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1.
为探讨山东蒙阴金伯利岩的成因及其岩浆演化过程,采用SEM、EPMA和LA-ICP-MS对该区金伯利岩中金云母的微组构进行了分析研究。结果表明,该区岩浆成因金云母主要呈斑晶、显微斑晶和基质云母产出。根据主量元素(Al、Fe和Mg#)特征将金云母分为原生金伯利岩金云母组、金云母-钡镁脆云母组、金云母-四配位铁金云母组和金云母-黑云母共生组。早期金云母结晶后,在岩浆上升过程中受源条件或矿物相在熔体中再吸收的影响,向Ⅱ型基质云母、四配位铁金云母、钡镁脆云母演化。晚期通过岩浆改造或与围岩的交代变质作用形成金云母-黑云母巨晶共生组。综上认为,蒙阴金伯利岩岩浆成分受到了多种改造,其演化过程是相当复杂的。  相似文献   

2.
王臻  陈振宇  李建康  李鹏  熊欣  杨晗  周芳春 《矿床地质》2019,38(5):1039-1052
仁里5号伟晶岩脉是湖南仁里超大型铌钽多金属矿床中含矿性最好且分带完整的一条含铌钽矿脉,云母作为其中的贯通性矿物出现于各分带中,由外部带至内部带表现出不同的成分和结构特征。文章通过对5号脉各带中的云母矿物进行详细的电子探针(EPMA)分析,查明了不同分带中云母矿物的演化规律:自外向内云母类型从白云母→锂云母的方向变化,Ⅰ带→Ⅲ带主要为白云母,Ⅳ带起出现富锂云母类型,并开始发育多种不平衡和交代结构;Ⅰ带→Ⅳ带云母的Li、Rb、Cs、F、Mg、Ti含量逐渐升高,K/Rb和K/Cs比值逐渐降低,从Ⅳ带→Ⅴ带,Mg、Ti降低、Li、Rb、Cs、F含量出现突增,其中,w(F)最高可达11.8%、w(Li_2O)可达8.33%,w(Cs_2O)为4.00%,而铯多硅锂云母中的w(Cs_2O)可达18.0%。这些证据均表明,5号脉具有极高的分异演化程度,从外部带向核部演化程度逐渐增高;Ⅳ带云母的突变很可能暗示其经历了岩浆-热液过渡过程,而Ⅴ带主要发育于热液阶段,此时的流体性质有利于Nb、Ta尤其是Ta元素的富集再沉淀。仁里矿床经历了岩浆-热液2阶段成矿作用,并且稀有金属的成矿很可能持续至热液阶段,这也是造就它特殊性(高品位)的重要原因。  相似文献   

3.
矿物的结构和成分可用来反演岩浆演化过程.为探讨酸性岩浆房内岩浆演化过程,以浙江拔茅火山主体英安岩中的斜长石为例,对其开展了矿物学、地球化学研究.结果显示,斜长石普遍具有核-幔-边结构,暗示其在喷发前处于开放性岩浆房内,并经历了复杂的岩浆过程.对代表性斜长石的电子探针成分及背散射图像分析表明,斜长石核部、幔部及边部分别具...  相似文献   

4.
金云母—蛭石间层矿物分晶层晶体化学式的计算及意义   总被引:10,自引:0,他引:10  
刘福生  彭同江 《岩石学报》2002,18(2):238-246
金云母-蛭石间层矿物由金云母晶层与蛭石晶层交叠排列而成,采用一般计算方法得出的晶体化学式不能充分揭示结构中金云母晶层与蛭石晶层各自的晶体化学特征。本文以化学成分分析与阳离子容量为基础,假定可交换性阳离子均为蛭石晶层层间阳离子,非交换性阳离子为金云母晶层层间阳离子,金云母晶层与蛭石晶层具有相同的八面体层等,计算出了结构中两种晶层的分晶层晶体化学式,确定了结构中两种晶层的比例和蛭石晶层的电荷数。并在此基础上讨论了新疆尉犁蛭石矿金云母-蛭石间层矿物的晶体化学特征。结果表明该方法设计合理,符合晶体化学原理,所计算的数据可靠。利用该方法计算出的两种晶层的比例为金云母-蛭石1:1规则间层矿物的确定提供了必要的依据。也为其它类似间层矿物的研究提供了一种计算分晶层晶体化学式的可行方法。  相似文献   

5.
根据矿物结构可以有效的识别开放性体系内的各种岩浆过程,在岩相学研究基础上,对全新世喷发的Ruapehu火山 Whakapapa组安山岩内的辉石斑晶进行了系统的矿物学分析。所研究样品中辉石斑晶以普通辉石及顽火辉石为主,具多样 结构与形态,根据其结构和成分特征可分为3类:(1)骸晶状的辉石(SP型),具有破碎的、筛孔状外形,核部具有异常高 的FeOT含量,可能为壳源捕掳晶;(2)具均一结构及成分的辉石(HP型),其内部未显示明显的熔融结构,形成于岩浆房 的内部,基本未受基性岩浆混合的影响;(3)具核-幔-边结构的 “绿核”辉石(GCP型),其幔部相比核部及边部具有更 高的En、Mg#、CaO、MgO和Cr2O3含量以及更低的FeOT、TiO2含量。且GCP辉石边部相比核部更加富CaO、MgO而贫 FeOT、TiO2。GCP型辉石幔部(边部)与核部形成明显的反环带结构,两者界线清晰,成分上存在突变,是偏基性岩浆注 入岩浆房边界层时,岩浆发生大规模扩散、混合之前形成于脉状岩浆“通道”内;而GCP辉石边部则结晶于混合后的岩浆 之中。辉石的结构及岩相学特征暗示,安山岩在喷发前经历了岩浆混合及地壳物质的混染,混合过程主要发生于地壳浅部 岩浆房的边界层及粥状层内,且这种混合过程可能是诱发火山喷发的重要机制之一。  相似文献   

6.
王亚飞 《地质与勘探》2022,58(6):1170-1178
山东牟平腊子沟金矿位于华北板块苏鲁造山带胶南-威海隆起区,牟平-乳山金矿成矿带中段,区内岩浆活动频繁,构造活动强烈,成矿地质条件优越。本文通过镜下显微结构观察、电子探针测试分析对腊子沟金矿载金矿物的组成、成分及金的赋存状态进行了研究,首次在该矿区发现含金独居石和含金磷灰石,金含量达到0.283%~0.456%,推测金可能通过类质同象形式替代磷灰石中的Ca2+或独居石中的稀土元素(Ce2+、 La2+)以晶格金的形式存在。前人研究认为成矿流体中金主要以Au[HS]2-和AuCl2-络合物形式进行迁移,本次含金磷酸盐矿物的发现表明:可能部分金以磷酸根络合物形式进行迁移。  相似文献   

7.
矿物环带结构是岩浆过程的良好记录,而矿物温压计可以定量计算岩浆的物理化学条件。该次研究对邯邢地区中生代侵入岩中两个浅成侵入体中典型的斜长石斑晶进行了电子探针和LA-ICP-MS元素面扫描,同时对其中不同成因的角闪石晶体进行了电子探针分析和物理化学条件计算。通过研究发现这两个样品中的斜长石斑晶属于循环晶。辉石闪长玢岩中的斜长石斑晶主要成分为更长石,而斑状石英二长岩中斜长石斑晶主要成分为中长石和拉长石。两者具有明显不同的环带结构,分别记录了不同的岩浆混合过程:前者记录了基性岩浆多次注入酸性岩浆房,并最终获得体积优势;后者记录了少量基性岩浆注入酸性岩浆房内,两者不断混合,形成均质化岩浆的过程。Fe元素从斜长石中心到边部有富集的趋势,表明岩浆最终向富铁的方向演化。角闪石温压计的计算结果表明,辉石闪长玢岩的岩浆房深度在5.5 km左右,温度大约为850 ℃,氧逸度大约为ΔNNO+1,熔体中的含水量大约为4.0%,其最终侵位于2.1 km的地壳深度。而斑状石英二长岩最终定位于2.0 km的地壳深度,角闪石结晶的平均温度为737 ℃,相对氧逸度为ΔNNO+1.2,熔体含水量为3.9%。  相似文献   

8.
唐红峰  周新民 《矿物学报》1999,19(3):308-314
龙游角闪橄榄岩出露于古老变质岩中,与围岩间的接触关系尚不清楚,但根据岩相学上矿物的平均共生关系,岩石的矿物化学组成和角闪橄榄岩及与之相关的花岗岩,金云母岩的微量元素地球化学特征,该橄榄岩很可能是富含流体组分的岩浆侵入而形成的,其形成的构造背景为具俯冲带性质的活动大陆边缘,富流体相的岩浆是由于其地幔源区受到了来自俯冲带的流体所交代的结果。  相似文献   

9.
杨喜安 《地质学报》2015,89(8):1437-1447
Maevatanana金矿床位于马达加斯加中部。由于地表覆盖较厚,有关该金矿床的研究程度甚低。目前通过ZK3-5钻孔发现,在Maevatanana金矿区隐伏花岗岩支下部发育金矿化, I-1金矿体中黄铁矿Re-Os等时线年龄为534±13 Ma,与泛非造山期后A型花岗岩的成岩时代范围内(537 ~522Ma)基本一致。野外地质证据和室内试验数据表明,Maevatanana金矿床的形成和泛非造山期后花岗岩具有密切的成因联系。该花岗岩是幔源起源的花岗岩。当铁镁质岩浆进入长英质岩浆时,产生了大量的气液流体,这种气液流体萃取了长英质岩浆中的金。因此,岩浆混合作用对Maevatanana金矿的形成起了重要作用。  相似文献   

10.
中国东南部中生代发育有拗陷型、断裂型、断陷型3种不同类型的盆地,其中前者发育于晚三叠世-早侏罗世,其内多为含煤建造;次者发育于中侏罗世-早白垩世,主要为火山岩建造;后者发育于白垩纪-古近纪,主要为陆相红岩建造。研究结果表明,盆地构造类型的演化与该区中生代壳内岩浆层的演化密切相关。与联合古陆解体相伴随的古太平洋板块俯冲使得东亚陆缘岩石圈的内能逐渐升高,其结果是壳内岩浆层的形成和增厚以及其上盖层岩石的弯曲变形,导致中生代早期众多拗陷盆地的形成;燕山早期的构造运动使印支期已强烈变形的地壳进一步破裂,为壳内岩浆层的物质溢出或喷发提供了通道条件,从而在重熔界面(岩浆层上界面)埋深较浅的本区东部形成众多火山岩盆地;系统内能在晚侏罗世后逐渐下降,地壳冷却收缩使得断块的重力调整逐渐占主导位置,形成众多由正断层控制的断陷盆地。  相似文献   

11.
Carbonatites of the Jacupiranga alkaline–carbonatite complex in São Paulo State, Brazil, were used to investigate mineral–fluid interaction in a carbonatite magma chamber because apatite showed a marked discontinuity between primary fluid inclusion-rich cores and fluid inclusion-poor rims. Sylvite and burbankite, apatite, pyrite, chalcopyrite and ilmenite are the common phases occurring as trapped solids within primary fluid inclusions and reflect the general assemblage of the carbonatite. The apatite cores had higher Sr and REE concentrations than apatite rims, due to the presence of fluid inclusions into which these elements partitioned. A positive cerium anomaly was observed in both the core and rim of apatite crystals because oxidised Ce4+ partitioned into the magma. The combined evidence from apatite chemistry, fluid inclusion distribution and fluid composition was used to test the hypotheses that the limit of fluid inclusion occurrence within apatite crystals arises from: (1) generation of a separate fluid phase; (2) utilization of all available fluid during the first stage of crystallization; (3) removal of crystals from fluid-rich magma to fluid-poor magma; (4) an increase in the growth rate of apatite; or (5) escape of the fluids from the rim of the apatite after crystallization. The findings are consistent with fractionation and crystal settling of a carbonatite assemblage in a fluid-stratified magma chamber. Secondary fluid inclusions were trapped during a hydrothermal event that precipitated an assemblage of anhedral crystals: strontianite, carbocernaite, barytocalcite, barite and norsethite, pyrophanite, magnesian siderite and baddeleyite, ancylite-(Ce), monazite-(Ce) and allanite. The Sr- and REE-rich nature of the secondary assemblage, and lack of a positive cerium anomaly indicate that hydrothermal fluids have a similar source to the primary magma and are related to a later carbonatite intrusion.  相似文献   

12.
鲁西碳酸岩中磷灰石的原位激光探针分析及其成岩意义   总被引:3,自引:2,他引:1  
邱检生  张晓琳  胡建  李真 《岩石学报》2009,25(11):2855-2865
以鲁西雪野和八陡碳酸岩中的磷灰石为对象,运用EMPA和LA-ICP-MS技术,分别测定了它们的主量与微量元素组成,并据此讨论了它们的成岩意义.研究结果表明,这些磷灰石富F(=1.07%~2.74%)贫Cl(<0.04%),种属为羟氟磷灰石或氟羟磷灰石.微量元素组成上富Sr、Th、U、Pb和轻稀土,是全岩中上述元素的主要载体之一.磷灰石的Sr、F含量与∑REE及LREE/HREE比值均表现出较明显的正相关性,其富Sr、贫Y和富轻稀土等特点与世界典型碳酸岩中的磷灰石相似,但它们具有更高的Sr/Y和Th/U比值,Sr、Ce、Th、Y含量接近地幔中由交代作用形成的磷灰石,说明其寄主碳酸岩岩浆源区应为遭受过流体交代作用的富集地幔.这些磷灰石的(La/Nd)_N比值>1,(La/Yb)_N比值多数在100以上,与世界其他地区典型碳酸岩中的磷灰石相比铕负异常相对更明显,表明其寄主碳酸岩浆经历一定程度的分异演化.雪野较八陡碳酸岩中磷灰石含更高的F、Sr和∑REE含量及(La/Yb)_N比值,说明其寄主岩浆的演化程度更高.  相似文献   

13.
The Nimchak granite pluton (NGP) of Chotanagpur Granite Gneiss Complex (CGGC), Eastern India, provides ample evidence of magma interaction in a plutonic regime for the first time in this part of the Indian shield. A number of outcrop level magmatic structures reported from many mafic-felsic mixing and mingling zones worldwide, such as synplutonic dykes, mafic magmatic enclaves and hybrid rocks extensively occur in our study domain. From field observations it appears that the Nimchak pluton was a vertically zoned magma chamber that was intruded by a number of mafic dykes during the whole crystallization history of the magma chamber leading to magma mixing and mingling scenario. The lower part of the pluton is occupied by coarse-grained granodiorite (64.84–66.61?wt.% SiO2), while the upper part is occupied by fine-grained granite (69.80–70.57?wt.% SiO2). Field relationships along with textural and geochemical signatures of the pluton suggest that it is a well-exposed felsic magma chamber that was zoned due to fractional crystallization. The intruding mafic magma interacted differently with the upper and lower granitoids. The lower granodiorite is characterized by mafic feeder dykes and larger mafic magmatic enclaves, whereas the enclaves occurring in the upper granite are comparatively smaller and the feeder dykes could not be traced here, except two late-stage mafic dykes. The mafic enclaves occurring in the upper granite show higher degrees of hybridization with respect to those occurring in the lower granite. Furthermore, enclaves are widely distributed in the upper granite, whereas enclaves in the lower granite occur adjacent to the main feeder dykes.Geochemical signatures confirm that the intermediate rocks occurring in the Nimchak pluton are mixing products formed due to the mixing of mafic and felsic magmas. A number of important physical properties of magmas like temperature, viscosity, glass transition temperature and fragility have been used in magma mixing models to evaluate the process of magma mixing. A geodynamic model of pluton construction and evolution is presented that shows episodic replenishments of mafic magma into the crystallizing felsic magma chamber from below. Data are consistent with a model whereby mafic magma ponded at the crust-mantle boundary and melted the overlying crust to form felsic (granitic) magma. The mafic magma episodically rose, injected and interacted with an overlying felsic magma chamber that was undergoing fractional crystallization forming hybrid intermediate rocks. The intrusion of mafic magma continued after complete solidification of the magma chamber as indicated by the presence of two late-stage mafic dykes.  相似文献   

14.
Melt inclusions in clinopyroxenes from lherzolitic xenoliths from the deep lithospheric mantle beneath the Slave Craton (Lac de Gras area, Canada) reveal multiple origins for carbonatitic melts. One type of inclusions consists of a series of silicate–carbonate–silicate concentric layers, interpreted to have unmixed under disequilibrium conditions during rapid ascent to the surface. Bulk major- and trace-element compositions are typical of Group 1 kimberlites and quantitative nuclear microprobe imaging of the globules reveals fractionation of related elements (e.g. F–Br, Nb–Ta) between the silicate and carbonate components. The globules probably formed by partial melting of carbonated peridotite, consistent with results of melting experiments and some models for the generation of kimberlite magmas. They provide evidence for a genetic relationship between some carbonate-rich magmas and ultramafic silicate magmas, and for the possibility of unmixing processes of these melts during their evolution.

The second inclusion type comprises carbonate-rich globules interpreted as samples of Mg-carbonatite melt that quenched on ascent to the surface. Bulk major- and trace-element compositions indicate that the melts were derived from a carbonate-rich source and oxygen, carbon, and strontium isotope data are consistent with the involvement of recycled crustal material and suggest that some mantle-derived carbonatites are unrelated to kimberlites.  相似文献   


15.
《地学前缘(英文版)》2019,10(2):769-785
The Weishan REE deposit is located at the eastern part of North China Craton (NCC), western Shandong Province. The REE-bearing carbonatite occur as veins associated with aegirine syenite. LA-ICP-MS bastnaesite Th-Pb ages (129 Ma) of the Weishan carbonatite show that the carbonatite formed contemporary with the aegirine syenite. Based on the petrographic and geochemical characteristics of calcite, the REE-bearing carbonatite mainly consists of Generation-1 igneous calcite (G-1 calcite) with a small amount of Generation-2 hydrothermal calcite (G-2 calcite). Furthermore, the Weishan apatite is characterized by high Sr, LREE and low Y contents, and the carbonatite is rich in Sr, Ba and LREE contents. The δ13CV-PDB (−6.5‰ to −7.9‰) and δ13OV-SMOW (8.48‰–9.67‰) values are similar to those of primary, mantle-derived carbonatites. The above research supports that the carbonatite of the Weishan REE deposit is igneous carbonatite. Besides, the high Sr/Y, Th/U, Sr and Ba of the apatite indicate that the magma source of the Weishan REE deposit was enriched lithospheric mantle, which have suffered the fluid metasomatism. Taken together with the Mesozoic tectono-magmatic activities, the NW and NWW subduction of Izanagi plate along with lithosphere delamination and thinning of the North China plate support the formation of the Weishan REE deposit. Accordingly, the mineralization model of the Weishan REE deposit was concluded: The spatial-temporal relationships coupled with rare and trace element characteristics for both carbonatite and syenite suggest that the carbonatite melt was separated from the CO2-rich silicate melt by liquid immiscibility. The G-1 calcites were crystallized from the carbonatite melt, which made the residual melt rich in rare earth elements. Due to the common origin of G-1 and G-2 calcites, the REE-rich magmatic hydrothermal was subsequently separated from the melt. After that, large numbers of rare earth minerals were produced from the magmatic hydrothermal stage.  相似文献   

16.
稀土元素(REE)作为"三稀资源"之一,是中国重要的战略性矿产资源,碳酸岩型稀土矿床是世界稀土的主要来源.成矿碳酸岩的岩浆演化以及稀土元素的富集和分异机理一直是碳酸岩型稀土矿床研究的热点和难点,国内外学者对碳酸岩的岩浆起源、岩浆演化过程中稀土元素富集与分异的机理进行了大量的研究与探讨,但仍存在较多的争议,限制了碳酸岩型稀土元素成矿理论的发展及国内外碳酸岩型稀土矿床的找矿勘查工作.文章重点对稀土成矿碳酸岩的起源、岩浆演化过程及在此过程中REE的富集与分异行为进行了详细的文献调研和评述,同时,基于笔者在冕宁牦牛坪稀土矿床前期的研究工作和最新发现,认为碳酸岩中普遍存在矿物学分带,它是岩浆演化过程的最佳记录,是不同成分矿物结晶分异作用的体现.对牦牛坪稀土矿床碳酸岩的矿物学分带特征及其中的熔体、熔流体和流体包裹体进行了初步描述与探讨,以期为研究碳酸岩的岩浆演化、岩浆-流体转化过程及稀土元素的富集与分异机理提供新的思路,促使对稀土碳酸岩矿物学分带及其对REE富集与分异的研究引起更多的关注和重视.  相似文献   

17.
Abstract The textural and compositional features of phlogopites in a contact-metamorphic dolomite marble inclusion in the Bergell intrusion (central Alps) and in a metasomatic reaction vein cutting through this marble suggest different origins for vein phlogopites:
(a) High-Al vein phlogopite represents former marble phlogopite which has been compositionally modified by reaction with the vein forming fluid.
(b) Low-Al vein phlogopite represents phlogopite precipitated from the vein forming fluid.
As both types of vein phlogopite were in contact with the same vein forming fluid at the same time, low-Al phlogopite most likely represents an equilibrium phlogopite composition, whereas high-Al phlogopite does not. High-Al vein phlogopite retained its Al-content from the contact-metamorphic marble parent phlogopite and only underwent Fe-Mg exchange with the metasomatic fluid.
All the vein phlogopites studied are strongly enriched in Fe relative to marble phlogopite. The data may suggest in general that phlogopite Al/Si ratios may be retained from the conditions under which the phlogopites first formed, whereas the Mg/Fe-ratios may be substantially modified by exchange with other ferromagnesian solid phases and/or a metamorphic fluid at later stages in their metamorphic history. This may have significant effects on calculated pressures and temperatures from thermobarometers involving biotite.  相似文献   

18.
西藏嘎拉勒矽卡岩型金(铜)矿床为近几年由西藏自治区第二地质大队发现的具有一定规模和潜力的矿床。本文以嘎拉勒金铜矿床中矽卡岩中金云母为研究对象,通过40Ar/39Ar同位素定年的方法,精确厘定了嘎拉勒矽卡岩型金铜矿床的成矿时代。金云母结晶在石榴子石和透辉石、黄铁矿和黄铜矿形成之间,并与石榴子石、针状透闪石和放射状阳起石密切共生。测试结果表明,嘎拉勒矿区金云母的40Ar/39Ar坪年龄为85.41±0.64 Ma,与相应的等时线年龄85.9±2.4 Ma一致,推测其成矿作用可能与拉萨地块和羌塘地块碰撞后在拉萨地块北侧发生岩石圈拆沉引起地幔物质上涌而诱发的岩浆活动有关。  相似文献   

19.
冈底斯北缘Pb-Zn-Ag-Cu-Fe多金属成矿带内发育有大量的矽卡岩矿床。本文研究的龙马拉矿床便是位于该成矿带东侧典型的层控式矽卡岩型Cu-Fe-Pb-Zn多金属矿床。对矿床成矿时代的精确厘定,是理解矿床成因机制和冈底斯北缘大规模矽卡岩型成矿地质背景的关键。本文首先对龙马拉矿床中与磁铁矿共生的蚀变云母进行了电子探针分析,结果显示这些云母为金云母;金云母的Ar-Ar同位素测年显示,其Ar-Ar坪年龄为56.32±0.48 Ma,等时线年龄为55.58±0.93 Ma。根据金云母与矿石矿物的共生关系可知,该年龄应代表龙马拉多金属矿床的成矿时代。综合前人的研究结果,认为龙马拉多金属矿床形成于印-亚陆陆碰撞的主碰撞汇聚成矿阶段,新特提斯洋壳板片的回卷很可能是该矿床形成的深部动力学机制。  相似文献   

20.
对白云鄂博稀土-铁-铌矿矿区一号碳酸岩墙内锆石U-Pb年龄进行了测定,三颗锆石测定数据点拟合直线与谐合线的上交点年龄为1416±77 Ma,它可能表明了白云鄂博矿区火成碳酸岩墙的侵入时代,而另外1颗锆石的表面年龄(1925±8 Ma)则可能是来自围岩的捕获锆石年龄.  相似文献   

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