The charge state in a highly dense molecular cloud

We have calculated the desorption rates of both physisorbed and chemisorbed ions from grain surfaces, due to the temperature increase at densities higher than 10^–13 g cm^–3. It has been found that physisorbed ions desorb from grain surfaces at neutral densities ofn>1.3×10¹¹ cm^–3, assuming that the desorption energyD is equal to 0.1 eV, while the desorption of chemisorbed ions from grain surface can only occur at neutral densities ofn>10¹⁵ cm^–3, at which point thermal ionization becomes more dominant.The electrons are assumed to be emitted from grain surfaces in a manner similar to the thermonic emission from heated solid surfaces. It was found that the temperature at which electrons are emitted from negatively charged grains depends on the value of the work function of the material of the grain.The charge state has been calculated for two limiting cases. Neglecting the grain surface reactions in case 1, the resulting relative charge density represents an upper limit, such that the electrical conductivity remains high. In this situation the magnetic flux dissipation is mainly contributed by ambipolar diffusion. In the second case, it has been assumed that the charged particles are chemically adsorbed on grain surfaces such that their desorption is negligible. In this case the charge density decreases sharply with increase of neutral density. Therefore, the electrical conductivity decreases sufficiently and Ohmic dissipation becomes effective.     

The Physics and Chemistry of Sputtering by Energetic Plasma Ions

Energetic ions from the solar wind, local pick-up ions or magnetospheric plasma ions impact the atmospheres and surfaces of a number of solar system bodies. These energetic incident ions deposit energy in the gas or solid. This can lead to the ejection of atoms and molecules, a process referred to as sputtering. In this paper we first describe the physics and chemistry of atmospheric and surface sputtering. We then apply this to the production of a thin atmosphere on Europa by magnetospheric ion bombardment of Europa's surface and show that Europa loses more Na atoms than it receives from the Jupiter magnetosphere. The loss of atmosphere from Mars in earlier epochs by pick-up ion sputtering of that atmosphere is also calculated. This revised version was published online in July 2006 with corrections to the Cover Date.     

GEOS-2 measurements of cold ions in the magnetosheath

The Suprathermal Plasma Analysers on GEOS-2 are able to make differential energy measurements of plasma particles down to sub-eV energies because the entire sensor package can be biased relative to the spacecraft. When the package is biased negatively with respect to space potential, low energy positive ions are sucked in and are more easily detected against the background. Large fluxes of ions with temperatures of the order of 1 eV or less were consistently detected at space potential when the spacecraft was in the magnetosheath though not when it was in the nearby magnetosphere. This apparent geophysical correlation, suggesting that the ions were part of the magnetosheath ion population, was contradicted by the fact that the ions showed no signs of the large drift velocity associated with the electric field in the magnetosheath. We conclude, after further investigation, that the observed ions were probably sputtered as neutrals from the spacecraft surface by the impact of solar wind ions and subsequently ionized by sunlight or electron impact. The effect of sputtering by solar wind ions has not been previously observed, although it could have consequences for the long-term stability of spacecraft surfaces.     

Proton Irradiation of Centaur,Kuiper Belt,and Oort Cloud Objects at Plasma to Cosmic Ray Energy

Times for accumulation of chemically significant dosages on icy surfaces of Centaur, Kuiper Belt, and Oort Cloud objects from plasma and energetic ions depend on irradiation position within or outside the heliosphere. Principal irradiation components include solar wind plasma ions, pickup ions from solar UV ionization of interstellar neutral gas, energetic ions accelerated by solar and interplanetary shocks, including the putative solar wind termination shock, and galactic cosmic ray ions from the Local Interstellar Medium (LISM). We present model flux spectra derived from spacecraft data and models for eV to GeV protons at 40 AU, a termination shock position at 85 AU, and in the LISM. Times in years to accumulate dosages ～100 eV per molecule are computed from the spectra as functions of sensible surface depth less than one centimeter at unit density.The collisional resurfacing model of Luu and Jewitt is reconsidered in thecontext of depth-dependent dosage rates from plasma, suprathermal,and higher energy protons, and global exposure, by micrometeoroiddust grain impacts, of moderately irradiated red material below athin crust of heavily irradiated neutral material. This material should be more visible on dynamically `cold’ objects in the ～40 AU region.     

X-ray probes of magnetospheric interactions with Jupiter's auroral zones, the Galilean satellites, and the Io plasma torus

Remote observations with the Chandra X-ray Observatory and the XMM-Newton Observatory have shown that the jovian system is a source of X-rays with a rich and complicated structure. The planet's polar auroral zones and its disk are both powerful sources of X-ray emission. Chandra observations revealed X-ray emission from the Io plasma torus and from the Galilean moons Io, Europa, and possibly Ganymede. The emission from the moons is due to bombardment of their surfaces by highly energetic magnetospheric protons, and oxygen and sulfur ions. These ions excite atoms in their surfaces leading to fluorescent X-ray emission lines. These lines are produced against an intense background continuum, including bremsstrahlung radiation from surface interactions of primary magnetospheric and secondary electrons. Although the X-ray emission from the Galilean moons is faint when observed from Earth orbit, an imaging X-ray spectrometer in orbit around one or more of these moons, operating from 200 eV to 8 keV with 150 eV energy resolution, would provide a detailed mapping of the elemental composition in their surfaces. Surface resolution of 40 m for small features could be achieved in a 100-km orbit around one moon while also remotely imaging surfaces of other moons and Jupiter's upper atmosphere at maximum regional resolutions of hundreds of kilometers. Due to its relatively more benign magnetospheric radiation environment, its intrinsic interest as the largest moon in the Solar System, and its mini-magnetosphere, Ganymede would be the ideal orbital location for long-term observational studies of the jovian system. Here we describe the physical processes leading to X-ray emission from the surfaces of Jupiter's moons and the properties required for the technique of imaging X-ray spectroscopy to map the elemental composition of their surfaces, as well as studies of the X-ray emission from the planet's aurora and disk and from the Io plasma torus.     

Low energy ions in the shuttle environment: Evidence for strong ambient-contaminant interactions

The quadrupole mass spectrometer flown by the Air Force Geophysics Laboratory on STS-4 in 1982 detected large intensities of several ions, primarily O⁺, H₂O⁺ and H₃O⁺, with energies less than 1.5 e V with respect to the Shuttle Orbiter. Ion-molecule reactions and non-reactive scattering between the outgassing neutral flux from the Orbiter surfaces and the ambient ionic species are identified as the primary source of these low energy ions.     

Chemical analysis of mineral dust grains by SIMS: Application to a cometary mission

Analysis of a dust sample (e.g. collected during a cometary rendezvous mission) by SIMS (Secondary Ion Mass Spectroscopy) can provide information on elemental abundances (? 100 amu), the molecular composition of grain surfaces, and isotopic ratios of selected elements. This can be accomplished with dust covering as little as 10^?4 of the collector surface area. In order to demonstrate these capabilities a special experimental set-up for substrate preparation, dust collection and SIMS analysis of dust under ultrahigh vacuum conditions was developed. The comparison of elemental abundance ratios for different olivines and pyroxenes measured with the special SIMS equipment with that measured by an electron microprobe indicated an accuracy for SIMS of the elemental abundance measurements of ? 30%. By varying the energy threshold of secondary ions to be mass-analysed from 0 to 50 eV it is possible to identify molecular ions in the spectra and to estimate their abundance with respect to elemental ions on the same mass line. The ratios of molecular to elemental ions vary by a factor of 1–25. The concept for a future cometary rendezvous experiment as well as first results of chemical investigation on mineral dust samples obtained are reported.     

Implantation of carbon and nitrogen ions in water ice

Solid surfaces of atmosphereless objects in the Solar System are continuously irradiated by energetic ions (from solar wind and flares, planetary magnetospheres, and cosmic rays). Reactive ions (e.g., H, C, N, O, S) induce all of the effects of any other ion including the synthesis of molecular species originally not present in the target. In addition, these ions have a chance, by implantation in the target, of forming new species containing the projectile. An ongoing research program performed at our laboratory aims at investigating the implantation of reactive ions in many relevant ices (and mixtures) by using IR spectroscopy. Here we present new results obtained by implanting carbon and nitrogen ions in water ice at 16 and 77 K. Carbon implantation produces carbon dioxide and the production yield has been measured. Nitrogen implantation does not produce any N-bearing species detectable by IR spectroscopy. Both ions are also capable of synthesizing hydrogen peroxide at the two investigated temperatures. We show that, although a relevant quantity of CO₂ can be formed by C implantation in the icy jovian moons, this is not the dominant formation mechanism of carbon dioxide.     

Ion irradiation experiments and nitrogen bearing species on Jovian and Saturnian icy surfaces

Implantation of reactive ions into targets of planetary interest is a relevant subject to be studied in the laboratory. It could in fact produce new molecular species that are not native to those surfaces. Presented here are new laboratory results obtained by nitrogen implantation (15–30 keV N⁺) on frozen mixtures of H₂O:CH₄ (2:1). These species have been chosen in view of their possible presence on the surface of Jovian and Saturnian satellites and rings. In fact these surfaces are exposed to intense irradiation by magnetospheric and/or solar energetic particles. The laboratory investigation utilizes IR spectroscopy. The main objectives of the present study are to identify newly produced species and to verify if these (or at least if the profile of their IR bands) are different from those produced by unreactive ions impinging on targets in which nitrogen is already present, occurring in the form of frozen NH₃ (Strazzulla and Palumbo, 1998) or N₂ (Palumbo et al., 1999). I find that CN-bearing group is in fact formed and its IR feature has a profile (peak position and band profile) that differs from that obtained after irradiation or frozen gases containing nitrogen. The relevance the results might have to elucidate the origin of some species observed on Jovian icy moons or predicted to be observed on Saturnian satellites are outlined.     

Elastic collisions in ion irradiation experiments: A mechanism for space weathering of silicates

Ion irradiation experiments have been performed on silicates (bulk samples) rich of olivine, pyroxene, and serpentine to simulate the effects of space weathering induced on asteroids by solar wind ions. We have used different ions (H⁺, He⁺, Ar⁺, Ar²⁺) having different energies (from 60 to 400 keV) to weather the samples, probed by Raman spectroscopy and UV-vis-NIR reflectance spectroscopy. All the irradiated materials have shown reddening and darkening of reflectance spectra in the 0.25-2.7 μm spectral range. We have found that the increase of the spectral slope of the continuum across the 1-μm band is strongly related with the number of displacements caused by colliding ions because of elastic collisions with the target nuclei. The spectral slopes have been compared, at increasing ion fluence, with those from irradiated Epinal meteorite. We show that formation of nuclear displacements by solar wind ion irradiation is a physical mechanism that reddens the asteroidal surfaces on a time-scale lower than 10⁶ years.     

Optical alteration of complex organics induced by ion irradiation:: 1. Laboratory experiments suggest unusual space weathering trend

Most ion irradiation experiments relevant to primitive outer Solar System objects have been performed on ice and silicate targets. Here we present the first ion irradiation experiments performed on natural complex hydrocarbons (asphaltite and kerite). These materials are very dark in the visible and have red-sloped spectra in the visible and near-infrared. They may be comparable in composition and structure to refractory organic solids on the surfaces of primitive outer Solar System objects. We irradiated the samples with 15-400 keV H⁺, N⁺, Ar⁺⁺, and He⁺ ions and measured their reflectance spectra in the range of 0.3-2.5 μm before ion implantation and after each irradiation step. The results show that irradiation-induced carbonization gradually neutralizes the spectral slopes of these red organic solids. This implies a similar space weathering trend for the surfaces of airless bodies optically dominated by spectrally red organic components. The reduction of spectral slope was observed in all experiments. Irradiation with 30 keV protons, which transfers energy to the target mostly via electronic (inelastic) collisions, showed lower efficiency than the heavier ions. We found that spectral alteration in our experiments increased with increasing contribution of nuclear versus electronic energy loss. This implies that nuclear (elastic) energy deposition plays an important role in changing the optical properties of irradiated refractory complex hydrocarbon materials. Finally, our results indicated that temperature variations from 40 K to room temperature did not influence the spectral properties of these complex hydrocarbon solids.     

On the impact of multiply charged heavy solar wind ions on the surface of Mercury, the Moon and Ceres

We have studied the impact of multiply charged solar wind O⁷⁺ and Fe⁹⁺ ions on the surfaces of Mercury, the Moon and on a Ceres-size asteroid using a quasi-neutral hybrid model.The simulations showed that heavy O⁷⁺ and Fe⁹⁺ ions impact on the surface of Mercury non-homogenously, the highest flux being near the magnetic cusps—much as in the case of impacting solar wind protons. However, in contrast to protons, the analyzed heavy ions do not create high ion impact flux regions near the open-closed magnetic field line boundary. Dawn-dusk asymmetry and the total ion impact flux were each found to increase with respect to the increasing mass per charge ratio for ions, suggesting that the Hermean magnetic field acts as a mass spectrometer for solar wind ions. The Moon, in contrast, does not have a global intrinsic magnetic field and, therefore, solar wind ions can freely impact on its surface when this body is in the solar wind. The same is true for a, non-magnetized, Ceres-size asteroid.The impact of multiply charged ions on a solid surface results in a large variety of physical processes, of often intimately inter-related atomic reactions, e.g. electron exchange between solid and approaching projectile, inelastic scattering of projectile, electronic excitation in the projectile and/or the solid, ejection of electrons, photons, neutral and iodized surface particles, and eventual slowing down and stopping of the projectile in the solid. The electron transfer process between impacting heavy ions and surface constituents can result in soft X-ray (E<1 keV) and extreme ultraviolet (EUV) photon emissions. These processes will eventually damage the target surface. Analysis of the hybrid Mercury model (HYB-Mercury) suggests that, at this planet the damaging processes result in non-homogenous ageing of the surface that is controlled by the intrinsic magnetic field of the planet and by the direction of the interplanetary magnetic field. In the corresponding Lunar model (HYB-Moon) and in the non-magnetized asteroid model (HYB-Ceres), surface ageing is demonstrated to take place on that side of the body that faces toward the flow of the solar wind.     

Calculations of ion-molecule deuterium fractionation reactions involving HD

Gas-phase chemical models of deuterium fractionation in dense interstellar clouds utilize a small number of exothermic reactions to achieve fractionation. Although HD is a major repository of deuterium, it appears not to exchange deuterium with many molecular ions. Useful semiquantitative reasons have been given for the unusual lack of reactivity of exothermic ion-HD deuterium exchange systems, but quantum chemical studies are needed to understand these ideas in more detail and to determine if the lack of reactivity pertains at very low temperatures not studied in the laboratory, or whether tunneling can drive the reactions. Accordingly, the potential energy surfaces of three representative ion-molecule exchange reactions involving protonated ions (H3+, CH3+, HCO+) and HD have been investigated with ab initio quantum chemical techniques. Our results generally confirm the semiquantitative picture as to which reactions are likely to occur and show that tunneling at low temperatures is unlikely to alter this picture.     

Ion bombardment of interplanetary dust

The recent discovery of ion tracks in interplanetary dust and the increasing evidence for carbon and carburized materials in these objects are strongly suggestive that chemical processing by energetic charged-particle bombardment has occured during the dust lifetimes. The track density gives a measure of the total ion fluence experienced by the grains. We use this information and laboratory data on the modification of icy surfaces by incident ions and electrons to discuss the likelihood that chondritic interplanetary dust particles could have been proceed, by plasma bombardment, from aggregates of particles which had volatile and/or ogranic mantles. Such a processing would leave carbon and carburized deposits and can affect estimates of the temperature of formation of these dust grains.     

Sources and losses of energetic protons in Saturn's magnetosphere

We present Cassini data revealing that protons between a few keV and about 100 keV energy are not stably trapped in Saturn's inner magnetosphere. Instead these ions are present only for relatively short times following injections. Injected protons are lost principally because the neutral gas cloud converts these particles to energetic neutral atoms via charge exchange. At higher energies, in the MeV to GeV range, protons are stably trapped between the orbits of the principal moons because the proton cross-section for charge exchange is very small at such energies. These protons likely result from cosmic ray albedo neutron decay (CRAND) and are lost principally to interactions with satellite surfaces and ring particles during magnetospheric radial diffusion. A main result of this work is to show that the dominant energetic proton loss and source processes are a function of proton energy. Surface sputtering by keV ions is revisited based on the reduced ion intensities observed. Relatively speaking, MeV ion and electron weathering is most important closer to Saturn, e.g. at Janus and Mimas, whereas keV ion weathering is most important farther out, at Dione and Rhea.     

Ion emission from micrometeorite impacts on atmosphereless planets

Conclusions have been drawn on the generation of intensive high-velocity ions and atoms fluxes on the surfaces of the Moon, Mercury and the atmosphereless satellites of Jupiter by micrometeorite impacts. About 30% of each flux is ejected at small angles and detained by planetary reliefs, forming surface-active layer of alkalines. The combined erosional effect of that layer, the thermocycling and the radiational tractks have been studied. The ion fluxes leaving Jupiter's atmosphereless satellites may well be one of the main sources of the short UV-emission in their vicinities.Paper presented at the European Workshop on Planetary Sciences, organised by the Laboratorio di Astrofisica Spaziale di Frascati, and held between April 23–27, 1979, at the Accademia Nazionale del Lincei in Rome, Italy.From September 1979.     

Diurnal variation of sodium and potassium at Mercury

Abstract— A summary is given of our published observations showing a large (3 to 4) morning/afternoon ratio of the abundances of sodium and potassium. The proposed mechanism is deposition of ions and atoms on the cold night side, followed by their outward diffusion and evaporation as the Sun rises. Published criticisms of this mechanism are discussed and answered. The rate at which Na atoms can evaporate from the surfaces of the Moon and Mercury is uncertain, but, after a review of laboratory measurements, we propose that it is substantial at temperatures of 400 K and higher. Possible reasons are discussed why another group does not find the diurnal variation. There are differences in observing geometry, but the matter remains unclear.     

Laboratory studies on the sputtering contribution to the sodium atmospheres of Mercury and the Moon

To ascertain the importance of sputtering by solar wind ions on the formation of a sodium exosphere around Mercury and the Moon, we have irradiated with 4 keV He ions, the Na bearing tectosilicates: albite, labradorite, and anorthoclase, as well as adsorbed Na layers deposited on albite and on olivine (a neosilicate that does not contain Na). Sodium at the surface and near surface (<40 Å) was quantified with X-ray photoelectron spectroscopy before and after each irradiation to determine the depletion cross section. We measured a cross section for sputtering of Na adsorbed on mineral surfaces, σ_s ≈ 1 × 10^?15 cm² atom^?1. In addition, mass spectrometric analyses of the sputtered flux show that a large fraction of the Na is sputtered as ions rather than as neutral atoms. These results have strong implications for modeling the sodium population within the mercurian and the lunar exospheres.     

An investigation of the presence and nature of phyllosilicates on the surfaces of C asteroids by an analysis of the continuum slopes in their near‐infrared spectra

Abstract– To understand the nature of C asteroid surfaces, which are often related to phyllosilicates and C chondrites, we report near‐infrared spectra for a suite of phyllosilicates, heated to 100–1100 °C in 100 °C intervals, and compare the results for telescope IRTF spectra for 11 C asteroids. As C asteroids have relatively featureless spectra, we focus on “continuum plots” (1.0–1.75 μm slope against 1.8–2.5 μm slope). We compare the continuum plots of the 11 C asteroids and our heated phyllosilicates with literature data for C chondrites. The CI, CR, CK, and CV chondrite meteorites plot in the C asteroid field, whereas CM chondrites plot in a close but discrete field. All are well separated from the large phyllosilicate field. Heating kaolinite and montmorillonite to ≥700 °C moves their continua slopes into the C asteroid field, whereas chlorite and serpentine slopes move into the CM chondrite field. Water losses during heating are generally 10–15 wt% and were associated with a 20–70% albedo drop. Our data are consistent with surfaces of the C asteroids consisting of the dehydration products of montmorillonite whereas the CM chondrites are the dehydration products of serpentine and chlorite. The presence of opaque minerals and evaporites does not provide quantitative explanations for the difference in continua slopes of the phyllosilicates and C asteroids. The CM chondrites can also be linked to the C asteroids by heating. We suggest that the CM chondrites are interior samples, and the presence of a 3 μm feature in C asteroid spectra also indicates the excavation of material.