N2 2P Fluorescence from scattering of N22σg photoelectrons

N₂ 2P fluorescent intensity was monitored as a function of incident photon energy from 40 to 70 eV. A structure was seen near 52.2 eV. This feature is attributed to the scattering of photoelectrons originating from the N₂ 2σ_g molecular orbital with a binding energy of about 37.7 eV. The kinetic energy of these photoelectrons corresponds to the peak of the 2P excitation cross section at 14.5 eV.     

Calculation of the Intensity Ratio and Intrinsic Redshift Ratio of the Cerenkov Iron Kα and Kβ Lines and Its Possible Application in the Study of AGNs

We have pointed out that, when thermal relativistic electrons with an isotropic velocity distribution move through a region of dense gas or impinge upon its surface, the Cerenkov effect will produce a particular kind of atomic or ionic emission line, which we have called the “Cerenkov line-like radiation”. This prediction for the optical wavebands has been verified by laboratory experiments. In this paper, we extend this line-like radiation theory to the X-ray waveband and give the basic formulae for calculating the intensity ratio and intrinsic redshift ratio of the Cerenkov iron K_α and K_β lines, for different ionization orders of iron. Potential application of this calculated result may be found in the study of AGNs. The recent observations of NGC3783 show that besides the iron K_α line at ∼6.4 keV, there is also a very strong iron Kβ line at ∼7.0 keV, and that the ratio of equivalent widths between the two is anomalous: EWK_α/EWK_β ≈ 3.43. It is difficult to explain this by the conventional mechanism of “photoelectric absorption-fluorescence emission”. We suggest that the mechanism of Cerenkov line-like radiation can provides a way of solving this puzzle. Besides, we expect that the calculated intrinsic redshift ratio of Cerenkov iron K_α and K_β lines could be tested in future observations. If our suggestion is further supported by observations, then our view on the physical environment around the central massive black hole of an AGN will be greatly modified: the activity becomes more energetic and violent, and the gas, much denser than previously thought.     

A laboratory atlas of the 5ν1 NH3 absorption band at 6475 Å with applications to Jupiter and Saturn

The 5ν₁ absorption band of NH₃ is displayed from 6418 to 6550 Å. The total band intensity has been measured: S_B = 0.66 cm^?1m^?1amagat^?1. Line intensities and self-broadening coefficients have been measured for some of the prominent lines. Our line intensities are in good agreement with those of Rank et al. (1966), but are about 2 times greater than those of Mason (1970). The spectrum displayed was obtained photoelectrically at a pressure of 0.061 atm, and shows many more lines than the spectrum obtained by McBride and Nicholls (1972a) at a pressure of 0.39 atm. Therefore, our new measurements can provide the basis for making a more complete rotational analysis than those of McBride and Nicholls (1972a).Since the total band absorption has previously been measured by others on moderate resolution photoelectric scans of the spectra of Jupiter and Saturn, we can use the band intensity to derive the NH₃ abundance in the atmospheres of these two planets. The NH₃ abundances in a single vertical path obtained by this method are about 10m amagat for Jupiter and 2m amagat for Saturn. These results are in agreement with previous results obtained from higher resolution photographic spectra.     

Discrimination of α and β/γ interactions in a TeO2 bolometer

TeO₂ crystals have proven to be superb bolometers for the search of neutrinoless double beta decay in many respects. However, if used alone, they do not exhibit any feature that allows to discriminate an α energy deposit from a β/γ one. This fact limits their ability to reject the background due to natural radioactivity and eventually affects the sensitivity of the search. In this paper we show the results of a TeO₂ crystal where, in coincidence with its bolometric heat signal, also the luminescence light escaping the crystal is recorded. The results show that we are able to measure the light produced by β/γ particles, which can be explained as due to Cerenkov emission. No light is detected from α particles, allowing the rejection of this background source.     

Distributions of the Venus 1.27-μm O2 airglow and rotational temperature

Imaging spectroscopic observations of the Venus 1.27-μm O₂ airglow were carried out with ground-based telescopes from 2002 to 2007. Spectral image cubes were taken with the Okayama Astrophysical Observatory/infrared imaging spectrometer (superOASIS), the Gunma Astronomical Observatory/near-infrared camera and NASA's Infrared Telescope Facility/cryogenic echelle spectrograph (CSHELL). The rotational temperature shows weak positive correlation with the airglow intensity. However, there are some regions that have almost same intensities but different temperatures. The intensities tend to decrease from the anti-solar point to the terminator besides local features. These results indicate that there are local strong downward flows superimposed on the subsolar-to-antisolar circulation.     

Identification of a new band system of isotopic CO2 near 3.3 μm: Implications for remote sensing of biomarker gases on Mars

We present the discovery of a new vibrational band system of isotopic CO₂ (carbon dioxide) near 3.3 μm, with multiple strong P, Q and R lines in the prime spectral region used to search for Mars CH₄ (methane). The band system was discovered on Mars using high-resolution spectrometers (λ/δλ>40,000, CSHELL and NIRSPEC) at telescopes (NASA-IRTF and Keck-2) atop Mauna Kea, HI. The observed line intensities and frequencies agree very well with values predicted by a vibrational band model that we developed using known parameters for the molecular levels involved. Using this model, we synthesized spectra for different observing conditions (from Space and ground-based telescopes) and for different spectral resolving powers (5000 to 40,000). Although the total atmospheric burden on Mars is more than 150 times smaller than on Earth, the greater mixing ratio of CO₂ ensures that its column abundance on Mars is almost 20 times greater than on Earth. Thus, weak telluric CO₂ band systems appear much stronger on Mars. Many molecules of possible biological and geothermal interest have strong signatures at these wavelengths, in particular hydrocarbons owing to their strong ro-vibrational CH stretching modes. For example, the new isotopic CO₂ band-system encompasses lines of CH₄, C₂H₆ (ethane), CH₃OH (methanol) and H₂O (water). Implications for previous and future searches of biomarker gases are presented.     

High dispersion observations of Venus during 1972: The CO2 band at 7820Å

Forty-seven well exposed photographic plates of Venus which show the spectrum of the carbon dioxide band at 7820Å were obtained at Table Mountain Observatory in September and October 1972. These spectra showed a semiregular four-day variation in the CO₂ abundance over the disk of the planet (Young et al., 1974). We also find evidence for temporal variations in the rotational temperature of this band and temperature variations over the disk. The two quantities, CO₂ abundance and temperature, do not show any obvious relationship; however, an increase in the temperature usually is accompanied by a decrease in the abundance of CO₂. The average temperature, found from a curve-of-growth analysis assuming a constant CO₂ line width, is 249±1.4K (one standard deviation). This temperature is noticeably higher than the rotational temperature of 242±2K found for this same band in 1967 (Schorn et al., 1969) and of 242±1.2K in 1968–1969 (Young et al., 1971).     

Analysis of Titan CH4 3.3 μm upper atmospheric emission as measured by Cassini/VIMS

After molecular nitrogen, methane is the most abundant species in Titan’s atmosphere and plays a major role in its energy budget and its chemistry. Methane has strong bands at 3.3 μm emitting mainly at daytime after absorption of solar radiation. This emission is strongly affected by non-local thermodynamic equilibrium (non-LTE) in Titan’s upper atmosphere and, hence, an accurate modeling of the non-LTE populations of the emitting vibrational levels is necessary for its analysis. We present a sophisticated and extensive non-LTE model which considers 22 CH₄ levels and takes into account all known excitation mechanisms in which they take part. Solar absorption is the major excitation process controlling the population of the v₃-quanta levels above 1000 km whereas the distribution of the vibrational energy within levels of similar energy through collisions with N₂ is also of importance below that altitude. CH₄-CH₄ vibrational exchange of v₄-quanta affects their population below 500 km. We found that the ν₃ → ground band dominates Titan’s 3.3 μm daytime limb radiance above 750 km whereas the ν₃ + ν₄ → ν₄ band does below that altitude and down to 300 km. The ν₃ + ν₂ → ν₂, the 2ν₃ → ν₃, and the ¹³CH₄ν₃ → ground bands each contribute from 5% to 8% at regions below 800 km. The ν₃ + 2ν₄ → 2ν₄and ν₂ + ν₃ + ν₄ → ν₂ + ν₄ bands each contribute from 2% to 5% below 650 km. Contributions from other CH₄ bands are negligible. We have used the non-LTE model to retrieve the CH₄ abundance from 500 to 1100 km in the southern hemisphere from Cassini-VIMS daytime measurements near 3.3 μm. Our retrievals show good agreement with previous measurements and model results, supporting a weak deviation from well mixed values from the lower atmosphere up to 1000 km.     

Modeling the atmospheric limb emission of CO2 at 4.3 μm in the terrestrial planets

The MIPAS instrument on board Envisat, in Earth orbit, the PFS and OMEGA instruments on Mars Express, and VIRTIS on board Venus Express are currently providing a dataset of limb measurements of the CO₂ atmospheric fluorescence emission at 4.3‐μm from the upper atmosphere of the three planets. These measurements represent an excellent dataset to perform comparative studies between the terrestrial planets’ upper atmospheres, and also to test our theoretical understanding of these emissions. In order to exploit these datasets, we apply a set of non-local thermodynamic equilibrium (non-LTE) models developed at the IAA/CSIC, in Granada, Spain, to a selection of data. In general, the models can explain the main spectral features of the measurements, and also the altitude and solar zenith angle variations. However, the simulations for Mars and Venus give an incorrect ratio of the emissions at two wavelengths, 4.4 and . In order to explain this deficiency, a revision of the most uncertain non-LTE energy transfer parameters has been performed. The quenching rate of ν₃ quanta of high-energy CO₂ states by CO₂ itself could reduce the model-data discrepancy if increased by a factor 2-4, still within its current uncertainty range. This factor, however, is subject to the uncertainty in the thermal structure. A number of simulations with the non-LTE models were also used to study and compare the role of radiative transfer in this spectral region in the three terrestrial planets. Sensitivity studies of density and temperature are also presented, and they permit an analysis of how the differences between the planets and between the three instruments affect their sounding capabilities.     

Theoretical interpretation of the 0.7820 μm CO2 band and 0.8226 μm H2O line on Venus

We have analyzed the P6, P8, and P10 lines in the 0.7820 μm CO₂ band of Venus using a scattering model. Our new results compare favorably with previous results from the 1.05 μm CO₂ band. We considered nonabsorbing and absorbing clouds. We found that the anisotropic scattering mean free path for both models at the 0.2atm level is between 0.55 and 0.73km, a range close to the value of 1 km for terrestrial hazes. We used our scattering models to synthesize the 0.8226 μm H₂O line, assuming that the clouds are composed of sulfuric acid drops, and found our nonabsorbing cloud required a sulfuric acid concentration of 82% by weight, while our thicker absorbing cloud required a concentration of 89%. A comparison of the variation of optical depth with height for our cloud models with the variation reported by Prinn (1973, Science182, 1132–1134) showed that, within a factor of 2, the variation for Prinn's thinnest cloud agreed with ours. Whitehill and Hansen (1973, Icarus20, 146–152) have recently confirmed the work of Regas et al. (1973a, J. Quant. Spectry. Radiative Transfer13, 461–463) which showed that two cloud layers are not required to explain the CO₂ phase variation of Venus. Prinn's recent photochemical study of sulfuric acid clouds further supports a single, continuous cloud layer in the line formation region instead of two cloud layers with an extensive clear region between. The single layer model appears more likely because the maximum particle density in Prinn's cloud occurs in the clear region between the two layers in the models of Hunt (1972, J. Quant. Spectry. Radiative Transfer12, 405–419) and Carleton and Traub (1972, Bull. Amer. Astron. Soc.4, 362.).     

On the interpretation of the “inverse phase effect” for CO2 equivalent widths on Venus

Computations of the equivalent widths of absorption lines as a function of planetary phase angle are made for a homogeneous cloud with particles having the properties (shape, refractive index, and size distribution) deduced from polarimetry of Venus. The computed equivalent widths show an “inverse phase effect” comparable to that which is observed for CO₂ lines on Venus. This result verifies a recent suggestion of Regas et al. that the existence of an inverse phase effect does not by itself imply the presence of multiple layers of scattering particles in the atmosphere of Venus.     

First observation of 628 CO2 isotopologue band at 3.3 μm in the atmosphere of Venus by solar occultation from Venus Express

The new ESA Venus Express orbiter is the first mission applying the probing technique of solar and stellar occultation to the atmosphere of Venus, with the SPICAV/SOIR instrument. SOIR is a new type of spectrometer used for solar occultations in the range 2.2-4.3 μm. Thanks to a high spectral resolving power R∼15,000-20,000 (unprecedented in planetary space exploration), a new gaseous absorption band was soon detected in the atmospheric transmission spectra around 2982 cm⁻¹, showing a structure resembling an unresolved Q branch and a number of isolated lines with a regular wave number pattern. This absorption could not be matched to any species contained in HITRAN or GEISA databases, but was found very similar to an absorption pattern observed by a US team in the spectrum of solar light reflected by the ground of Mars [Villanueva, G.L., Mumma, M.J., Novak, R.E., Hewagama, T., 2008. Icarus 195 (1), 34-44]. This team then suggested to us that the absorption was due to an uncatalogued transition of the ¹⁶O¹²C¹⁸O molecule. The possible existence of this band was soon confirmed from theoretical considerations by Perevalov and Tashkun. Some SOIR observations of the atmospheric transmission are presented around 2982 cm⁻¹, and rough calculations of line strengths of the Q branch are produced, based on the isotopic ratio measured earlier in the lower atmosphere of Venus. This discovery emphasizes the role of isotopologues of CO₂ (as well as H₂O and HDO) as important greenhouse gases in the atmosphere of Venus.     

2002 AA29: Earth's recurrent quasi-satellite?

We study the dynamical evolution of Asteroid 2002 AA₂₉. This object moves in the co-orbital region of the Earth and is the first known asteroid which experiences recurrent horseshoe-quasi-satellite transitions. The transitions between the HS and QS states are unique among other known Earth co-orbital asteroids and in the QS state 2002 AA₂₉ remains very close to Earth (within 0.2 AU for several decades [Connors, M., Chodas, P., Mikkola, S., Wiegert, P., Veillet, C., Innanen, K., 2002. Meteorit. Planet. Sci. 37, 1435-1441]). Based on results obtained analytically by Brasser et al. [Brasser, R., Heggie, D.C., Mikkola, S., 2004b. Celest. Mech. Dynam. Astron. 88, 123-152] we developed a simple analytical method to describe and analyze the motion of 2002 AA₂₉. We distinguish a few moments in time crucial for understanding its dynamics. Near 2400 and 2500 this object will be close to going through the maxima of the averaged disturbing function and it will either change its co-orbital regime by transition from the HS into QS state, or leave the librating mode. These approaches generate instability in the motion of 2002 AA₂₉. By means of 66 observations, covering a two-year interval, we extend the analysis of the long term evolution of this object presented by Connors et al. [Connors, M., Chodas, P., Mikkola, S., Wiegert, P., Veillet, C., Innanen, K., 2002. Meteorit. Planet. Sci. 37, 1435-1441] and Brasser et al. [Brasser, R., Innanen, K.A., Connors, M., Veillet, C., Wiegert, P., Mikkola, S., Chodas, P.W., 2004a. Icarus 171, 102-109]. Our analysis is based on a sample of 100 cloned orbits. We show that the motion of 2002 AA₂₉ is predictable in the time interval [−2600,7100] and outside of this interval the past and future orbital history can be studied using statistical methods.     

FT-IR measurements of cold C3H8 cross sections at 7–15 μm for Titan atmosphere

We present absorption cross sections of propane (C₃H₈) at temperatures from 145 K to 297 K in the 690–1550 cm⁻¹ region. Pure and N₂-broadened spectra were measured at pressures from 3 Torr to 742 Torr using a Bruker IFS125 FT-IR spectrometer at JPL. The gas absorption cell, developed at Connecticut College, was cooled by a closed-cycle helium refrigerator. The cross sections were measured and compiled for individual spectra recorded at various experimental conditions covering the planetary atmosphere and Titan. In addition to the cross sections, a propane pseudoline list with a frequency grid of 0.005 cm⁻¹, was fitted to the 34 laboratory spectra. Line intensities and lower state energies were retrieved for each line, assuming a constant width. Validation tests showed that the pseudoline list reproduces discrete absorption features and continuum, the latter contributed by numerous weak and hot band features, in most of the observed spectra within 3%. Based on the pseudoline list, the total intensity in the 690–1550 cm⁻¹ region was determined to be 52.93 (±3%) × 10⁻¹⁹ cm⁻¹/(molecule cm⁻²) at 296 K; this value is within 3% of the average from four earlier studies. Finally, the merit of the pseudoline approach is addressed for heavy polyatomic molecules in support of spectroscopic observation of atmospheres of Titan and other planets. The cold cross sections will be submitted to the HITRAN database (hitran.harvard.edu), and the list of C₃H₈ pseudolines will be available from a MK-IV website of JPL (http://mark4sun.jpl.nasa.gov/data/spec/Pseudo).     

Comparisons of Supergranule Characteristics During the Solar Minima of Cycles 22/23 and 23/24

Supergranulation is a component of solar convection that manifests itself on the photosphere as a cellular network of around 35 Mm across, with a turnover lifetime of 1 – 2 days. It is strongly linked to the structure of the magnetic field. The horizontal, divergent flows within supergranule cells carry local field lines to the cell boundaries, while the rotational properties of supergranule upflows may contribute to the restoration of the poloidal field as part of the dynamo mechanism, which controls the solar cycle. The solar minimum at the transition from cycle 23 to 24 was notable for its low level of activity and its extended length. It is of interest to study whether the convective phenomena that influence the solar magnetic field during this time differed in character from periods of previous minima. This study investigates three characteristics (velocity components, sizes and lifetimes) of solar supergranulation. Comparisons of these characteristics are made between the minima of cycles 22/23 and 23/24 using MDI Doppler data from 1996 and 2008, respectively. It is found that whereas the lifetimes are equal during both epochs (around 18 h), the sizes are larger in 1996 (35.9 ± 0.3 Mm) than in 2008 (35.0 ± 0.3 Mm), while the dominant horizontal velocity flows are weaker (139 ± 1 m s⁻¹ in 1996; 141 ± 1 m s⁻¹ in 2008). Although numerical differences are seen, they are not conclusive proof of the most recent minimum being inherently unusual.     

A measurement of the O2(b1Σg+−X3Σg−) atmospheric band and the OI(1S) green line in the nightglow

Simultaneous measurements of the nightglow profiles of the O₂(b¹Σ_g⁺?X³Σ_g^?) A-band, the atomic oxygen green line and the OH (8?3) Meinel band are presented. The altitude profiles are used to determine both the excitation mechanisms for the oxygen emissions and the atomic oxygen altitude distribution. It is shown that the measurements are consistent with a green line excitation through the Barth mechanism and that the molecular oxygen emission is excited through oxygen recombination and the reaction between OH¹ and atomic oxygen. The derived atomic oxygen concentrations,6.2 × 10¹¹cm^?3at 98km, are consistent with the Jacchia (1971) model.     

Transport Characteristics of the Near-Surface Layer of the Nucleus of Comet 67P/Churyumov–Gerasimenko

Solar System Research - The paper considers the free molecular flow of gas through the dusty porous surface layer of a comet nucleus. The study is based on computer models of generation of a porous...     

On the relationship of 6300 Å airglow to parameters of the F-region of the ionosphere

It is shown that variations in 6300 Å airglow intensities can, under certain assumptions, be simply related to $\text{?}{}_0\text{F2}$ and its time derivative. In deriving the relationship it is not necessary to assume that the concentration of the neutral atmosphere remains constant and so the relationship is useful on occasions when changes in the neutral atmosphere do occur making it difficult to obtain agreement between observed and calculated 6300 Å intensities; An example is given of a night in which a post-midnight enhancement occurred in the airglow and for which the observations could not be reproduced using a neutral atmosphere constant with time. It is shown that the airglow variations can be explained in terms of the variations of f₀F2, implying that the airglow is due to recombination and that, during the night, changes occurred in the concentrations of the constituents of the neutral atmosphere.