Metal concentrations, fluxes, inventories and chronologies in sediments from Sepetiba and Ribeira Bays: A comparative study

Three sediment cores were sampled at Sepetiba Bay and four cores at Ribeira Bay, Rio de Janeiro State, Brazil. Sediment accumulation rates and chronologies were obtained from ²¹⁰Pb activity-depth profiles. Sediment accumulation rates in Ribera Bay ranged from 1.2 mm y⁻¹ in the inner bay to 2.6 mm y⁻¹ close to its entrance. In Sepetiba Bay two sediment accumulation rates were observed: a lower rate of 0.35 cm y⁻¹ before the 1960s and 0.76 cm y⁻¹ since then. The cause of this change is due to the construction of the Santa Cecília impoundment (1955) that brings water from the Paraíba do Sul Basin into the Guandu River, which increased its flow from the original 20 m³ s⁻¹ to 160 m³ s⁻¹. Concentration of 44 elements was obtained by ICP-MS after total dissolution of samples from two selected cores. The relative differences between the concentrations of crustal elements, such as Al, Fe and Ti are only about 20% (p < 0.05). Cd and Zn are 15 and four times larger in Sepetiba Bay than in Ribeira Bay, respectively. Other major and minor elements show lower statistically significant differences. The enrichment factors and metal inventories show that Sepetiba Bay can be considered polluted with Bi, Cd, Cr, Cu, Sb and Zn. Particularly, Cd and Zn present concentrations three and four times higher than the Brazilian existing limits.     

An instrument system for the investigation of particle fluxes

We present the rationale, design, and use of an instrument system to measure the variability of vertical and horizontal particle fluxes. The system features a new sequentially sampling sediment trap which collects and seals 10 separate samples during a single deployment. Horizontal particle fluxes are simultaneously monitored with a beam transmissometer interfaced to a standard Aanderaa current meter. Results from a 10-week deployment of instruments at several depths in a deep fjord estuary indicate that the trapping rate increases from 0.5g m⁻² day⁻¹ at 20 m to 150g m⁻² day⁻¹ at 200 m (5 m above bottom) because of frequent erosion in the deep waters. Periodic flushing of the deep water by intrusions of marine water over the seaward sill markedly enhances erosion and causes an up-estuary particle transport comparable to the vertical particle flux originating at the surface.     

Neodymium isotopic study of Baffin Bay water: sources of REE from very old terranes

Water samples were collected from Baffin Bay and surrounding areas in order to evaluate this region as a potential source of Nd from old continental material to Atlantic water. The isotopic data ranged from ε_Nd(0) = −9.0 to −26 with most of the data around ε_Nd(0) = −20 compared with values of North Atlantic Deep Water (NADW) with ε_Nd(0) = −13.5. The concentration of Nd in Baffin Bay waters was as high as 6 × 10⁻¹² g/g compared with 2.5 × 10⁻¹² g/g for NADW. The combination of low ε_Nd and high Nd concentration indicates that Baffin Bay may be a significant source of Nd from very old crustal material. A simple box model was used to evaluate the contribution to the Nd budget of NADW and it was concluded that a substantial fraction of the Nd from ancient crustal sources that is required to maintain the isotopic composition of NADW could be supplied by Baffin Bay outflow.     

Ecological evaluation of the Cumberland Basin ecosystem model

A holistic ecosystem simulation model has been developed for the Cumberland Basin and upper Chignecto Bay, a turbid macrotidal estuary at the head of the Bay of Fundy. This one-dimensional deterministic model has three compartments, three boundaries and three interacting submodels (physical, pelagic and benthic). Twenty-eight biological state variables represent broad functional groups of organisms and non-living organic carbon pools. All major components of the estuarine ecosystem are included. At the present stage of development, individual pelagic state variables give reasonable annual simulations which are in general agreement with available calibration data. Major problems remain with some benthic state variables, especially the subtidal ones about which little is known. In aggregate, the model performs well and output at the ecosystem level agrees with field observations. In the Cumberland Basin water column, annual community respiration exceeds phytoplankton net production (1–3 g C m⁻³) by a factor of 2–5 suggesting the importance of carbon imported from surrounding saltmarshes and the seaward boundary. Annual community respiration and microalgal net production (28 g C m⁻²) on the other hand are closely balanced in intertidal sediments. Respiration in subtidal sediments is entirely dependent upon sedimented carbon. The model supports the hypothesis that the Cumberland Basin is a heterotrophic ecosystem with low primary production which requires imported organic carbon to support the production and respiration of higher trophic levels.     

Fluid flow from pore pressure measurements off La Palma, Canary Islands

In situ subseafloor pore pressure results from the western flank of the island of La Palma, Canary Islands, are presented. The data obtained with a Pop Up Pore Pressure Instrument (PUPPI) provide constraints on the fluid circulation and its causes in a very special context: The sediment piles near an intraplate oceanic island built on the continental rise of the Northwest African Margin. The ambient pore pressures estimated from 2 to 4 days long record are negative in almost all cases with values, at depths of a few meters below sea floor, usually on the order of −10 to −70 Pa. Excess pore pressures develop only in the distal most areas. The permeabilities and compressibilities obtained respectively from the decay of the insertion pressures and the amplitude of the tidally induced pore pressure variations range between 2.5×10⁻¹⁸ and 6.6×10⁻¹⁶ m² and, 6.2×10⁻⁹ and 1.5×10⁻⁷ Pa⁻¹. According to these permeabilities fluid flow is estimated to be mostly downward and usually on the range between 0 and −0.3 mm y⁻¹. However, from the excess pore pressure profile a complex pattern of fluid circulation is inferred where horizontal fluid motion cannot be neglected. Horizontal flow is probably controlled by significant contrasts in the permeability of the different layers. The prevailing downward fluid flow is abnormal for a classical passive margin. We thus interpret these results as the superposition to the loss of fluids by sediment compaction (on the continental rise), of a large-scale flow system stimulated by thermal buoyancy (100 km wide) related to the volcanic activity on the island of La Palma.     

The flux of particulate material through a well-mixed estuary

The flux of suspended particulate material across the mouth of a well-mixed estuary was measured over 12 months. Samples were taken over one neap and one spring tidal cycle each month and analysed for total suspended particulate material, inorganic and organic particulates, particulate organic carbon and particulate organic nitrogen. Water volume transport at discrete time-steps were determined by means of a one-dimensional hydrodynamic model, calibrated for each tidal cycle sampled. Net transport varied between tidal cycles with regard to direction (import or export) and magnitude. Annual budgets revealed a net export of 5306 tonne of total suspended particulate material (3900 tonne of inorganic particulates, 1286 tonne of particulate organic carbon and 120 tonne of particulate organic nitrogen). The sources of particulate organic carbon are mainly from saltmarshes (194 g POC m²y¹) and from intertidal invertebrate production (586 g POC m⁻²y⁻¹).     

Tidally-induced sediment transport patterns in the upper Bay of Fundy: A numerical study

The Minas Basin, the eastern end of the Bay of Fundy, is well known for its high tide ranges and strong tidal currents, which can be exploited to extract electricity power. The properties of the tidally-induced sediment transport in the Minas Basin, where significant changes in tidal processes may occur due to a recently proposed tidal power project, have been studied with a three-dimensional hydrodynamic model, an empirical bed load sediment transport model and surface sediment concentrations derived from the remotely-sensed images. The hydrodynamic model was evaluated against independent observational data, which include tidal elevation, tidal current (in the full water column and bottom layer), residual current profile and tidal asymmetry indicators. The evaluation shows that the model is in good agreement with the observations.The sediment transport includes two components, bed load and suspended particulate load. The bed load is calculated using the modelled bottom shear stress and the observed grain size data. The estimated features of bed load transport roughly agree with the observed patterns of the erosion and deposition in the Minas Basin and Cobequid Bay. The transport of the suspended load is estimated using the modelled velocity fields and the surface sediment concentration derived from remote-sensing images. The comparisons between the modelled results and the limited observations illustrate that the observed directions of suspended sediment transport are basically reproduced by the model. The modelled net suspended sediment input into the Minas Basin through Minas Passage is 2.4×10⁶ m³ yr^?1, which is comparable to the observed value of 1.6×10⁶ m³ yr^?1.The variations of the bed load and the suspended load in space and time are also presented. The total net transport, defined as the mean value of the sum of bed and suspended load transports during the tidal cycle, shows strong spatial variability. The magnitude of the transport flux ranges from 0.1 to 0.2 kg m^?1 s^?1 in Minas Channel and Minas Passage, 0.1 kg m^?1 s^?1 in Cobequid Bay, to 0.01 kg m^?1 s^?1 in the central Minas Basin and Southern Bight. In Minas Channel, the sediment transport follows the structure of the tidal residual circulation, which features a large anticlockwise gyre. The sediment in Minas Passage moves eastward and deposits into the central Minas Basin. However, the sediment from the eastern part of the Basin moves westward and deposits in the central Minas Basin as well. In the Cobequid Bay, sediment moves eastward and deposits in the upper bay.     

Transport ofBe andBe in the ocean

Beryllium isotopes (¹⁰Be and⁹Be) have been measured in suspended particles of < 1 mm size collected by mid-water sediment traps deployed in the eastern Pacific at MANOP sites H (6°32′N, 92°50′W, water depth 3600 m) and M (8°50′N, 104°00′W, 3100 m). For comparison, surface sediments from box cores taken from the two sites were also studied. The concentrations of¹⁰Be and⁹Be in sediment-trap particles are about an order of magnitude smaller than those in the bottom sediments which contain about 8 × 10⁹ and 6 × 10¹⁶ atoms g⁻¹ of¹⁰Be and⁹Be, respectively. The sediment trap samples collected from 50 m off the bottom showed significant (26–63%) contributions from resuspended bottom sediments. The¹⁰Be/⁹Be ratio in trap samples varies from 3 to 20 × 10⁻⁸. The variation may partly result from varied proportion of authigenic/detrital material. The fluxes of both isotopes exhibit a very strong seasonality. The fluxes of¹⁰Be into the traps at about 1500 m are estimated as 9 × 10⁵ and 4 × 10⁵ atoms cm⁻² a⁻¹ at sites H and M respectively. These values are to be compared with the fluxes into the sediments of 4–5 × 10⁵ atoms cm⁻² a⁻¹ at both locations. Good correlations exist between¹⁰Be,⁹Be and²⁷Al indicating that the primary carrier phase(s) for the beryllium isotopes in the water column may be aluminosilicates.     

One century sedimentary record of Hg and Pb pollution in the Sagua estuary (Cuba) derived from Pb and Cs chronology

The vertical distribution of Hg and Pb were determined in a sediment core collected from the Sagua estuary (North Cuba) that receives input from the Sagua river, one of the most polluted rivers discharging into the Cuban coastal environment. Depth profiles of metal concentrations were converted to time-based profiles using the ²¹⁰Pb dating method and confirmed with the ¹³⁷Cs fallout peak. The mean mass accumulation rate was estimated to be 0.17 ± 0.04 g cm⁻² y⁻¹ (mean sediment accumulation rate 0.52 ± 0.13 cm y⁻¹) and the core bottom was estimated to date back about 130 years. The historical sedimentary record showed a strong enrichment of mercury concentrations in the past decades, caused by the incomplete treatment of industrial wastes from a chlor-alkali plant with mercury-cell technology in the Sagua river basin. Lead fluxes to sediments showed a gradual increase from the 1920s to present, which agrees with a population increase in Sagua la Grande City. Fluxes of both metals have increased the past 25 years, with values reaching a maximum of 0.5 and 3.9 μg cm⁻² y⁻¹ for Hg and Pb, respectively.     

Helium accumulation in groundwater, III. Limits on helium transfer across the mantle-crust boundary beneath Australia and the magnitude of mantle degassing

The groundwaters of the Great Artesian Basin (Australia) have been previously shown to be accumulating in-situ production helium for groundwaters ages < 50 kyr and an external helium flux equivalent to whole crustal production for groundwater ages > 100 kyr [1,2]. New helium isotope measurements show that the observed in-situ production helium (³He/⁴He 1.6 × 10⁻⁸) is isotopically distinct from the crustal degassing helium flux (³He/⁴He 6.6 × 10⁻⁸). Furthermore, the crustal degassing helium isotope ratio is marginally in excess of the whole crustal production ratio (³He/⁴He= 3.5 × 10⁻⁸) and the production ratio in a variety of continental rock types. This suggests that the upper limit on volatile transport across the mantle-crust boundary beneath the (relatively) stable and “complacent” Australian continent can be characterized by a “conductive-diffusive” helium/heat flux ratio of 2.6 × 10⁶⁴He atoms mW⁻¹ s⁻¹ which is two orders of magnitude less than the “intrusive-volcanic” ratio of 2.9 × 10⁸⁴He atoms mW⁻¹ s⁻¹ measured at the Galapagos [16]. These results constrain the transcrustal mantle degassing fluxes of⁴He and⁴⁰Ar to be much less than the mid-ocean ridge degassing fluxes; which are much less than the degassing of⁴He and⁴⁰Ar from continental crust. Thus, the degassing of the Earth's interior is dominated by magmatic processes but the dominant fluxes of⁴He and⁴⁰Ar to the atmosphere must come from the continental crust.     

Sources, sinks and resuspension of suspended particulate matter in the eastern English Channel

Seasonal observations on the nature and concentration of suspended particulate matter (SPM) are presented for a cross-section of the English Channel, between the Isle of Wight (UK) and Cotentin peninsula (France) i.e. the western boundary of the eastern English Channel. The highest concentrations of suspended material are found adjacent to the English coastline, whereas the offshore waters are associated with low concentrations. Seasonal variations in the concentration and nature of suspended material are identified, with highest concentrations in winter. At this time, the suspended particles are characterised generally by peaked grain size spectra and an enrichment in coarse silt particles; in summer, the distributions are generally flat. The diatom communities found within the suspended matter indicate that material resuspended in the coastal zone and the estuarine environments is transported offshore. SPM fluxes (based upon the observed SPM concentrations and the output from a 2-D hydrodynamic model) from the western Channel through the Wight–Cotentin Section, ranged between 2 and 71×10⁶ t a⁻¹ with a mean of around 20×10⁶ t a⁻¹ over the period of the observations (1994–1995). These fluxes are comparable to the order of magnitude and mean value reported as output through the Dover Strait. Therefore, it is possible that the eastern English Channel may be characterised as an area of fine-grained sediment ‘bypass'. This interpretation is corroborated by: (a) the absence of fine-grained sediment deposits over the area; and (b) correlation between the potential resuspension time of the fine particles and the seabed sediment distribution.     

Sediment transport in distributary channels and its export to the pro-deltaic environment in a tidally dominated delta: Fly River, Papua New Guinea

Current metre deployments, suspended sediment measurements and surface sediment samples were collected from three locations within distributary channels of the tidally dominated Fly River delta in southern Papua New Guinea. Net bedload transport vectors and the occurrence of elongate tidal bars indicate that mutually evasive ebb- and flood-dominant transport zones occur in each of the distributary channels. Suspended sediment experiments at two locations show a phase relationship between tidal velocity and sediment concentration such that the net suspended sediment flux is directed seaward. Processes that control the export of fluid muds with concentrations up to 10 g l⁻¹ from the distributary channels across the delta front and onto the pro-delta are assessed in relation to the available data. Peak spring tidal current speeds (measured at 100 cm above the bed) drop off from around 100 cm s⁻¹ within the distributary channels to <50 cm s⁻¹ on the delta front. Gravity-driven, 2-m thick, fluid mud layers generated in the distributary channels are estimated to require at least 35 h to traverse the 20-km-wide, low-gradient (2×10⁻³ degrees) delta front. The velocities of such currents are well below those required for autosuspension. A 1-month time series of suspended sediment concentration and current velocity from the delta front indicates that tidal currents alone are unable to cause significant cross-delta mud transport. Wave-induced resuspension together with tides, storm surge and barotropic return-flow may play a role in maintaining the transport of fine sediment across the delta front, but insufficient data are available at present to make any reliable estimates.     

Turbulence measurements in a submarine canyon

Profiles of velocity turbulence in Monterey Canyon, made with a recently developed expendable probe, show the existence of a very turbulent bottom boundary layer. The turbulent flow is up to 170 m thick and has peak microscale shears of 1 m s⁻¹ per meter. The rate of dissipation of kinetic energy, based on the observed shear variance, averaged over the depth of the turbulent boundary layer ranged from 70 to 500 × 10⁻⁶W m⁻³. Temperature measurements indicate that the flow was up canyon at a time of low tide. The upper bound for the vertical eddy viscosity is estimated to be17 × 10⁻⁴m²s⁻¹ and for the vertical eddy diffusivity is estimated to be 15 × 10⁻⁴m²s⁻¹. The large vertical scale and the intensity of the observed boundary layer suggest that the flow in Monterey Canyon may be important for the renewal and circulation of water over the continental shelf in the bay area.     

Particle fluxes and recent sediment accumulation on the Aquitanian margin of Bay of Biscay

As a part of the ANR-Forclim experiment, particle mass fluxes and sedimentation processes were investigated on the slope of Aquitanian margin of the Bay of Biscay, between the canyons of Cap-Breton and Cap-Ferret. Interface sediments were collected along a depth transect from 145 to 2000 m; simultaneously a mooring line was deployed at the deepest station (WH, 2000 m) with two traps (800 and 1700 m) for a 16-month period (June 2006–November 2007). ²¹⁰Pb activities of settling particles and of interface sediments were determined to study transport processes of particles. Sediment and mass accumulation rates, calculated from excess ²¹⁰Pb profiles in the sediment column, show the expected decreasing trend with depth, as usually observed on margins. Mean particulate mass fluxes at 800 and 1700-m depth at site WH are, respectively, 27 and 70 g m^?2 a^?1.The ²¹⁰Pb budget points out events of temporary high lateral input of particles. The comparison of mass and ²¹⁰Pb fluxes between the water column and the seabed indicates that lateral transport plays an important role in particle accumulation on the Aquitanian margin. Regarding the objectives of the ANR-Forclim program, which aims to improve significantly the interpretation of fossil foraminifera signals, as a proxy for hydrological changes in the North Atlantic ocean, these results highlight advection processes must be considered when interpreting fluxes of foraminifers on the Aquitanian margin.     

Dynamics of the transport of the phosphorus and silicon at the water-bottom boundary in the Baltic Sea

The study of the fine structure of the phosphorus and silicon distribution in near-bottom layers and in the interstitial water of the sediments has been carried out in the different Baltic Sea regions (Gulf of Finland, Bornholm, Gotland). The data of this study are used to calculate the flows and effective transport coefficients for mineral phosphorus and silicon exchange processes between sediment and near-bottom layer. The values of nutrient flows varied depending on sediment type from 9.8 to 632 μg-at. m⁻² year⁻¹ for phosphorus and from 232.4 to 1881.1 μg-at. m⁻² year⁻¹ for silicon. The dependence of the effective transport coefficients versus the distance from the bottom (h) is expressed by empirically-derived equation: K_eff = Ah^−b. The values of constants “A” and “b” depend on the hydrochemical conditions, sediment type and hydrophysical conditions in the near-bottom layers. Calculated constants for regions are discussed.     

Harmful algal blooms (HABs) in Daya Bay, China: An in situ study of primary production and environmental impacts

A month-long investigation of phytoplankton biomass and primary production (PP) was carried out during a harmful algal bloom (HAB) in Daya Bay, China, in 2003. During the bloom, the phytoplankton community was dominated by Scrippsiella trochoidea and Chattonella marina. The phytoplankton biomass (Chl a) and PP reached peak levels of 519.21 mg m⁻³ and 734.0 mgC m⁻³ h⁻¹, respectively. Micro-phytoplankton was the key contributor to Chl a and PP in a cage-culture area and in the adjacent HAB-affected waters, with percentages of up to 82.91% and 84.94%, respectively. The HAB had complicated relationships with hydrological and meteorological factors in Daya Bay. However, the water around the cage-culture area always showed statistically greater phytoplankton biomass and nutrient loadings than in adjacent waters, suggesting that this was the “trigger area” of the bloom. The spatial and temporal distribution of diverse HABs in Daya Bay, their ecological characteristics, and their environmental impacts are also discussed in this paper.     

The 1975 sub-terminal lavas, mount etna: a case history of the formation of a compound lava field

The 1975 sub-terminal activity was characterised by low effusion rates (0.3–0.5 m³ s⁻¹) and the formation of a compound lava field composed of many thousands of flow units. Several boccas were active simultaneously and effusion rates from individual boccas varied from about 10⁻⁴ to 0.25 m³s⁻¹. The morphology of lava flows was determined by effusion rate (E): aa flows with well-developed channels and levees formed when E > 2 × 10⁻³ m³ s⁻¹, small pahoehoe flows formed when 2 × 10⁻³ m³ s⁻¹ >E > 5 > 10⁻⁴ m³ s⁻¹ and pahoehoe toes formed when E < 5 × 10⁻⁴ m³ s⁻¹. There was very little variation with time in the effusion temperature, composition or phenocryst content of the lava.New boccas were commonly formed at the fronts of mature lava flows which had either ceased to flow or were moving slowly. These secondary boccas developed when fluid lava in the interior of mature aa flows either found a weakness in the flow front or was exposed by avalanching of the moving flow front. The resulting release of fluid lava was accompanied by either partial drainage of the mature flow or by the formation of a lava tube in the parent flow. The temperature of the lava forming the new bocca decreased with increasing distance from the source bocca (0.035°C m⁻¹). It is demonstrated from the rate of temperature decrease and from theoretical considerations that many of the Etna lavas still contained a substantial proportion of uncooled material in their interior as they came to rest. The formation of secondary boccas is postulated to be one reason why direct measurements of effusion rates tend, in general, to overestimate the total effusion rates of sub-terminal Etna lava fields.     

A device to examine the in situ response of intertidal cohesive sediment deposits to fluid shear

A self-contained, field-portable recirculating seawater flume was designed and constructed in order to measure in situ the erodibility of cohesive estuarine muds. The flume can be easily deployed by one person and is designed for subaerial use only. Bed shear stresses up to 0.6 Nm⁻² can be generated by the flume. Rates of sediment erosion are assessed in terms of the mass of particulate material eroded with time. Flow calibrations yield a drag coefficient (C_D) of 4.5 × 10⁻³ which enables single mid-depth velocity measurements to be related directly to the imposed bed stress. Water motions within the flume are complex, but secondary (radial) circulations are not considered sufficiently competent to dominate sediment erosion. Stratification effects due to high levels of suspended sediment ( 1.5 gl⁻¹) are negligible. However, the drag-reducing properties of the sediment suspension are uncertain.     

Geotechnical properties and behavior of high-porosity, organic-rich sediments in Eckernförde Bay, Germany

The organically rich, fine-grained, very soft, high porosity sediments in the inner portion of Eckernförde Bay, Germany have varying amounts of methane gas, with the horizon of gas fluctuating vertically on a seasonal cycle. The sharp vertical gradient in water content, with values exceeding 500% at the sediment–water interface, and corresponding gradient in density can be expected to cause a significant subbottom acoustic impedance contrast in these surficial sediments. Equations are presented to characterize geotechnical property variations of the upper 5 m. The upper 1.5 m exhibits appreciable ‘apparent’ overconsolidation with a trend toward a normally consolidated stress state at 2.5 m depth. The coefficient of permeability of the upper 40 cm is low (4×10^-6 cm s^-1) and the sediment is highly compressible with compression indices of 2.7–6.8. Triaxial compression test results indicate that the sediment behaves as a normally consolidated clay with a low friction angle (22°). The rheological behavior of the upper 20–30 cm, determined with a small vane device, is indicative of a shear-thinning material, implying that the resistance to penetration decreases with increasing velocity.     

Sediment and trace element depositional history from the Ajkwa River estuarine mangroves of Irian Jaya (West Papua), Indonesia

Radiotracer ²¹⁰Pb and contaminant copper were used to estimate sediment accumulation rates in 4 cores from the Ajkwa River estuary and mangrove tidal channels in western Irian Jaya. Mass accumulation rates (4.5–13 kg dry wt m⁻² yr⁻¹) were within the envelope of expectations for a region of high rainfall, great river catchment relief, and rapid tectonic uplift of mountains. Copper accumulation rates were enhanced 40 fold in surface sediments, compared to pre-1950 sections of the sediment cores. These recent sediments with enhanced copper concentrations come from Freeport Indonesia mine tailings over the last 27 years. Variations in sediment core profiles of Al, Fe, and organic carbon were small, indicating no great change in bulk sediment composition. Sulfur concentrations decline toward the sediment surface, suggesting a decline in rates of microbial sulfate reduction. Enhanced sediment copper concentrations will be a useful tracer of sediment dispersal from the Ajkwa River estuary along this coast.