Two samplers for large-volume collection of chlorinated hydrocarbons

Two sampling devices for the in situ extraction of chlorinated hydrocarbons from water are described. Both samplers use the macroreticular adsorbent Amberlite XAD-2. They include a “fish” sampler which has been used to collect samples for PCB analysis from waters around the British Isles. Operation of this sampler causes a minimum of interruption to a ship's cruise programme and at the same time allows a large area to be surveyed. The second sampler is a self-powered in situ pump which is cheap to construct and can be left unattended to extract large volumes of water at a fixed station. The device is serviced by divers and samples may be collected daily on a routine sampling basis.     

A simple,inexpensive and large volume pore water sampler for sandy and muddy substrates

The construction and testing of a low cost, simple, intertidal and sub-tidal pore water sampler for use in sandy and muddy substrates are described in this note. The sampler, “porextractor”, is made of polyvinyl chloride (PVC) plumbing materials that can be readily sourced at any local hardware shop and costs AU $ 15.00 to build. The only mechanical component of the porextractor is a plunger that is used only once at the time of deployment. The porextractor has been designed for use on seagrass beds to collect pore water samples with minimal disturbance to the substratum for nutrient flux studies. The relative efficiency of the porextractor was tested against the widely used “Winger and Lasier” sampler, a vacuum operated diffuser stone pore water sampler. The two samplers were compared for the volume of pore water collected in sandy and muddy substrates in the laboratory, and the concentrations of total nitrogen and total phosphorus in samples collected from a sandy substrate in Amphibolis and Posidonia seagrass meadows off the Adelaide coast. While the porextractor and the Winger and Lasier samplers worked equally well in the sandy sediments, the porextractor was more efficient than the latter in muddy sediments, where clogging was a major problem. In addition, there were no significant differences (p ≤ 0.05) in the concentrations of total nitrogen and total phosphorus measured from the pore water samples collected by the two samplers in situ from the seagrass bed. The simplicity, ease of construction, non-substrate specificity, and large sample volume yield are some of the major merits of the porextractor over other conventional techniques used for pore water sampling.     

Comparing the passive sampler and biomonitoring of organic pollutants in water: A laboratory study

Passive sampling could provide the solution to problems associated with costly and time consuming sampling programmes and biomonitoring. Mussels (Mytilus edulis) and Chemcatcher passive sampler were simultaneously analyzed for sequestered pesticides and polychlorinated biphenyls (PCBs) by gas chromatography with mass spectrometry (GC/MSD). The Chemcatcher passive sampler based on a solid phase extraction disc with two types of diffusion-limiting membranes (polyethelene and polysulphone), were also compared. Diuron, atrazine, irgarol and lindane were accumulated in the polysulphone passive sampler in greater concentration than in the mussels or in the other passive samplers with polyethelene limiting-membrane. Mussels can accumulate in their tissue high concentration of non polar compounds such as PCB 52, dieldren and PCB 153; more than the passive sampler with polysulphone membrane. The device with polyethelene limiting membrane has high affinity capacity to concentrate high amount of phenenthrene, dieldrin, PCB 153 and PCB 52, so it acts as a sampler for non-polar compounds. The highest uptake rate of hydrophobic compounds by Chemcatcher was observed for analytes with log octanol-water partition coefficient (K_OW) between 4.5 and 7.5. Laboratory-based studies using passive samplers to assess the potential for bioaccumulation could provide robust and reliable information at relatively low cost compared to biomonitoring data. Laboratory data obtained using passive samplers could be related to accumulation under field conditions where field assessments are required.     

A comparative study of energy performance of hydrostatic seafloor sediment samplers and a new high-efficiency sampler

The hydrostatic energy of high-pressure seawater is a renewable and green energy source for ocean exploration and have been used to replace underwater electrical energy transmission through the cable and underwater battery pack to power seafloor equipment. The advantage of the energy supply method is the cost-effective and the robustness. In the paper, the energy performance of the existing hydrostatic seafloor sediment samplers powered by seawater hydrostatic energy are modelled and analyzed and compared. In view of the common shortcoming of existing technology, a novel hydrostatic seafloor sediment sampler is proposed. The model of energy conversion of the new sampler is built, and its energy performance is obtained. The analysis results indicate that the energy conversion efficiency of the novel sediment sampler is much higher than the existing ones, which means that the new sampler can collect much longer sample with the limited amount of hydrostatic energy. The seawater hydrostatic energy conversion system of the new sampler can also be used to power other seafloor equipment.     

A Novel Mechanical Gas-Tight Sampler for Hydrothermal Fluids

A new mechanical gas-tight sampler has been designed to collect hydrothermal fluids at the seafloor. A key feature of the sampler is the novel sample valve which is pressure balanced under deep sea, and actuated by the ram on a submersible's manipulator. The sampler is designed to be deployed at the seafloor 3000 m underwater and can be used to sample hydrothermal fluid with temperature up to 400degC. Compressed gas is used to compensate for pressure reduction of sample fluids. Simulation of the flow system was conducted to estimate the fill rate. The sampler has been tested successfully in the first Sino-American Cooperative Deep Submergence Project from August 13 to September 3, 2005.     

New devices for sediment and water sampling

Four new devices for sediment and water sampling are described, viz. (1) a large-volume water sampler; (2) a water sampler for thin water layers, (3) a bottom-water sampler, and (4) a gravity corer with exchangeable plastic tubes for use in a small boat.     

A new, automatic hydrothermal fluid sampler using a shape-memory alloy

A new hydrothermal fluid sampler has been developed to provide more maneuverability in underwater operation. The sampler characteristically employs a shape-memory alloy, which senses high temperature and actuates the suction mechanism. A shape-memory alloy is also used to switch the intake valve of the sampler, the intention being to avoid missampling when the inlet is in low temperature water. Prototype samplers were designed to collect the fluids hotter than 80°C. Test sampling was performed at hydrothermal vents (1372–1374 m deep) in the submarine volcano, Suiyo Seamount, Izu-Bonin Arc, northwestern Pacific. Observed fluid temperature was between 138 and 298°C, while the ambient seawater temperature was 3.1°C. Each prototype collected about 100 ml fluid as designed. The magnesium concentration in the samples indicated a seawater content of 47.5–90.8%, which indicates the entrainment of ambient seawater. Microscopic observatinn revealed the occurrence of microorganisms in the sample fluids at a population density of 10⁵ to 10⁶ cells ml⁻¹, which is 2–3 orders of magnitude higher than those in seawater at that depth. The use of the newly developed fluid sampler will greatly facilitate the collection of vent-associated microorganisms, which are of potential biological and biotechnological interest.     

A new gas-tight isobaric sampler for hydrothermal fluids

A new gas-tight isobaric sampler for the collection of hydrothermal fluids venting at the seafloor has been designed, constructed, and tested at a ridge-crest vent site. The new device is constructed of chemically inert titanium, is gas-tight to 450 bar and can be used to sample fluids with temperatures up to 400°C. Compressed gas is used to maintain the sample at seafloor pressure before and during sample withdrawal onboard ship, allowing subsampling without degassing the fluid remaining in the sampler. This feature eliminates the need to collect separate gas-tight and major element samples since a single fluid sample can be analyzed quantitatively for major, trace, semi-volatile, and volatile components. The sampler fill rate is regulated to minimize entrainment of ambient seawater during collection of fluids from environments characterized by low fluid flow such as diffuse hydrothermal vents. In addition to deployment at the ridge-crest, the samplers can be used to collect gas-tight samples from other subseasurface environments such as hydrocarbon seeps, areas of methane-gas hydrate formation, cold seeps associated with serpentinites, regions of groundwater egress to the oceans, and the water column.     

Use of different intertidal habitats by faunal communities in a temperate coastal lagoon

The faunal communities of four intertidal habitats namely sand, mud, seagrass (Zostera noltii) and seagrass patches (mixSM) of a temperate coastal lagoon, Ria Formosa (southern Portugal), were sampled. A total of 47 species were taken in 428 bottomless drop sampler samples, with the highest number of species and the more commonly occurring species belonging to the Mollusca phylum. The dominance of these gastropod species underlines the importance of the grazing food chain in these habitats. Bittium reticulatum was the most abundant species, being especially abundant in the seagrass habitat. The most frequent and highest biomass species in the community was Carcinus maenas, a predator that makes use of the available resources and that is adapted to the highly variable intertidal environment. Pomatoschistus microps was the most abundant fish species, with highest densities in the mud habitat, which demonstrates an ability to occupy a low depth area. The seagrass habitat had the highest diversity, abundance and biomass, followed by the mixSM habitat and was different from all the others. Assemblages were highly influenced by the presence of vegetation, providing forage and refuge from predation. A well defined summer group was identified in all habitats. These results highlight the importance of seagrass beds and the idea that their decrease implies the decrease of lagoon production through the impoverishment of the trophic structure of the lagoon.     

基于实际气体状态方程的深海采样压力补偿技术

压缩气体通常用于深海压力保持采样器的压力补偿。回收的流体样品的压力和体积与预充气体高度相关。为了更好地理解高压下气体的行为,我们提出了一个新的基于压缩因子Z的实际气体状态方程,该方程是从实验数据得出的。然后基于该经验气态方程引入了样品压力和体积的理论计算方法。最后,通过采样器进行了在115MPa下的高压模拟采样实验,很好地验证了本文所提出的计算理论。     

A sampler for quantitatively assessing the macrobenthic epifaunal community of a hard substrate

A quick and effective underwater quantitative quadrat sampler was designed for sampling macrobenthic epifauna on hard substrates. Using a 400 cm² quadrat, divers could take samples quickly and with little or no loss of organisms. The sampler can be used successfully in adverse conditions in the open ocean on any relatively flat substrate, regardless of its orientation.     

高精度CTD采水器控制系统的设计与分析

本系统是国家“８６３”任务中８１８－０２Ａ项目的重要组成部 和高精度ＣＴＤ测量仪联用,可以完成任意深度、任意时刻的采水控制功能,它采用国内外最新的技术和元器件,打破了原有的采水控制装置的设计思想,使采水器的动作完全合理准确。本文重点介绍其工作原理和关键技术。     

A Remotely Operated Serial Sampler for Collecting Gas-Tight Fluid Samples

This paper describes the design, construction and preliminary test results for a gas-tight serial sampler intended to be deployed at seafloor for long-term operation to take time-series fluid samples from deep-sea environments such as cold seeps, water column and hydrothermal vents. The serial sampler is a modular system that is based on independent and identical sampling modules, which are designed to collect six 160 ml gas-tight fluid samples maintained at high pressure to a depth of 4000 meters. With two working modes, the sampler can be deployed either with seafloor cabled observatory for remote control or as a stand-alone device for autonomous operation. A prototype of the instrument has been constructed and tested on the MARS cabled observatory for two months. The laboratory and field tests proved the success of the design and construction of the serial sampler, and indicated the potential for future ocean sciences.     

深海新型取样仪器-电视抓斗及使用方法

每一位海洋地质工作者都非常重视外业调查及第一手资料的获取,而这些往往得益于海洋地质调查仪器的帮助.以前我们常用的表层沉积物取样仪器,有普通蚌式抓斗、小箱式取样器、多管取样器等.这里介绍一种深海新型取样仪器--电视抓斗.目前,它在深海及大洋洋中脊资源调查,特别是在深海底块状硫化物、多金属结核、锰结壳调查等勘测中扮演着重要...     

Haamer vibrocorer and its affect on the geotechnical properties of cohesive sediments in gothenburg harbor,Sweden

Abstract

The Haamer vibrocorer is a cheap and easily handled sampler for containing continuous cohesive or cohesionless sediment cores. This vibrocorer can be handled on board an ordinary trawler or small vessel. The penetration of the sampling barrel is actuated by two synchronized vibrators. Additional penetration force is provided by the buoyancy of a guiding buoy. To extend the maximum sampling length and to decrease the degree of disturbance, the vibrocorer is equipped with a plastic foil, which encases the core as it enters the liner and reduces inside friction. By providing the sampler with jetting water, the necessary penetration force is decreased. Testing a prototype is always difficult, but a working cycle of up to three cores an hour has been reached using a 6 m vibrocorer. A limited investigation has been conducted to determine the quality of the recovered cores; however, because of the poorly defined quality of the reference samples, no definitive answer to the question of sample disturbance can be given.     

XD-1型箱式采样器

箱式采样器由美国斯克里普斯海洋研究所于1962年研制成功,经多次改进后被广泛应用于海洋底质中采集沉积物原状样品和上覆水。我们于1979年着手研制并于1981年初试制成功带有测定沉积物方位的XD-1型箱式采样器。 本文就XD-1型箱式采样器的构造、工作原理、稳定条件及采样效果报道如下。     

可浮动自锁式深海气密采水器的研制

深海海水中气体的含量可以在一定程度上标识深海资源蕴藏量,因而实现对深海海水的气密采样意义重大.为此设计了一种可浮动的自锁装置,并采用压力自适应平衡原理,实现了对深海海水的气密采样.实验室和海上试验结果均表明深海气密采水器在装上可浮动自锁装置后耐压能力和气密性都得到了有效的提高,对初始压强为1.208 MPa的N2气保压2 h,压力损失不到1.2%,并成功地实现了对960 m深的海水样品的气密采样.此样品中CH4浓度为5.44 nmol/dm^3,CO2浓度为140.6nmol/dm^3.该可浮动自锁式深海气密采水器的研制为深海资源勘探分析提供了必要的技术支持.     

A high-pressure serial sampler to measure microbial activity in the deep sea

A high-pressure serial sampler (HPSS) has been developed to obtain microbial activity data unbiased by decompression during retrieval with the same frequency as used for the measurement of other hydrological parameters. We fitted a commercially available multisampling device with eight pressure-retaining vessels. This device allows the collection of eight 500 ml samples of undecompressed water during the same hydrocast to a depth of 3500 m. The HPSS includes a CTD; therefore the eight sampling depths can be selected using the conventional hydrological parameters. During the retrieval and the incubation period pressure conditions of each sampler are permanently recorded on the surface computer. Incubation is in a temperature-controlled water bath to keep the samples in the natural temperature conditions. During the incubation period, several sub-samples may be successively collected without pressure loss within the culture vessel, allowing time-course experiments. During a stratified period, comparison of microbial production rates simultaneously measured on the decompressed and undecompressed seawater samples collected between 850 and 2000 m depth showed that the deep-sea bacteria were affected by decompression during retrieval.     

SON microbiological sampler for hydrobiological investigation

A cylinder-type sampler, which is attached to the rod of Van Dorn sampler, was newly deviced for microbiological collection of 3-liter water samples from shallow layers.     

大容量海水采水器的研制

介绍一种实用新型的采水器，该采水器具有全新的开闭装置及密封结构．文章对采水器的构造、工作原理及特点进行了有益的探讨。