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1.
The synthesis boundaries of the phase transformation; ++ in (Mg0.9, Fe0.1)SiO4, have been clarified at temperatures to 2000° C and pressures up to 20 GPa in order to synthesize single crystals of high quality. A single crystal of (Mg0.9, Fe0.1)2SiO4 was grown successfully to a size of 500 m. The crystal structure has been refined from single-crystal X-ray intensities. The ferrous ions prefer M1 and M3 sites to over the larger M2 site. The volume change of all the occupied polyhedra does not contribute to the decrease of total volume in the transformation; rather it tends to increase the bulk volume through the expansion of occupied tetrahedra. The volume reduction in the phase transformations is accounted for by unoccupied polyhedra, with the octahedra contributory 60% and the tetrahedra 40% to the V of the transition. The volume change in the transformation is caused also partly by the volume decrease of MO
6 (25%), partly the unoccupied tetrahedra (45%) and octahedra (30%). 相似文献
2.
Cristobalite, a high temperature phase of silica, SiO2, undergoes a (metastable) first-order phase transition from a cubic,
, to a tetragonal, P43212 (or P41212), structure at around 220° C. The cubic C9-type structure for -cristobalite (Wyckoff 1925) is improbable because of two stereochemically unfavorable features: a 180° Si-O-Si angle and an Si-O bond length of 1.54 Å, whereas the corresponding values in tetragonal -cristobalite are 146° and 1.609 Å respectively. The structure of the -phase is still controversial. To resolve this problem, a symmetry analysis of the
(or P41212) transition in cristobalite has been carried out based on the Landau formalism and projection operator methods. The starting point is the ideal cubic (
) C9-type structure with the unit cell dimension a (7.432 Å) slightly larger than the known a dimension (7.195 Å at 205° C) of -cristobalite, such that the Si-O-Si angle is still 180°, but the Si-O bond length is 1.609 Å. The six-component order parameter driving the phase transition transforms according to the X4 representation. The transition mechanism essentially involves a simultaneous translation and rotation of the silicate tetrahedra coupled along 110. A Landau free-energy expression is given as well as a listing of the three types of domains expected in -cristobalite from the transition. These domains are: (i) transformation twins from a loss of 3-fold axes, (ii) enantiomorphous twins from a loss of the inversion center, and (iii) antiphase domains from a loss of translation vectors 1/2 110 (FP). These domains are macroscopic and static in -cristobalite, and microscopic and dynamic in -cristobalite. The order parameter , couples with the strain components as 2, which initiates the structural fluctuations, thereby causing the domain configurations to dynamically interchange in the -phase. Hence, the - cristobalite transition is a fluctuation-induced first-order transition and the -phase is a dynamic average of -type domains. 相似文献
3.
William F. Bleam Philip E. Pfeffer James S. Frye 《Physics and Chemistry of Minerals》1989,16(5):455-464
This study examines the links between 31P solidstate NMR studies of aluminum phosphate minerals and their crystallographic structures. We found that 31P isotropic chemical shift values, iso, carry little information about mineral structures. There seems to be no relation between the chemical shift anisotropy, =33–11 (33>22> 11), and indicies of phosphate-tetrahedra distortion. 31P1H heteronuclear magnetic dipole interactions, on the other hand, carry important information about hydrous phosphate mineral structures, information that should prove to be quite valuable in studies of phosphate adsorbed on mineral surfaces. This interaction can be measured through a variety of qualitative and quantitative experiments. It appears that spin diffusion is so rapid that subtle differences in hydrogen-bonding environments cannot be resolved. 相似文献
4.
Birgit Lange Fritz Scholz Hans-Joachim Bautsch Ferdinand Damaschun Gert Wappler 《Physics and Chemistry of Minerals》1993,19(7):486-491
The electrochemical reduction of xanthoconite, proustite, pyrostilpnite, and pyrargyrite was studied by abrasive stripping voltammetry, a technique which is based upon a preliminary mechanical transfer of trace amounts of the mineral onto the surface of a paraffin impregnated graphite electrode. Because the electrochemical reduction proceeds near to reversibility and is very similar for each pair of minerals, the peak potentials in differential pulse voltammetry can be used to calculate the standard enthalpy of phase transformation of xanthoconite to proustite and of pyrostilpnite to pyrargyrite: T
H
(xanth proust)
O = 35.46 ± 14.15 kJ/mol and T
H
(pyrostilp pyrarg)
O = 38.85 ± 6.60 kJ/mol. These values are not accessible otherwise until now. 相似文献
5.
Y. Moëlo G. Roger D. Maurel-Palacin E. Marcoux A. Laroussi 《Mineralogy and Petrology》1995,53(4):229-250
Electron microprobe analysis of Pb-Cu(Fe)-Sb-Bi sulfosalts from Bazoges and Les Chalanches (France), and Pedra Luz (Portugal), give new data about (Bi, Sb) solid-solution and incorporation of the minor elements Cu, Fe or Ag in jaskolskiite, and in izoklakeite-giessenite and kobellite-tintinaite series. Jaskolskiite from Pedra Luz has high Sb contents (from 17.9 to 20.7 wt.%), leading to the extended general formula: Cu
x
Pb2+x
(Sb1–y
Bi
y
)2–x
S5, with 0.10 x 0.22 and 0.19 y 0.41. Fe-free, Bi-rich izoklakeite from Bazoges has high Ag contents (up to 2.2 wt. %), leading to the simplified formula Cu2Pb22Ag2(Bi, Sb)22S57; in Les Chalanches it contains less Ag content (1.2 wt.%), but has an excess of Cu that gives the formula: Cu2.00 (Cu0.49Ag1.18)=1.67Pb22.70(Bi12.63Sb8.99)=21.62S57.27.In tintinaite from Pedra Luz, the variation of the Fe/Cu ratio can be explained by the substitution: Cu + (Bi, Sb) Fe + Pb; Fe-free kobellite from Les Chalanches has a Cu-excess, corresponding to the formula Cu2.81Ag0.54Pb9.88(Bi10.37Sb5.21)=15.38S35.09. Eclarite from the type locality, structurally related to kobellite, shows a Cu excess too. In natural samples of the kobellite homologous series, Fe is positively correlated with Pb, and its contents never exceed that of Cu. Ag substitutes for Pb, together with (Bi, Sb). Taking into account the possibility of Cu excess, but excluding formal Cu2+ and Fe3+, general formulae can be written: 相似文献
6.
Data on the mechanisms of mantle phase transformations have come primarily from studies of analogue systems reacted experimentally at low pressures. In order to study transformation mechanisms in Mg2SiO4 at mantle pressures, forsterite () has been reacted in the stability field of -phase, at 15 GPa and temperatures up to 900° C, using a multianvil split-sphere apparatus. Transmission electron microscope studies of samples reacted for times ranging from 0.25–5.0 h show that forsterite transforms to -phase by an incoherent nucleation and growth mechanism involving nucleation on olivine grain boundaries. This mechanism and the resultant microstructures are very similar to those observed at much lower pressures in analogue systems (Mg2GeO4 and Ni2SiO4) as the result of the olivine to spinel () transformation. Metastable spinel () also forms from Mg2SiO4 olivine at 15 GPa, in addition to -phase, by the incoherent nucleation and growth mechanism. With time, the spinel progressively transforms to the stable -phase. After 1 h, spinels exhibit a highly striated microstructure along {110} and electron diffraction patterns show streaking parallel to [110] which indicates a high degree of structural disorder. High resolution imaging shows that the streaking results from thin lamellae of -phase intergrown with the spinel. The two phases have the orientation relationship [001]//[001] and [010]//[110] so that the quasi cubic-close-packed oxygen sublattices are continuous between both phases. These microstructures are similar to those observed in shocked meteorites and show that spinel transforms to -phase by a martensitic (shear) mechanism. There is also evidence that the mechanism changes to one involving diffusion-controlled growth at conditions close to equilibrium. 相似文献
7.
R. Klemd A. M. van den Kerkhof E. E. Horn 《Contributions to Mineralogy and Petrology》1992,111(3):409-419
The eclogite-facies metasedimentary rocks in the Münchberg gneiss complex (T=630±30° C/P17–24 kbar) locally contain CO2–N2-rich fluid inclusions of extremely low molar volumes (32 cm3/mol) in quartz. These fluid compositions are mainly found in rocks intercalated with calcsilicate bands. Densities were determined from low-temperature phase transitions like stable or metastable homogenization (L+VL), partial homogenization (S+L+VS+L) and the transition S+LL (L = liquid, V = vapour, S = solid). The high fluid densities are in agreement with eclogite-facies pressure and temperature and subsequent amphibolite facies. CO2–N2 inclusions were not observed in adjacent eclogites nor in non-calcareous metasediments. These rock types contain predominantly H2O-rich inclusions correlating with amphibolite-facies conditions. The variation of fluid composition with lithological differences indicates local fluid gradients and speaks against a pervasive fluid flow during eclogite-facies metamorphism. 相似文献
8.
A. Chopelas 《Physics and Chemistry of Minerals》1990,17(2):142-148
The pressure dependence of the Raman spectrum of forsterite was measured over its entire frequency range to over 200 kbar. The shifts of the Raman modes were used to calculate the pressure dependence of the heat capacity, C
v, and entropy, S, by using statistical thermodynamics of the lattice vibrations. Using the pressure dependence of C
v and other previously measured thermodynamic parameters, the thermal expansion coefficient, , at room temperature was calculated from = K
S
(T/P)
S
C
V/TVK
T, which yields a constant value of ( ln / ln V)T= 6.1(5) for forsterite to 10% compression. This value is in agreement with ( ln / ln V)T for a large variety of materials.At 91 kbar, the compression mechanism of the forsterite lattice abruptly changes causing a strong decrease of the pressure derivative of 6 Raman modes accompanied by large reductions in the intensities of all of the modes. This observation is in agreement with single crystal x-ray diffraction studies to 150 kbar and is interpreted as a second order phase transition. 相似文献
9.
Gordillo C. E. Schreyer W. Werding G. Abraham K. 《Contributions to Mineralogy and Petrology》1985,90(1):93-100
NaBe-cordierites (Fe/(Fe+Mn+Mg)=0.49–0.57) with BeO contents up to 1.16 weight % and additional Li2O contents up to 0.21 wt.% occur in cordierite-apatite-uraninite-muscovite-biotite-chlorite-feldspar-quartz nodules within pegmatites penetrating gneissic roof pendants of a lower Palaeozoic granite batholith. Occasional small crystals of beryl are interpreted to coexist stably with unaltered cordierite. Be and Li are incorporated in cordieriteaccording to the substitutions Na[Channel] + Be[4] Al[4] and Na[Ch]+Li[6]R2+[6], respectively. The coexisting phyllosilicates do apparently not contain appreciable amounts of Li. According to powder IR-data, the analyzed water contents of the cordierites are dominantly of type II, and there is also little CO2. Their distortion indices are rather low (0.121–0.145) and so are their optic angles (2V=50-51°). Considering all eleven NaBeLi-cordierites known thus far there is a strong positive correlation between Na and (Be+Li) with a slope close to 1.0. However, there is virtually no correlation between Be and Li, their incorporation into cordierite depending on the local geochemical environment. A strong negative correlation exists between the distortion indices of the NaBeLi-cordierites and their Be contents. Li has a disturbing influence on this relationship, and the versus Na correlation is also statistically worse than versus Be.Deceased December 20, 1984 相似文献
10.
Chiaki Uyeda Akira Tsuchiyama Takamitu Yamanaka Muneyuki Date 《Physics and Chemistry of Minerals》1993,20(2):82-85
The harmonic oscillations of large diamagnetic mineral samples induced by a magnetic field is reported, for single crystals of quartz, corundum, and calcite. It was seen for the first time that the period of oscillation, , was proportional to the reciprocal of the magnetic field, H, where the restoring force of the string suspending the crystal became negligible in the high magnetic field. Accordingly, the value of diamagnetic anisotropy, , could be measured from the — H curve with a sensitivity of 5 × 10–10 emu/cc. The values were 5.50 × 10–9 emu/cc for quartz, 4.20 × 10–9 emu/cc for corundum, 9.9 × 10–8 emu/cc for calcite, and 8.8 × 10–8 emu/cc for polycrystalline talc piled with the (001) planes aligned parallel. Significant field-induced rotations were observed for the suspended crystals. When the field was applied along the direction of the diamagnetic hard axis of the stationary crystal, the crystal gradually rotated with increasing field, so that the direction of the hard-axis was perpendicular to the applied field. The field-induced energy has a the maximum value when the field is applied along the diamagnetic hard axis. This reorientation of the crystal occurs because the torque due to the field-induced anisotropic energy exceeds that of the restoring force in high magnetic fields. 相似文献
11.
Dane R. Spearing Ian Farnan Jonathan F. Stebbins 《Physics and Chemistry of Minerals》1992,19(5):307-321
Relaxation times (T1) and lineshapes were examined as a function of temperature through the - transition for 29Si in a single crystal of amethyst, and for 29Si and 17O in cristobalite powders. For single crystal quartz, the three 29Si peaks observed at room temperature, representing each of the three differently oriented SiO4 tetrahedra in the unit cell, coalesce with increasing temperature such that at the - transition only one peak is observed. 29Si T1's decrease with increasing temperature up to the transition, above which they remain constant. Although these results are not uniquely interpretable, hopping between the Dauphiné twin related configurations, 1 and 2, may be the fluctuations responsible for both effects. This exchange becomes observable up to 150° C below the transition, and persists above the transition, resulting in -quartz being a time and space average of 1 and 2. 29Si T1's for isotopically enriched powdered cristobalite show much the same behavior as observed for quartz. In addition, 17O T1's decrease slowly up to the - transition at which point there is an abrupt 1.5 order of magnitude drop. Fitting of static powder 17O spectra for cristobalite gives an asymmetry parameter () of 0.125 at room T, which decreases to <0.040 at=" the=" transition=" temperature.=" the=" electric=" field=" gradient=" (efg)=" and=" chemical=" shift=" anisotropy=" (csa),=" however,=" remain=" the=" same,=" suggesting=" that=" the=" decrease=" in=">0.040> is caused by a dynamical rotation of the tetrahedra below the transition. Thus, the mechanisms of the - phase transitions in quartz and cristobalite are similar: there appears to be some fluctuation of the tetrahedra between twin-related orientations below the transition temperature, and the -phase is characterized by a dynamical average of the twin domains on a unit cell scale. 相似文献
12.
Summary Baotite occurs in the Garaoulére orebody, at Pierreftte, France, as an accessory mineral, included in alstonite and celsian, and associated with sphalerite, galena, pyrite, siderite and calcite in hydrothermal veins crosscutting calcareous, rutile-bearing, siltstones. Microprobe analyses revealed high W03 concentrations (up to 6 wt.%) in baotite. The empirical formula of W-rich baotite is Ba3.959Ti4(Ti3.169W0.393Fe0.116Al0.073 Cr0.048Nb0.024)3.823 Si4.05O28Cl1.166. The excess of charges due to the presence of W6+ and Nb5+ is compensated by the introduction of M3+ (Fe, Al, Cr) into Ti-octahedra, by the appearance of Al in Si-tetrahedra (for W-poor baotite) and by the appearance of vacancies in Ti-octahedra (3Ti4 -> 2W6+ + and in Ba-sites (Ti4+ Ba2+ W6+, ). The unit-cell parameters of W-rich baotite are: a = 19.92(2), c = 5.930(8) Å. Niobium-rich baotites (Baiyun-Obo,Semenov et al., 1961; Karlstein,Nmec, 1987) are characterized by substitutions: Ti4+(VI), Si4+(IV)Nb5+(VI), Al3+(IV) and 2Ti4+, Ba2+ 2Nb5+, .
Wolfram führender Baotit von Pierrefitte, Pyrenäen, Frankreich
Zusammenfassung Baotit kommt in dem Garaoulére Erzkórper in Pierrefitte, Frankreich als ein akzessorisches Mineral in Einschlÿussen in Alstonit und Celsian vor. Er ist mit Zinkblende, Bleiglanz, Pyrit, Siderit und Calcit assoziiert. Diese Paragenese ist an hydrothermale Gänge gebunden, die kalkige rutil-führende Siltsteine durchsetzen. Mikrosondenanalysen zeigen hohe W03 Gehalte (bis zu 6 Gew.%) in Baotit. Die empirische Formel von wolfram-reichem Baotit ist: Ba3.959Ti4(Ti3.169W0.393Fe0.116Al0.073Cr0.048Nb0.024)3.823 Si4.05O28Cl1.66. Der durch die Anwesenheit von W6+ und Nb5+ erforderliche Ladungsausgleich ergibt sich durch das Eintreten von M3+ (Fe, Al; Cr) in Ti-Oktaeder, und von Al in Si-Tetraeder (für W-armen Baotit) und schließlich durch das Erscheinen von Leerstellen in Ti-Oktaedern (3Ti4+ 2W6+ + und in Ba-Stellen (Ti4+, Ba` W6+, Die Zellparameter von ldW-reichem Baotit sind: a = 19.92(2), c = 5.930(8) Å. Niob-reiche Baotite (Baiyun-Obo, Semenov et al., 1961; Karlstein, Nmec, 1987) sind durch Substitutionen charakterisiert: Ti4+(VI), Si4+(IV)Nb5+(VI), Al3+(IV) und 2Ti4+, Ba2+ 2Nb5+, .相似文献
13.
Thirteen energy-dispersive x-ray diffraction spectra for -Fe2SiO4 (spinel) collected in situ at 400° C and pressures to 24 GPa constitute the basis for an elevated-temperature static compression isotherm for this important high-pressure phase. A Murnaghan regression of these molar volume measurements yields 177.3 (±17.4) GPa and 5.4(±2.5) for the 400° C, room pressure values of the isothermal bulk modulus (K
P
0) and its first pressure derivative (K
P
0), respectively. When compared to the room-Tdeterminations of K
P
0 available in the literature, our 400° C K
P
0 yields -4.1 (±6.2)×10-2 GPa/degree for the average value of (K/T)
P
0 over the temperature interval 25° C<><400°>400°>A five-parameter V(P, T) equation for -Fe2SiO4 based on simultaneous regression of our data combined with the elevated P-Tdata of Yagi et al. (1987) and the extrapolated thermal expansion values from Suzuki et al. (1979) yields isochores which have very little curvature [(2
T/P
2)
v
0], in marked contrast to the isochores for fayalite (Plymate and Stout 1990) which exhibit pronounced negative curvature [(T/P
2)
v
<0]. along=" the=">0].>-Fe2SiO4 reaction boundary VRvaries from a minimum of approximately 8.3% at approximately 450° C to approximately 8.9% at 1200° C. Extrapolation of the fayalite and -Fe2SiO4
V(P, T) relationships to the temperature and pressure of the 400 km discontinuity suggests a V
R
of approximately 8.4% at that depth, approximately 10% less than the 9.3% V
R
at ambient conditions. 相似文献
14.
Structural relaxation in silicate melts and non-Newtonian melt rheology in geologic processes 总被引:4,自引:0,他引:4
The timescale of structural relaxation in a silicate melt defines the transition from liquid (relaxed) to glassy (unrelaxed) behavior. Structural relaxation in silicate melts can be described by a relaxation time, , consistent with the observation that the timescales of both volume and shear relaxation are of the same order of magnitude. The onset of significantly unrelaxed behavior occurs 2 log10 units of time above . In the case of shear relaxation, the relaxation time can be quantified using the Maxwell relationship for a viscoelastic material; S = S/G
(where S is the shear relaxation time, G
is the shear modulus at infinite frequency and S is the zero frequency shear viscosity). The value of G
known for SiO2 and several other silicate glasses. The shear modulus, G
, and the bulk modulus, K
, are similar in magnitude for every glass, with both moduli being relatively insensitive to changes in temperature and composition. In contrast, the shear viscosity of silicate melts ranges over at least ten orders of magnitude, with composition at fixed temperature, and with temperature at fixed composition. Therefore, relative to S, G
may be considered a constant (independent of composition and temperature) and the value of S, the relaxation time, may be estimated directly for the large number of silicate melts for which the shear viscosity is known.For silicate melts, the relaxation times calculated from the Maxwell relationship agree well with available data for the onset of the frequency-dependence (dispersion) of acoustic velocities, the onset of non-Newtonian viscosities, the scan-rate dependence of the calorimetric glass transition, with the timescale of an oxygen diffusive jump and with the Si-O bond exchange frequency obtained from 29Si NMR studies. 相似文献
15.
Oxygen isotope geochemistry of hydrothermally-altered synmetamorphic granitic rocks from South-Central Maine,USA 总被引:1,自引:0,他引:1
Douglas Rumble III John M. Ferry Thomas C. Hoering 《Contributions to Mineralogy and Petrology》1986,93(4):420-428
Hydrothermally-altered mesozonal synmetamorphic granitic rocks from Maine have whole-rock
18O (SMOW) values 10.7 to 13.8. Constituent quartz, feldspar, and muscovite have
18O in the range 12.4 to 15.2, 10.0 to 13.2, and 11.1 to 12.0, respectively. Mean values of
Q–F (
18Oquartz–
18Ofeldspar)=2.4 and
Q–M (
18Oquartz–
18Omuscovite)=3.3 are remarkably uniform (standard deviations of both are 0.2). Measured
Q–F and
Q–M values demonstrate that the isotopic compositions of the minerals are altered from primary magmatic
18O values but that the minerals closely approached oxygen isotope exchange equilibrium at subsolidus temperatures. Analyzed muscovites have D (SMOW) values in the range –65 to –82.Feldspars in the granitic rocks are mineralogically altered to either (a) muscovite+calcite, (b) muscovite+calcite+epidote, (c) muscovite+epidote, or (d) muscovite only. A consistent relation exists between the assemblage of secondary minerals and the oxygen isotope composition of whole rocks, quartz, and feldspar. Rocks with assemblage (a) have whole-rock
18O>12.1 and contain quartz and feldspar with
18O>13.8 and >11.4, respectively. Rocks with assemblages (b), (c), and (d) have whole-rock
18O<11.4 and contain quartz and feldspar with
18O< 13.1 and <11.0, respectively. The correlation suggests that the mineralogical alteration of the rocks was closely coupled to their isotopic alteration.Three mineral thermometers in altered granite suggest that the hydrothermal event occurred in the temperature range 400°–150° C, 100°–150° C below the peak metamorphic temperature inferred for country rocks immediately adjacent to the plutons. Calculations of mineral-fluid equilibria indicate that samples with assemblage (a) coexisted during the event with CO2-H2O fluids of
and
18O=10.8 to 12.2 while samples with assemblages (b), (c), or (d) coexisted with fluids of
and
18O=9.4 to 10.1. Compositional variations of the hydrothermal fluids were highly correlated: fluids enriched in CO2 were also enriched in 18O. Because CO2 was added to the granites during hydrothermal alteration and because fluids enriched in CO2 were enriched in
18O, some or all of the variation in
18O of altered granites may have been caused by addition of 18O to the rocks during the hydrothermal event. The source of both the CO2 and 18O could have been high-18O metasedimentary country rocks. The inferred change in isotopic composition of the granites is consistent with depletion of the metacarbonate rocks in 18O close to the plutons and with large volumes of fluid that were inferred from petrologic data to have infiltrated the metacarbonate rocks during metamorphism.A close approach of minerals to oxygen isotope exchange equilibrium in altered mesozonal rocks from Maine is in marked contrast to hydrothermally-altered epizonal granites whose mineral commonly show large departures from oxygen isotope exchange equilibrium. The difference in oxygen isotope systematics between altered epizonal granites and altered mesozonal granites closely parallels a differences between their mineralogical systematics. Both differences demonstrate the important control that depth exerts on the products of hydrothermal alteration. Deeper hydrothermal events occur at higher temperature and are longer-lived. Minerals and fluid have sufficient time to closely approach both isotope exchange and heterogeneous chemical equilibrium. Shallower hydrothermal events occur at lower temperatures and are shorter-lived. Generally there is insufficient time for fluid to closely approach equilibrium with all minerals. 相似文献
16.
Electron paramagnetic resonance (EPR) spectra of CO
3
3–
molecule-ions stabilized by Sc3+ in natural calcite were identified and studied at X-band frequencies and room temperature. The principal values of the g-tensor (g
xx= 1.9997, g
yy = 2.0030, g
zz = 1.9972) and the direction cosines of the g and A tensors for CO
3
3–
-Sc3+ center were found to be close to that for the well-known CO
3
3–
-Y3+ center. A quantitative comparison of different impurity contents in calcite samples and analysis of the intensities of forbidden transitions were used to identify Sc3+. An estimation of the unpaired electron spin density on the nuclei of paramagnetic centers confirms that both centers, CO
3
3–
-Sc3+ and CO
3
3–
-Y3+, have the same nature. 相似文献
17.
Titania, TiO2, precipitation in natural blue sapphire (Fe, Ti: -Al2O3) has been investigated using high resolution and analytical transmission electron microscopy. The structure and habit of the TiO2 precipitate depends on both the Ti4+ concentration and the temperature at which the precipitate formed. Tetragonal TiO2 (Rutile) grows at 1350° C but at 1150° C an orthorhombic non-equilibrium TiO2 polymorph precipitates. Both TiO2 polymorphs nucleate in the (0001)s plane as lens shaped discs twinned along their diameter. The crystallographic alignment of each type of TiO2 precipitate with respect to the -Al2O3 host matrix provides a high degree of structural coherency with minimal lattice mismatch. Electron diffraction analysis established the following precipitate/host orientation relationships: tetragonal TiO2: {011}r {11
07B;100}r(0001)s and 01
r10
0s twinned along the (011)r planeand orthorhombic TiO2: {021}{11
0}s, {100}(0001)s and 0
2 10
0s twinned along the (021) plane. 相似文献
18.
The behavior of supersonic mixing layers under three conditions has been examined by schlieren photography and laser Doppler velocimetry. In the schlieren photographs, some largescale, repetitive patterns were observed within the mixing layer; however, these structures do not appear to dominate the mixing layer character under the present flow conditions. It was found that higher levels of secondary freestream turbulence did not increase the peak turbulence intensity observed within the mixing layer, but slightly increased the growth rate. Higher levels of freestream turbulence also reduced the axial distance required for development of the mean velocity. At higher convective Mach numbers, the mixing layer growth rate was found to be smaller than that of an incompressible mixing layer at the same velocity and freestream density ratio. The increase in convective Mach number also caused a decrease in the turbulence intensity (
u
/U).List of Symbols
a
speed of sound
-
b
total mixing layer thickness betweenU
1 – 0.1U andU
2 + 0.1U
-
f
normalized third moment ofu-velocity,f u
3/(U)3
-
g
normalized triple product ofu
2
v,g u
2
v/(U)3
-
h
normalized triple product ofu v
2, h uv'
2/(U)3
-
l
u
axial distance for similarity in the mean velocity
-
l
u
axial distance for similarity in the turbulence intensity
-
M
Mach number
-
M
c
convective Mach number (for 1=2),M
c
(U
1–U
2)/(a
1+a
2)
-
P
static pressure
-
r
freestream velocity ratio,rU
2/U
1
-
Re
unit Reynolds number,Re U/
-
s
freestream density ratio,s
2/
1
-
T
t
total temperature
-
u
instantaneous streamwise velocity
-
u
deviation ofu-velocity,u u–U
-
U
local mean streamwise velocity
-
U
1
primary freestream velocity
-
U
2
secondary freestream velocity
-
U
average of freestream velocities, ¯U (U
1 +U
2)/2
-
U
freestream velocity difference,U U
1 –U
2
-
v
instantaneous transverse velocity
-
v
deviation ofv-velocity,v v – V
-
V
local mean transverse velocity
-
x
streamwise coordinate
-
y
transverse coordinate
-
y
0
transverse location of the mixing layer centerline
-
ensemble average
-
ratio of specific heats
-
boundary layer thickness (y-location at 99.5% of free-stream velocity)
-
similarity coordinate, (y –y
0)/b
-
compressible boundary layer momentum thickness
-
viscosity
-
density
-
standard deviation
-
dimensionless velocity, (U –U
2)/U
- 1
primary stream
- 2
secondary stream
A version of this paper was presented at the 11th Symposium on Turbulence, October 17–19, 1988, University of Missouri-Rolla 相似文献
19.
Michael Raith 《Contributions to Mineralogy and Petrology》1976,57(1):99-117
The compositional variations in epidotes, Ca2Al2(Fe3+, Al)-Si3O12(OH), from a prograde Mesozoic rock series in the Eastern Alps, Austria, are systematically related to metamorphic grade and the oxidation state of the rock. With increasing metamorphic grade the average composition of the zoned epidotes shifts to Fe3+-poorer compositions reflecting not only the effect of temperature and total pressure but also the concomitant decrease of the oxidation state of the rocks. Oxidized hematite-bearing assemblages are: 90 mole % Al2FeEp (greenschists) 70 mole % Al2FeEp (garnet amphibolites) 58 mole % Al2FeEp (eclogites); reduced sulfidebearing assemblages are: 42 mole % Al2FeEp (greenschists) 24 mole % Al2FeEp (garnet amphibolites) 23 mole % Al2FeEp (eclogites).A similar compositional evolution of the epidotes as in the spatial sequence of the samples can be observed within the single zoned crystals, reflecting the temporal changes of temperature, total pressure and oxygen fugacity during the prograde crystallization. The Fe3+-contents of core and rim decrease with increasing metamorphic grade and decreasing oxidation state. Generally the zoned epidotes consist of a Fe3+-rich core (90 to 63 mole % Al2FeEp) and a Fe3+-poorer rim (55 to 23 mole % Al2FeEp). Core and rim of the epidote crystals are separated by a compositional gap the extension of which is independent of the bulk rock composition, the oxidation state, and the mineralogical composition of the assemblages but becomes smaller with increasing metamorphic grade: 7253 mole % Al2FeEp (low grade greenschists, 400° C) 6355 mole % Al2FeEp (higher grade greenschists, 500° C), and 6055 mole % Al2FeEp (garnet amphibolites, 500–550° C). At the temperature conditions of the highest grade garnet amphibolites and eclogites (550° C) the compositional gap closes at a composition of 58 mole % Al2FeEp.The data presented thus confirm clearly the existence of an asymmetric miscibility gap in the monoclinic Al-Fe(III)-epidote solid solution series, which, for the first time, has been assumed by Strens (1964, 1965).A model is proposed that describes the prograde compositional evolution of the epidotes studied through the competing mechanisms of growth and diffusional Al-Fe3+ exchange and their dependence on metamorphic grade and oxidation state. 相似文献
20.
Chiaki Uyeda 《Physics and Chemistry of Minerals》1993,20(2):77-81
The diamagnetic anisotropy of oxide minerals is analyzed in terms of a new model, in which the anisotropy is assigned to the individual chemical bond in the [MO6] octahedral unit of the crystal. The diamagnetic principal axis of the individual M-O bond is assumed to be parallel to the direction of the bond. The calculated anisotropy based on this model shows a good correlation with the measured diamagnetic anisotropy, , for various minerals such as talc, sericite, kaolinite of the sheetsilicate group, forsterite of the orthosilicate group, and corundum of the hematite group. The values of many diamagnetic minerals are still unknown since the measurement is difficult to perform by means of conventional methods. The magnetic grain orientation recently observed in the mineral suspensions is effective for estimating the value, when the single crystal of the mineral cannot be obtained. The observation of fieldinduced crystal oscillation in the high magnetic fields can be applied for measuring the minerals with small values of less than 5 × 10–10 emu/cc. The chemical bond model on the diamagnetic anisotropy can be confirmed, when the compiling of data on various mineral is made by means of the above two methods. 相似文献