Geochemistry of waters in the Valley of Ten Thousand Smokes region, Alaska

Meteoric waters from cold springs and streams outside of the 1912 eruptive deposits filling the Valley of Ten Thousand Smokes (VTTS) and in the upper parts of the two major rivers draining the 1912 deposits have similar chemical trends. Thermal springs issue in the mid-valley area along a 300-m lateral section of ash-flow tuff, and range in temperature from 21 to 29.8°C in early summer and from 15 to 17°C in mid-summer. Concentrations of major and minor chemical constituents in the thermal waters are nearly identical regardless of temperature. Waters in the downvalley parts of the rivers draining the 1912 deposits are mainly mixtures of cold meteoric waters and thermal waters of which the mid-valley thermal spring waters are representative. The weathering reactions of cold waters with the 1912 deposits appear to have stabilized and add only subordinate amounts of chemical constituents to the rivers relative to those contributed by the thermal waters. Isotopic data indicate that the mid-valley thermal spring waters are meteoric, but data is inconclusive regarding the heat source. The thermal waters could be either from a shallow part of a hydrothermal system beneath the 1912 vent region or from an incompletely cooled, welded tuff lens deep in the 1912 ash-flow sheet of the upper River Lethe area.Bicarbonate-sulfate waters resulting from interaction of near-surface waters and the cooling 1953–1968 southwest Trident plug issue from thermal springs south of Katmai Pass and near Mageik Creek, although the Mageik Creek spring waters are from a well-established, more deeply circulating hydrothermal system. Katmai caldera lake waters are a result of acid gases from vigorous drowned fumaroles dissolving in lake waters composed of snowmelt and precipitation.     

Chemical and isotopic changes in the hydrology of the tauhara geothermal field due to exploitation at wairakei

Depressurisation of the Tauhara field due to massive withdrawal of deep chloride water from the adjacent Wairakei field for geothermal power has caused considerably hydrological and chemical changes at Tauhara. In the undisturbed state (1962), deep chloride water discharged as hot and boiling dilute chloride springs on the east and west flanks of the field (the Terrace and Spa areas, respectively), while steam from the two-phase zone of the deep system produced by absorption into near-surface groundwater, steam-heated sulphatebicarbonate waters and by mixing with chloride water, chloride-sulphate waters. By 1978–1981 the chloride waters had stopped discharging on the western flank, the steam flow towards the surface had greatly increased (by 5–10 fold) increasing the volume and temperature of the steam-heated waters, but the dilute chloride waters of the Terrace area had changed very little. Silica concentrations in the near-surface waters appear to be controlled by the solubility of amorphous silica, which is present in the surface zone rocks (e.g., Taupo pumice breccias). The increased steam flow led to enrichment in the ¹³O and D contents of the steam-heated waters by loss of secondary steam and enlargement of the area and intensity of steaming ground, the latter accompanied by hydrothermal eruptions in 1974 and 1981. Generation of the steam-heated waters has been modelled using mass, heat and isotope balances. The model is consistent with observed heat and cold groundwater flows and requires that a large proportion of the heat from adsorbed primary steam is released as secondary steam. Tritium contents show that the steam-heated waters have a mean residence time of 50–100 years. In the future, invasion of the deep system by cooler surface waters may reduce steam flow and lower surface aquifer temperatures.     

Isotope composition of groundwater in the Azov-Kuban and Eastern Pre-Caucasian artesian basins

Studying results of the groundwater isotope composition in the Neogene-Quaternary and Mesozoic sediments of the Azov-Kuban and Eastern Pre-Caucasian artesian basins have shown in the Pliocene sediments a rather wide distribution of ??relict?? groundwater, formed because of melting of the Late Pleistocene Caucasian glaciers, as well as of groundwater formed due to its mixing with the meteogenic waters of the subsequent Holocene infiltration cycles. Also, the areas are revealed in the Lower-Miocene sediments where meteogenic waters are mixed with sedimentation waters, while in the Mesozoic formations??the areas where into the sedimentation waters wedge-shaped meteogenic waters of Pleistocene and Holocene infiltration periods are intruded.     

The distribution of trace elements in surface continental waters and the character of their migration in water

The results of studying the elemental composition of surface continental waters in the European Russia from tundra to arid zone are discussed. The relative concentrations of elements in the solid residue of waters from various natural-climatic zones are evaluated, and the enrichment or dispersion of continental waters by these elements are analyzed as compared with their clarkes in the rocks that occur in the catchment areas. The coefficients of migration in water are evaluated, and the major elements with respect to which surface waters enrich under anthropogenic load are identified. The territorial distribution of higher concentrations of the most hazardous elements in waters of lakes is characterized.     

On the ecology of ciliates in riverwaters: The evaluation of water quality via ciliates and filamentous bacteria

Since sewage treatment plants are most effective in Switzerland, the micro-benthic communities in receiving running waters have changed considerably. From January 1980 to September 1981 the periphyton communities in 13 Swiss streams and rivers were monthly investigated. The NH₄-N concentration in these waters varied between 0.015 and 1.0 mg/l. Four typical communities of microorganisms were found:In unpolluted running waters mainly small vagile ciliates were abundant; in slightly polluted waters peritricha (in the presence of bacteria) were found; in moderatly polluted waters peritricha in combination of few hymenostomata and Sphaerotilus could grow when bacteria and some degredable organic material where present; in polluted waters the well-known Spaerotilus-community (after Liebmann) could be found.The microscopic as well as the macroscopic aspect should be considered to qualify the degree of pollution in streams and rivers.     

用氚讨论中国西部新疆干旱区的水循环率

Tritium concentrations are used to trace water circulation in the Urumqi and Turfan basins in the Xinjiang, western China. Tritium analyses were made for 77 water samples of river waters, groundwaters, spring waters, lake waters and glacier ice collected in summers in 1992 and 1994. The tritium concentrations in the waters are in a wide range from 0 to 125 TU, most of which are considerably high compared with those of most waters in Japan, because tritium levels in precipitation in the area are over ten times as high as those in Japan. River waters originating in glacier regions contain melt glacier, the proportion of which is over 0.5 to river water. The mean resi-dence time of circulating meteoric water in the mountain regions is estimated to be about 15 years. Most groundwaters and spring waters in the flat regions are mainly derived from river waters originating in glacier regions. The groundwater of greatest tritium concentrations in wells in Urumqi City is derived from Urumqi River about 25 years ago. It takes several ten years for river water to pass the underground to many springs. Some groundwaters and spring waters have taken a long time more than 40 years to travel under the ground. Enrichment of tritium in lake water by evaporation is considered to estimate the contribution of groundwater flow to the recharge of lake. Various contributions of groundwater to lakes are inferred for the various type of salinity in closed or semi-closed lakes. The inflow rates of groundwater to salt lakes are small as against fresh water lakes.     

The distribution of dissolved lead in the coastal waters of the East China Sea

The distribution of dissolved lead in the coastal waters of the East China Sea was investigated seasonally. The average concentrations in surface waters during the spring and autumn were 0.52 nM and 0.27 nM, respectively. In the spring, the concentration of dissolved Pb in the surface waters and bottom waters ranged from 0.13 to 1.86 nM and from 0.15 to 0.94 nM, respectively. For both the surface water and the bottom water, the highest values were observed at the Yangtze River Estuary. Seasonal variability of D-Pb between spring and autumn in the ECS was observed. These results suggested that riverine inputs and atmospheric inputs may be the main sources of lead in this area, while adsorption and co-precipitation on suspended particles at the river estuary and biological process may be the major sinks.     

西藏羊卓雍错流域水体水质评价及主要污染因子

水质是流域生态系统的重要指标,水质评价则是开展流域水体污染防治等工作的基础.基于2010-2014年羊卓雍错流域湖泊、河流水质及2012-2014年流域居民饮用井水、自来水水质监测资料,结合单因子污染评价法和内梅罗污染指数法,对流域水质现状进行分析和评价.结果表明,12处地表水体中,羊卓雍错和巴纠错受中度污染,其他水体清洁或尚清洁,硒及氟化物为主要污染因子;9处居民饮用水体中,自来水水质明显好于井水,但也仅有3处自来水达清洁标准,硒、铝及硝酸盐为主要超标项.污染因子通过水-土-植被-动物系统破坏流域生态环境、阻碍农业生产发展,并直接或间接影响人类身体健康.因此,必须做好流域环境的综合整治、控制农业面源污染、完善饮用水基础设施建设,同时继续加强水质监测.     

Dissolved trace metals in the surface waters of Puget Sound

Employing clean and quantitative techniques, a marine monitoring programme succeeded in detecting large surface elevations in the concentrations of dissolved Cu, Zn and Pb in the marine surface waters of Puget Sound adjacent to Seattle and Tacoma, Washington. Physical mixing with cleaner waters was the controlling factor in reducing the dissolved concentrations of Cu downstream of these contaminated regions. Comparisons between Puget Sound waters and coastal waters adjacent to Puget Sound suggest that a portion of this Cu, Zn and Pb pollution is being advected out of Puget Sound. The low Ni and Cd concentrations found in this study indicate that these trace metals are not a significant pollution problem in the main basin of Puget Sound.     

Macrobenthic community structure in the northern Saudi waters of the Gulf, 14 years after the 1991 oil spill

The 1991 Gulf oil spill heavily impacted the coastal areas of the Saudi waters of the Arabian Gulf and recent studies have indicated that even 15 years after the incident, macrobenthos had not completely recovered in the sheltered bays in the affected region such as, Manifa Bay. This study investigates the community conditions of macrobenthos in the open waters in one of the impacted areas, Al-Khafji waters, about 14 years after the spill. Diversity measures and community structure analyses indicate a healthy status of polychaete communities. The BOPA index reveals that oil sensitive amphipods were recolonized in the study area. This confirms that the benthic communities of the oil spill impacted area had taken only <14 years to recover in the open waters of the impacted areas. The study also reveals the existence of three distinct polychaete communities along the depth and sediment gradients.     

Geochemical study on natural gas and water discharges in the Southern Latium (Italy): circulation, evolution of fluids and geothermal potential in the region

The waters discharged in Southern Latium (south of Rome) are mainly meteoric in origin. Two types of circulation occur in the region: one infiltrates the carbonate sediments outcropping in the area and emerges from fractures along their borders, the other consists of waters that infiltrate and circulate essentially within the Albani volcanic rocks.The first type produces either alkaline earth bicarbonate-sulfate waters or, if they mix with fossil marine waters or interact with recent marine sediments, alkaline-chloride waters (on the Pontina Plain). The chemistry of the waters produced by the second type of circulation (alkaline earth-bicarbonate or alkaline-bicarbonate) is strictly related to their gaseous phases, which consist for the most part of the CO₂ produced at depth.Silica and gas geothermometers, whose results correlate well, indicate that low enthalpy fluids (≤ 80°C) are present throughout the study area, with the exception of the northwestern part where medium enthalpy fluids (150°C) also appear.     

滇池福保湾间隙水氮磷分布及其与底泥微生物和磷酸酶相互关系

在滇池福保湾不同区域应用Peeper(渗析膜式)技术,分析了底泥间隙水NH4 -N、Po43--p的垂向分布特征和近表层10cm内底泥的微生物活性(FDA)、碱性磷酸酶活性(APA),并对它们之间的相互关系进行了统计分析.结果表明,NH4 -N和Po43--p浓度自上覆水向下层间隙水呈先升后降趋势,反映它们有自间隙水向上覆水扩散的潜在危害;底泥有机质(Loss-on-Ignion,LOI)、APA和FDA活性也有从表层底泥向下层逐步降低的趋势.在空问分布上,Po43--p浓度变化为河口区>湾心区>西部沿岸区>东部沿岸区,与沉积物中LOI、APA和FDA活性的大小顺序基本相同.间隙水NH4 6-N浓度与表层10cm内底泥的APA和FDA活性具有显著正相关性(α＝0.01).Po43--p浓度与底泥APA和FDA活性具有负相关性.但相关系数很低.     

Hydrogeochemistry of the Simav geothermal field, western Anatolia, Turkey

Thermal waters hosted by Menderes metamorphic rocks emerge along fault lineaments in the Simav geothermal area. Thermal springs and drilled wells are located in the Eynal, Çitgöl and Na a locations, which are part of the Simav geothermal field. Studies were carried out to obtain the main chemical and physical characteristics of thermal waters. These waters are used for heating of residences and greenhouses and for balneological purposes. Bottom temperatures of the drilled wells reach 163°C with total dissolved solids around 2225 mg/kg. Surface temperatures of thermal springs vary between 51°C and 90°C. All the thermal waters belong to Na–HCO₃–SO₄ facies. The cold groundwaters are Ca–Mg–HCO₃ type. Dissolution of host rock and ion-exchange reactions in the reservoir of the geothermal system shift the Ca–Mg–HCO₃ type cold groundwaters to the Na–HCO₃–SO₄ type thermal waters. Thermal waters are oversaturated at discharge temperatures for aragonite, calcite, quartz, chalcedony, magnesite and dolomite minerals giving rise to a carbonate-rich scale. Gypsum and anhydrite minerals are undersaturated with all of the thermal waters. Boiling during ascent of the thermal fluids produces steam and liquid waters resulting in an increase of the concentrations of the constituents in discharge waters. Steam fraction, y, of the thermal waters of which temperatures are above 100°C is between 0.075 and 0.119. Reservoir pH is much lower than pH measured in the liquid phase separated at atmospheric conditions, since the latter experienced heavy loss of acid gases, mainly CO₂. Assessment of the various empirical chemical geothermometers and geochemical modelling suggest that reservoir temperatures vary between 175°C and 200°C.     

An evaluation of the ecohydrological separation hypothesis in a semiarid catchment

The ecohydrological separation hypothesis states that transpiration through plants and drainage to streams and groundwater are sourced from separate soil water pools, which possess distinct isotopic signatures. Evidence for ecohydrological separation has relied on the globally ubiquitous observation that plant water and draining water are isotopically distinct. We evaluated the ecohydrological separation hypothesis in the Dry Creek Experimental Watershed in the semiarid, snow‐dominated landscape of southwest Idaho, USA. We found that plant water is indeed isotopically distinct from streams and groundwater. However, we were unable to track those waters to subsurface soil waters, nor were we able to relate soil water mobility to isotopic composition. Soil waters of different mobility can be isotopically similar, and isotopic distinction in soil water can occur for reasons not related to mobility. We suggest that isotopic distinction between root‐absorbed and draining waters may not be an appropriate indicator of ecohydrological separation of soil waters, and that hydrologic explanations for such isotopic distinction may not be sufficient.     

Zonal features of the formation of water chemistry in small lakes in European Russia

Appreciable observational data were used to reveal zonal features of the formation of the chemical composition of waters in small lakes on the territory of European Russia along a transect from tundra to the arid zone. Inter-zonal variability in the parameters of the chemical composition of waters is determined. Zonal differentiation according to hydrochemical parameters is substantiated. The main differentiating elements of the chemical composition of waters in different natural-climatic zones are distinguished. The contribution of the main natural and anthropogenic factors, determining the present-day processes of water formation is analyzed. Different degrees of the effect of non-zonal factors (including anthropogenic ones) on the formation of the chemical composition of lake waters in the humid and arid zones are demonstrated.     

滇池蓝藻对沉水植物生长的影响

本文通过模拟生态系统和大型试验围隔,研究了蓝藻(Cycanobateria)胁迫下的蓖齿眼子菜(Potamogeton pectinatus)和竹叶眼子菜(Potamogeton malaianus)生长情况．模拟生态系统研究结果表明,蓖齿眼子菜生长受蓝藻的影响不大,其在有大量蓝藻胁迫的水体中生长22d后,生物量为试验初始时的91．6％,在没有蓝藻胁迫的水体中,其生物量增加了27．7％,差异不显著;而竹叶眼子菜生长受蓝藻影响显著,在有蓝藻胁迫的水体中生长22d后,其生物量下降了57．1％,在没有蓝藻胁迫的水体中,其生物量增加了24．1％．野外10hm^2大型围隔栽种试验结果显示,在有蓝藻胁迫条件下蓖齿眼子菜生长良好,经过5个月生长其覆盖率达到60％,而竹叶眼子菜几乎全部死亡．综合上述两方面试验结果表明蓖齿眼子菜耐受蓝藻胁迫的能力比竹叶眼子菜强．     

PCB and HCB in the sediments and waters of the Tiber estuary

The contamination by polychlorinated biphenyls (PCB) and hexachlorobenzene (HCB) in sea waters and sediments of Tiber River estuary has been studied in 1976 and 1977.PCBs have been detected in all the samples analysed at mean levels of 0.297 ppb (1976) and 0.135 ppb (1977); these levels are much higher than those proposed as acceptable for surface waters. Contamination increases with increasing distance from the shore.HCB has been identified in only 16% of the water samples analysed and it was found absent in sediment samples.The results are discussed relative to both the levels of PCB in other sea waters and the toxicity of these products to the aquatic animals.     

On the disposal of contaminated milk in coastal waters.

Estimates have been made of the reduction in dissolved oxygen levels in coastal waters that would result from the disposal of contaminated milk following a radiological accident. Two contrasting sites were chosen: the Bristol Channel near Hinkley Point and the coast of Cumbria near Sellafield. The results suggest that the dilution would be sufficiently strong near Hinkley Point, due to vigorous tidal mixing, that the impact on the DO levels of the coastal waters would be negligible. However, at both Sellafield and Heysham the disposal of milk could result in a reduction of the DO by 1-2 mg l(-1). In contrast to shallow estuarine waters, the recovery of oxygen levels due to the effects of re-aeration through surface gas exchange is unlikely to be significant due to the depth of the coastal waters. However, the recovery of the dissolved oxygen levels to ambient conditions following the completion of the discharge would occur on a time scale of about 17 days due to mixing of the DO deficit plume into the surrounding waters.     

Geochemical studies on the Feshcha Springs,Dead Sea basin

The Feshcha springs issue in a 4 km long strip on the Dead Sea shores. They constitute two separate groups: a) T-N waters, similar in their salt composition, temperature and radon content to the many other members of the Rift Valley “Tiberias-Noit water association”. The hydrologic, radon, tritium and carbon-14 indicate they are mixtures of recent meteoric waters with ancient (trapped) T-N waters of an age of at least 18000 years. b) Z-Y waters which, like other members of the Dead Sea basin “Zohar-Yesha water group”, originate by a mixing of T-N waters with Dead Sea waters. This is seen in the chemical compositions and is confirmed by the oxygen-18 and deuterium data.     

Evaluation of the possibility for phytoplankton monitoring frequency reduction in the coastal waters of the Community of Valencia, in the scope of the Water Framework Directive

The Water Framework Directive, under the European Legislation, requires that all European waters, should reach a good ecological status by 2015. To achieve this goal, a phytoplankton monitoring network with monthly water samplings was established to evaluate the ecological quality, in the coastal waters of the Community of Valencia, and the collected data have allowed us to study the efficiency of the monthly campaigns of the monitoring network. With the results obtained in this research, we have designed a new monitoring strategy for the coastal waters of Valencia that for certain water bodies can mean lower sampling frequency. The new monitoring policy provides results as reliable as the previous strategy and allows a precise ecological classification of water bodies at a lower cost. The methodologies we have developed can be used in other monitoring networks and are not limited by geographic location or by the type of water body.