Distribution of hydrate on Europa: Further evidence for sulfuric acid hydrate

Sulfuric acid hydrate has been proposed as an important species on Europa's surface, the acid being produced by radiolysis of surficial sulfur compounds. We investigated the spectral properties of disordered and crystalline forms of sulfuric acid and suggest that the hydration properties of Europa's hypothesized sulfuric acid lie between two end members: liquid sulfuric acid and its higher crystalline hydrates. The spectra of these end members are similar except for spectral shifts at the band edges. We measured the optical constants of sulfuric acid octahydrate and used these with simple radiative transfer calculations to fit Europa spectra obtained by Galileo's Near Infrared Mapping Spectrometer (NIMS). The global distribution of the hydrate that we associate here with hydrated sulfuric acid shows a strong trailing-side enhancement with a maximum fractional hydrate abundance of 90% by volume, corresponding to a sulfur atom to water molecule ratio of 10%. The hydrate concentration spatially correlates with the ultraviolet and visible absorption of the surface and with the sulfur dioxide concentration. The asymmetric global distribution is consistent with Iogenic plasma ion implantation as the source of the sulfur, possibly modified by electron irradiation and sputtering effects. The variegated distribution also correlates with geologic forms. A high spatial resolution image shows resolved lineae with less hydrate appearing within the lineae than in nearby crustal material. The low concentration of hydrated material in these lineae argues against their conveying sulfurous material to the surface from the putative ocean.     

SWIFT: An adaptive optics assisted I/z band integral field spectrograph

SWIFT is an adaptive optics assisted integral field spectrograph covering the I and z astronomical bands (0.7–1.0 μm) at a spectral resolving power R  5000. At its heart is an all-glass image slicer with high throughput based on a novel de-magnifying design allowing a compact instrument. SWIFT profits from two recent developments: (i) the improved ability of second generation adaptive optics systems to correct for atmospheric turbulence in SWIFTS’s bandpass, and (ii) the availability of CCD array detectors with high quantum efficiency at very red wavelengths. It is a dedicated integral field spectrograph, specifically built to address a range of interesting astrophysical questions.     

Spectral Energy Distribution fitting: Application to Lyα-emitting galaxies

Spectral Energy Distribution (SED) fitting is a well-developed astrophysical tool that has recently been applied to high-redshift Lyα-emitting galaxies. If rest-frame ultraviolet through near-infrared photometry is available, it allows the simultaneous determination of the star formation history and dust extinction of a galaxy. Lyα-emitter SED fitting results from the literature find star formation rates 3 M yr⁻¹, stellar masses 10⁹ M for the general population but 10¹⁰ M for the subset detected by IRAC, and very low dust extinction, A_V  0.3, although a couple of outlying analyses prefer significantly more dust and higher intrinsic star formation rates. A checklist of 14 critical choices that must be made when performing SED fitting is discussed.     

Sulfuric acid aerosols in the atmospheres of the terrestrial planets

Clouds and hazes composed of sulfuric acid are observed to exist or postulated to have once existed on each of the terrestrial planets with atmospheres in our solar system. Venus today maintains a global cover of clouds composed of a sulfuric acid/water solution that extends in altitude from roughly 50 km to roughly 80 km. Terrestrial polar stratospheric clouds (PSCs) form on stratospheric sulfuric acid aerosols, and both PSCs and stratospheric aerosols play a critical role in the formation of the ozone hole. Stratospheric aerosols can modify the climate when they are enhanced following volcanic eruptions, and are a current focus for geoengineering studies. Rain is made more acidic by sulfuric acid originating from sulfur dioxide generated by industry on Earth. Analysis of the sulfur content of Martian rocks has led to the hypothesis that an early Martian atmosphere, rich in SO₂ and H₂O, could support a sulfur-infused hydrological cycle. Here we consider the plausibility of frozen sulfuric acid in the upper clouds of Venus, which could lead to lightning generation, with implications for observations by the European Space Agency's Venus Express and the Japan Aerospace Exploration Agency's Venus Climate Orbiter (also known as Akatsuki). We also present simulations of a sulfur-rich early Martian atmosphere. We find that about 40 cm/yr of precipitation having a pH of about 2.0 could fall in an early Martian atmosphere, assuming a surface temperature of 273 K, and SO₂ generation rates consistent with the formation of Tharsis. This modeled acid rain is a powerful sink for SO₂, quickly removing it and preventing it from having a significant greenhouse effect.     

Stellar populations in barred spirals

OASIS observations obtained at the Canada–France–Hawaii Telescope for the spiral galaxies NGC 4900 and NGC 5430 produce one spectrum for each 0.41″ element of the 11″ × 15″ field of view. This allows for the spatial characterisation of the different stellar populations. From these observations we study the young (10 Myr) and older stellar populations using evolutionary synthesis codes. Based on the gas emission lines, we find that the young populations are located in relatively small regions and dominate the integrated flux. In NGC 4900, the young populations are distributed in a bar-like structure featuring a hole near the position of the galaxy’s centre. The young stellar populations of NGC 5430 form a nuclear ring and two patches at the base of the spiral arms. Based on Mg₂ and FeI absorption lines, we find that in both galaxies, the young stars are superimposed on a relatively homogenous population of a few Gyr.     

Propagating of sound and thermal waves in a reacting fluid

The propagation of linear sound and thermal waves in a reacting fluid, in which the heating and cooling processes can be represented by a heat-loss functionL(, T, is studied. A complex dispersion relation is found, from which the phase velocity and the scale length for damping (or amplification), of the above two-wave mode are calculated Wave amplification may occur in reacting locally stable fluids. Results are applied to a hydrogen plasma model assumed to be heated at a non-specified constant rate and cooled by recombination, excitation, and ionization by collisions, and free-free transitions. The phase velocity , the scale-length for damping , and the relevant relaxation times are calculated as functions of the dimensionless frequency , for temperatures ranging from those at which the hydrogen plasma is neutral to those at which it becomes completely ionized.     

Sulfuric Acid Production on Europa: The Radiolysis of Sulfur in Water Ice

Europa's surface is chemically altered by radiolysis from energetic charged particle bombardment. It has been suggested that hydrated sulfuric acid (H₂SO₄·nH₂O) is a major surface species and is part of a radiolytic sulfur cycle, where a dynamic equilibrium exists between continuous production and destruction of sulfur polymers S_x, sulfur dioxide SO₂, hydrogen sulfide H₂S, and H₂SO₄·nH₂O. We measured the rate of sulfate anion production for cyclo-octal sulfur grains in frozen water at temperatures, energies, and dose rates appropriate for Europa using energetic electrons. The measured rate is G_Mixture(SO₄²⁻)=f_Sulfur (r₀/r)^βG₁ molecules (100 eV)⁻¹, where f_Sulfur is the sulfur weight fraction, r is the grain radius, r₀=50 μm, β≈1.9, and G₁=0.4±0.1. Equilibrium column densities N are derived for Europa's surface and follow the ordering N(H₂SO₄) » N(S)>N(SO₂)>N(H₂S). The lifetime of a sulfur atom on Europa's surface for radiolysis to H₂SO₄ is τ(−S)=120(r/r₀)^β years. Rapid radiolytic processing hides the identity of the original source of the sulfurous material, but Iogenic plasma ion implantation and an acidic or salty ocean are candidate sources. Sulfate salts, if present, would be decomposed in <3800 years and be rapidly assimilated into the sulfur cycle.     

Oscillations of coronal electron traps inferred from hard X-ray data

The work of Brown and Hoyng (1975) on the betatron acceleration of hard X-ray source electrons trapped in a vibrating flux tube is generalised to include Fermi acceleration by the varying transverse field. This development can explain the trajectory of bursts in a plot of equivalent thick-target electron flux versus spectral index as inferred from observations obtained by ESRO TD1A. Specifically the loops observed in this , diagram, unexplained in Brown and Hoyng's anslysis are accounted for by a changing phase relationship between the varying field strength f(t) and magnetic scale length g(t)- Application of the formalism to the detailed TD1A observations of the large events of 1972, August 4 and 7, allows inference of the evolution of f(t), g(t) in these events.Now at: Space Sciences Laboratory, University of California, Berkeley, U.S.A.     

Sound and thermal waves propagation in a hydrogen plasma heated by an external radiation field

The thermal equilibrium of a hydrogen plasma heated and ionized by an external radiation field, diluted by a factorW _* and defined by an effective temperatureT _*, is studied. In addition, the problem of propagation of acoustic and thermal waves in the above plasma model is also analysed. It is found that an external radiation field has stabilizing effects against wave amplification. From the dispersion relation obtained, the phase velocity for sound and thermal waves and their respective scale-length of damping (or anti-damping) is calculated as a function of the frequency for representative values of the plasma temperature and the external radiation fieldT _*.     

The thermodynamics of dust formation: Evidence from meteorites

A substantial fraction of interstellar dust probably formed in the nebulae around protostars, a setting similar to that envisioned for meteoritic material. From studies of the mineralogy and composition of meteorites it is possible to obtain quantitative information on the conditions that prevailed in the nebula. For example, pressures in the range 10^–3 to 10^–6 atm are indicated. At these pressures the kinetics of nucleation and grain growth are favorable.The fact that the gas associated with interstellar dust has solar H/S ratios indicates that FeS, which forms at 680 K, independent of pressure, is not present in the dust. Since iron only becomes oxidized at even lower temperatures, also via pressure-independent reactions, oxidized iron is not expected in the dust. If most interstellar dust forms in nebulae and is ejected back into space, a relatively high temperature is implied, 700K. Dust formation around stars with high C/O ratios is expected to produce minerals found in the highly reduced enstatite chondrites.High-temperature fractionation processes ( 1000 K) played an important role in the nebula. Much of the Al, Ca, Ti, etc., evidently condensed and accreted into cm-sized objects, some of which are found in carbonaceous chondrites. These objects are explicable in terms of formation from a cooling neutral gas with cosmic composition. Their most important distinguishing characteristics are low volatile and low Si contents, coupled with high refractory element contents constrains formation via isothermal compression to grain temperature 1000 K.Invited contribution to the proceedings of a workshop onThermodynamics and Kinetics of Dust Formation in the Space Medium held at the Lunar and Planetary Institute, Houston, 6–8 September, 1978.     

The ultraviolet radiation environment in the habitable zones around low-mass exoplanet host stars

The EUV (200–911 Å), FUV (912–1750 Å), and NUV (1750–3200 Å) spectral energy distribution of exoplanet host stars has a profound influence on the atmospheres of Earth-like planets in the habitable zone. The stellar EUV radiation drives atmospheric heating, while the FUV (in particular, Lyα) and NUV radiation fields regulate the atmospheric chemistry: the dissociation of H₂O and CO₂, the production of O₂ and O₃, and may determine the ultimate habitability of these worlds. Despite the importance of this information for atmospheric modeling of exoplanetary systems, the EUV/FUV/NUV radiation fields of cool (K and M dwarf) exoplanet host stars are almost completely unconstrained by observation or theory. We present observational results from a Hubble Space Telescope survey of M dwarf exoplanet host stars, highlighting the importance of realistic UV radiation fields for the formation of potential biomarker molecules, O₂ and O₃. We conclude by describing preliminary results on the characterization of the UV time variability of these sources.     

POWER SPECTRA OF SOLAR NETWORK AND NON-NETWORK FIELDS

We report new properties of solar magnetic fields in a quiet region as found from their magnetic power spectra. The power spectra of network and intranetwork fields (non-network fields) are separately calculated from a Big Bear magnetogram obtained with moderately high spatial resolution of 1.5 arc sec and a high sensitivity reaching 2 Mx cm^-2. The effect of seeing on the power spectrum has been corrected using Fried's (1966) Modulation Transfer Function with the seeing parameter determined in our previous analysis of the magnetogram. As a result, it is found that the two-dimensional power spectra of network and non-network fields appear in a form: ( ₁) ^-1 and ( ₁) ^-3.5. Here ₀ 0.47 Mm^-1 for network fields and ₀ 0.69 Mm^-1 for non-network fields, the latter of which corresponds to the size of mesogranulation; ₁ 3.0 Mm^-1 for both, which is about the size of a large granule. The network field spectrum below ₀ appears nearly flat, whereas that of non-network fields instead decreases towards lower wave numbers as ( ) ^1.3. The turnover behavior of magnetic field spectra around ₁ coincides with that found for the velocity power spectrum, which may justify the kinetic approach taken in previous theoretical studies of the solar magnetic power spectra.     

Static spherical configurations of cold matter in the Einstein-Cartan theory of gravitation

We investigate static, spherical configurations of cold catalized matter in the Einstein-Cartan theory of gravitation. Assuming that density of spin is proportional to the number density of baryonsn and using an equation of state of a degenerate, relativistic Fermi gas, we numerically integrated the relativistic equation of equilibrium. We have also studied the stability of those configurations. Configurations with central number densityn _c such that where is the effective pressure, are very similar to general relativistic configurations with the same central density. In the Einstein-Cartan theory there exists another disjoint family of equilibrium configurations for which but . Those configurations have very small masses 10^–6 g and raddi 10^–34 cm and are unstable.Supported in part by Research Grant MR-I-7.     

Comets and the formation of planets

A morphological study of the physical and dynamical processes of planet formation is presented, with emphasis on the intermediary role of comet nuclei. Although guided by a particular model of the evolution of the pre-planetary solar nebula, implying the freezing-out of hydrogen in the region of the giant planets, the derivations and conclusions are of wider import, applicable to other cosmogonic models as well as to certain phases of star formation. The items evaluated physically, dynamically, or statistically comprise: (1) the total number mass of comets in Oort's cloud; (2) a re-evaluation of the diameters and masses of cometary nuclei; (3) the processes of nucleation from gravitational and Boltzmann instabilities of gaseous media to agglomerations of particulate matter as conditioned by inbuilt angular momentum; (4) the statistical-dynamical conditions and time scales of orbital interaction of comets with the planets and the consequences of disintegration.A consistent model proposes the formation of comets and planets in pre-planetary rings of the residual solar nebula, with subsequent ejection, chiefly by Jupiter, of the comets to Oort's sphere. Screening by absorbing matter is not only probable, but necessary to protect the comets from dis-integration during the process of ejection.Paper dedicated to Prof. H. C. Urey on the occasion of his 80th birthday on 29 April, 1973.This work has been currently supported by grants from the National Aeronautics and Space Administration, Goddard Space Flight Center, Greenbelt, Maryland.     

Gas,dust and molecules in the Galaxy

The relative abundances of cool neutral hydrogen, carbon monoxide and formaldehyde are studied using all the available observational data in the literature. The obtained mean valuesN _{H 1}/ ,N _{H 1}/N _CO,N _CO/ are approximately constant in the dark clouds of the solar neighbourhood and in the distant molecular clouds.The observed correlationsN _CO,A _v and ,A _v show that formaldehyde can also be used as an indicator of molecular hydrogen. The ratioN H₁/A _v depends on densities and decays considerably in the ranges of visual absorptions in which the molecules become detectable (A _v 2 mg); an average of /N _{H 1}10 is calculated for the dense dark clouds.Indications of systematic temperature gradiens T/A _v are found for formaldehyde and neutral hydrogen inside the dark clouds, and qualitative comparisons are made with theoretical quantum mechanics calculations.The observed carbon monoxide and formaldehyde abundances, the free electron layer in the Galaxy, the distribution of neutral hydrogen in different states are only compatible if an ionization rate of 10^–16 is accepted, provided presumably by 2 MeV protons of cosmic radiation.Three main states for neutral hydrogen and dust are identified from different kinds of observational data (21 cm line in emission, absorption in galactic radio sources and self-absorption in the hot gas background): (1) a homogeneous intercloud stratum of tenuous gas and dust with a galactic halfwidth of 350 pc and mean parametersn _H=0.2 atom cm^–3, spin temperatureT _s 10000 K andn _d 0.3 mg kpc^–1; (2) cool gas and dust concentrated in spiral features with a galactic half-width of less than 100 pc, probably forming clouds with diffuse and indefinite limits, with mean parametersn _H2 atom cm^–3,T _s <1100 K (probable average,T _s =135 K) andn _d 3 mg kpc^–1; (3) dense gas and dust clouds with a mean diameter of 7 pc and mean parametersn _H700 atom cm^–3 (90% in a molecular state),T _s 63 K andn _d 1 mg pc^–1 on which molecules as CO and H₂CO are formed.The application of the Jeans criteria for gravitational instability shows that the dense clouds are gravitationally bound while the gas in the intermediate state (2) can be protected against collapse by the total internal energy in the medium increasing due to cosmic rays and the magnetic field in the Galaxy.The observed velocity halfwidths and galacticZ-halfwidths in states (1) and (2) are compatible with a total mass density in the galactic layer of 90M pc^–2 (gas plus stars) according to the barometric equation.The relative abundancesN _{H 1}/N _CO, calculated from C¹²O and C¹³O data and comparisons with studies in the 21 cm emission line, show that the antenna temperatureT _A ⁺ in the 2.6 mm line of C¹²O is a good indicator of the cool gas densities in the Galaxy. The possible application of this for studies in galactic structure is discussed and hypothetical distributions of carbon monoxide in the zones outside the galactic planeB=0° are presented.From a synthesis based on the results obtained, a cycle is postulated for the neutral hydrogen in the Galaxy: condensation and cooling of gas molecular formation gravitational collapse and star formation gas dissipation and heating by cosmic rays and UV radiation.     

Short-term periodicities of the sun's ‘mean’ and differential rotation

We have looked for periodicities in solar differential rotation on time scales shorter than the 11-year solar cycle through the power- spectrum analysis of the differential rotation parameters determined from Mt. Wilson velocity data (1969–1994) and Greenwich sunspot group data (1879–1976). We represent the differential rotation by a set of Gegenbauer polynomials (()= + (5sin₂–1)+ (21sin₄–14sin₂+1)). For the Mt. Wilson data, we focus on observations obtained after 1981 due to the reduced instrumental noise and have binned the data into intervals of 19 days. We calculated annual averages for the sunspot data to reduce the uncertainty and corrected for outliers occuring during solar cycle minima. The power spectrum of the photospheric mean rotation , determined from the velocity data during 1982–1994, shows peaks at the periods of 6.7–4.4 yr, 2.2 ± 0.4 yr, 1.2 ± 0.2 yr, and 243 ± 10 day with 99.9% confidence level, which are similar to periods found in other indicators of solar activity suggesting that they are of solar origin. However, this result has to be confirmed with other techniques and longer data sets. The 11-yr periodicity is insignificant or absent in . The power spectra of the differential rotation parameters and , determined from the same subset, show only the solar cycle period with a 99.9% confidence level.The time series of determined from the yearly sunspot group data obtained during 1879–1976 is very similar to the corresponding time series of . After correcting for data with large error bars (occurring during cycle minima), we find periods, which are most likely harmonics of the solar cycle, such as 18.3 ± 3.0 yr and 7.5 ± 0.5 yr in and confirmed these and the 3.0 ± 0.1 yr period in . The original time series show in addition some shorter periods, absent in the corrected data, representing temporal variations during cycle minimum. Given their large error bars, it is uncertain whether they represent a solar variation or not. The results presented here show considerable differences in the periodicities of and determined from the velocity data and the spot group data. These differences may be explained by assuming that the rotation rates determined from velocity and sunspot data represent the rotation rates of the Sun's surface layers and of somewhat deeper layers.     

A new model for interstellar dust

Some physical, chemical and optical properties of mixed oxide grain material are discussed and the formation of such dust is examined. Surface chemistry on these grains may be responsible for the selective depletion of elements and for the formation of molecules such as H₂CO in diffuse clouds. Spectra of mixed oxide grains yield features at 9.6 and 18 m together with a broad band at 4.6 m^–1.Invited contribution to the Proceedings of a Workshop onThermodynamics and Kinetics of Dust Formation in the Space Medium held at the Lunar and Planetary Institute, Houston, 6–8 September, 1978.     

Sulfur Chemistry at Millimeter Wavelengths in C/Hale-Bopp

The recent availability of bright comets has given us an excellent opportunity to study cometary chemistry. Comet Hale-Bopp (1995 O1)gave us the particularly rare opportunity to study a bright and active comet for almost two years. Our program concentrated on millimeter-wave observations of sulfur-bearing molecules in an effort to understand the total sulfur budget of the comet. Using the National Radio Astronomy Observatory 12-m telescope on Kitt Peak we monitored both the long and short-term variations in H₂S, CS, and OCS, as well as observing H₂CS and SO. This was the first observation of H₂CS in any comet (Figure 1). Additionally, we mapped CS with the BIMA interferometer. Variations in the line profiles and changes in line intensity as large as a factor of two were seen in day to day observations of both H₂S and CS. An example for H₂S is shown in Figure 2. This is the first time we can attempt to study the entire group of sulfur-bearing molecules. Models of the sulfur coma have thus far largely been based on observations of the daughter products CS and atomic sulfur made over the last 18 years using the International Ultraviolet Explorer (IUE) satellite, coupled with radio observations of CS and H₂S in several recent comets. Four new sulfur-bearing species have been observed in comets Hale-Bopp and Hyaku take, three of them parent species. The high resolution maps in CS will also allow spatial information to be included in the sulfur model for the first time. C/Hale-Bopp is the first comet in which so many sulfur species have been observed. Analysis of the abundances of these species in comparison to the total atomic sulfur observed should reveal whether or not we can now account for all of the primary sulfur sources in comets. Perhaps the most interesting question that these observations raised was why C/Hale-Bopp appeared to contain so much more SO and SO₂ (as observed by others) than any other comet. This spurred the discovery that the UV fluorescence models of these species were incorrect (S. J. Kim, this issue). Analysis of the data and modeling of the sulfur budget are still underway. This revised version was published online in July 2006 with corrections to the Cover Date.     

Europa’s ridged plains and smooth low albedo plains: Distinctive compositions and compositional gradients at the leading side-trailing side boundary

This investigation uses linear mixture modeling employing cryogenic laboratory reference spectra to estimate surface compositions and water ice grain sizes of Europa’s ridged plains and smooth low albedo plains. Near-infrared spectra for 23 exposures of ridged plains materials are analyzed along with 11 spectra representing low albedo plains. Modeling indicates that these geologic units differ both in the relative abundance of non-ice hydrated species and in the abundance and grain sizes of water ice. The background ridged plains in our study area appear to consist predominantly of water ice (∼46%) with approximately equal amounts (on average) of hydrated sulfuric acid (∼27%) and hydrated salts (∼27%). The solutions for the smooth low albedo plains are dominated by hydrated salts (∼62%), with a relatively low mean abundance of water ice (∼10%), and an abundance of hydrated sulfuric acid similar to that found in ridged plains (∼27%). The model yields larger water ice grain sizes (100 μm versus 50-75 μm) in the ridged plains. The 1.5-μm water ice absorption band minimum is found at shorter wavelengths in the low albedo plains deposits than in the ridged plains (1.498 ± .003 μm versus 1.504 ± .001 μm). The 2.0-μm band minimum in the low albedo plains exhibits a somewhat larger blueshift (1.964 ± .006 μm versus 1.983 ± .006 μm for the ridged plains).The study area spans longitudes from 168° to 185°W, which includes Europa’s leading side-trailing side boundary. A well-defined spatial gradient of sulfuric acid hydrate abundance is found for both geologic units, with concentrations increasing in the direction of the trailing side apex. We associate this distribution with the exogenic effects of magnetospheric charged particle bombardment and associated chemical processing of surface materials (the radiolytic sulfur cycle). However, one family of low albedo plains exposures exhibits sulfuric acid hydrate abundances up to 33% lower than found for adjacent exposures, suggesting that these materials have undergone less processing, thus implying that these deposits may have been emplaced more recently.Modeling identifies high abundances (to 30%) of magnesium sulfate brines in the low albedo plains exposures. Our investigation marks the first spectroscopic identification of MgSO₄ brine on Europa. We also find significantly higher abundances of sodium-bearing species (bloedite and mirabilite) in the low albedo plains. The results illuminate the role of radiolytic processes in modifying the surface composition of Europa, and may provide new constraints for models of the composition of Europa’s putative subsurface ocean.     

The influence of spectral resolution on line blending and wavelength positions in the solar UV spectrum

For representative sections of the solar UV spectrum ( 2765 Å– 2790 Å, 2765 Å– 2805 Å) the line density and the accuracy of wavelength positions of absorption features are derived as function of the spectral resolution. In low resolution spectrograms unresolved blends may shift intrinsic wavelength positions of absorption lines by amounts up to a few tenths of the spectral resolution.The results obtained for the solar spectrum are applied to the flux spectrogram of CMi.Guest Investigator in the BUSS Program jointly performed by the Space Research Laboratory, Utrecht, The Netherlands, and the NASA L. B. Johnson Space Center, Houston, U.S.A.