Sorption–Desorption Transformation of the Runoff of Dissolved Microelements at River–Sea Geochemical Barrier (Based on Data of Experimental Laboratory Simulation)

Water Resources - A new method was used for experimental simulation of the sorption–desorption transformation of microelement composition of the adsorbed complex of solid substances of river...     

Space–Time Analysis of Hydrochemical Composition and Pollution of Water in the Northern Dvina Basin

Water Resources - Water quality dynamics along the Northern Dvina River is analyzed under the conditions of anthropogenic impact. Overall, river water is classified as very polluted. The cases of...     

Modeling Optimal Control of the Ecological–Socioeconomic System Water Body–Watershed: Case Study of the White Sea Region

Water Resources - A cognitive model of optimal control of an ecological–socioeconomic system water body–watershed for the case of the White Sea (Beloe more) and its watershed...     

Prediction of the Dead Sea dynamic behaviour with the Dead Sea–Red Sea Canal

A project to link the Dead Sea (DS) to the Red Sea (RS) via a canal is undergoing extensive study. In a previous work, a generalised mathematical model describing the behaviour of the Dead Sea has been developed. Here, the model is extended to include the proposed canal project with a desalination plant. The general effects of a DS–RS Canal predicted by the model were the formation of a permanent two-layer system thus re-establishing stratification conditions, an increase in the evaporation rate due to a decrease in the top layer salinity, the cease in aragonite precipitation, and the re-occurrence of seasonal gypsum precipitation after the filling period depending on the filling regime applied.     

Geochemical changes at the Bagni di Triponzo thermal spring during the Umbria-Marche 1997–1998 seismic sequence

After the earthquakes of September 26, 1997, that hit the Umbria-Marcheboundary (Apennine, Central Italy), with a maximum 6.0 M_w, aprogram of geochemical surveying together with a collection ofhydrogeological changes episodes was extended throughout theepicentre-area, taking the yearly period of the seismic sequence as a whole.After a first areal screening, the Bagni di Triponzo thermal spring wasselected for a discrete temporal monitoring (weekly and monthly basis),being the unique thermal spring throughout the epicentre area. This sitedeserves peculiar interest in deepening the knowledge about deep fluidscirculation changing during seismicity.Laboratory and on-field analyses included major, minor and trace elementsas well as dissolved gases (He, Ar, CH₄, CO₂, H₂S,²²²Rn, NH₄, As, Li, Fe, B, etc...) and selected isotopic ratios(C, H, O, He, Sr, Cl), meaningful from tectonic point of view.The chemistry and isotopic chemistry of the spring were fully outlined anddiscussed, pointing out the main process involving the thermal aquifer: thewater-rock interaction inside the Evaporite Triassic Basement (ETB),possibly involving also the Paleozoic Crystalline Basement. On theother hand, sudden and apparent geochemical and hydrogeologicalvariations during the seismic sequence ruled out an evolution in thewater-rock interaction processes. They occurred both at depth, i.e.,induced by fluid remobilization within the crust explained by the Coseismic Strain Model and by the Fault Valve Activity Model, and in the shallow part of the reservoir (i.e., meteoric watercontamination). A statistical multivariable analysis (Factor Analysis) wasaccomplished to better constrain the correlation between the paroxysmalphases of the seismic sequence and the observed trends and spike-likeanomalies. The groundwater variations was inferred to occur mainly insidethe ETB, from depth (1–2 km) up to surface, particularly in associationof the Sellano earthquake (14/10/1997) and of the seismic re-activationof the sequence at the end of March 1998 (Gualdo Tadino-Rigali andVerchiano areas). The lack of deeper input from below the ETB (slightsignature of PCB), as the lack of He mantle signature, during the seismicperiod as a whole, accounted for seismogenic fault segments rooted onlyin the crust. The results also provide useful information about theearthquake-related response mechanisms occurring at this site, thatrepresent the basic task for planning and managing the impendinghydro-geochemical network aimed at defining the relationships betweenseismic cycle, fluids and reliable earthquake forerunners.     

Geochemical model of a magmatic–hydrothermal system at the Lastarria volcano, northern Chile

Lastarria volcano (25°10′ S, 68°31′ W; 5,697 m above sea level), located in the Central Andes Volcanic Zone (northern Chile), is characterized by four distinct fumarolic fields with outlet temperatures ranging between 80°C and 408°C as measured between May 2006–March 2008 and April–June 2009. Fumarolic gasses contain significant concentrations of high temperature gas compounds (i.e., SO₂, HCl, HF, H₂, and CO), and isotopic ratios (³He/⁴He, δ¹³C–CO₂, δ¹⁸O–H₂O, and δD–H₂O) diagnostic of magmatic gas sources. Gas equilibria systematics, in both the H₂O-H₂-CO₂-CO-CH₄ and alkane–alkene C₃ system, suggest that Lastarria fumarolic gasses emanate from a superheated vapor that is later cooled and condensed at relatively shallow depths. This two-stage process inhibits the formation of a continuous aquifer (e.g., horizontal liquid layer) at relatively shallow depth. Recent developments in the magmatic gas system may have enhanced the transfer and release of heat causing shallow aquifer vaporization. The consequent pressure increase and aquifer vaporization likely triggered the inflation events beginning in 2003 at the Lastarria volcano.     

Hydrochemical Characteristics of the Aral Sea in 2012–2013

The decrease in Aral Sea area, which started in the 1960s, caused considerable changes in the hydrological, chemical, and biological structure of sea water. Regular observations of Aral water chemistry ceased in the early 1990s. There were no observations of the concentrations of biogenic element compounds in water (the so-called “first-day analyses”). During expeditions of the Institute of Oceanology, RAS, in September 2012 and October 2013, integrated hydrochemical observations were carried out, including measuring the concentrations of biogenic element compounds, dissolved oxygen, hydrogen sulfide, and carbonate equilibrium components. An objective of this study was to develop methods of hydrochemical studies under high water salinity (mineralization). In addition to the standard hydrochemical complex, water samples were taken to determine total water mineralization and the concentration of dissolved and suspended metal forms. The results of these studies are given.     

On the Ekman instability at the core–mantle boundary

It is shown that the instability of turbulent flows with Ekman velocity profiles in the vicinity of the core–mantle boundary leads to the formation of horizontally oriented circulating roll structures. The geophysical implications of the presence of such structures in the liquid core are explored, namely, the formation of the hot zones with enhanced conductivity and their influence on geomagnetic reversals.     

Depoliticizing water conflict: functional peacebuilding in the Red Sea–Dead Sea Water Conveyance project

ABSTRACT

This article analyses the nexus of technocracy–peacebuilding and its implications on water conflicts and hydropolitics. It is a conceptual exploration which advances an interdisciplinary approach by combining theories from two distinct research fields: peacebuilding and transboundary water management. It probes the argument that synergies between water management, development and peacebuilding frequently lead to technocratic and functional solutions. As empirical case illustration, the transboundary project, the Red Sea–Dead Sea Water Conveyance (RSDSWC) is analysed regarding its peacebuilding and peace promoting potential. Three concluding remarks are drawn from the conceptual and empirical analysis. First, strong emphasis on technocratic solutions is inclined to favour supply-oriented options rather than solutions based on ethics of sustainable development and rights-based distribution. Second, functional solutions to water conflicts downplay at times complex hydro-political and asymmetrical relations between adversaries. Third, wider trends of privatization in the water sector coincide with similar developments in the field of peacebuilding, where new transnational actors are gaining influence as “new peacemakers”, which are likely to have long-term consequences on power relations and the resolution of water conflict.

EDITOR D. Koutsoyiannis; ASSOCIATE EDITOR not assigned     

Glacio–isostatic Adjustment in the Po Plain and in the Northern Adriatic Region

Vertical movements in the Po plain (northern Italy) are controlled by natural and anthropogenic effects. Since Italy is located in the far–field of the former late Pleistocene ice sheets, isostatic deformations are primarily driven by melt water loading and represent a major component of long–term natural movements across the entire Mediterranean. In addition to far–field sources, here we consider the isostatic effects of melting of the nearby Würm Alpine ice–sheet, suggesting that it is possible to put bounds on its maximum thickness, extent and chronology by Holocene relative sea level observations from the northern Adriatic. Using various plausible ice models, and adopting a viscosity profile that matches Holocene relative sea level observations in the Mediterranean, we find that melting of the Alpine ice sheet is always responsible for upward movements in the Po plain, currently at rates of ~ 0.5 mm/yr. When both far– and near–field sources are considered, the rate of sea level change in the Venetian Lagoon for the most reasonable mantle rheology and melting chronology is negative, i.e., opposite to that attributed to human activity and recent climatic variations. However, its amplitude (fractions of mm/yr) is small compared to the secular signal observed by tide gauges (~2 mm/yr), which makes glacial isostasy a second–order mechanism of sea level variation in this region.     

Isotope–Geochemical Characteristics of Natural Waters in the Southwestern Part of the Crimean Peninsula

Water Resources - The results of our study show that the natural waters in the southwestern part of the Crimean Peninsula are characterized by a wide range of chemical and isotopic composition. The...     

Spatial variations of methane distribution in marine environment and its fluxes at the water–atmosphere interface in the western Sea of Okhotsk

Data of integrated gas-geochemical studies in the 45 cruise of the R/V Akademik M.A. Lavrent’ev in July 2008 were used to study the spatial distribution of methane in the surface seawater layer, the distribution and qualitative composition of hydrocarbon gases in bottom sediments of the northwestern continental shelf, northeastern slope of Sakhalin Island, and Deryugin depression in the Sea of Okhotsk. The specific features of the methane anomalies that form in this case are considered. Tectonic faults and the distribution of oil-and-gas-bearing structures are the main factors governing the formation of hydrocarbon gas fluxes in the study area. The surface water in the entire examined area was found to be oversaturated with methane. A developed model was used to calculated methane fluxes at the water–atmosphere interface and to identify areas with maximal fluxes (up to 324 mol/(km² day).     

Focal Depths of Earthquakes in the Crimea–Black Sea Region

The problem of determining focal depths of earthquakes in the Crimea–Black Sea region is considered. Based on the results of interannual studies, it is found that the focal depths of Crimean earthquakes are mainly crustal, with maximum values of up to 60 km. Some recent publications, however, have described deep-focus earthquakes with depths of up to 300 km which were “revealed” in the Crimean region. In this respect, there arose the need to study such a large difference in estimated focal depths. Convincing examples show that the sensational “revelation” of deep earthquakes in Crimea was caused by incorrect processing of the experimental data, in particular, due to (1) a sharp distortion in the recorded arrival times of body waves, (2) exclusion of data from stations nearest to a source, (3) unreasonable arbitrary selection of data from seismic stations, and (4) dropping of data from the worldwide seismological network, including those on deep seismic phases. Thus, the conclusions about the presence of deep mantle earthquakes in Crimea are erroneous. We have redetermined the parameters of hypocenters and verified that the focal depths of earthquakes in the Crimea–Black Sea region are no more than 60 km. Based on these data, we analyze the features of the spatial distribution of focal depths to show that earthquake sources are grouped along conduits that dip southeastward, from the continental part of Crimea toward the Black Sea Basin, in the case of grouping of sources in the Alushta–Yalta and Sevastopol areas. The seismic focal layer of the Kerch–Anapa area dips northeastward, from the Black Sea beneath the North Caucasus.     

Paleoseismicity and Segmentation Along the Active Fault at the Northern Boundary of Huailai-Zhuolu Basin,Hebei Province

The northern boundary fault of Huailai-Zhuolu basin,Hebei Province,has a total length of 58 km and a general strike of NE.The geometry and feature of activity of the 5 segments of the fault greatly differ from each other.17 paleoseismic events have been recognized within 11 trenches excavated along the different segments of the fault.It is found that each segment is characterized by its distinct recurrence of paleoearthquakes.The recurrence intervals of strong earthquakes for each segment are 3500-7000 a for the shortest and 17,000-20,500 a for the longest.However,the recurrence interval of strong earthquakes for whole fault ranges between 750-8500 a.The boundary of the segments can be recognized as the junction,gap,bending,jog and salient of the fault.The length of the segment ranges between 7.5-14 km.     

An integrated East China Sea–Changjiang Estuary model system with aim at resolving multi-scale regional–shelf–estuarine dynamics

A high-resolution numerical model system is essential to resolve multi-scale coastal ocean dynamics. So a multi-scale unstructured grid-based finite-volume coastal ocean model (FVCOM) system has been established for the East China Sea and Changjiang Estuary (ECS–CE) with the aim at resolving coastal ocean dynamics and understanding different physical processes. The modeling system consists of a three-domain-nested weather research and forecasting model, FVCOM model with the inclusion of FVCOM surface wave model in order to understand the wave–current interactions. The ECS–CE system contains three different scale models: a shelf-scale model for the East China Sea, an estuarine-scale model for the Changjiang Estuary and adjacent region, and a fine-scale model for the deep waterway regions. These three FVCOM-based models guarantee the conservation of mass and momentum transferring from outer domain to inner domain using the one-way common-grid nesting procedure. The model system has been validated using data from various observation data, including surface wind, tides, currents, salinity, and wave to accurately reveal the multi-scale dynamics of the East China Sea and Changjiang Estuary. This modeling system has been demonstrated via application to the seasonal variations of Changjiang diluted water and the bottom saltwater intrusion in the North Passage, and it shows strong potential for estuarine and coastal ocean dynamics and operational forecasting.     

On the Problem of Deep Earthquakes in Crimea–Black Sea Region

It is a common opinion that only crustal earthquakes can occur in the Crimea–Black Sea region. Since the existence of deep earthquakes in the Crimea–Black Sea region is extremely important for the construction of a geodynamic model for this region, an attempt is made to verify the validity of this widespread view. To do this, the coordinates of all earthquakes recorded by the stations of the Crimean seismological network are reinterpreted with an algorithm developed by one of the authors. The data published in the seismological catalogs and bulletins of the Crimea–Black Sea region for 1970–2012 are used for the analysis. To refine the coordinates of hypocenters of earthquakes in the Crimea–Black Sea region, in addition to the data from stations of the Crimean seismological network, information from seismic stations located around the Black Sea coast are used. In total, the data from 61 seismic stations were used to determine the hypocenter coordinates. The used earthquake catalogs for 1970–2012 contain information on ~2140 events with magnitudes from–1.5 to 5.5. The bulletins provide information on the arrival times of P- and S-waves at seismic stations for 1988 events recorded by three or more stations. The principal innovation of this study is the use of the original author’s hypocenter determination algorithm, which minimizes the functional of distances between the points (X, Y, H) and (x, y, h) corresponding to the theoretical and observed seismic wave travel times from the earthquake source to the recording stations. The determination of the coordinates of earthquake hypocenters is much more stable in this case than the usual minimization of the residual functional for the arrival time of an earthquake wave at a station (the difference between the theoretical and observed values). Since determination of the hypocenter coordinates can be influenced by the chosen velocity column beneath each station, special attention is focused on collecting information on velocity profiles. To evaluate the influence of the upper mantle on the results of calculating the velocity model, two different low-velocity and high-velocity models are used; the results are compared with each other. Both velocity models are set to a depth of 640 km, which is fundamentally important in determining hypocenters for deep earthquakes. Studies of the Crimea–Black Sea region have revealed more than 70 earthquakes with a source depth of more than 60 km. The adequacy of the obtained depth values is confirmed by the results of comparing the initial experimental data from the bulletins with the theoretical travel-time curves for earthquake sources with depths of 50 and 200 km. The sources of deep earthquakes found in the Crimea–Black Sea region significantly change our understanding of the structure and geotectonics of this region.     

Terraces and Tectonic Uplifts at Yandantu and Changcaogou on the Northern Margin Fault of Altun

The formation of strath and strath terrace is closely related to tectonic uplift in the drainage basin. Based on the investigation of straths at Yandantu and Changcaogou on the eastern segment of the northern margin fault of Altun, and in combination with the paleoclimatic data,the tectonic uplift since late Epipleistocene as revealed by stream terraces at the two places is discussed. At Yandantu, three levels of stream terraces( T1, T2 and T3 )have developed since 16ka BP, where T1, T3 and T2 are fill terraces and the buried major straths are exposed. The ages of three treads are dated to be about 16.1ka BP, 12 .Ska BP and 6.2ka BP, respectively. The three terraces reflect three tectonic uplift events, while the ages of the treads represent the occurrence time of these events. The stream is still beveling the bedrock and widening the channel at present, and the modern strath is being generated. The uplift rate is 4.8～4.5mm/a since 16.1 ka BP in this area. From 12.8ka B .P to 6.2ka BP, The uplift rate was 6.4mm/a.The uplift rate is 3. lmm/a since 6.2ka BP.At Changcaogou, four levels Of stream terraces(T1, T2, T3 and T1)have developed since 7ka BP. All of them are fill terraces. There are buried straths under the deposits. The buried major strath is exposed on T3 and T2 and the minor strath on T1‘and T1. The ages of treads of the three terraces (T3, T2 and T1’) are 7 ka BP, 3 ka BP and 2.5 ka BP, respectively. The four terraces reflect two uplift events induced by tectonic activities. One occurred in about 7 ka BP, and the other in 3ka BP. The uplift rate is 5.gmm/a since 7.0 ka BP at Changcaogou.From 7ka BP to 3ka BP, the uplift rate was 7.0mm/a, and since 3ka BP till now, the uplift rate is 4.7 mm/a.     

Causes of the Regional Variability in Observed Sea Level,Sea Surface Temperature and Ocean Colour Over the Period 1993–2011

We analyse the regional variability in observed sea surface height (SSH), sea surface temperature (SST) and ocean colour (OC) from the ESA Climate Change Initiative datasets over the period 1993–2011. The analysis focuses on the signature of the ocean large-scale climate fluctuations driven by the atmospheric forcing and do not address the mesoscale variability. We use the ECCO version 4 ocean reanalysis to unravel the role of ocean transport and surface buoyancy fluxes in the observed SSH, SST and OC variability. We show that the SSH regional variability is dominated by the steric effect (except at high latitude) and is mainly shaped by ocean heat transport divergences with some contributions from the surface heat fluxes forcing that can be significant regionally (confirming earlier results). This is in contrast with the SST regional variability, which is the result of the compensation of surface heat fluxes by ocean heat transport in the mixed layer and arises from small departures around this background balance. Bringing together the results of SSH and SST analyses, we show that SSH and SST bear some common variability. This is because both SSH and SST variability show significant contributions from the surface heat fluxes forcing. It is evidenced by the high correlation between SST and buoyancy-forced SSH almost everywhere in the ocean except at high latitude. OC, which is determined by phytoplankton biomass, is governed by the availability of light and nutrients that essentially depend on climate fluctuations. For this reason, OC shows significant correlation with SST and SSH. We show that the correlation with SST displays the same pattern as the correlation with SSH with a negative correlation in the tropics and subtropics and a positive correlation at high latitude. We discuss the reasons for this pattern.     

Three-dimensional flow patterns at the river–aquifer interface — a case study at the Danube

The three-dimensional groundwater flow patterns in a gravel bar at the Danube east of Vienna were investigated and are discussed in this paper. The observed groundwater level gradients are highly dynamic and respond very quickly to changes in the river water levels. A variably saturated groundwater model was calibrated to the data to describe the complex dynamics of flow in the gravel bar. The model results suggest that short-term (6–48 h) fluctuations of river water levels cause variations in the exchange flow rates from − 35 l/s to 82 l/s. The highest rates occur during brief infiltration after rapidly rising river water levels. Simulations of different scenarios indicate that riverbank clogging will decrease the exchange fluxes by up to 80%, while clogging of both riverbank and riverbed essentially stops the flow exchange. The groundwater model is also used to simulate the transport of a conservative tracer. The variation of river water levels over time is shown to increase the extent of the active river–aquifer mixing zone in the gravel bar. These dynamic factors significantly enhance the dilution of conservative tracer concentrations in this zone.