Authigenetic K—feldspars and Their Relations to Sn—polymetallic Mineralization in the Dachang Ore Field

Sn-polymetallic ores at Dachang,Guangxi Autonomous Region,China,are hosted in Middle-Upper Devonian reef limestones,siliceous rocks,banded and lenticular limestones,etc.Two types of orebodies can be distinguished according to their telations to the bedding:one is distributed along the bedding and the.other cuts across the bedding.Sn and sulfide orebodies associated with K-feldspare are mostly characterized by laminated ore structure. Microscopic examinations of K-feldspar-bearing rocks,in conjunction with X-ray diffraction,chemical composiion and cathodoluminescence data for K-feldspars,as well as their telations to mineralization,the authors consider that the K-feldspare are of authigenic origin,subordinate to the epigenetic stage of diagenesis,They resulted from the reaction of mixed,deep-seated,circulating underground hot waters rich in K,Al and Si with argillaceous carbonates during the Indo nesian orogenic movement.It is suggested more attention should be paid to the effect of authigenic K-feldspars on Sn mineralization.In the meantime the event related to circulating underground hot waters should also be taken into account so as to provide new clues to blind ore prospecting.     

Isotope Geochemistry of the Dongchuan Copper Deposit,Yunnan,SW China： Stratigraphic Chronology and Application of Lead Isotopes in Geochemical Exploration

In this paper the Pb-Pb isochron method was used to determine the isotopic ages of the Luoxue Formation dolomites (1716 ±56 Ma), the Heishan Formation carbonaceous slates ( 1607 ±128 Ma) of the middle sub-group of the Kunyang Group and the Dayingpan Formation carbonaceous slates (1258 ±70Ma) of the upper sub-group of the Kunyang Group. The age of the middle sub-group of the Kunyang Group is about 1800 – 1600 Ma, belonging to the Late Paleo-Proterozoic, and that of the Dayingpan Formation in the upper sub-group of the Kunyang Group is about 1200 – 1300 Ma, belonging to the Middle Proterozoic. In addition, the Pb isotope chemical exploration techniques were used to study systematically the Pb isotopic compositions of rocks and ores across the No. 14 vein in the middle segment of the No. 1 pit of the Tangdan copper deposit and the result showed that the Pb isotope V₁ values are negatively correlated with the copper contents. It is the first trial to use the systematic section method to conduct Pb isotope chemical exploration. This research project was financially supported jointly by the National Natural Science Foundation of China (Grant Nos. 49702022, 40073001) and the State 973 Program (No.G1999043215).     

China‘s First Exploration of Chukchi Sea and Its Adjacent Waters in the Arctic -A Study on Lead Geochemistry of Atmospheric Aerosol

The Pb concentrations of atmospheric aerosol in the Chukchi Sea of the Arctic vary within the range of 0.167-0.962ng/m^2,with an average of 0.532ng/m^3,These concentration values are 200 times higher than the natural background values of snow samples there.Calculation of the Pb enrichment factor of aerosol indicates that the ocean-and continent-source lead account for 9.23% and 0.01%,respectively,but industrially released Pb accounts for more than 90% of the atmospheric Pb.The Pb isotopic composition of aerosol has revealed that the sources of lead from industrial lead that causes pollution include mainly the western part of North America,East Europe and the former Soviet union.The calculation of the total fallout flux of Pb indicates that the mean value of input flux into the Chukchi Sea is 0.02mgm^-2a^-1,equivalent to that of southern Pacific but slightly lower than that of northern Indian Sea and southern Atlantic.It is evidenced that the Pb input flux into the Chukchi Sea is far lower than that off the Baltic Sea,the North Sea and the Mediterranean Sea.     

辽北地区钾长石矿地质特征及开发应用方向

以铁岭县湾龙背地区的钾长石矿为例,研究了辽北地区伟晶岩型钾长石矿的分异相带特点及空间分布规律。指出具新太古代壳源岩浆成因的钾长石分异相带明显,可分为内中外三个相带,其中内部相带的块体状钾长石、中间相带的团块状具文象结构的钾长石质量好,并在对国内的钾长石的市场潜力分析的基础上,指明了辽北地区钾长石矿的开发利用方向。     

Alkali ion migration in albite and K-feldspar

As part of a study of ion migration mechanisms in feldspars, the dynamical behaviour of the alkali metal cations ions in albite and K-feldspar has been investigated using a combination of dielectric spectroscopy and atomistic computer simulation techniques. The low-frequency dielectric properties of these minerals have been studied from room temperature to 1100 K. At each temperature, the dielectric constant, conductivity and dielectric loss were determined over a range of frequencies from 100 Hz to 10 MHz. At high temperatures a distinct Debye-type relaxation in the dielectric loss spectra was observed for both albite and K-feldspar; the activation energy for these processes was determined to be 1.33 eV in both albite and K–feldspar. Atomistic simulation techniques were used to elucidate the mechanism and energetics of the cation migration processes. Mechanisms involving the conventional hopping of Na⁺ and K⁺ ions between cation sites in the (010) plane were found to give calculated energy barriers in good agreement with the experimentally determined activation energies. These results assist in understanding the nature of the processes responsible for the observed dielectric behaviour.     

宜昌第四纪砾石层钾长石主、微量元素物源研究及其地质意义

位于长江三峡出口的宜昌地区分布着一套第四纪砂砾石层,详细记录了区域内古环境变迁以及长江的形成与演化,但这些砾石层何时与长江上游物质建立物源关系一直存在较大争议。而钾长石是河流沉积物中常见的矿物,其地球化学元素组成在不同区域内存在显著差异,是进行河流物源对比研究的理想矿物。基于此,利用激光剥蚀电感耦合等离子质谱仪（LA-ICP-MS）对宜昌第四纪砾石层和宜昌以上长江流域开展碎屑钾长石原位主微量元素和主成分（PCA）分析,结合砾石层已发表的地层沉积年龄,综合区域内已发表的研究结果,系统对比分析宜昌砾石层与长江上游物质建立物源联系的时间,结果表明在1.15 Ma时宜昌砾石层和长江流域存在物源关系;在0.75 Ma时随着长江上游水系的拓展与调整,有新物源区的物质进入长江。这些物源变化现象,主要体现了1.2~0.7 Ma期间长江流域受东亚和南亚夏季风的气候影响出现的沉积过程。      

华南东部中生代岩浆作用的动力学背景及其与铀成矿关系

中国东南大陆在中生代岩浆作用十分强烈 ,形成了大批稀有和有色金属矿床。发生在早中生代 (T)的印支运动和晚中生代 (J K)的燕山运动是发动该区岩浆作用和成矿作用的动力条件。印支运动在区域挤压框架下导致华南大陆发生板内伸展作用 ,形成印支期花岗岩。燕山运动是相对于印支运动的后造山地质事件 ,以岩石圈发生强烈裂解为特征 ,诱发了大规模岩浆活动 ,并形成了丰富的矿产资源。受燕山期构造 岩浆热事件叠加的印支期花岗岩与铀成矿关系密切 ,可能是铀源体。因此 ,在华南的铀矿找矿工作应加强对印支期花岗岩分布格局和成矿因素的研究     

~(40)Ar-~(39)Ar Age of K-feldspar from K-feldspar Granite in the Qiaohuote Copper Deposit, Bayanbulak, Xinjiang, and Its Geological Significance

By using the 40Ar-39Ar chronological method to date K-feldspar from K-feldspar granite in the Qiaohuote copper district, the authors obtained a plateau age of 274.78±0.44 Ma and an isochron age of 272.7±3.0 Ma. Because there is no tectonic deformation overprinted or hydrothermal alteration in the K-feldspar granite intrusion after its emplacement, the 40Ar-39Ar age represents the crystallization age of K-feldspar in K-feldspar granite, i.e. the late crystallization age of the K-feldspar granite intrusion, which indicates that the K-feldspar granite formed in the intraplate extensional stage during the Early Permian. Moreover, based on the spatial relationship between the K-feldspar granite intrusion and copper orebodies, variations of copper ore grade, REE characteristics of K-feldspar granite and copper ores, and H and O isotopic compositions of fluid inclusions in copper ores, the metallogenesis of the Qiaohuote copper deposit is directly related to intrusive activities of the K-feldspar granite, and     

黑龙江金厂金矿钾长石的结构状态与温度及其成矿意义

钾长石有序度及结构温度可以为探明矿床形成的物化条件、成矿历史等问题提供重要的依据.为阐明本区钾长石及其与矿化的关系,本文分别采用红外光谱和X射线粉晶衍射两种方法对金厂金矿18#矿体的钾长石进行了有序度等相关参数的测定,X粉晶衍射测得有序度及三斜度为:0.42～0.64,0.00～0.125;红外光谱测得有序度:0.60～1.40;结构参数为0.143～0.991;最终结构温度为370～450℃.结果发现,X射线单斜有序度Sm与红外光谱有序度θ反映出的钾长石有序度的变化规律是一致的,且有序度随着蚀变程度增强而增大;本区钾长石为热液蚀变的产物,其形成过程与金矿的沉淀富集有密切关系,可作为矿床的有利找矿标志.     

河南嵩县庙岭金矿地质特征与钾长石40Ar/39Ar定年

河南嵩县庙岭金矿位于华北陆块南缘熊耳山—外方山地区。矿床赋存于中元古界熊耳群火山岩中近南北向断裂带内,矿体呈似层状、透镜状产出,矿石具浸染状、细网脉状构造和微细粒它形粒状晶粒结构、交代结构,围岩热液蚀变有硅化、钾长石化、绢云母化、黄铁矿化等,矿化具有多阶段的特点,属破碎带蚀变岩型金矿。成矿热液蚀变矿物钾长石Ar-Ar法测年的结果：坪年龄为121.6Ma±1.2Ma,等时线年龄为117.0Ma±1.6Ma,表明矿床形成于早白垩世,与熊耳山地区祁雨沟、瑶沟等金矿床形成于同一时期,属与早白垩世构造-岩浆-流体活动有关的产物。     

内蒙古乌拉山石英-钾长石脉金矿床铅和硫同位素研究

内蒙古乌拉山金矿床是近年在我国北方发现的大型金矿之一。矿床主要由赋存在太古界乌拉山群变质地层中一系列石英－钾长石脉和石英脉组成，矿区范围内晚古生代一中生代花岗岩类分布广泛并且同金矿化具密切时，空分布关系。本文对乌拉山金矿床。大桦背花岗岩体和变质岩地层的硫，铅同位素比值进行了系统测定，并解释了不同地质体硫，铅同位素变化特征。研究表明：金成矿作用生发在２４０×１０＾６ａ，成矿物质主要来自大桦背华岗岩体     

河南嵩县庙岭金矿地质特征与钾长石40Ar/39Ar定年

河南嵩县庙岭金矿位于华北陆块南缘熊耳山—外方山地区。矿床赋存于中元古界熊耳群火山岩中近南北向断裂带内,矿体呈似层状、透镜状产出,矿石具浸染状、细网脉状构造和微细粒它形粒状晶粒结构、交代结构,围岩热液蚀变有硅化、钾长石化、绢云母化、黄铁矿化等,矿化具有多阶段的特点,属破碎带蚀变岩型金矿。成矿热液蚀变矿物钾长石Ar-Ar法测年的结果：坪年龄为121.6Ma±1.2Ma,等时线年龄为117.0Ma±1.6Ma,表明矿床形成于早白垩世,与熊耳山地区祁雨沟、瑶沟等金矿床形成于同一时期,属与早白垩世构造-岩浆-流体活动有关的产物。