Beryllium-10 in Australasian tektites: Constraints on the location of the source crater

By using accelerator mass spectrometry we have measured the ¹⁰Be concentrations of 86 Australasian tektites. Corrected to the time of tektite production ∼0.8 My ago, the ¹⁰Be concentrations (10⁶ atom/g) range from 59 for a layered tektite from Huai Sai, Thailand, to 280 for an australite from New South Wales, Australia. The average value is 143 ± 50. When tektites are sorted by country, their average measured ¹⁰Be concentrations increase slowly with increasing distance from Southeast Asia, the probable location of the tektite producing event, from 59 ± 9 for 6 layered tektites from Laos to 136 ± 20 for 20 splash-form tektites from Australia. The lowest ¹⁰Be concentrations for tektites fall on or within a contour centered off the shore of Vietnam, south of the Gulf of Tonkin (107°E; 17°N), but also encompassing two other locations in the area of northeastern Thailand previously proposed for the site of a single tektite-producing impact. The ¹⁰Be concentrations of layered tektites show only a weak anticorrelation (R ∼ −0.3) with the numbers of relict crystalline inclusions.Loosely consolidated, fine-grained terrestrial sediments or recently consolidated sedimentary rocks are the most likely precursor materials. Dilution of sediments with other kinds of rock raises problems in mixing and is not supported by petrographic data. Sedimentary columns that have the right range of ¹⁰Be concentrations occur off the coasts of places where sedimentation rates are high relative to those in the deep sea. A single impact into such a region, 15 to 300 m thick, could have propelled near-surface, high-¹⁰Be material farthest—to Australia—while keeping the deeper-lying, low-¹⁰Be layers closer to home. We do not rule out, however, other proposed mechanisms for tektite formation.     

Chemical analyses of Bosumtwi crater target rocks compared with the Ivory Coast tektites

The Bosumtwi crater, Ghana, was excavated in phyllites and greywackes with subordinate microgranite dykes and quartz veins of the 2000 Ma old Lower Birimian System with a granodiorite intrusion at Pepiakese on its northeastern side. New major and trace element analyses are presented for 7 phyllites, 5 greywackes, 2 microgranites, 3 Pepiakese intrusion rocks and 1 suevite using XRF and INNA.Means and standard deviations were calculated using all available modern analyses for each element in the Bosumtwi target rocks, Bosumtwi suevite glasses and Ivory Coast tektites. Good agreements between the means were found for the three groups with the suevite glasses and tektites having more limited compositional ranges than the target rocks. Least squares mixing between target rock types shows that the best fits to the tektite and suevite glass compositions require components of about a third or a quarter from the Pepiakese intrusion and some extra silica, derived from quartz veins, as well as the metasediments.The new data provide evidence for vapour phase fractionation of P₂O₅ and Na₂O in the tektites in addition to the previously reported Pb and Rb. Evidence for a meteoritic component in the tektites was found to be equivocal since the target rocks are probably a sufficient source of the meteorite indicator elements Ni and Ir.     

Single crystal U-Pb zircon age and Sr-Nd isotopic composition of impactites from the Bosumtwi impact structure, Ghana: Comparison with country rocks and Ivory Coast tektites

The 1.07?Myr old Bosumtwi impact structure (Ghana), excavated in 2.1-2.2?Gyr old supracrustal rocks of the Birimian Supergroup, was drilled in 2004. Here, we present single crystal U-Pb zircon ages from a suevite and two meta-graywacke samples recovered from the central uplift (drill core LB-08A), which yield an upper Concordia intercept age of ca. 2145?±?82?Ma, in very good agreement with previous geochronological data for the West African Craton rocks in Ghana. Whole rock Rb-Sr and Sm-Nd isotope data of six suevites (five from inside the crater and one from outside the northern crater rim), three meta-graywacke, and two phyllite samples from core LB-08A are also presented, providing further insights into the timing of the metamorphism and a possibly related isotopic redistribution of the Bosumtwi crater rocks. Our Rb-Sr and Sm-Nd data show also that the suevites are mixtures of meta-greywacke and phyllite (and possibly a very low amount of granite). A comparison of our new isotopic data with literature data for the Ivory Coast tektites allows to better constrain the parent material of the Ivory Coast tektites (i.e., distal impactites), which is thought to consist of a mixture of metasedimentary rocks (and possibly granite), but with a higher proportion of phyllite (and shale) than the suevites (i.e., proximal impactites). When plotted in a Rb/Sr isochron diagram, the sample data points (n?=?29, including literature data) scatter along a regression line, whose slope corresponds to an age of 1846?±?160?Ma, with an initial Sr isotope ratio of 0.703?±?0.002. However, due to the extensive alteration of some of the investigated samples and the lithological diversity of the source material, this age, which is in close agreement with a possible "metamorphic age" of ～?1.8-1.9?Ga tentatively derived from our U-Pb dating of zircons, is difficult to consider as a reliable metamorphic age. It may perhaps reflect a common ancient source whose Rb-Sr isotope systematics has not basically been reset on the whole rock scale during the Bosumtwi impact event, or even reflect another unknown geologic event.     

Xenotime in the Lower Buntsandstein of Central Europe: Evidence from cathodoluminescence investigation

Xenotime and zircon in heavy mineral separates of siliciclastic sediments can easily be distinguished by means of cathodoluminescence (CL). All shades of bright blue, yellow and grey to white colours have been reported for zircon while only bottle green to greenish yellow colours have been found in xenotime in heavy mineral separates of Lower Buntsandstein samples as well as in two samples from crystalline rocks from Bahia (Brazil) and the Karpaty Mts. (Slovakia). The CL-spectra of both minerals are commonly dominated by narrow emission bands of rare earth elements, especially Dy³⁺. The two different crystal lattices induce differences in the intensity ratios of the emission lines that are thought to be the reason for the different CL-colours. Additionally, intrinsic broad bands that may occur in the CL-spectra of zircon are missing in the xenotime spectra. The possibility to distinguish minerals with similar optical properties underlines the large potential of cathodoluminescence in sedimentary petrology.     

Evidence for the presence of the Vedde Ash in Central Europe

As part of ongoing research to find distal tephra, two lacustrine cores were analysed for the presence of volcanic ash layers, not visible to the naked eye: Soppensee, in Switzerland, and Rotmeer, in Southern Germany. The Laacher See Tephra (12,900 ka BP) is present as a visible layer in both sites. In both cores we found a discrete tephra horizon, with similar morphologies, in the middle of the biostratigraphic units equivalent to the Younger Dryas stadial. The vitreous components of these two tephra layers are geochemically identical. Comparison of the geochemical, stratigraphical, and chronological data from both sites, strongly suggest that the tephra can be attributed to the Icelandic Vedde Ash, a widely distributed horizon found throughout the North Atlantic and Northern Europe. Our results indicate that a precise and direct correlation between the Greenland ice cores and Central European sequences is now possible, based on a co-located tephra layer. This means that there is now the potential, to independently test climate synchronicity between Greenland and Europe, as far south as the Alps.     

Beryllium-10 contents of core samples from the St. Severin meteorite

Eleven samples taken from along the 35-cm core AIII of the LL-chondrite St. Severin have ¹⁰Be contents ranging from 20 to 28 dpm/kg and averaging 24.5 ± 0.9 dpm/kg. The ¹⁰Be contents increase with depth in the outermost 8 cm while at depths greater than 8 cm the ¹⁰Be contents change little. Calculations based on cross sections for proton-induced reactions that make ¹⁰Be disagree seriously with the measured values. Relatively large cross sections were constructed for neutron-induced reactions below 1 GeV. They give calculated ¹⁰Be production rates that agree with the measured values to within 10%. Cosmogenic ¹⁰Be in stony meteorites is better described as a medium-energy product than as a high-energy one.     

Evidence for Regional Stream Aggradation in the Central Oregon Coast Range during the Pleistocene-Holocene Transition

Low, nearly continuous terraces of similar age are present along streams in drainage basins that range in size from Drift Creek (190 km²) to the Umpqua River (11,800 km²) in the Oregon Coast Range. Radiocarbon ages from near the bose of fluvial sediments underlying these terraces are clustered at about 9000-11,000 ¹⁴C yr B.P. Beveled bedrock surfaces (straths) that underlie the fluvial sediments are 1-8 m above summer stream levels and are present along most of the nontidal reaches of the rivers that we studied. Where exposed, the bedrock straths are overlain by 2-11 m of fluvial sediment that consists of a bottom-stratum (channel) facies of sandy pebble-cobble gravel and a top-stratum (overbank) facies of sandy silt or silt. Eight radiocarbon ages from the fluvial sediments allow correlation of the lowest continuous terrace over a wide area and thus indicate that a regional aggradation episode occurred in Coast Range drainage basins during the Pleistocene-Holocene transition. The cause of such widespread aggradation is unknown but may be related to climate-induced changes in the frequency of evacuation of colluvium from hollows, which are common in all drainage basins in the region.     

Evidence for a nitrogen flux directly derived from the European subcontinental mantle in the Western Eger Rift, Central Europe

In the Czech-German border region of the Vogtland and NW Bohemia (western Eger rift, Central Europe), chemical and isotopic compositions (C, N, He, Ar) of free gas from a thermal water escape (fluorite mine, Schönbrunn), two mineral springs (“Eisenquelle,” Bad Brambach; “Sprudel III,” Bad Elster) and a mofette (Bublak) located along an ∼40-km long traverse are reported. The gases of Bublak and Bad Brambach are CO₂-rich (>99 vol.%) and have δ¹³C values of −1.95 and −4.29‰, respectively. With distance from the center of CO₂ degassing (Bublak) the δ¹³C values decrease, most likely due to physico-chemical fractionation of CO₂ between gaseous and aqueous phases rather than to admixture of organic/biogenic CO₂. The δ¹⁵N values range between −3.2 and −0.6‰, compared to an upper mantle value of −4.0 ± 1.0‰. The four locations are characterized by ³He/⁴He ratios decreasing from 5.9 R_a in the center (Bublak) to 0.8 R_a in the periphery (Schönbrunn) and give evidence for mixing of He from a deep-seated magmatic source with a crustal source. The location with the highest ³He/⁴He ratio (5.9 R_a) is accompanied by the highest ⁴⁰Ar/³⁶Ar (550). We argue that the nitrogen of the Bublak mofette gas is a mixture of predominantly atmospheric and mantle-derived components, whereas at the other three locations crustal nitrogen may also be present. The Bublak δ¹⁵N value of ≈−4.5 ± 1.0‰ represents the first free gas δ¹⁵N reference from the European subcontinental mantle (ESCM) and indicates that, in contrast to the ³He/⁴He ratios, the δ¹⁵N values are equal for ESCM and MORB, respectively.     

Geochemistry and Evolution of Subcontinental Lithospheric Mantle in Central Europe: Evidence from Peridotite Xenoliths of the Kozakov Volcano, Czech Republic

Neogene basanite lavas of Kozákov volcano, located alongthe Lusatian fault in the northeastern Czech Republic, containabundant anhydrous spinel lherzolite xenoliths that providean exceptionally continuous sampling of the upper two-thirdsof central European lithospheric mantle. The xenoliths yielda range of two-pyroxene equilibration temperatures from 680°Cto 1070°C, and are estimated to originate from depths of32–70 km, based on a tectonothermal model for basalticunderplating associated with Neogene rifting. The sub-Kozákovmantle is layered, consisting of an equigranular upper layer(32–43 km), a protogranular intermediate layer that containsspinel–pyroxene symplectites after garnet (43–67km), and an equigranular lower layer (67–70 km). Negativecorrelations of wt % TiO₂, Al₂O₃, and CaO with MgO and clinopyroxenemode with Cr-number in the lherzolites record the effects ofpartial fusion and melt extraction; Y and Yb contents of clinopyroxeneand the Cr-number in spinel indicate 5 to 15% partial melting.Subsequent metasomatism of a depleted lherzolite protolith,probably by a silicate melt, produced enrichments in the largeion lithophile elements, light rare earth elements and highfield strength elements, and positive anomalies in primitivemantle normalized trace element patterns for P, Zr, and Hf.Although there are slight geochemical discontinuities at theboundaries between the three textural layers of mantle, theretends to be an overall decrease in the degree of depletion withdepth, accompanied by a decrease in the magnitude of metasomatism.Clinopyroxene separates from the intermediate protogranularlayer and the lower equigranular layer yield ¹⁴³Nd/¹⁴⁴Nd valuesof 0·51287–0·51307 (_Nd = +4·6 to+8·4) and ⁸⁷Sr/⁸⁶Sr values of 0·70328–0·70339.Such values are intermediate with respect to the Nd–Srisotopic array defined by anhydrous spinel peridotite xenolithsfrom central Europe and are similar to those associated withthe present-day low-velocity anomaly in the upper mantle beneathEurope. The geochemical characteristics of the central Europeanlithospheric mantle reflect a complex evolution related to Devonianto Early Carboniferous plate convergence, accretion, and crustalthickening, Late Carboniferous to Permian extension and gravitationalcollapse, and Neogene rifting, lithospheric thinning, and magmatism. KEY WORDS: xenoliths; lithospheric mantle; REE–LILE–HFSE; Sr–Nd isotopes; Bohemian Massif     

Experimental studies of granitoids from the Central and Southern Coast Ranges,California

Summary The mineral phase relationships have been determined in the presence of excess water to a water pressure of 10 kb for three quartz diorites, a granodiorite, and a quartz monzonite from the Central and Southern Coast Ranges of California. Water pressure-temperature curves were constructed to locate the beginning of melting and the disappearance of K-feldspar, quartz, biotite, plagioclase and hornblende. Results indicate that plagioclase is the silicate liquidus phase in all granitoids studied at low water pressures, while hornblende or biotite is the silicate liquidus phase at high water pressure. New data illustrate the potent effect of water pressure on magma composition at temperatures 50° to 100°C above the solidus. At a water pressure of 1 kb, magmas are granitic to quartz monzonitic, while at water pressures of 10 kb, they are granodioritic to quartz dioritic.

---

Des études expérimentales des granitoids des chaînes du centre et du sud de la côte de la Californie

Résumé On a determiné en présence d'un excès d'eau jusqu'à une pression d'eau de 10 kb les corrélations entre les phases minérales de trois diorites quartziques, une granodiorite, et une monzonite quartzique obtenues des chaînes du centre et du sud de la côte de la Californie. On a utilisé des courbes de pression d'eau contre température afin de fixer le commencement de fusion et la disparition de K-feldspath, quartz, biotite, plagioclase, et hornblende. Les résultats indiquent que plagioclase est la phase liquidus de silicate pour tous les granitoids examinés aux pressions d'eau basses, en même temps que soit hornblende, soit biotite la phase liquidus de silicate aux pressions d'eau hautes. Des données nouvelles manifestent l'effet puissant de la pression d'eau sur la composition de magma aux températures élevées 50° ou 100°C plus que le solidus. Avec une pression d'eau de 1 kb les magmas sont granitiques à quartz monzonitiques; avec une pression d'eau de 10 kb ils sont granodioritiques à quartz dioritiques.

---

---

With 8 Figures     

Geochemical evidence of a near-surface history for source rocks of the central Coast Mountains Batholith,British Columbia

Major and trace elemental concentrations as well as Sr and Pb isotopic data, obtained for 41 plutonic samples from the Coast Mountains Batholith ranging in age from ～108 to ～50 Ma, indicate that the source regions for these rocks were relatively uniform and typical of Cordilleran arcs. The studied rocks are mineralogically and chemically metaluminous to weakly peraluminous and are mainly calc-alkaline. Initial whole-rock ⁸⁷Sr/⁸⁶Sr ratios range from 0.7035 up to 0.7053, whereas lead isotopic data range from 18.586 to 19.078 for ²⁰⁶Pb/²⁰⁴Pb, 15.545 to 15.634 for ²⁰⁷Pb/²⁰⁴Pb, and 37.115 to 38.661 for ²⁰⁸Pb/²⁰⁴Pb. In contrast to these relatively primitive isotopic data, δ ¹⁸O values for quartz separates determined for 19 of the samples range from 6.8 up to 10.0‰. These δ ¹⁸O values preclude the possibility that these melts were exclusively generated from the Mesozoic mantle wedge of this continental arc, just as the Sr and Pb data preclude significant involvement of an old (Precambrian) crustal/mantle lithospheric source. We interpret the high δ ¹⁸O component to represent materials that had a multi-stage crustal evolution. They were originally mafic rocks derived from a circum-Pacific juvenile mantle wedge that experienced a period of near-surface residence after initial crystallization. During this interval, these primitive rocks interacted with meteoric waters at low temperatures, as indicated by the high δ ¹⁸O values. Subsequently, these materials were buried to lower crustal depths where they remelted to form the high δ ¹⁸O component of the Coast Mountains Batholith. This component makes up at least 40% (mass) of the Cretaceous through Eocene batholith in the studied area. The remainder of the source materials comprising the Coast Mountains Batholith had to be new additions from the mantle wedge. A prolonged period of contractional deformation beginning with the Early Cretaceous collisional accretion of the Insular superterrane is inferred to have been responsible for underthrusting the high δ ¹⁸O component into the lower crust. We suggest that mafic rocks of the Insular superterrane (e.g. Alexander–Wrangellia) are of appropriate composition, and were accreted to and overthrust by what would become the Coast Mountains Batholith just prior to initiation of magmatism in the region.     

Seasonal Variability of Carbon Dioxide in the Rivers and Lagoons of Ivory Coast (West Africa)

We report partial pressure of CO₂ (pCO₂) and ancillary data in three rivers (Bia, Tanoé, and Comoé) and five lagoons (Tendo, Aby, Ebrié, Potou, and Grand-Lahou) in Ivory Coast (West Africa), during four cruises covering the main climatic seasons. The three rivers were oversaturated in CO₂ with respect to atmospheric equilibrium, and the seasonal variability of pCO₂ was due to dilution during the flooding period. Surface waters of the Potou, Ebrié, and Grand-Lahou lagoons were oversaturated in CO₂ during all seasons. These lagoons behaved similarly to the oligohaline regions of macrotidal estuaries that are CO₂ sources to the atmosphere due to net ecosystem heterotrophy and inputs of riverine CO₂ rich waters. The Aby and Tendo lagoons were undersaturated in CO₂ with respect to the atmosphere because of their permanent haline stratification (unlike the other lagoons) that seemed to lead to higher phytoplankton production and export of organic carbon below the pycnocline.     

Palaeozoic amalgamation of Central Europe: new results from recent geological and geophysical investigations

Multidisciplinary studies of geotransects across the North European Plain and Southern North Sea, and geological reexamination of the Variscides of the North Bohemian Massif, permit a new 3-D reassessment of the relationships between the principal crustal blocks abutting Baltica along the Trans-European Suture Zone (TESZ). Accretion was in three stages: Cambrian accretion of the Bruno–Silesian, Lysogory and Malopolska terranes; end-Ordovician/early Silurian accretion of Avalonia; and early Carboniferous accretion of the Armorican Terrane Assemblage (ATA). Palaeozoic plume-influenced metabasite geochemistry in the Bohemian Massif explains the progressive rifting away of peri-Gondwanan crustal blocks before their accretion to Baltica. Geophysical data, faunal and provenance information from boreholes, and dated small inliers and cores confirm that Avalonian crust extends beyond the Anglo-Brabant Deformation Belt eastwards to northwest Poland. The location and dip of reflectors along the TESZ and beneath the North European Plain suggest that Avalonian crust overrode the Baltica passive margin, marked by a high-velocity lower crustal layer, on shallowly southwest-dipping thrust planes forming the Heligoland–Pomerania Deformation Belt. The “Variscan orocline” of southwest Poland masks two junctions between the Armorican Terrane Assemblage (ATA) and previously accreted crustal blocks. To the east is a dextrally transpressive contact with the Bruno–Silesian and Malopolska blocks, accreted in the Cambrian, while to the north is a thrust contact with easternmost Avalonia, deeply buried beneath younger sedimentary cover. In the northeast Bohemian and Rhenohercynian Massifs Devonian “early Variscide” deformation dominated by WNW and NW-directed thrusting, records closure of Ordovician–Devonian seaways between detached “islands” of the ATA and Avalonia.     

Palaeoproterozoic high-pressure granulite overprint of the Archean continental crust: evidence for homogeneous crustal thickening (Man Rise, Ivory Coast)

The character of mountain building processes in Palaeoproterozoic times is subject to much debate. Based on the discovery of high-pressure granulites in the Man Rise (Côte d'Ivoire), several authors have argued that Eburnean (Palaeoproterozoic) reworking of the Archean basement was achieved by modern-style thrust-dominated tectonics.
A mafic granulite of the Kouibli area (Archean part of the Man Rise, western Ivory Coast) displays a primary assemblage (M1) containing garnet, diopsidic clinopyroxene, red-brown pargasitic amphibole, plagioclase (andesine), rutile, ilmenite and quartz. This assemblage is associated with a subvertical regional foliation. Symplectites that developed at the expense of the M1 assemblage contain orthopyroxene, clinopyroxene, plagioclase (bytownite), green pargasitic amphibole, ilmenite and magnetite (M2). Multiequilibrium thermobarometric calculations and P–T pseudosections calculated with thermocalc suggest granulite facies conditions of ∼ 13 kbar, 850 °C and <7 kbar, 700–800 °C for M1 and M2, respectively. In agreement with the qualitative information obtained from reaction textures and chemical zoning of minerals, this suggests an evolution dominated by decompression accompanied by moderate cooling. A Sm–Nd garnet – whole-rock age of 2.03 Ga determined on this sample indicates that this evolution occurred during the Palaeoproterozoic. It is argued that from the geodynamic point of view the observed features are best explained by homogeneous thickening of the margin of the Archean craton, re-heated and softened due to the accretion of hot, juvenile Palaeoproterozoic crust, as well as coeval intrusion of juvenile magmas. Crustal shortening was mainly accommodated by transpressive shear zones and by lateral crustal spreading rather than large-scale thrust systems.     

LA-MC-ICPMS and SHRIMP U-Pb dating of complex zircons from Quaternary tephras from the French Massif Central: Magma residence time and geochemical implications

Analyses of zircon grains from the Queureuilh Quaternary tephras (pumice) provide new information about their pre-eruptive history. U-Pb dating was performed in situ using two methods: SHRIMP and LA-MC-ICPMS equipped with a multi-ion counting system. Both methods provided reliable ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁶Pb/²³⁸U ratios as well as U and Th abundances required for U-Pb Concordia intercept age determination, after initial ²³⁰Th disequilibrium correction. The new LA-MC-ICPMS method was validated by dating a reference zircon (61.308B) and zircons from a phonolitic lava dated independently with the two techniques. A time resolution of about 20 kyr for 1 Ma zircon crystals was achieved for both methods.The clear euhedral zircon population from Queureuilh tephras is quite complex from several points of view: (1) some grains are reddish or yellowish while others are colorless; (2) the U and Th composition changes by more than an order of magnitude and Th/U is generally high (∼1-2); (3) there are three discrete ages recorded at 2.35 ± 0.04, 1.017 ± 0.008 and 0.640 ± 0.010 Ma.From the previously determined ⁴⁰Ar/³⁹Ar age at 0.571 ± 0.060 Ma [Duffell H. (1999) Contribution géochronologique à la stratigraphie volcanique du Massif des Monts Dore par la méthode ⁴⁰Ar/³⁹Ar. D.E.A. Univ. Clermont-Ferrand, 56 p.], the discontinuous zircon age populations, the color of the grains and their composition, we favor the following model as explanation: The oldest, less numerous group of reddish zircons represents xenocrystic grains resulting from assimilation of the local material during magma ascent. A primitive magma chamber, perhaps deep in crustal level, was formed at 1.0 Ma. The related magma, previously characterized by high Th/U ratio (2.2 ± 1.1), underwent rejuvenation during ascent to a new chamber at shallow depth and/or during injection of more mafic magmas. During this stage, at 0.64 Ma, the colorless zircon grains of lower Th/U ratio (1.3 ± 0.5) crystallized. This last stage defined the magma residence time of 70 kyr prior to eruption dated by the ⁴⁰Ar/³⁹Ar method. However, if the primitive magma is considered, the magma residence time as a whole from this first stage reached 446 kyr.In the light of the complex history of such magmas, which commonly involves recycling of zircon grains that precipitated tens to hundreds of kyr earlier than eruptions, the use of Zr concentration in geochemical modeling of whole rock compositional data can be problematic.     

Oxygen isotopic and chemical compositions of cosmic spherules collected from the Antarctic ice sheet: Implications for their precursor materials

Bulk chemical compositions and oxygen isotopic compositions were analyzed for 48 stony cosmic spherules (melted micrometeorites) collected from the Antarctic ice sheet using electron- and ion-microprobes. No clear correlation was found between their isotopic compositions and textures. The oxygen isotopic compositions showed an extremely wide range from −28‰ to +93‰ in δ¹⁸O and from −21‰ to +13‰ in Δ¹⁷O. In δ¹⁸O-δ¹⁷O space, most samples (38 out of 48) plot close to the terrestrial fractionation line, but 7 samples plot along the carbonaceous chondrite anhydrous mineral (CCAM) line. Three samples plot well above the terrestrial fractionation line. One of these has a Δ¹⁷O of +13‰, the largest value ever found in solar system materials. One possible precursor for this spherule could be ¹⁶O-poor planetary material that is still unknown as a meteorite. The majority of the remaining spherules are thought to be related to carbonaceous chondrites.     

Petrologic Reconnaissance of Franciscan Metagraywackes from the Diablo Range, Central California Coast Ranges

The complexly folded and faulted Diablo antiform representsa core of pervasively metamorphosed Late Mesozoic Franciscanrocks surrounded by roughly contemporaneous, less deformed,only feebly recrystallized Great Valley strata. The contactbetween the two lithologic series is nearly everywhere a high-anglethrust, the Ortigalita fault. Thin sections of 679 metaclastics from the 3000 km² Franciscanarea of the Diablo Range have been studied. A very rough correlationseems to exist between the degree of textural reconstitutionand phase assemblage. Many feebly metamorphosed Franciscan rockscontain relict clastic biotite; chlorite, white mica, and minoramounts of pumpellyite appear to be newly generated from claysand detrital plagioclase which has been albitized. In more thoroughlyrecrystallized Franciscan rocks, lawsonite has grown by hydrationof the minor An component of plagioclase, but more commonlyby the inferred interaction of interstitial clays+calcium carbonate;some of these rocks carry metamorphic aragonite. Intensely recrystallizedFranciscan metagraywackes contain jadeitic pyroxene±glaucophane.The observed changes in mineral assemblages are thought to reflectprogressive pressure increment at nearly constant temperature. In the north-western portion of the Range, jadeitic metaclasticrocks are located along the faulted margin of the antiform.Elsewhere there appears to be no clear relationship betweensystematic Franciscan parageneses and the tectonic contact withrocks of the Great Valley sequence. Evidently Diablo Range metaclasticassemblages do not owe their present areal distribution to apostulated process involving tectonic overpressures accompanyingthrusting of the Great Valley strata over the Franciscan alongthe Ortigalita fault. Jadeitic pyroxenebearing metagraywackesalso appear to be unrelated to the emplacement of alpine-typeperidotites.     

The Western Pacific Working Group of the INQUA Loess Commission: expansion from Central Europe

The INQUA Loess Commission expanded from its Central European base after the 1977 INQUA Congress. The first, furthest, and probably most successful expansion was the Western Pacific Working Group(WPWG). Co-operative loess research between China, Australia and New Zealand demonstrated the ideal working of a dedicated research group within the INQUA protocols. The WPWG functioned from 1978 to about 1988, a critical ten years during which China re-appeared on the world loess scene. The WPWG meeting in China in 1985 was a useful precursor to the INQUA Congress in Beijing in 1991. The main function of the WPWG turned out to be facilitating the return of China to the world of loess scholarship.     

Geochemistry of soils along a transect from Central Mexico to the Pacific Coast: A pilot study for continental-scale geochemical mapping

The Mexican Geological Survey (SGM), the National Institute of Statistics, Geography and Informatics (INEGI) and the Autonomous University of San Luis Potosi (UASLP) have established a multidisciplinary team with the objective of creating a national program of geochemical mapping of soils in Mexico. This is being done as part of the North American Soil Geochemical Landscapes Project in partnership with the US Geological Survey and the Geological Survey of Canada. As the first step, a pilot study was conducted over a transect that extends from the Mexico–US border near Ciudad Juarez in the north to the Pacific Ocean in the south. This pilot transect was conducted in two phases, and this paper presents results from the first phase, which sampled soils at about a 40-km spacing along a 730-km transect beginning in Central Mexico and ending at the Pacific Coast. Samples were collected from the A and C horizons at each site and 60 elements were analyzed. This pilot study demonstrates that geochemical mapping based on a 40-km spacing is adequate to identify broad-scale geochemical patterns. Geologic influence (i.e., soil parent material) was the most important factor influencing the distribution of elements along the transect, followed by the influence of regional mineralization. The study also showed that influence by human activities over the transect is minimal except possibly in large mining districts. A comparison of element abundance in the A horizon with the environmental soil guidelines in Mexico showed that the natural concentrations of the studied soils were lower than the established threshold for soil restoration with the exception of V and As. The former had a median value (75 mg/kg) approximately equal to the value established in Mexico for soil restoration in agricultural and residential lands (78 mg/kg), and the latter had three values higher than the 22 mg/kg threshold for soil restoration in agricultural and residential lands. These cases demonstrate the importance of knowing the national- and regional-scale geochemistry of Mexican soils as a support for the decision-making process, particularly for the proper formulation and application of soil guidelines designed to protect human and ecosystem health.