Microtektites: a chemical comparison of bottle-green microtektites,normal microtektites and tektites

Trace element abundances in Ivory Coast normal microtektites and Australasian bottle-green microtektites confirm that microtektites are genetically related to tektites in the associated strewn field. Although major and compatible trace element abundances imply that bottle-green microtektites are members of a fractional crystallization sequence, the similar rare earth element distributions in Australasian normal and bottle-green microtektites and tektites cannot be explained by a simple fractionation model. The similar REE abundances in tektites and microtektites of widely different major element composition also preclude simple models calling for sedimentary rock precursors.     

Age and provenance of the target materials for tektites and possible impactites as inferred from Sm-Nd and Rb-Sr systematics

Sm-Nd and Rb-Sr analyses of tektites and other impactites can be used to place constraints on the age and provenance of target materials which were impact melted to form these objects. Tektites have large negative ε^Nd(0) values and are uniform within each tektite group while the ε^Sr(0) are large positive values and show considerable variation within each group. Chemical, trace element, and isotopic compositions of tektites are consistent with production by melting of sediments derived from old terrestrial continental crust. Each tektite group is characterized by a uniform Nd model age,T_CHUR^Nd, interpreted as the time of formation of the crustal segment which weathered to form the parent sediment for the tektites: (1) ～1.15 AE for Australasian tektites; (2) ～1.91 AE for Ivory Coast tektites; (3) ～0.9 AE for moldavites; (4) ～0.65 AE for North American tektites, and (5) ～0.9 AE for high-Si irghizites. Sr model ages,T_UR^Sr, are variable within each group reflecting Rb-Sr fractionation and in the favorable limit of very high Rb/Sr ratios, approach the time of sedimentation of the parent material which melted to form the tektites. Australasian tektites are derived from ～0.25 AE sediments, moldavites from ～0.0 AE sediments, Ivory Coast tektites from ～0.95 AE sediments. Possible parent sediments of other tektite groups have poorly constrained ages. Our data on moldavites and Ivory Coast tektites are consistent with derivation from the Ries and Bosumtwi craters, respectively. Irghizites are isotopically distinct from Australasian tektites and are probably not related. Sanidine spherules from a Cretaceous-Tertiary boundary clay have initial ε^Nd ～ +2; ε^Sr ～ +5 and are not derived from old continental crust or meteoritic feldspar. They may represent a mixture of basaltic oceanic crust and sediments, implying an oceanic impact. These isotopic results are also consistent with a volcanic origin for the spherules.     

Paleomagnetic reconstruction of the global geomagnetic field evolution during the Matuyama/Brunhes transition: Iterative Bayesian inversion and independent verification

The Earth's magnetic field changed its polarity from the last reversed into today's normal state approximately 780 000 years ago. While before and after this so called Matuyama/Brunhes reversal, the Earth magnetic field was essentially an axial dipole, the details of its transitional structure are still largely unknown. Here, a Bayesian inversion method is developed to reconstruct the spherical harmonic expansion of this transitional field from paleomagnetic data. This is achieved by minimizing the total variational power at the core–mantle boundary during the transition under paleomagnetic constraints. The validity of the inversion technique is proved in two ways. First by inverting synthetic data sets from a modeled reversal. Here it is possible to reliably reconstruct the Gauss coefficients even from noisy records. Second by iteratively combining four geographically distributed high quality paleomagnetic records of the Matuyama/Brunhes reversal into a single geometric reversal scenario without assuming an a priori common age model. The obtained spatio-temporal reversal scenario successfully predicts most independent Matuyama/Brunhes transitional records. Therefore, the obtained global reconstruction based on paleomagnetic data invites to compare the inferred transitional field structure with results from numerical geodynamo models regarding the morphology of the transitional field. It is found that radial magnetic flux patches form at the equator and move polewards during the transition. Our model indicates an increase of non-dipolar energy prior to the last reversal and a non-dipolar dominance during the transition. Thus, the character and information of surface geomagnetic field records is strongly site dependent. The reconstruction also offers new answers to the question of existence of preferred longitudinal bands during the transition and to the problem of reversal duration. Different types of directional variations of the surface geomagnetic field, continuous or abrupt, are found during the transition. Two preferred longitudinal bands along the Americas and East Asia are not predicted for uniformly distributed sampling locations on the globe. Similar to geodynamo models with CMB heatflux derived from present day lower mantle heterogeneities, a preference of transitional VGPs for the Pacific hemisphere is found. The paleomagnetic duration of reversals shows not only a latitudinal, but also a longitudinal variation. Even the paleomagnetically determined age of the reversal varies significantly between different sites on the globe. The described Bayesian inversion technique can easily be applied to other high quality full vector reversal records. Also its extension to inversion of secular variation and excursion data is straightforward.     

Paleomagnetism and radiochemical age estimates for Late Brunhes polarity episodes

Several reversed polarity magnetozones occur within deep-sea sediment core CH57-8 from the Greater Antilles Outer Ridge, within sediment of latest Pleistocene/Late Brunhes age. The uppermost reversed interval spanning 31 data points coincides with the X faunal zone of the Last Interglacial Period. Radiochemical dating of cores CH57-8 and KN25-4 has shown that all the reversed polarity magnetozones are significantly younger than the Brunhes/Matuyama boundary at 0.7 m.y. B.P. A variation of the excess²³⁰Th method was used, in which²¹⁰Po and²³⁸U were the actual radionuclides measured. In a third core from the Mid-Atlantic Ridge, our²¹⁰Po results were similar to those which others obtained earlier by direct²³⁰Th measurements.     

Microtektites in the Middle Pleistocene deep-sea sediments of the South China Sea*

This is a preliminary study on the microtektites that were found in large numbers from the interval between 7.80 and 8.10 m depth of core S095-17957-2 (10°53.9’N, 115°18.3’E, water depth 2 195 m), northern Nansha area of the South China Sea. The microtektites vary in shape, with spherules predominating, and are commonly less than 1 mm in diameter, transparent or semitransparent, brownish in color, with bubbles inside. Based on coarse fraction stratigraphy and foraminifera/nanofossil biostratigraphical events the microtektite layer was assigned to nearly the Bm-hes/Matuyama magnetic reversal boundary (some 0.78 MaBP). Obviously, the present microtektites, and those found from the middle Pleistocene of the Indian Ocean, Australia and loess of northern China, were products of the same impact event and therefore, are useful as a reliable mark in Quaternary stratigraphy, as well as in paleoclimatic studies. Project supported by the National Natural Science Foundation of China (Grant Nos. 49676287, 49732060).     

中国黄土与红色粘土记录的地磁极性界限及地质意义

本文报道由蓝田、陕县、洛川、西峰、平凉、兰州及靖远等剖面获得的古地磁研究结果．主要结论为：１．中国黄土剖面记录了Ｂｒｕｎｈｅｓ正极性带与Ｍａｔｕｙａｍａ负极性带，Ｂｒｕｎｈｅｓ／Ｍａｔｕｙａｍａ极性转换过程位于第８层黄土（Ｌ８）．在段家坡黄土剖面该转换过程对应的地层厚度为０．３７５ｍ，持续时间约６０００ａ．转换过程由３次极性变化构成，每次经历的时间约为４００ａ．２．Ｊａｒａｍｉｌｌｏ正极性亚带（Ｊ）位于标志层Ｌ９至Ｌ１５之间，大约Ｓ１０－Ｓ１３位置．３．Ｏｌｄｕｖａｉ正极性亚带（Ｏ）对应的地层为Ｓ２７－Ｓ３３４．Ｒｅｕｎｉｏｎ正极性亚带（Ｒ）由两部分组成，在蓝田段家坡黄土剖面分别位于Ｌ３６和Ｓ３８５．Ｍａｔｕｙａｍａ负极性带与Ｇａｕｓｓ正极性带界限（Ｍ／Ｇａ）位于黄土和红色粘土交界处，中国黄土的底界年龄为２．４８Ｍａ左右．黄土与红色粘土为整合接触关系．６．黄土下伏的红色粘土记录了Ｇａｕｓｓ正极性带，Ｇｉｌｂｅｒｔ负极性带和古地磁年表编号５（Ｅｐｏｃｈ５）．     

High-precision 40Ar/39Ar dating of pleistocene tuffs and temporal anchoring of the Matuyama-Brunhes boundary

High-precision ⁴⁰Ar/³⁹Ar ages for a series of proximal tuffs from the Toba super-volcano in Indonesia, and the Bishop Tuff and Lava Creek Tuff B in North America have been obtained. Core from Ocean Drilling Project Site 758 in the eastern equatorial Indian Ocean contains discrete tephra layers that we have geochemically correlated to the Young Toba Tuff (73.7 ± 0.3 ka), Middle Toba Tuff (502 ± 0.7 ka) and two eruptions (OTTA and OTTB) related to the Old Toba Tuff (792.4 ± 0.5 and 785.6 ± 0.7 ka, respectively) (⁴⁰Ar/³⁹Ar data reported as full external precision, 1 sigma). Within ODP 758 Termination IX is coincident with OTTB and hence this age tightly constrains the transition from Marine Isotope Stage 19–20 for the Indian Ocean. The core also preserves the location of the Australasian tektites, and the Matuyama-Brunhes boundary with Bayesian age-depth models used to determine the ages of these events, c. 786 and c. 784 ka, respectively. In North America, the Bishop Tuff (766.6 ± 0.4 ka) and Lava Creek Tuff B (627.0 ± 1.5 ka) have quantifiable stratigraphic relationships to the Matuyama-Brunhes boundary. Linear age-depth extrapolation, allowing for uncertainties associated with potential hiatuses in five different terrestrial sections, defines a geomagnetic reversal age of 789 ± 6 ka. Considering our data with respect to the previously published age data for the Matuyama-Brunhes boundary of Sagnotti et al. (2014), we suggest at the level of temporal resolution currently attainable using radioisotopic dating the last reversal of Earths geomagnetic field was isochronous. An overall Matuyama-Brunhes reversal age of 783.4 ± 0.6 ka is calculated, which allowing for inherent uncertainties in the astronomical dating approach, is indistinguishable from the LR04 stack age (780 ± 5 ka) for the geomagnetic boundary. Our high-precision age is 10 ± 2 ka older than the Matuyama-Brunhes boundary age of 773 ± 1 ka, as reported previously by Channell et al. (2010) for Atlantic Ocean records. As ODP 758 features in the LR04 marine stack, the high-precision ⁴⁰Ar/³⁹Ar ages determined here, as well as the Matuyama-Brunhes boundary age, can be used as temporally accurate and precise anchors for the Pleistocene time scale.     

Palaeomagnetic and palaeontological dating of a section at Gioia Tauro,Italy: Identification of the Blake Event

Palaeomagnetic and palaeontological studies on samples withdrawn from a 250-m-long unorientated core from Reggio di Calabria, Italy (38°N, 16°E) are described. The lower 200 m of core penetrated off-shore clays and visual examination of the split sections of core indicated no obvious breaks in deposition. After alternating field demagnetization in 200 Oe the palaeomagnetic inclination log shows the Brunhes/Matuyama boundary at 110 m below which the Jaramillo and Olduvai Events within the Matuyama Epoch are identified. This interpretation of the magnetostratigraphy is supported by palaeontological evidence. The rate of accumulation of clay is estimated to have ranged between about 60 and 190 mm/kyr with an overall average through the Matuyama Epoch of about 90 mm/kyr. Assuming that this average rate continued through the Brunhes Epoch, the age of the top of the clay unit is estimated to be about 90,000 yr B.P. About 5 m from the unconformable top surface of the clay, a split sequence of reversed inclinations is interpreted as a record of the Blake Event, and the overall average deposition rate implies that its duration may have been as long as 50,000 yr. No other reversed event is recorded by the palaeomagnetic inclination log through the Brunhes Epoch, though there are four horizons where shallow positive inclinations are recorded.     

高分辨率洛川剖面黄土磁性地层学

洛川剖面作为经典的黄土剖面,磁极性地层界线的具体位置还不清楚.通过对洛川黄土-古土壤序列以10 cm间隔的古地磁研究,厘定了磁极性界线的具体位置：（1）MB (Matuyama-Brunhes) 界线位于53 m处,S8的上部.（2）Jaramillo位于67.8~72.5 m,上界在S₁₀的上部,其下界位于L₁₃的顶部.（3）Olduvai位于107.2~114.2 m,上界位于S₂₅的顶部,相当于WS₂的上部,其下界位于L₂₉的上部,相当于WL₂的上部.4）并未检测到Matuyama的底界,可能位于红粘土内.     

Magnetostratigraphic and paleoclimatic studies on the Red Earth Formation from the Chengdu Plain in Sichuan Province,China

Two red earth sections from the Chengdu Plain in Sichuan Province are dated using geomagnetic methods. The Brunhes/Matuyama (B/M) reversal boundary is recognized within the upper parts of the two sections,and the Jaramillo normal subzone occurs in the middle-lower parts of the vermiculated red soil (VRS),which indicate that the parent material for the VRS deposited in the middle Quaternary. Sedimentologic and geochemical studies suggest that the Chengdu Clay and part of the parent material for the VRS are of aeolian origin. Pollen analysis indicates that the Chengdu Plain was mainly covered by needle-leaved forest with a cool to cool temperate humid climate when the parent material for the VRS deposited. The relatively cool to cool temperate climatic condition in the Chengdu Plain in the middle Quaternary,which may be caused by the uplift of the Tibetan Plateau,was a response to the geo-environmental changes of global significance.     

Rock magnetism and magnetostratigraphy of the loess-sol series of Ukraine (Roksolany,Boyanychi, and Korshev sections)

The results of the rock magnetic and paleomagnetic studies for the Quaternary loess-sol deposits of Ukraine are reported. The magnetic properties of the rocks composing the sections in the Pre-Black-Sea Depression (Roksolany) and Volyn Upland (Boyanychi and Korshev) are compared. Based on the highly precise measurements by modern instruments, the primary magnetization component is isolated in the rocks and its polarity is reliably determined in both the loess and soil horizons. The position of the Matuyama–Brunhes boundary in the Roksolany section is determined at a depth of 46.6 m at the contact of the Lubenskii and Martonoshskii soil horizons. This is consistent with the present-day notions of the group of Ukrainian scientists about the Quaternary stratigraphy of the south of Ukraine and inconsistent with the previous results that placed this boundary at a depth of 34 m in loesses above the PK₇ level.     

A Quaternary geomagnetic instability time scale

Reversals and excursions of Earth's geomagnetic field create marker horizons that are readily detected in sedimentary and volcanic rocks worldwide. An accurate and precise chronology of these geomagnetic field instabilities is fundamental to understanding several aspects of Quaternary climate, dynamo processes, and surface processes. For example, stratigraphic correlation between marine sediment and polar ice records of climate change across the cryospheres benefits from a highly resolved record of reversals and excursions. The temporal patterns of dynamo behavior may reflect physical interactions between the molten outer core and the solid inner core or lowermost mantle. These interactions may control reversal frequency and shape the weak magnetic fields that arise during successive dynamo instabilities. Moreover, weakening of the axial dipole during reversals and excursions enhances the production of cosmogenic isotopes that are used in sediment and ice core stratigraphy and surface exposure dating. The Geomagnetic Instability Time Scale (GITS) is based on the direct dating of transitional polarity states in lava flows using the ⁴⁰Ar/³⁹Ar method, in parallel with astrochronologic age models of marine sediments in which oxygen isotope and magnetic records have been obtained. A review of data from Quaternary lava flows and sediments gives rise to a GITS that comprises 10 polarity reversals and 27 excursions that occurred during the past 2.6 million years. Nine of the ten reversals bounding chrons and subchrons are associated with ⁴⁰Ar/³⁹Ar ages of transitionally-magnetized lava flows. The tenth, the Gauss-Matuyama chron boundary, is tightly bracketed by ⁴⁰Ar/³⁹Ar dated ash deposits. Of the 27 well-documented geomagnetic field instabilities manifest as short-lived excursions, 14 occurred during the Matuyama chron and 13 during the Brunhes chron. Nineteen excursions have been dated directly using the ⁴⁰Ar/³⁹Ar method on transitionally-magnetized volcanic rocks and these form the backbone of the GITS. Excursions are clearly not the rare phenomena once thought. Rather, during the Quaternary period, they occur nearly three times as often as full polarity reversals.     

The use of the rock magnetic and paleomagnetic data for the Loess Plateau deposits in China for their climatologic and chronologic correlation to the oxygen isotopic timescale

The results of numerous rock magnetic and paleomagnetic studies of Pleistocene deposits in the Loess Plateau in China which were obtained over a period of a few decades are analyzed. It is shown that two important problems remain unsolved. These are (1) developing the particular mechanism of “magnetic enhancement” in the soils, probably with a more accurate assessment of the level of effect of various natural factors causing qualitative changes in the magnetic fraction of the soil. Here, both the chemical composition of the newly crystallized magnetic mineral causing this enhancement and the parameters of the corresponding secondary (chemical) magnetization process should be determined. (2) Fixing the exact climate-stratigraphic position of the main paleomagnetic benchmarks of the Pleistocene, primarily the Matuyama–Brunhes reversal. In contrast to many conclusions, it is inferred that the Pleistocene paleoclimatic loess-soil record in China generally disagrees with the oxygen isotope (OI) record in the deep-sea sediments. This inconsistency is particularly significant for the Matuyama chron deposits.     

ESR dating of Pleistocene archaeological localities of the Nihewan Basin,North China – Preliminary results

The well-developed, late Cenozoic Nihewan Beds in northern China are amongst the most famous and well-preserved Quaternary strata in East Asia. The Nihewan Basin is also well-known for its mammalian fossils and stone artifacts, which document early human settlements in high northern latitudes (around 40°N). It is a key geological place to study palaeoenvironments and ancient human activities due to the excellent age-control of the formation by palaeomagnetism. In the present paper, the sediments of two Paleolithic sites were dated using the ESR signals of the titanium center in quartz. In order to check the reliability of our analytical procedures, a reference sample collected near the Brunhes/Matuyama (B/M) boundary at the Donggutuo site was firstly analyzed, yielding an age of 750 ± 88 ka. Then, three samples collected from the Dongpo site were analyzed by the same procedures. Our ESR results indicate that the age of the Dongpo cultural layer ranges between 304 ± 12 ka and 333 ± 23 ka, with an average of approximately 321 ± 15 ka.     

Isotopic fractionation of zinc in tektites

Tektites are terrestrial natural glasses produced during a hypervelocity impact of an extraterrestrial projectile onto the Earth's surface. The similarity between the chemical and isotopic compositions of tektites and terrestrial upper continental crust implies that the tektites formed by fusion of such target rock. Tektites are among the driest rocks on Earth. Although volatilization at high temperature may have caused this extreme dryness, the exact mechanism of the water loss and the behavior of other volatile species during tektite formation are still debated. Volatilization can fractionate isotopes, therefore, comparing the isotope composition of volatile elements in tektites with that of their source rocks may help to understand the physical conditions during tektite formation.For this study, we have measured the Zn isotopic composition of 20 tektites from four different strewn fields. Almost all samples are enriched in heavy isotopes of Zn compared to the upper continental crust. On average, the different groups of tektites are isotopically distinct (listed from the isotopically lightest to the heaviest): Muong-Nong type indochinites (δ^66/64Zn = 0.61 ± 0.30‰); North American bediasites (δ^66/64Zn = 1.61 ± 0.49‰); Ivory Coast tektites (δ^66/64Zn = 1.66 ± 0.18‰); the Australasian tektites (others than the Muong Nong-type indochinites) (δ^66/64Zn = 1.84 ± 0.42‰); and Central European moldavites (δ^66/64Zn = 2.04 ± 0.19‰). These results are contrasted with a narrow range of δ^66/64Zn = 0–0.7‰ for a diverse spectrum of upper continental crust materials.The elemental abundance of Zn is negatively correlated with δ^66/64Zn, which may reflect that isotopic fractionation occurred by evaporation during the heating event upon tektite formation. Simple Rayleigh distillation predicts isotopic fractionations much larger than what is actually observed, therefore, such a model cannot account for the observed Zn isotope fractionation in tektites. We have developed a more realistic model of evaporation of Zn from a molten sphere: during its hypervelocity trajectory, the molten surface of the tektite will be entrained by viscous coupling with air that will then induce a velocity field inside the molten sphere. This velocity field induces significant radial chemical mixing within the tektite that accelerates the evaporation process. Our model, albeit parameter dependent, shows that both the isotopic composition and the chemical abundances measured in tektites can be produced by evaporation in a diffusion-limited regime.     

The contribution of loess magnetism in China to the retrieval of past global changes—some problems

In the loess plateau of China, the stratigraphical position of the Brunhes / Matuyama boundary was not found in loess unit L8 at Luochuan and Jixian as is commonly accepted. The interbedded palaeosols may be differentiated from the parent loess not only by their high magnetic susceptibility but also by their enhanced remanence properties. These contrasts mainly result from concentration changes of the inherited magnetic minerals, grain-size changes and authigenic formation of magnetic minerals, which are all linked to climate-controlled soil formation processes.     

Loess in the Czech Republic: Magnetic properties and paleoclimate

Summary We have studied 454 oriented samples from seven loess outcrops in the Czech Republic for comparison and correlation of the magnetic properties with those of the loess profiles in China and Central Asia. Three sections at Sedlec (Prague), Zeměchy and Dolní Věstonice cover the time span of the last glacial-interglacial cycle. Loess from the middle Pleistocene period including pedocomplexes V and VI was studied at Sedlešovice (Znojmo) and Karlštejn. Loess of uncertain — possibly lower to middle Pleistocene age — was sampled at Sedlec near Mikulov. At Červeny Kopec (Red Hill, Brno) we investigated the oldest loess near the Matuyama/Brunhes (M/B) boundary. The characteristic remanence (ChRM) determined after magnetic clearning is of normal polarity throughout all sections except at Červeny Kopec. There, two polarity changes from reversed to normal were found within two sections initially thought to represent two successive stratigraphic intervals. However, the marked similarities between lithological, susceptibility, declination and inclination profiles lead us to suggest that the two polarity changes are in fact one and the same. The two sections are therefore laterally equivalent and both have recorded the M/B field reversal. The susceptibility variations were used to mutually correlate the Czech sections and to construct a composite profile across the present day loess outcrops in the Czech Republic. They also serve as a paleoclimate proxy which can be compared and correlated with the paleoclimatic records observed in the Chinese and Central Asian loess. The origin of the low field susceptibility variations was studied by measuring the frequency dependence of susceptibility which revealed that the enhancement within the pedocomplexes is controlled by the amount of fine-grained ferromagnetic minerals present.     

Onset of Xiashu loess deposition in southern China by 0.9 Ma and its implications for regional aridification

The Xiashu loess is a typical Quaternary eolian deposit in southern China and represents an important terrestrial paleoclimate archive in this low-latitude monsoon region. However, the chronological framework of Xiashu loess deposition has yet to be established. Determining the timing of the onset of Xiashu loess deposition will allow researchers to better understand late Quaternary aridification across the Asian continent, the evolution of the East Asian monsoon and regional environmental changes in subtropical regions. Therefore, in this study, a systematic chronological study of the Xiashu loess is conducted to answer this question. For the first time, magnetostratigraphic classification reveals that the Matuyama/Brunhes (M/B) reversal is present in the Xiashu loess at two sites in Jiangsu Province, the Qingshan profile at Yizheng and the Dagang core in Zhenjiang. Based on the results of magnetostratigraphy and optically stimulated luminescence (OSL) dating, the age of the lower boundary of the Xiashu loess is estimated to be approximately 0.9 Ma. Consequently, this Xiashu loess deposit is the oldest reported to date and is comparable in age to the red soil deposit in Xuancheng, Anhui Province. The onset of Xiashu loess deposition by 0.9 Ma represents the further expansion of arid range in Asia in the late Quaternary in response to significant aridification and winter monsoon strengthening in this subtropical region. We suggest that these climate changes were primarily driven by global cooling and an increase in high-latitude ice volume in the Northern Hemisphere and that the initiation of Xiashu loess accumulation was a regional response of southern China to the 0.9 Ma global cooling event.     

A new approach to the problem of tektite genesis

Variations in the major cation ratios in the (micro-) tektites of each of the different strewn fields were studied with the help of Niggli parameters. There is a high degree of variability in almost each individual strewn field which, however, is not random. Invariably, as SiO₂ increases the proportion of alumina and the alkalies among the cations increases, that ofMgO + ΣFeO (total iron as FeO) and CaO decreases; simultaneouslyK₂O/Na₂O increases whileMgO/FeO decreases. This is entirely analogous to magmatic differentiations and is incompatible with an explanation by mechanical mixing of sedimentary parent rocks. The picture can best be explained by partial melting, in analogy to fulgurites and combustion ultrametamorphic glasses.In some strewn fields (e.g. javaites, georgiaites, bediasites), all tektites formed from the same set of parent rocks. In these fields each cation parameter, when plotted against silica, follow a linear slightly curved path with a very small scatter (simple type). In others (e.g. moldavites, philippinites, australites) some or all cation parameters show a strong scatter which sometimes almost obliterates the differentiation trends. These complex diagrams can be reduced to 2–5 diagrams (lineages) of the simple type, each reflecting a different combination of parent rocks. Most lineages again show the influence of partial melting differentiation.If the chemical variations of tektites are caused by partial melting, the silica-poor end of each variation diagram (case of total melting) and not the average composition corresponds to the parent rock combination involved. Thus, neglecting losses by evaporation (which are minor), the chemical compositions of 25 starting materials were established. All except one of these can very closely be matched by a combination, in appropriate proportions, of only two of the most common sedimentary rocks. The only group which cannot be duplicated by a combination of any two sedimentary rocks are the bottle-green microtektites.     

North American microtektites from the Caribbean Sea and their fission track age

Over 6000 microscopic glass spherules between 125 μm and 1 mm in diameter were found in a sediment core (RC9-58) from the Caribbean Sea. These glassy objects are mostly confined to a zone ～ 40 cm thick at a depth of ～ 250 cm. We believe that the microscopic glass objects are microtektites belonging to the North American strewnfield, based on their geographical location, appearance, physical properties, stratigraphic age (middle Upper Eocene), fission track age (～34.6 my) and major element compositions. The occurrence of North American microtektites in the Caribbean Sea indicates that the North American strewnfield is two to three times larger than previously indicated. An estimate on the abundance of microtektites in core RC9-58 indicates that the North American strewnfield may contain greater than 10¹⁷ g of tektite material.