The formation heritage of Jupiter Family Comet 10P/Tempel 2 as revealed by infrared spectroscopy

We present spectral and spatial information for major volatile species in Comet 10P/Tempel 2, based on high-dispersion infrared spectra acquired on UT 2010 July 26 (heliocentric distance R_h = 1.44 AU) and September 18 (R_h = 1.62 AU), following the comet’s perihelion passage on UT 2010 July 04. The total production rate for water on July 26 was (1.90 ± 0.12) × 10²⁸ molecules s^?1, and abundances of six trace gases (relative to water) were: CH₃OH (1.58% ± 0.23%), C₂H₆ (0.39% ± 0.04%), NH₃ (0.83% ± 0.20%), and HCN (0.13% ± 0.02%). A detailed analysis of intensities for water emission lines provided a rotational temperature of 35 ± 3 K. The mean OPR is consistent with nuclear spin populations in statistical equilibrium (OPR = 3.01 ± 0.18), and the (1σ) lower bound corresponds to a spin temperature >38 K. Our measurements were contemporaneous with a jet-like feature observed at optical wavelengths. The spatial profiles of four primary volatiles display strong enhancements in the jet direction, which favors release from a localized vent on the nucleus. The measured IR continuum is much more sharply peaked and is consistent with a dominant contribution from the nucleus itself. The peak intensities for H₂O, CH₃OH, and C₂H₆ are offset by ～200 km in the jet direction, suggesting the possible existence of a distributed source, such as the release of icy grains that subsequently sublimed in the coma. On UT September 18, no obvious emission lines were present in our spectra, nevertheless we obtained a 3σ upper limit Q(H₂O) < 2.86 × 10²⁷ molecules s^?1.     

Stardust-NExT,Deep Impact,and the accelerating spin of 9P/Tempel 1

The evolution of the spin rate of Comet 9P/Tempel 1 through two perihelion passages (in 2000 and 2005) is determined from 1922 Earth-based observations taken over a period of 13 year as part of a World-Wide observing campaign and from 2888 observations taken over a period of 50 days from the Deep Impact spacecraft. We determine the following sidereal spin rates (periods): 209.023 ± 0.025°/dy (41.335 ± 0.005 h) prior to the 2000 perihelion passage, 210.448 ± 0.016°/dy (41.055 ± 0.003 h) for the interval between the 2000 and 2005 perihelion passages, 211.856 ± 0.030°/dy (40.783 ± 0.006 h) from Deep Impact photometry just prior to the 2005 perihelion passage, and 211.625 ± 0.012°/dy (40.827 ± 0.002 h) in the interval 2006–2010 following the 2005 perihelion passage. The period decreased by 16.8 ± 0.3 min during the 2000 passage and by 13.7 ± 0.2 min during the 2005 passage suggesting a secular decrease in the net torque. The change in spin rate is asymmetric with respect to perihelion with the maximum net torque being applied on approach to perihelion. The Deep Impact data alone show that the spin rate was increasing at a rate of 0.024 ± 0.003°/dy/dy at JD2453530.60510 (i.e., 25.134 dy before impact), which provides independent confirmation of the change seen in the Earth-based observations.The rotational phase of the nucleus at times before and after each perihelion and at the Deep Impact encounter is estimated based on the Thomas et al. (Thomas et al. [2007]. Icarus 187, 4–15) pole and longitude system. The possibility of a 180° error in the rotational phase is assessed and found to be significant. Analytical and physical modeling of the behavior of the spin rate through of each perihelion is presented and used as a basis to predict the rotational state of the nucleus at the time of the nominal (i.e., prior to February 2010) Stardust-NExT encounter on 2011 February 14 at 20:42.We find that a net torque in the range of 0.3–2.5 × 10⁷ kg m² s^?2 acts on the nucleus during perihelion passage. The spin rate initially slows down on approach to perihelion and then passes through a minimum. It then accelerates rapidly as it passes through perihelion eventually reaching a maximum post-perihelion. It then decreases to a stable value as the nucleus moves away from the Sun. We find that the pole direction is unlikely to precess by more than ～1° per perihelion passage. The trend of the period with time and the fact that the modeled peak torque occurs before perihelion are in agreement with published accounts of trends in water production rate and suggests that widespread H₂O out-gassing from the surface is largely responsible for the observed spin-up.     

On liquid phases in cometary nuclei

In this paper we review the relevant literature and investigate conditions likely to lead to melting of H₂O ice, methanol (CH₃OH) ice, ethane (C₂H₆) ice and other volatile ices in cometary nuclei. On the basis of a heat balance model which takes account of volatiles loss, we predict the formation of occasional aqueous and hydrocarbon liquid phases in subsurface regions at heliocentric distances, r_h of 1–3 AU, and 5–12 AU, respectively. Low triple-point temperatures and low vapour pressures of C₂H₆, C₃H₈, and some higher-order alkanes and alkenes, favour liquid phase formation in cometary bodies at high r_h. Microporosity and the formation of a stabilization crust occluding the escape of volatiles facilitate liquid-phase formation. Characteristics of the near-surface which favour subsurface melting include; low effective surface emissivity (at low r_h), high amorphous carbon content, average pore sizes of ～10 μm or less, presence of solutes (e.g. CH₃OH), mixtures of C₂–C₆ hydrocarbons (for melting at high r_h), diurnal thermal cycling, and slow rotation rate. Applying the principles of soil mechanics, capillary forces are shown to initiate pre-melting phenomena and subsequent melting, which is expected to impart considerable strength of ～10⁴ Pa in partially saturated layers, reducing porosity and permeability, enhancing thermal conductivity and heat transfer. Diurnal thermal cycling is expected to have a marked effect on the composition and distribution of H₂O ice in the near-surface leading to frost heave-type phenomena even where little if any true melting occurs. Where melting does take place, capillary suction in the wetted zone has the potential to enhance heat transfer via capillary wetting in a low-gravity environment, and to modify surface topography creating relatively smooth flat-bottomed features, which have a tendency to be located within small depressions. An important aspect of the “wetted layer” model is the prediction that diurnal melt–freeze cycles alter the mixing ratio vs. depth of solutes present, or of other miscible components, largely through a process of fractional crystallization, but also potentially involving frost heave. Wetted layers are potentially durable and can involve significant mass transport of volatile materials in the near-surface, increasing in extent over many rotations of the nucleus prior to and just after perihelion passage, and causing stratification and trapping of the lowest-melting mixtures at depths of several metres. A possible mechanism for cometary outbursts is proposed involving a heat pulse reaching the liquid phase in the deepest wetted zone, leading to supersaturation and triggering the sudden release under pressure of dissolved gases, in particular CO₂, CO, CH₄ or N₂, contained beneath a consolidated near-surface layer. This study indicates that liquid water can persist for long periods of time in the near-surface of some intermediate-sized bodies (10²–10³ km radius) within protoplanetary discs.     

Observation of DCl and upper limit to NH3 on Venus

To search for DCl in the Venus atmosphere, a spectrum near the D³⁵Cl (1–0) R4 line at 2141.54 cm^?1 was observed using the CSHELL spectrograph at NASA IRTF. Least square fitting to the spectrum by a synthetic spectrum results in a DCl mixing ratio of 17.8 ± 6.8 ppb. Comparing to the HCl abundance of 400 ± 30 ppb (Krasnopolsky [2010a] Icarus, 208, 314–322), the DCl/HCl ratio is equal to 280 ± 110 times the terrestrial D/H = 1.56 × 10^?4. This ratio is similar to that of HDO/H₂O = 240 ± 25 times the terrestrial HDO/H₂O from the VEX/SOIR occultations at 70–110 km. Photochemistry in the Venus mesosphere converts H from HCl to that in H₂O with a rate of 1.9 × 10⁹ cm^?2 s^?1 (Krasnopolsky [2012] Icarus, 218, 230–246). The conversion involves photolysis of HCl; therefore, the photochemistry tends to enrich D/H in HCl and deplete in H₂O. Formation of the sulfuric acid clouds may affect HDO/H₂O as well. The enriched HCl moves down by mixing to the lower atmosphere where thermodynamic equilibriums for H₂ and HCl near the surface correspond to D/H = 0.71 and 0.74 times that in H₂O, respectively. Time to establish these equilibriums is estimated at ～3 years and comparable to the mixing time in the lower atmosphere. Therefore, the enriched HCl from the mesosphere gives D back to H₂O near the surface. Comparison of chemical and mixing times favors a constant HDO/H₂O up to ～100 km and DCl/HCl equal to D/H in H₂O times 0.74.Ammonia is an abundant form of nitrogen in the reducing environments. Thermodynamic equilibriums with N₂ and NO near the surface of Venus give its mixing ratio of 10^?14 and 6 × 10^?7, respectively. A spectrum of Venus near the NH₃ line at 4481.11 cm^?1 was observed at NASA IRTF and resulted in a two-sigma upper limit of 6 ppb for NH₃ above the Venus clouds. This is an improvement of the previous upper limit by a factor of 5. If ammonia exists at the ppb level or less in the lower atmosphere, it quickly dissociates in the mesosphere and weakly affects its photochemistry.     

The role of sputtering and radiolysis in the generation of Europa exosphere

The exosphere of an atmosphereless icy moon is the result of different surface release processes and subsequent modification of the released particles. At Europa icy moon, water molecules are directly released, but photolysis and radiolysis due to solar UV and Jupiter’s magnetospheric plasma, respectively, can result in OH, H, O and (possibly) H₂ production. These molecules can recombine to reform water and/or new chemical species. As a consequence, Europa’s neutral environment becomes a mixture of different molecules, among which, H₂O dominates in the highest altitudes and O₂, formed mainly by radiolysis of ice and subsequent release of the produced molecules, prevails at lower altitudes. In this work, starting from a previously developed Monte Carlo model for the generation of Europa’s exosphere, where the only considered species was water, we make a first attempt to simulate also the H₂ and O₂ components of the neutral environment around Europa, already observed by the Hubble Space Telescope and the Ultraviolet Imaging Spectrograph on board Cassini, during its flyby of Jupiter. Considering a specific configuration where the leading hemisphere coincides with the sunlit hemisphere, we estimate along the Europa–Sun line an O₂ column density of about 1.5 × 10¹⁹ m^?2 at the dayside and 3 × 10¹⁸ m^?2 at the nightside. In this work we also improve our previous estimation of the sputtered H₂O exosphere of this moon, taking into consideration the trailing–leading asymmetry in the magnetospheric ion bombardment and the energy and temperature dependences of the process yields. We find that a density of 1.5 × 10¹² H₂O/m³ is expected at altitudes ～0.1R_E above the surface of the trailing hemisphere. Additionally, we calculate the escape of H₂O, O₂ and H₂. The total number of neutral atoms in Europa’s neutral torus, is estimated to be in the range 7.8 × 10³²–3.3 × 10³³.     

Absolute magnitudes of asteroids and a revision of asteroid albedo estimates from WISE thermal observations

We obtained estimates of the Johnson V absolute magnitudes (H) and slope parameters (G) for 583 main-belt and near-Earth asteroids observed at Ond?ejov and Table Mountain Observatory from 1978 to 2011. Uncertainties of the absolute magnitudes in our sample are <0.21 mag, with a median value of 0.10 mag. We compared the H data with absolute magnitude values given in the MPCORB, Pisa AstDyS and JPL Horizons orbit catalogs. We found that while the catalog absolute magnitudes for large asteroids are relatively good on average, showing only little biases smaller than 0.1 mag, there is a systematic offset of the catalog values for smaller asteroids that becomes prominent in a range of H greater than ～10 and is particularly big above H ～ 12. The mean (H_catalog ? H) value is negative, i.e., the catalog H values are systematically too bright. This systematic negative offset of the catalog values reaches a maximum around H = 14 where the mean (H_catalog ? H) is ?0.4 to ?0.5. We found also smaller correlations of the offset of the catalog H values with taxonomic types and with lightcurve amplitude, up to ～0.1 mag or less. We discuss a few possible observational causes for the observed correlations, but the reason for the large bias of the catalog absolute magnitudes peaking around H = 14 is unknown; we suspect that the problem lies in the magnitude estimates reported by asteroid surveys. With our photometric H and G data, we revised the preliminary WISE albedo estimates made by Masiero et al. (Masired, J.R. et al. [2011]. Astrophys. J. 741, 68–89) and Mainzer et al. (Mainzer, A. et al. [2011b]. Astrophys. J. 743, 156–172) for asteroids in our sample. We found that the mean geometric albedo of Tholen/Bus/DeMeo C/G/B/F/P/D types with sizes of 25–300 km is p_V = 0.057 with the standard deviation (dispersion) of the sample of 0.013 and the mean albedo of S/A/L types with sizes 0.6–200 km is 0.197 with the standard deviation of the sample of 0.051. The standard errors of the mean albedos are 0.002 and 0.006, respectively; systematic observational or modeling errors can predominate over the quoted formal errors. There is apparent only a small, marginally significant difference of 0.031 ± 0.011 between the mean albedos of sub-samples of large and small (divided at diameter 25 km) S/A/L asteroids, with the smaller ones having a higher albedo. The difference will have to be confirmed and explained; we speculate that it may be either a real size dependence of surface properties of S type asteroids or a small size-dependent bias in the data (e.g., a bias towards higher albedos in the optically-selected sample of asteroids). A trend of the mean of the preliminary WISE albedo estimates increasing with asteroid size decreasing from D ～ 30 down to ～5 km (for S types) showed in Mainzer et al. (Mainzer, A. et al. [2011a]. Astrophys. J. 741, 90–114) appears to be mainly due to the systematic bias in the MPCORB absolute magnitudes that progressively increases with H in the corresponding range H = 10–14.     

Remote sensing of a comet at millimeter and submillimeter wavelengths from an orbiting spacecraft

The ESA Rosetta Spacecraft, launched on March 2, 2004 with the ultimate destination being Comet 67P/Churyumov–Gerasimenko, carries a relatively small and lightweight millimeter–submillimeter spectrometer instrument, the first of its kind launched into deep space. The instrument, named Microwave Instrument for the Rosetta Orbiter (MIRO), consists of a 30-cm diameter, offset parabolic reflector telescope, which couples energy in the millimeter and submillimeter bands to two heterodyne receivers. Center-band operating frequencies are near 190 GHz (1.6 mm) and 562 GHz (0.5 mm). Broadband, total power continuum measurements can be made in both bands. A 4096-channel spectrometer with 44 kHz resolution is connected to the submillimeter receiver. The spectral resolution is sufficient to observe individual, thermally broadened spectral lines (T⩾10 K). The submillimeter radiometer/spectrometer is fixed tuned to measure four volatile species—CO, CH₃OH, NH₃ and three isotopes of water, H₂¹⁶O, H₂¹⁷O and H₂¹⁸O. The MIRO experiment will use these species as probes of the physical conditions within the nucleus and coma. The basic quantities measured by MIRO are surface temperature, gas production rates and relative abundances, and velocity and excitation temperature of each species, along with their spatial and temporal variability. This information will be used to infer coma structure and outgassing processes, including the nature of the nucleus/coma interface.     

Identification of C4H5, C4H4, C3H3 and CH3 radicals produced from the reaction of atomic carbon with propene: Implications for the atmospheres of Titan and giant planets and for the interstellar medium

We observed the products C₄H₅, C₄H₄, C₃H₃ and CH₃ of the C(³P) + C₃H₆ reaction using product time-of-flight spectroscopy and selective photoionization. The identified species arise from the product channels C₄H₅ + H, C₄H₄ + 2H and C₃H₃ + CH₃. Product isomers were identified via measurements of photoionization spectra and calculations of adiabatic ionization energy. Product C₄H₅ probably involves three isomers HCCCHCH₃, H₂CCCCH₃ and H₂CCCHCH₂. In contrast, products C₄H₄ and C₃H₃ involve exclusively HCCCHCH₂ and H₂CCCH, respectively. Reaction mechanisms are unraveled with crossed-beam experiments and quantum-chemical calculations. The ³P carbon atom attacks the π orbital of propene (C₃H₆) to form a cyclic complex c-H₂C(C)CHCH₃ that rapidly opens the ring to form H₂CCCHCH₃ followed by decomposition to HCCCHCH₃/H₂CCCCH₃/H₂CCCHCH₂ + H and H₂CCCH + CH₃; the corresponding branching ratios are 7:5:10:78 predicted with RRKM calculations at collision energy 4 kcal mol^?1. Nascent C₄H₅ with enough internal energy further decomposes to HCCCHCH₂ + H. Ratios of products C₄H₅, C₄H₄ and C₃H₃ are experimentally evaluated to be 17:8:75. This work provides a comprehensive look at product channels of the title reaction and gives implications for the formation of hydrocarbons in extra-terrestrial environments such as Titan and carbon-rich interstellar media. We suggest that the title reaction, hitherto excluded in any chemical networks, needs to be taken into account at least in the atmosphere of Titan and carbon-rich molecular clouds where rapid neutral–neutral reactions are dominant and carbon atoms and propene are abundant.     

A photo-chemical method for the production of olivine nanoparticles as cosmic dust analogues

This paper describes a new experimental method to synthesise metal silicate particles in the laboratory with compositions and structures which reflect those likely to form in planetary atmospheres and in relatively cool regions of oxygen-rich stellar outflows. Fe–Mg-silicate nanoparticles of olivine composition were produced by the photo-oxidation of a mixture of Fe(CO)₅, Mg(OC₂H₅)₂ and Si(OC₂H₅)₄ vapours in the presence of O₃ at room temperature and atmospheric pressure. Transmission electron microscope X-ray and electron energy loss analysis of the particles from a number of experiments run with different precursor vapour mixture ratios show that Mg_2xFe_2?2xSiO₄ particles can be produced ranging from x = 0 to 1, where x is linearly proportional to the ratio of Mg(OC₂H₅)₂/(Fe(CO)₅ + Mg(OC₂H₅)₂). Electronic structure calculations with hybrid density functional/Hartree–Fock theory are then used to explore the pathways involved in producing olivine particles from the FeO₃, MgO₃ and SiO₂ produced from the photolysis of the organometallic precursors in O₃. These calculations indicate that highly exothermic reactions lead to the formation of Mg₂SiO₄, MgFeSiO₄ and Fe₂SiO₄ molecules, which then polymerize. An alternative pathway, also strongly favoured thermodynamically, is the polymerization of MgSiO₃ and FeSiO₃ to form pyroxenes, which then undergo structural rearrangement to olivine and silica phases. The implications for metal silicate formation in planetary atmosphere and stellar outflows are then discussed.     

Chandra X-ray observations of two unusual BAL quasars

We report sensitive Chandra X-ray non-detections of two unusual, luminous Iron Low-Ionization Broad Absorption Line Quasars (FeLoBALs). The observations do detect a non-BAL, wide-binary companion quasar to one of the FeLoBAL quasars. We combine X-ray-derived column density lower limits (assuming solar metallicity) with column densities measured from ultraviolet spectra and CLOUDY photoionization simulations to explore whether constant-density slabs at broad-line region densities can match the physical parameters of these two BAL outflows, and find that they cannot. In the “overlapping-trough” object SDSS J0300+0048, we measure the column density of the X-ray absorbing gas to be N_H ? 1.8 × 10²⁴ cm^?2. From the presence of Fe ii UV78 absorption but lack of Fe ii UV195/UV196 absorption, we infer the density in that part of the absorbing region to be n_e ? 10⁶ cm^?3. We do find that a slab of gas at that density might be able to explain this object’s absorption. In the Fe iii-dominant object SDSS J2215–0045, the X-ray absorbing column density of N_H ? 3.4 × 10²⁴ cm^?2 is consistent with the Fe iii-derived N_H ? 2 × 10²² cm^?2 provided the ionization parameter is log U > 1.0 for both the n_e = 10¹¹ cm^?3 and n_e = 10¹² cm^?3 scenarios considered (such densities are required to produce Fe iii absorption without Fe iiabsorption). However, the velocity width of the absorption rules out its being concentrated in a single slab at these densities. Instead, this object’s spectrum can be explained by a low density, high ionization and high temperature disk wind that encounters and ablates higher density, lower ionization Fe iii-emitting clumps.     

The gas production of Comet 9P/Tempel 1 around the Deep Impact date

The target of the Deep Impact space mission (NASA), Comet 9P/Tempel 1, was observed from two nights before impact to eight nights after impact using the FORS spectrographs at the ESO VLT UT1 and UT2 telescopes. Low resolution optical long-slit spectra were obtained to study the evolution of the gas coma around the Deep Impact event. Following first results of this observing campaign on the CN and dust activity [Rauer, H., Weiler, M., Sterken, C., Jehin, E., Knollenberg, J., Hainaut, O., 2006. Astron. Astrophys. 459, 257-263], this work presents a study of the complete dataset on CN, C₂, C₃, and NH₂ activity of Comet 9P/Tempel 1. An extended impact gas cloud was observed moving radially outwards. No compositional differences between this impact cloud and the undisturbed coma were found as far as the observed radicals are concerned. The gas production rates before and well after impact indicate no change in the cometary activity on an intermediate time scale. Over the observing period, the activity of Comet 9P/Tempel 1 was found to be related to the rotation of the cometary nucleus. The rotational lightcurve for different gaseous species provides indications for compositional differences among different parts of the nucleus surface.     

The light curve of the comet 9P/Tempel 1: Temporal evolution from 1867 till 2005

The light curves of the periodic comet 9P/Tempel 1 obtained during its apparitions in 1972, 1983, 1994, and 2005 have been constructed and studied. The values of the photometric parameters H ₀, n, and H ₁₀ have been determined for these apparitions; and secular variations of the comet’s brightness have been studied. The light curve of the comet obtained close to the moment of the artificial impact agrees well with the change in the production rate of water molecules. The presented results are important from the point of the possible change in the photometric parameters induced by the artificial impact and the long-term evolution of the cometary core activity.     

Mineral reaction buffering of Venus’ atmosphere: A thermochemical constraint and implications for Venus-like planets

The equilibrium suggested as a buffer for CO₂ in the Venus atmosphere, CaCO₃ + SiO₂ = CaSiO₃ + CO₂, cannot act as a buffer at the Venus surface/troposphere – the pressure–temperature slope of the equilibrium and that of the atmosphere (dry adiabat with significant greenhouse heating) do not provide buffering capacity (if indeed CaCO₃ were present). Instead, perturbations to T or P(CO₂) can produce catastrophic expansion or collapse of the atmosphere. This instability can be generalized to all devolatilization reactions that produce a radiatively active gas in a planetary atmosphere dominated by such gases, and gives a simple thermochemical criterion for whether a reaction could buffer such an atmosphere. Simple decarbonation reactions fail this criterion, suggesting that the abundance of CO₂ in a CO₂-dominated atmosphere cannot be buffered by chemical reactions with the surface; a similar conclusion holds for the abundance of H₂O in an H₂O-dominated (steam) atmosphere. Buffering of minor gases is more likely; a mineral buffer equilibrium for SO₂ proposed for Venus, FeS₂ + CO₂ = Fe₃O₄ + SO₂ + CO, passes the thermochemical criterion, as does a reaction involving Ca sulfate. These inferences can be generalized to atmospheres in ‘moist’ adiabatic equilibria, and to extrasolar Venus-like planets, and will help in interpreting the compositions of their atmospheres.     

Upper limits for H2SO4 in the mesosphere of Venus

Rapid temporal variability of SO₂ and SO in the Venus 85–100 km mesosphere (Sandor, B.J., Clancy, R.T., Moriarty-Schieven G.H. [2007]. Bull. Am. Astron. Soc. 39, 503; Sandor, B.J., Clancy, R.T., Moriarty-Schieven, G.H., Mills, F.P. [2010]. Icarus 208, 49–60) requires in situ sources and sinks for these molecules. While many loss mechanisms are recognized, no process for in situ production is known. Observational investigations to find, or constrain other potential sulfur reservoirs offer one method toward understanding the applicable photochemistry. Here, we report upper limits for gas-phase H₂SO₄ (sulfuric acid) abundances in Venus’ 85–100 km upper mesosphere, derived from 16 ground-based sub-mm spectroscopic observations in the period 2004–2008. Unlike the ubiquitous sulfuric acid solid/liquid aerosol, the gas phase would be photochemically active, potentially both source and sink for SO and SO₂. H₂SO₄ is retrieved from sub-mm lines located in the same bandpass as the SO₂ and SO lines described by Sandor et al. (Sandor, B.J., Clancy, R.T., Moriarty-Schieven, G.H., Mills, F.P. [2010]. Icarus 208, 49–60). H₂SO₄ upper limits reported here are thus simultaneous and spatially coincident with measurements of SO₂ and SO, providing for analysis of the three sulfur species collectively. The average H₂SO₄ abundance over 16 observations is 1 ± 2 ppb (i.e. <3 ppb). Upper limits for individual observations range from 3 to 44 ppb, where quality of the observing weather is the dominant constraint on measurement precision. The sum of H₂SO₄, SO₂ and SO varies widely. In one comparison, the sum [H₂SO₄ + SO₂ + SO] measured on one date differs by 10-σ from the sum measured 2 months later. We conclude that upper mesospheric sulfur atoms are not conserved among the three molecules, that H₂SO₄ is not a significant sulfur reservoir for balancing the observed variations of [SO₂ + SO], and is not relevant to the (still unknown) photochemistry responsible for observed behavior of SO₂ and SO. Having ruled out H₂SO₄, we infer that elemental sulfur is the most probable candidate for the needed third reservoir.     

A new absolute magnitude calibration with 2MASS for cataclysmic variables

Using reliable trigonometric measurements, we find that the absolute magnitude of cataclysmic variables depends on the orbital period and de-reddened (J − H)₀ and (H − K _s)₀ colours of 2MASS (Two Micron All Sky Survey) photometric system. The calibration equation covers the ranges 0.032^d < P_orb ⩽ 0.454^d, −0.08 < (J − H)₀ ⩽ 1.54, −0.03 < (H − K_s)₀ ⩽ 0.56 and 2.0 < M_J < 11.7; It is based on trigonometric parallaxes with relative errors of (σ_π/π) ⩽ 0.4. By using the period-luminosity-colours (PLCs) relation, we estimated the distances of cataclysmic variables with orbital periods and 2MASS observations and compared them with distances found from other methods. We suggest that the PLCs relation can be a useful statistical tool to estimate the distances of cataclysmic variables.     

Suggestion for the search of H2CC in cool cosmic objects

The transition 1₁₁ ? 1₁₀ at 4.829 GHz of formaldehyde (H₂CO) was the first one showing the anomalous absorption, i.e., the absorption against the cosmic microwave background. Anomalous absorption is an unusual phenomena. Structure of H₂CC is very similar to that of H₂CO and H₂CS. Both H₂CO and H₂CS have already been identified in a number of cosmic objects. Though H₂CC is not yet identified in the cosmic objects, we propose that H₂CC may be identified in cool cosmic objects through its transition 1₁₁ ? 1₁₀ at 4.85 GHz in anomalous absorption.     

Pressure dependent trace gas trapping in amorphous water ice at 77 K: Implications for determining conditions of comet formation

The nature of cometary volatile materials is subject to debate. Theoretical models of cometary nuclei and laboratory studies suggest that these objects could be made of amorphous water ice in addition to other volatile molecules and refractory grains. This water ice structure has the ability to encapsulate the gases of surrounding environment, reflecting the physical and chemical conditions during their deposition. Therefore, the knowledge of the chemical composition of volatile molecules trapped in amorphous water ice provides a tool for probing the formation environment of cometary ice grains. Experimental studies of gas trapping efficiency in amorphous water ice have been previously conducted mostly under kinetic conditions, where dynamic pumping and temperature gradients prevented rigorous calibrations. In this work, we investigated the trapping efficiencies of Ar, CO, CH₄, Kr and N₂ by depositing water vapor as ice in the presence of trace gases in a volume submerged in liquid nitrogen at 77 K. The gas trapping efficiencies were determined simply by monitoring the pressure difference of the trace gases before and after the deposition of a known amount of water molecules as amorphous ice.Our results show that the trapped gas to water molecule ratio in amorphous ice is controlled primarily by the partial pressure of the gas during water ice deposition, and is independent of the ice deposition rate as well as the gas to water ratio in the vapor phase. The trapping efficiencies of gases decrease in the order of Kr > CH₄ > CO > Ar > N₂ in accordance with previous studies. Assuming that the water ice structure of comets is at least partially amorphous water ice at the time of their formation, these results suggest that the total pressure and composition of the surrounding environment of amorphous ice formation are significant controlling factors of trace gas concentrations in cometary ice. This further indicates that the evolution of the solar nebula and timing of cometary ice condensation can also be important parameters in linking the volatile contents of comets and their formation process.     

Hβ line width and the UV–X-ray spectra of luminous AGN

The width of the broad Hβ emission line is the primary defining characteristic of the NLS1 class. This parameter is also an important component of Boroson and Green’s optical “Eigenvector 1” (EV1), which links steeper soft X-ray spectra with narrower Hβ emission, stronger Hβ blue wing, stronger optical Fe II emission, and weaker [O III] λ5007. Potentially, EV1 represents a fundamental physical process linking the dynamics of fueling and outflow with the accretion rate. We attempted to understand these relationships by extending the optical spectra into the UV for a sample of 22 QSOs with high quality soft-X-ray spectra, and discovered a whole new set of UV relationships that suggest that high accretion rates are linked to dense gas and perhaps nuclear starbursts. While it has been argued that narrow (BLR) Hβ means low Black Hole mass in luminous NLS1s, the C IV λ1549 and Lyα emission lines are broader, perhaps the result of outflows driven by their high Eddington accretion rates. We present some new trends of optical-UV with X-ray spectral energy distributions. Steeper X-ray spectra appear associated with stronger UV relative to optical continua, but the presence of strong UV absorption lines is associated with depressed soft X-rays and redder optical–UV continua.     

Astrophysical and structural parameters of the open clusters NGC 6866, NGC 7062, and NGC 2360

We derive astrophysical and structural parameters of the poorly studied open clusters NGC 6866, NGC 7062, and NGC 2360 based on filtered 2MASS (J, J ? H) diagrams, and stellar radial density profiles. The field star decontamination technique is utilised for selecting high-probability cluster members. The E(B ? V) reddening values of the three clusters derived from 2MASS JHK_s agree with those inferred from UBV and uvby ? β photometries. We find that the core mass function slopes are flatter than the halo’s for the three clusters. The large core and cluster radii of NGC 6866 and NGC 2360 indicate an expanded core, which may suggest the presence of stellar mass black-holes. NGC 2360 is located in the third quadrant (? = 229°.80), where Giant Molecular Clouds are scarce that, together with its relatively large mass (～1800 m_⊙), might explain its longevity (～1.8 Gyr) in the Galaxy.     

Explaining the redox imbalance between the H and O escape fluxes at Mars by the oxidation of methane

From a comparison between the different observations of Martian methane existing today, including the new TES methane maps (Fonti and Marzo, 2010), we show that all sets of data are globally consistent with each other, and that a well definite seasonal cycle of methane has been at work for at least 10 yr. With a simple model of the balance between the loss fluxes of H and O, using up-to-date values of the escape fluxes, we show that the long-standing enigma of the imbalance between H and O escape fluxes may be solved by assuming that the missing sink of oxygen is the oxidation of methane. If no H₂ is released together with CH₄, a good agreement is found between the present CH₄ flux and the value imposed by the balance between H and O escape fluxes, an average over the last ≈10³ yr. If H₂ is released together with CH₄, as expected if CH₄ originates in serpentinization, the average level of CH₄ during the last 10³ yr should have been at least ten times lower than the present one. The lack of present H₂ release could suggest a long-term storage of methane in the subsurface under the form of clathrates, whereas H₂ has been lost to the atmosphere shortly after being produced. We suggest that the thin layer of CO₂ ice covering the permanent southern polar cap could result from the release of methane since the end of the last obliquity transition (time scale: 1 Myr), at an average rate of 0.1 Mt yr^?1, consistent with the values derived from: (i) the present observations of methane (time scale: 10 yr), (ii) the estimate from the observed imbalance between the H and O escape fluxes (time scale: 1 kyr). If so, the present release of methane from subsurface clathrates would have acted at a similar rate since at least 3 Myr.