Distribution coefficients of210Pb and210Po in laboratory and natural aquatic systems

We have measured the distribution coefficient (Kd) of²¹⁰Po and²¹⁰Pb in laboratory systems and in natural freshwater systems. In the laboratory systems, an inverse relationship was observed between the particle concentration of sand or lake sediment, and the distribution coefficients of²¹⁰Po and²¹⁰Pb. The slope of the log-linearK _d vs particle concentration relation is consistent with existingK _d-particle concentration theories. These laboratory observations are consistent with similar measurements in two lakes. TheK _d values of Po and Pb for the bottom sediment-pore water system with a high particle concentration were 10 to 100 times lower than those for dilute concentrations of particles suspended in the lake water. TheK _d of²¹⁰Pb in the sediments was >10⁴ so that the diffusive transport of²¹⁰Pb has only a small influence on the interpretation of²¹⁰Pb concentration-depth profiles and the²¹⁰Pb dating of these sediments.This is the second of a series of papers to be published by this journal following the 20^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P. G. Appleby is guest editing.     

A Holocene paleoenvironmental history of Lake Alexandria,South Australia

An investigation of Holocene sediments within Lake Alexandrina, a shallow coastal lake at the mouth of the Murray River, South Australia, is presented based on a multidisciplinary approach.¹⁴C and²¹⁰Pb radiometric dating methods are used to establish a geochronological framework for the last 7000 yr BP, and diatoms, sand-siltclay ratios, organic carbon, phosphorus and copper concentrations are used to infer paleoenvironmental changes.The diatom assemblages indicate a change from marine-brackish to oligosaline-freshwater conditions between 7000 and 6000 yr BP, with sea-level stabilisation and continuous barrier formation across the Murray mouth. Sand pulses after 2300 yr BP document sand spit formation in the lake and the commencement of extensive lacustrine sedimentation.In the past 100 years which include the advent of European settlement in the region, the short-term²¹⁰Pb-based mass accumulation rate of 0.063 g cm^–2 yr^–1 is greater than that of the longer-term mean¹⁴C-based rate (0.023 g cm^–2 yr^–1), and high concentrations of phosphorus and copper correspond to historical records of blue-green algal blooms.This is the fifth in a series of papers published in this issue on the paleolimnology of aric regions. These papers were presented at the Sixth International Paleolimnology Symposium held 19–21 April, 1993 at the Australian National University, Canberra, Australia. Dr A. R. Chivas served as guest editor for these papers.     

How reliable is the210Pb dating method? Old and new results from Switzerland

We present a historical overview of applications of²¹⁰Pb dating in Switzerland with a special emphasis on the work performed at the University of Bern. It is demonstrated that the average specific activity of²¹⁰Pb in the lower atmosphere is very constant and does not show seasonal variations. We then concentrate on new results from Lobsigensee, a very small lake, and on published and new data from Lake Zurich. Several²¹⁰Pb profiles from these lakes show obvious disturbances and a disagreement of the resulting sedimentation rate when compared to that for the 23 years defined by¹³⁷Cs peaks of 1986 (Chernobyl) and 1963 (bomb fallout).A mean sedimentation rate of about 0.14 g cm^–2 y^–1 is found in the oxic and suboxic center part of Lake Zurich. In the oxic locations, the²¹⁰Pb flux to the sediments was close to the atmospheric input of about 1/60 Bq cm^–2 y^–1. In other parts of the lake a significant deficit in the inventory of²¹⁰Pb was found in the sediments. This could be due to a chemical redissolution of²¹⁰Pb together with Mn under reducing conditions. In contrast, in the suboxic part of the lake (135 m depth) the flux of²¹⁰Pb was about twice the atmospheric input. This excess is not caused by allochthonous contributions and is tentatively explained by the transport of sediment material resulting from small slides at the very steep lake shores or more probably by reprecipitation of²¹⁰Pb together with Mn when the conditions in the lake water become locally and seasonally more oxidizing. Dissolved²¹⁰Pb may migrate from locations with reducing conditions and reprecipitate under more oxic conditions. Indeed, a correlation of Mn and²¹⁰Pb in sediments of Lake Zurich was found.This is the first of a series of papers to be published by this journal following the 20^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P. G. Appleby is guest editing this series.     

A sedimentary record of human disturbance from Lake Miragoane,Haiti

Lake Miragoane, Haiti is one of the largest, natural freshwater lakes in the Caribbean (A=7.06 km², z_max=41.0 m, conductivity = 350 S cm^–1). Lake waters are dominated by calcium and bicarbonate ions. The lake was thermally stratified, and oxygen profiles were clinograde during summer visits in 1983 and 1985. A 72-cm mud-water interface core was taken near the center of the lake and dated with ²¹⁰Pb. The local ²¹⁰Pb fallout rate is low (0.09 pCi cm^–2 yr^–1), about 20% of the global average. Bulk sedimentation rates ranged from 0.008 to 0.030 g cm^–2 yr^–1 during the past 130 years (0–8 cm depth). Sediment geochemistry and pollen have been analyzed in the topmost 58 cm of the section. Tentative ages were assigned to the core by extrapolation of ²¹⁰Pb dates. According to this preliminary chronology, the bottom part of the core (58–30 cm) records pre-Columbian sedimentation (1000–500 B.P.) and contains pollen evidence of intact, dry and mesic forest. Pre-Columbian deposits are rich in organic matter (x = 30%) and relatively poor in carbonates (x = 15% as CO₂). The top 30 cm of the core preserve the record since European contact (500 B.P. to present). Pollen data reveal two episodes of deforestation following European arrival. Consequent soil erosion is documented by a decrease in organic matter content (x = 15%) and an increase in carbonates (x = 27% as CO₂). Surficial sediments reflect the widespread deforestation and soil loss that characterize the watershed today.     

Evaluation of210Pb dating in lake sediments using stable Pb,Ambrosia pollen,and137Cs

We used sediment chronology data from fourteen published studies of lake cores across much of North America and Scandinavia in order to make a large scale comparison of the different dating techniques. The uncertainty of²¹⁰Pb derived dates was determined using common sediment event markers: the stable Pb rise, the¹³⁷Cs rise, and theAmbrosia pollen rise. For all data combined, the 95% confidence intervals for the stable Pb rise and theAmbrosia rise, were approximately 30 years. These 95% confidence intervals are slightly higher than those derived by First-Order Error analysis performed by others on²¹⁰Pb derived dates. When comparing the concordance of two²¹⁰Pb models (CRS and CIC) against markers of known history, we found that the CRS model dates (constant rate of supply) had consistently better agreement than the CIC model dates (constant initial concentration). Major discrepancies between¹³⁷Cs and²¹⁰Pb were common, but were consistently more severe in sediments of soft water lakes pointing to an inability of sediments with low mineral content to immobilize Cs.This is the ninth of a series of papers to be published by this journal following the 20 ^th anniversary of the first application of²¹⁰Pb dating of lake sediments, Dr. P. G. Appleby is guest editing this series.     

Resolving the chronology of recent lake sediments: an example from Devils Lake,North Dakota

Devils Lake is a closed, saline lake in North Dakota; it is typical of lake basins in the Great Plains Region, where windy conditions and fluctuating water-levels disturb sediment and confound chronostratigraphy. Pollen analysis and ²¹⁰Pb dating of two cores collected from bathymetrically contrasting embayments demonstrate (1) how certain agriculture-related pollen types differ in their value as chronostratigraphic markers, (2) how pollen and ²¹⁰Pb stratigraphies can be reconciled to determine the approximate depth of sediment mixing, and (3) the importance of coring-site selection, especially in lakes with unstable sedimentary conditions.     

Application of210Pb in soils

The spectroscopic measurement of soil samples is described.²¹⁰Pb data from a soil survey in western-Europe are briefly reviewed. The average²¹⁰Pb flux from the atmosphere, as determined from²¹⁰Pb _exc soil inventories, is 90 Bq m^–2a^–1. A simple one-dimensional box-chain model is described. The model simulates the vertical, post depositional transport of natural and fall-out radionuclides in the soil. Simulation of measured²¹⁰Pb _exc ,¹³⁴Cs,¹³⁷Cs, and²⁴¹Am soil profiles shows that mixing (bioturbation) is a very efficient transport mechanism. Lead seems to be strongly fixed to organic and clay particles. It is transported by the displacement of the organic and clay carrier substances. The mean residence time of lead, caesium, plutonium and americium in organic rich forest soils is in the order of 250–1000 years. An applicability study in investigate the use of²¹⁰Pb in erosion problems showed erosion rates from 60–180 g m^–2a^–1 on organic rich forest and meadow sites with 10°–25° slopes.This is the eighth of a series of papers to be published by this journal following the 20 ^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P. G. Appleby is guest editing this series.     

Biological and Geochemical Record of Anthropogenic Impacts in Recent Sediments from Lake Pupuke, Auckland City, New Zealand

Frozen sediment cores from Lake Pupuke in Auckland City, New Zealand, contain a high resolution decadal to annual scale record of changing lake paleoenvironments and geochemistry that reflects changing landuse and hydrology in the catchment over the past c. 190 years. A reliable chronology is available from AMS ¹⁴C and ²¹⁰Pb dating of the sediments, with the timing of the older part of the record supported by the first appearance of pollen of introduced Pinus and Plantago lanceolata associated with European settlement of Auckland in the early 1840s. Diatom stratigraphy, sediment elemental and carbon isotope geochemistry reflect changes in sediment sources and lake conditions commensurate with European development of the Lake Pupuke catchment, in particular enhanced algal productivity controlled by the influx of nutrients after c. 1920 AD. Attempts to prevent nuisance algal blooms in 1933, 1934 and 1939 using CuSO₄ addition produced Cu spikes in the sediment that allowed confirmation of the accuracy of the ²¹⁰Pb chronology. Hence, the elemental and isotopic composition of the Lake Pupuke sediments reflect the timing of significant anthropogenic activities, rather than climatic variations, that have occurred within the watershed over the past c. 190 years. The comparison of records of land use change in the catchment with the multi-proxy record of changes in the sediments usually allowed unambiguous identification of the signatures of change and their causes.     

Evaluating the mobility of137Cs,239+240Pu and210Pb from their distributions in laminated lake sediments

Post-depositional mobility of¹³⁷Cs,^239+240Pu and²¹⁰Pb was assessed in six small lake basins by comparing sedimentary nuclide profiles with their known fallout history. Laminae couplets, when present, were determined to be varves because the¹³⁷Cs and^239+240Pu 1963 fallout peaks are present in laminae couplets corresponding to years 1962–1964. There is no evidence of mobility of²¹⁰Pb, because 1) mass accumulation rates based on²¹⁰Pb agree with those based on¹³⁷Cs and^239+240Pu peak depths and with those based on varve counts, and 2)²¹⁰Pb ages agree with varve ages. Significant mobility of¹³⁷Cs is evident from the penetration of¹³⁷Cs to depths 15–20 cm deeper than^239+240Pu. Deep penetration of¹³⁷Cs in spite of a sharp gradient below the peak is interpreted by a numerical model to suggest that¹³⁷Cs is present in two distinct forms in these sediments, 67–82% as an immobile form and 18–33% reversibly adsorbed with a K _d of approximately 5000. The profiles can be interpreted equally well assuming a small portionof the total¹³⁷Cs was present as an extremely mobile phase (K _d 5000) in the months to years following peak fallout, slowly becoming more strongly adsorbed. High NH ₄ ⁺ concentrations in porewaters may enhance diffusion of the mobile form of¹³⁷Cs, but not of the immobile form of¹³⁷Cs that defines the sharp gradient. Mobility of¹³⁷Cs is likely also enhanced by the low clay content and the high porosity of these sediments. Thus the first detection of¹³⁷Cs in the sediments cannot automatically be assumed to correspond to a date of 1952 (initial testing of thermonuclear weapons), although the depth of the peak can be assumed to correspond to 1963 (the year of maximum fallout from testing of thermonuclear weapons).^239+240Pu is a more reliable sediment chronometer than¹³⁷Cs because it is significantly less mobile.This is the sixth of a series of papers to be published by this journal following the 20 ^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P.G. Appleby is guest editing this series.     

The transport and mass balance of fallout radionuclides in Blelham Tarn, Cumbria (UK)

Although lake sediment archives are widely used for reconstructing historical records of atmospherically delivered pollutants, the quantitative relationship between fallout levels and their record in the sediments is complex and not well known. The original input signal from the atmosphere can be significantly distorted by mediating transport processes in the catchment, through the water column and within the sediments themselves. Since these processes also affect the fallout radionuclide ²¹⁰Pb commonly used to date sediments, a better understanding of their impact is also important to improving the accuracy and reliability of sediment dating. Blelham Tarn has been the subject of a number of palaeolimnological investigations using radiometric dating techniques since the early 1970s. More recently it was the site of a major study carried out within the EU Transuranics project concerning the long-term fate of fallout radionuclides in catchment/lake systems. This paper reviews the radiometric data from this study and uses the results to determine mass balances for fallout ²¹⁰Pb, ¹³⁷Cs and ^239+240Pu in Blelham Tarn, and their spatial distribution over the bed of the lake. Atmospheric fluxes were determined by measuring concentrations in rainwater and cumulative inventories in soil cores from non-eroding sites. Sediment records in a grid of 16 cores were used to determine the spatial distribution over the bed of the lake, and net inputs from the catchment. Mass balance calculations indicate that c. 47% of ²¹⁰Pb in the sediments derives from erosive inputs from the catchment. For ^239+240Pu the figure rises to 61%. Reduced amounts of ¹³⁷Cs in the sediments are attributed to greater losses of this radionuclide from the water column via the outflow due to its greater solubility. Inputs of radionuclides from the catchment are concentrated near one of the major input streams. Away from this part of the lake the sediment record is dominated by direct atmospheric fallout, though the detailed pattern is influenced by sediment focussing. A one parameter catchment/lake transport model is developed that incorporates the assumption that transport rates will decline with time as fallout on the catchment diffuses into the soil and becomes less available for removal. Values of the transport parameter were calculated for ²¹⁰Pb and ^239+240Pu and found to be comparable. The results suggest that it will take c. 11000 years to remove 50% of ^239+240Pu from the catchment to the lake.     

Interpretation of210Pb profiles and verification of the CRS dating model in PIRLA project lake sediment cores

This paper reports results and analysis of²¹⁰Pb-activity measurements in 51 lake-sediment cores from 32 lakes in the four PIRLA (Paleoecological Investigations of Recent Lake Acidification) project regions (Adirondack Mountains [New York], Northern New England, Northern Florida, and the Northern Great Lakes States). General application of the Constant Rate of Supply (Constant Flux) model for²¹⁰Pb dating is valid for lakes in the PIRLA study, although application of the model is equivocal in a few lakes.²¹⁰Pb inventories and profiles are replicable among closely spaced cores within a lake. Specific²¹⁰Pb activity in surface sediments is negatively correlated with bulk sediment accumulation rate in seepage lakes, but not in drainage lakes. Drainage lakes with lower pH have lower unsupported²¹⁰Pb inventories in sediments, but the relationship does not occur in seepage lakes.²¹⁰Pb profiles in only seven of the cores, all from either the Adirondacks or the northern Great Lakes states, exhibit exponential decay curves. Deviations from an exponential profile include a flattening of the profile in the top few cm or excursions of one or a few measurements away from an exponential curve.²¹⁰Pb dates typically agree with other chronostratigraphic markers, most of which are subject to greater uncertainty. Several hypotheses, including sediment mixing, hydrologic regime, sediment focusing, and acidification, are proposed to explain variation of²¹⁰Pb distribution among lakes and regions. Hydrologic factors exert control on unsupported²¹⁰Pb inventories in PIRLA lakes, and there is a strong focusing effect in drainage lakes but a weak focusing effect in seepage lakes.This is the third of a series of papers to be published by this journal following the 20^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P. G. Appleby is guest editing this series.     

1400-year cold/warm fluctuations reflected by environmental magnetism of a lake sediment core from the Chen Co, southern Tibet, China

Lake Chen Co, situated at 90°33–39E, 28°53–59N with a lake level of 4420 m asl, is an enclosed lake with 148 km² of catchment area and 40 km² of lake surface. It is mainly supplied by glacier melt water either from surface inflow or groundwater. Atmospheric precipitation is mainly concentrated in June–September. A 216-cm long lake sediment core was obtained at a site with 8 m of water depth, 800 m from the lakeshore and 1.5% of the bottom slope in this lake. The sediment core was taken by a piston sampler and was sliced with an interval of 1 cm each. ²¹⁰Pb dating measurement suggested that the average sedimentary rate was 0.16 cm yr^–1, which also was confirmed by ¹³⁷Cs peak occurrence. Magnetic analyses included low-frequency dependent susceptibility (_LF), susceptibility of anhysteretic remanent magnetism (_ARM), the saturation isothermal remanent magnetism (SIRM), the isothermal remanent magnetism (IRM) reverse and Soft and Hard contents were performed for the sediment core. Results showed that _LF was an index for reflecting the environmental conditions, but was not sufficient to reveal details of magnetic features. This had been proved by measurements of IRM Reverse percentage and Soft and Hard magnetic minerals values. The log(SIRM/_LF) had much more information to reveal environmental changes. The _ARM/_LF might be more sensitive to the local environmental conditions because it was well able to indicate the grain-size variations of magnetic particles. In the past ca. 1400 years, the warm stages were ca. 620–740 AD, 1120–1370 AD and since ca. 1900 AD. After an intensively cold stage during ca. 1550–1690 AD, a cold-humid stage from ca. 1690–1900 AD and a warm-dry stage since ca. 1900 AD followed. Among these stages, the warmest one occurred in ca. 1120–1370 AD and the coldest stage was between ca. 1550 and 1690 AD. This result might be compared with many other research results from lake cores, ice cores and the Chinese historical documents.     

Low-background gamma counting: applications for210Pb dating of sediments

Sediment cores from three lakes were dated with²¹⁰Pb using a constant rate of supply (CRS) model. We used low-background gamma counting to measure naturally occurring levels of²¹⁰Pb,²²⁶Ra, and¹³⁷Cs in sediment samples because sample preparation is simple and non-destructive,²²⁶Ra activity provides a direct measure of supported²¹⁰Pb activity for each sample analyzed, and¹³⁷Cs activity may provide an independent age marker for the 1962–1963 peak in atmospheric fallout of this radionuclide. In one core supported²¹⁰Pb activity was estimated equally well from²²⁶Ra activity of each sampling interval or from the mean total²¹⁰Pb activity of constant activity samples at depth. Supported²¹⁰Pb activity was constant with depth in this core. In a short freeze core, determining²²⁶Ra activity of every sample proved advantageous in estimating supported²¹⁰Pb activity because supported²¹⁰Pb activity could be estimated from²¹⁰Pb measurements only at the deepest sampling interval. Supported²¹⁰Pb activity estimated from²²⁶Ra activity also yielded more precise estimates of highly variable sedimentation rates. In the third core²²⁶Ra activity exceeded²¹⁰Pb activity at the top of the core and varied 20 fold with depth. This high input of²²⁶Ra in disequilibrium with²¹⁰Pb is attributed to recent erosion of radium-bearing materials in the drainage basin. These data invalidate the assumption that supported²¹⁰Pb activity is constant in sediment cores and can be estimated from the mean total²¹⁰Pb activity at depths where²¹⁰Pb activity is constant. We recommend using gamma counting or another independent assay of²²⁶Ra to validate the assumption of constant supported²¹⁰Pb activity in sediment cores if there is reason to expect that²²⁶Ra activity varies with depth.This is the fourth of a series of papers to be published by this journal following the 20 ^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr. P.G. Appleby is guest editing this series.     

Chronology of Sediment Deposition in Upper Klamath Lake, Oregon

A combination of tephrochronology and ¹⁴C, ²¹⁰Pb, and ¹³⁷Cs measurements provides a robust chronology for sedimentation in Upper Klamath Lake during the last 45 000 years. Mixing of surficial sediments and possible mobility of the radio-isotopes limit the usefulness of the ¹³⁷Cs and ²¹⁰Pb data, but ²¹⁰Pb profiles provide reasonable average sediment accumulation rates for the last 100–150 years. Radiocarbon ages near the top of the core are somewhat erratic and are too old, probably as a result of detrital organic carbon, which may have become a more common component in recent times as surrounding marshes were drained. Below the tops of the cores, radiocarbon ages in the center of the basin appear to be about 400 years too old, while those on the margin appear to be accurate, based on comparisons with tephra layers of known age.Taken together, the data can be combined into reasonable age models for each site. Sediments have accumulated at site K1, near the center of the basin, about 2 times faster than at site CM2, on the margin of the lake. The rates are about 0.10 and 0.05 cm/yr, respectively. The chronological data also indicate that accumulation rates were slower during the early to middle Holocene than during the late Holocene, consistent with increasing wetness in the late Holocene.     

A test of the possible influence of seabird activity on the <Superscript>210</Superscript>Pb flux in high Arctic ponds at Cape Vera,Devon Island,Nunavut: implications for radiochronology

A large seabird colony of northern fulmars (Fulmarus glacialis) at Cape Vera on Devon Island in the Canadian high Arctic has been shown to act as an effective biological pump, transporting large quantities of marine-derived nutrients and contaminants to the ponds beneath their nesting sites. Previous research has shown that seabirds also have the potential to elevate radionuclide concentrations in their immediate surroundings. Here, we assess the influence of the Cape Vera seabird colony on the ²¹⁰Pb budgets of six affected ponds and one control site, and discuss potential implications with respect to ²¹⁰Pb dating methodologies. In general, fluxes of ²¹⁰Pb at Cape Vera were similar to, or less than, those measured at other Arctic locations not influenced by seabirds. Plots of unsupported ²¹⁰Pb activity versus depth showed a number of non-monotonic features in all sediment cores, necessitating the use of the constant-rate-of-supply (CRS) model to derive age-depth profiles. We conclude that seabird activity has not dramatically increased the ²¹⁰Pb flux to the ponds at Cape Vera. Overall, the low flux of excess ²¹⁰Pb made accurate dating problematic for some of the study cores, necessitating the use of independent dating markers (e.g., ¹³⁷Cs and PCB concentrations) to verify the reliability of the chronologies.     

Anthropogenic impacts recorded in recent sediments from Otisco Lake,New York,USA

Geochemical analysis of ²¹⁰Pb-dated sediment cores from Otisco Lake (New York) combined with analysis of recent land cover change in the watershed revealed the history of land use change, lake management, and industrial pollution since European settlement in the northeastern US. Clearance of forestland for agriculture characterized the early settlement era that was marked in the Otisco Lake sediments by a decline in organic carbon (OC) and OC:N ratios, which indicate a change in the sources of organic matter to the lake. Agricultural land use reached its greatest areal extent in the Otisco watershed around 1900, followed by field abandonment and reforestation over the last century. In the 1920s sediment accumulation rates began to increase coincident with residential development along the lake shore. Nitrogen and organic carbon, which are transported from the watershed, show increased fluxes to the lake in response to this change. Deposition of inorganic carbon increased markedly over a short period from the 1940s to the 1980s, which is consistent with enhanced mobilization of watershed calcium by increased acidic deposition, followed by alkalinization of the lake waters and calcite precipitation. An increase in copper content in the sediments reflects application, since 1942, of the algicide copper sulfate to the lake waters to control algal blooms. This CuSO₄ marker confirmed the accuracy of the ²¹⁰Pb chronology. Atmospheric mercury (Hg) fluxes to the lake were affected by increased sediment transport from the watershed. The maximum Hg peak in the sediment record, however, was dated to the early 1970s and coincides with maximum Hg emissions to the atmosphere in the Great Lakes region.     

210Pb and 137Cs dating methods in lakes: A retrospective study

²¹⁰Pb has been used for more than two decades to provide the geochronology of annually deposited sediments and to construct pollution histories. Evidence from some lakes suggests that this radionuclide may be adequately mobile to compromise dating reliability. This study provides one test of that possibility by comparing recent measurements of ²¹⁰Pb and trace metals to ones carried out more than 20 yrs in the past. ¹³⁷Cs dating is used to confirm sediment accumulation rates in the recent cores. In the three Connecticut, USA, lakes studied, sediment accumulation rates changed abruptly to higher values between 40-50 yrs ago (increasing by factors of 2.2, 2.9, and 3.0). In all three lakes, rates calculated from ²¹⁰Pb distributions both above and below this horizon agreed, within measurement uncertainty, in recent and older cores. Furthermore, when the older data were corrected for 20 yrs of burial, the changes in slope in ²¹⁰Pb distributions occurred at the same depth in each pair of cores. The depth of sharp peaks in concentrations of trace metals also matched. In general, this evidence supports the idea that sediments in these lakes have simply been buried, without significant diagenetic remobilization of ²¹⁰Pb and trace metals . Nevertheless, some important differences were also observed. For two of the three lakes, there was a significant difference in average sediment accumulation rate during the past 33 yrs as calculated from ¹³⁷Cs and ²¹⁰Pb in the recent cores. Most potential causes for this difference can be ruled out, and it appears that one of the two nuclides is remobilized compared to the other. There were also significant differences in the total inventories of both ²¹⁰Pb and trace metals (both up to 2 ×) between recent and older cores in some cases. This may be due to dissimilar sediment focusing, since it is not known for certain whether the new cores were collected at exactly the same sites as in the past.     

Environmental changes in the Zirahuén Basin, Michoacán, Mexico, during the last 1000 years

Lago de Zirahuén (19° 26 N, 101° 44 W) lies within a montane basin in highland Michoacán, Mexico at 2075 m a.s.l. The lake basin has high recreational value and is promoted as a tourist attraction. Four short (<1 m), sediment–water interface cores were used to investigate Late Holocene environmental change. The cores span approximately the last 1000 years, based on ²¹⁰Pb dating, AMS ¹⁴C dating and tephrochronology. Cesium-137, Americium-241 and tephra layers from Volcan Paricutín (AD 1943–1952) and Volcan Jorullo (AD 1759–1774) provide independent age markers. Cores were analysed for diatoms, magnetic susceptibility and heavy metals (iron, lead, manganese, copper and zinc). Drier climate around 1000 years BP is tentatively inferred from the diatom assemblage and is concordant with other regional records. Increased soil erosion between ca. AD 1100 and AD 1550 may be associated with Pre-Hispanic settlement in the basin, but there is no archaeological evidence to support this. A period of catchment stability occurred during the early Colonial Period, ca. AD 1550–1750. The dramatic decline in the indigenous population following the Spanish Conquest in 1521 may have promoted vegetation recovery on the basin slopes. After the mid-18th century, a significant change in diatom species composition is observed along with an increase in soil erosion, as inferred from the magnetic susceptibility profile. Concentrations of copper and lead also increased. These changes are associated with the establishment of a copper smelting industry in the basin and increased Colonial agricultural development. Recently, tourist developments and commercial agriculture have impacted on the basin. The diatom flora has changed dramatically in the last 20 years, apparently in response to the onset of cultural eutrophication. The palaeoenvironmental evidence suggests that the lake is responding rapidly to land use intensification in the basin, which may have implications for future developments.     

A chronological assessment of Lake Okeechobee (Florida) sediments using multiple dating markers

Reconstructing recent limnological history often relies on lead-210 dating to accurately ascribe a chronology to a sediment profile. In Lake Okeechobee, Florida, a large, shallow subtropical lake that may experience severe mixing, multiple dating methods are required to confirm that conformable sedimentation has been preserved and that the assumptions of the ²¹⁰Pb method are satisfied. This study uses stratigraphic profiles of heavy metals, ¹³⁷Cs, PCBs and pollen as independent dating markers to validate the sediment chronology as determined by ²¹⁰Pb for three cores from the central mud zone of the lake. Unsupported ²¹⁰Pb and most dating markers show distinct concentration/depth profiles, suggesting that the sediments have not been severely mixed for at least the last 75 years. Onset and maximum activity of the radioisotope ¹³⁷Cs in the cores coincides with the ²¹⁰Pb-dated interval of 1945–1970. This agrees well with the known timing of atmospheric deposition of ¹³⁷Cs that resulted from above-ground nuclear testing during late 1940s until 1963. Sediment core profiles of atmospherically deposited metals such as Zn and Pb, which reflect regional increases during industrialization and decreases after regulation in the 1970s, exhibit expected concentration increases and peaks coinciding within 5–15 years of the predicted ²¹⁰Pb dates. Uranium, a contaminant in some phosphate fertilizers, shows large concentration increases at core depths dated to be about 1950 by ²¹⁰Pb, matching the intensification of agriculture after WWII. PCBs, which are expected to peak in the early 1970s, were measured in one core, and the observed peak corresponds to a ²¹⁰Pb date of about 1960. Pollen makers were unable to verify specific events, but increases in disturbance taxa and declines in native types correspond generally with the expected dates assigned by ²¹⁰Pb dating. Conformity between the ²¹⁰Pb defined dates and independent markers of < ±15 years confirm that Lake Okeechobee sediments do preserve a sequential and reliable stratigraphic history of the lake, useful for reconstructing past limnological conditions.     

Late holocene paleoclimatic and paleobiologic records from sediments of Devils Lake,North Dakota

An 84 cm sediment core collected from the center of Devils Lake, North Dakota, was analyzed at 1-cm intervals for,²¹⁰Pb,¹³⁷Cs, sediment conductivity, the concentrations of, biogenic silica, total organic carbon, carbon to nitrogen ratio, and the carbon and nitrogen isotopic composition of the organic fraction. Variations in²¹⁰Pb activities in the upper 20 centimeters indicate that sediment accumulations rates in Devils Lake are not constant, and that accumulation rates were highest during periods of high lake level. The mean sedimentation accumulation rate was calculated as 0.24 cm^–1 yr. The¹³⁷Cs profile is characterized by near-surface maximum concentrations, possibly the result of redistribution of¹³⁷Cs during salinity excursions.Biogenic silica is strongly correlated to lake level in Devils Lake. Periods of low lake level (characterized by high sediment conductivity) correspond to low biogenic silica concentrations. The trends in biogenic silica are attributed to variations in diatom productivity in the lake and to variations in sediment accumulation rates. Based on biogenic silica content and the composition of organic matter in the sediment (total organic carbon, carbon:nitrogen ratio and the ¹³C and ¹⁵N composition of total organic matter), paleobiologic conditions of Devils Lake during low lake stands were characterized by, (1) decreased primary productivity, (2) decreased input of detrital organic matter, and (3) increased nitrogen availability.During the 350 years of sediment accumulation represented by the 84-cm sediment core Devils Lake has experienced two periods of sustained high lake level; one between about 130 and 170 years ago (1820 to 1860 A.D.) and the second between 270 and 310 years ago (1680 to 1720 A.D.). Devils Lake experienced a period of intense drying about 260 years ago (1720 A.D.).