生物固土用于防风固沙的研究进展

文章对近年来基于生物固土技术的防风固沙研究进行了回顾和分析。常用于防风固沙的生物过程包括基于微生物或酶诱导碳酸钙沉积（MICP或EICP）的矿化固土技术,加入黄原胶等生物高聚物作为辅助剂,可获得更好的固土效果。土壤风蚀过程中,除了风力本身,风携带的跃移颗粒对土的撞击,也是侵蚀破坏的重要因素,这在生物固化土风蚀试验中体现明显。生物固化防风固沙的处理过程简单易行,以尿素和钙盐作为处理材料,用细菌或脲酶作为催化诱导媒介,对土体进行单遍喷洒处理即可获得很好的抗风效果。室内抗风试验中,将风蚀速率与临界起动风速两个指标结合是较为合理的评估方法。在室内和现场条件下,表面贯入强度测试可用来快速测定处理效果和抗风性能。目前的现场试验研究表明,生物固化土中植物可以生长,但是极端条件下生长受限。为了将该方法推向实用,需要从多重侵蚀因子作用下的抗风力侵蚀能力、生态恢复能力和现场施工技术等方面进一步研究探索。     

无固相钻井液在吉林省油页岩勘探中的研制与应用

无固相聚合物钻井液是一种抑制性、防塌性能力强的钻井液体系。在对常用聚合物进行优选的基础上,用正交试验法确定了以聚乙烯醇（PVA）为主、有机与无机聚合物相复合、可用于实际生产的强抑制性无固相聚合物钻井液配方,探讨了钻井液中各组分的作用和钻井液的防塌机理。研制的无固相聚合物钻井液在吉林省农安和梅河口矿区两个油页岩勘探孔的实际应用中,取得了较好的技术经济效果。     

区域土壤污染普查监测点位布设方法探讨

以江苏无锡和镇江两地为例,比较了8 km×8 km网格和4 km×4 km网格两种布点方式下,所得到的土壤中11种无机元素（As、Cd、Cr、Cu、Hg、Mn、Ni、Pb、Se、V、Zn）以及4类有机污染物（有机氯农药、多环芳烃、多氯联苯和酞酸酯类）的监测结果。按顺序统计量排列,发现多数无机元素和有机污染物的含量,从最小值到90%值总体吻合,而在90%值以上,两种布点方式的调查测定值出现差异,说明对于污染物含量低的地区,8 km×8 km网格和4 km×4 km网格获得的结论基本一致,而污染物含量高的     

废弃泥浆合理处置技术分析

对钻孔废弃泥浆诱发的环境问题,应针对不同的废弃泥浆中污染物种类和浓度不同,采用不同的无害化处理技术。石油钻井废弃泥浆较多的采用固化法处理,亦有采用固液分离后分别对固相、液相进行二次处理;建筑施工废弃泥浆的处理为化学方法或化学加机械方法。对废弃的泥浆应实现高效率、低能耗的处理,并使泥浆处理产物可再利用。     

土壤有机无机复合体的研究进展

对土壤有机无机复合体结构模型、有机无机复合体与团聚体的关系、有机无机复合体的肥力特征等方面的最新研究成果进行了综合评述。现代测试技术和计算机技术的应用为土壤有机无机复合体的研究提供了新的研究途径,发展形成了腐殖质胶体、有机无机复合体及有机质-异源生物物质复合体的结构模型,在纳米化学水平和三维分子结构模型上重新认识和阐明土壤有机无机复合体的结构和功能;有机无机复合体是土壤改良剂、营养源和重金属或有机有毒污染物过滤器;应在土壤科学、环境科学和生态学中,重视有机物质与矿物质相互作用和结构模型研究,加强土壤有机无机复合体环境化学行为和颗粒迁移动力学的研究。     

水中有机污染物的超声处理技术发展研究

超声技术在处理水中有机污染物的应用近年来受到越来越多的关注。与常规处理方法相比,超声处理技术高效省时,对众多难处理有机污染物具有良好的降解作用。结合近年来超声技术处理水中有机污染物的研究进展,通过介绍超声降解有机污染物的原理、方法及其应用,最后对水中有机物的超声处理技术的发展趋势进行了展望,指出高效、省时的超生空化技术...     

镍钛交联改性膨润土处理工业废水的实验

以钠基膨润土为原料制备了镍钛无机交联、有机交联系列改性膨润土，比较了二者对废水中化学需氧量（COD）、Cr（Ⅵ）、色度、浊度的去除效果，探讨了改性膨润土用量、pH值、搅拌时间等因素对实验的影响。结果表明：镍钛有机交联膨润土对COD和Cr（Ⅵ）的处理效果明显优于镍钛无机交联膨润土；二者对浊度和色度处理效果相当。其吸附行为符合Langmuir方程。     

基于脲酶诱导碳酸钙沉积固化土体的研究进展

诱导碳酸钙沉积的土体固化是近年来岩土工程领域新兴起的新型环保地基处理技术, 该技术利用产脲酶菌的微生物诱导碳酸钙沉积（Microbially Induced Calcite Precipitation,即MICP技术）或基于脲酶的酶诱导碳酸钙沉积（Enzyme Induced Carbonate Precipitation,即EICP技术）,将松散的土体颗粒胶结成为整体,达到提高土体抗剪强度的目的。与MICP技术相比,EICP技术不存在生物安全风险,无需考虑是否有氧,且可适用于更小粒径土体的处理,因此具备广阔的实际工程应用前景。文章从脲酶类型与来源、EICP固化土体处理方法及EICP固化土体强度增长等方面,对近20年基于脲酶诱导碳酸钙沉积固化土体的研究进行了回顾与总结。     

水中氯代烃单体碳同位素分析中预富集方法进展

高精度准确测定氯代烃单体碳同位素对示踪污染物来源,了解污染物的生物降解过程具有重要意义。在环境转化过程中,有机污染物的同位素组成可能是稳定不变的,也有可能发生改变。若污染物的同位素组成在迁移转化过程中不变,根据其同位素组成可以示踪污染物的来源;若同位素组成变化,根据同位素分馏结果,可以评价环境中有机污染物降解发生的可能性和程度。本文综述了固相微萃取、静态顶空进样、吹扫-捕集、多级串联技术等前处理方法与气相色谱-燃烧-同位素比值质谱仪(GC-C-IRMS)联用分析水中氯代烃单体碳同位素的研究进展,比较了分析方法的优缺点。液-液萃取较少用于水中氯代烃的单体同位素分析。静态顶空进样、固相微萃取、吹扫-捕集都是无溶剂富集技术,与GC-C-IRMS联用分析水中氯代烃单体同位素过程中不存在或存在小且恒定的可校正的同位素分馏,分析精度一般优于1‰,没有二次污染,降低了杂质干扰,提高了GC-C-IRMS的分辨率和分析精度,降低了检测限。从静态顶空进样、固相微萃取、吹扫-捕集,到多级串联等技术与GC-C-IRMS联用分析水中氯代烃单体同位素比值,检测限逐渐降低。目前,吹扫-捕集-GC-C-IRMS在分析水中氯代烃中应用最广泛,重现性好、检测限低。针内微萃取、管内微萃取、搅动棒吸附萃取和顶空进样吸附萃取等前处理方法与GC-C-IRMS仪联用具有一定的应用前景。     

污泥处理的固化/稳定化技术研究进展

固化/稳定化（S/S）是目前比较有效的一种污泥处置技术,是通过向污泥中添加固化剂材料,与污泥发生一系列的物理化学反应,提高污泥的力学强度和稳定污泥中的重金属污染物,从而达到污泥安全处置和资源化利用的目的,因此,探索高效、低廉和低碳的S/S技术一直是该领域的重点。根据近些年来国内外学者对该领域研究所取得的成果,着重从污泥的种类、固化剂种类、主要技术指标、关键影响因素及固化/稳定化机理等几个方面总结了该课题的研究现状及进展。得到以下主要认识:污泥按来源可分为河湖污泥、市政污泥和工业污泥3大类,由于不同来源污泥成分差别很大,处置方式也不尽相同;对于污泥的S/S处理,常用的固化剂可分为无机和有机两大类,且无机固化剂占主导,目前最流行的是水泥和石灰,还包括一些工业矿渣、黏土等作为辅助材料;S/S的优劣主要通过两个关键技术指标进行评价:固化体的无侧限抗压强度及浸出毒性;污泥的固化/稳定化效果主要受初始含水率、养护时间、固化剂种类、掺入量、pH值和Eh值等因素的影响;固化剂及其产物在污泥中形成骨架,并通过物理化学作用与污泥颗粒胶结和填充大的孔隙,从而起到固化增强作用;固化剂及其产物主要通过物理包裹、沉淀和吸附作用,将污泥中的有害物质封闭在固化体内,从而达到无害化、稳定化目的。最后,针对目前污泥S/S技术研究的不足,提出了今后该课题的研究重点及方向,主要包括:改善污泥的前期脱水效率、进一步掌握固化体的变形特性、开发针对多种重金属离子的综合S/S技术、建立重金属离子固定/溶出模型和迁移模型、研发新型固化剂等。     

玄武岩石材矿尾砂应用实验研究

针对玄武岩质建筑石材矿山产生的废弃物（碎石和尾砂）,依据环氧树脂有机胶黏剂的热固成型原理,使用环氧树脂乳液、有机固化剂和无机胶黏剂对废弃物进行复合石材试验.经物料均匀搅拌、模具成型、热压机施压和样品干燥、抛光、切边、修整等工序试制复合石材.通过测试复合样品的物理性能参数,其抗折强度超过天然石材商品,其他指标也基本达到相应建筑石材产品的质量标准.这种矿山废料的再利用方法,对减少矿山尾砂、治理环境污染、变废为宝以及增加企业经济收益有一定的作用.     

植物修复技术在污染治理中的应用现状

植物修复技术是利用活的植物对污染土、污染地下水等介质进行修复。植物对金属元素的净化机理是植物积累、根系过滤、植物根系对土的稳定作用;植物对有机物的净化机理是植物降解、生物刺激和植物的蒸发作用;此外植物的水力控制也是控制污染的主要途径。目前国外在利用植物修复卤代烃、农药、汽油、柴油、重金属、放射性物质、废旧炸药、处理污染填土淋滤液、利用植物分解处理空气中的污染物质或将氧化氮转化为氮气等多方面的研究已取得很多重要成果,而其中最为显著的是利用杂交植物对卤代烃污染地下水进行修复和研究利用转基因植物吸收土壤中的甲基汞。我国在植物修复技术方面的研究也取得重大成果,如利用凤眼莲修复污水中的某些农药、利用蜈蚣草叶片富集砷,利用印度芥菜对土壤中难溶态镉的吸收等。     

Heavy metal accumulation in soil after application of organic wastes

Municipal solid waste compost and cattle manure are used as organic fertilizers in agriculture and horticulture. These wastes, however, may also have some negative effects on the agricultural environment. This study investigates the effects of municipal solid waste compost of Kerman (MSC) and cattle manure (CM) on availability of the heavy metal in calcareous soil (extractable with EDTA) in greenhouse conditions. The MSC and CM were mixed thoroughly with soil at rates of 0%, 2%, and 4% of dry matter. After 90 days of incubation, the soil samples were analyzed. Addition of levels of each two organic wastes into soil significantly decreased the soil pH and increased the soil EC as compared with control (unamended soil).The available contents (EDTA-extractable) of Cd, Pb, Cu, Zn, and Cu in the soil samples were increased because of each two organic treatments applied. The heavy metal contents in the soil samples amended with MSC were more than CM. The heavy metal contents of organic wastes were well below the maximum allowed by USEPA. It is recommended that in Iran, the legal maximum permissible limit for heavy elements in organic wastes must be determined.     

The deterioration of the Nigerian environment: Problems of solid wastes disposal in the metropolitan Lagos

Proper management of solid wastes is a key to environmental sanitation. In recent times the quality of life in most of the cities of the developing world is being deminished by uncontrolled and poorly managed solid wastes in the urban environment. Lagos urban is a typical example. It must be acknowledged that although wastes from homes, businesses and institutions make up a small part of the total load of solid wastes generated in any urban environment they are certainly the most offensive and most dangerous to health when they accumulate near residential points. The quality of life in urban Lagos, Nigeria, with respect to indiscriminate dumping of uncollected solid wastes approximates an aesthetic disaster. This study is therefore designed to examine the problems of solid wastes disposal in Lagos, Nigeria and to provide data base against which effective solid wastes disposal system in the Nigerian capital city might be monitored and tested.Acknowledgement: I wish to thank members of the Environmental Problems and Effects class (1978/9 Session) Geography Department, University of Calabar for their assistance in collecting data for this study.The Year of the last valid population census in Nigeria.     

垃圾填土压缩特性的室内试验研究

在调查分析了典型生活垃圾填埋场成分组成的基础上,配制了9组具有不同初始物理力学性质的垃圾土,共54个试样,进行室内常规固结试验。试样有两种尺寸,用来对比试样尺寸的影响;着重分析了初始含水量W、初始孔隙比e0及易降解有机物含量B0对垃圾填土压缩性的影响。试样的初始孔隙比变化范围为：e0 为2.5～4.6;初始含水量w的变化为50 %～100 %;易降解有机物含量B0 为10.1 %～45.1 %。分析结果表明,压缩指数Cc为0.824 2～1.234 6;修正压缩指数 为0.165 9～0.243 6,与国内外相似研究的取值基本一致。提出了考虑垃圾填土初始物理参数的压缩参数建议取值方法,为指导工程实践提供参考。     

Coal fly ash and steel slag valorisation throughout a vitrification process

The aim of this research was to evaluate the feasibility of using the vitrification process as an alternative solution to the disposal of a coal fly ash and metallurgical slags in landfills. The starting wastes were characterised in terms of chemical, granulometric, mineralogical, and microstructural analysis. A selected batch composition composed by 58.5% fly ash, 31.5% metallurgical slag and 10.0 Na₂O% (wt%) was melted at 1450 °C and poured to obtain monolithic glass samples. The environmental behaviour of the starting wastes and the resulting glass was evaluated by standard leaching tests, which shows that vitrification leads to a stabilisation process in which the inorganic components of the wastes are immobilised throughout their incorporation into the glass structure. Moreover, vitrification transforms those hazardous wastes into a new non-hazardous glass. A preliminary study shows that the new glass is suitable for developing glass–ceramic tiles appropriate for floor pavement and wall covering.     

Development of a master plan for industrial solid waste management

Rapid industrial growth in the province of Khuzestan in the south west of Iran has resulted in disposal of about 1750 tons of solid waste per day. Most of these industrial solid wastes including hazardous wastes are disposed without considering environmental issues. This has contributed considerably to the pollution of the environment. This paper introduces a framework in which to develop a master plan for industrial solid waste management. There are usually different criteria for evaluating the existing solid waste pollution loads and how effective the management schemes are. A multiple criteria decision making technique, namely Analytical Hierarchy Process (AHP), is used for ranking the industrial units based on their share in solid waste related environmental pollution and determining the share of each unit in total solid waste pollution load. In this framework, a comprehensive set of direct, indirect, and supporting projects are proposed for solid waste pollution control. The proposed framework is applied for industrial solid waste management in the province of Khuzestan in Iran and a databank including GIS based maps of the study area is also developed. The results have shown that the industries located near the capital city of the province, Ahwaz, produce more than 32 percent of the total solid waste pollution load of the province. Application of the methodology also has shown that it can be effectively used for development of the master plan and management of industrial solid wastes.     

Comparison of the effectiveness of different binders in solidification/stabilization of a contaminated soil

In the current research, solidification/stabilization (S/S) treatment of the contaminated soil using hydraulic binders and additives was used to (1) reduce the mobility of organic and inorganic contaminants and (2) compare the ability of various binders in fixing contaminants. The samples were collected from Franco-Tunisian Petroleum Company, located in Sidi Litayem, Sfax (Southern Tunisia). Leaching tests were performed on contaminated soil, containing metallic elements, and hydrocarbons. Calcium aluminate cement (CAC), ordinary Portland cement (OPC), and ground-granulated blast-furnace slag (GGBFS), additives especially the bentonite and water, were used for S/S treatment. The obtained standard specimens were subjected for treating after treatment the leachability of pollutants, compressive strength (CS), and XRD analysis. The results of analysis conducted on contaminated soils showed that concentrations of metallic elements were in the range of 9.08–427 mg/kg and 15,520 mg/kg of organic compound. Next, 10% of the used binder improved the immobilization of pollutants and gave a satisfactory CS exceeding 1 MPa. Thus, the CAC is more effective in reducing the leachability of metal contaminants than OPC + GGBFS and produces much higher strength, which was of the order of 2.41 MPa. The mechanical characterization was confirmed by XRD analysis. The lowest values of organic compounds are presented in mixtures treated by 10% of used binder, indicating the effectiveness of those with the presence of 10% of bentonite. This work shows that 10% (OPC + GGBFS) +?10% bentonite improved the immobilization of metallic elements and hydrocarbons, thus proving its efficiency due to its low cost.     

Physical and chemical characteristics of after-reclamation dust from used sand moulds

The paper presents the results of investigations of physical and chemical properties of after reclamation dust that is generated in the foundry industry. Universally applied mechanical reclamation processes of spent moulding sands generate large amounts of after-reclamation dusts containing mainly rubbed spent binding agents and quartz dusts. An amount of after-reclamation dusts—in dependence of the reclamation system efficiency and the reclaim dedusting system—can reach 5–10 % in relation to the total reclaimed spent moulding sand. After-reclamation dusts originated from spent moulding sands with different kinds of resins mostly belong to dangerous wastes, since they contain chemo-setting binders with dangerous substances removed in the reclamation process. None of the companies producing mechanical reclamation systems offers presently the complex technology and equipment for utilisation of after reclamation dusts, which would meet technical and economic expectations of foundry plants. The paper presents the results of research carried out at the Faculty of Foundry Engineering AGH UST in Cracow which aims on the determination of possibilities of using the post-reclamation dust generated during mechanical reclamation of used moulding sands with organic resins as a source of energy. Different dusts generated in the mechanical reclamation process of used organic sands, delivered from foundries, were tested to determine their chemical composition, granular characterisation and physicochemical properties. As a result of the investigations, possible ways to utilise the dusts are presented.     

Limitations and feasibility of the land disposal of organic solvent-contaminated wastes

The limitations and feasibility of the land disposal of solid wastes containing organic solvents and refrigerants (chlorinated fluorocarbons) were investigated by evaluating the attenuation capacity of a hypothetical waste-disposal site by numerical modeling. The basic theorem of this approach was that the land disposal of wastes would be environmentally acceptable if subsurface attenuation reduced groundwater concentrations of organic compounds to concentrations that were less than health-based, water-quality criteria. Computer simulations indicated that the predicted concentrations of 13 of 33 organic compounds in groundwater would be less than their health-based criteria. Hence, solid wastes containing these compounds could be safely disposed at the site. The attenuation capacity of the site was insufficient to reduce concentrations of four compounds to safe levels without limiting the amount of mass available to leach into groundwater. Threshold masses based on time-dependent migration simulations were estimated for these compounds. The remaining 16 compounds, which consisted mainly of chlorinated hydrocarbons and fluorocarbons could not be safely landfilled without severe restrictions on the amounts disposed. These organic compounds were candidates to ban from land disposal.