Crystal Structure and Chemical Composition of Ludwigite from Vranovac Ore Deposit (Boranja Mountain,Serbia)

The crystal structure of ludwigite from Vranovac ore deposit (Boranja Mt., Serbia) was refined using the X-ray powder diffraction (XRPD) Rietveld method in the space group Pbam to a final RB=7.45% and RF=5.26%. It has the unit cell dimensions of: a=9.2515(2) ?; b=12.3109(2) ?; c=3.03712(7) ?; and V=345.91(1) ?3. The calculated distances and angles are mostly in good agreement with the Mg2+-Fe2+ substitutions across the M(1) and M(3) sites, as well as with the Fe3+-Al3+ replacement in the M(4) site. However, the mean observed M(2)-O distance is considerably shorter than prescribed, due to a slight increase of the Fe3+ content in the M(2) site. Such replacement was compensated by slight increase of the Fe2+ content in the M(4) site, resulting in the (Mg1.48Fe2+0.46Fe3+0.05Mn0.02)2.01(Fe3+0.94Fe2+0.04Al0.02)1.00B1.00O5 composition. The formation temperature was estimated to be about 500–600°C. The influences of the various chemical compositions to the crystallographic parameters, M-O distances, M(3) and M(4) sites shift, distortion parameters and estimated valences, were also studied and compared with other reference samples.     

Land degradation analysis of mine-impacted zone of Kolubara in Serbia

This paper presents the effect of land-use changes on land degradation by utilization of remote sensing methods and the Gavrilovi? erosion potential method, due to surface mining activities in the period 2001–2011. Studied area includes the zone of influence of the Rudarski basen Kolubara, which covers the exploitation area of the Kolubara coal basin in the Republic of Serbia. The analysis is based on the processing of Landsat 5 satellite images from 2001 and 2011. In the analysis of satellite images, the supervised classification method was used. The results suggest that the observed spatial–temporal area is exposed to erosion as a result of land-use changes. Preliminary conclusion is that the dominant anthropogenic factor, responsible for changes in land use, is pronounced through the mining activity, industrialization, construction as well as agricultural activities. Very small changes in land use that occurred in the period 2001–2010 have led to relatively small amount of change from the aspect of land degradation. Also, due to the planned exploitation of the mine which included into account the sustainability of ecosystems, primarily through appropriate conservation measures, RB Kolubara is not in danger of a possible erosion processes that could undermine the stability of the basin.     

膨胀土堑坡稳定性分析

提出膨胀土堑坡稳定性分析时应考虑自然营力、膨胀力、孔隙水压力等因素的综合作用，详细讨论了这些因素对堑坡稳定性的影响，提出了膨胀力的作用规律，将这种综合分析方法应用于成都市三环路工程时，得出了较合理的结果。     

偏高岭土基地质聚合物原位水热合成P型沸石分子筛的研究

本文以偏高岭土基地质聚合物(SiO_2/Al_2O_3=3.2)为基体,通过水热合成法将其原位转化成P型沸石分子筛。研究水热温度、NaOH浓度及水热时间对P型沸石分子筛的结晶程度及形貌的影响,得到偏高岭土基地质聚合物原位合成P型沸石分子筛的适宜条件为:水热温度100℃,NaOH浓度2.0 mol/L,水热时间24 h。该法工艺简单,环境友好,可控成型。在此方法的基础上通过改变原材料和反应条件,可以合成其他类型的沸石分子筛。     

粉质黏土图像的纹理特征分析

粉质黏土通常为絮状结构, 难以使用肉眼直接判别出颗粒的形状和大小。将现场拍摄得到的粉质黏土彩色图像转化为灰度图像,得到了灰度图像灰度直方图的6个纹理特征参数（均值、方差、平滑度、3阶矩、能量、熵）。在建立灰度共生矩阵的基础上,得到了像素平面分布关系的5个纹理特征参数（角2阶矩、对比度、相关度、逆差矩、熵）。对这些纹理特征参数与粉质黏土传统工程性质指标进行了多元线性回归分析,得到了相应回归方程。结果表明,粉质黏土图像的纹理特征参数与传统工程性质具有较好的对应关系,可以用于快速确定粉质黏土的工程性质指标,对软土地区岩土工程设计具有一定的参考价值。     

Deformation analysis of shallow penetration in clay

A new method of analysis is described for estimating the deformations and strains caused by shallow undrained penetration of piles and caissons in clay. The formulation combines previous analyses for steady, deep penetration, with methods used to compute soil deformations due to near-surface ground loss, and is referred to as the Shallow Strain Path Method (SSPM). Complete analytical solutions for the velocity and strain rates are given for a planar wall, an axisymmetric, closed-ended pile and unplugged, open-ended pile geometries. In these examples, the analyses consider a single source penetrating through the soil at a constant rate, generating a family of penetrometers with rounded tips, referred to as simple wall, pile and tube geometries. Soil deformations and strains are obtained by integrating the velocity and strain rates along the particle paths. The transition from shallow to deep penetration is analysed in detail. Shallow penetration causes heave at the ground surface, while settlements occur only in a thin veneer of material adjacent to the shaft and in a bulb-shaped region around the tip. The size of this region increases with the embedment depth. Deformations inside an open-ended pile/caisson are affected significantly by details of the simple tube wall geometry. © 1997 by John Wiley & Sons, Ltd.     

Structure refinement of a nonstoichiometric pyroxene synthesized under ambient pressure

Structure refinement was carried out on a nonstoichiometric clinopyroxene grown under the ambient pressure from a glass with composition of 23%(mol)Di+53%Es+24%An. The degree of nonstoichiometry in this crystal is significantly larger than those of clinopyroxenes reported previously, which were found in high pressure products. The refinement gave the empirical chemical formula (Ca_0.742Fe_0.087)(Mg_0.016Al_0.888Fe_0.075)(Al_0.500Si_1.500)O₆ for the crystal and showed that vacancies are located mainly at M2 sites. Despite replacement of Si by Al, the crystal has a smaller cell volume than diopside primarily owing to a significant amount of Mg at M1 being replaced by Al. Received: 25 June 1997 / Revised, accepted: 6 September 1997     

Quantitative analysis of clay minerals and their admixtures

Clay minerals are of non uniform composition and particle size. Also their identification and nomenclature have given much confusion. Examples are given. Quantitative analysis of clay minerals from deposits and soils, by X-ray, thermo- and infrared analysis is treated. Examples are given of the large variability in the results; even for X-ray and electron microscope pure- and 85 to 90% chemical pure samples of kaolinite a well defined clay mineral. They are caused mainly by varying conditions of crystal growth from which result differences in isomorphous replacements, structure, ordering and strain. An amorphous weathering substance coating the mineral particles (Beilby layer) upsets in particular quantitative analyses of the finer kinds of clay minerals. Clay minerals from soils have, as compared to those from pure deposits, in particular formed by hydrothermal action, only poor characteristics of small intensity. Examples are given. Quantitative analyses are further hindered by specific characteristics for a certain mineral being masked by those of other minerals which usually occur in the same sample. Examples are given.     

Numerical analysis of sampling disturbances in clay soils

In this paper, an insight is provided into the quality of soil samples during the penetration of soil samplers. An updated Lagrangian finite element formulation with the second Piola–Kirchhoff stress rate (the Truesdell stress increment) to account for the large deformation behaviour near the sampling tube is used to determine the mechanical disturbances to a soft clay. The penetration of the sampler is simulated by splitting a group of nodes ahead of the penetration route up to a sufficient depth and applying incremental displacements to match the geometric configuration of the sampling tube. Consolidation effect is included to account for the rate of penetration. Thin-layer elements are added at the inside wall of the sampling tube to model the soil–sampler interface. The numerical results show that the central core of the sample is subjected to three distinct stages of vertical strain history, compression–extension–recompression, with the primary irrecoverable disturbances due to the compression stage ahead of the sampler. The degree of disturbance for a frictionless sampler was found to be constant after a penetration depth of 75 per cent of the sample tube diameter, while for a frictional sampler the degree of disturbances keeps increasing as the penetration proceeds. The results of a parametric study to determine the influence on sampling disturbances due to the rate of penetration, the thickness and the tip angle of the sample tube and sampler type are also presented.     

成都平原区成都粘土的粒度特征及其成因意义

对成都平原区内5个代表性的第四系剖面上的成都粘土进行了系统的粒度分析。结果表明,成都粘土以粉砂颗粒(5~50μm)为主,平均粒径约为7.1~7.3φ(7.4~6.6μm),缺少粗尾,>63μm颗粒的含量很少,以细颗粒物质为主,呈双峰分布。其粒度分布及粒度参数特征与北方黄土及甘孜黄土非常相似,而与河流相沉积物有很大差异,表明成都粘土属于风成堆积。根据光释光测年(OSL)结果,成都平原区的成都粘土是晚更新世中期至晚期末次冰期堆积物,其物质主体是远源的。     

扰动结构性软土地基的沉降特性分析

天然软黏土一般都具有一定的结构性,地基处理会改变结构性软土的工程特性。对比扰动软土原位和室内压缩曲线,分析了扰动软土的沉降机理及其压缩性的上下限,给出了考虑扰动影响的结构性软土沉降计算公式。算例分析表明,在孔隙比e0和0.42e0之间所对应的应力水平范围内,扰动会增加地基沉降量,附加沉降量大小与应力水平、扰动度直接相关,通常在0.1～0.3 m之间,但随着应力水平的提高,不同扰动度的结构性软土地基的最终沉降量将趋于相同,得出的有关结论具有工程参考价值。     

Geostatistical analysis of field hydraulic conductivity in compacted clay

Hydraulic conductivity(K) of fractured or porous materials is associated intimately with water flow and chemical transport. Basic concepts imply uniform flux through a homogeneous cross-sectional area. If flow were to occur only through part of the area, actual rates could be considerably different. Because laboratory values ofK in compacted clays seldom agree with field estimates, questions arise as to what the true values ofK are and how they should be estimated. Hydraulic conductivity values were measured on a 10×25 m elevated bridge-like platform. A constant water level was maintained for 1 yr over a 0.3-m thick layer of compacted clay, and inflow and outflow rates were monitored using 10×25 grids of 0.3-m diameter infiltration rings and outflow drains subtending approximately 1×1 m blocks of compacted clay. Variography of inflow and outflow data established relationships between cores and blocks of clay, respectively. Because distributions of outflow rates were much less and bore little resemblance to the distributions of break-through rates based on tracer studies, presence of macropores and preferential flow through the macropores was suspected. Subsequently, probability kriging was applied to reevaluate distribution of flux rates and possible location of macropores. Sites exceeding a threshold outflow of 100×10^–9 m/s were classified as outliers and were assumed to probably contain a significant population of macropores. Different sampling schemes were examined. Variogram analysis of outflows with and without outliers suggested adequacy of sampling the site at 50 randomly chosen locations. Because of the potential contribution of macropores to pollutant transport and the practical necessity of extrapolating small plot values to larger areas, conditional simulations with and without outliers were carried out. Simulated scenarios based on all available data compared well with conditional simulations based on randomly chosen locations.This paper was presented at MGUS 87 Conference, Redwood City, California, 14 April 1987.     

Elasto-plastic consolidation analysis for strutted excavation in clay

Ground movements and strut loads in strutted excavations in clay have been observed to change with time. In this paper, the time-dependent behaviour of excavation support system is studied by comparing the results of undrained and consolidation analyses with data from an instrumented excavation project. Dissipation of excess pore pressure is modelled using a fully coupled consolidation analysis while the soil is assumed to be an elastic-perfectly plastic material obeying the Mohr-Coulomb yield criterion. The results of the study show that the undrained analysis underestimates the sheet pile wall movement and fail to reflect the progressive movement of the sheet pile. In contrast, these effects are well-predicted by the consolidation analysis, thereby indicating that dissipation of excess negative pore pressure can indeed account for much of the observed progressive ground movement and build-up of strut loads with time. The elasto-plastic consolidation model can also simulate excavation sequence including uneven excavation and time delays in excavation and strutting.     

Adaptive finite element analysis of cone penetration in clay

This paper presents a numerical technique for the analysis of the cone penetration test by means of the commercial finite element code ABAQUS. The von Mises yield criterion with its associated flow rule is assumed to model the plastic behaviour of elastoplastic undrained clays. An explicit finite element scheme is used to efficiently perform a large number of loading increments and to simplify the treatment of contact. An Arbitrary Langrangian–Eulerian (ALE) scheme is adopted to preserve the quality of mesh throughout the numerical simulation. A volumetric weighting algorithm adjusts the relative positions of nodes after each loading increment. This prevents mesh over distortion and allows the simulation to run continuously. The variation of the cone resistance is examined in relation to various parameters such as the in situ stress state, shaft and cone face roughness, and the material strength when steady state conditions have been reached. The trends of these variations are highlighted and compared with those found by other researchers. This technique can be extended to analyse the plastic behaviour of elastoplastic sands often modelled using either the Drucker–Prager yield criterion or a critical state model.     

Optical second harmonic signals from clay minerals

Using a neodymium glass laser and time-synchronized pulse detection, second harmonic signals were observed from a number of clay mineral powders. The second harmonic generation (SHG) experiments provide the first physical evidence (other than diffraction patterns) for the polar nature of the kaolinite layer and its stacking sequences. Well-crystallized nacrite and dickite specimens gave signals comparable to those of quartz, but the SHG intensities from the smaller kaolinite and halloysite crystallites were noticeably weaker. Based on results from eight specimens, there appears to be a direct correlation between SHG intensity and particle size, similar to that reported previously for quartz.     

干法提纯新疆天然钠基膨润土制备防水毯原料的研究和经济分析

采用新疆天然钠基膨润土作为防水毯颗粒原料,通过中试和1∶ 1工业实验对原矿进行干法提纯,测试确定了最佳提纯工艺生产条件.实验证明,在最佳条件之下,产品的各种性能较原矿均有较大提高;在不添加任何其他辅料的情况下膨胀指数和吸蓝量就可以达到防水毯产品原料标准.相比湿法提纯工艺,该项研究可以直接指导工业生产,有十分重要的实际意义和经济意义.     

Assessment of air pollution originating from copper smelter in Bor (Serbia)

Air quality monitoring was performed at the measuring sites in the urban-industrial and suburban zone during the period 2005–2007 in Bor (Serbia). Arsenic, lead, cadmium, copper and sulphur dioxide are predominantly of industrial origin as a result of copper production in the study area. The smelter, which is a part of the Mining-Metallurgical Complex Bor, is the major pollution source. As and SO₂ are the pollutants which pose the biggest threat for the inhabitants of the Bor area, since the measured concentrations exceed the proposed limit values. The obtained concentrations showed that the endangered areas are in close vicinity of the smelter, as well as in the directions of the prevailing winds. By grouping these pollutants into separate clusters, the results of cluster analysis confirmed high loads of As and SO₂ in the air. The results of principal component analysis showed that copper production has major influence on air pollution.     

黏土地基中能量桩力学特性数值分析

能量桩是将地源热泵系统中的换热管埋置在桩体内部,桩同时起到承载和换热的作用,是一种新型的基础型式。为了合理分析黏土地基中能量桩的力学特性,需要了解能量桩运行过程中桩和地基土的温度响应,并考虑温度变化对土体力学性能的影响。基于有限元软件ABAQUS建立了能量桩传热分析三维有限元模型,把能量桩的传热简化为换热管内液体与管壁之间的对流传热、桩体中的热传导和地基中的热传导,将计算结果与常规理论和实测数据进行了对比验证。对热力耦合边界面本构模型进行了二次开发,通过算例验证了模型对土体压缩和剪切性状温度效应的模拟能力。利用所提出的能量桩传热分析方法和热边界面模型,考虑不同的桩顶工作荷载水平,对正常固结黏土地基中能量桩单桩的长期性能进行了研究,分析了温度循环对桩顶沉降、桩侧摩阻力和桩身轴力的影响。结果表明,工作荷载越高,温度循环次数越多,桩顶累积沉降越大。     

Modification of the subcontinental mantle beneath East Serbia: Evidence from orthopyroxene-rich xenoliths

Orthopyroxene-rich olivine websterite xenoliths (OWB₂) in Palaeogene basanites in East Serbia are mostly composed of tabular low-Al₂O₃ orthopyroxene (> 70 vol.%, Mg# 85–87) containing tiny Cr spinel inclusions. Orthopyroxene shows a slightly U-shaped primitive mantle-normalized trace element pattern with strong peaks at U and Pb, similar to that of orthopyroxene from normal regional peridotitic mantle. In between the orthopyroxenes are interstitial spaces composed of partially altered olivine (Mg# 85–87), clinopyroxene, Ti-rich spinel, Mg-bearing calcite, K-feldspar, apatite, ilmenite and relicts of a hydrous mineral. Clinopyroxene appears as selvages around orthopyroxene and as coarser euhedral crystals. Trace element patterns of the clinopyroxene selvages resemble those of adjacent orthopyroxene, whereas the coarser ones have flatter and more LREE- and LILE-enriched patterns, similar to that of metasomatic clinopyroxene. The OWB₂ xenoliths are interpreted as having formed in two stages. During Stage I orthopyroxene crystallized, along with some spinel, olivine and probably hydrous phase(s). This original OWB₂ lithology was a hydrous olivine-bearing orthopyroxenite that crystallised from subduction-related SiO₂-saturated, boninite-like magmas. During Stage II the interstitial minerals formed due to infiltration of a low-SiO₂, high-CaO and CO₂-rich external melt, accompanied by decomposition of original H₂O-bearing minerals. The calculated composition of the infiltrating liquid corresponds to a mafic alkaline melt similar to the basanitic host but more enriched in CO₂, LREE and LILE. Metasomatism is interpreted in terms of small degree melts related to the Palaeogene mafic alkaline magmatism.