极低饱和度和近饱和状态下海水中方解石和文石溶解动力学研究

利用free-drift开放反应系统,在恒压力(101.325 kPa)和恒温度(25.0±0.2)℃环境条件下,研究人工海水中二氧化碳分压(pCO2)的变化对方解石和文石的溶解速率及反应级数的影响.研究结果表明:如果溶解实验中pCO2未达到完全平衡,计算得出的反应级数偏小,且反应液pCO2不平衡是造成不同反应阶段反应...     

Influence of magnesium on the ion-activity product of calcium and carbonate dissolved in seawater: A new approach

The influence of Mg²⁺ ions on the ion-activity product of calcium and carbonate dissolved in seawater has been investigated. The present approach is based mainly on: (1) the preponderance of this element in the marine system; (2) the observations by Weyl (1965), Jansen and Kitano (1963), and more recently by Plummer and Mackenzie (1974) on the higher solubility of magnesian calcite relative to pure calcite; and (3) the inferences drawn from our laboratory studies on the Ca²⁺—Mg²⁺ ion-exchange behaviour on surfaces of pure calcite. From these considerations, the pK value corresponding to a calcite containing 12 mole% of MgCO, has been estimated to be 7.7± 0.1 at 20°C. This value has serious reflections on the extent of saturation of seawater with respect to calcium-carbonate polymorphs. The reassessed degree of carbonate saturation for an average warm-surface ocean turns out to be only between 1.0 and 2.2.     

温度和过饱和度对海水中碳酸钙沉淀速率的影响I.镁方解石

采用稳定加液一反应系统对5、15和25 ° C下镁方解石沉淀在海水中的形成过程进行了研究.结果表明镁方解石的沉淀速率(R)对过饱和度(Ω)的响应均可通过R=k(Ω-1)°或Log(R)=nLog(Ω-1)+Log(k)形式的动力学方程加以表达.pCO2的变化会显著改变过饱和度进而影响到镁方解石沉淀速率,但这一变化并不会对镁方解石沉淀形成过程的动力学表达产生影响.相比之下,不同温度下镁方解石沉淀形成的动力学方程存在明显差异,表明这一动力学过程同时还具有强烈的热力学相关性.     

Application of data on seawater light scattering for the study of marine particles: a selective review focusing on Russian literature

This paper presents a selective review of applications of data on seawater light scattering for the study and monitoring of marine particles. Particular emphasis is placed on ocean waters and the seas surrounding Russia, where earlier studies by the author with his coworkers are little known because published mostly in Russian. In those assessments, methods of solving the inverse problem of seawater light scattering have been developed. Low-parametric models of optical properties were created by means of statistical analyses of experimental data, solving the inverse problem and comparing results derived from optical methods with those based on particle counts. Estimates of the volume and mass concentrations of suspended matter and its components were derived from light-scattering data for different regions. The potential of using optical methods for assessing spatiotemporal variability in suspended matter supply, propagation, and distribution is also considered.     

Ultraviolet spectroscopic determination of the stability constants for copper carbonate and bicarbonate complexes up to the ionic strength of seawater

An ultraviolet spectroscopic study at 25°C is used to determine the stoichiometric stability constant of CuCO₃⁰ (β_CuCO3⁰) over a range of ionic strengths; extrapolation to zero ionic strength provides a thermodynamic constant (log β⁰_CuCO3⁰ = 6.89). At 0.69 m ionic strength, log β_CuCO3⁰) is 6.33.This study provides the first experimental evidence for the existence of CuHCO₃⁺. At 0.69 m ionic strength, log β_CuHCO3⁺ is 2.77.The ultraviolet molal absorptivity spectra for the two complexes are also determined. The spectrum for CuCO₃⁰ consists of a single band centered at 276.5 nm and was described well by a Gaussian function. The spectrum of CuHCO₃⁺ consists of at least two overlapping bands.Side reactions which might affect the data interpretation were included in the analysis of the results. The effects of the Cu(II) hydrolysis reactions were accounted for by using data from previous work, and possible effects due to copper-organic species were eliminated by a subtraction procedure.     

Evidence for aggregate formation in a nepheloid layer and its possible role in the sedimentation of particulate matter

During cruise 73-A-3 of the R/V “Alaminos”, seawater samples from the nepheloid layer and overlying water were collected and filtered through 0.4 μm Millipore^® Ultra Thin filters for microscopic analysis with a Jeol JSM-U3 scanning electron microscope. The results of the studies of the suspended matter with the scanning electron microscope indicate that there is a significant increase in the percentage of the total number of particles that are associated as aggregates for the nepheloid layer relative to the overlying water. This suggests that once nepheloid layers are formed, they might represent regions of high sedimentation due to aggregate formation.     

前期夏季西太平洋暖池热含量对江南春雨的影响及其可能机理

利用GODAS海洋温度资料、中国753站逐日降水资料以及NCEP/NCAR逐日再分析资料讨论了前期夏季西太平洋暖池热含量异常对江南春雨的影响,并通过高低层环流异常解释了其可能过程和机制。研究结果表明:(1)前期夏季暖池区热含量影响春雨的敏感海区位于9°~16°N,150°~166°E,与春雨强度呈显著反相关,前期夏季关键区热含量的显著偏低是春雨异常偏多的强信号。(2)多雨年和少雨年大气环流差值场与夏季暖池热含量(取反号)回归的次年春季大气环流形态基本一致。低层菲律宾海异常反气旋西北侧的暖湿西南气流输送及江南地区高层辐散抽吸运动是造成春雨偏多的直接原因。(3)关键区热含量在前期夏季的异常偏低使低层异常反气旋在其西北侧触发生成,并在菲律宾海附近持续存在(前夏至当年春季),春季引导强盛的西南气流向江南输送水汽;同时,热含量异常偏低在我国大陆东部激发出高层异常气旋并持续维持(前秋至当年春季),导致春季西风急流轴异常南压,高层形成异常辐散中心,形成强烈的抽吸作用,导致江南春雨显著偏多。前夏热含量显著偏高引起江南春雨偏少的过程则与之相反。     

海洋硅藻硅质细胞壁结构的形成机理研究概述

硅藻具有形态各异、结构复杂、精美绝伦的硅质细胞壁,是海洋中进行生物硅化最主要的生物体。硅质细胞壁的形成同样是一个错综复杂的过程,它涉及硅藻细胞将硅酸从胞外转运到胞内;硅酸在细胞内的转移;在硅沉积囊泡(SDV)中的浓缩沉积;最后合成具种类特异性的细胞壁。重点介绍硅酸转运基因(SITs)的分子特征与作用机制;与生物硅化相关的三种蛋白即硅体蛋白(frus-tulins)、亲硅蛋白(silaffins)和侧壁蛋白(pleuralins)的结构与功能;硅质结构如何在硅沉积囊泡内最终形成的模式。     

气泡羽流的研究进展和应用

从试验、积分羽流模型、CFD模型方面综述了气泡羽流的研究现状。在此基础上,介绍了一些应用领域的研究进展,包括海上天然气泄露、海上溢油的围控、水处理和污水处理以及疏浚工程。     

沉积物埋藏深度和碳酸钙含量对南海沉积物干密度的影响

在古海洋学研究中,质量堆积速率是反映地质历史时期某种物质沉积通量变化趋势的重要指标。计算质量堆积速率的一个必要参数是沉积物的干密度（DBD）。但是,很多钻孔沉积物的干密度数据往往因采样间隔稀疏而分辨率太低,甚至没有实测数据,为后续研究带来一定限制。前人研究中曾经发现深海沉积物的DBD可以用沉积物中的CaCO3含量进行估算,但这一方法在南海是否可行尚缺乏研究。笔者根据前人经验,对南海ODP184,IODP 349、367、368共4个航次17个站位的DBD、CaCO3含量与样品埋藏深度数据进行了分析,发现沉积物埋藏深度是影响DBD的重要因素,DBD和CaCO3含量仅在南海南部的ODP1143站位表现出良好的关系。而在南海北部及中部可能由于受到不同程度深层流活动的影响,导致沉积环境极不稳定,非碳酸钙组分来源复杂多变,故DBD与CaCO3%的相关性差。在南海南部,以沉积物埋藏深度和CaCO3%为变量,对ODP1143站位用二元多项式拟合出一经验公式,该公式适用于南海南部海域与1143站位有相似沉积环境的沉积物样品干密度的估算。     

夏季巴拉望岛西北部海域净热通量的时空变化特征和形成机理初析

利用OAFLUX气候态月平均热通量资料及TMI云量、降雨、SST和QuikScat风场资料,对南海、特别是巴拉望岛西北海域净热通量的时空特征进行了深入分析.研究发现,夏季在巴拉望岛西北海域存在一局域净热通量极小值区,在7月份该海域海洋甚至呈现失热达20 W/m2情况.分析认为该局地净热通量异常可能与南海暖水的发生、发展有关,即由于西南季风爆发,巴拉望岛西北海域对流加强,一方面,蒸发增大使得潜热增大、云量增多,导致入射太阳短波辐射的减少;另一方面,降水的增大使得该海域出现障碍层现象,障碍层导致的局地海温正反馈进一步增强了局地对流,从而加剧海洋失热过程,促成了巴拉望岛西北海域净热通量局地异常的出现.进一步的经验正交模态（EOF）分析表明,在季节变化尺度上,南海净热通量的第一模态（89.1%）呈同位相变化,反映了南海受冬、夏季风的交替驱动特征;其中南海北部（海南岛至台湾海峡南段的带状海域）为振幅最大区,这与该海域存在年平均最大风速有关;第二模态（10.0%）以吕宋岛至雷州半岛一线为界,南北两侧反相,并具有显著的局域特征;不仅反映了黑潮入侵与南海环流的季节变化,而且还发现巴拉望岛西北海域存在一局地极值域,对应夏季净热通量异常区.     

Arctic ocean shelf–basin interaction: An active continental shelf CO2 pump and its impact on the degree of calcium carbonate solubility

The Arctic Ocean has wide shelf areas with extensive biological activity including a high primary productivity and an active microbial loop within the surface sediment. This in combination with brine production during sea ice formation result in the decay products exiting from the shelf into the deep basin typically at a depth of about 150 m and over a wide salinity range centered around S ～33. We present data from the Beringia cruise in 2005 along a section in the Canada Basin from the continental margin north of Alaska towards the north and from the International Siberian Shelf Study in 2008 (ISSS-08) to illustrate the impact of these processes. The water rich in decay products, nutrients and dissolved inorganic carbon (DIC), exits the shelf not only from the Chukchi Sea, as has been shown earlier, but also from the East Siberian Sea. The excess of DIC found in the Canada Basin in a depth range of about 50–250 m amounts to 90±40 g C m^?2. If this excess is integrated over the whole Canadian Basin the excess equals 320±140×10¹² g C. The high DIC concentration layer also has low pH and consequently a low degree of calcium carbonate saturation, with minimum aragonite values of 60% saturation and calcite values just below saturation. The mean age of the waters in the top 300 m was calculated using the transit time distribution method. By applying a future exponential increase of atmospheric CO₂ the invasion of anthropogenic carbon into these waters will result in an under-saturated surface water with respect to aragonite by the year 2050, even without any freshening caused by melting sea ice or increased river discharge.     

干细胞技术进展及其在海洋动物研究中的应用展望

干细胞（Stemcell）是具有多向分化潜能、自我更新能力的细胞，是处于细胞系起源顶端的最原始的、在体内能够分化产生某种特定组织类型的细胞。在干细胞和其终末分化的子代细胞之间存在着被称为“定向祖细胞”的中间祖细胞群，具有有限扩增能力和限制性分化潜能。按照发生学来源，干细胞可分为胚胎干细胞和成体干细胞，胚胎干细胞具有发育的全能性，理论上可以诱导分化为机体所有类型的细胞，在体外可以大量扩增、筛选、冻存和复苏而不会丧失原有特性；成体干细胞是指存在于一种已经分化组织中的未分化细胞，能够自我更新和特化形成组织细胞，甚至能够表现出很强的跨组织分化潜能。由于干细胞在医学和农业上有巨大的应用潜力，在1999年被《Science》杂志列为世界十大科技进展之首，2000年再度人选世界十大科技进展。     

The status of research and utilisation on the subtidal kelp along the Chilean coast: A literature review

The most important marine coastal ecosystem in the Chilean coast are kelp forests. This review is based on ecological studies regarding different aspects of subtidal kelp ecosystems along the Chilean coast. It highlights the most interesting findings in (1) biology of subtidal kelp in Chile, with particular reference to (2) habitats formed by kelp, and considered the successful examples and promising results in the (3) kelp as an industrial resource (Biotechnological approach of kelps and aquaculture). The impact caused by (4) El Ni?o-Southern Oscillation is discussed as an important climatic event that could help to forecast the future of the kelp ecosystem. In addition, this literature review outlines the knowledge gaps on subtidal kelp along the Southeast Pacific Coast of Chile, so that research can be strengthened in the future.     

海底浅层气的成因、赋存特征及其对工程的危害

利用1986～1992年珠江口盆地灾害地质与工程地质调查、2000～2001年亚太光缆网络系统路由调查等获得的资料,对海底浅层气的分布与赋存特征作了分析研究,认为海底浅层气主要分布于河口与陆架地区,以层状、团(块)状、高压气囊及气底辟等4种形态赋存于海底,在侧扫声纳、浅地层剖面等图像中有4种主要识别标志。海底浅层气常常会给基础工程施工带来严重影响,因此,对其给工程带来的影响及危害应予以足够的重视。     

Large-scale depositional characteristics of the Ulleung Basin and its impact on electrical resistivity and Archie-parameters for gas hydrate saturation estimates

Gas hydrate saturation estimates were obtained from an Archie-analysis of the Logging-While-Drilling (LWD) electrical resistivity logs under consideration of the regional geological framework of sediment deposition in the Ulleung Basin, East Sea, of Korea. Porosity was determined from the LWD bulk density log and core-derived values of grain density. In situ measurements of pore-fluid salinity as well as formation temperature define a background trend for pore-fluid resistivity at each drill site. The LWD data were used to define sets of empirical Archie-constants for different depth-intervals of the logged borehole at all sites drilled during the second Ulleung Basin Gas Hydrate Drilling Expedition (UBGH2). A clustering of data with distinctly different trend-lines is evident in the cross-plot of porosity and formation factor for all sites drilled during UBGH2. The reason for the clustering is related to the difference between hemipelagic sediments (mostly covering the top ∼100 mbsf) and mass-transport deposits (MTD) and/or the occurrence of biogenic opal. For sites located in the north-eastern portion of the Ulleung Basin a set of individual Archie-parameters for a shallow depth interval (hemipelagic) and a deeper MTD zone was achieved. The deeper zone shows typically higher resistivities for the same range of porosities seen in the upper zone, reflecting a shift in sediment properties. The presence of large amounts of biogenic opal (up to and often over 50% as defined by XRD data) was especially observed at Sites UBGH2-2_1 and UBGH2-2_2 (as well as UBGH1-9 from a previous drilling expedition in 2007). The boundary between these two zones can also easily be identified in gamma-ray logs, which also show unusually low readings in the opal-rich interval. Only by incorporating different Archie-parameters for the different zones a reasonable estimate of gas hydrate saturation was achieved that also matches results from other techniques such as pore-fluid freshening, velocity-based calculations, and pressure-core degassing experiments. Seismically, individual boundaries between zones were determined using a grid of regional 2D seismic data. Zoning from the Archie-analysis for sites in the south-western portion of the Ulleung Basin was also observed, but at these sites it is linked to individually stacked MTDs only and does not reflect a mineralogical occurrence of biogenic opal or hemipelagic sedimentation. The individual MTD events represent differently compacted material often associated with a strong decrease in porosity (and increase in density), warranting a separate set of empirical Archie-parameters.     

中国区域滨海湿地固碳能力研究现状与提升

对我国滨海湿地的固碳能力进行了评估,同时,对其固碳能力的遥感监测和评估方法进行了总结和分析,最后提出了滨海湿地固碳能力的提升技术。全球看来,我国滨海湿地的固碳能力总体上不高。国内看来,在北方泥炭地和植被覆盖率高,生长茂盛的区域,尤其是有红树林生长的区域固碳能力相对较高。滨海湿地主要分布在潮间带,人为监测困难,卫星遥感的出现为滨海湿地的监测带来很大方便,遥感监测已成为评估湿地固碳能力的一种高时效方法。滨海湿地固碳蕴藏着巨大潜力,提升滨海湿地的固碳能力可以大大降低全球CO2含量,对于改善全球温室效应有不可替代的作用。     

A grey model with periodic term for sea-level analysis and its application to the Guangxi coast

A~as~Sof~~LIngeneral,sealevelisresolvedintOatrendtermplusaPeriedictermintheanalysisofsealevelvdriations(haetal.1996;ZuoandChen,1996;QinandLi,1997;Zhengetal.,1993;RenandZhang,1993),namely,thetimeequencesofmonthlyorannualmeansealevely(o)(t)canbeexpr~asy(o)(t)=T(o)(t) p(o)(t) X(o)(t) .(o)(t),(l)whereT(o)(t)isadefinitetrendterm;p(o)(t)isadefiniteperiedicterm;X(o)(t)isatimeseriesofrandomterm;a(o)(t)iswhitenoise.Thefunctionstructuresofthetrendtermaregenerallyunknown,whiledeterminingthetrendter…     

A high sensitivity method for the determination of nanomolar concentrations of Nitrate and Nitrite in seawater with a technicon autoanalyzer II

A high sensitivity manifold for the determination of trace quantities (nanomolar concentrations) of nitrate+nitrite and nitrite alone is described. The method uses a classical Technicon AutoAnalyzer II usually employed for shipboard analysis. A reproducibility of ± 1 nmol dm⁻³ for nitrate plus nitrite and nitrite alone was obtained, with an analytical rate of 40 samples h⁻¹.