of the Yellow River is significantly lower than that of the Nile River,Yangtze River and Siberia rivers,but higher than those of other rivers,reflecting their differences in chemical weathering and biological activity.Theδ~(34)S_(SO4)values of the Yellow River water range from-3.8‰to 14.1‰,averaging 7.97‰.There is some correlation between SO_4~(2-)content andδ~(34)S_(SO4).The factors controlling theδ~(34)S_(SO4)of the Yellow River water are the SO_4 in the meteoric water,the SO_4 from gypsum or anhydrite in evaporite rocks,oxidation and dissolution of sulfides in the mineral deposits,magmatic rocks and sedimentary rocks,the sulfate reduction and precipitation process and the sulfate from fertilizer.The~(87)Sr/~(86)Sr ratios of all samplesrange from 0.71041 to 0.71237,averaging 0.71128.The variations in the~(87)Sr/~(86)Sr ratio and Sr concentration of river water are primarily caused by mixing of waters of various origins with different~(87)Sr/~(86)Sr ratios and Sr contents resulting from water-rock interaction with different rock types.     

黄河源区冻土特征及退化趋势

黄河源区位于青藏高原多年冻土区东北部边缘地带,是季节冻土、岛状多年冻土和在大片连续多年冻土并存地带.多年冻土层在垂向分布上有衔接状和不衔接状两大类.不衔接状又可分为浅埋藏(8m)、深埋藏(8m)和双层多年冻土等形式.从20世纪80年代以来,源区气温以0.02℃.a-1增温率持续上升,人类经济活动日益增强,导致冻土呈区域性退化.多年冻土下界普遍升高50～80m,最大季节冻深平均减少了0.12m,浅层地下水温度上升0.5～0.7℃.冻土退化总体趋势是由大片状分布逐渐变为岛状、斑状分布,多年冻土层变薄,冻土面积缩小,融区范围扩大.部分多年冻土岛完全消失变为季节冻土.     

中国东部主要入海河流As元素分布、来源及影响因素分析

为查明中国河流中As等重金属元素的分布规律,于2007—2008年分丰水期和枯水期对中国东部30余条入海河流水体、悬浮物统一进行采样分析。结果表明:东部河流中As元素溶解态含量均值为3.1μg/L,同世界河流相比,明显偏高;且频率分布直方图具有多个峰值,反映出明显的人为污染。利用富集系数的研究表明,悬浮物同样受到较明显的人为污染。As在河水中的迁移形式以溶解态为主,pH值和温度对As的迁移形式有明显影响。流域内岩石类型对河流中As含量影响显著,火山岩、火山碎屑岩类广泛分布的流域河水中As含量明显偏高,花岗岩及中、深变质岩广泛分布的流域河流中As含量则偏小。利用生活、工业污水作为As元素人为来源端元,对海河、黄河、长江、珠江等河流人为源进行了估算,分别为46.7%、18.7%、13.5%、8.3%。     

鄂陵湖晚全新世沉积物记录的黄河源区气候环境变化

通过对青藏高原黄河源区鄂陵湖35cm长的沉积物岩芯（NR-1）中总有机碳含量（TOC）、总氮含量（TN）、碳氮比值（C_org/N_tot）以及有机碳同位素（δ¹³C_org）和总氮同位素（δ¹⁵N_tot）等地球化学指标的分析,并结合青海地区文献资料记载的人口数量变化以及高原湖泊水位记录,对研究区近1500a以来的气候环境变化进行了深入探讨。结果表明：近两百多年以来鄂陵湖沉积物中TOC和TN指标呈现明显上升的趋势,与青海东部地区人口数量变化趋势一致,表明近代人类活动已经对青藏高原最大淡水湖生态系统产生了显著的影响;而沉积物中δ¹³C_org值变化与青海湖水文环境重建指标具有可比性,说明高原大型淡水湖泊沉积物δ¹³C_org值可指示湖泊水位波动;此外δ¹⁵N_tot值变化趋势与青藏高原东北部已有的古温度记录总体一致,推测鄂陵湖沉积物δ¹⁵N_tot值可能响应了湖泊水体营养状态的变化,间接指示了湖泊夏季表层水温的波动。本研究为青藏高原腹地高海拔现代湖泊沉积物中有机碳和总氮含量及其同位素指标的解译提供了全新的思路。

     

南海北部琼东南海域HQ-48PC站位地球化学特征及对天然气水合物的指示意义

南海北部陆坡琼东南海域是中国天然气水合物勘探最具潜力的区域之一。对该海域的HQ-48PC站位沉积物样品的顶空气甲烷含量、孔隙水阴、阳离子及微量元素含量等地球化学特征进行综合分析,结果显示:在硫酸盐-甲烷界面(SMI,Sulfate-Methane Interface)(推算深度约为6.05 mbsf)发生了强烈的甲烷厌氧氧化反应(AMO,Anaerobic Meth-ane Oxidation),主要表现为SO24-含量线性降低接近于0、CH4含量发生骤增、有机碳和黄铁矿含量达到最大值及形成一个"钡锋"等特征。在SMI之上,HCO3-浓度随深度的增加呈明显上升的趋势,Ca2+、Mg2+、Sr2+等离子浓度随深度的增加呈降低的趋势,Mg2+/Ca2+比值随深度的增加呈明显增加的趋势,自生碳酸盐矿物以方解石为主;在SMI之下,HCO3-浓度随深度的增加呈缓慢下降的趋势,Ca2+浓度变化不大,Mg2+、Sr2+浓度和Mg2+/Ca2+比值随深度的增加呈降低的趋势,自生碳酸盐矿物以白云石为主。沉积物孔隙水的PO34-和NH4+含量较高,它们随深度的增加呈明显升高的趋势,且这种变化趋势与SO42-含量的下降趋势大致呈镜像关系。这些地球化学异常特征与国际上已发现有天然气水合物地区的地球化学特征相类似,暗示该采样站位深部沉积物中可能赋存有天然气水合物藏。