Tectonic and magmatic evolution of the eastern Karakoram,India

Abstract

The Shyok suture zone separates the Ladakh terrane to the SW from the Karakoram terrane to the NE. Six tectonic units have been distinguished. From south to north these are; 1. Saltoro formation; 2. Shyok volcanites; 3. Saltoro molasse; 4. Ophiolitic melange; 5. Tirit granitoids; 6. Karakoram terrane including the Karakoram batholith. Albian—Aptian Orbitolina-bearing lime-stones and turbidites of the Saltoro formation tectonically overlie high-Mg-tholeiites similar to the tectonically overlying Shyok volcanites. The high-Mg tholeiitic basalts and calcalkaline andesites of the Shyok volcanites show an active margin signature. The Saltoro molasse is an apron-like, moderately folded association of redgreen shales and sandstones that are interbedded with ~ 50 m porphyritic andesite. Desiccation cracks and rain-drop imprints indicate deposition in a subaerial fluvial environment. Rudist fragments from a polygenic conglomerate of the Saltoro molasse document a post-Middle Cretaceous age. The calcalkaline andesites of the Shyok volcanites are intruded by the Tirit granitoids, which are located immediately south of the Ophiolitic melange and belong to a weakly deformed trondhjemite-tonalite-granodiorite-granite suite. These granitoids are subalkaline, I-type and were emplaced in a volcanic arc setting. The subalkaline to calcalkaline granitoids of the Karakoram batholith are I-and S-type granitoid. The I-type granitoids represent a typical calcalkaline magmatism of a subduction zone environment whereas the S-type granitoids are crustderived, anatectic peraluminous granites. New data suggest that the volcano-plutonic and sedimentary successions of the Shyok suture zone exposed in northern Ladakh are equivalent to the successions exposed along the Northern suture in Kohistan. It is likely that the o istan and Ladakh blocks evolved as one single tectonic domain uring the Cretaceous-Palaeogene. Subsequently, collision, suturing and accretion of the Indian plate along the Indus suture (50–60 Ma) together with tectonic activity along the Nanga Parbataramosh divided Kohistan and Ladakh into two arealy distinct magmatic arc terranes. The activity and a dextral offset along the Karakoram fault (Holocene-Recent) disrupted the original tectonic relationships. © 1999 Éditions scientifiques et médicales Elsevier SAS     

Dextral transpression and late Eocene magmatism in the trans-Himalayan Ladakh Batholith (North India): implications for tectono-magmatic evolution of the Indo-Eurasian collisional arc

The trans-Himalayan Ladakh batholith is a result of arc magmatism caused by the northward subduction of the Tethyan oceanic lithosphere below the edge of the Eurasian plate. The batholith dominantly consists of calc-alkaline I-type granitoids which are ferromagnetic in nature with the presence of magnetite as the principal carrier of magnetic susceptibility. The mesoscopic and magnetic fabric are concordant and generally vary from WNW–ESE to ENE–WSW for different intrusions of ferromagnetic granites in different parts of the batholith. Strike of magnetic fabric is roughly parallel with the regional trend of the Ladakh batholith in the present study area and is orthogonal to the direction of India-Eurasia collision. In Khardungla and Changla section, the magnetic fabric is distributed in a sigmoidal manner. It is inferred that this sigmoidal pattern is caused by shearing due to transpression induced by oblique convergence between the two plates. U–Pb zircon geochronology of a rhyolite from the southern parts of the batholith gives a crystallization age of 71.7 ± 0.6 Ma, coeval with ~68 Ma magmatism in the northern parts of the batholith. The central part of the batholith is characterized by S-type two-mica granites, which gives much younger age of magmatism at 35.5 ± 0.5 Ma. The magnetic fabric of these two-mica granites is at a high angle to the regional trend of the batholith. It is proposed that these two-mica granites were emplaced well after the cessation of subduction and arc magmatism, along fractures that developed perpendicular to the regional strike of the batholith due to shearing.     

Construction of the granitoid crust of an island arc part I: geochronological and geochemical constraints from the plutonic Kohistan (NW Pakistan)

We present major and trace element analyses and U–Pb zircon intrusion ages from I-type granitoids sampled along a crustal transect in the vicinity of the Chilas gabbronorite of the Kohistan paleo-arc. The aim is to investigate the roles of fractional crystallization of mantle-derived melts and partial melting of lower crustal amphibolites to produce the magmatic upper crust of an island arc. The analyzed samples span a wide calc-alkaline compositional range (diorite–tonalite–granodiorite–granite) and have typical subduction-related trace element signatures. Their intrusion ages (75.1 ± 4.5–42.1 ± 4.4 Ma) are younger than the Chilas Complex (~85 Ma). The new results indicate, in conjunction with literature data, that granitoid formation in the Kohistan arc was a continuous rather than punctuated process. Field observations and the presence of inherited zircons indicate the importance of assimilation processes. Field relations, petrographic observations and major and trace element compositions of the granitoid indicate the importance of amphibole fractionation for their origin. It is concluded that granitoids in the Kohistan arc are derivative products of mantle derived melts that evolved through amphibole-dominated fractionation and intra crustal assimilation.     

A late Neoarchaean–early Palaeoproterozoic crustal thickening event in the eastern North China Craton: petrological and geochronological evidence from Eastern Hebei terrane

Determining an age framework for Precambrian crystalline rocks and associated granulite-facies metamorphism of the inner blocks in the North China Craton (NCC) is important for determining the tectonic setting and evolution of the craton during the Neoarchaean–Palaeoproterozoic. The Eastern Hebei terrane (EHT), located in the Eastern Block of the NCC, is composed of tonalitic-trondhjemitic-granodioritic (TTG) gneisses and potassium-rich granitoids, along with rafts of supracrustal rocks that are intruded by basic dikes. TTG gneisses in the EHT yield crystallization ages of 2516–2527 Ma. The oldest age of inherited zircons from a mylonitic TTG gneiss is ~2918 Ma. Granulite-facies supracrustal metamorphic rocks in the Zunhua high-grade meta-greenstone belt indicate an andesitic/basaltic protolith that was formed at ~2498 Ma. A syn-deformational granite in the Jinchangyu greenschist-facies shear zone yields a crystallization age of ~2474 Ma. Metamorphism of the supracrustal rocks and mylonitic greenschist took place at ~2461 and ~2475 Ma, respectively. Rare earth elements (REE) patterns and slightly negative Nb and Ta anomalies indicate that the magmatic precursors of the supracrustal rocks might be derived from partial melting of a sub-arc mantle wedge and metasomatized by fluids derived from a subducting slab. These rocks plot in the island arc basalts (IAB) field on a La/Nb vs. La diagram, further supporting this interpretation. The microstructures of a garnet–two-pyroxene granulite indicate an approximately clockwise P-T path. The crystallization ages of the TTG gneisses represent periods of the major crustal growth in the NCC, and the granulite- and greenschist-facies metamorphism indicates an orogenic event that involved crustal thickening at ~2.47 Ga.     

Late Palaeoproterozoic Hekou Group in Sichuan,Southwest China: geochronological framework and tectonic implications

The Palaeoproterozoic Hekou Group, an outcrop along the SW-margin of the Yangtze Block, consists of volcanic and sedimentary rocks that experienced greenschist facies metamorphism and was intruded by gabbroic and granitic plutons. The sedimentary rocks consist of coarse to fine-grained siliciclastic and carbonate rocks including quartzite, mica schists, polymictic meta-conglomerates and marble, whereas volcanic rocks consist of sodic lava and pyroclastic rocks including albitites, interbeded metatuffs, and metabasalts. Metatuffs from five layers have zircon U–Pb age of 1710 ± 18 Ma (MSWD = 1.6), 1637 ± 7 Ma (MSWD = 0.65), 1601 ± 15 Ma (MSWD = 0.94), 1661 ± 7 Ma (MSWD = 1.4), and 1718 ± 11 Ma (MSWD = 0.3) and these ages show that the Hekou Group deposited at ~1.7–1.6 Ga. The high content of light rare earth element (LREE), the low content of highrare earth element (HREE) and negative Ti anomalies, relatively high content of incompatible fluid-insoluble elements (Nb, Ta, and Th), and the high varied εNd(t) values (?6.0 to +4.6) of the metavolcanic rocks show that these rocks are formed in back-arc basin. Our study also implies that the Yangtze Block also underwent subduction-related, continental margin accretion on its SW-margin during the growth of the Nuna supercontinent at ~1.7–1.6 Ga.     

Construction of the granitoid crust of an island arc. Part II: a quantitative petrogenetic model

Results of simple model calculations that integrate cumulate compositions from the Kohistan arc terrain are presented in order to develop a consistent petrogenetic model to explain the Kohistan island arc granitoids. The model allows a quantitative approximation of the possible relative roles of fractional crystallization and assimilation to explain the silica-rich upper crust composition of oceanic arcs. Depending in detail on the parental magma composition hydrous moderate-to-high pressure fractional crystallization in the lower crust/upper mantle is an adequate upper continental crust forming mechanism in terms of volume and compositions. Accordingly, assimilation and partial melting in the lower crust is not per se a necessary process to explain island arc granitoids. However, deriving few percent of melts using low degree of dehydration melting is a crucial process to produce volumetrically important amounts of upper continental crust from silica-poorer parental magmas. Even though the model can explain the silica-rich upper crustal composition of the Kohistan, the fractionation model does not predict the accepted composition of the bulk continental crust. This finding supports the idea that additional crustal refining mechanism (e.g., delamination of lower crustal rocks) and/or non-cogenetic magmatic process were critical to create the bulk continental crust composition.     

Geochemistry of mafic–ultramafic magmatism in the Western Ghats belt (Kudremukh greenstone belt), western Dharwar Craton,India: implications for mantle sources and geodynamic setting

Western Ghats Belt of western Dharwar Craton is dominated by metavolcanic rocks (komatiites, high-magnesium basalts (HMBs), basalts, boninites) with occasional metagabbros. This rock-suite has undergone post-magmatic alteration processes corresponding to greenschist- to lower-amphibolite facies conditions. Komatiites are Al-depleted, characterized by lower Al₂O₃/TiO₂ and high CaO/Al₂O₃. Their trace element distribution patterns suggest most of the primary geochemical compositions are preserved with minor influence of post-magmatic alteration processes and negligible crustal contamination. Chemical characteristics of Al-depleted komatiites imply their derivation from deeper upper mantle with/without garnet involvement. HMBs and basalts are differentiated based on their magnesium content. Basalts and occasionally associated gabbroic sills have similar geochemical characteristics. HMB are characterized by light rare earth element (LREE) enrichment, with significant Nb–Ta and Zr negative anomalies. Basalts and associated gabbros display tholeiitic affinity, with LREE-enriched to slightly fractionated heavy rare earth element (HREE) patterns. Boninites are distinctive in conjunction of low abundances of incompatible elements with respect to the studied komatiites. Chondrite-normalized REE patterns of boninites show relative enrichment in LREE and HREE with respect to MREE. Prominent island arc signatures are evident in HMB, basalts, boninites, and gabbros in terms of their Nb–Ta and Zr–Hf negative anomalies, LREE enrichment and HFSE depletion. It is suggested that these HMB–basalts (associated gabbros)–boninites are the products of arc magmatism. Their REE chemistry attests to a gradual transition in melting depth varying between spinel and garnet stability field in an arc regime. The close spatial association but contrasting elemental characteristics of komatiites and HMB–basalts–boninites can be explained by a plume-arc model, in which the ~3.0 Ga komatiites are considered to be the products of plume volcanism in an oceanic setting, while the HMB, basalts, boninites, and associated gabbros were emplaced in a continental margin setting around 2.8–2.7 Ga.     

Phlogopite- and clinopyroxene-dominated fractional crystallization of an alkaline primitive melt: petrology and mineral chemistry of the Dariv Igneous Complex,Western Mongolia

We present field relationships, petrography, and mineral major and trace element data for the Neoproterozoic Dariv Igneous Complex of the Altaids of Western Mongolia. This unique complex of high-K plutonic rocks is composed of well-exposed, km-scale igneous intrusions of wehrlites, phlogopite wehrlites, apatite-bearing phlogopite clinopyroxenites, monzogabbros, monzodiorites, and clinopyroxene-bearing monzonites, all of which are intruded by late stage lamprophyric and aplitic dikes. The biotite-dominated igneous complex intrudes depleted harzburgitic serpentinite. The observed lithological variability and petrographic observations suggest that the plutonic rocks can be ascribed to a fractionation sequence defined by olivine + clinopyroxene ± Fe–Ti oxides → phlogopite + apatite → K-feldspar + plagioclase → amphibole + quartz. Notably, phlogopite is the dominant hydrous mafic mineral. Petrogenesis of the observed lithologies through a common fractionation sequence is supported by a gradual decrease in the Mg# [molar Mg/(Fe_total + Mg) × 100] of mafic minerals. Crystallization conditions are derived from experimental phase petrology and mineral chemistry. The most primitive ultramafic cumulates crystallized at ≤0.5 GPa and 1,210–1,100 °C and oxygen fugacity (fO₂) of +2–3 ?FMQ (log units above the fayalite–quartz–magnetite buffer). Trace element modeling using clinopyroxene and apatite rare earth element compositions indicates that the dominant mechanism of differentiation was fractional crystallization. The trace element composition of a parental melt was calculated from primitive clinopyroxene compositions and compares favorably with the compositions of syn-magmatic lamprophyres that crosscut the fractionation sequence. The parental melt composition is highly enriched in Th, U, large ion lithophile elements, and light rare earth elements and has a pronounced negative Nb–Ta depletion, suggestive of an alkaline primitive melt originating from a subduction-imprinted mantle. Comparison with a global compilation of primitive arc melts demonstrates that Dariv primitive melts are similar in composition to high-K primitive melts found in some continental arcs. Thus, the high-K fractionation sequence exposed in the Dariv Igneous Complex may be a previously unrecognized important fractionation sequence resulting in alkali-rich upper crustal granitoids in continental arc settings.     

The dynamics of the suture between the Kohistan island arc and the Indian plate in the Himalaya of Pakistan

ABSTRACT The pressure-temperature and temperature-time paths derived for rocks in the Kohistan arc and adjacent Nanga Parbat-Haramosh massif record the dynamics of the collision between the island arc and the Indian plate. Studies of P-T-t paths show that the Kohistan arc was thrust over the Nanga Parbat-Haramosh massif at least 25 Ma ago, but not more than 30–35 Ma ago. Rocks in the Kohistan arc followed decreasing pressure paths, with the early metamorphism beginning at high pressures (9.5 kbar) and later metamorphism occurring at 8.0 kbar. In contrast, rocks in the Nanga Parbat-Haramosh massif (Indian plate) experienced increasing pressure and temperature paths. Prior to thrusting, the massif was at low pressures (4.0 kbar) and low temperatures (450°c). Later, the pressure and temperature increased to 8 kbar and 580°c. The authors interpret the convergence (to approximately the same pressure and temperature) of the P-T paths in the two terranes as being the result of thrusting and thermal equilibration between the thrust sheets. ⁴⁰Ar/³⁹Ar cooling ages of hornblendes and other geochronological data suggest that the time of peak metamorphism and hence the completion of thickening was approximately 30–35 Ma ago. Temperature-time paths show that after thrusting, during the period 25–10 Ma, the Kohistan arc and Nanga Parbat-Haramosh massif were uplifted at similar rates (0.5 km Ma). However, in the past 10 Ma the Nanga Parbat-Haramosh massif has been uplifted more rapidly than the adjacent Kohistan arc. Rapid uplift has been accommodated by late faults along the edge of the massif.     

Importance of water for Archaean granitoid petrology: a comparative study of TTG and potassic granitoids from Barberton Mountain Land,South Africa

A new model for Archaean granitoid magmatism is presented which reconciles the most important geochemical similarities and differences between tonalite–trondhjemite–granodiorite (TTG) and potassic granitoids. Trace element abundances reveal a strong arc magmatism signature in all studied granitoids from Barberton Mountain Land. Characteristic features include HFSE depletion as well as distinct enrichment peaks of fluid-sensitive trace elements such as Pb in N-MORB normalisation, clearly indicating that all studied granitoids are derived from refertilised mantle above subduction zones. We envisage hydrous basaltic (s.l.) melts as parental liquids, which underwent extensive fractional crystallisation. Distinctive residual cumulates evolved depending on initial water content. High-H₂O melts crystallised garnet/amphibole together with pyroxenes and minor plagioclase, but no olivine. This fractionation path ultimately led to TTG-like melts. Less hydrous basaltic melts also crystallised garnet/amphibole, but the lower compatible element content indicates that olivine was also a liquidus phase. Pronounced negative Eu-anomalies of the granitic melts, correlating with Na, Ca and Al, indicate plagioclase to be of major importance. In the context of our model, the post-Archaean disappearance of TTG and concomitant preponderance of granites (s.l.), therefore, is explained with secular decrease of aqueous fluid transport into subduction zones and/or efficiency of deep fluid release from slabs.     

Subducting sediment-derived arc granitoids: evidence from the Datong pluton and its quenched enclaves in the western Kunlun orogen, northwest China

This paper presents detailed SHRIMP zircon U–Pb chronology, mineral chemistry, major and trace element, and Sr–Nd–Hf isotope geochemistry of the Datong pluton and its quenched enclaves from the western Kunlun orogen, northwest China, in an attempt to achieve a better understanding on the origin of diverse arc magmas. The Datong host granitoids are intermediate to acid in composition (SiO₂?=?57.5?~?73.1 wt.%), and exhibit high-K calc-alkaline to shoshonitic affinities. The quenched enclaves are silica-rich ultrapotassic rocks. Detailed SHRIMP zircon U–Pb dating indicates that the Datong pluton was emplaced in Ordovician time (473.4–447.7 Ma), which places the Datong pluton in an active continental margin setting, rather than a syn-collision setting of Early Silurian age. The Datong host granitoids were derived by partial melting of subducted sediments, with the subsequent melt interacting with the overlying mantle wedge during its ascent. Partial melting of the veined mantle wedge hybridized by sediment-derived melts generated the silica-rich ultrapotassic magma, which was injected into the Datong granitoid magma chamber and quenched, resulting in enclaves hosted by granitoids. This contribution provides evidence that arc magmas can be derived directly by partial melting of subducted sediments, which is helpful to further understand the origin of diverse arc magmas.     

Magmatic and tectonic history of Jurassic ophiolites and associated granitoids from the South Apuseni Mountains (Romania)

The Jurassic ophiolites in the South Apuseni Mountains represent remnants of the Neotethys Ocean and belong to the East Vardar ophiolites that contain ophiolite fragments as well as granitoids and volcanics with island-arc affinity. New U–Pb zircon ages, and Sr and Nd isotope ratios give insights into their tectono-magmatic history. The ophiolite lithologies show tholeiitic MOR-type affinities, but are occasionally slightly enriched in Th and U, and depleted in Nb, which indicates that they probably formed in a marginal or back-arc basin. These ophiolites are associated with calc-alkaline granitoids and volcanics, which show trace element signatures characteristic for subduction-enrichment (high LILE, low HFSE). Low ⁸⁷Sr/⁸⁶Sr ratios (0.703836–0.704550) and high ¹⁴³Nd/¹⁴⁴Nd ratios (0.512599–0.512616) of the calc-alkaline series overlap with the ratios measured in the ophiolitic rocks (0.703863–0.704303 and 0.512496–0.512673), and hence show no contamination with continental crust. This excludes a collisional to post-collisional origin of the granitoids and is consistent with the previously proposed intra-oceanic island arc setting. The new U–Pb ages of the ophiolite lithologies (158.9–155.9 Ma, Oxfordian to Early Kimmeridgian) and granitoids (158.6–152.9 Ma, latest Oxfordian to Late Kimmeridgian) indicate that the two distinct magmatic series evolved within a narrow time range. It is proposed that the ophiolites and island arc granitoids formed above a long-lived NE-dipping subduction zone. A sudden flip in subduction polarity led to collision between island arc and continental margin, immediately followed by obduction of the ophiolites and granitoids on top of the continental margin of the Dacia Mega-Unit. Since the granitoids lack crustal input, they must have intruded the Apuseni ophiolites before both magmatic sequences were obducted onto the continental margin. The age of the youngest granitoid (~153 Ma, Late Kimmeridgian) yields an estimate for the maximum age of emplacement of the South Apuseni ophiolites and associated granitoids onto the Dacia Mega-Unit.     

Geochemical characteristics of ophiolitic rocks from the southern margin of the Sivas basin and their implications for the Inner Tauride Ocean,Central-Eastern Turkey

Number of dismembered ophiolite bodies crop out between Sivas and Malatya on the top of the Eastern Tauride platform in the central-eastern Turkey. One of which at the southern margin of the Sivas basin in the Tecer Mountain area comprises melange and the lower part of an oceanic lithospheric section on top of the Tauride platform. The mantle tectonites are characterized by variably serpentinized harzburgites and dunites, and are intruded by numerous isolated dykes. The gabbroic cumulates consist of olivine gabbro, gabbro and gabbronorite. The major and trace element geochemistry of the mafic cumulate rocks suggests that the primary magma was compositionally similar to those observed in modern island-arc tholeiitic sequences. The isolated dykes are exclusively basaltic in composition and display geochemically two distinct subgroups: Group I is represented by high TiO₂ (.87–1.47 wt.%) and other incompatible elements, whereas Group II is characterized by low TiO₂ (.36–.66 wt.%) and other incompatible elements. The Group I isolated diabase dykes have flat to slightly LREE-depleted profiles (La/Yb_N = .32–.79), whereas the Group II isolated diabase dykes are more depleted in general and have a LREE-depleted character (La/Yb_N = .19–.49). This suggests that the isolated dykes were derived from an island arc tholeiitic magma (Nb/Y = .02–.05) with different degrees of partial melting (Group II > Group I) and relatively high oxygen fugacity in intra-oceanic subduction zone. The ophiolitic rocks in the study area may well be compared with the Divri?i ophiolite to the southeast. All the evidence suggests that the isolated dykes in the Tecer Mountain area differ from the alkaline isolated dykes cutting the Divri?i ophiolite. Since the late stage dykes (~76 Ma) in the Divri?i area are alkaline, the tholeiitic isolated dykes in the present study should have been emplaced prior to the alkaline dykes during Late Cretaceous SSZ-spreading (~90 Ma) within the Inner Tauride Ocean.     

Hugoniot and sound velocity of antigorite and evidence for sluggish decomposition

Antigorite is one kind of hydrous serpentine that is present in meteorites and in the Earth mantle. In order to understand its dynamic behaviors, metastability and decomposition, shock experiments on antigorite have been conducted using a two-stage gas gun, and wave profiles of particle velocities have been measured to obtain the Hugoniot up to ~130 GPa and sound velocity at high pressures. The results show three regions of low-pressure phase below ~43 GPa and its metastable extension above a pressure of ~43 GPa for short durations of shock and high-pressure phase(s) above a pressure of ~43 GPa for long durations of shock. The dynamic behaviors of antigorite depend on not only the pressure but also the compression duration. Metastable extension state indicates that antigorite may survive beyond the stability depending on the shock conditions. Shock temperatures for antigorite are calculated along the Hugoniot. The pressure–density, sound velocity–pressure and shock temperature–pressure plots demonstrate that the decomposition reaction of antigorite into high-pressure phase(s) is accompanied by a volume expansion, sound velocity increase and temperature decrease, relative to the metastable extension phase above ~43 GPa. The decomposition should be sluggish and needs enough reaction time to complete and to overcome the activation energy. As a result of the high metastability of antigorite and possible decomposition assemblages, the hydrous serpentine (antigorite) may play a crucial role for the origin of water during the Earth accretion.     

Continental rift and oceanic protoliths of mafic–ultramafic rocks from the Kechros Complex,NE Rhodope (Greece): implications from petrography,major and trace-element systematics,and MELTS modeling

The whole-rock chemistry of eclogites, partially amphibolitized eclogites, and dyke amphibolites from the metamorphic Kechros complex in the eastern Rhodope Mountains preserves evidence of the geodynamic framework for the origin of their protoliths. Major and trace-element concentrations define two distinct protolith groups for the eclogites. The low-Fe–Ti (LFT) eclogites have low-TiO₂ content (<0.67 wt%), negative high field strength element anomalies, and variable enrichments in large ion lithophile elements (LILE). The rare earth element (REE) patterns are characterized by strong light-REE (LREE) enrichment and heavy-REE (HREE) depletion. The high-Fe–Ti (HFT) eclogites have small to moderate LILE enrichment and lack Nb anomalies. The REE patterns of the HFT eclogites are characterized by LREE depletion and relatively flat MREE–HREE patterns. The rock compositions and petrographic features of the LFT eclogites resemble gabbros formed in a continental rift environment with minor to moderate contamination of a mantle-derived mafic magma by continental crust, whereas the HFT eclogites resemble mafic rocks formed in extensional oceanic environments. We interpret the HFT suite to represent a later stage in an evolution from continental rift to open ocean, following the origin of the LFT suite. Dyke amphibolite compositions, except for probable SiO₂ loss associated with metamorphic dehydration reactions, appear to represent liquid compositions quenched in conduits through the lower crust. MELTS modeling shows that dyke amphibolite compositions can be related to each other by fractional crystallization under strongly oxidizing conditions at ~0.5 GPa pressure, and all can be derived from a low-degree melt of modified fertile peridotite from around 1.7 GPa. Cumulates crystallized from the parental liquids of the amphibolites under oxidizing conditions may have yielded the protoliths of the HFT suite.     

Inferred Palaeoproterozoic arc rifting along a consuming plate margin: insights from the stratigraphy,volcanology and geochemistry of the Kangerluluk sequence,southeast Greenland

The 200- to 300-m-thick volcano-sedimentary sequence in the Kangerluluk Fjord, associated with penecontemporaneous and late-tectonic dykes, as well as a synvolcanic plutonic suite, represents an integral component of the Palaeoproterozoic Ketilidian Mobile Belt, south Greenland. The ca. 1808-Ma Kangerluluk supracrustal sequence contains four distinct mappable lithofacies: (a) a conglomerate-sandstone lithofacies; (b) a pyroclastic lithofacies; (c) a volcanic lithofacies; and (d) a peperite lithofacies. The volcanic lithofacies, up to 200 m thick, is characterized by shallow-water subaqueous brecciated and pillowed flows. Flows are either (a) feldspar-phyric, or (b) feldspar-pyroxene-phyric, with 0.2- to 3-cm-size plagioclase and 0.2- to 3-cm-size pyroxene that constitute between 20 and 30% (locally up to 50%) of the flows. Mafic dykes intruded wet unconsolidated pyroclastic lithofacies, resulting in the formation of peperites. Geochemically, the volcanic and pyroclastic units represent a distinct tholeiitic magmatic suite enriched in incompatible trace elements including Th, La, Yb, Zr and Nb, and exhibiting (La/Yb)_n~10. The plutonic suite and associated dykes display a calc-alkaline trend with enriched LREE and unfractionated flat HREE patterns, La_n ranging between 50 and 100, (La/Yb)_n ratios between 8 and 22, and negative Nb and Ti anomalies on the mantle-normalized, incompatible multi-element patterns. The pillowed flows lie in the continental flood basalt field on the Y-Nb-Zr discrimination diagram, and display a Nb anomaly and K₂O-enrichment that collectively suggest a crustal component and/or a subduction-modified mantle source. The geology, stratigraphy of the Kangerluluk area and geochemistry can be used to infer a change in magma genesis from arc to rift volcanism. The 1850- to 1800-Ma calc-alkaline Julianehåb batholith represents a magmatic arc that rifted during crustal extension, allowing for the ascent of mantle-derived mafic magma. The geochemistry of the mafic volcanic flows, synvolcanic dykes and pyroclastic deposits favours a crustal component in magma genesis and offers new insights into the tectonic evolution of the Ketilidian Mobile Belt.     

Petrogenesis of continental mafic dykes from the Izera Complex, Karkonosze-Izera Block (West Sudetes, SW Poland)

The Izera Complex (West Sudetes) contains widespread bodies of metagabbro, metadolerite and amphibolite (the Izera metabasites), and less abundant dykes of weakly altered dolerites, emplaced in a continental setting. The primary magmas of the Izera metabasites were probably formed through adiabatic decompression melting of upwelling asthenosphere (mantle plume) that was associated with the early Palaeozoic fragmentation of Gondwana (initial rift). The rocks are mildly alkaline, transitional-to-tholeiitic basalts and have OIB-like trace element patterns. Trace element modelling reveals that the mafic magmas were generated by variable degrees of partial melting (1–7%) of fertile, garnet-bearing asthenospheric source similar in composition to primitive mantle. Together with an increase in degree of partial melting, the compositional affinity of the magmas and the depth of segregation changed progressively from ca. 70–90 km (mildly alkaline magmas of the metadolerites and amphibolites) to ca. 60–75 km (transitional-to-tholeiitic magmas of the metagabbros). The systematics of incompatible versus compatible element distribution, and major and trace element modelling, indicate that some rocks experienced low-pressure (<5 kbar) differentiation resulting in up to 50% fractionation of clinopyroxene, olivine and minor plagioclase and ilmenite. The genetically distinct weakly altered dolerites are basaltic andesite in composition and possibly related to late- or post-orogenic events in the Karkonosze-Izera Block. These rocks are calc-alkaline, with relatively flat MREE–HREE patterns, enrichment in LREE and other highly incompatible elements relative to primitive mantle, and negative Nb–Ta, Ti, P anomalies. The geochemical features and geochemical modelling, indicate that their primary magmas segregated at depths ≤70 km and were produced by ~2% melting of a metasomatized sublithospheric mantle source presumably containing small amounts of hydrated phases. Although the present study is inconclusive as to the origin of the metasomatic component in the source (? slab-derived fluid/melts, OIB-like alkaline melt percolation of subcontinental lithosphere), the genesis of the Izera basaltic andesites is seemingly related to upwelling of asthenosphere and heat flow triggered by a postulated decoupling of the mantle lithosphere and post-collisional extensional collapse and uplift in the Karkonosze-Izera Block.     

Mineral/melt partitioning of trace elements during hydrous peridotite partial melting

This experimental study examines the mineral/melt partitioning of incompatible trace elements among high-Ca clinopyroxene, garnet, and hydrous silicate melt at upper mantle pressure and temperature conditions. Experiments were performed at pressures of 1.2 and 1.6 GPa and temperatures of 1,185 to 1,370 °C. Experimentally produced silicate melts contain up to 6.3 wt% dissolved H ₂O, and are saturated with an upper mantle peridotite mineral assemblage of olivine+orthopyroxene+clinopyroxene+spinel or garnet. Clinopyroxene/melt and garnet/melt partition coefficients were measured for Li, B, K, Sr, Y, Zr, Nb, and select rare earth elements by secondary ion mass spectrometry. A comparison of our experimental results for trivalent cations (REEs and Y) with the results from calculations carried out using the Wood-Blundy partitioning model indicates that H ₂O dissolved in the silicate melt has a discernible effect on trace element partitioning. Experiments carried out at 1.2 GPa, 1,315 °C and 1.6 GPa, 1,370 °C produced clinopyroxene containing 15.0 and 13.9 wt% CaO, respectively, coexisting with silicate melts containing ~1–2 wt% H ₂O. Partition coefficients measured in these experiments are consistent with the Wood-Blundy model. However, partition coefficients determined in an experiment carried out at 1.2 GPa and 1,185 °C, which produced clinopyroxene containing 19.3 wt% CaO coexisting with a high-H ₂O (6.26±0.10 wt%) silicate melt, are significantly smaller than predicted by the Wood-Blundy model. Accounting for the depolymerized structure of the H ₂O-rich melt eliminates the mismatch between experimental result and model prediction. Therefore, the increased Ca ²⁺ content of clinopyroxene at low-temperature, hydrous conditions does not enhance compatibility to the extent indicated by results from anhydrous experiments, and models used to predict mineral/melt partition coefficients during hydrous peridotite partial melting in the sub-arc mantle must take into account the effects of H ₂O on the structure of silicate melts.     

Static elasticity of cordierite II: effect of molecular CO2 channel constituents on the compressibility

Two natural CO₂-rich cordierite samples (1.00 wt% CO₂, 0.38 wt% H₂O, and 1.65 wt% CO₂, 0.15 wt% H₂O, respectively) were investigated by means of Raman spectroscopy and single-crystal X-ray diffraction at ambient and high pressures. The effect of heavy-ion irradiation (Au 2.2 GeV, fluence of 1 × 10¹² ions cm^?2) on the crystal structure was investigated to characterize the structural alterations complementary to results reported on hydrous cordierite. The linear CO₂ molecules sustained irradiation-induced breakdown with small CO₂-to-CO conversion rates in contrast to the distinct loss of channel H₂O. The maximum CO₂ depletion rate corresponds to ~12 ± 5 % (i.e. ~0.87 and ~1.49 wt% CO₂ according to the two samples, respectively). The elastic properties of CO₂-rich cordierite reveal stiffening due to the CO₂ molecules (non-irradiated: isothermal bulk modulus K ₀ = 120.3 ± 3.7 GPa, irradiated: K ₀ = 109.7 ± 3.7 GPa), but show the equivalent effect of hydrous cordierite to get softer when irradiated. The degree of anisotropy of axial compressibilities and the anomalous elastic softening at increasing pressure agrees with those reported for hydrous cordierite. Nevertheless, the experimental high-pressure measurements using ethanol–methanol reveal a small hysteresis between compression and decompression, together with the noticeable effect of pressure-induced over-hydration at pressures between 4 and 5 GPa.     

Phase-equilibrium geobarometers for silicic rocks based on rhyolite-MELTS. Part 1: Principles,procedures, and evaluation of the method

Constraining the pressure of crystallization of magmas is an important but elusive task. In this work, we present a method to derive crystallization pressures for rocks that preserve glass compositions (either glass inclusions or matrix glass) representative of equilibration between melt, quartz, and 1 or 2 feldspars. The method relies on the well-known shift of the quartz–feldspar saturation surface toward higher normative quartz melt compositions with decreasing pressure. The critical realization for development of the method is the fact that melt, quartz and feldspars need to be in equilibrium at the liquidus for the melt composition. The method thus consists of calculating the saturation surfaces for quartz and feldspars using rhyolite-MELTS over a range of pressures, and searching for the pressure at which the expected assemblage (quartz+1 feldspar or quartz+2 feldspars) is found at the liquidus. We evaluate errors resulting from uncertainties in glass composition using a series of Monte Carlo simulations for a quartz-hosted glass inclusion composition from the Bishop Tuff, which reveal errors on the order of 20–45 MPa for the quartz+2 feldspars constraint and on the order of 25–100 MPa for the quartz+1 feldspar constraint; we suggest actual errors are closer to the lower bounds of these ranges. We investigate the effect of fluid saturation in two ways: (1) By applying our procedure over a range of water contents for three glass compositions; we show that the effect of fluid saturation is more important at higher pressures (~300 MPa) than at lower pressures (~100 MPa), but reasonable pressure estimates can be derived irrespective of fluid saturation for geologically relevant H₂O concentrations >3 wt% and (2) by performing the same type of pressure determinations with a preliminary version of rhyolite-MELTS that includes a H₂O–CO₂ mixed fluid phase; we use a range of H₂O and CO₂ concentrations for two compositions characteristic of early-erupted and late-erupted Bishop Tuff glass inclusions and demonstrate that calculated pressures are largely independent of CO₂ concentration (for CO₂ <1,000 ppm), at least for relatively high H₂O contents, as expected in most natural magmas, such that CO₂ concentration can be effectively neglected for application of our method. Finally, we demonstrate that pressures calculated using the rhyolite-MELTS geobarometer compare well with those resulting from H₂O–CO₂ glass inclusion barometry and Al-in-hornblende barometry for an array of natural systems for which data have been compiled from the literature; the agreement is best for quartz-hosted glass inclusions, while matrix glass yields systematically lower rhyolite-MELTS pressures, suggestive of melt evolution during eruptive decompression.