Mud volcanic natural phenomena in the South Caspian Basin: geology,fluid dynamics and environmental impact

The South Caspian sedimentary basin is a unique area with thick Mesozoic-Cenozoic sediments (up to 30–32 km) characterized by an extremely high fluid generation potential. The large amount of active mud volcanoes and the volumes of their gas emissions prove the vast scale of fluid generation. Onshore and offshore mud volcanoes annually erupt more than 10⁹ cubic meters of gases consisting of CH₄ (79–98%), and a small admixture of C₂H₆, C₃H₈, C₄H₁₀, C₅H₁₂, CO₂, N, H₂S, Ar, He. Mud volcanism is closely connected to the processes occurring in the South Caspian depression, its seismicity, fluctuations of the Caspian Sea level, solar activity and hydrocarbon generation.The large accumulations of gas hydrates are confined to the bottom sediments of the Caspian Sea, mud volcanoes crater fields (interval 0–0.4 m, sea depth 480 m) and to the volcanoes body at the depth of 480–800 from the sea bottom. Resources of HC gases in hydrates saturated sediments up to a depth of 100 m and are estimated at 0.2×10¹⁵–8×10¹⁵ m³. The amount of HC gases concentrated in them is 10¹¹–10¹² m³.The Caspian Sea, being an inland closed basin is very sensitive to climatic and tectonic events expressed in sea level fluctuations. During regressive stages as a result of sea level fall and the reducing of hydrostatic pressure the decomposition of gas hydrates and the releasing of a great volume of HC gases consisting mainly of methane are observed.From the data of deep drilling, seismoacoustics, and deep seismic mud volcanic activity in the South Caspian Basin started in the Lower Miocene. Activity reached its highest intensity at the boundary between the Miocene and Pliocene and was associated with dramatic Caspian Sea level fall in the Lower Pliocene of up to 600 m, which led to the isolation of the PaleoCaspian from the Eastern ParaTethys. Catastrophic reduction of PaleoCaspian size combined with the increasing scale of mud volcanic activity caused the oversaturation and intoxication of water by methane and led to the mass extinction of mollusks, fishes and other groups of sea inhabitants. In the Upper Pliocene and Quaternary mud volcanism occurred under the conditions of a semi-closed sea periodically connected with the Pontian and Mediterranean Basins. Those stages of Caspian Sea history are characterized by the revival of the Caspian organic world.Monitoring of mud volcanoes onshore of the South Caspian demonstrated that any eruption is predicted by seismic activation in the region (South-Eastern Caucasus) and intensive fluid dynamics on the volcanoes.     

The driving forces behind the Caspian Sea mean water level oscillations

Closed basins such as the Caspian Sea rapidly respond to variations in atmospheric and geological events. This study has been conducted to deduce the role of natural and anthropogenic influences on the Caspian Sea mean water level fluctuations for the period of 1998–2005. It is recognized that climate is the primary mechanism of the Caspian Sea mean water level variations based on the relatively small differences of the Caspian Sea hydrologic budget residuals and the Caspian Sea mean water level fluctuations. This is further supported by the similarity in water-level variations of the Caspian Sea with those of Lake Van and Lake Urmia. On the other hand, the Caspian Sea needed to lose some of its water to attain water balance equilibrium in 2000 and 2001. The year 2000 showed anomalous seismic activity particularly in the southwestern part of the Caspian Sea. Two significant earthquakes with magnitudes of 6.8 and 6.5 M_w occurred on November 25, 2000. The focal mechanisms of these earthquakes and numerous aftershocks indicated normal faulting and, therefore, caused the Caspian Sea lake level to decline in 2000. The contribution of submarine mud volcano eruptions to the Caspian Sea lake level could be insignificant based on the comparison of water budget residuals and the mean water level variations. Neither crustal deformation (based on the GPS measurements) nor the offshore oil and natural gas production activities in the Caspian Sea are responsible for noticeable changes to the level of the Caspian Sea.     

Comparative Characteristics of Composition and Radioactivity of Oligocene Clays in the Greater Caucasus and Talysh

The paper presents results of the comparative analysis of organic matter (OM), mineralogical characteristics, and radioactivity in Oligocene clayey rocks from the Greater Caucasus and Talysh, which bound the South Caspian Depression on the southeast and northwest, respectively. It is established that Oligocene clays of the Greater Caucasus and Talysh substantially differ in terms of quantitative and qualitative parameters of OM, its maturity, integral radioactivity, and composition of radioactive elements. At the same time, the mineral composition of clays from these mountainous massifs shows a certain similarity. It is concluded that the Fore-Talysh subsidence zone and adjacent areas of the Caspian Sea are characterized by a lower oil and gas potential as compared with Oligocene rocks developed at the southeastern margin of the Greater Caucasus.__________Translated from Litologiya i Poleznye Iskopaemye, No. 4, 2005, pp. 430–439.Original Russian Text Copyright © 2005 by Feyzullayev, Kheirov, Ch. Aliyev, Abbasova, K. Aliyev.     

The Lower Jurassic of the Eastern Caspian region and the Middle Caspian Basin: Lithology,facies, taphonomy

Lithofacies of the productive Upper Triassic-Lower Jurassic deposits of the Eastern Caspian region, studied in wells on the Caspian coast and exposed in the outcrops of the Mountainous Mangyshlak, are described and analyzed. The similarity of the structure of the Mesozoic sedimentary beds of the Middle Caspian Basin and of those of the land adjacent to its eastern coast is confirmed. Comparative analysis of lithofacies allowed the reconstruction of the paleogeographic setting and depositional environments in the studied region during the Early Jurassic. A unique fossil plant occurrence is discovered in the upper part of the Lower Jurassic series (in the lower subformation of the Kokala Formation; Eastern Caspian region). Fossil plant taphonomy and the lithology of host rocks in the occurrence resulted from unusual paleogeographic settings that existed in the Middle Caspian Basin at the time of the Early-Middle Jurassic boundary.     

Impact of anthropogenic and natural factors on the air quality above the northern Caspian Sea and the ecological risk level for the human population in the coastal zone

The paper reports monitoring results (obtained in 2000–2001) of the seasonal variations in the quality of lower atmospheric air in the coastal zone of the northern Caspian Sea due to the occurrence of aerosols with submicrometer-sized particles and soot in the lower atmosphere. The contributions of natural and anthropogenic factors to the ecological risk for the local human population are evaluated, along with the contribution of the premature mortality of the human population in the coastal zone in 2005 to its overall average death rate for the Russian Federation (approximately 24%). The authors’ estimates are consistent with those made by the World Health Organization at the United Nations (WHO) for the Russian Federation as a whole (approximately 21%). The information presented in this publication is important for evidence-based recommendations on preventive environment-protective measures to be taken with regard for the development of oil and gas fields on- and offshore the northern Caspian Sea.     

Messinian events in the Black Sea

Past hydrological interactions between the Mediterranean Sea and Black Sea are poorly resolved due to complications in establishing a high‐resolution time frame for the Black Sea. We present a new greigite‐based magnetostratigraphic age model for the Mio‐Pliocene deposits of DSDP Hole 380/380A, drilled in the southwestern Black Sea. This age model is complemented by ⁴⁰Ar/³⁹Ar dating of a volcanic ash layer, allowing a direct correlation of Black Sea deposits to the Messinian salinity crisis (MSC) interval of the Mediterranean Sea. Proxy records divide these DSDP deposits into four intervals: (i) Pre‐MSC marine conditions (6.1–6.0 Ma); (ii) highstand, fresh to brackish water conditions (~6.0–5.6 Ma); (iii) lowstand, fresh‐water environment (5.6–5.4 Ma) and (iv) highstand, fresh‐water conditions (5.4–post 5.0 Ma). Our results indicate the Black Sea was a major fresh‐water source during gypsum precipitation in the Mediterranean Sea. The introduction of Lago Mare fauna during the final stage of the MSC coincides with a sea‐level rise in the Black Sea. Across the Mio‐Pliocene boundary, sea‐level and salinity in the Black Sea did not change significantly.     

Structure of the crust and upper mantle of the Black and Caspian Seas

Many geophysical characteristics of the Caspian and Black Seas' deep basins are similar, having: suboceanic type of the crust, low average seismic velocity, absence of earthquakes and relatively small variation of magnetic anomalies. However, the sediments in the Caspian Sea deep basin are folded whereas in the Black Sea they are approximately horizontal. The Caspian Sea also has a far greater thickness of sediment accumulation.

The deep basins of the Caspian, Black and Mediterranean seas represent a sequence having similar crustal structures but with a decreasing thickness of sediments and consolidated layer, in that order. It is possible that the intensive sinking and accumulation of sediments began earliest in the Caspian Sea and spreaded continuously to the Black Sea and then the Mediterranean Sea. The Caspian and Black Sea deep basins have existed for long time (perhaps from Paleozoic time or even earlier) as areas with a specific and related type of evolution.     

Amplitude,frequency and drivers of Caspian Sea lake-level variations during the Early Pleistocene and their impact on a protected wave-dominated coastline

The Caspian Sea, the largest isolated lake in the world, witnessed drastic lake-level variations during the Quaternary. This restricted basin appears very sensitive to lake-level variations, due to important variations in regional evaporation, precipitation and runoff. The amplitude, frequency and drivers of these lake-level changes are still poorly documented and understood. Studying geological records of the Caspian Sea might be the key to better comprehend the complexity of these oscillations. The Hajigabul section documents sediment deposited on the northern margin of the Kura Basin, a former embayment of the Caspian Sea. The 2035 m thick, well-exposed section was previously dated by magneto-biostratigraphic techniques and provides an excellent record of Early Pleistocene environmental, lake-level and climate changes. Within this succession, the 1050 m thick Apsheronian regional stage, between ca 2·1 Ma and 0·85 Ma, represents a particular time interval with 20 regressive sequences documented by sedimentary and palaeontological changes. Sequences are regressing from offshore to coastal, lagoonal or terrestrial settings and are bounded by abrupt flooding events. Sediment reveals a low energy, wave-dominated, reflective beach system. Wave baselines delimiting each facies association appear to be located at shallower bathymetries compared to the open ocean. Water depth estimations of the wave baselines allow reconstruction of a lake-level curve, recording oscillations of ca 40 m amplitude. Cyclostratigraphic analyses display lake-level frequency close to 41 kyr, pointing to allogenic forcing, dominated by obliquity cycles and suggesting a direct or indirect link with high-latitude climates and environments. This study provides a detailed lake-level curve for the Early Pleistocene Caspian Sea and constitutes a first step towards a better comprehension of the magnitude, occurrence and forcing mechanisms of Caspian Sea lake-level changes. Facies models developed in this study regarding sedimentary architectures of palaeocoastlines affected by repeated lake-level fluctuations may form good analogues for other (semi-)isolated basins worldwide.     

Analysis and prediction of Caspian Sea level pattern anomalies observed by satellite altimetry using autoregressive integrated moving average models

In this study, we successfully present the analysis and forecasting of Caspian Sea level pattern anomalies based on about 15 years of Topex/Poseidon and Jason-1 altimetry data covering 1993–2008, which are originally developed and optimized for open oceans but have the considerable capability to monitor inland water level changes. Since these altimetric measurements comprise of a large datasets and then are complicated to be used for our purposes, principal component analysis is adopted to reduce the complexity of large time series data analysis. Furthermore, autoregressive integrated moving average (ARIMA) model is applied for further analyzing and forecasting the time series. The ARIMA model is herein applied to the 1993–2006 time series of first principal component scores (sPC1). Subsequently, the remaining data acquired from sPC1 is used for verification of the model prediction results. According to our analysis, ARIMA (1,1,0)(0,1,1) model has been found as optimal representative model capable of predicting pattern of Caspian Sea level anomalies reasonably. The analysis of the time series derived by sPC1 reveals the evolution of Caspian Sea level pattern can be subdivided into five different phases with dissimilar rates of rise and fall for a 15-year time span.     

The eastern flank of the Caspian Basin: Sedimentary complexes and sedimentation conditions in the Early-Middle Carboniferous

Carboniferous and Lower Permian Carbonate and terrigenous rocks with the total thickness of >4000 m serve as the productive units in the Paleozoic subsalt complex at the eastern flank of the basin surrounding the northern area of the present-day Caspian Sea (hereafter, Caspian Basin in the broad sense). In recent years, several large oil and gas-condensate fields were discovered in these rocks. The complexity of geological evolution of this region, which is situated at the junction between the East European Platform and the Ural orogen, as well as multiple changes of sedimentation conditions during the Middle and Late Paleozoic, are reflected in the diversity of types of terrigenous and carbonate sediments and their facies alterations. Reconstruction of these environments makes it possible to elucidate specific features of the location of reservoir rocks in vertical and horizontal sections, as well as regularities of variations in their filtration-capacitive properties.     

First results of investigation into the relation between magnetic properties of bottom sediments in the Northern Caspian and variations in the Caspian Sea level in the Late Neo-Pleistocene

The first data of investigation into the relation between changes in magnetic properties of the Northern Caspian sediments and variations in the Caspian Sea level in the Late Neo-Pleistocene are presented. It is shown that there is a certain correlation between magnetic characteristics of sediments and variations in the Caspian Sea level that cause changes in the lithological and faunistic composition of sediments.     

River inflow and salinity changes in the Caspian Sea during the last 5500 years

Pollen, spores and dinoflagellate cysts have been analysed on three sediment cores (1.8–1.4 m-long) taken from the south and middle basins of the Caspian Sea. A chronology available for one of the cores is based on calibrated radiocarbon dates (ca 5.5–0.8 cal. ka BP). The pollen and spores assemblages indicate fluctuations between steppe and desert. In addition there are some outstanding zones with a bias introduced by strong river inflow. The dinocyst assemblages change between slightly brackish (abundance of Pyxidinopsis psilata and Spiniferites cruciformis) and more brackish (dominance of Impagidinium caspienense) conditions. During the second part of the Holocene, important flow modifications of the Uzboy River and the Volga River as well as salinity changes of the Caspian Sea, causing sea-level fluctuations, have been reconstructed. A major change is suggested at ca 4 cal. ka BP with the end of a high level phase in the south basin. Amongst other hypotheses, this could be caused by the end of a late and abundant flow of the Uzboy River (now defunct), carrying to the Caspian Sea either meltwater from higher latitudes or water from the Amu-Daria. A similar, later clear phase of water inflow has also been observed from 2.1 to 1.7 cal. ka BP in the south basin and probably also in the north of the middle basin.     

Changes in the water regime of the caspian sea

The article deals with issues of structure and dynamics of the Caspian Sea water balance. On the base of historical, paleogeomorphological and other data the evolution history of the Caspian Sea and its basin has been observed for different time intervals down to 400 thous. years ago. Presented are computerized data on water balance components in the current centenary obtained from instrumental observations, revealed are causes of the sea-level fluctuations within that time interval and anthropogenic factor contribution to this process. Based on the analysis of this material, an attempt has been undertaken to present a scenarion of a possible sea-level position of the Caspian Sea with the expected versions of climatic changes at the end of the XX and beginning of the XXI centuries.     

Caspian Sea level prediction using satellite altimetry by artificial neural networks

The demand for accurate predictions of sea level fluctuations in coastal management and ship navigation activities is increasing. To meet such demand, accessible high-quality data and proper modeling process are critically required. This study focuses on developing and validating a neural methodology applicable to the short-term forecast of the Caspian Sea level. The input and output data sets used contain two time series obtained from Topex/Poseidon and Jason-1 satellite altimetry missions from 1993 to 2008. The forecast is performed by multilayer perceptron network, radial basis function, and generalized regression neural networks. Several tests of different artificial neural network (ANN) architectures and learning algorithms are carried out as alternative methods to the conventional models to assess their applicability for estimating Caspian Sea level anomalies. The results derived from the ANN are compared with observed sea level values and with the forecasts calculated by a routine autoregressive moving average (ARMA) model. Different ANNs satisfactorily provide reliable results for the short-term prediction of Caspian Sea level anomalies. The root mean square errors of the differences between observations and predictions from artificial intelligence approaches can be significantly reduced by about 50 % compared with ARMA techniques.     

Natural and anthropogenic rapid changes in the Kara-Bogaz Gol over the last two centuries reconstructed from palynological analyses and a comparison to instrumental records

Palynological analyses (pollen and dinocysts) of a sediment core taken in the Kara-Bogaz Gol have been used to reconstruct rapid and catastrophic environmental changes over the last two centuries (chronology based on ²¹⁰Pb). A natural cyclicity (65 years) of water level changes in the Caspian Sea (CS) and in the Kara-Bogaz Gol (KBG) and anthropogenic factors (building of a dam separating the CS and the KBG waters) combine to induce rapid changes in water levels of the KBG, in the salinity of its waters and in vegetation cover of its surroundings. The impact of low water levels on the dinocysts is marked by a lower diversity and the survival of two species that are typical of the KBG, the Caspian Sea species present in the KBG having disappeared. During periods of higher water levels (AD 1871–1878), the lake is surrounded by a steppe-like vegetation dominated by Artemisia; whereas during periods of low water levels (AD 1878–1913 and AD 1955–1998), the emerged shore are colonised by Chenopodiaceae. The period of AD 1913–1955 corresponding to decreasing water levels has an extremely low pollen concentration and a maximum of reworking of arboreal taxa. During the last low-level period, humans responded by abandoning the shores of the bay. What happened to the KBG can be used as an example of what may happen in the future for the Aral Sea.A problem of reworking of Tertiary dinocysts into modern deposits has been detected owing to the knowledge of the modern dinoflagellate assemblages recently made available through a water survey. A comparison to modern surface pollen samples from Central Asia (Anzali, Caspian Sea south and central basins, Aral Sea, Lake Balkhash, Lake Issyk-Kul and the Chinese Tien-Shan range) allows us to establish the potential reworking of at least five arboreal pollen taxa possibly by run-off and dust storms.     

Dietary overlap between invasion ctenophora (M. leidyi ) and anchovy (C. engrauliformis) in the southern parts of Caspian Sea

Mnemiopsis leidyi, native to America, Invaded the Caspian Sea in 1999. By the end of 2000, the entire sea was accupied with them. In parallel, a sharp decline in pelagic fish such accurrred.This survey was studied the relationship between the M. leidyi and this decline. Dietary analysis was conducted on anchovy sprat (Clupeonnela engrauliformis) and M. leidyi from August 2001 to October 2002 in the coastal water in the southern parts of Caspian Sea, in Iran. M. leidyi was caught by plankton net, (the mesh size ～5 mm), at three depth at 5, 10 and 15m. Sprat was caught by fisheries boat at Babolasar fishery harbor. Samples were not fixed in M. leidyi common fixative, 96% Ethanol were used. The Schoener index analysis reflected a similar diet composition of both species, with an critical level of overlap (>89 in Babolsar samples and >84 in Noushahar samples). This competition is one of the reasons for the decline of anchovy sprat. also, the results show M. leidyi is feeding on fish eggs, but effects of this factor on anchovy population is less than feeding competition. Controlling of M. leidyi population is reducing the pressure of its invasion and the effective approach is introduces a predator to the Caspian Sea.     

Kara-Bogaz-Gol Bay: Physical and Chemical Evolution

Kara-Bogaz-Gol Bay is a large (around 18,000 km²) and shallow (few meters deep) lagoon located east of the Caspian Sea. Its water surface was several meters to several dozens cm lower than in the Caspian Sea, so water flows from the Caspian Sea through a narrow strait into the bay, where it evaporates. Kara-Bogaz-Gol Bay is one of the saltiest bodies of water in the world; its water salinity amounts to 270–300 g/l. Different kinds of salts available in this natural evaporative basin has been used commercially since at least the 1920s. In March 1980, in order to decelerate a continuous fall of the Caspian Sea level, which in 1977 was the lowest over the last 400 years (?29 m), the Kara-Bogaz-Gol Strait was dammed. In response to this human intervention, the bay had already dried up completely by November 1983. In 1992, the dam was destroyed, and Kara-Bogaz-Gol Bay had been filling up with the Caspian Sea water at a rate of about 1.7 m/year up to 1996 as observed by the TOPEX/Poseidon satellite altimetry mission. Since then, Kara-Bogaz-Gol Bay level evolution with characteristic seasonal and interannual oscillations has been similar to that of the Caspian Sea. Physical and chemical evolution of the bay in the twentieth and twenty-first centuries is traced in detail in the paper.     

Cenozoic Magmatism of the North-Eastern Eurasian Margin: The Role of Lithosphere Versus Asthenosphere

Sikhote-Alin and Sakhalin are located in the Russian Far Eastflank of the northernmost part of the Sea of Japan. Magmatismin this region preceded, was concurrent with, and continuedafter the extension and sea-floor spreading (25–18 Ma)that formed the Sea of Japan. Among the Sikhote-Alin and Sakhalinvolcanic suites, Eocene–Oligocene (55–24 Ma) lavasare characterized by greater large ion lithophile element andrare earth element enrichments compared with Early–Mid-Miocene(23–15 Ma) tholeiites, and also show a depletion in highfield strength elements (HFSE). The geochemical characteristicsof the Eocene–Oligocene and Early–Mid-Miocene basaltsare consistent with migration of the locus of magma generationbeneath the Sikhote-Alin and Sakhalin areas from subduction-modifiedlithospheric mantle into mid-ocean ridge basalt (MORB)-sourceasthenosphere as spreading in the Sea of Japan progressed. Mid-Miocene–Pliocene(14–5 Ma) lavas, erupted following the opening of theSea of Japan, include alkaline and sub-alkaline basalts withwide ranges in trace-element abundances, varying between twodistinct end-members: (1) volumetrically minor alkaline basaltswith Zr–Nb and Sr–Nb–Pb isotope compositionssimilar to asthenosphere-derived, intra-plate–hotspotbasalts from eastern China; (2) more abundant, lithosphere-derived,low-alkali tholeiites depleted in HFSE. The similarity of isotopicsignatures coupled with systematically different rare earthelement (REE) abundances in the Mid-Miocene–Pliocene andChinese basalts are best modeled by similar extents of meltingof spinel lherzolite and garnet lherzolite, respectively. TheMid-Miocene–Pliocene alkali basalts were generated bysmall degrees of partial melting of hot asthenosphere beneatha thin lithospheric lid; the thin lithospheric mantle beneaththe Sikhote-Alin and Sakhalin region resulted from heating andextension associated with the opening of the Sea of Japan. KEY WORDS: north-eastern Eurasian margin; Sikhote-Alin–Sakhalin; Japan Sea opening; subcontinental lithosphere; asthenosphere     

Deep Structure and Geodynamics of the Black Sea–Caspian Region

Geotectonics - New data on the crust structure of the Black Sea?Caspian region, including the Scythian and Anatolian plate margins, the Caucasus, Black Sea and Southern Caspian structures are...     

Paleochannels on the Northern Slope of the Derbent Basin,Caspian Sea

The results of studies in the paleochannel of the Volga River, which was discovered earlier on the northwestern slope of the Derbent Basin, Caspian Sea, are presented. Seismoacoustic profiling in the paleochannel, combined with placement of submerged buoy stations equipped with current gauges, water temperature gauges, and sediment traps showed that the channel is not silted and cold heavy water is transported along it to the deep sea part of the sea, avoiding the general water transit along the western coast of the Central Caspian Sea. The preliminary calculations show that water discharge through the channel to the near-bottom part of the sea can be about 8–10 km³/yr.