单元两相气液包裹体热力学方程的推导和应用

Three thermodynamical equations, for unitary two-phase fluid inclusions have been deduced. (1) The thermodynamical equation for mutual transformation between gas and liquid phases in fluid inclusions. The transformation direction from one phase to the other can be known in terms of the density and filling degree of gas and liquid. (2) The thermodynamical equation for pressure effect on temperature after homogenization of fluid inclusions. The coefficient of P-T variation is directly proportional to the fining degree of gas phase and inversely to the density of gas phase and liquid phase. Equations for homogenization, decrepitation and formation temperatures of fluid inclusions can be inferred from. this equation. (3) The thermodynomical equation for decrepitation temperatures of fluid inclusions. Many factors have effects on the decrepitation temperatures of fluid inclusions.Decrepitation temperature cannot be considered in any case as formation temperature.Thermal and vapor halos produced by decrepitation of minerals of the same kind and the same period from the same locality are worthy of consideration.     

白云鄂博矿床碳酸岩墙/脉和赋矿白云岩中流体包裹体研究

Fluid inclusion study has been carried out for the carbonatite dykes/veins and the ore-hosted dolostone of the Bayan Obo superlarge REE-Fe-Nb deposit in order to provide the evidence and constraint for their origin.Based on the detailed geological observation and mineralogical investigation,the heating and cooling stage and laser Raman spectroscopy were mainly used for the laboratory work of this study.Following results have been obtained:(1)The discovery of melt and melt-fluid inclusions from carbonatite dykes/veins in the Dulahara and Jianshan Mountains,combined with the fine-grained(aplitic)texture of rocks,as well as the types and features of fluid inclusions such as CO_2 enrichment,higher homogenization temperature,provides a direct evidence for the magmatic origin of these dykes/veins.(2)The carbonatite dykes/veins distributed in two regions,nearby the axis of the Kuangou anticline and in the east to Bayan Obo town,mainly show coarse-grained texture.No melt inclusion was found,and the fluid inclusions possess features of less CO_2,lower homogenization temperature and higher salinity.They are tentatively identified as veins formed by some carbonate-rich hydrothermal solution.(3)Bedding carbonate layers/lens within the hanging wall and foot wall of ore-hosted dolostone,previously recognized as of magmatic origin,mainly composed by dolomite.The existence of single phase pure aqueous inclusions with very low homogenization temperature indicates their sedimentary origin.(4)The ore-hosted dolostone possesses apparent bedding and laminated structures.No melt inclusion was found,but,both single phase pure aqueous inclusions and CO_2 bearing multi-phase fluid inclusions coexisted in dolostones.In the direction towards ore-bodies,the homogenization temperature and CO_2 contents of fluid inclusion show an increasing tendency.It indicates the sedimentary origin of dolostone superimposed by late fluid metasomatism.     

Velocity and Structural Modeling of Mesozoic Chiltan Limestone and Goru Formation for Hydrocarbon Evaluation in the Bitrisim Area, Lower Indus Basin, Pakistan

The present study focuses on building a workflow for structural interpretation and velocity modeling and implementing to Jurassic-Cretaceous succession (Chiltan Limestone and Massive sand of the Lower Goru Formation). 2D-Migrated seismic sections of the area are used as data set and in order to confirm the presence of hydrocarbons in the study area, P and S-wave seismic velocities are estimated from single-component seismic data. Some specific issues in the use of seismic data for modeling and hydrocarbon evaluation need to deal with including distinguishing the reservoir and cap rocks, and the effects of faults, folds and presence of hydrocarbons on these rocks. This study has carried out the structural interpretation and modeling of the seismic data for the identification of traps. The results demonstrate existence of appropriate structural traps in the form of horst and grabens in the area. 2D and 3D velocity modeling of the horizons indicates the presence of high velocity zones in the eastern half of the study while relatively low velocity zones are encountered in the western half of the area. Two wells were drilled in the study area (i.e. Fateh-01 and Ichhri-01) and both are dry. Immature hydrocarbons migration is considered as a failure reason for Fateh-01 and Ichhri-01 well.     

Assessment of Geological Security and Integrated Assessment Geo‐environmental Suitability in Worst‐hit Areas in Wenchuan Quake

Abstract: The Wenchuan earthquake in 2008 and geo-hazards triggered by the earthquake caused large injuries and deaths as well as destructive damage for infrastructures like construction, traffic and electricity. It is urgent to select relatively secure areas for townships and cities constructed in high mountainous regions with high magnitude earthquakes. This paper presents the basic thoughts, evaluation indices and evaluation methods of geological security evaluation, water and land resources security demonstration and integrated assessments of geo-environmental suitability for reconstruction in alp and ravine with high magnitude earthquakes, which are applied in the worst-hit areas (12 counties). The integrated assessment shows that: (1) located in the Longmenshan fault zone, the evaluated area is of poor regional crust stability, in which the unstable and second unstable areas account for 79% of the total; (2) the geo-hazards susceptibility is high in the evaluation area. The spots of geo-hazards triggered by earthquake are mainly distributed along the active fault zone with higher distribution in the moderate and high mountains area, in which the areas of high and moderate susceptibility zoning accounts for 40.1% of the total; (3) geological security is poor in the evaluated area, in which the area of the unsuitable construction occupies 73.1%, whereas in the suitable construction area, the areas of geological security, second security and insecurity zoning account for 8.3%, 9.3% and 9.3% of the evaluated area respectively; (4) geo-environmental suitability is poor in the evaluated area , in which the areas of suitability and basic suitability zoning account for 3.5% and 7.3% of the whole evaluation area.     

The Gas Resources Assessment Expert System of the Songliao Basin

The gas resources assessment expert system is one of the advanced methods for appraising oil and gas resources. The establishment of a knowledge base is the focal task in developing the expert system. This paper presents a summary of the mechanism and the major controlling factors in the formation of gas pools in the southeast uplift of the Songliao basin. Then an appropriate assessment model is established for trapping the gas resources and a knowledge base built in the expert system to realize the model. By using the expert system to appraise the gas-bearing probability of 25 major traps of the Quantou and Denglouku Formations in the Shiwu-Dehui area, the authors have proved that the expert system is suitable for appraising traps in the Songliao basin and similar basins.     

Monomineral universal clinopyroxene and garnet barometers for peridotitic,eclogitic and basaltic systems

New versions of the universal Jd-Di exchange clinopyroxene barometer for peridotites,pyroxenites and eclogites,and also garnet barometer for eclogites and peridotites were developed.They were checked using large experimental data sets for eciogitic(~530) and peridotitic systems(650).The precision of the universal Cpx barometer for peridotites based on Jd-Di exchange is close to Cr-Tschermalite method produced by Nimis and Taylor(2000).Cpx barometer was transformed by the substitution of major multiplier for K_D by the equations dependent from Al-Na-Fe.Obtained equation in combination with the thermometer of Nimis and Taylor(2000) allow to reconstruct position of the magma feeder systems of the alkali basaltic magma within the mantle diapirs in modern platforms like in Vitim plateau and other Southern Siberia localities and several localities worldwide showing good agreement of pressure ranges for black and green suites.These equations allow construct PTX diagrams for the kimberlite localities in Siberia and worldwide calculating simultaneously the PT parameters for different groups of mantle rocks.They give very good results for the concentrates from kimberlite lamproites and placers with mantle minerals.They are useful for PT estimates for diamond inclusions.The positions of eclogite groups in mantle sections are similar to those determined with new Gar—Cpx barometer produced by C.Beyer et al.(2015).The Fe rich eclogites commonly trace the boundary between the lower upper parts of subcontinental lithospheric mantle(SCLM) at 3-4 CPa marking pyroxenite eclogites layer.Ca-rich eclogites and especially grospydires in SCLM beneath Precambrian kimberlites occurs near pyroxenite layer but in younger mantle sections they became common in the lower parts.The diamondiferous Mg Cr-less group eclogites referring to the ancient island arc complexes are also common in the middle part of mantle sections and near 5-6 GPa.Commonly eclogites in lower apart of mantle sections are remelted and trace the high temperature convective branch.The Mg-and Fe-rich pyroxenites also show the extending in pressure trends which suggest the anatexic melting under the influence of volatiles or under the interaction with plums.     

无机气相色谱仪在气液包裹体成分研究中的应用

CXL-101 inorganic gas chromatography is eharacterised by its high sensitivity,high speed, small quantity of sample required, less adsorption and reliability of result. It is especially suitable for the determination of H2O and CO2 in fluid inclusions. H2O and CO2 contents in fluid inclusions of 41 samples were measured by this instrument from a number of types of tungsten and quarts deposits, Regular variation has heen found in the content of H2O, i.e., it decreases with decreasing distance toward the parent rock, or with increasing temperature, and vice versa. This regularity may be ascribed to the origin of fluid, distance between parent rock and ore deposit, temperature of form.ation, changes in the way of fluid movement as well Hs the nature of country rocks.     

Application of Lead Isotopes to Geochemical Exploration of Gold Deposits in Baoban , Hainan Province, China

Lead isotopes have been widely applied in geochemical exploration and evaluation of ore deposits, as well as in ascertaining the age of mineralization and the source of ore fluids.Long-term practice showed that the method of lead isotope targeting is somewhat efficient for macroscopic evaluation of forecasting areas, but not powerful enough for for ecasting concealed orebodies. As the contents of U and the variation of U/Pb ratio sharply decrease with depth in the lithosphere, U-Th-Pb isotopic differentiation must have occurred during the crust-mantle e-volution. Lead isotopic ratios show a wide variation range, varying in the front of mineralizationand shallow-derived ores, but maintaining very stable in the major orebody and being usuallyclose to the average isotopic composition of the crust and mantle of the continent block fromwhich the ores were derived. Therefore, the lead isotopic composition can serve as a measure for identifying the position of mineralization. The lead isotope geochemistry was applied to the ex-ploration and evaluation of the Baoban gold deposits of Hainan Province, China. The an alyticalresults of ore veins and adjacent rocks showed that there is a correlation between the lead isotopedata and the position of orebody. Based on the experience from the Baoban gold deposits and other ore deposits in Yunnan Province, an exploration principle has been established, that is,positive anomalies of lead isotope eigenvectors for prospecting deep-seated orebodies and nega-tive anomalies of eigenvectors for enlarging lateral exploration surrounding the known deposit.The ore beds in the Erjia and Beiniu mining districts should be as signed to the deep part of the orebody and those in the Tuwaishan mining district should be the shallow part, so ore beds cor-responding to those in the Erjia and Beiniu mining districts may be found in the Tuwaishan min-ing district.     

On the Mechanism of Transformation fromPrimary Ores into Oxidized Ores in FinelyDisseminated Gold Deposits

This paper, taking the finely disseminated gold deposits in southwestern Guizhou and northwestern Guangxi as examples, discusses the difference between the occurrence of primary ores and that of oxidized ores, analyzes the occurrence mechanism in terms of crystallochemistry and geochemistry, and especially studies the chemical model for supergene leaching transformation of clay minerals in the two types of ores. This study proposes a new idea for dressing and smelting technology for primary gold ores.     

Rock—Forming and Ore—Forming Temperatures of Lianhuashan Tungsten Deposit,Guangdong Province

The Lianhuashan tungsten deposit occurs in the volcanic terrain in the coastal area of Southeast China,where rhyolite,quartz porphyry and granite consitute a complee magmatic series.The orebodies are located in the endo-and exo-contacts between the quartz porphyry and the metasandstone of the Xiaoping coal measues.Hongenization temperatures of melt inclusions in zircon and quartz are 1100℃and 1050℃ for rhyolite,1000℃ and 860℃for quartz porphyry,and 950-1000℃and 820℃ for granite,respectively,demonstrating that the rockforming temperatures dropped successively from the eruptive to the intrusive rocks and that the homogenization temperatures of melt inclusions in zircon are 50-180℃higher than those in quartz.Homogenization temperatures of gas-liquid inclusions in quartz are 230-520℃（mostly 230-270℃）for quartz porphyry,200-450℃（mostly 200-360℃）for ore-bearing quartz veins,150-210℃for granite 170-200℃ for the vein quartz in it.Quartz from the quartz porphyry and from the ore-earing quartz veins show similar characteristics in inclusion type and homogenization temperature,indicating that intergranular solutions must have been formed upon cooling of magma and that ore-forming solutions for the tungstem mineralization were evolved mainly from ore-bearing intergranular solutions in the quartz porphyry.     

气水化合物的水合常数及其在水溶液包裹体多组分挥发分测定中的应用

During the microthermometric measurement(cooling)of aqueous inclusions with multivolatile components,solid crystals of gas clathrates often occur with snow-flower-or soft-ice appearances.The structural formula of these solids is M·nH_2O(where n≥5.67).Many hydrocarbons,related compounds and their binary or multi-component mixtures may generate gas clathrates.This phenomenum is of fundamental importance to the study of inclusions with hydrocarbon aqueous solutions,because this is related to the determination of inclusion parameters and the computation of thermodynamic parameters. In the nature most aqueous inclusions contain not merely one volatile component but multi-volatile components.Therefore,the measurement of aqueous inclusions with multivolatile components is of universal significance and great importance.There have been many studies and available formula or figures about the computation of thermodynamic parameters for aqueous inclusions with one volatile component.Nevertheless,there are few studies concerning with muhivolatile components and it is very difficult to computate thermodynamic parameters for aqueous inclusions with these components. In this paper,hydrated coefficient K is introduced.K_i is the ratio of molar fraction of component i in the gas phase to that in the gas clathrate,or K_i=y_i/x_i.Because K is a function of temperatures and pressures,it can be used to evaluate the temperature-pressure conditions on the phase behavior with muhivolatile components. Based on the regression analysis of available experimental data,the authors have developed computational expression of hydrated coefficients in relation to temperature and pressure for most hydrocarbons and other volatile components,which is helpful to conveniently compute thermodynamic parameters on stability state for elathrates with volatile components.As aqueous inclusions with muhivolatile components are common in the nature,by the use of final melting temperatures of clathrates from mierothermometry and these formula,fluid density of gas phase with valotile components and bulk fluid density of inclusions can be accurately calculated. Furthermore,this method may provide foundations to determine the isochores of inclusions and to calculate trapping temperatures and pressures. Finally,detailed analyses for two computational examples about aqueous inclusions with muhivolatile components are presented.     

晚期折返过程含石墨流体包裹体及其意义：以印度两个不同地体为例

Archean greenstone belts and Proterozoic granulite mobile belts are products of fundamentally different tectonic processes that culminated in different levels of crustal incision.The present study focuses on graphite-bearing fluid inclusions from two such terrains in India,the Angul domain of Eastern Ghats Mobile Belt and Hutti-Maski schist belt of the eastern Dharwar greenstone-granite belt.In beth cases,a high population of such inclusions within the fluid inclusion assemblage rules out the possibility of graphite being a captive phase,and instead confirms that it was deposited by the fluid within the inclusion cavity.Graphite is usually observed to be occurring with either pure water or a pure carbonic( CO_2 only)liquid,or with a CH_4 dominated carbonic liquid without vapor at room temperature.Graphite precipitation in inclusions is brought about by reaction of the CO2 and CH4 trapped as a homogeneous fluid to give rise to H_2O and C(graphite).Molar volume calculations for the CO_2-CH_4 mixture assuming an appropriate PVTX relationship indicates that there is a substantial increase in volume with decreasing pressure at a given temperature.The reaction producing graphite and H_2O from CH_4 and CO_2 involves substantial volume reduction,and hence would be favored when the rock undergoes rapid exhumation.Graphite-beating inclusions in quartz in a late-stage leucosome from migmatites in the Angul domain of the EGMB are accompanied by other fluid inclusion evidence for isothermal decompression.In the Hutti-Maski schist belt of the eastern Dharwar Craton,graphite-bearing inclusions occur in structurally controlled quartz veins(often auriferous)within metamorphosed mafic volcanics(schists and amphibolites).The Raman spectra indicate that graphites in fluid inclusions from the Hutti-Maski schist belt have both ordered(O)and the disordered(D)peaks,whereas those from the Angul area of EGMB lack the disordered(D)peaks, with both having perfectly symmetrical‘S’peak.This implies that in both belts,exhumation from the burial depth maxima was a rapid process.However,the Hutti-Maski schist belt experienced a lower amount of uplift than the Angul domain,where the driving mechanism led to a deeper level of incision.This difference in the extent and rate of exhumation is speculated to be related to a fundamental difference in the nature of tectonism.A more detailed comparative study of the fluid inclusion characteristics would possibly throw more light on the changing tectonic style from the Archean to the Proterozoic,a topic that is extensively debated.     

Metasomatic Mechnanism of Weathering—Pedogenesis of Carbonate Rocks：I.Mineralogical and Micro—Textural Evidence

On the basis of mineralogical ,geochemical and micro-textural studies of the typical sections of the red weathering crust of carbonate rocks in the subtropical karst areas of Guizhou Province and Guangxi Autonomous Region,we have found,either on a microscopic or on a mac-roscopical scale and in different positions of the sections,the most direct and most important mineralogical and micro-textural evidence for the development of metasomatism in the process of weathering-pedogenesis of numerous carbonate rocks.This paper also has expounded for the first time and systematically the mechanism of metasomatism involved in the process of weathering-pedogenesis of carbonate rocks and proposed the sequence of mineral metasomatic evolution in the process of weathering-pedogenesis of carbonate rocks.     

Assessment of heavy metals contamination in soils of Dexing region, Jiangxi Province, China

Heavy metal contamination has attracted huge concern due to its toxicity, abundance and persistence in the environment, and subsequent accumulation in soil, sediment and water. Mining is one of the most important sources of heavy metals in the environment. Mining-milling operations and disposal of tailings （the finely ground remains of milled ores） in addition to smelting and metal refining provide significant sources of pollution. Mining and mineral processing in the Dexing region of China have been carried out for over forty years and have contaminated the soils with heavy metals, Many studies were conducted to assess and establish the extent of heavy metal contamination in the soils due to mining. The aim of this work was to assess the environmental impact of mining on soils in the Dexing region and to identify the main factors involved in heavy metals dispersion. A 4800 km^2 study area was assessed with respect to its heavy metals on the basis of the current guideline values. In order to assess the extent of heavy metals contamination resulting from past mining activities in the Dexing region, 919 soil samples were collected and analyzed for As, Hg, Cd, Cr, Zn, Cu and Pb, Heavy metals levels were determined using inductively couple plasma-atomic emission spectrometry and X-ray fluorescence spectrometry. Results of soil samples reported concentrations between 1.790-899 mg/kg for As, 0.034-4.980 mg/kg for Hg, 0.043-8.330 mg/kg for Cd, 10-666 mg/kg for Cr, 25-18500 mg/kg for Zn, 6-1825 mg/kg for Cu, and 16-1312 mg/kg for Pb, respectively. The maximum values of As, Hg, Cd, Cr, Zn, Cu and Pb concentration in soils were up to 60, 33, 41, 7, 185, 52 and 37 times higher than the tolerable level, respectively. Meanwhile, the single-factor pollution index and Nemerow pollution index were used to assess the environment quality of heavy metals contamination.     

Research advances in non-Darcy flow in low permeability media

More and more experimental results show that Darcy’s law is not fully applicable in low permeability media,and non-Darcy flow has been identified.In this paper we reviewed the research of non-Darcy flow experiments in low-permeability media in recent decades,discuss the existence of non-Darcy flow,and summarize its constitutive equations.The reasons for the threshold gradient were also discussed and summarized for the criterion of the critical point of non-Darcy flow.On this basis,the future development of non-Darcy flow experiments in the rock and clay media were discussed,in order to provide a certain reference for subsequent research on seepage laws in low permeability media.     

吉林陨石中包裹体特征，形成温度及其意义的探讨

Glass and gas inclusions have been observed in olivine and other minerals in 30 doubly polished tin sections of Jilin meteorites, indicating that there must have been melting And condensation stages during the process of meteorite formation. Temperatures of formation have been determined by homogenization and quenching runs,giving 1050-200℃ and 502℃ for glass and gas inclusions respectively, Meanwhile,the fibrous radial crystals of pyroxene have been notieed to grow when heated over 800℃. These observations are in general agreement with the available experimental data and theoretical calculations regarding meteorite.     

REE Geochemistry in the Weathered Crust of Granites, Longnan Area,Jiangxi Province

Warm and humid climate and gentle hilly topography have provided favourable conditions for the devel-opment of the weathering crust of the granite intrusions in the Longnan area, Jiangxi Province. REE is mostlyconcentrated in an adsorption state in clay in the wholly weathered zone. The rare-earth minerals enriched inthe parent rocks provided the source material for the REE enrichment. Exchangeable REE accounts for48-86%. Extraction experiments and stable isotopic study of clay minerals suggest that the downward infiltra-tion of meteoric water and increasing gradient of pH values have played an important role in the enrichment ofREE during the progressive weathering. Slight fractionation of individual REE can not change their distribu-tion patterns in the profiles. which are inherited from the parent rocks.     

Potential and Suitability Evaluation of CO2 Geological Storage in Major Sedimentary Basins of China, and the Demonstration Project in Ordos Basin

From 2010 to 2012, the China Geological Survey Center for Hydrogeology and Environmental Geology Survey (CHEGS) carried out the project “Potential evaluation and demonstration project of CO2 Geological Storage in China”. During this project, we developed an evaluation index system and technical methods for the potential and suitability of CO2 geological storage based on China’s geological conditions, and evaluated the potential and suitability of the primary basins for CO2 geological storage, in order to draw a series of regional scale maps (at a scale of 1:5000000) and develop an atlas of the main sedimentary basins in China. By using these tools, we delineated many potential targets for CO2 storage. We also built techniques and methods for site selection and the exploration and assessment of CO2 geological storage in deep saline aquifers. Furthermore, through cooperation with the China Shenhua Coal to Liquid and Chemical Co., Ltd., we successfully constructed the first coal-based demonstration project for CO2 geological storage in deep saline aquifers in the Yijinhuoluo Banner of Ordos in the Inner Mongolia Autonomous Region, which brought about the basic preliminary theories, techniques, and methods of geological CO2 storage in deep saline aquifers under China’s geological conditions.     

Temporo-Spatial Distribution and Evolution of Ore Deposits in the West Sector of the Northern Qilian Mountains

The west sector of the northern Qilian Mountains is well-known for the Jingtieshan-type iron deposits. A new breakthrough has been made in prospecting for gold and copper in recent years. In this paper, the distribution characteristics of ore deposits in the study area are discussed from the viewpoint of tectonic evolution. It is suggested that there are 9 stages of mineralization from the Palaeoproterozoic to Indosinian. Four minerogenetic series and two minerogenetic subseries of ore deposits are recognized. Iron mineralization occurred in several stages, while most of the metals were accumulated in large amounts in the Caledonian. The enrichment and mineralization of gold is related to large-scale shear-strike-slip faults and the ascent and unloading of deep-seated fluids.