Hydrogeochemical processes in the groundwater environment of Heihe River Basin,northwest China

The Heihe River Basin is a typical arid inland river basin for examining stress on groundwater resources in northwest China. The basin is composed of large volumes of unconsolidated Quaternary sediments of widely differing grain size, and during the past half century, rapid socio-economic development has created an increased demand for groundwater resources. Understanding the hydrogeochemical processes of groundwater and water quality is important for sustainable development and effective management of groundwater resources in the Heihe River basin. To this end, a total of 30 representative groundwater samples were collected from different wells to monitor the water chemistry of various ions and its quality for irrigation. Chemical analysis shows that water presents a large spatial variability of chemical facies (SO₄ ²⁻–HCO₃⁻, SO₄ ²⁻–Cl⁻, and Cl⁻–SO₄ ²⁻) as groundwater flow from recharge area to discharge area. The ionic ratio indicates positive correlation between the flowing pairs of parameters: Cl⁻ and Na⁺(r = 0.95), SO₄ ²⁻ and Na⁺ (r = 0.84), HCO₃ ⁻ and Mg²⁺(r = 0.86), and SO₄ ²⁻ and Ca²⁺ (r = 0.91). Dissolution of minerals, such as halite, gypsum, dolomite, silicate, and Mirabilite (Na₂SO₄·10H₂O) in the sediments results in the Cl⁻, SO₄ ²⁻, HCO₃ ⁻, Na⁺, Ca²⁺ and Mg²⁺ content in the groundwater. Other reactions, such as evaporation, ion exchange, and deposition also influence the water composition. The suitability of the groundwater for irrigation was assessed based on the US Salinity Laboratory salinity classification and the Wilcox diagram. The results show that most of the groundwater samples are suitable for irrigation uses barring a few locations in the dessert region in the northern sub-basin.     

Combinatorial analysis on spatial information statistics for the karst water environment in Guiyang, China

The karst groundwater system is extremely vulnerable and easily contaminated by human activities.To understand the spatial distribution of contaminants in the groundwater of karst urban areas and contributors to the contamination,this paper employs the spatial information statistics analysis theory and method to analyze the karst groundwater environment in Guiyang City.Based on the karst ground water quality data detected in 61 detection points of the research area in the last three years,we made Kriging evaluation isoline map with some ions in the karst groundwater,such as SO4 2-,Fe 3+,Mn 2+and F -,analyzed and evaluated the spatial distribution,extension and variation of four types of ions on the basis of this isoline map.The results of the analysis show that the anomaly areas of SO4 2-,Fe 3+,Mn 2+,Fand other ions are mainly located in Baba’ao,Mawangmiao and Sanqiao in northwestern Gui- yang City as well as in its downtown area by reasons of the original non-point source pollution and the contamination caused by human activities(industrial and domestic pollution).     

Geostatistical analysis of spatiotemporal variability of groundwater level fluctuations in Amman–Zarqa basin,Jordan: a case study

The main objective of this study was to assess the spatial and temporal variability of groundwater level fluctuations in the Amman–Zarqa basin, during the period 2001–2005. In the year 2003, as a consequence of war, there was a sudden increase in the population in this basin. Knowing that the basin is already heavily populated and witnesses most of the human and industrial activities in Jordan, this study was prompted to help make wise water resources management decisions to cope with the new situation. Data from 31 fairly distributed wells in the upper aquifer of the basin were subjected to geostatistical treatment. Kriging interpolation techniques have indicated that the groundwater flow directions remained almost constant over the years. The two main directions are SW–NE and E–W. Kriging mapped fluctuations have also showed that drop and rise events are localized in the basin. Forecasting possibilities for management purposes were tackled using autocorrelation analysis. The constructed autocorrelograms indicated, in general, the temporal dependence of seasonal water level fluctuations, and that forecasting can be carried out within a period of 3–21 months. Several suggestions were made to mitigate the drop and rise hazards in the detected sites.     

Nitrate contamination of groundwater in an agroecosystem in Zhangye Oasis,Northwest China

In order to assess the extent of groundwater contamination by nitrate (NO₃ ⁻–N) and to provide information about the deterioration of the groundwater quality in Zhangye Oasis, Northwest China, a study was conducted in this area. The mean value of NO₃ ⁻–N concentrations in groundwater samples was 10.66 ± 0.19 mg l⁻¹. NO₃ ⁻–N concentrations exceeding 10 mg l⁻¹ (the threshold for drinking water set by the World Health Organization) were found in 32.4% of 71 wells, and were 13, 33.3, 52.4 and 50.0% in the groundwater samples from drinking wells, irrigation wells, hand-pumping wells and groundwater table observation wells, respectively. The result showed that the groundwater samples that had NO₃ ⁻–N concentrations exceeding the threshold for drinking water were mostly collected from a depth of less than 20 m. Groundwater NO₃ ⁻–N concentrations in areas used for the cultivation of vegetables, seed maize and intercropped maize were significantly higher than those in urban or paddy areas. NO₃ ⁻–N contamination of groundwater in areas with sandy soil was more severe than in those with loam soil.     

Hydrochemical evaluation of groundwater quality in the Çavuşçayı basin, Sungurlu-Çorum, Turkey

The purpose of this study is to investigate the quality and usage possibility of groundwater in the Çavuşçayı basin and suggest the best water structure for the groundwater use. Results from hydrochemical analyses reveal that groundwater is mostly affected by salty (Na⁺–Cl⁻) waters of the Incik Formation and brackish (Ca²⁺, Mg²⁺–SO ₄ ²⁻ ) waters of the Bayındır Formation. The Alibaba saltpan discharged (2 l/s) from the Incik Formation is used for salt production. In the basin, salinity risk increases with depth and along the groundwater flow direction. Therefore, shallow water and trenches opened in the alluvium aquifer at the east of the basin were determined to yield suitable water with no Na⁺ and Cl⁻ contamination. Following the heavy rainy period, waters of less salinity and conductivity are possibly used for agriculture.     

Nutrient chemistry and salinity mapping of the Delhi aquifer,India: source identification perspective

Present study is an effort to distinguish between the contributions of natural weathering and anthropogenic inputs towards high salinity and nutrient concentrations in the groundwater of National Capital Territory (NCT) Delhi, India. Apart from the source identification, the aquifer of entire territory has been characterized and mapped on the basis of salinity in space and water suitability with its depth. Major element chemistry, conventional graphical plots and specific ionic ratio of Na⁺/Cl⁻, SO₄ ²⁻/Cl⁻, Mg²⁺/Ca²⁺ and Ca²⁺/(HCO₃ ⁻ + SO₄ ²⁻) are conjointly used to distinguish different salinization sources. Results suggest that leaching from the various unlined landfill sites and drains is the prime cause of NO₃ ⁻ contamination while study area is highly affected with inland salinity which is geogenic in origin. The seasonal water level fluctuation and rising water level increases nutrients concentration in groundwater. Mixing with old saline sub-surface groundwater and dissolution of surface salts in the salt affected soil areas were identified as the principle processes controlling groundwater salinity through comparison of ionic ratio. Only minor increase of salinity is the result of evaporation effect and pollution inflows. The entire territory has characterized into four groups as fresh, freshening, near freshening and saline with respect to salinity in groundwater. The salinity mapping suggests that in general, for drinking needs, groundwater in the fresh, freshening and near freshening zone is suitable up to a depth of 45, 20 and 12 m, respectively, while the saline zones are unsuitable for any domestic use. In the consideration of increasing demand of drinking water in the area; present study is vital and recommends further isotopic investigations and highlights the need of immediate management action for landfill sites and unlined drains.     

The effects of human activities on oasis climate and hydrologic environment in the Aksu River Basin,Xinjiang, China

Under the influence of human activities, the differences in climate changes emerged obviously in the Aksu Oasis. The summer air temperature in Aksu City increased at a rate of 0.20°C·(10 annum)⁻¹, while the air temperature in Aler in summer decreased at a rate of −0.27°C·(10 annum)⁻¹. Human intervention has become the dominant factor in the the changes of water resources in the Aksu Oasis. Compared with the Xidaqiao hydrological station, which is located on the upper reaches of the Aksu River, the runoff ratio at the Aler hydrological station increased in summer and decreased in spring. Though the natural water inflow has increased in the last 50 years, irrigation diversion and water consumption for human activities have increased unceasingly due to the increased reclamation of land and the development of extensive agriculture. The water quality at the Xidaqiao station is in Grade I at different periods, and the water quality at the Aler station of the Tarim River is good because the river did not suffer from human disturbance before the large-scale development of oasis agriculture; but the salinity of river water increased from 0.67 g L⁻¹ in 1960 to 5.27 g L⁻¹ in 2000 at the Aler station after farmland development, reclamation and salt washing in the oasis. The geographic distribution of surface water resources has changed due to human activities and in turn affected groundwater replenishment, bringing about changes to groundwater table and quality.     

The threshold value of epikarst runoff in forest karst mountain area

Hydrochemical investigations were carried out in Damagh area, Hamadan, western Iran, to assess chemical composition of groundwater. Forty representative groundwater samples were collected from different wells to monitor the water chemistry of various ions. Chemical analysis of the groundwater showed that the mean concentration of the cations is in the order Na⁺ > Ca²⁺ > Mg²⁺ > K⁺, while that for anions was HCO₃⁻ > Cl⁻ > SO₄^{2 −} > NO₃⁻. All of the investigated groundwaters present two different chemical facies (Ca–HCO₃ and Na–HCO₃) which is in relation with their interaction with the geological formations of the basin, cation exchange between groundwater and clay minerals and anthropogenic activities. The principal component analysis (PCA) performed on groundwater identified three principal components controlling their variability in groundwater. Electrical conductivity, Mg²⁺, Na⁺, SO₄²⁻, and Cl⁻ content were associated in the same component (PC1) (salinity), determined principally by anthropogenic activities. The pH, CO₃^{2 −}, HCO₃⁻, and Ca²⁺ (PC2) content were related to the geogenic factor. Finally, the NO₃⁻, Cl⁻ and K⁺ (PC3) were controlled by anthropogenic activity as a consequence of inorganic fertilizers.     

Assessment of groundwater quantity and quality and saltwater intrusion in the Damghan basin,Iran

This study describes the groundwater quantity and quality conditions in the Damghan aquifer in Iran. The quantitative analysis of data obtained from observation wells indicates overexploitation of groundwater during recent years, which has resulted in deterioration of water quality. The mean water level has declined about 7.4 m between years of 1966 and 2010. The hydrochemical facies of water collected from sampling wells were investigated though Piper and Chadha diagrams, and the general dominant type of water in the study area was determined as Na-Cl. The quality assessment examined the suitability of groundwater for drinking and irrigation purposes. Compared to the World Health Organization (WHO) guidelines for drinking water, all regions were found to have unpotable groundwater. Furthermore, unsuitability of groundwater for agricultural applications due to high salinity was observed through analysis of major quality indicators. The saltwater intrusion was investigated by ionic ratio analyses and was determined to be the main factor contributing to high salinity and deterioration of the groundwater quality in the Damghan basin.     

Geochemical provenance and spatial distribution of fluoride in groundwater of Taiyuan basin,China

Hydrogeochemistry data were utilized to understand origin, distribution, and geochemical evolution of the high-fluoride groundwater in Taiyuan basin, China. In the study area, the spatial distribution of the high-fluoride groundwater are strictly controlled by the host rock and geomorphic conditions. Three types of groundwater with the F⁻ concentration of <1.5 mg/L, 1.5–2 mg/L and >2 mg/L are located in the areas bordering the limestone zones, in the areas bordering the sandstone of Permian and Carboniferous, and in the depressions of the central parts of the basin, respectively. The high-fluoride groundwater mostly have the high values of TDS, and its values of pH range from 7.2 to 8.8. The most common water types of the high-fluoride groundwater are Na·Ca–HCO₃ and Na·Mg–HCO₃. The geochemical mode reveals that the dissolution of the fluorine-containing minerals and the evaporation effect of the shallow groundwater control the evolution of high F⁻ concentration in Taiyuan basin.     

Sources of deep groundwater salinity in the southwestern zone of Bangladesh

Twenty groundwater samples were collected from two different areas in Satkhira Sadar Upazila to identify the source of salinity in deep groundwater aquifer. Most of the analyzed groundwater is of Na–Cl–HCO₃ type water. The trends of anion and cation are Cl⁻ > HCO₃ ⁻ > NO₃ ⁻ > SO₄ ²⁻ and Na⁺ > Ca²⁺ > Mg²⁺ > K⁺, respectively. Groundwater chemistry in the study area is mainly governed by rock dissolution and ion exchange. The dissolved minerals in groundwater mainly come from silicate weathering. The salinity of groundwater samples varies from ~1 to ~5%, and its source is possibly the paleo-brackish water which may be entrapped during past geologic periods.     

Hydrochemical characteristics of groundwater in the Kingston Basin,Kingston, Jamaica

The Kingston Basin in Jamaica is an important hydrologic basin in terms of both domestic and industrial sector. The Kingston hydrologic basin covers an area of approximately 258 km² of which 111 km² underlain by an alluvium aquifer, 34 km² by a limestone aquifer and the remainder underlain by low permeability rocks with insignificant groundwater resources. Rapid development in recent years has led to an increased demand for water, which is increasingly being fulfilled by groundwater abstraction. A detailed knowledge of the water quality can enhance understanding of the hydrochemical system, promoting sustainable development and effective management of groundwater resources. To achieve this, a hydrochemical investigation was carried out in the Kingston Basin. Results showed that the water is Na–Ca–Cl–HCO₃ and Na–Ca–HCO₃ type with higher concentrations of nitrate, sodium and chloride as the leading causes of contamination in most of the wells. High concentrations of nitrate correlate with wells from areas of high population density and could be attributed to anthropogenic causes, mainly involving improper sewage treatment methodologies or leaking sewer lines. Jamaica, owing to its island nature, has the continuous problem of saline water intrusion, and this is reflected in the higher levels of chloride, sodium and conductivity in the water samples collected from the wells. The wells studied show higher concentrations of chloride ranging from around 10.2 mg/l in wells located approximately (4931.45 m) from the coast to around 234 mg/l in the well located near to the coast. The conductivity values also closely correlate with the chloride levels found in the wells.     

Hydrochemical characteristics of groundwater in the Zhangye Basin, Northwestern China

The Zhangye Basin, located in arid northwest China, is an important agricultural and industrial center. In recent years rapid development has created an increased demand for water, which is increasingly being fulfilled by groundwater abstraction. Detailed knowledge of the geochemical evolution of groundwater and water quality can enhance understanding of the hydrochemical system, promoting sustainable development and effective management of groundwater resources. To this end, a hydrochemical investigation was conducted in the Zhangye Basin. Types of shallow groundwater in the Zhangye Basin were found to be HCO₃ ⁻, HCO₃ ⁻–SO₄ ²⁻, SO₄ ²⁻–HCO₃ ⁻, SO₄ ²⁻–Cl⁻, Cl⁻–SO₄ ²⁻ and Cl⁻ . The deep aquifer groundwater type was found to be HCO₃⁻–SO₄²⁻ throughout the entire area. Ionic ratio and saturation index calculations suggest that silicate rock weathering and evaporation deposition are the main processes that determine the ionic composition in the study area. The suitability of the groundwater for irrigation was assessed based on the US Salinity Laboratory salinity classification and the Wilcox diagram. In the study area, the compositions of the stable isotopes δ¹⁸O and δD in groundwater samples were found to range from −4.00 to −9.28‰ and from −34.0 to −65.0‰, respectively. These values indicate that precipitation is the main recharge source for the groundwater system; some local values indicate high levels of evaporation. Tritium analysis was used to estimate the ages of the different groundwaters; the tritium values of the groundwater samples varied from 3.13 to 36.62 TU. The age of the groundwater at depths of less than 30 m is about 5–10 years. The age of the groundwater at depths of 30–50 m is about 10–23 years. The age of the groundwater at depths of 50–100 m is about 12–29 years. For groundwater samples at depths of greater than 100 m, the renewal time is about 40 years.     

Influence of hydrogeochemical processes on temporal changes in groundwater quality in a part of Nalgonda district, Andhra Pradesh, India

Geochemical processes that take place in the aquifer have played a major role in spatial and temporal variations of groundwater quality. This study was carried out with an objective of identifying the hydrogeochemical processes that controls the groundwater quality in a weathered hard rock aquifer in a part of Nalgonda district, Andhra Pradesh, India. Groundwater samples were collected from 45 wells once every 2 months from March 2008 to September 2009. Chemical parameters of groundwater such as groundwater level, EC and pH were measured insitu. The major ion concentrations such as Ca²⁺, Mg²⁺, Na⁺, K⁺, Cl⁻, and SO₄ ²⁻ were analyzed using ion chromatograph. CO₃ ⁻ and HCO₃ ⁻ concentration was determined by acid–base titration. The abundance of major cation concentration in groundwater is as Na⁺ > Ca²⁺ > Mg²⁺ > K⁺ while that of anions is HCO₃ ⁻ > SO₄ ²⁻ > Cl⁻ > CO₃ ⁻. Ca–HCO₃, Na–Cl, Ca–Na–HCO₃ and Ca–Mg–Cl are the dominant groundwater types in this area. Relation between temporal variation in groundwater level and saturation index of minerals reveals the evaporation process. The ion-exchange process controls the concentration of ions such as calcium, magnesium and sodium. The ionic ratio of Ca/Mg explains the contribution of calcite and dolomite to groundwater. In general, the geochemical processes and temporal variation of groundwater in this area are influenced by evaporation processes, ion exchange and dissolution of minerals.     

Influence of surface/groundwater interaction on pollution by pesticides in farmlands of the Fucino Plain,central Italy

This paper analyses flow and transport of pesticides from the unsaturated zone to groundwater so as to predict concentration of those contaminants in the Fucino Plain’s groundwater, by site investigations and numerical simulations. Pesticides were detected in surface water (peaks of 13 μg L⁻¹) and groundwater (peaks of 0.37 μg L⁻¹). Modelling tools made it possible to identify that pattern of precipitation, organic matter content, and root thickness are the key factors involved in vertical seepage of pesticides. Numerical simulations indicated that a significant fraction of contaminants is leached from the most surficial soil layers through runoff, while only a secondary fraction is mobilised towards groundwater. Likelihood of contaminating deep groundwater is fairly low, whereas surface waters show higher susceptibility. Results of the proposed conceptual hydrogeological model show that pesticides are more likely to be entrained by mixing of stream water with shallow groundwater in periods of high water exploitation from shallow wells.     

Characterization and appraisal of facets influencing geochemistry of groundwater in the Kulpawn sub-basin of the White Volta Basin, Ghana

Groundwater composition in the Kulpawn basin is largely controlled by aluminosilicates dissolution and cation exchange resulting in mainly Ca-Mg-HCO₃ and NaHCO₃ water types. Principal component analysis, Piper graphical classification, and stable isotope (¹⁸O and ²H) of groundwater and surface-water samples were used to delineate geochemical processes and groundwater facies. The groundwater is mildly acid to neutral and low in conductivity. Chemical constituents except HCO₃ ⁻ and SiO₂ have low concentration. No cation shows clear majority, however, the order of relative abundance is Na⁺ > Ca²⁺ > Mg²⁺ > K⁺. HCO₃ ⁻ is the predominant anion and the order of abundance is HCO₃ ⁻ > NO₃ ⁻ > SO₄ ²⁻ > Cl⁻. SiO₂ concentration is high compared with the major cations. Dissolution of plagioclase, pyroxene and biotite and cation exchange are responsible for groundwater composition. Isotopic data suggest integrative, smooth and rapid recharge from meteoric origin. The groundwater quality is generally good for domestic usage; however, 18 and 47% of boreholes respectively have NO₃ ⁻ and F⁻ levels outside WHO recommended limits suggesting potential physiological problems in some localities. The groundwater has low sodium absorption ratio and low to moderate salinity hazard but significant magnesium hazard partially limiting its use for irrigation.     

Spatio-temporal characterization of the Pliocene aquifer conditions in Wadi El-Natrun area,Egypt

Wadi El-Natrun area has recently undergone extensive urban and agricultural expansion. Due to the absence of natural surface irrigation supplies, the only source of water in the area is the Pliocene groundwater aquifer. As a result, secondary salinization from increased abstractions is the major threat to the groundwater aquifer. There is a dire need for efficient strategies to ensure long-term sustainability of the area’s productive agriculture. These strategies should be based on scientific spatio-temporal monitoring and analysis of the groundwater conditions that is also lacking. To capture the spatio-temporal variability in groundwater conditions, field measurements of total dissolved solids, electrical conductivity, pH, temperature, and water level as well as lab-based ionic composition were performed on 47 groundwater samples collected during 2006 and 2007. Determinations of the hydrochemical characteristics, water types, salt assemblages, and the sodium adsorption ratio were carried out on the samples. Reference data sets recorded in 1973 and 1997 were available for the area and were used to monitor the changes occurred in these periods. Geographic information system (GIS) was appraised for mapping and for integrated analysis of the different layers. Remotely sensed change detection techniques were applied to the Landsat TM and the ETM + imageries and used to highlight the extensive reclamation and urbanization and to find key trends for the alterations in the groundwater conditions and their spatial association with land covers. Results revealed a topographic depression-induced flow pattern, predominance of leaching and dissolution processes, the presence of saline lakes, over-pumping from the Pliocene aquifer, and temporal changes in land uses are the main factors combined to control the spatio-temporal variability in the groundwater. Results also clarified the presence of two: northwestern and southeastern zones that varied distinctively in their hydrodynamic and hydrochemical characteristics. The northwestern zone showed an average water level decline of 15 m, the water of which is brackish (av. 2,037 mg/l) with dominant Na⁺, Cl⁻ and SO₄ ²⁻ ions. The groundwater of this zone is characterized by high to very high salinity hazard and high to very high alkali hazard and is not recommended for irrigation on soils with poor drainage and without proper management for salinity control. The southeastern zone showed water level decline less than 2 m, the water of which is fresh (av. 424 mg/l) with major Na⁺, HCO₃ ⁻, Cl⁻, and SO₄ ²⁻ ions, and quality suitable for irrigation with medium to high salinity and low to medium alkali hazards. The article represents the first step towards an integrated management of Wadi El-Natrun groundwater resources within a GIS framework.     

Optimization of water resources management using SWOT analysis: the case of Zakynthos Island, Ionian Sea, Greece

Zakynthos, an island of 408 km² in the Ionian Sea, is completely dependent on its groundwater resources for fulfilling the demands of the water supplies. The use of groundwater resources has become particularly intensive during the last decades because of the intense urbanization, the tourist development and the irrigated land expansion that took place. The main aquifers are developed in limestones (karstic), sandstones of neogene deposits (confined) and alluvial deposits (phreatic). This paper focuses on the assessment of their hydrogeological characteristics and the groundwater quality. For this investigation, groundwater level measurements, drilling data, pumping tests and chemical analyses of groundwater samples were used. The average annual consumption that is abstracted from the aquifer systems, is 4.9 × 10⁶ m³ year⁻¹. The exploitable groundwater reserves were estimated to be 3.3 × 10⁶ m³ year⁻¹. In the last decades, the total abstractions exceed the natural recharge, due to the tourist development; therefore the aquifer systems are not used safely. The results of chemical analyses showed a deterioration of the groundwater quality. According to the analyses the shallow alluvial aquifer and the confined aquifer are polluted by nitrates at concentrations in excess of 25 mg L⁻¹. High sulphate concentrations might be related to the dissolution of gypsum. Seawater intrusion phenomena are recorded in coastal parts of aquifer systems. The increased Cl⁻ concentrations in karstic aquifer indicate signs of overexploitation. Strengths, weaknesses, opportunities and threats (SWOT) analysis was applied in order to evaluate the SWOT of the groundwater resources. Moreover, some recommendations are made to assist the rational management that aim at improving the sustainability of the groundwater resources of Zakynthos Island.     

Assessment of groundwater contamination by NO<Subscript>3</Subscript><Superscript>−</Superscript> using geographical information system in the Zhangye Basin,Northwest China

Geographical information system (GIS) technology was used to investigate NO₃ ⁻ concentration of groundwater in the Zhangye Basin, Northwest China. Thematic information and NO₃ ⁻ data of groundwater from the Zhangye Basin were analyzed in a GIS environment to study the extent and variation of NO₃ ⁻ concentration and to establish spatial relationships with corresponding land use types. About 38.8% of groundwater samples showed NO₃ ⁻ concentration above the human affected value (13 mg/l NO₃ ⁻), while more than 10.2% exceeded the maximum acceptable level (50 mg/l NO₃ ⁻) according to WHO regulations. The spatial distribution of NO₃ ⁻ of groundwater in the Zhangye Basin showed an obvious character of zonation; the high NO₃ ⁻ concentration was mainly located in the city seat areas, and Zhangye City was the high-value center. The probability of over 90% for NO₃ ⁻ concentration exceeding 13 mg/l was found in urban seat areas. The spatial analyses indicated that groundwater contamination by NO₃ ⁻ was closely related to one specific land use class, the urban. The NO₃ ⁻ concentration of groundwater under urban was significantly higher than that under irrigation land or sand dune. Most of the unacceptable NO₃ ⁻ levels were found in groundwater samples assigned to urban area, but a few were also found allotted to irrigation land class. Therefore, urban source was considered the principal source of NO₃ ⁻ contamination of groundwater in the Zhangye Basin, while irrigation land source was still a possible source of NO₃ ⁻ contamination.     

Vulnerability of headwater catchment resources to incidences of <Superscript>210</Superscript>Pb excess and <Superscript>137</Superscript>Cs radionuclide fallout

Recent identification of elevated excess ²¹⁰Pb (≤302.6 mBq L⁻¹) and ¹³⁷Cs (≤111.3 mBq L⁻¹) activity in drinking water wells up to 20 m depth indicates some transport of airborne radionuclide fallout beyond soils in the Shaker Village catchment, Maine. Estimated airborne mass loading ²¹⁰Pb_ex fluxes of about 0.9 mBq m⁻³, canvass this headwater catchment and may be sufficient to pose risks to unprotected shallow wells. Inventories of ²¹⁰Pb_ex and ¹³⁷Cs in pond sediments indicate maximum median activities of 943 mBq g⁻¹ and 40.0 mBq g⁻¹, respectively. Calculated ²¹⁰Pb_ex fluxes in the catchment soils range from 0.62–0.78 Bq cm⁻² year⁻¹ and yield a mean residence time of near 140 years. Measured ¹³⁷Cs activity up to 51.1 mBq g⁻¹ occurs in sediments at least to 5 m depth. Assumed particle transport in groundwater with apparent ⁸⁵Kr ages less than 5 years BP (2005) may explain the correlation between these particle-reactive radionuclides and elevated activity in some drinking water wells.