秦岭旬阳盆地下古生界钠长石岩岩石学和地球化学特征

热水沉积钠长石岩在南秦岭上古生界中颇具特点，与南秦岭众多的大型、超大型铅锌成矿关系密切。最近，在南秦岭旬阳盆地下古生界铅锌矿集区内的志留系梅子垭组地层中首次识别出一条近东西方向延伸长达10余千米的钠长石沉积岩带，与地层整合产出，渐变过渡，厚层块状、条带状、角砾状构造，均粒微-细晶结构、内碎屑结构；其化学成分以富含SiO2、Al2O3及Na2O为特征，富Fe、Mn，贫Co、Ni、Cu等微量元素；该钠长石岩的∑KEE、LKEE、HREE均较围岩偏低，具明显Eu亏损的特征。球粒陨石标准化配分曲线为右倾曲线。通过与秦岭泥盆纪热水沉积钠长石岩的岩相学及岩石化学对比，结合本区下古生界属于扬子北缘被动陆缘裂谷环境，初步认为这里下古生界钠长石岩可能属于热水沉积成因。     

南秦岭旬阳志留系热水沉积钠长石岩地质地球化学特征

热水沉积钠长石岩在南秦岭上古生界中颇具特点,与南秦岭众多的大型超大型铅锌矿成矿关系密切.最近,在南秦岭旬阳下古生界铅锌矿集区内的志留系梅子垭组地层中首次识别出一条近东西方向延伸长达10余千米的钠长石沉积岩带,与地层整合产出,渐变过渡,厚层块状、条带状、角砾状构造.均粒微-细晶结构、内碎屑结构;矿物成分以石英和钠长石为主,铁白云石、镁电气石常见;化学组成以富含SiO2、Al2O3及Na2O为特征;富Fe、Mn,贫Co、Ni、Cu等微量元素;稀土元素配分曲线与围岩类似.但总量较囤岩偏低.钠长石岩中锆石形态、图像及SHIRMPU-Pb测年结果反映锆石为热液上升过程中捕获的基底及下佚地层柱中的碎屑锆石.结合该区下古生界属于扬子北缘被动陆缘裂谷环境,认为该钠长石岩属于热水沉积成因.     

南秦岭志留系铅锌矿床中硅质岩岩石学及地球化学

南秦岭泥盆系内产出的众多矿床中含有层纹条带状硅质岩-硅质板岩,对其成因的研究有助于查明矿床成因和确定区域找矿方向.研究表明,硅质岩化学成分纯净,SiO2含量多在90%以上.硅质岩中大部分微量元素含量低于地壳克拉克值,但富集Zn、Pb、As、Sb、Ag;硅质岩的Fe-Mn-(Cu+Ni+Co)×10图解表明硅质岩具热水沉积性质.硅质岩与矿石两者的稀土元素特点相似,具有ΣREE低(44.52×10-6)、轻重稀土分异较明显(LREE/HREE=6.51)、北美页岩标准化配分曲线呈平缓趋势、铈负异常不明显(δCe值为0.97)和铕正异常明显(δEu值为1.42)的特点;硅质岩的δ30Si为-0.5‰～0.0‰,δ18O为17.8‰～19.9‰,硅、氧同位素组成及形成温度(84～101℃)也暗示它为海底热水沉积成因.     

陕西南秦岭志留系中铅锌矿床地质地球化学特征研究

文章以泗人沟、南沙沟等铅锌矿床为例,讨论南秦岭志留系中铅锌矿床形成的地质地球化学特征。矿石稀土元素地球化学反映了矿石及金属硫化物矿物与地层的稀土配分曲线的一致性．说明成矿物质主体来自于地层;闪锌矿矿物的微量元素含量及一些特征值介于热液矿床和热水沉积矿床之间．属改造型;硫同位素组成结果表明矿石与地层硫同位素组成不一致,矿石较地层富集轻硫,可能反映了造山作用产生的热液使其硫同位素发生了一定程度的均一化或者有深源硫的参加,显示出矿石硫和地层硫的混合特征;流体氢氧同位素组成特征表明成矿介质可能是封存于深部的变质流体。这些矿床地球化学特点可能反映该区域铅锌矿床的最终定位与印支一燕山期的逆冲推覆构造有关。     

南秦岭花红树坪花岗闪长岩年代学及地球化学特征

对出露于南秦岭陕西省凤县境内的花红树坪花岗闪长岩体进行LA-ICP-MS锆石U-Pb年代学和岩石地球化学研究,获得岩体表面年龄为214.3±2.7Ma(MSWD=2.6),表明其形成时代为晚三叠世。岩体的SiO_2=61.45%~65.10%,TiO_2=0.52%~0.63%;Al_2O_3=14.97%~15.74%,Mg O=2.33%~3.02%,Mg#=51.31~53.61,高Sr(485×10-6~563×10-6)和Sr/Y(28.2~30.4),低Y(17.0×10-6~19.1×10-6)和Yb(1.46×10-6~1.83×10-6),微弱负Eu异常(δEu=0.83~0.99),具有明显高镁埃达克岩地球化学特征。结合区域地质背景,认为花红树坪岩体是后碰撞构造环境下加厚下地壳拆沉熔融与先存地幔岩浆交代混染作用下的产物,其可能与凤太矿集区多金属矿成矿关系密切。     

南秦岭城口火山岩锆石LA-ICP-MS U-Pb定年和地球化学研究

南秦岭大巴山城口断裂带出露一套玄武安山岩、安山岩组合,火山岩锆石LA-ICP-MS U-Pb定年测试结果为716±4Ma,表明其为新元古代岩浆产物;岩石地球化学研究表明火山岩富集轻稀土元素,原始地幔标准化微量元素蛛网图显示以富集大离子亲石元素Cs、Ba、Th、U及高场强元素分异为特征,Nb、Ta强烈亏损以及低的Ti(Ti O_20.85%)含量,与典型的岛弧火山岩相似;微量元素La/Nb、Th/Yb及Hf/Ta比值特征也显示岛弧岩浆属性,相对高的Zr/Y、Ta/Yb和低的Zr/Nb比值区别于大洋岛弧火山岩,具有明显的大陆亲缘性,表明城口火山岩形成于陆缘岛弧环境。综合已有的地质、地球化学及同位素年代学研究表明新元古代晚期扬子板块北缘及南秦岭地区为一活动陆缘岩浆杂岩弧,暗示中国华南板块很可能位于Rodinia超大陆的边缘部位。     

南秦岭古生代沉积岩的地球化学特征及其反映的区域地壳活动性

各类地质体的地球化学特征是地球物质化学运动的记录。深部岩石圈层次卷入地表地质作用的程度反映区域地壳的活动性。古生代南秦岭的区域地壳活动性在早古生代有增强的趋势,晚古生代则又逐渐减弱,以志留纪早期区域地壳活动性最强;空间上以紧邻松潘－甘孜地块的康县－褒河小区和紧邻扬子克拉通北缘的紫阳－竹溪小区构成的近东西向狭长地带区域地壳活动性最强,而且东西两段各有特色。这种区域地壳活动性的时空变化格局可能与新元古代至早古生代松潘－甘孜与扬子联合大陆北部边缘的地壳伸展及早古生代末与华北地台的碰撞拼合有关。     

南秦岭武当山十堰地区中生代镁铁质岩石成因与构造意义——岩石地球化学、锆石U-Pb年龄和Hf同位素制约

南秦岭的北大巴山—武当山—十堰—随州一带发育大规模的镁铁质岩墙群,其岩石学成因为地质学家所广泛关注。本文对其中的武当山十堰地区黄龙—方滩一带发育的辉长岩体开展了全岩地球化学、SHRIMP锆石U-Pb年龄以及LA—MC—ICP—MS锆石Hf同位素组成研究。结果表明,辉长岩形成于晚三叠世(221.2±2.5 Ma);岩石地球化学组成显示辉长岩为亚碱性拉斑玄武岩系列,轻稀土富集重稀土亏损,其平滑右倾的稀土配分模式与E—MORB相似;中等Ti、Zr、Hf、Nb含量,亏损Rb、Sr等大离子亲石元素,以及结晶年龄锆石的ε_(Hf)(t)值在-13.5至-6.18之间,表明岩石具有古老的两阶段Hf模式年龄(2103～1640 Ma)。综合分析表明:该套辉长岩岩浆为尖晶石二辉橄榄岩低压、中等程度部分熔融形成,并且其源区为亏损地幔与富集地幔组分混合成因;结合区域构造演化的相关资料,认为该套E—MORB性质辉长岩形成于类似汇聚边缘的构造环境,可能为受勉略洋壳俯冲影响,为俯冲—碰撞造山阶段产物。     

Petrology,geochemistry and tectonic significance of serpentinized ultramafic rocks from the South Arm of Sulawesi,Indonesia

Serpentinized ultramafic rocks occur in two separate basement complexes in the South Arm of Sulawesi, the Bantimala and Barru Blocks. We present petrographic, mineral chemical and geochemical data for these rocks, and interpret them in terms of petrogenesis and tectonic setting. The rocks of both blocks show strong serpentinization of original anhydrous silicates. The Bantimala ultramafics consist mainly of peridotite (harzburgite and dunite) and clinopyroxenite, with lenses of podiform chromitite. Metamorphism is evidenced by the occurrence of amphibolite-facies tremolite schist. In contrast, the Barru ultramafics consist of harzburgite peridotite and podiform chromitite, which also show an amphibolite-facies overprint that in this case may be related to intrusion by a large dacite/granodiorite body. Whole-rock trace element analyses and spinel compositions show that the Barru harzburgite is depleted relative to primitive mantle, and has had some melt extracted. In contrast, the Bantimala dunite, harzburgite and clinopyroxenite are cumulates. Both are derived from a supra-subduction zone environment, and were obducted during the closure of small back-arc basins. If there has been no rotation of the blocks, then the Bantimala ultramafics were emplaced from an ENE direction, while the Barru ultramafics were emplaced from the WNW. The ultramafic suites from these two blocks are juxtaposed with metamorphic assemblages, which were later intruded by younger volcanics, particularly in the Barru Block.     

沂水杂岩中超镁铁质岩的岩石地球化学特征

主要以捕虏体形式存在于沂水岩浆杂岩和变质杂岩中的超镁铁质岩石不发育鬣刺结构,岩石化学组成以高MgO和低SiO2、TiO2、K2O含量为主要特征。按岩石中是否含有橄榄石大致可以分为橄榄辉石岩和尖晶角闪二辉石岩两种,前者以强烈发育蛇纹石化为特征,矿物组合以单斜(透)辉石+橄榄石为主(偶见斜方辉石),蚀变矿物组合为蛇纹石±铬铁矿+磁铁矿±角闪石±尖晶石等;后者以局部发育滑石化为特征,矿物组合以斜方(古铜)辉石+单斜(透)辉石+尖晶石为主,其次是角闪石+磁铁矿±滑石等。岩石总体以稀土元素总量(∑REE)相对较低、LREE/HREE=1.64~4.40为特征,稀土元素的球粒陨石标准化配分图解显示所有样品均具Eu和Ce的负异常,除3个橄榄辉石岩样品外,多数样品无明显的轻稀土元素、轻重稀土元素和重稀土元素分异。岩石的微量元素组成以不相容元素Rb、Ba、U、Nb、Sr、Zr等具有明显不同的异常为特征:Ba、Nb呈现负异常,而Rb、U呈现正异常,Sr部分呈正异常,Zr和Ti负异常出现在橄榄辉石岩中,其他样品无Zr异常。样品YS0631的SHRIMP锆石U-Pb定年结果显示其变质锆石年龄值为2 560~2 605 Ma;另有一颗结晶锆石的年龄值为2 719 Ma,εHf(t)值为8.2,亏损地幔模式年龄为2 680 Ma。综上所述,该超镁铁质岩石源于地幔,形成于新太古代早期,随后遭受深熔及岩浆作用影响,经历了变质作用的改造。     

Petrology and geochemistry of boninite series volcanic rocks from the Mariana trench

Boninite series volcanic rocks have been recovered from three dredge hauls on the inner slope of the Mariana Trench. These hauls included olivine boninites, boninites, boninitic andesites and boninitic dacites, as well as island arc tholeiitic basalts and andesites. The boninite series volcanics range from 52 to 68% SiO₂, and are characterized by very low abundances of high-field-strength cations and heavy-rare-earth elements. Boninites and olivine boninites have phenocrysts of olivine and orthopyroxene, the andesites phenocrysts of orthopyroxene and clinopyroxene, and the dacites orthopyroxene, clinopyroxene, and plagioclase. Most of the major and trace element variation in the series from boninite to boninitic dacite can be modelled by fractionation of olivine, orthopyroxene, clinopyroxene, and plagioclase in the proportions 2.5412, leaving 47% residual liquid. The fractionation must be in part open-system: reverse zoned phenocrysts, resorbed olivine and plagioclase xenocrysts, and bulk rock compositions which cannot be fit by simple closed system crystallization indicate some magma mixing and phenocryst accumulation. Two boninitic magma stems can be identified, with similar high-field-strength element abundances, but different amounts of Ca, Na, Al and light-rare-earth elements. There is also evidence for a magma stem transitional in chemistry from the boninites to arc tholeiites. The compositions of these boninites are consistent with hypotheses for boninite formation by partial melting of a depleted mantle mixed with an incompatible element enriched fluid. The Mariana forearc boninite series lacks a strong iron enrichment, but produces andesites with lower Ti, Al and Y/Zr, and higher Mg, Ni and Cr than typical calcalkaline arc andesites and dacites. Boninites in the Mariana system were erupted only in the earliest phases of subduction zone activity.     

南秦岭勉略带铧厂沟火山岩锆石U-Pb年代学及地球化学研究

陕西省西南部铧厂沟火山岩以英安岩为主(～ 90vol％),夹玄武岩构造透镜体(～ 10vol％).玄武岩SiO2含量为43.6％ ～ 54.7％,具有低K、Ti,高Na、Mg的特征;稀土总量为24×10-6 ～29×10-6,中稀土轻微富集,Eu、Sr轻微正异常;具有正Rb、Ba异常及负Nb、Zr异常,LaN/YbN值为1.81 ～2.87,Th/Yb值为0.19 ～0.23,Th/Nb值为0.11 ～0.20,Nb/La值为0.26～0.70,Hf/Th值为0.50 ～ 0.67,显示亚碱性弧玄武岩的特征.英安岩SiO2含量为59.5％～ 72.3％,稀土总量较低(116×10-6～187 × 10-6),为右倾式配分模式,Eu负异常,富集大离子亲石元素(如Rb、Ba、Th、K等),亏损高场强元素(如Nb、P、Ti、Ta等),显示弧火山岩地球化学特征.获得玄武岩的锆石SHRIMP U-Pb年龄为801.7±4.7Ma (MSWD=1.18;n=12),英安岩的锆石LA-ICP-MS U-Pb年龄为802.1±5.3Ma (MSWD=1.02;n=19),二者在误差范.内一致.因此,铧厂沟火山岩是一套火山弧环境的亚碱性玄武质-英安质火山岩组合,表明新元古代曾有大洋板块向南俯冲到扬子古板块北缘之下;这套火山岩裹挟于泥盆系沉积地层中,与泥盆系地层一起,共同组成了一套由晚古生代-三叠纪勉略洋闭合所致的构造混杂岩带.     

Petrology and geochemistry of plutonic rocks in the Northwest Pacific Ocean and their geodynamic interpretation

The paper presents data on the petrology and geochemistry of plutonic rocks dredged from the Stalemate Fracture Zone, Northwest Pacific Ocean, during Cruise SO201-1 of the R/V “Sonne”. We proposed also the reconstruction of their formation conditions and interpretation of their tectonic evolution. The genesis of gabbroids found among plutonic rocks composing the Cretaceous-Paleogene basement of the northwestern part of the Pacific Ocean was related to magmatism at the ancient spreading center and provides record of the evolution of the parental magmatic melts of N-MORB. Along with related peridotites, basalts, and dolerites, these rocks can be attributed to the disintegrated the Cretaceous-Paleogene oceanic lithosphere of the Pacific Ocean. The shallow mantle beneath the ancient oceanic crust of this area is made up of depleted magmatic spinel lherzolite, harzburgite, and dunite. The fact that gabbro-diorite and diorite that are not genetically related to the rocks of the Cretaceous-Paleogene basement of the Northwest Pacific occur at the eastern termination of the Stalemate Fracture Zone possibly reflects the complicated structure of the tectonic collage of rocks of different age that were produced in different geodynamic environments and were later tectonically brought together near the frontal portion of the Aleutian island arc. Judging by the isotopic-geochemical characteristics of these rocks, they cannot be classed with the family of oceanic plagiogranites. Deformations of the oceanic basement can be discerned throughout the whole Stalemate Fracture Zone as brecciation and large-amplitude vertical displacements within the oceanic lithosphere.     

Petrology and geochemistry of Mesozoic granitic rocks from the Nansha micro-block, the South China Sea: Constraints on the basement nature

There are several micro-blocks dispersed in the South China Sea (SCS), e.g., Xisha-Zhongsha block, Nansha block and Reed-Northeastern Palawan block, etc., but detailed petrological constraints on their basement nature were previously lacking. The magmatic ages for granitic rock samples from two dredge stations in the Nansha micro-block vary from 159 to 127 Ma, which are comparable to magmatic activities occurred in the northern margin (Pearl river mouth), HongKong and East China. Petrographic characteristics, major-, trace element and Sr–Nd isotopic data of nine samples from two dredged station performed in the Nansha micro-block, the SCS, are reported. Petrographically, these granitic rocks can be divided into two groups which underwent a complex history of magmatic process, i.e., tonalitic rock (Group I) and monzogranitic rock (Group II). The Rittmann index (σ) for these rocks (1.9–3.1) suggest that they belong to calc-alkaline rocks. Group I rocks which is of typical I-type, have higher contents of TiO₂, Al₂O₃, FeO, MgO, CaO, Na₂O and P₂O₅, but lower values of SiO₂ and K₂O, when compared with those of Group II with I-type characteristics. Group I rocks are produced by partial melting of older Precambrian basement with the variable influence of mantle-derived magma which results from the interaction of released fluids from the subducted slab and the overlying mantle wedge in a general convergent margin setting, and Group II rocks result from partial melting of lower crustal basic rocks (amphibolite) and/or further partial melting of the Group I rocks associated with the variable influence from the underplating mantle-derived magma resulting from lithospheric extensional regime. Both Groups I and II have undergone assimilation and fractional crystallization (AFC) processes during its petrogenesis. This study therefore demonstrates that there exists a continental basement within micro-blocks in the South China Sea, and further supports the idea that a Middle Jurassic to Mid-Cretaceous subduction zone existed across the temporary Taiwan, Palawan to Southern Vietnam, which was associated with westward to northestward convergence of the Pacific Plate during Late Mesozoic. We suggest that this subduction zone may have been connected with the paleo-Pacific plate subduction zone offshore eastern China during Mesozoic era. This study provides petrologic data for the pre-Cenozoic tectonic evolution of the South China Sea.     

辽西白塔地区侏罗纪火山岩岩石学、同位素年代学与地球化学特征

出露于辽西白塔地区的侏罗纪中酸性火山岩及火山碎屑岩组合,主要是由粗安岩、流纹质岩屑晶屑熔结凝灰岩、粗面英安岩和流纹岩组成。通过系统的LA-ICPMS锆石的U-Pb同位素年代学研究,研究区火山岩形成年代为165~149 Ma。岩石地球化学特征显示,酸性火山岩属于钙碱性火山岩系,中性火山岩分别属于碱性火山岩系和中-高钾钙碱性火山岩系,中性岩具有埃达克质岩的地球化学特征,SiO_2≥56.20%、Al_2O_3≥15.09%、MgO≤2.89%、Sr≥561×10~(-6)、Y≤13.15×10~(-6)、Yb≤1.47×10~(-6)和无明显Eu异常。研究区火山岩普遍具有富集大离子亲石元素(Rb、K、Ba、Sr、Pb)和轻稀土元素,亏损高场强元素(Ti、Nb、Ta、P)的特征。其原始岩浆来源于基性下地壳物质的部分熔融,形成于古太平洋板块俯冲影响下板内挤压造山的构造环境。     

Petrology and geochemistry of the archean rocks of the malton gneiss complex,British Columbia

Hornblendic and felsic groups of Archean age and each of broadly similar geochemical composition across the Malton Gneiss Complex southeast of Valemount, Bristish Columbia, show detailed mineralogical and chemical variations from one geographical district to another. The complex appears to be composed of meta-igneous rocks which were originally developed as petrologically discrete units on a roughly 10-km scale, but which all belonged to one similar petrographic province. Overall they are characterized by rather high immobile trace and alkali element abundances. Their nearest geochemical equivalent appear to be found in the grey gneiss complexes of the North Atlantic Craton rather than in the granite-greenstone complexes of the Canadian Shield, but no other Archean complex possesses their overall characteristics. Some similarities in A-F-M and Q-Ab-Or content of these gneisses and those of the Laramie Range, Wyoming, are noted.