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Crystallization of anatectic melts in high-temperature metamorphic terrains releases volatile-rich magmas that can be transported into adjacent lithologies. This study addresses the variations in the oxygen, boron and hydrogen isotopic composition of aplite-pegmatite dikes that formed during the crystallization of anatectic melts in regional high-temperature metamorphism on the island of Naxos, Greece, and propagated upward into the overlying sequences of metamorphic schist. The transport distance of these dikes was increased through a significant horizontal component of travel that was imposed by contemporaneous low-angle extensional shearing. Laser fluorination oxygen isotope analyses of quartz, tourmaline, garnet, and biotite mineral separates from the aplite-pegmatite dikes show a progressive rise in δ18O values with increasing distance from the core. Oxygen isotope fractionations among quartz, tourmaline, and garnet show temperature variations from > 700°C down to ∼400°C. This range is considered to reflect isotopic fractionation beginning with crystallization at high temperatures in water-undersaturated conditions and then evolving through lower temperature crystallization and retrograde sub-solidus exchange. Two processes are examined for the cause of the progressive increase in δ18O values: (1) heterogeneous δ18O sources and (2) fluid-rock exchange between the aplite/pegmatite magmas and their host rock. Although the former process cannot be ruled out, there is as yet no evidence in the exposed sequences on Naxos for the presence of a suitable high δ18O magma source. In contrast, a tendency for the δ18O of quartz in the aplite/pegmatite dikes to approach that of the quartz in the metamorphic rock suggests that fluid-rock exchange with the host rock may potentially be an important process. Advection of fluid into the magma is examined based on Darcian fluid flow into an initially water-undersaturated buoyantly propagating aplitic dike magma. It is shown that such advective flow could only account for part of the 18O-enrichment, unless it were amplified by repeated injection of magma pulses, fluid recycling, and deformation-assisted post-crystallization exchange. The mechanism is, however, adequate to account for hydrogen isotope equilibration between dike and host rock. In contrast, variations in the δ11B values of tourmalines suggest that 11B/10B fractionation during crystallization and/or magma degassing was the major control of boron geochemistry rather than fluid-rock interaction and that the boron isotopic system was decoupled from that of oxygen. 相似文献
3.
The most important source of yellow gem elbaite is the Canary mining area in the Lundazi District of eastern Zambia. The tourmaline has been mined since 1983 from both pegmatite and eluvial/alluvial deposits, in colors typically ranging from yellow-green to yellow to orange and brown; much of the orange-to-brown material is heated to attain a ‘golden’ or ‘canary’ yellow color. The elbaite is Mn-rich (up to 9.18 wt% MnO documented in the literature) and contains small amounts of Ti and little or no Fe. The distinctive composition of this tourmaline is probably the result of the early crystallization of abundant schorl from an unusual B-rich, Li-poor pegmatite melt, which depleted Fe while conserving Mn until the late-stage crystallization of gem pockets. The simple mineralogy of the pegmatite consists of feldspars, quartz, and tourmaline; the lack of micas, phosphates, or Li minerals, and the presence of very little garnet, allowed Mn to fractionate to high levels during pegmatite crystallization. The presence of abundant gem tourmaline in a Li-poor pegmatite is highly unusual. 相似文献
4.
Rainer Thomas Paul Davidson Dieter Rhede Michael Leh 《Contributions to Mineralogy and Petrology》2009,157(4):505-523
In this paper, we show that the crystallization of miarolitic pegmatites at K?nigshain started at about 700°C, in melts containing
up to 30 mass% water. Such high water concentration at low pressures (1–3 kbar) is only possible if the melts are peralkaline.
Such peralkaline melts are highly corrosive, and reacted with the wall rock—here the granite host—forming the graphic granite
zone, in part via a magmatic–metasomatic reaction. With cooling, the water concentration in some melt fractions increased
up to 50 mass% H2O. The melt-dominated system ends below 600°C and passes into a fluid-dominated system, the beginning of which is characterized
by strong pressure fluctuations, caused by the change of OH and CO3
2− in the melt, to molecular water and CO2. We note two generations of smoky quartz, one crystallized above the β–α-transition of quartz (≈573°C), and one below, both
of which contain melt inclusions. This indicates that some melt fraction remains during at least the higher-temperature portion
of the growth of minerals into the miarolitic cavity, contradicting the view that minerals growing into a pegmatite chamber
only do so from aqueous fluids. We show that the K?nigshain miarolitic pegmatites are part of the broad spectrum of pegmatite
types, and the processes active at K?nigshain are representative of processes found in most granitic pegmatites, and are thus
instructive in the understanding of pegmatite formation in general, and constraining the composition and characteristics of
pegmatite-forming melts.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
5.
Dirk Küster Rolf L. Romer Dandena Tolessa Desta Zerihun K. Bheemalingeswara Frank Melcher Thomas Oberthür 《Mineralium Deposita》2009,44(7):723-750
The Kenticha rare-element pegmatite, a globally important tantalite source in the Neoproterozoic Adola Belt of southern Ethiopia,
is a highly fractionated, huge (2,000 m long and up to 100 m thick), subhorizontal, sheet-like body, discordantly emplaced
in ultramafic host rock. It corresponds to the spodumene subtype of the rare-element pegmatite class and belongs to the lithium–cesium–tantalum
petrogenetic family. The Kenticha pegmatite is asymmetrically zoned from bottom to top into granitic lower zone, spodumene-free
intermediate zone, and spodumene-bearing upper zone. A monomineralic quartz unit is discontinuously developed within the upper
zone. Whole-rock data indicate an internal geochemical differentiation of the pegmatite sheet proceeding from the lower zone
(K/Rb ~36, K/Cs ~440, Al/Ga ~2,060, Nb/Ta ~2.6) to the upper zone (K/Rb ~19, K/Cs ~96, Al/Ga ~1,600, Nb/Ta ~0.7). The latter
one is strongly enriched in Li2O (up to 3.21%), Rb (up to 4,570 ppm), Cs (up to 730 ppm), Ga (up to 71 ppm), and Ta (up to 554 ppm). Similar trends of increasing
fractionation from lower zone to upper zone were obtained in muscovite (K/Rb 23–14, K/Cs 580–290, K/Tl 6,790–3,730, Fe/Mn
19–10, Nb/Ta 6.5–3.8) and columbite–tantalite (Mn/Mn + Fe 0.4–1, Ta/Ta + Nb 0.1–0.9). The bottom-to-top differentiation of
the Kenticha pegmatite and the Ta mineralization in its upper part are principally attributed to upward in situ fractionation
of a residual leucogranitic to pegmatitic melt, largely under closed system conditions. High MgO contents (up to 5.05%) in
parts of the upper zone are the result of postmagmatic hydrothermal alteration and contamination by hanging wall serpentinite.
U–Pb dating of Mn-tantalite from two zones of the Kenticha pegmatite gave ages of 530.2 ± 1.3 and 530.0 ± 2.3 Ma. Mn-tantalite
from the Bupo pegmatite, situated 9 km north of Kenticha, gave an age of 529.2 ± 4.1 Ma, indicating coeval emplacement of
the two pegmatites. The emplacement of the pegmatites is temporally related to postorogenic granite magmatism, producing slightly
peraluminous, I-type plutons in the area surrounding the Kenticha pegmatite field. Fractionated members of this suite might
be envisaged as potential parental magmas. 相似文献
6.
Chemical composition of tourmaline from the Yunlong tin deposit, Yunnan, China: implications for ore genesis and mineral exploration 总被引:1,自引:0,他引:1
Summary ?The Yunlong tin deposit is located in the northern part of the Lancangjiang metamorphic zone of the Sanjiang Tethys orogen
series in western Yunan province of China. It consists of vein-type cassiterite ores, which are mainly hosted in migmatites
of Caledonian age. Abundant tourmaline is associated with the ores, quartz–tourmaline veins and barren migmatized gneiss and
migmatites. A detailed electron microprobe study has been carried out to document the chemical compositions of tourmaline
from this deposit. The results exhibit a systematic compositional change that might be used as tracer for ore genesis and
in prospecting for tin mineralization. Tourmalines from the ore bodies are dravite with Fe/(Fe + Mg) ratios of 0.09 ∼ 0.31
and Ca/(Ca + Na) ratios of 0.03 ∼ 0.40. These tourmalines are also rich in chromium (up to 0.74 wt% Cr2O3) and tin (up to 0.42 wt% Sn). In contrast, tourmalines from the barren migmatites are mostly schorl with Fe/(Fe + Mg) ratios
of 0.38 ∼ 0.94 and Ca/(Ca + Na) ratios of 0.00 ∼ 0.14. Tourmalines from quartz–tourmaline veins that occur between ore bodies
and the migmatites show intermediate compositions, i.e., Fe/(Fe + Mg) = 0.09 ∼ 0.59, Ca/(Ca + Na) = 0.01 ∼ 0.22.
It is suggested that the Mg-rich nature of the tourmaline can be used as an exploration tool in this region to target tin
mineralization, because the tourmalines show increasing Mg contents and are more dravitic when approaching the ore bodies.
It is likely that the formation of the Yunlong tin deposit was related to migmatitic-hydrothermal processes. The high Mg and
Cr contents in tourmalines from the ore bodies were probably derived from the local meta-sedimentary and meta-volcanic rocks
of the Precambian Chongshan Group rather than from the granites in the region.
Received December 28, 2000; revised version accepted January 25, 2002 相似文献
7.
Experiments at 750 °C, 200 MPa(H2O), a
(H2O)=1, and fO2∼Ni-NiO established that the equilibrium among tourmaline, biotite, cordierite, and melt (± spinel, aluminosilicate, or corundum)
occurs with ∼2 wt% B2O3 in strongly peraluminous melt with an aluminosity, measured by the parameter ASI, of >1.2. The experiments demonstrate the
relationship of tourmaline stability to the activity product of the tourmaline components boron and aluminum, which are inversely
related to one another. Tourmaline is unstable in metaluminous to mildly peraluminous melts (ASI <1.2) at 750 °C regardless
of their boron content. For a given aluminosity, addition of components such as F requires a greater boron content of melt
at this equilibrium. The stability of tourmaline increases with decreasing temperatures below 750 °C. At the inception of
melting, tourmaline breaks down incongruently to assemblages containing crystalline AFM silicates (biotite, cordierite, garnet,
sillimanite), aluminates (spinel, corundum), and B-enriched but Fe-Mg-poor melt. Granitic melts are likely to be undersaturated
in tourmaline from the start of their crystallization, and their initial boron contents will be limited by the abundance of
tourmaline in their source rocks. Quartzofeldspathic (gneissic, metapelitic) rocks that reached conditions of the granulite
facies and still contain (prograde) tourmaline are rare, and probably have never yielded a partial melt. Most leucogranitic
magmas will initially crystallize biotite, cordierite, or garnet, but not tourmaline. With crystallization, the Fe-Mg content
of melt decreases, and the B2O3 content increases until the tourmaline-biotite and/or tourmaline-cordierite (or garnet) equilibria are attained. The B2O3 content of melt is buffered as long as these equilibria continue to operate, but low initial Fe-Mg contents of the magmas
limit the quantity of boron that can be consumed by these reactions to <1 wt% B2O3. Normally, leucogranitic magmas contain insufficient Fe and Mg to conserve all boron as tourmaline and thus lose a large
fraction of magmatic boron to wallrocks. Leucogranites and pegmatites with tourmaline as an early and only AFM silicate mineral
probably contained >2 wt% B2O3 in their bulk magmas.
Received: 6 August 1996 / Accepted: 21 July 1997 相似文献
8.
F. G. Reyf 《Mineralium Deposita》1997,32(5):475-490
Uneconomic tungsten mineralization associated with the Mariktikan granite pluton of the Transbaikalian igneous province,
eastern Siberia, is confined to a marginal part of the pluton referred to as the Andreyevsky body. This is composed of rocks
similar to those of the main pluton, but is likely to be an autonomous, although kindred, body. On the basis of cross-cutting
relationships between rock varieties, and their textural features, the crystallization history is subdivided into three stages
of unequal duration. Melt and fluid inclusions related to each of them have been studied using microthermometric and micro-analytical
procedures, including a technique for atomic emission spectroscopy of individual fluid inclusions opened by a laser microprobe.
During the main crystallization stage (1045–1012 °C) more than 70% of the parental magma is believed to have crystallized
(at the level studied), resulting in the formation of a crystalline framework rigid enough for the appearance of fractures
within which some portion of the intercrystalline melt accumulated, giving rise to thin aplite veins. Almost complete crystallization
of intercrystalline and fracture-hosted melt occurred during the late stage (1012–990 °C), whereas during the final stage
only small bunches of schlieric, sometimes miarolitic pegmatite were formed from a few pockets of residual melt (990–917 °C).
In spite of the low water content of the melt (about 1 wt.%), fluid separation took place from the onset of crystallization.
During the main crystallization stage, the exsolved fluid divided into two immiscible phases, CO2-rich gas and salt-rich liquid (brine). However, it was homogeneous thereafter. Major ore components of the brine (Mn, Fe,
W) displayed different behaviour as crystallization progressed. W concentration was below 0.1 wt.% at the main stage, attained
1 wt.% during the late stage and increased to 1.8 wt.% at the final stage. Comparison of these data with calculations carried
out using estimated parameters for the parental magma enables us to infer that obtained concentration values are reasonable
for the special case studied here. However, they are unlikely to be attainable if the magma is H2O enriched and lacks an anomalously high W content. In the Andreyevsky body of the Mariktikan pluton, the following features
of the parental magma made possible the generation of W-rich solutions: (1) high liquidus temperature (1045 °C) and elevated
Cl content (c.0.15 wt.%) that resulted in enlargement of the fluid/melt distribution coefficient (c.10), (2) low water content
(c.1%) and elevated W content (c.0.001 wt.%) that provided a relatively high W/H2O ratio within the system. At the same time, because of the low water content of the magma, the total mass of W-bearing solutions
has proved to be insufficient for the production of large-scale mineralization (a reduced W content of the great bulk of the
exsolved brine may have had an unfavourable effect as well).
Received: 2 May 1996 / Accepted: 29 January 1997 相似文献
9.
《Geochimica et cosmochimica acta》1987,51(8):2225-2232
Trace rare earth elements (REE) have been determined by radiochemical neutron activation analysis for tourmaline samples from an internally zoned, rare-element, granitic pegmatite, located in the Black Hills, South Dakota. The total REE concentrations range from 40 ppm–0.2 ppm, and are highest in tourmaline from the exomorphic halo (country rock) and pegmatite border zone. Chondrite-normalized patterns are highly fractionated from light REE to heavy REE; and REE concentrations decrease in tourmaline from the outer wall zone and first intermediate zone, through the inner wall zone and third intermediate zone, to lowest levels in the pegmatite core. The REEs, as recorded by tourmaline, appear to behave compatibly in this pegmatite system due to early crystallization of apatite and other possible “REE-sink” minerals. The large range of REE concentrations and differences in slopes of chondrite-normalized patterns probably also reflect significant changes in the structural state of the pegmatite melt, caused by changes in pH2O and other volatiles (B, F, P) as crystallization progressed. Tourmaline samples that appear to have been fluid-derived are HREE-depleted relative to coexisting silicate-melt-derived tourmaline. Tourmaline does not exhibit any strong preference for specific REEs, rather its REE content appears to reflect the REE content of the medium from which the tourmaline crystallized. 相似文献
10.
陈福坤 《中国地球化学学报》2002,21(2):107-119
High-grade metamorphic Variscan basement is exposed in the Moldanubian zone of the Black Forest (BF), being the internal zone of the European Variscan belt. Zircon grains from K-rich felsic orthogneisses and an anatectic paragneiss in the Moldanubian Black Forest demonstrate a multi-stage crystallization at ~ 600 Ma, ~ 480 Ma, ~ 400 - 380 Ma, and ~350 Ma. The last three stages of crystallization probably represent metamorphic overprint during pre-Variscan and Variscan metamorphism.Using stepwise leaching procedures, garnet minerals from felsic orthogneisses as well as paragneisses in the Moldanubian Black Forest yielded Early Carboniferous Sm-Nd ages (~ 330- 340 Ma), which are consistent with the well-constrained Variscan HT metamorphic event,and Early Palaeozoic ( ~480 Ma) to Devonian ( ~400 - 370 Ma) Pb-Pb ages. The coincidence of growth time for zircon and garnet minerals at Early Palaeozoic is interpreted as dating a metamorphic event. These garnet data demonstrate that the Moldanubian BF basement underwent at least two metamorphic events during the Early Palaeozoic and Early Carboniferous.During the Variscan HT metamorphism, the Sm-Nd system of garnet was disturbed, but not the U-Pb system, implying the peak metamorphic temperature was lower than ~800℃. 相似文献
11.
E. V. Badanina V. V. Gordienko A. Wiechowski G. Friedrich 《Geology of Ore Deposits》2008,50(8):772-781
Composition and localization of REE mineralization in miarolitic pegmatites and its role in the pegmatite formation were studied at the Malkhan gem deposit (jewel-quality tourmaline, morganite, danburite, and hambergite) in the central Transbaikal region. The chemical composition of Ti-, Ta-, Nb- and REE-bearing minerals, their relationships with rock-forming and accessory minerals indicate that two geochemically specialized stages of pegmatite formation are distinguished. The early stage gave rise to the crystallization of quartz-feldspar aggregates including K-feldspar block zone with Sc and REE mineralization. The rare-metal (Li, Cs, F, B, Be) albite-lepidolite-cleavelandite complex with pockets of gem mineralization was formed at the late stage. 相似文献
12.
Boron recycling in the continental crust of the central Andes from the Palaeozoic to Mesozoic, NW Argentina 总被引:4,自引:2,他引:2
Simone Kasemann Jörg Erzinger Gerhard Franz 《Contributions to Mineralogy and Petrology》2000,140(3):328-343
Whole-rock chemical composition and 11B/10B isotope ratios in tourmaline was investigated to study the geochemical recycling of boron during the evolution of the Andean
basement from the Palaeozoic to Mesozoic. In the basement (Cambrian to Ordovician high-grade paragneisses, migmatites and
orthogneisses, the Eocambrian Puncoviscana Formation, and Paleozoic-Mesozoic granitoid igneous rocks) whole-rock B contents
are generally below 100 ppm, but B contents of ˜1 wt% are found in cogenetic aplite and pegmatite dikes and in tourmaline–quartz
rocks. In the metasedimentary rocks, no systematic variation in B content because of metamorphic grade and no correlation
of B with other incompatible elements are apparent. Tourmalines from the high-grade metamorphic basement yield δ11B values ranging from −11.2 to −6.8‰ and isotope fractionation during migmatisation was small. Metamorphic tourmalines from
the Puncoviscana Formation have δ11B values between −6.3 and −5.8‰. The calculated (corrected for fractionation) δ11B values of −6 to −2‰ for the sedimentary protolith of the metamorphic basement indicate a continental B source with subordinate
marine input. Tourmalines from Palaeozoic and Mesozoic granitoids display an identical range of δ11B values from −12 to −5.3‰ and indicate a similarly homogeneous B source throughout time. Tourmalines from pegmatites and
tourmaline–quartz rocks record the average δ11B values of the parental granitic magma. We assume that B in the Palaeozoic and Mesozoic granitoids is derived from the local
metamorphic basement supporting the hypothesis that recycling of the lower Palaeozoic crust is the dominant process in granitic
magma formation from Palaeozoic to Mesozoic.
Received: 15 December 1999 / Accepted: 11 July 2000 相似文献
13.
M. V. Portnyagin L. V. Danyushevsky V. S. Kamenetsky 《Contributions to Mineralogy and Petrology》1997,128(2-3):287-301
We present a detailed mineralogical, petrological and melt inclusion study of unusually fresh, primitive olivine + clinopyroxene
phyric Lower Pillow Lavas (LPL) found near Analiondas village in the northeastern part of the Troodos ophiolite (Cyprus).
Olivine phenocrysts in these primitive LPL show a wide compositional range (Fo82–92) and have higher CaO contents than those from the Upper Pillow Lavas (UPL). Cr-spinel inclusions in olivine are significantly
less Cr-rich (Cr/Cr + Al = 28–67 mol%) compared to those from the UPL (Cr# = 70–80). These features reflect differences in
melt compositions between primitive LPL and the UPL, namely higher CaO and Al2O3 and lower FeO* compared to the UPL at a given MgO. LPL parental melts (in equilibrium with Fo92) had ∼10.5 wt% MgO and crystallization temperatures ∼1210 °C, which are significantly lower than those previously published
for the UPL (14–15 wt% MgO and ∼1300 °C for Fo92). The fractionation path of LPL parental melts is also different from that of the UPL. It is characterized initially by olivine + clinopyroxene
cotectic crystallization joined by plagioclase at ∼9 wt% MgO, whereas UPL parental melts experienced a substantial interval
of olivine-only crystallization. Primitive LPL melts were formed from a mantle source which was more fertile than that of
tholeiites from well-developed intra-oceanic arcs, but broadly similar in its fertility to that of Mid-Ocean Ridge Basalt
(MORB) and Back Arc Basin Basalts (BABB). The higher degrees of melting during formation of the LPL primary melts compared
to average MORB were caused by the presence of subduction-related components (H2O). Our new data on the LPL coupled with existing data for the UPL support the existing idea that the LPL and UPL primary
melts originated from distinct mantle sources, which cannot be related by progressive source depletion. Temperature differences
between these sources (∼150 °C), their position in the mantle (∼10 kbar for the colder LPL source vs 15–18 kbar for the UPL
source), and temporal succession of Troodos volcanism, all cannot be reconciled in the framework of existing models of mantle
wedge processes, thermal structure and evolution, if a single mantle source is invoked. Possible tectonic settings for the
origin of the Troodos ophiolite (forearc regions of intra-oceanic island arc, propagation of backarc spreading into arc lithosphere)
are discussed.
Received: 20 May 1996 / Accepted: 25 March 1997 相似文献
14.
Mineral chemistry of submarine lavas from Hilo Ridge, Hawaii: implications for magmatic processes within Hawaiian rift zones 总被引:10,自引:0,他引:10
Huai-Jen Yang Frederick A. Frey David A. Clague Michael O. Garcia 《Contributions to Mineralogy and Petrology》1999,135(4):355-372
The crustal history of volcanic rocks can be inferred from the mineralogy and compositions of their phenocrysts which record
episodes of magma mixing as well as the pressures and temperatures when magmas cooled. Submarine lavas erupted on the Hilo
Ridge, a rift zone directly east of Mauna Kea volcano, contain olivine, plagioclase, augite ±orthopyroxene phenocrysts. The
compositions of these phenocryst phases provide constraints on the magmatic processes beneath Hawaiian rift zones. In these
samples, olivine phenocrysts are normally zoned with homogeneous cores ranging from ∼ Fo81 to Fo91. In contrast, plagioclase, augite and orthopyroxene phenocrysts display more than one episode of reverse zoning. Within each
sample, plagioclase, augite and orthopyroxene phenocrysts have similar zoning profiles. However, there are significant differences
between samples. In three samples these phases exhibit large compositional contrasts, e.g., Mg# [100 × Mg/(Mg+Fe+2)] of augite varies from 71 in cores to 82 in rims. Some submarine lavas from the Puna Ridge (Kilauea volcano) contain phenocrysts
with similar reverse zonation.
The compositional variations of these phenocrysts can be explained by mixing of a multiphase (plagioclase, augite and orthopyroxene)
saturated, evolved magma with more mafic magma saturated only with olivine. The differences in the compositional ranges of
plagioclase, augite and orthopyroxene crystals between samples indicate that these samples were derived from isolated magma
chambers which had undergone distinct fractionation and mixing histories. The samples containing plagioclase and pyroxene
with small compositional variations reflect magmas that were buffered near the olivine + melt ⇒Low-Ca pyroxene + augite +
plagioclase reaction point by frequent intrusions of mafic olivine-bearing magmas. Samples containing plagioclase and pyroxene
phenocrysts with large compositional ranges reflect magmas that evolved beyond this reaction point when there was no replenishment
with olivine-saturated magma. Two of these samples contain augite cores with Mg# of ∼71, corresponding to Mg# of 36–40 in
equilibrium melts, and augite in another sample has Mg# of 63–65 which is in equilibrium with a very evolved melt with a Mg#
of ∼30. Such highly evolved magmas also exist beneath the Puna Ridge of Kilauea volcano. They are rarely erupted during the
shield building stage, but may commonly form in ephemeral magma pockets in the rift zones.
The compositions of clinopyroxene phenocryst rims and associated glass rinds indicate that most of the samples were last equilibrated
at 2–3 kbar and 1130–1160 °C. However, in one sample, augite and glass rind compositions reflect crystallization at higher
pressures (4–5 kbar). This sample provides evidence for magma mixing at relatively high pressures and perhaps transport of
magma from the summit conduits to the rift zone along the oceanic crust-mantle boundary.
Received: 8 July 1998 / Accepted: 2 January 1999 相似文献
15.
V.Ye. Zagorsky 《Russian Geology and Geophysics》2012,53(6):522-534
A detailed study was given to the composition and structure of alkali feldspars from the pockets of the Sosedka pegmatite vein, a large source of gems within the Malkhan tourmaline deposit. The vein is of concentric-zonal structure. Three types of pockets were recognized by mineral composition: A—quartz–lepidolite–Mn–Li–Al–tourmaline (± pollucite, hambergite, borocookeite, boromuscovite, danburite, light pink beryl); B—quartz–adularia–axinite (± laumontite); and C—quartz and laumontite (± B-containing cookeite). Each type of pockets contains feldspars of specific composition and structure. This evidences that pockets formed in strongly different conditions, though some pockets of different types are localized as close as 0.5–2 m from each other within a zone. The reported data disagree with the common model implying the formation of zonal pegmatite bodies as a result of crystallization differentiation within the vein. 相似文献
16.
Sub-solidus Oligocene zircon formation in garnet peridotite during fast decompression and fluid infiltration (Duria, Central Alps) 总被引:1,自引:0,他引:1
Summary A garnet peridotite lens from Monte Duria (Adula nappe, Central Alps, Northern Italy) contains porphyroblastic garnet and
pargasitic amphibole and reached peak metamorphic conditions of ∼830 C, ∼2.8 GPa. A first stage of near isothermal decompression
to pressures <2.0 GPa is characterised by domains where fine grained spinel, clinopyroxene, orthopyroxene and amphibole form.
The newly formed amphibole contains elevated levels of fluid mobile elements such as Rb, Ba and Pb indicating that recrystallization
was assisted by infiltration of a crustal-derived fluid. Further decompression and cooling to ∼720 °C, 0.7–1.0 GPa associated
with limited fluid influx is documented by the formation of orthopyroxene-spinel-amphibole symplectites around garnet.
Zircon separated from this garnet peridotite exhibits two distinct zones. Domain 1 displays polygonal oscillatory zoning and
high trace element contents. It contains clinopyroxene and amphibole inclusions with the same composition as the same minerals
formed during the spinel peridotite equilibration, indicating that this domain formed under sub-solidus conditions during
decompression and influx of crustal fluids. Domain 2 has no zoning and much lower trace element contents. It replaces domain
1 and is likely related to zircon recrystallization during the formation of the symplectites. SHRIMP dating of the two domains
yielded ages of 34.2 ± 0.2 and 32.9 ± 0.3 Ma, respectively, indicating fast exhumation of the peridotite within the spinel
stability field. We suggest that the Duria garnet peridotite originates from the mantle wedge above the tertiary subduction
of the European continental margin and that it was assembled to the country rock gneisses between 34 and 33 Ma.
Third author was Deceased 相似文献
17.
Diffusion of dissolved SiO2 in H2O at 1 GPa, with implications for mass transport in the crust and upper mantle 总被引:4,自引:0,他引:4
Cation diffusion rates at 690 ± 30 °C have been calculated by inverse modelling of observed manganese (Mn) zonation profiles
in 40 garnets from two kyanite-bearing metapelite samples from the High Himalayan Crystalline Series, Zanskar, northwest India.
Knowledge of the initial growth profile of Mn in garnet is a pre-requisite for this technique. Following previous workers
we model Mn partitioning into growing garnet in terms of a Rayleigh fractionation process, and demonstrate that the Mngarnet:whole rock partition coefficient is 60–100. Three-dimensional zonation profiles were obtained by successively grinding and polishing
∼1 cm slabs of each sample at 0.1–0.2 mm intervals and analysing the garnets at each stage, thus ensuring that core sections
were measured. The diffusion model assumes that garnet has a spherical geometry and behaves as a closed system, and simulates
diffusive modification of the hypothetical Mn Rayleigh growth profile for each garnet. The derived measure of the time-integrated
diffusion history for each garnet is then combined with radiometric and field-relation constraints for the duration of the
Himalayan metamorphic event to calculate cation diffusion rates. The average cation interdiffusion rate calculated for garnets
in the two samples examined is (6 ± 3.2) × 10−23 m2s−1. This interdiffusion rate pertains to a temperature of 690 ± 30 °C, which is 0.97 × T
PEAK, the peak temperature conditions experienced by the samples estimated using standard thermobarometric techniques. Garnet
compositions are Py2–17Alm65–77Gro6–16Sp1–17. These new diffusion data are consistent with, and more precise than, existing high-temperature (>1000 °C) experimentally
determined diffusion data, although some uncertainties remain difficult to constrain. Qualitative comparison between diffusively
modified Mn growth profiles in garnets from the Scottish Dalradian and the Himalayan garnets suggests that the duration of
metamorphism affecting the Dalradian garnets was 10–20 times longer than that endured by the Himalayan garnets.
Received: 5 June 1996 / Accepted: 29 January 1997 相似文献
18.
Summary Elevated P contents of up to 0.086 apfu (1.21 wt.% P2O5) were found in garnet from leucocratic granitic rocks (orthogneisses, granites, barren to highly evolved pegmatites) in the
Moldanubicum and Silesicum, Czech Republic, and in complex granitic pegmatites from southern California, USA, and Australia.
Minor concentrations (0.15–0.55 wt.% P2O5) appear ubiquitous in garnet from leucocratic granitic rocks of different origins and degrees of fractionation. Concentrations
of P are not related to Mn/(Mn + Fe) that vary from 0.12–0.86 and to textural types of garnet (i.e., isolated anhedral to
euhedral grains and nodules, graphic and random garnet–quartz aggregates, subsolidus veins of fine-grained garnet). Garnet
compositions exhibit negative correlations for P/Si and P/R2+ where R2+ = Fe + Mn + Mg + Ca, while Al is constant at ∼2.05 apfu. Concentrations of Na are largely below 0.02 apfu but positively correlate with P. The main substitution may involve A-site vacancy and/or the presence of some light element(s) in the crystal structure. The substitution □P2 R2+ −1Si−2 and/or alluaudite-type Na□P3 R2+ −1Si−3 seem the most likely P-incorporating mechanisms. The partitioning of P among garnet and associated minerals in granitic systems
remains unclear; however, it directly affects the distribution of Y and REEs. 相似文献
19.
We have analyzed the chemical composition and boron isotope composition of tourmaline from tourmalinites, granite and a quartz-tourmaline
vein from the Deri ore zone and from a pegmatitic band in the Rampura-Agucha ore body. These two Proterozoic massive sulfide
deposits occur in the Aravalli-Delhi orogenic belt, Rajasthan, northwest India. Tourmaline from stratiform tourmalinites closely
associated with the massive sulfides in the Deri deposit have preserved their original chemical compositions despite regional
and thermal metamorphism in the area. These tourmalines have low Fe/(Fe + Mg) ratios (0.19–0.30; mean 0.26) that suggest formation
close to the sediment-sea water interface. The δ11B values (−15.5 and −16.4‰) are compatible with boron derived from leaching of argillaceous sediments and/or felsic volcanics
underlying the original massive sulfide deposit during its formation. Boron isotope compositions measured in tourmaline from
a post-ore granite and quartz-tourmaline vein in the Deri deposit indicate that boron in these tourmalines was derived from
the tourmalinites produced during ore formation. The boron isotope systematics of a coarse brown tourmaline crystal from a
pegmatitic band on the hanging wall contact of the Rampura-Agucha deposit indicate that 45 ± 25% of the boron within the original
tourmaline was lost during upper amphibolite facies regional metamorphism.
Received: 3 April 1996 / Accepted: 11 April 1996 相似文献
20.
Mona-Liza C. Sirbescu Emily E. Hartwick James J. Student 《Contributions to Mineralogy and Petrology》2008,156(3):289-305
We evaluated the crystallization regime of a zoned pegmatite dike and
the degree of magma undercooling at the onset of crystallization by analyzing
coeval fluid and melt inclusion assemblages. The liquidus temperature of the
pegmatite magma was ~720°C, based on re-melting of crystallized-melt
inclusions in heating experiments. The magma crystallized sequentially starting
with a thin border zone, which formed in less than one day at an average
temperature of ~480°C based on primary fluid inclusions, meaning 240°C
undercooling. The primary inclusions from the outer zones were postdated by
secondary inclusions trapped between 580 and 720°C, representing fluid exsolved
from hotter, still crystallizing inner pegmatite units. The huge temperature
contrast between the pegmatite’s inner and outer zones was simulated by
conductive-heat numerical modeling. A 2.5 m wide dike emplaced in 220°C rocks
cools entirely to <400°C in less than 50 days. Unidirectional and skeletal textures
also indicate rapid, disequilibrium crystallization. 相似文献