Deformation and Compression Behaviour of a Cement–Bentonite Slurry for Groundwater Control Applications

Cement bentonite (CB) barriers are self-supporting, low permeability, structures used to retard groundwater flow and as such strength and hydraulic conductivity parameters are often stipulated when developing the mixtures. This paper reports an investigation into the deformation and compression behaviour of a CB containing ground granulated blastfurnace slag using the unconfined compressive strength apparatus, triaxial (undrained, unconsolidated) and oedometer. Samples were also exposed to drying and rewetting to investigate possible response to changes in environmental conditions. Cracking was observed prior to peak stress suggesting that the hydraulic conductivity of a barrier may be adversely affected before the shear strength is reached in undrained conditions. The compression response of CB indicates the presence of a threshold stress; once exceeded the magnitude of settlements are significantly greater than those encountered below this threshold. If a barrier experiences localised changes in loading conditions then there is the potential for damage from induced differential settlements; thus it is recommended that the threshold stress should also be considered at the design stage in addition to strength and hydraulic conductivity requirements. The response of the material exposed to drying-rewetting was unexpected and requires further investigation to determine how a barrier will respond to changing environmental conditions.     

Portland Cement Stabilization of Soil–Bentonite for Vertical Cutoff Walls Against Diesel Oil Contaminant

The objective of this study was to evaluate the effect of water-cement ratio and cement content on the hydraulic behavior of soil–cement–bentonite (SCB) and soil–bentonite (SB) mixtures permeated with water and diesel oil, to assist with the design of vertical cutoff walls constructed with those mixtures. The experimental program included unconfined compression tests, hydraulic conductivity tests and X-ray diffraction analysis. The test results indicated changes in hydraulic conductivity take place due to the variation of the water-cement ratio and permeant fluid. The hydraulic conductivity of the SB mixtures permeated with diesel oil was higher than the hydraulic conductivity of the same samples permeated with water. X-ray diffraction analyses suggest that this might be due to the decrease in double layer thickness and increase of seepage pore space imparted by diesel oil permeation. Conversely, Portland cement addition increased the hydraulic conductivity of the SCB specimens permeated with water, whereas subsequent diesel oil permeation reduced the hydraulic conductivity of the SCB specimens; this might be due to the relatively lower impact imparted by diesel permeation on the double layer characteristics of the bentonite stabilized with Portland cement.     

Recent Development in Simultaneous Multi-Element Determination of the Platinum Group Elements and Gold in Geological and Environmental Samples

In recent years, the modern methods of multi-element analysis of precious metals have attracted wide attention in scientific research and industry. The application and development in the decomposition of samples, separation and enrichment, and modern instrumental analysis of the platinum-group elements (PGEs) and gold in geological and environmental samples have been reviewed. Finally, the tendency of analysis of precious metals is also prospected.     

Laboratory Investigation of the Influence of Geotextile on the Stress–Strain and Volumetric Change Behavior of Sand

This paper presents the results of triaxial tests conducted for the investigation of the influence of geotextile on both the stress–strain and volumetric change behavior of reinforced sands. Tests were carried out on loose sand. The experimental program includes drained compression tests on samples reinforced with different values of both geotextile layers (1 ≤ Ng ≤ 3) and confining pressure (\(\upsigma_{\text{c}}^{\prime }\)) varying from 50 to 200 kPa. Tests show that the contribution of geotextile is negligible until an axial strain threshold that range between 2.5% for a confining pressure of 50 kPa to lower than 1% for 100 and 200 kPa confining pressure. At higher values of ε_a, geotextile induces a quasi-linear increase in the stress deviator (q) and volume contraction in the reinforced sand. Tests show a negligible influence of the number of geotextile layers (Ng) on the contribution of geotextile to both stress–strain and volumetric change, when normalized with Ng. Tests also show that the contribution of geotextile to the stress–strain mobilization augments with the increase in the confining pressure, while its contribution to the volume contraction decreases with the increase in the confining pressure. The reinforced soil becomes contracting in the case of 2 and 3 geotextile layers.     

Evaluation of Engineering and Cement–Stabilization Parameters of Clayey–Sand Mixtures under Soaked Conditions

Clay soils, especially clay soils of high or very high swelling potential often present difficulties in construction operations. However, the engineering properties of these clay soils can be enhanced by the addition of cement, thereby producing an improved construction material. Higher strength loss of cement stabilized clay soils after soaking in water is attributed to water absorbing capacity of the clay fraction (e.g. montmorillonite). Kaolinite and illitic soils are largely inert and resist to water penetration. These clays generally develop satisfactory strengths resulting to low strength reduction [Croft, 1967]. The swelling clays such as bentonite soaked in water, due to environmental conditions, result to volume increase causing macro and micro-fracturing in engineering structures. These fractures accelerate water penetration and consequently cause greater strength loss [Sällfors and Öberg-Högsta, 2002]. The water intrusion during soaking creates swelling and disrupts the cement bonds. The development of internal and external force systems in soil mass, due to soaking conditions, establish the initiation of slaking. Internal force system of a stabilized clayey soil consists of the resultant stresses established by the bonding potential of a cementing agent and the swelling potential of a clay fraction. In an effort to study this influence of soaking conditions and final absorbed water content on the stabilization parameters (cement, compaction, curing time), both unconfined compressive strength and slaking (durability) tests were carried out on two different cement stabilized clayey mixtures consisted of active bentonite, kaolin and sand.     

Study on the Erodibility and Mechanical Resistance of Mulches Prepared from Micro Silica–Cement Mixtures

Geotechnical and Geological Engineering - Mulching is fastest strategy to control sand dune movement in arid and semiarid areas. In the present study the effect of micro silica- cement mixture was...     

Design Method of Slurry Volume–Weight in Trenching Construction of Underground Diaphragm Wall in Soft Stratum

Using the limit equilibrium analysis method, a global and a local stability mechanical models of trench wall in trenching construction of underground diaphragm wall were established, respectively, and the calculation formulas of critical slurry volume–weight, which can ensure the trench wall stable during trenching construction of underground diaphragm wall, were derived. And then, a design method of slurry volume–weight in trenching construction of underground diaphragm wall in soft stratum was formed, and also an application example was carried out. The results show that the design method of slurry volume–weight advanced in this paper is reliable, and in the similar projects (i.e., sand pebble stratum), the slurry volume–weight calculated by the local stability model of trench wall is more suitable.     

Investigation of groundwater mineralization in the Hammamet–Nabeul unconfined aquifer,north-eastern Tunisia: geochemical and isotopic approach

Detailed hydrogeochemical and isotopic data of groundwaters from the Hammamet–Nabeul unconfined aquifer are used to provide a better understanding of the natural and anthropogenic processes that control the groundwater mineralization as well as the sources of different groundwater bodies. It has been demonstrated that groundwaters, which show Na–Cl and Ca–SO₄–Cl water facies, are mainly influenced by the dissolution of evaporates, the dedolomitization and the cation-exchange process; and supplementary by anthropogenic process in relation with return flow of irrigation waters. The isotopic signatures permit to classify the studied groundwaters into two different groups. Non-evaporated groundwaters that are characterized by depleted δ ¹⁸O and δ ²H contents highlighting the importance of modern recharge at higher altitude. Evaporated groundwaters with enriched contents reflecting the significance infiltration of return flow irrigation waters. Tritium data in the studied groundwaters lend support to the existence of pre-1950 and post-1960 recharge. Carbon-14 activities in shallow wells that provide evidence to the large contamination by organic ¹⁴C corroborate the recent origin of the groundwaters in the study area.     

Rb–Sr and Sm–Nd study of granite–charnockite association in the Pudukkottai region and the link between metamorphism and magmatism in the Madurai Block

Pudukkottai region in the northeastern part of the Madurai Block exposes the garnetiferous pink granite that intruded the biotite gneiss. Charnockite patches are associated with both the rock types. Rb–Sr biotite and Sm–Nd whole-rock isochron ages indicate a regional uplift and cooling at ～550 Ma. The initial Nd isotope ratios (\(\varepsilon _{\text {Nd}}^{\mathrm {t}}=-20\) to ?22) and Nd depleted-mantle model ages (T_DM = 2.25 to 2.79 Ga) indicate a common crustal source for the pink-granite and associated charnockite, while the biotite gneiss and the charnockite within it represent an older crustal source (\(\varepsilon _{\text {Nd}}^{\mathrm {t}}= -29\) and T_DM = > 3.2 Ga). The Rb–Sr whole-rock data and initial Sr–Nd isotope ratios also help demonstrate the partial but systematic equilibration of Sr isotope and Rb/Sr ratios during metamorphic mineral-reactions resulting in an ‘apparent whole-rock isochron’. The available geochronological results from the Madurai Block indicate four major periods of magmatism and metamorphism: Neoarchaean–Paleoproterozoic, Mesoproterozoic, mid-Neoproterozoic and late-Neoproterozoic. We suggest that the high-grade and ultrahigh-temperature metamorphism was preceded by magmatism which ‘prepared’ the residual crust to sustain the high P–T conditions. There also appears to be cyclicity in the tectono-magmatic events and an evolutionary model for the Madurai Block should account for the cyclicity in the preserved records.     

Water–Rock Interactions: An Investigation of the Relationships Between Mineralogy and Groundwater Composition and Flow in a Subtropical Basalt Aquifer

A holistic study of the composition of the basalt groundwaters of the Atherton Tablelands region in Queensland, Australia was undertaken to elucidate possible mechanisms for the evolution of these very low salinity, silica- and bicarbonate-rich groundwaters. It is proposed that aluminosilicate mineral weathering is the major contributing process to the overall composition of the basalt groundwaters. The groundwaters approach equilibrium with respect to the primary minerals with increasing pH and are mostly in equilibrium with the major secondary minerals (kaolinite and smectite), and other secondary phases such as goethite, hematite, and gibbsite, which are common accessory minerals in the Atherton basalts. The mineralogy of the basalt rocks, which has been examined using X-ray diffraction and whole rock geochemistry methods, supports the proposed model for the hydrogeochemical evolution of these groundwaters: precipitation + CO₂ (atmospheric + soil) + pyroxene + feldspars + olivine yields H₄SiO₄, HCO₃ ⁻, Mg²⁺, Na⁺, Ca²⁺ + kaolinite and smectite clays + amorphous or crystalline silica + accessory minerals (hematite, goethite, gibbsite, carbonates, zeolites, and pyrite). The variations in the mineralogical content of these basalts also provide insights into the controls on groundwater storage and movement in this aquifer system. The fresh and weathered vesicular basalts are considered to be important in terms of zones of groundwater occurrence, while the fractures in the massive basalt are important pathways for groundwater movement.     

Reconstructing in space and time the closure of the middle and western segments of the Bangong–Nujiang Tethyan Ocean in the Tibetan Plateau

International Journal of Earth Sciences - When and how the Bangong–Nujiang Tethyan Ocean closed is a highly controversial subject. In this paper, we present a detailed study and review of the...     

Age of Carbonates and Phosphorites in the Sedimentary Cover of the Tuva–Mongolian Microcontinent

The ages of the two main stages of carbonate cover formation within the Tuva–Mongolian microcontinent have been determined. The Pb–Pb age and Sr–chemostratigraphic characteristics of the carbonate rocks of the Irkutnaya, Agaringol, and Zabita formations, as well as of the Zabita Formation phosphorite, demonstrate that the first stage began in the Middle Riphean (Late Ectasian) at about 1290 Ma and the second stage started in the Early Vendian (Early Ediacaran) at 630–600 Ma. The accumulation of phosphorite deposits started in the Ediacaran at about 580 Ma.     

Secondary alterations of globular and platy phyllosilicates of the glauconite–illite series in the Precambrian and Vendian–Cambrian rocks

Previously published and new data on secondary transformations of the globular and platy phyllosilicates of the glauconite–illite series from the Upper Proterozoic terrigenous rocks of the Olenek and Anabar uplifts (East Siberia), Srednii Peninsula (Murmansk coast), and Vendian–Cambrian boundary rocks of the Podolian Dniester area (Ukraine) are generalized for the first time. Plastic deformation, aluminization, chloritization, berthierinization, as well as replacement of phyllosilicates of different morphology by corrensite- chlorite and pyrite at different lithogenesis stages, are considered and lithological-mineralogical characteristics of the glauconite-bearing rocks are reported. The structural, crystal-chemical, genetic, and isotopegeochronological features of di- and trioctahedral phyllosilicates are discussed.     

Peculiarities of Subduction in the Junction of the Kuril–Kamchatka and Aleutian Island Arcs

Doklady Earth Sciences - The peculiarities of the junction between the Kuril–Kamchatka and Aleutian island arcs are studied using different techniques and experimental data. The models of...     

Factors and Trends in the Formation of Natural–Technogenic Associations of Polycyclic Aromatic Hydrocarbons in the Snow–Soil System

Doklady Earth Sciences - The content of polycyclic aromatic hydrocarbons (PAHs) in soil and snow cover near the carbon black plants in Moscow, Omsk, and Samara regions was studied. The differences...     

Formation of the disk structure and jets in the symbiotic system Z and during periods of activity in 2006–2010

We present an analysis of spectrophotometric observations of the latest cycle of activity of the symbiotic binary Z And from 2006 to 2010. We estimate the temperature of the hot component of Z And to be ≈150 000−170 000 K at minimum brightness, decreasing to ≈90 000 K at the brightness maximum. Our estimate of the electron density in the gaseous nebula is N _e = 10¹⁰−10¹² cm⁻³ in the region of formation of lines of neutral helium and N _e = 10⁶−10⁷ cm⁻³ in the region of formation of the [OIII] and [NeIII] nebular lines. A trend for the gas density derived from helium lines to increase and the gas density derived from [OIII] and [NeIII] lines to simultaneously decrease with increasing brightness of the system was observed. Our estimates show that the ratios of the theoretical and observed fluxes in the [OIII] and [NeIII] lines agree best when the O/Ne ratio is similar to its value for planetary nebulae. The model spectral energy distribution showed that, in addition to a cool component and gaseous nebula, a relatively cool pseudophotosphere (5250–11 500 K) is present in the system. The simultaneous presence of a relatively cool pseudophotosphere and high-ionization spectral lines is probably related to a disk-like structure of the pseudophotosphere. The pseudophotosphere formed very rapidly—over several weeks—during a period of increasing brightness of Z And. We infer that in 2009, as in 2006, the activity of the system was accompanied by a collimated bipolar ejection of matter (jets). In contrast to the situation in 2006, the jets were detected even before the system reached its maximum brightness. Moreover, components with velocities close to 1200 km/s disappeared at the maximum, while those with velocities close to 1800 km/s appeared.     

Timing of Back–Arc Spreading of the Paleozoic Island Arc of the Urals: Implication of Sm–Nd and U–Pb Dating of Dolerites and the Composition of Inclusions in Zircon

Doklady Earth Sciences - Dolerites of the parallel dikes formed in a back-arc spreading setting have been dated by Sm–Nd to the Silurian (426 ± 34 Ma) for Mount Azov in the Central...