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1.
Yong-Fei Zheng 《Physics and Chemistry of Minerals》1998,25(3):213-221
The modified increment method has been applied to the calculation of oxygen isotope fractionation factors for hydroxide minerals.
The results suggest the following sequence of 18O-enrichment in the common hydroxides: limonite > gibbsite > goethite > brucite > diaspore. The hydroxides are significantly
enriched in 18O relative to the corresponding oxides. The sequence of 18O-enrichment in the hydroxides and oxides of trivalent cations is as follows: M(OH)3 > MO(OH) > M2O3. There are also considerable fractionations within the polymorphos of Al(OH)3. The internally consistent fractionation factors for hydroxide–water systems are obtained for the temperature range of 0
to 1200 °C, which are comparable with the data derived from synthesis experiments and natural samples at surficial temperatures.
Temperature dependence of oxygen isotope fractionations between goethite, gibbsite, boehmite and diaspore and water are significant
enough for the purpose of geothermometry. Thus the hydroxide–water pairs hold great promise of serving as reliable paleothermometers
in surficial geological environments.
Received: 22 January 1997 / Revised, accepted: 2 June 1997 相似文献
2.
Adsorption of divalent metal ions, including Cu2+, Pb2+, Zn2+, Cd2+ and Ni2+, on quartz surface was measured as a function of metal ion concentration at 30°C under conditions of solution pH= 6. 5 and
ion strength I = 0. 1mol/L. Results of the experimental measurements can be described very well by adsorption isotherm equations
of Freudlich. The correlation coefficients (r) of adsorption isotherm lines are > 0. 96. Moreover, the experimental data were interpreted on the basis of surface complexation
model. The experimental results showed that the monodentate-coordinated metal ion surface complex species (SOM+) are predominant over the bidentate-coordinated metal ion surface complex species [(SO)2M] formed only by the ions Cu2+, Zn2+ and Ni2+. And the relevant apparent surface complexation constants are lgKM = 2.2–3.3 in order of KCd≥KPb > KZn > KNi≥KCu, and lgβM = 5.9-6.8 in order of βNi > βZn > βCu. Therefore, the reactive ability of the ions onto mineral surface of quartz follows the order of Cd > Pb > Zn > Ni> Cu under
the above-mentioned solution conditions. The apparent surface complexation constants, influenced by the surface potential,
surface species and hydrolysis of metal ions, depend mainly on the Born solvation coefficient of the metal ions.
This project was financially supported by the National Natural Science Foundation of China (No. 49572091). 相似文献
3.
E. Huang J.-F. Lin J. Xu T. Huang Y.-C. Jean H.-S. Sheu 《Physics and Chemistry of Minerals》1999,26(7):576-583
Various X-ray diffraction methods have been applied to study the compression behavior of gibbsite, Al(OH)3, in diamond cells at room temperature. A phase transformation was found to take place above 3 GPa where gibbsite started
to convert to its high-pressure polymorph. The high-pressure (HP) phase is quenchable and coexists with gibbsite at the ambient
conditions after being unloaded. This HP phase was identified as nordstrandite based on the diffraction patterns obtained
at room pressure by angle dispersive and energy dispersive methods. On the basis of this structural interpretation, the bulk
modulus of the two polymorphs, i.e., gibbsite and nordstrandite, could be determined as 85 ± 5 and 70 ± 5 GPa, respectively,
by fitting a Birch-Murnaghan equation to the compression data, assuming their Ko
′ as 4. Molar volume cross-over occurs at 2 GPa, above which the molar volume of nordstrandite is smaller than that of gibbsite.
The differences in the molar volume and structure between the two polymorphs are not significant, which accounts for the irreversibility
of the phase transition. In gibbsite, the axial compressibility behaves as c/c
o > a/a
o > b/b
o. This is due to the fact that the dioctahedral sheets along the c-axis are held by the relatively weak hydrogen bonding, which results in the greater compressibility along this direction.
In nord- strandite, the axial compressibility is b/b
o > c/c
o > a/a
o, which can also be interpreted as resulting from the the existence of hydrogen bonds along the b-axis.
Received: 28 September 1998 / Revised, accepted: 22 December 1998 相似文献
4.
B. P. Artamonov V. V. Bruevich A. S. Gusev O. V. Ezhkova M. A. Ibrahimov S. P. Ilyasov S. A. Potanin Yu. A. Tillaev Sh. A. Ehgamberdiev 《Astronomy Reports》2010,54(11):1019-1031
We have determined the realistic seeing of the 1.5-m AZT-22 telescope of the Mt. Maidanak Observatory (Astronomical Institute,
Uzbek Academy of Sciences) using more than 20 000 CCD frames with stellar images in the UBV RI bands acquired in 1996–2005: ε = 1.065″ in the V band. The characteristic seeing reduced to unit air mass, ε
med
V
(M(z) = 1), is 0.945″. We derived color equations for the CCD detectors used with the telescope. Atmospheric-extinction coefficients
in different photometric bands were also determined. The mean V -band atmospheric extinction is 0.20
m
± 0.04
m
. The time needed for the conditions to settle, in the free atmosphere as well as inside the telescope dome, is 2–2.5 hours
after the end of astronomical twilight. For nights with ε
med
V
> 0.9″, we find a persistent difference between the seeing found at this telescope and measured simultaneously with a differential
image motion monitor, amounting to ∼0.1
m
. 相似文献
5.
A holistic study of the composition of the basalt groundwaters of the Atherton Tablelands region in Queensland, Australia
was undertaken to elucidate possible mechanisms for the evolution of these very low salinity, silica- and bicarbonate-rich
groundwaters. It is proposed that aluminosilicate mineral weathering is the major contributing process to the overall composition
of the basalt groundwaters. The groundwaters approach equilibrium with respect to the primary minerals with increasing pH
and are mostly in equilibrium with the major secondary minerals (kaolinite and smectite), and other secondary phases such
as goethite, hematite, and gibbsite, which are common accessory minerals in the Atherton basalts. The mineralogy of the basalt
rocks, which has been examined using X-ray diffraction and whole rock geochemistry methods, supports the proposed model for
the hydrogeochemical evolution of these groundwaters: precipitation + CO2 (atmospheric + soil) + pyroxene + feldspars + olivine yields H4SiO4, HCO3
−, Mg2+, Na+, Ca2+ + kaolinite and smectite clays + amorphous or crystalline silica + accessory minerals (hematite, goethite, gibbsite, carbonates,
zeolites, and pyrite). The variations in the mineralogical content of these basalts also provide insights into the controls
on groundwater storage and movement in this aquifer system. The fresh and weathered vesicular basalts are considered to be
important in terms of zones of groundwater occurrence, while the fractures in the massive basalt are important pathways for
groundwater movement. 相似文献
6.
Peter J. Swedlund Jenny G. Webster Gordon M. Miskelly 《Geochimica et cosmochimica acta》2009,73(6):1548-43
Adsorption of Cu2+, Zn2+, Cd2+, and Pb2+ onto goethite is enhanced in the presence of sulfate. This effect, which has also been observed on ferrihydrite, is not predicted by the diffuse layer model (DLM) using adsorption constants derived from single sorbate systems. However, by including ternary surface complexes with the stoichiometry FeOHMSO4, where FeOH is a surface adsorption site and M2+ is a cation, the effect of SO42− on cation adsorption was accurately predicted for the range of cation, goethite and SO42− concentrations studied. While the DLM does not provide direct molecular scale insights into adsorption reactions there are several properties of ternary complexes that are evident from examining trends in their formation constants. There is a linear relationship between ternary complex formation constants and cation adsorption constants, which is consistent with previous spectroscopic evidence indicating ternary complexes involve cation binding to the oxide surface. Comparing the data from this work to previous studies on ferrihydrite suggests that ternary complex formation on ferrihydrite involves complexes with the same or similar structure as those observed on goethite. In addition, it is evident that ternary complex formation constants are larger where there is a stronger metal-ligand interaction. This is also consistent with spectroscopic studies of goethite-M2+-SO42− and phthalate systems showing surface species with metal-ligand bonding. Recommended values of ternary complex formation constants for use in SO4-rich environments, such as acid mine drainage, are presented. 相似文献
7.
On the Ratios between Elastic Modulus and Uniaxial Compressive Strength of Heterogeneous Carbonate Rocks 总被引:3,自引:3,他引:0
V. Palchik 《Rock Mechanics and Rock Engineering》2011,44(1):121-128
The ratios M
R = E/σ
c for 11 heterogeneous carbonate (dolomites, limestones and chalks) rock formations collected from different regions of Israel
were examined. Sixty-eight uniaxial compressive tests were conducted on weak-to-strong (5 MPa < σ
c < 100 MPa) and very strong (σ
c > 100 MPa) rock samples exhibiting wide ranges of elastic modulus (E = 6100–82300 MPa), uniaxial compressive strength (σ
c = 14–273.9 MPa), Poisson's ratio (ν = 0.13–0.49), and dry bulk density (ρ = 1.7–2.7 g/cm3). The observed range of M
R = 60.9–1011.4 and mean value of M
R = 380.5 are compared with the results obtained by Deere (Rock mechanics in engineering practice, Wiley, London, pp 1–20,
1968) for limestones and dolomites, and the statistical analysis of M
R distribution is performed. Mutual relations between E, σ
c, ρ, M
R for all studied rocks, and separately for concrete rock formations are revealed. Linear multiple correlations between E on the one hand and σ
c and ρ on the other for Nekorot and Bina limestone and Aminadav dolomite are obtained. It is established that the elastic modulus
and M
R in very strong carbonate samples are more correlated with ρ−σ
c combination and ε
a max, respectively, than in weak to strong samples. The relation between M
R and maximum axial strain (ε
a max) for all studied rock samples (weak-to-strong and very strong) is discussed. 相似文献
8.
The thermoelastic behaviour of anthophyllite has been determined for a natural crystal with crystal-chemical formula ANa0.01
B(Mg1.30Mn0.57Ca0.09Na0.04) C(Mg4.95Fe0.02Al0.03) T(Si8.00)O22
W(OH)2 using single-crystal X-ray diffraction to 973 K. The best model for fitting the thermal expansion data is that of Berman
(J Petrol 29:445–522, 1988) in which the coefficient of volume thermal expansion varies linearly with T as α
V,T
= a
1 + 2a
2 (T − T
0): α298 = a
1 = 3.40(6) × 10−5 K−1, a
2 = 5.1(1.0) × 10−9 K−2. The corresponding axial thermal expansion coefficients for this linear model are: α
a
,298 = 1.21(2) × 10−5 K−1, a
2,a
= 5.2(4) × 10−9 K−2; α
b
,298 = 9.2(1) × 10−6 K−1, a
2,b
= 7(2) × 10−10 K−2. α
c
,298 = 1.26(3) × 10−5 K−1, a
2,c
= 1.3(6) × 10−9 K−2. The thermoelastic behaviour of anthophyllite differs from that of most monoclinic (C2/m) amphiboles: (a) the ε
1 − ε
2 plane of the unit-strain ellipsoid, which is normal to b in anthophyllite but usually at a high angle to c in monoclinic amphiboles; (b) the strain components are ε
1 ≫ ε
2 > ε
3 in anthophyllite, but ε
1 ~ ε
2 ≫ ε
3 in monoclinic amphiboles. The strain behaviour of anthophyllite is similar to that of synthetic C2/m
ANa B(LiMg) CMg5
TSi8 O22
W(OH)2, suggesting that high contents of small cations at the B-site may be primarily responsible for the much higher thermal expansion
⊥(100). Refined values for site-scattering at M4 decrease from 31.64 epfu at 298 K to 30.81 epfu at 973 K, which couples with similar increases of those of M1 and M2 sites. These changes in site scattering are interpreted in terms of Mn ↔ Mg exchange involving M1,2 ↔ M4, which was first detected at 673 K. 相似文献
9.
Computer modelling techniques were used to elucidate the hydration behaviour of three iron (hydr)oxide minerals at the atomic level: white rust, goethite and hematite. A potential model was first adapted and tested against the bulk structures and properties of eight different iron oxides, oxyhydroxides and hydroxides, followed by surface simulations of Fe(OH)2, α-FeO(OH) and α-Fe2O3. The major interaction between the adsorbing water molecules and the surface is through interaction of their oxygen ions with surface iron ions, followed by hydrogen-bonding to surface oxygen ions. The energies released upon the associative adsorption of water range from 1 to 17 kJ mol−1 for Fe(OH)2, 26 to 80 kJ mol−1 for goethite and 40 to 85 kJ mol−1 for hematite, reflecting the increasing oxidation of the iron mineral. Dissociative adsorption at goethite and hematite surfaces releases larger hydration energies, ranging from 120 to 208 kJ mol−1 for goethite and 76 to 190 kJ mol−1 for hematite.The thermodynamic morphologies of the minerals, based on the calculated surface energies, agree well with experimental morphologies, where these are available. When the partial pressures required for adsorption of water from the gas phase are plotted against temperature for the goethite and hematite surfaces, taking into account experimental entropies for water, it appears that these minerals may well be instrumental in the retention of water during the cyclic variations in the atmosphere of Mars. 相似文献
10.
The elastic behaviour and the high-pressure structural evolution of a natural topaz, Al2.00Si1.05O4.00(OH0.26F1.75), have been investigated by means of in situ single-crystal X-ray diffraction up to 10.55(5) GPa. No phase transition has been observed within the pressure range investigated. Unit-cell volume data were fitted with a third-order Birch-Murnaghan Equation of State (III-BM-EoS). The III-BM-EoS parameters, simultaneously refined using the data weighted by the uncertainties in P and V, are: V
0=345.57(7) Å3, K
T0=164(2) GPa and K′=2.9(4). The axial-EoS parameters are: a
0=4.6634(3) Å, K
T0(a)=152(2) GPa, K′(a)=2.8(4) for the a-axis; b
0=8.8349(5) Å, K
T0(b)=224(3) GPa, K′(b)=2.6(6) for the b-axis; c
0=8.3875(7) Å, K
T0(c)=137(2) GPa, K′(c)=2.9(4) for the c-axis. The magnitude and the orientation of the principal Lagrangian unit-strain ellipsoid were determined. At P−P
0=10.55 GPa, the ratios ε1:ε2:ε3 are 1.00:1.42:1.56 (with ε1||b, ε2||a, ε3||c and |ε3| > |ε2| > |ε1|). Four structural refinements, performed at 0.0001, 3.14(5), 5.79(5) and 8.39(5) GPa describe the structural evolution in terms of polyhedral distortions. 相似文献
11.
The high-pressure elastic behaviour of a synthetic zeolite mordenite, Na6Al6.02Si42.02O96·19H2O [a=18.131(2), b=20.507(2), c=7.5221(5) Å, space group Cmc21], has been investigated by means of in situ synchrotron X-ray powder diffraction up to 5.68 GPa. No phase transition has been observed within the pressure range investigated. Axial and volume bulk moduli have been calculated using a truncated second-order Birch–Murnaghan equation-of-state (II-BM-EoS). The refined elastic parameters are: V
0=2801(11) Å3, K
T0= 41(2) GPa for the unit-cell volume; a
0=18.138(32) Å, K
T0(a)=70(8) GPa for the a-axis; b
0=20.517(35) Å, K
T0(b)=29(2) GPa for the b-axis and c
0=7.531(5) Å, K
T0(c)=38(1) GPa for the c-axis [K
T0(a): K
T0(b): K
T0(c)=2.41:1.00:1.31]. Axial and volume Eulerian finite strain versus “normalized stress” plots (fe–Fe plot) show an almost linear trend and the weighted linear regression through the data points yields the following intercept values: Fe(0)=39(4) GPa for V; Fe
a
(0)=65(18) GPa for a; Fe
b
(0)=28(3) GPa for b; Fe
c
(0)=38(2) GPa for c. The magnitudes of the principal Lagrangian unit-strain coefficients, between 0.47 GPa (the lowest HP-data point) and each measured P>0.47 GPa, were calculated. The unit-strain ellipsoid is oriented with ε1 || b, ε2 || c, ε3 || a and |ε1|> |ε2|> |ε3|. Between 0.47 and 5.68 GPa the relationship between the unit-strain coefficient is ε1: ε2: ε3=2.16:1.81:1.00. The reasons of the elastic anisotropy are discussed.An erratum to this article can be found at 相似文献
12.
13.
The Sanggok mine used to be one of the largest lead-zinc mines in the Hwanggangri mining district, Republic of Korea. The
present study characterizes the heavy metal contamination in the abandoned Sanggok mine creek on the basis of physico-chemical
properties of various kinds of water samples (mine, surface and groundwater). Hydrochemistry of the water samples is characterized
by the relatively significant enrichment of Ca2+, HCO3
–, NO3
– and Cl– in the surface and groundwaters, whereas the mine water is relatively enriched in Ca2+, Mg2+, heavy metals, and HCO3
– and SO4
2–. The more polluted mine water has a lower pH and higher Eh, conductivity and TDS values. The concentrations of some toxic
elements (Al, As, Cd, Cu, Fe, Mn, Pb, Se, Sr, Pb and Zn) are tens to hundreds of times higher in the mine water than in the
unpolluted surface and groundwaters. However, most immobile toxic pollutants from the mine drainage were quickly removed from
the surface water by the precipitation of Al and Fe oxyhydroxides. Geochemical modeling showed that potentially toxic heavy
metals might exist largely in the forms of MSO4
2– and M2+ in the mine water. These metals in the surface and groundwaters could form M2+, CO3
2– and OH– complex ions. Computer simulation indicates that the saturation indices of albite, alunite, anhydrite, chlorite, fluorite,
gypsum, halloysite and strontianite in the water samples are undersaturated and have progressively evolved toward the saturation
condition. However, barite, calcite, chalcedony, dolomite, gibbsite, illite and quartz were in equilibrium, and only clay
minerals were supersaturated. Ground and mine waters seemed to be in equilibrium with kaolinite field, but some surface water
were in equilibrium with gibbsite and seceded from the stability field of quartz. This indicates that surface water samples
in reaction with carbonate rocks would first equilibrate with carbonate minerals, then gibbsite to kaolinite. Investigations
on water quality and environmental improvement of the severely polluted Sanggok creek, as well as remediation methods on the
possible future pollution of the groundwater by the acid mine drainage from the abandoned metal mines, are urgently required.
Received: 4 February 2000 · Accepted: 9 May 2000 相似文献
14.
P. A. van Aken V. J. Styrsa B. Liebscher A. B. Woodland G. J. Redhammer 《Physics and Chemistry of Minerals》1999,26(7):584-590
The Fe M
2,3-edge spectra of solid solutions of garnets (almandine-skiagite Fe3(Al1–xFex)2[SiO4]3 and andradite-skiagite (Fe1–xCax)3Fe2[SiO4]3), pyroxenes (acmite-hedenbergite (Ca1–xNax)(Fe2+
1−xFe3+
x)Si2O6), and spinels (magnetite-hercynite Fe(Al1–xFex)2O4) have been measured using the technique of parallel electron energy-loss spectroscopy (EELS) conducted in a transmission
electron microscope (TEM). The Fe M
2,3 electron energy-loss near-edge structures (ELNES) of the minerals exhibit a characteristic peak located at 4.2 eV and 2.2 eV
for trivalent and divalent iron, respectively, prior to the main maximum at about 57 eV. The intensity and energy of the pre-edge
feature varies depending on Fe3+/ΣFe. We demonstrate a new quantitative method to extract the ferrous/ferric ratio in minerals. A systematic relationship
between Fe3+/ΣFe and the integral intensity ratio of the main maximum and the pre-edge peak of the Fe M
2,3 edge is observed. Since the partial cross sections of the Fe M
2,3 edges are some orders of magnitude higher than those of the Fe L
2,3 edges, the Fe M
2,3 edges are interesting for valence-specific imaging of Fe. The possibility of iron valence-specific imaging is illustrated
by Fe M
2,3-ELNES investigations with high lateral resolution from a sample of ilmenite containing hematite exsolution lamellae that
shows different edge shapes consistent with variations in the Fe3+/ΣFe ratio over distances on the order of 100 nm.
Received: 14 April 1998 / Revised, accepted: 8 March 1999 相似文献
15.
V. Palchik 《Rock Mechanics and Rock Engineering》2012,45(2):217-224
A semi-analytical equation for the modeling of stress–strain relationship for heterogeneous carbonate rocks exhibiting large
axial strains (εaf > 1%) is formulated. The equation is derived by modifying the stress–strain model based on Haldane’s distribution proposed
by Palchik (2006) for carbonate rocks exhibiting ε
af ≤ 1%. The developed exponential model is used to relate normalized axial stress (σ
a/σ
c) over the whole pre-failure strain range to current axial strain (ε
a) and failure strain (ε
af). For carbonate rocks exhibiting ε
af > 1%, the value of pre-calculated parameter δ involved in the stress–strain model is not constant, but dependent on the failure strain value (ε
af). The normalized stress–strain model can be used to calculate the failure strain in terms of uniaxial compressive strength
and stress–strain measurement at one point only. The advantages of the failure strain model and ways of its use in engineering
practice are discussed. 相似文献
16.
Virender K. Sharma Ria A. Yngard Zoltan Homonnay Abhishek Dey Chun He 《Aquatic Geochemistry》2010,16(3):483-490
The kinetics of the formation of the purple-colored species between FeIII-EDTA and peroxynitrite were studied as a function of pH (10.4–12.3) at 22°C in aqueous solutions using a stopped-flow technique.
A purple-colored species was immediately formed upon mixing, which had an absorbance maximum at 520 nm. The increase in absorbance
with time could be fit empirically by a power function with two parameters a and b. The power equation determined was absorbance = a*t
b
, where a increased linearly with pH and the concentration of peroxynitrite, while b almost remained constant with a value of ~0.25. The molar extinction coefficient ε520 nm for the colored species was determined as 13 M−1cm−1, which is much lower than ε520 nm = 520 M−1 cm−1 for the [FeIII(EDTA)O2]3−, a purple species observed in the FeIII–EDTA–H2O2 system. The results of kinetics and spectral measurements of the present study are briefly discussed and compared with those
of the reaction between Fe(III)-EDTA and hydrogen peroxide. 相似文献
17.
Shahid Azam 《Geotechnical and Geological Engineering》2012,30(1):107-118
Knowledge of slurry settling is essential for geotechnical engineering applications such as coastal land reclamation and mine
waste disposal. In the presence of charged solids and ion-rich liquids, complex physicochemical interactions govern the behavior
of slurries. The main objective of this study was to develop a fundamental understanding of self-weight settling of laterite
ore slurries. To capture the influence of geology and the environment, samples were obtained from mining operations in different
parts of the globe. Based on laboratory testing, the investigated ores were found to be either oxide-rich with goethite, gibbsite,
meghamite and hematite making at least 90% of the material or clay-rich with chrysotile, cholritic intergrade, and siliceous
minerals accounting for more than 50% of the sample. The dominance of salt forming ions such as Na+, K+, Ca2+, Mg2+, Cl−, NO3
−, HCO3
− and SO4
2− in the pore waters indicated the influence of seawater on the waters used for slurry preparation. The oxide-rich ores in
low ionic waters resulted in flocculated fabrics whereas the clay-rich ores in high ionic waters led to cardhouse microstructures.
The aggregated fabrics with low tortuousity and fewer dead ends resulted in a high settling rate and amount (k
i
= 10−1 to 10−2 cm/s and SP = 62 to 49%) whereas the cardhouse morphologies with high tortuousity and lower pore connectivity exhibited a
slow and low settling (k
i
= 10−3 to 10−4 cm/s and SP = 37 to 17%). The initial hydraulic conductivity was found to be directly proportional to settling potential. 相似文献
18.
I. V. Pekov N. V. Zubkova Ya. E. Filinchuk N. V. Chukanov A. E. Zadov D. Yu. Pushcharovsky E. R. Gobechiya 《Geology of Ore Deposits》2010,52(8):767-777
New minerals, shlykovite and cryptophyllite, hydrous Ca and K phyllosilicates, have been identified in hyperalkaline pegmatite
at Mount Rasvumchorr, Khibiny alkaline pluton, Kola Peninsula, Russia. They are the products of low-temperature hydrothermal
activity and are associated with aegirine, potassium feldspar, nepheline, lamprophyllite, eudialyte, lomonosovite, lovozerite,
tisinalite, shcherbakovite, shafranovskite, ershovite, and megacyclite. Shlykovite occurs as lamellae up to 0.02 × 0.02 ×
0.5 mm in size or fibers up to 0.5 mm in length usually combined in aggregates up to 3 mm in size, crusts, and parallel-columnar
veinlets. Cryptophyllite occurs as lamellae up to 0.02 × 0.1 × 0.2 mm in size intergrown with shlykovite being oriented parallel
to {001} or chaotically arranged. Separate crystals of the new minerals are transparent and colorless; the aggregates are
beige, brownish, light cream, and pale yellowish-grayish. The cleavage is parallel to (001) perfect. The Mohs hardness of
shlykovite is 2.5–3. The calculated densities of shlykovite and cryptophyllite are 2.444 and 2.185 g/cm3, respectively. Both minerals are biaxial; shlykovite: 2V
meas = −60(20)°; cryptophyllite: 2V
meas > 70°. The refractive indices are: shlykovite: α = 1.500(3), β = 1.509(2), γ = 1.515(2); cryptophyllite: α = 1.520(2), β
= 1.523(2), γ = 1.527(2). The chemical composition of shlykovite determined by an electron microprobe (H2O determined from total deficiency) is as follows, wt %: 0.68 Na2O, 11.03 K2O, 13.70 CaO, 59.86 SiO2, 14.73 H2O; the total is 100.00. The empirical formula calculated on the basis of 13 O atoms (OH/H2O calculated from the charge balance) is (K0.96Na0.09)Σ1.05Ca1.00Si4.07O9.32(OH)0.68 · 3H2O. The idealized formula is KCa[Si4O9(OH)] · 3H2O. The chemical composition of cryptophyllite determined by an electron microprobe (H2O determined from the total deficiency) is as follows, wt %: 1.12 Na2O, 17.73 K2O, 11.59 CaO, 0.08 Al2O3, 50.24 SiO2, 19.24 H2O, the total is 100.00. The empirical formula calculated on the basis of (Si,Al)4(O,OH)10 (OH/H2O calculated from the charge balance) is (K1.80Na0.17)Σ1.97Ca0.99Al0.01Si3.99O9.94(OH)0.06 · 5.07H2O. The idealized formula is K2Ca[Si4O10] · 5H2O. The crystal structures of both minerals were solved on single crystals using synchrotron radiation. Shlykovite is monoclinic;
the space group is P21/n; a = 6.4897(4), b = 6.9969(5), c = 26.714(2)?, β = 94.597(8)°, V = 1209.12(15)?3, Z = 4. Cryptophyllite is monoclinic; the space group is P21/n; a = 6.4934(14), b = 6.9919(5), c = 32.087(3)?, β = 94.680(12)°, V= 1451.9(4)?, Z = 4. The strongest lines of the X-ray powder patterns (d, ?-I, [hkl] are: shlykovite 13.33–100[002], 6.67–76[004], 6.47–55[100], 3.469–45[021], 3.068–57[$
\bar 1
$
\bar 1
21], 3.042–45[121], 2.945–62[ 23], 2.912–90[025, 12, 211]; cryptophyllite 16.01–100[002], 7.98–24[004], 6.24–48[101], 3.228–22[$
\bar 1
$
\bar 1
09], 3.197–27[0.0.10], 2.995–47[122], 2.903–84[123, 204, $
\bar 1
$
\bar 1
24, 211], 2.623–20[028, 08, 126]. Shlykovite and cryptophyllite are members of new related structural types. Their structures
are based on a two-layer packet consisting of tetrahedral Si layers linked with octahedral Ca chains. Mountainite, shlykovite
and cryptophyllite could be combined into the mountainite structural family. Shlykovite is named in memory of Russian geologist
V. G. Shlykov (1941–2007); the name cryptophyllite is from the Greek words meaning concealed and leaf that allude to its layered structure (phyllosilicate) in combination with a lamellar habit and intimate intergrowths with
visually indistinguishable shlykovite. Type specimens of the minerals are deposited at the Fersman Mineralogical Museum of
the Russian Academy of Sciences, Moscow. 相似文献
19.
Zheming Wang Yuanxian Xia Tom C. Resch Dean A. Moore C. Liu 《Geochimica et cosmochimica acta》2011,75(10):2965-8740
The adsorption and speciation of U(VI) was investigated on contaminated, fine grained sediment materials from the Hanford 300 area (SPP1 GWF) in simulated groundwater using cryogenic laser-induced U(VI) fluorescence spectroscopy combined with chemometric analysis. A series of reference minerals (montmorillonite, illite, Michigan chlorite, North Carolina chlorite, California clinochlore, quartz and synthetic 6-line ferrihydrite) was used for comparison that represents the mineralogical constituents of SPP1 GWF. Surface area-normalized Kd values were measured at U(VI) concentrations of 5 × 10−7 and 5 × 10−6 mol L−1 that displayed the following affinity series: 6-line-ferrihydrite > North Carolina chlorite ≈ California clinochlore > quartz ≈ Michigan chlorite > illite > montmorillonite. Both time-resolved spectra and asynchronous two-dimensional (2D) correlation analysis of SPP1 GWF at different delay times indicated that two major adsorbed U(VI) species were present in the sediment that resembled U(VI) adsorbed on quartz and phyllosilicates. Simulations of the normalized fluorescence spectra confirmed that the speciation of SPP1 GWF was best represented by a linear combination of U(VI) adsorbed on quartz (90%) and phyllosilicates (10%). However, the fluorescence quantum yield for U(VI) adsorbed on phyllosilicates was lower than quartz and, consequently, its fractional contribution to speciation may be underestimated. Spectral comparison with literature data suggested that U(VI) exist primarily as inner-sphere complexes with surface silanol groups on quartz and as surface U(VI) tricarbonate complexes on phyllosilicates. 相似文献
20.
Célia Dalou Kenneth T. Koga Nobumichi Shimizu Julien Boulon Jean-Luc Devidal 《Contributions to Mineralogy and Petrology》2012,163(4):591-609
We experimentally determined F and Cl partition coefficients together with that of 19 trace elements (including REE, U-Th,
HFSE and LILE) between basaltic melt and lherzolite minerals: olivine, orthopyroxene, clinopyroxene, plagioclase and garnet.
Under conditions from 8 to 25 kbars and from 1,265 to 1,430°C, compatibilities of F and Cl are globally ordered as D
Cpx/melt > D
Opx/melt > D
Grt/melt > D
Ol/melt > D
Plag/melt, and D
F
mineral/melt is larger than D
Clmineral/melt. Four other major results were brought to light. (1) Chlorine partition coefficients positively correlate with the jadeite
component in orthopyroxene, and increase of the CaTs component promotes Cl incorporation in clinopyroxene. (2) Variations
of fluorine partition coefficients correlate strongly with melt viscosity. (3) F and Cl partition coefficients correlate with
the Young’s modulus (E
0) of pyroxene octahedral sites (M sites) and with Raman vibrational modes of pyroxenes. This demonstrates a fundamental interaction
between the M site of pyroxenes and the incorporation of F and Cl. (4) We also determined the parameters of the lattice-strain
model applied to 3+ cation trace elements for the two M sites in orthopyroxene and clinopyroxene: D
0M1, D
0M2, r
0M1, r
0M2, E
0M1 and E
0M2. 相似文献