The timing of sea-level high-stands during Marine Isotope Stages 7.5 and 9: Constraints from the uranium-series dating of fossil corals from Henderson Island

Direct dating of fossil coral reefs using the U-series chronometer provides an important independent test of the Milankovitch orbital forcing theory of climate change. However, well-dated fossil corals pre-dating the last interglacial period (>130 thousand years ago; ka) are scarce due to, (1) a lack of sampling localities, (2) insufficient analytical precision in U-series dating methods, and (3) diagenesis which acts to violate the assumption of closed-system U-series isotopic decay in fossil corals. Here we present 50 new high-precision U-series age determinations for fossil corals from Henderson Island, an emergent coral atoll in the central South Pacific. U-series age determinations associated with the Marine Isotope Stage (MIS) 9 interglacial and MIS 7.5 interstadial periods are reported. The fossil corals show relatively little open-system U-series behaviour in comparison to other localities with fossil coral reefs formed prior to the last glacial cycle, however, open-system U-series behaviour is still evident in most of the dated corals. In particular, percent-level shifts in the [²³⁰Th/²³⁸U]_act composition are observed, leading to conventional U-series ages that are significantly younger or older than the true sample age. This open-system U-series behaviour is not accounted for by any of the open-system U-series models, indicating that new models should be derived. The new U-series ages reported here support and extend earlier findings reported in Stirling et al. (2001), providing evidence of prolific coral reef development on Henderson Island at ∼320 ka, most likely correlated with MIS 9.3, and subsequent reef development at ∼307 ka during MIS 9.1, while relative sea-level was potentially ∼20 m lower than during MIS 9.3. The U-series ages for additional well-preserved fossil corals are suggestive of minor reef development on Henderson Island during MIS 7.5 (245-230 ka) at 240.3 ± 0.8 and 234.7 ± 1.3 ka. All U-series observations are consistent with the Milankovitch theory of climate change, in terms of the timing of onset and termination of the dated interglacial and interstadial periods. The best preserved samples also suggest that the oceanic ²³⁴U/²³⁸U during MIS 9 and MIS 7.5 was within five permil of the modern open ocean composition.     

The Last Interglacial sea level change: new evidence from the Abrolhos islands,West Australia

U-series ages measured by thermal ionisation mass spectrometry (TIMS) are reported for a Last Interglacial (LI) fossil coral core from the Turtle Bay, Houtman Abrolhos islands, western Australia. The core is 33.4 m long the top of which is approximately 5 m a.p.s.l. (above present sea level). From the²³²Th concentrations and the reliability of the U-series ages, two sections in the core can be distinguished. Calculated U/Th ages in core section I (3.3 m a.p.s.l to 11 m b.p.s.l) vary between 124±1.7 ka BP (3.3 m a.p.s.l.) and 132.5±1.8 ka (4 m b.p.s.l., i.e. below present sea level), and those of section II (11–23 m b.p.s.l.) between 140±3 and 214±5 ka BP, respectively. The ages of core section I are in almost perfect chronological order, whereas for section II no clear age-depth relationship of the samples can be recognised. Further assessments based on the ϖ²³⁴U_(T) criteria reveal that none of the samples of core section II give reliable ages, whereas for core section I several samples can be considered to be moderately reliable within 2 ka. The data of the Turtle Bay core complement and extend our previous work from the Houtman Abrolhos showing that the sea level reached a height of approximately 4 m b.p.s.l at approximately 134 ka BP and a sea level highstand of at least 3.3 m a.p.s.l. at approximately 124 ka BP. Sea level dropped below its present position at approximately 116 ka BP. Although the new data are in general accord with the Milankovitch theory of climate change, a detailed comparison reveals considerable differences between the Holocene and LI sea level rise as monitored relative to the Houtman Abrolhos islands. These observation apparently add further evidence to the growing set of data that the LI sea level rise started earlier than recognised by SPECMAP chronology. A reconciliation of these contradictionary observations following the line of arguments presented by Crowley (1994) are discussed with respect to the Milankovitch theory.     

Late Pleistocene (Last Interglacial) terrace deposits, Bahia Coyote, Baja California Sur, México

Late Pleistocene age terrace deposits are exposed in the narrow cliffed coastal plain of Bahia Coyote, Baja California Sur, resting unconformably on the lagoonal-shallow water volcaniclastics of the early Miocene Cerro Colorado Member of the El Cien Formation. The terrace is dissected by widely spaced arroyos and partically covered by alluvial fans in the inner and central areas. The marine deposits vary in thickness from 0.5 to 10 m and were laid down in pre-existing erosional channels and depressions in the Pleistocene landscape. The sequence begins with a cobble conglomerate with oyster shells, overlain by poorly bedded molluscan-rich bioclastic sands and coral rubble, beds of massive Porites in growth position and coral-rhodolith sands and marls. Beach sands and gravels and coastal dunes cap the sequence.Samples of Porites panamensis selected for U/Th dating are well-preserved aragonite (>95%). Preliminary results yield U/Th ages of 109–209 ka but the corals have initial δ ²³⁴U values in excess of modern seawater values. This indicates open-system behavior and uncertainty associated with the ages. A corrected age for the top of the massive Porites unit suggests that the corals grew during the last interglacial, marine isotope stage (MIS) 5e sea level high stand.Assuming global sea level during MIS 5e was ca. 4–5 m above present-day sea level (McCulloch and Esat, 2000) and the growth position of the corals was 1–5 m below sea level, the terraces have been uplifted between 12 and 25 m (12–15 cm/kyr). This is consistent with other terrace-based uplift rates for the central Baja California peninsula, north of the La Paz fault.     

文石-方解石石笋U/Th体系的封闭性判断及意义

湖南省龙山县莲花洞两根大型石笋LLl(文石-方解石型)和LL5(文石型)ICP-MS230Th结果表明,82个年龄数据并不完全符合石笋生长层序律.根据U/Th同位素比值、沉积和矿物学特征,分析了同位素体系开放度对建立石笋正确年代学模式的影响.莲花洞LLl石笋全新世以来234U/238U对230Th/238U的比值具有谐和性特征并且230Th年龄层序正常,说明文石矿物基本接近U/Th同位素封闭系统,实测年龄基本可靠.10～40 ka期间234U/238U与230Th/238U离散度较大和矿物具有溶蚀、风化现象,表明体系发生U加入/流失作用.LL5石笋60～80 ka期间封闭性较好,实测年龄可信.上述结果表明,同一洞穴中文石石笋U/Th同位素体系开放度与时间的关系并不是线性关系,沉积时水文和物理化学性质以及随后的保存状况是决定洞穴文石石笋同位素封闭性的关键因素.     

New data on the pleistocene of Mallorca

Stratigraphic, geomorphologic and isoleucine epimerization studies at 15 sites in Mallorca define four aminozones (A, C, E and F-G) of increasing age that are related to transgressive-regressive marine cycles from the Holocene to the mid Pleistocene. Calibration of aminozone E (Glycymeris aIle/Ile mean from all sites = 0.41 ± 0.03 (n=38)) is provided by a 129 ± 7 ka U-series coral age on Cladocora caespitosa from Son Grauet. Of the younger aminozones, A relates to the Holocene transgression and aminozone C to a mid to late isotopic stage 5 event (90 ± 15 ka) revealed only by supralittoral eolianites. Assigning an age to the older, poorly resolved aminozones F and G (called F-G in this case) is uncertain without supporting radiometric data. But an age of > 180 ka can be assigned to these aminozone (s) F-G based on a kinetic model and other examples in the Mediterranean.Several deposits, previously dated (U-series, molluscs) between 75 and > 300 ka appear to belong to the last interglacial complex (Stage 5) and aminozone E. A proposed revision of the positive sea level history of Mallorca shows multiple minor oscillations during the major last interglacial cycle (Stage 5) and two mid Pleistocene sea levels, one lower than present and the other at about 14 m a.s.l.     

Interstadial coral reef terraces and relative sea-level changes during marine oxygen isotope stages 3–4, Kikai Island, central Ryukyus, Japan

Coral reef terraces are one of the best recorders of relative sea-level changes during the last glacial cycle. Thus far, knowledge of relative sea-level record based on coral reefs during the marine Oxygen Isotope Stage (OIS) 3 has been limited to studies of the Huon Peninsula, Papua New Guinea. High-precision a α-spectrometric ²³⁰Th/²³⁴U dating demonstrated an offlapping sequence of five coral reef complexes, ages of which are 66, 64, 62, 55 and 52 ka, in the northern part of Kikai Island, central Ryukyus of Japan. Interstadial reefs, characterized by deepening-upward sequences of coral assemblages, recorded three hemicycles from transgression to highstand at 52, 62, and 66 ka, during which these reefs were drowned. These highstands in the relative sea-level record can be correlated with the eustatic record reconstructed from the Huon reef terraces and with the interstadials 14, 18, and 19 of the GISP 2 oxygen isotope record. This consistency confirms the Huon sea-level record of OIS 3 and implies that the eustatic sea level responded to the millennial-scale climate changes even during the glacial period of OIS 4.     

Barbados岛珊瑚礁高精度铀系年龄及讨论

应用同位素稀释法热电离质谱(TIMS)技术测定珊瑚礁的高精度铀系年龄。通过对BarbadosⅢ、Ⅳ阶地等样品分析,RendezvousHil和Curacao+6m的TIMS年龄分别为129.2±1.2kaB.P.和125.4±1.1kaB.P.,对应深海沉积物氧同位素第5期5e段的高海面;Kendal山阶地为208.1±1.9kaB.P.,可能代表7c间冰期高海平面的时代。该结果与Edwards等测定同一阶地的年龄一致,与α谱法数据在误差范围内吻合。另外,探讨了初始铀同位素比值的变化,并对TIMS年龄的可靠性做了评价。     

Sea-level history of the past two interglacial periods: new evidence from U-series dating of reef corals from south Florida

As a future warm-climate analog, much attention has been directed to studies of the Last Interglacial period or marine isotope substage (MIS) 5.5, which occurred ～120,000 years ago. Nevertheless, there are still uncertainties with respect to its duration, warmth and magnitude of sea-level rise. Here we present new data from tectonically stable peninsular Florida and the Florida Keys that provide estimates of the timing and magnitude of sea-level rise during the Last Interglacial period. The Last Interglacial high sea stand in south Florida is recorded by the Key Largo Limestone, a fossil reef complex, and the Miami Limestone, an oolitic marine sediment. Thirty-five new, high-precision, uranium-series ages of fossil corals from the Key Largo Limestone indicate that sea level was significantly above present for at least 9000 years during the Last Interglacial period, and possibly longer. Ooids from the Miami Limestone show open-system histories with respect to U-series dating, but show a clear linear trend toward an age of ～120 ka, correlating this unit with the Last Interglacial corals of the Key Largo Limestone. Older fossil reefs at three localities in the Florida Keys have ages of ～200 ka and probably correlate to MIS 7. These reefs imply sea level near or slightly above present during the penultimate interglacial period. Elevation measurements of both the Key Largo Limestone and the Miami Limestone indicate that local (relative) sea level was at least 6.6 m, and possibly as much as 8.3 m higher than present during the Last Interglacial period.     

Electron spin resonance (ESR) and thermal ionization mass spectrometric (TIMS) 230Th/234U dating of teeth in Middle Paleolithic layers at Amud Cave,Israel

Electron spin resonance (ESR) dating and thermal ionization mass spectrometric ²³⁰Th/²³⁴U dating was conducted on six teeth from the prehistoric site of Amud Cave. By combining the ESR and ²³⁰Th/²³⁴U analyses, we obtained burial ages for teeth in various layers of the site. Layer B₁/6–7, from which the Amud I Neanderthal skeleton was recovered, is dated to 53 ± 8 ka. Layer B₂/8, which yielded other important human remains including the Amud 7 skeleton, gives a mean burial age of 61 ± 9 ka. One tooth from the lowest layer (B₄) yielded a date of 70 ± 11 ka, but another tooth from this layer gave an 113 ± 18 ka. Despite this discrepancy, these ages agree with previously published TL ages on heated flints for the corresponding layers. This agreement between ESR on tooth enamel and TL on burned flint is also seen at all other sites studied with both methods in Israel. © 2001 John Wiley & Sons, Inc.     

Quaternary hinterland evolution of the active Banda Arc: Surface uplift and neotectonic deformation recorded by coral terraces at Kisar,Indonesia

Coral terrace surveys and U-series ages of coral yield a surface uplift rate of ∼0.5 m/ka for Kisar Island, which is an emergent island in the hinterland of the active Banda arc–continent collision. Based on this rate, Kisar first emerged from the ocean as recently as ∼450 ka. These uplifted terraces are gently warped in a pattern of east–west striking folds. These folds are strike parallel to more developed thrust-related folds of similar wavelength imaged by a seismic reflection profile just offshore. This deformation shows that the emergence of Kisar is influenced by forearc closure along the south-dipping Kisar Thrust. However, the pinnacle shape of Kisar and the protrusion of its metamorphic rocks through the forearc basin sediments also suggest a component of extrusion along shear zones or active doming.Coral encrusts the island coast in many locations over 100 m above sea level. Terrace morphology and coral ages are best explained by recognizing major surfaces as mostly growth terraces and minor terraces as mostly erosional into older terraces. All reliable and referable coral U-series ages determined by MC-ICP-MS correlate with marine isotope stage (MIS) 5e (118–128 ka). The only unaltered coral samples are found below 6 m elevation; however an unaltered Tridacna (giant clam) shell in growth position at 95 m elevation yields a U-series age of 195 ± 31 ka, which corresponds to MIS 7. This age agrees with the best-fit uplift model for the island. Loose deposits of unaltered coral fragments found at elevations between 8 and 20 m yield U-series ages of <100 years and may represent paleotsunami deposits from previously undocumented tectonic activity in the region.     

The chronostratigraphy of the latest Middle Pleistocene aeolian and alluvial activity on the Island of Hvar,eastern Adriatic,Croatia

Pleistocene aeolian sands and alluvial deposits can frequently be traced along the Mediterranean coast. Such deposits also exist along the eastern Adriatic coast and the nearby islands. Four stratigraphical sections of these deposits were studied on the Island of Hvar with the purpose of establishing a chronological framework of the aeolian–alluvial depositional system, using luminescence dating and magnetic susceptibility stratigraphy. Luminescence dating was applied on coarse‐grained feldspar and quartz grains separated from the sands. Both quartz optically stimulated luminescence (OSL) and feldspar post‐IR infrared stimulated luminescence (pIRIR) age estimates are in good agreement, with values ranging between 167±24 to 120±12 ka (OSL) and 179±18 to 131±18 ka (pIRIR measured at 290 °C) after a fading correction for the pIRIR signal. The results can be clearly correlated to around the end of oxygen isotope stage (OIS) 6 and the beginning of OSI 5, indicating that the aeolian accumulation of sands was a result of the Penultimate Glacial and climate fluctuations at the beginning of the Last Interglacial. Variations in magnetic susceptibility (MS) data can be interpreted alongside these dating results; several stronger peaks detected at the very end of the Penultimate Glacial and the initial stage of the Last Interglacial cycle most probably indicates more intensive pedogenesis resulting from a more favourable climate, probably because of climate changes. Breccias related to major bounding surfaces in association with evidence of soil formation and bioturbation could be the result of more favourable climate conditions and changes during the transition from OIS 6 to OIS 5 (Penultimate Glacial–Last Interglacial). These results are in agreement with similar data from the wider Mediterranean area.     

U-series dating of co-seismic gypsum and submarine paleoseismology of active faults in Northern Chile (23°S)

The convergence of the Nazca and South American plates along the subduction margin of the central Andes results in large subduction earthquakes and tectonic activity along major fault systems. Despite its relevance, the paleoseismic record of this region is scarce, hampering our understanding about the relationship between the Andes building and earthquake occurrence. In this study, we used the U-series disequilibrium method to obtain absolute ages of paleoearthquake events associated with normal displacements along the active Mejillones and Salar del Carmen faults in the Coastal Range of the Atacama Desert of northern Chile. The ²³⁰Th–²³⁴U disequilibrium ages in co-seismic gypsum salts sampled along the fault traces together with marine evidences indicate that earthquakes occurred at ca. 29.7 ± 1.7 ka, 11 ± 4 ka and 2.4 ± 0.8 ka. When coupled with paleoseismic marine and radiocarbon (¹⁴C) records in the nearby Mejillones Bay evidencing large dislocations along the Mejillones Fault, the geochronological dataset presented here is consistent with the notion that gypsum salts formed during large earthquakes as a result of co-seismic dilatancy pumping of saline waters along the major faults. Based on maximum observed cumulative vertical offsets in the studied faults, this phenomena could have occurred episodically at a rate in the order of 1:40 to 1:50 with respect to the very large subduction earthquakes during the latest Pleistocene–Holocene period. The results presented here reveal that the U-series disequilibrium method can be successfully applied to date the gypsum salts deposited along faults during seismic events, and therefore directly constrain the age of large paleoearthquakes in hyperarid and seismically active zones.     

Uranium-series dating of pedogenic silica and carbonate, Crater Flat, Nevada

A ²³⁰Th-²³⁴U-²³⁸U dating study on pedogenic silica-carbonate clast rinds and matrix laminae from alluvium in Crater Flat, Nevada was conducted using small-sample thermal-ionization mass spectrometry (TIMS) analyses on a large suite of samples. Though the ²³²Th content of these soils is not particularly low (mostly 0.1-9 ppm), the high U content of the silica component (mostly 4-26 ppm) makes them particularly suitable for ²³⁰Th/U dating on single, 10 to 200 mg totally-digested samples using TIMS. We observed that (1) both micro- (within-rind) and macro-stratigraphic (mappable deposit) order of the ²³⁰Th/U ages were preserved in all cases; (2) back-calculated initial ²³⁴U/²³⁸U fall in a restricted range (typically 1.67±0.19), so that ²³⁴U/²³⁸U ages with errors of about 100 kyr (2σ) could be reliably determined for the oldest, 400 to 1000 ka rinds; and (3) though 13 of the samples were >350 ka, only three showed evidence for an open-system history, even though the sensitivity of such old samples to isotopic disruption is very high. An attempt to use leach-residue techniques to separate pedogenic from detrital U and Th failed, yielding corrupt ²³⁰Th/U ages. We conclude that ²³⁰Th/U ages determined from totally dissolved, multiple sub-mm size subsamples provide more reliable estimates of soil chronology than methods employing larger samples, chemical enhancement of ²³⁸U/²³²Th, or isochrons.     

U-Th dating of Lake Lisan (late Pleistocene dead sea) aragonite and implications for glacial east Mediterranean climate change

U-series dating can be an effective means to obtain accurate and precise ages on Quaternary carbonates. However, most samples require a correction for U and Th in admixed detritus. This complication is often addressed through generation of U-Th isochrons, requiring analyses of several coeval samples. In addition, presence of water-derived (hydrogenous) Th in the carbonate can cause inaccuracies in isochron ages.This study reports a high-resolution U-series chronology of sediments deposited by Lake Lisan, the last glacial precursor of the Dead Sea. The strategy employed combines multiple measurements from a few stratigraphic heights and fewer analyses from many heights in a single described and measured section. The resulting chronology is based on ages at 22 heights in a ∼40-m-thick section covering the interval of ∼70-14 calendar ka BP. The effects of admixed detritus are evaluated using trace elements. Nearly pure aragonite samples, indicated by very low abundances of insoluble elements such as Nb and Zr, were found to contain hydrogenous Th, which causes the uncorrected U-²³⁰Th age of a modern sample to be ∼2.5 ka. Nevertheless, accurate ages have been obtained by correcting for the detrital and aqueous interferences. The resulting ages are in stratigraphic order, and their accuracy is evidenced by consistency of Lisan Formation U-series and ¹⁴C ages with the coral-based calendar-radiocarbon age calibration.The U-Th ages provide a context to unravel the limnological history of Lake Lisan. Boundaries between the Lower, Middle, and Upper stratigraphic units correspond to the MIS 4/3 and 3/2 transitions, respectively. During MIS 2 and 4 the lake generally showed a stable two-layer configuration and a positive fresh-water balance, reflected by deposition of laminated aragonite-detritus. Dry intervals during MIS 2 and 4 are indicated by thick gypsum layers and an inferred depositional hiatus, which are temporally associated with Heinrich events H1 at ∼17 ka and H6 at ∼65 ka, respectively. During MIS 3 the lake level was unstable with intermittent dry periods indicated by abundant clastic layers and a significant hiatus between ∼43-49 ka. Clastic layers are associated with Dansgaard-Oeschger events during MIS 3, and indicate lake level declines during abrupt Northern Hemisphere warmings. Overall, the climate of the Eastern Mediterranean region shows a strong linkage to the Northern Hemisphere climate, with increasing lake size and stability during cold periods, and fluctuations and dessication during warmings and Heinrich events.     

Global sea-level fluctuations during the Last Interglaciation (MIS 5e)

The geomorphology and morphostratigraphy of numerous worldwide sites reveal the relative movements of sea level during the peak of the Last Interglaciation (Marine Isotope Stage (MIS) 5e, assumed average duration between 130±2 and 119±2 ka). Because sea level was higher than present, deposits are emergent, exposed, and widespread on many stable coastlines. Correlation with MIS 5e is facilitated by similar morphostratigraphic relationships, a low degree of diagenesis, uranium–thorium (U/Th) ages, and a global set of amino-acid racemization (AAR) data. This study integrates information from a large number of sites from tectonically stable areas including Bermuda, Bahamas, and Western Australia, and some that have experienced minor uplift (∼2.5 m/100 ka), including selected sites from the Mediterranean and Hawaii. Significant fluctuations during the highstand are evident at many MIS 5e sites, revealed from morphological, stratigraphic, and sedimentological evidence. Rounded and flat-topped curves derived only from reef tracts are incomplete and not representative of the entire interglacial story. Despite predictions of much different sea-level histories in Bermuda, the Bahamas, and Western Australia due to glacio- and hydro-isostatic effects, the rocks from these sites reveal a nearly identical record during the Last Interglaciation.The Last Interglacial highstand is characterized by several defined sea-level intervals (SLIs) that include: (SLI#1) post-glacial (MIS 6/5e Termination II) rise to above present before 130 ka; (SLI#2) stability at +2 to +3 m for the initial several thousand years (∼130 to ∼125 ka) during which fringing reefs were established and terrace morphology was imprinted along the coastlines; (SLI#3) a brief fall to near or below present around 125 ka; (SLI#4) a secondary rise to and through ∼+3–4 m (∼124 to ∼122 ka); followed by (SLI#5) a brief period of instability (∼120 ka) characterized by a rapid rise to between +6 to +9 m during which multiple notches and benches were developed; and (SLI#6) an apparently rapid descent of sea level into MIS 5d after 119 ka. U/Th ages are used to confirm the Last Interglacial age of the deposits, but unfortunately, in only two cases was it possible to corroborate the highstand subdivisions using radiometric ages.Sea levels above or at present were relatively stable during much of early MIS 5e and the last 6–7 ka of MIS 1, encouraging a comparison between them. The geological evidence suggests that significant oceanographic and climatic changes occurred thereafter, midway through, and continuing through the end of MIS 5e. Fluctuating sea levels and a catastrophic termination of MIS 5e are linked to the instability of grounded and marine-based ice sheets, with the Greenland (GIS) and West Antarctic (WAIS) ice sheets being the most likely contributors. Late MIS 5e ice volume changes were accompanied by oceanographic reorganization and global ecological shifts, and provide one ominous scenario for a greenhouse world.     

U/Th systematics and ages of authigenic carbonates from Hydrate Ridge, Cascadia Margin: recorders of fluid flow variations

Uranium (U) concentrations and activity ratios (δ²³⁴U) of authigenic carbonates are sensitive recorders of different fluid compositions at submarine seeps of hydrocarbon-rich fluids (“cold seeps”) at Hydrate Ridge, off the coast of Oregon, USA. The low U concentrations (mean: 1.3 ± 0.4 μg/g) and high δ²³⁴U values (165-317‰) of gas hydrate carbonates reflect the influence of sedimentary pore water indicating that these carbonates were formed under reducing conditions below or at the seafloor. Their ²³⁰Th/²³⁴U ages span a time interval from 0.8 to 6.4 ka and cluster around 1.2 and 4.7 ka. In contrast, chemoherm carbonates precipitate from marine bottom water marked by relatively high U concentrations (mean: 5.2 ± 0.8 μg/g) and a mean δ²³⁴U ratio of 166 ± 3‰. Their U isotopes reflect the δ²³⁴U ratios of the bottom water being enriched in ²³⁴U relative to normal seawater. Simple mass balance calculations based on U concentrations and their corresponding δ²³⁴U ratios reveal a contribution of about 11% of sedimentary pore water to the bottom water. From the U pore water flux and the reconstructed U pore water concentration a mean flow rate of about 147 ± 68 cm/a can be estimated. ²³⁰Th/²³⁴U ages of chemoherm carbonates range from 7.3 to 267.6 ka. ²³⁰Th/²³⁴U ages of two chemoherms (Alvin and SE-Knoll chemoherm) correspond to time intervals of low sealevel stands in marine isotope stages (MIS) 2, 4, 5, 6, 7 and 8. This observation indicates that fluid flow at cold seep sites sensitively reflects pressure changes of the hydraulic head in the sediments. The δ¹⁸O_PDB ratios of the chemoherm carbonates support the hypothesis of precipitation during glacial times. Deviations of the chemoherm δ¹⁸O values from the marine δ¹⁸O record can be interpreted as to reflect temporally and spatially varying bottom water and/or vent fluid temperatures during carbonate precipitation between 2.6 and 8.6°C.     

长白山天池火山晚更新世以来的喷发活动：

应用高精度铀系不平衡TIMS法测定了吉林长白山天池火山岩锥体中上部的11个熔岩、浮岩样品的年龄，并据此划分出晚更新世、全新世以来6个喷发活动期次，分别为：＞350ka、70ka、18－25ka、10ka、4－5ka和1－0．75ka。此外，还介绍了铀系不平衡法火山岩年代学的基本原理和试验流程，讨论了样品封闭等问题。     

High resolution analysis of uranium and thorium concentration as well as U-series isotope distributions in a Neanderthal tooth from Payre (Ardèche, France) using laser ablation ICP-MS

We have mapped U (²³⁸U) and Th (²³²Th) elemental concentrations as well as U-series isotope distributions in a Neanderthal tooth from the Middle Palaeolithic site of Payre using laser ablation ICP-MS. The U-concentrations in an enamel section varied between 1 and 1500 ppb. The U-concentration maps show that U-migration through the external enamel surface is minute, the bulk of the uranium having migrated internally via the dentine into the enamel. The uranium migration and uptake is critically dependent on the mineralogical structure of the enamel. Increased U-concentrations are observed along lineaments, some of which are associated with cracks, and others may be related to intra-prismatic zones or structural weaknesses reaching from the dentine into the enamel. The uranium concentrations in the dentine vary between about 25,000 and 45,000 ppb. Our systematic mapping of U-concentration and U-series isotopes provides insight into the time domain of U-accumulation. Most of the uranium was accumulated in an early stage of burial, with some much later overprints. None of the uranium concentration and U-series profiles across the root of the tooth complied with a single stage diffusion-adsorption (D-A) model that is used for quality control in U-series dating of bones and teeth. Nevertheless, in the domains that yielded the oldest apparent U-series age estimates, U-leaching could be excluded. This means that the oldest apparent U-series ages of around 200 ka represent a minimum age for this Neanderthal specimen. This is in good agreement with independent age assessments (200-230 ka) for the archaeological layer, in which it was found.The Th elemental concentrations in the dental tissues were generally low (between about 1 and 20 ppb), and show little relationship with the nature of the tissue.     

Crystallization and eruption ages of Breccia Museo (Campi Flegrei caldera,Italy) plutonic clasts and their relation to the Campanian ignimbrite

The Campi Flegrei volcanic district (Naples region, Italy) is a 12-km-wide, restless caldera system that has erupted at least six voluminous ignimbrites during the late Pleistocene, including the >300 km³ Campanian ignimbrite (CI) which originated from the largest known volcanic event of the Mediterranean region. The Breccia Museo (BM), a petrologically heterogeneous and stratigraphically complex volcanic deposit extending over 200 km² in close proximity to Campi Flegrei, has long remained contentious regarding its age and stratigraphic relation to the CI. Here, we present crystallization and eruption ages for BM plutonic ejecta clasts that were determined via uranium decay series and (U–Th)/He dating of zircon, respectively. Despite mineralogical and textural heterogeneity of these syenitic clasts, their U–Th zircon rim crystallization ages are indistinguishable with an average age of 49.7 ± 2.5 ka (2σ errors; mean square of weighted deviates MSWD = 1.2; n = 34). A subset of these crystals was used to obtain disequilibrium-corrected (U–Th)/He zircon ages which average 41.7 ± 1.8 ka (probability of fit P = 0.54; n = 15). This age closely overlaps with published CI ⁴⁰Ar/³⁹Ar eruption ages (40.6 ± 0.1 ka) after recalibration to recently revised flux monitor ages. Concordant eruption ages for BM and CI agree with previous chemostratigraphic and paleomagnetic correlations, suggesting their origin from the same eruption. However, they are at variance with recalibrated ⁴⁰Ar/³⁹Ar ages which have BM postdate CI by 3 ± 1 ka. BM syenites show similar geochemical and Sr–Nd isotopical features of pre-caldera rocks erupted between 58 and 46 ka, but are distinctive from subsequent caldera-forming magmas. Energy-constrained assimilation and fractional crystallization modeling of Nd–Sr isotopic data suggests that pre-caldera magmas formed a carapace of BM-type intrusions in a mid-crust magma chamber (≥8 km depth) shielding the younger CI magma from contamination by Hercynian basement wall rocks. An ~41–50 ka hiatus in crystallization ages implies rapid solidification of these pre-CI intrusions. This argues against protracted pre-eruptive storage of a large volume of CI magma at shallow crustal levels.     

U‐Th Zircon Dating by Laser Ablation Single Collector Inductively Coupled Plasma‐Mass Spectrometry (LA‐ICP‐MS)

Zircon crystals in the age range of ca. 10–300 ka can be dated by ²³⁰Th/²³⁸U (U‐Th) disequilibrium methods because of the strong fractionation between Th and U during crystallisation of zircon from melts. Laser ablation inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) analysis of nine commonly used reference zircons (at secular equilibrium) and a synthetic zircon indicates that corrections for abundance sensitivity and dizirconium trioxide molecular ions (Zr₂O₃⁺) are critical for reliable determination of ²³⁰Th abundances in zircon. When corrected for abundance sensitivity and interferences, mean activity ratios of (²³⁰Th)/(²³⁸U) for nine reference zircons analysed on five different days averaged 0.995 ± 0.023 (95% confidence weighted by data‐point uncertainty only, MSWD = 1.6; n = 9), consistent with their U‐Pb ages > 4 Ma that imply equilibrium for all intermediate daughter isotopes (including ²³⁰Th) within the ²³⁸U decay chain. U‐Th zircon ages generated by LA‐ICP‐MS without mitigating (e.g., by high mass resolution) or correcting for abundance sensitivity and molecular interferences on ²³⁰Th are potentially unreliable. To validate the applicability of LA‐ICP‐MS to this dating method, we acquired data from three late Quaternary volcanic units: the 41 ka Campanian Ignimbrite (plutonic clasts), the 161 ka Kos Plateau Tuff (juvenile clasts) and the 12 ka Puy de Dôme trachyte lava (all eruption ages by Ar/Ar, with zircon U‐Th ages being of equal or slightly older). A comparison of the corrected LA‐ICP‐MS results with previously published secondary ion mass spectrometry (SIMS) data for these rocks shows comparable ages with equivalent precision for LA‐ICP‐MS and SIMS, but much shorter analysis durations (~ 2 min vs. ~ 15 min) per spot with LA‐ICP‐MS and much simpler sample preparation. Previously undated zircons from the Yali eruption (Kos‐Nisyros volcanic centre, Greece) were analysed using this method. This yielded a large age spread (~ 45 to > 300 ka), suggesting significant antecryst recycling. The youngest zircon age (~ 45 ± 10 ka) provides a reasonable maximum estimate for the eruption age, in agreement with the previously published age using oxygen isotope stratigraphy (~ 31 ka).