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新疆哈密香山西铜镍-钛铁矿床系同源岩浆分异演化产物——矿相学、锆石U-Pb年代学及岩石地球化学证据 总被引:10,自引:9,他引:10
香山西岩体是东天山地区发现的唯一的一个铜镍-钛铁复合型含矿岩体,前人对香山西铜镍-钛铁矿床成因认识一直存在争议。本次通过矿相学研究结合电子探针分析,在香山西铜镍矿石中发现了铜镍硫化物与钛铁氧化物共生的现象,并首次测定了香山西钛铁辉长岩的SIMS锆石U-Pb年龄为278.6±1.8Ma(MSWD=1.2),与前人测得香山中岩体角闪辉长岩的锆石U-Pb年龄基本一致,证实了香山西铜镍矿与钛铁矿为共生关系,两者空间上渐变过渡。岩石地球化学研究表明,香山岩体(包括钛铁辉长岩)为同源岩浆经结晶分异作用形成的一套镁铁-超镁铁质岩体,具有拉斑玄武质岩浆分异演化趋势,并且经历了与地壳物质的混染。与中段和东段岩石相比,香山西辉长岩类具有相对高的REE、SiO2(平均48.99%)、K2O+Na2O(平均3.43%)、TiO2(平均1.26%)和明显低的Mg#值(平均62.4),表现出分异演化程度高于中段和东段。经反演得出香山岩体原始岩浆含MgO约10%,FeO约9%,TiO2约1.14%,与同一成矿带内其它含铜镍矿岩体原始岩浆成份相近,应为 普通的拉斑玄武质岩浆。因此,香山西钛铁矿床的形成机制可能是由普通的拉斑玄武质岩浆,经历了较高程度的分异演化导致钛铁氧化物在残余岩浆中逐步富集,岩浆在上升侵位过程中与地壳物质的混染,不仅促使了岩浆中硫化物的饱和,同时提高了岩浆体系的氧逸度,进而促使了钛铁氧化物结晶沉淀。对香山西钛铁矿床成因研究的启示意义在于,除我国攀西地区高钛的玄武质岩浆外,普通的拉斑玄武质岩浆,在有利的分异演化条件下(如初始低氧逸度、相对高度的分异演化、后期与地壳物质混染)也有可能形成大型钛铁矿床。 相似文献
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东天山香山铜镍硫化物-钛铁氧化物矿床成因 总被引:3,自引:1,他引:2
新疆东天山地区是中国重要的Cu-Ni-Au-Mo-Fe矿集区,目前,该地区唯一的一个铜镍硫化物-钛铁氧化物复合型矿床产自香山岩体中。通过对香山岩体的岩石地球化学和同位素地球化学研究,表明香山岩体是同源岩浆不同演化阶段的产物;硫化物熔离主要受控于岩浆自身分离结晶作用,同化混染和外来硫的加入对硫化物熔离具有一定促进作用。岩浆高度演化、残余岩浆中Ti、Fe元素富集、岩浆体系高氧逸度、富含流体相和挥发分使钛铁氧化物逐步结晶,并在合适的容矿空间富集成矿。 相似文献
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新疆香山杂岩体的成岩与成矿时序 总被引:6,自引:2,他引:4
新疆东天山香山地区镁铁-超镁铁杂岩体中产有香山中中型铜镍矿和香山西大型铜镍-钛铁矿床.杂岩体可分为辉长岩类、超镁铁质岩类和钛铁辉长岩类.野外证据表明三者具有先后侵位关系.本文通过对香山杂岩体不同岩相年代学资料梳理,补充了定年数据,获得香山杂岩体侵位年龄为283.2±2.1Ma,验证了不同岩石系列的侵位时序.此外,锆石年龄数据还记录了本地区曾经发生过的构造-岩浆热事件.利用角闪石40Ar/39Ar测年结果,并结合锆石U-Pb测年结果推测香山西岩体侵位较深,香山中岩体侵位较浅,进一步推测西岩体剥蚀量较大,而中岩体剥蚀量较小.结合野外穿插关系,厘定了杂岩体侵入-成矿事件的时序. 相似文献
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岩浆铜镍矿与钒钛磁铁矿的过渡类型--新疆哈密香山西矿床 总被引:20,自引:1,他引:20
铜镍硫化物矿床与钒钛磁铁矿矿床虽然同属与镁铁-超镁铁质岩有关的岩浆型矿床范畴,但在一般情况下,二者是不共生的.新疆东天山地区的香山西矿床则是一个铜镍矿与钛铁矿共生的实例.香山地区为一复式含矿杂岩体,最早期形成辉长岩(如角闪辉长岩、灰白色细粒辉长岩等)为主体的侵入;第二期侵入的是以辉橄岩、单辉橄榄岩、二辉橄榄岩等为主的超镁铁质岩,含铜镍硫化物矿化;第三期则为岩浆期后残余岩浆形成的含钛铁矿化的辉长岩(脉).香山西铜镍-钛铁矿床含矿岩石的碱度、镁铁指数、岩浆酸度、钙碱富集指数等地球化学参数,氧逸度和硫逸度等物理化学参数均介于独立的典型铜镍硫化物和典型钒钛磁铁矿矿床之间.矿床中磁铁矿较其他钒钛磁铁矿矿床(尾亚)具较高的V和Ti含量,同时黄铁矿和黄铜矿具较高的Co、Ni和Cu含量,反映出成矿过程中,Cu-Ni-Co系列与V-Ti-Fe系列的分离不够彻底.形成本区CuNi-VTi复合型矿床的原因,可能在于矿床所处独特的构造环境--产于造山带,而不是克拉通(边缘). 相似文献
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东天山香山铜镍硫化物矿床铂族元素地球化学特征及其意义 总被引:4,自引:0,他引:4
香山含铜镍矿岩体位于东天山北部的土墩-图拉尔根镁铁-超镁铁岩带中段,受康古尔塔格-黄山深大断裂控制,为由辉长岩、辉橄岩、细粒辉长岩和钛铁辉长岩组成的复式岩体。香山铜镍矿床岩石铂族元素总量(∑PGE)变化范围为0.74×10-9~2.82×10-9,矿石∑PGE变化范围为20.64×10-9~148.99×10-9,PPGE(Pd、Pt)和IPGE(Ru、Ir、Os)之间分异均较弱,二者具有相似PGE原始地幔标准化配分曲线形式。香山铜镍矿床原生岩浆w(MgO)下限值为4.97%,源于亏损型地幔,PGE丰度较高,母岩浆为高镁玄武质岩浆,PGE处于亏损状态且亏损的原因是发生了硫化物熔体不混溶作用,引发硫饱和的机制为地壳物质同化混染作用,以及橄榄石、辉石和基性斜长石等矿物的结晶分离作用。 相似文献
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新疆东天山香山岩体橄榄石特征及其成因意义 总被引:3,自引:0,他引:3
新疆东天山香山镁铁-超镁铁杂岩体位于东天山镜儿泉-黄山镁铁-超镁铁质岩带的西段,由香山东、香山中、香山西3个岩体组成。其中香山中产出中型铜镍矿,香山西为小型铜镍-钒钛铁复合型矿床。香山岩体橄榄石为贵橄榄石,Fo值多为81.90~85.66,Ni含量为638×10-6~2 283×10-6。模拟计算得出香山岩体母岩浆w(MgO)=10.70%,w(FeO)=10.66%,属于高镁玄武质岩浆。香山岩体橄榄石中Ni含量的最大值为2 283×10-6,母岩浆中Ni含量为326×10-6,是由原始地幔发生14%的部分熔融而成。香山岩体在橄榄石结晶过程中伴随硫化物熔离,隙间硅酸盐和硫化物对橄榄石作用明显,造成早期结晶橄榄石成分改变。 相似文献
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东天山黄山南镁铁-超镁铁岩体的岩浆演化过程:矿物学、Sr-Nd同位素特征的指示 总被引:1,自引:0,他引:1
黄山南镁铁-超镁铁质岩体位于东天山造山带觉罗塔格构造带内,属于土墩-黄山-图拉尔根镁铁-超镁铁质岩带。本文在前人研究的基础上,从橄榄石、辉石矿物学组成和全岩Sr、Nd同位素等方面对黄山南岩体进行了分析研究,并与黄山、黄山东、香山等典型含矿岩体作了对比,旨在进一步查明黄山南岩体的岩浆源区和母岩浆性质及其岩浆演化过程。Sr-Nd同位素特征表明黄山南岩体来自一个弱亏损的地幔源区,相较黄山、黄山东、香山等岩体的源区具有更加富集的特征。黄山南岩体中的橄榄石属于贵橄榄石,斜方辉石主要为古铜辉石,少数为紫苏辉石,单斜辉石主要为顽透辉石、普通辉石和少数的透辉石。单斜辉石和橄榄石的成分特征表明形成黄山南岩体的母岩浆为演化程度较低的拉斑玄武质岩浆,且母岩浆成分具有高Mg、高Ni的特点。计算得到黄山南岩体母岩浆的Fe O~T=13.20%、MgO=16.96%、Ni=377.2×10~(-6),且母岩浆在结晶分异过程中没有经历充分的硫化物熔离作用,这也是造成母岩浆中Ni含量较高以及岩体含矿性较差的主要因素。 相似文献
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圪塔山口含铜镍镁铁-超镁铁质岩体位于东天山黄山–镜儿泉–图拉尔根铜镍矿带东段。岩体由I-1,I-2,I-3,I-4四个小岩体组成,主要岩石类型为辉石橄榄岩、橄榄辉石岩、辉长岩和闪长岩,主要赋矿岩相为辉石橄榄岩。I-2号含矿岩体锆石SHRIMP U-Pb年龄为275.0±3.6 Ma,与东天山地区含铜镍矿镁铁–超镁铁岩体形成时代相近,I-4号不含矿岩体锆石SHRIMP U-Pb年龄为364.2±3.9 Ma,明显早于含矿岩体。样品的主量元素组成显示岩浆演化过程主要发生了橄榄石和少量辉石的分离结晶/堆晶作用;稀土元素球粒陨石标准化配分曲线呈轻稀土略富集的右倾型,Eu异常不明显;微量元素特征显示相对富集大离子亲石元素(Cs、Sr、Ba),适度亏损高场强元素(Nb、Ta、Ti)。岩石地球化学特征表明岩浆演化过程中遭受了较弱的中–下地壳物质混染。U/Th-Th/Zr、Ba/Th-Th/Yb图解,La/Nb、La/Ba和Ba/Nb比值表明岩浆源区遭受了明显的俯冲流体交代作用。综合含矿岩体年代学、岩石地球化学特征及区域演化历史,认为圪塔山口含矿岩体形成于碰撞后伸展背景,可能同时叠加了塔里木地幔柱活动的影响。 相似文献
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西南暗色岩铜镍硫化物矿化岩体与峨眉山玄武岩的关系--以云南金宝山岩体为例 总被引:23,自引:0,他引:23
内容提要本文以金宝山为典型实例,根据元素地球化学特征探讨了西南暗色岩铜镍硫化物矿化岩体与峨眉山玄武岩的关系。分析表明,金宝山超镁铁岩与低钛峨眉山玄武岩在元素地球化学特征上具有一致的岩浆成因属性,两者在成岩机制上互补,低钛峨眉山玄武岩普遍经历了橄榄石结晶分异和硫化物熔离亏损作用,金宝山成矿岩体则与低钛峨眉山玄武岩同源岩浆深部分异的堆晶相相对应,由堆晶橄榄石及熔离硫化物和部分残余熔体构成的“晶-糊”侵位形成,因此认为铜镍硫化物矿床成矿岩体与低钛峨眉山玄武岩为同源异相产物。 相似文献
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新疆巴楚小海子是近年来在塔里木大火成岩省探获的一个低品位-大吨位岩浆型钒钛磁铁矿床,其成岩成矿机制以及资源利用前景尚不清楚。文章针对小海子岩体2种含矿岩相橄榄辉长岩和橄榄辉石岩开展了地质地球化学研究。橄榄辉长岩相和橄榄辉石岩相虽然在空间上关系不明,但岩相学观察表明它们矿物组成的差异与矿物堆晶作用有关,且二者具有相似的稀土元素球粒陨石标准化和微量元素原始地幔标准化配分曲线,说明是同源岩浆演化的产物,橄榄石较低的Fo值(67.9~72.5)指示幔源母岩浆在深部岩浆房中发生了分异。小海子岩体和与相距约45 km的瓦吉里塔格相比,岩石组成和地球化学组成相似,表明为同源岩浆成因,但后者矿物组成变化范围更大,指示瓦吉里塔格岩体在形成过程中经历了更高程度的分离结晶作用,这可能是造成瓦吉里塔格岩体比小海子岩体的w(TiO2)更高的原因。小海子岩体虽然w(TiO2)较低(3%~4%),但铁钛氧化物固溶体分离结构不发育,且矿物颗粒粗大,使得铁和钛选矿解离比中国其他地区的钒钛磁铁矿更为容易,因此钛资源利用前景巨大,笔者建议出台地方性的勘查技术规范,为这类铁钛资源的开发利用提供技术标准。 相似文献
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金川矿床是我国最大的岩浆铜镍硫化物矿床,岩体主要由硫化物橄榄岩、含辉橄榄岩、二辉橄榄岩和橄榄辉石岩等岩相组成。以金川Ⅱ号岩体为例,根据岩相学观察和常量元素、微量元素地球化学特征的分析,试图对岩浆上升过程中的演化分异进行深入探讨,发现金川Ⅱ号岩体岩浆结晶分异演化过程主要包括深部岩浆房中尖晶石—橄榄石的分离结晶和浅部岩浆房辉石与斜长石的结晶,而地壳物质的同化混染发生在岩浆上升的整个过程,地壳物质的同化混染是导致母岩浆中硫饱和的主要因素。该岩浆分异演化过程间接支持了汤中立提出的"深部分异-熔离,依次贯入"成矿模式。 相似文献
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Xiao-Qi Zhang Xie-Yan Song Lie-Meng Chen Song-Yue Yu Wei Xie Yufeng Deng Jia-Fei Zhang Shu-Guang Gui 《Contributions to Mineralogy and Petrology》2013,166(1):193-209
The Permian Baima mafic layered intrusion, believed to be related to the S-undersaturated Emeishan high-Ti basalts, hosts a giant Fe–Ti-V oxide deposit in the lower part of the intrusion. Uniformly high Cu/Pd (1.9 × 106–6.1 × 104) and low Pd/Zr (<0.1) indicate that the Baima parental magma experienced prior sulfide segregation. Mantle-liked δ34S values and low S/Se values indicate negligible external sulfur addition. Primitive mantle-normalized PGE patterns and MELTS calculations indicate that extensive fractional crystallization (~59 %) of chromite, olivine and pyroxene at depth drove the primitive picritic magma to S saturation. Strong positive correlation between IPGE and PPGE and between PGE and V, Cr and S suggest that magmatic sulfide is the dominant mineral controlling the distribution of PGE in the Baima intrusion. A positive correlation between S and Cr, FeOT + TiO2 and V content, together with MELTS calculations, indicate that the parental magma of the Baima intrusion reached a second stage of S saturation in the shallower Baima magma chamber, which was likely triggered by decreasing Fe2+ accompanying magnetite precipitation. Primitive mantle-normalized PGE patterns for Baima intrusion rocks display similar trends to high-Ti basalts inside the Panxi area, suggesting that they are comagmatic, and following a similar differentiation trend. However, the lavas erupted before they reached sulfide saturation. The more evolved nature of high-Ti basalts outside the Panxi area indicate that they experienced more extensive pre-eruption fractional crystallization. Further fractional crystallization process led these lavas show more PGE fractionated feature. 相似文献
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香山铜镍矿体主要赋存于香山中岩体,与东天山地区其他典型铜镍矿床形成时代、岩浆源区性质、部分熔融程度及构造背景一致, 香山铜镍矿床中镁铁-超镁铁岩在岩体中所占比例小于20%,明显低于图拉尔根矿床超镁铁岩比例(约90%),暗示与图拉尔根矿床相比香山地区铜镍矿剥蚀深度较小, 深部具有继续寻找超镁铁质含矿岩体的潜力。香山矿床3个主要矿体(Ⅰ-1、Ⅰ和Ⅱ号矿体)由西向东Cu含量逐渐降低, Ni/Cu平均值分别为1.49、1.74和2.25, 呈逐渐增加的趋势, 且由西向东超镁铁岩比例变大, 这都表明含硫化物珠滴的岩浆流动为由东向西。高精度重力和磁法测量表明香山东和香山中岩体深部应该是相连的, 二者结合部位是深部含矿岩浆上升的通道。可控源音频大地电磁测深(CSAMT)揭示深部存在低阻异常体, 结合已施工的ZK4401和ZK5202地质资料, 认为该低阻异常体为含矿超镁铁岩的主体, 是下一步深部找矿的重点勘查对象。 相似文献
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Mingjie Zhang Chusi Li Piaoer Fu Peiqing Hu Edward M. Ripley 《Mineralium Deposita》2011,46(2):153-170
The Permian Huangshanxi Cu–Ni deposit is the second largest magmatic sulfide deposit discovered to date in a major Ni–Cu province
related to protracted basaltic magmatism in eastern Xinjiang, China. It is hosted by a small mafic–ultramafic intrusion comprised
predominantly of lherzolites, olivine websterites, gabbronorites, and gabbros. The Huangshanxi intrusion is coeval with Permian
basalts of tholeiitic and alkaline affinities in the Tuha and Tarim basins, respectively. To evaluate a possible genetic relationship
between the Huangshanxi intrusion and a specific type of coeval basalt in the region, as well as ore genesis in the intrusion,
we have carried out an integrated mineralogical, petrological, and geochemical study. Our data reveal that the Huangshanxi
intrusive rocks are characterized by relatively flat chondrite-normalized REE patterns, depletion in Nb and Ta, and elevated
εNd values varying between 6 and 10. These features are similar to those of coeval tholeiitic basalts in the nearby Tuha basin,
but are significantly different from those of coeval alkaline basalts in the relatively remote Tarim basin. The geochemical
similarities and differences suggest that the Huangshanxi intrusion is genetically related to the tholeiitic basalts in the
Tuha basin, not to the alkaline basalts in the Tarim basin, as suggested previously by some researchers. This implies that
regional exploration for the Huangshanxi-type Cu–Ni deposits should be centered in the Tuha basin instead of the Tarim basin.
More specifically, the uplifted areas around the Tuha basin where similar intrusions may have been brought close to the surface
should be carefully examined for mineralization potential. Intrusive relations and mass balance constraints from incompatible
trace elements and sulfide abundances suggest that the Huangshanxi intrusion represents a dynamic magma conduit through which
multiple pulses of magma ascended to higher levels or to the surface. Numerical simulation of magma evolution and mixing calculations
using Sr–Nd isotopes indicate that selective assimilation of S-bearing crustal materials is important for sulfide saturation
during the early stages of magma evolution when lherzolites formed. Fractional crystallization may have also played a role
in the attainment of sulfide saturation during the later stages of magma evolution when olivine websterites and gabbronorites
formed. In both cases, immiscible sulfide droplets were retained in the conduit to form disseminated sulfide lenses while
the fractionated silicate liquids and buoyant phases such as plagioclase continued to ascend. Extremely low PGE tenors in
the sulfide ores of the Huangshanxi deposit suggest that the parental magma was highly depleted in chalcophile elements possibly
due to previous sulfide segregation at depth. 相似文献
18.
Cihai and Cinan are Permian magnetite deposits related to mafic-ultramafic intrusions in the Beishan region, Xinjiang, NW China. The Cihai mafic intrusion is dominantly composed of dolerite, gabbro and fine-grained massive magnetite ore, while gabbro, pyrrhotite + pyrite-bearing clinopyroxenite and magnetite ore comprise the major units in Cinan. Clinopyroxene occurs in both deposits as 0.1–2 mm in diameter subhedral to anhedral grains in dolerite, gabbro and clinopyroxenite. High FeO contents (11.7–28.9 wt%), low SiO2 (43.6–54.3 wt%) and Al2O3 contents (0.15–6.08 wt%), and low total REE and trace element contents of clinopyroxene in the Cinan clinopyroxenite imply crystallization early, at high pressure. This clinopyroxene is FeO-rich and Si and Ti-poor, consistent with the clinopyroxene component of large-scale Cu-Ni sulfide deposits in the Eastern Tianshan and Panxi ares, as well as Tarim mafic intrusion and basalt, implying the Cinan mafic intrusion and sulfide is related to tectonic activity in the Tarim LIP. The similar mineral chemistry of clinopyroxene, apatite and magnetite in the Cihai and Cinan gabbros (e.g., depleted LREE, negative Zr, Hf, Nb and Ta anomalies in clinopyroxene, lack of Eu anomaly in apatite and similarity of oxygen fugacity as indicated by V in magnetite), indicate similar parental magmatic characteristics. Mineral compositions suggest a crystallization sequence of clinopyroxenite/with a small amount of sulfide – gabbro – magnetite ore in the Cinan deposit, and magnetite ore – gabbro – dolerite in Cihai. The basaltic magma was emplaced at depth, with magnetite segregation (and formation of the Cinan magnetite ores) occurring in relatively low fO2 conditions, after clinopyroxenite and gabbro fractional crystallization. The evolved Fe-rich basaltic magma rapidly rose to intermediate or shallow depths, forming an immiscible Fe-Ti oxide magma as fO2 increased and leaving a Fe-poor residual magma in the chamber. The residual magmas was emplaced at different levels in the crust, forming the Cihai gabbro and dolerite, respectively. Finally, the immiscible Fe-Ti oxide magma was emplaced into the earlier formed dolerite because of late magma pulse uplift, resulting in a distinct boundary between the magnetite ores and dolerite. 相似文献