Micromorphology and quality attributes of the loess derived soils affected by land use change: A case study in Ghapan watershed, Northern Iran

In order to study the effects of different land vegetative covers on soil quality attributes, a loess hill slope was selected in eastern Golestan Province, Ghapan watershed, Iran. Four profiles in four land uses, including Quercus natural forest; Pinus artificial forest; Cupressus artificial forest and a cultivated land, were studied. Results showed that MWD was significantly different in the studied land uses, and it varied between 1.6 mm in Quercus natural forest and o.31 mm in cultivated land use. The lowest CEC, microbial respiration rate and organic carbon were 28.4 cmol·kg^1, 177 μgCO2·g^-1·day^-1 and 1.32 % found in cultivated land use, respectively. The organic matter was considerably higher content in the forest areas than that of cultivated land use. The studies on soil profile development revealed that the natural forest soils were highly developed. The soils of the Quercus natural forest were classified as Calcic Haploxeralfs with a well developed argillie horizon unlike the cultivated soils which showed the minimum development and classified as Typic Xerorthents. The soils of the artificial forests had both mollic epipedons and were classified as Typic Calcixerolls with moderate profile development. Micromorphological studies revealed that argillic horizons had speckled and partly crystallitic b-fabric in the natural forest indicating the high landscape stability. In contrast, the crystallitic b-fabric of other land uses shows the absence of enough leaching of carbonate and the subsequent migration of clay particles indicating the unstable conditions and high soil erosion. Intense erosion of the surface horizons of cultivated land use has resulted in the outcropping of the subsurface carbonate rich horizons preventing soil development.     

Spatial heterogeneity of soil mineral oxide components in depression between karst hills,Southwest China

In karst regions,the spatial heterogeneity of soil mineral oxides and environmental variables is still not clear.We investigated the spatial heterogeneity of SiO2,Al2O3,Fe2O3,CaO,MgO,P2O5,K2O,and MnO contents in the soils of slope land,plantation forest,secondary forest,and primary forest,as well as their relationships with environmental variables in a karst region of Southwest China.Geostatistics,principal component analysis(PCA),and canonical correlation analysis(CCA)were applied to analyze the field data.The results show that SiO2was the predominant mineral in the soils(45.02%–67.33%),followed by Al2O3and Fe2O3.Most soil mineral oxide components had a strong spatial dependence,except for CaO,MgO,and P2O5in the plantation forest,MgO and P2O5in the secondary forest,and CaO in the slope land.Dimensionality reduction in PCA was not appropriate due to the strong spatial heterogeneity in the ecosystems.Soil mineral oxide components,the main factors in all ecosystems,had greater influences on vegetation than those of conventional soil properties.There were close relationships between soil mineral oxide components and vegetation,topography,and conventional soil properties.Mineral oxide components affected species diversity,organic matter and nitrogen levels.     

Micromorphology of surface crusts in the Knersvlakte, South Africa

Soils in the Knersvlakte are particularly prone to crusting and have lower inherent infiltrability than other soils across western southern Africa. Micromorphological techniques were used to examine the structure and porosity of soil crusts in the Knersvlakte to ascertain why crusting is so intense in this region. Quantile regression using boundary lines was employed to examine the relationships between infiltrability and soil properties for all samples （n = 67）. This analysis showed that infiltrability is potentially maximal at low water- dispersible ＇clay plus silt＇ content and low silt content （r^2 = 0.72 and 0.64; respectively, n = 67） （Figure 2）. The strength of crusts, pH, EC, clay mineralogy, and water-dispersible clay, silt and ＇clay plus silt＇ content were compared, and a pore analysis using optical microscopy was undertaken on images of six soil thin sections （n = 6） （circular and parallel polarizers）. Pore analysis was further undertaken on five horizontal slices of equal dimensions taken through each soil thin section. The porosity samples with low infiltrability （〈 100 mm·hr^-1, n = 4） had greater crust strength, lower porosity （both total and in the least porous slice） and greater water-dispersible ＇day plus silt＇ and silt content than the porosity samples with high infiltrability （〉 100mm·hr^-1, n = 2）. The porosity samples with low infiltrability showed a trend of lower pH and greater water dispersible clay percentage. Porosity varied within the porosity samples due to the presence of dense clay/silt bands （〈 0.5 mm in width） with relatively few air vesicles. The porosity samples with horizontal slices of low porosity （but large numbers of air vesicles） had low infiltrability, while those without slices of low porosity （and relatively few air vesicles） had high infiltrability. We conclude that the intense crusting and resultant low infiltrability of soils in the Knersvlakte appears to be related to the formation of thin, dense clay/silt bands in the pedoderm.     

Features of soil redistribution and major element migration in a karst hillslope of Southwest China

In this study, we investigated the spatial characteristics of the rate of soil distribution and the mechanism of major element migration in a typical karst hillslope in Guangxi Province, Southwestern China. Soil redistribution was examined using ¹³⁷Cs technique under different hillslope components. With the combination of geochemical methods, the migration characteristics of major elements in soils of three hillslope components in both the horizontal and vertical directions were determined. Thirty-seven soil samples were collected and analyzed for ¹³⁷Cs and the major elements were determined. By using the profile distribution model the mean soil redistribution rates were found to be -17.01, 0.40 and -23.30 t ha^-1 yr^-1 in the summit (BYSD), shoulder (BYSY) and toeslope (BYSJ) components of the studied hillslope, respectively. In comparison to BYSD, the sesquioxides of Fe₂O₃ and TiO₂ tend to be enriched, whereas the alkalis (CaO, MgO, Na₂O and K₂O) tend to be depleted, both in the shoulder and toeslope components. Due to human and animal activities, the contents of CaO, MgO, K2O and Na₂O have somewhat increased within the topsoil. The results indicated that ¹³⁷Cs activities are significantly correlated with clay particles and organic matter, and are affected by the pedogenic process and vegatation. Overall, it maybe necessary to use techniques such as ¹³⁷Cs to investigate soil erosion with the combination of geochemical methods.     

Spectrum characteristics of major ion concentrations at Wuhan sectoin of the Changjiang Rriver

Spectrum analyses of water quality time series have been carried out for five hydrometric stations including Wuhan hydrometric station of the Changjiang(Yangtze) River, etc. The fluctuations of Ca²⁺, Mg²⁺ and HCO ₃ ⁻ concentrations in river water under different physical geography conditions have about two-year cycle which is corresponding to hydrometeorological quasi-biannual-oscillation (QBO). Na⁺, Cl⁻ SO ₄ ²⁻ have about two-year cycle in the area lightly affected by human activities while two-year cycle doesn’t exist in the area heavily affected by human activities. All the fluctuations of major ions have about three-month cycle. The river diseharge fluctuation accounts for 43.9%, 45.1%, 54.3%, 33.9%, 30.3% and 42.7% of the variance of Ca²⁺, Mg²⁺, HCO ₃ ⁻ , Na⁺, Cl⁻, SO ₄ ²⁻ , respectively, at Wuhan from 1962 to 1985. According to the spectrum characteristic of major ions, the duration of the time series has to be at least 13 years for trend analysis of monthly water quality data. Foundation item: Under the auspices of the National Natural Science Foundation of China (No. 49671017). Biography: XIA Xing-hui(1971-), female, a native of Hunan Province, Ph. D. Her research interest includes environmental chemistry.     

Bioflocculant Produced by Klebsiella sp. MYC and Its Application in the li＇eatment of Oil-field Produced Water

Seventy-nine strains of bioflocculant-producing bacteria were isolated from 3 activated sludge samples. Among them, strain MYC was found to have the highest and stable flocculating rate for both kaolin clay suspension and oil-field produced water. The bacterial strain was identified as Klebsiella sp. MYC according to its morphological and biochemical characteristics and 16SrDNA sequence. The optimal medium for bioflocculant production by this bacterial strain was composed of cane sugar 20 g L^-1, KH2PO4 2 g L^-1, K2HPO4 5 g L^- 1, （ NH4）2SO4 0.2 g L^-1, urea 0.5 g L^- 1 and yeast extract 0.5 g L^- 1, the initial pH being 5.5. When the suspension of kaolin clay was treated with0.5% of Klebsiella sp. MYC culture broth, the flocculating rate reached more than 90.0% in the presence of 500mg L^-1 CaCI2, while the flocculating rate for oil-field produced water was near 80.0% in a pH range of 7.0 - 9.0 with the separation of oil and suspended particles from the oil-field produced water under similar conditions. The environment-friendly nature of the bioflocculant and high flocculating rate of the strain make the bioflocculant produced by Klebsiella sp. MYC an attractive bioflocculant in oil-field produced water treatment.     

Assessment of soil organic carbon stock in the upper Yangtze River basin

Soil organic carbon is of great importance to terrestrial ecosystems.Studies on the amount and spatial distribution of soil organic carbon stock in various types of soil can help to better understand the role of soil in the global carbon cycle and provide a scientific basis for the assessment of the magnitude of carbon stored in a given area.Here we present estimates of soil organic carbon stock in soils in the upper reaches of the Yangtze River based on soil types as defined by Chinese Soil Taxonomy and recently compiled into a digital soil database.The results showed that the total soil organic carbon stock of the upper Yangtze River to a depth of 100 cm was 1.452×1013kg.The highest soil organic carbon stock was found in felty soils(2.419×1012kg),followed by dark brown soils(1.269×1012kg),and dark felty soils(1.139×1012kg).Chernozems and irrigation silting soils showed the lowest soil organic carbon stock,mainly due to the small total area of such soils.The soil organic carbon density of these major soil types ranged from 5.6 to 26.1 kg m-2.The average soil organic carbon density of the upper reaches of the Yangtze River was 16.4 kg m-2,which was higher than that of the national average.Soil organic carbon density indicated a distinct decreasing trend from west to east,which corresponds to the pattern of increasing temperature from cold to subtropical.     

Decomposition of algal lipids in clay-enriched marine sediment under oxic and anoxic conditions

A series of laboratory incubation experiments were conducted to examine the decomposition of algal organic matter in clay-enriched marine sediment under oxic and anoxic conditions. During the 245-day incubation period, changes in the concentrations of TOC, major algal fatty acid components (14:0, 16:0, 16:1, 18:1 and 20:5), and n-alkanes (C₁₆–C₂₃) were quantified in the samples. Our results indicate that the organic matters were degraded more rapidly in oxic than anoxic conditions. Adsorption of fatty acids onto clay minerals was a rapid and reversible process. Using a simple G model, we calculated the decomposition rate constants for TOC, n-alkanes and fatty acids which ranged from 0.017–0.024 d⁻¹, 0.049–0.103 d⁻¹ and 0.011 to 0.069 d⁻¹, respectively. Algal organic matter degraded in two stages characterized by a fast and a slow degradation processes. The addition of clay minerals montmorillonite and kaolinite to the sediments showed significant influence affecting the decomposition processes of algal TOC and fatty acids by adsorption and incorporation of the compounds with clay particles. Adsorption/association of fatty acids by clay minerals was rapid but appeared to be a slow reversible process. In addition to the sediment redox and clay influence, the structure of the compounds also played important roles in affecting their degradation dynamic in sediments.     

Isotopic evidence for holocene climatic changes in Bosten Lake, Southern Xinjiang, China

Based on the δ¹³C and δ¹⁸O fluctuation of lacustrine carbonate, CaCO₃ content and sporo-pollen data, a palaeoclimatic history of Bosten Lake during the Holocene has been outlined, several stages of climatic changes are divided, and the following result es are obtained: (1) Palaeoclimatic changes revealed by carbonate isotope around Bosten Lake are basically identical with that revealed by other geological records in Xinjiang. Environmental changes presented apparent Westlies Style model: during cold period, relative humidity increased, δ¹⁸O, δ¹³C and CaCO₃ appeared low; but in warm periods, the dry regime aggravated. (2) The temperature reflected by δ¹⁸O exist evident features being increase in the late period during the Holocene. Together with the δ¹³C, pollen and CaCO₃ analyses, several cold and warm phases which are of broad regional significance can be identified. The warm peaks occurred at about 11.0 ka B.P., 9.4 ka B.P., 7.5 ka B.P., 5.0 ka B.P., 3.0 ka B.P. and 2.0 ka B.P.; the cold peaks at 11.5 ka B.P., 10.5 ka B.P., 8.8 ka B.P., 5.5 ka B.P., 3.3 ka B.P., 2.2 ka B.P. and 1.5 ka B.P.. (3) Several climatic events with the nature of “abrupt climatic changes” are revealed in the periods of 11.0 ka B.P. −10.5 ka B.P., 9.4 ka B.P. −8.8 ka B.P., 5.5 ka B.P. −5.0 ka B.P. and 2.0 ka B.P. −1.5 ka B.P.. (4) The results show that carbonate isotopic record of lacustrine sediment in arid area is very sensitive to climatic changes, and may be play a very important role in understanding the features and mechanism of palaeoclimatic changes.     

Chemical characteristics of water environment in limnic wetlands in the western Songnen Plain, China

Duetoregionalhydrogeologicandclimaticconditions,inthewesternSongnenPlain,themostdistinctcharacteristicofwaterenvironmentinlimnicwetlandsisthatmanywaterbodieshavehighsaltcontentsandpHvalues,andsomelimnicwetlandsbelongtosaltmarshes.Thelimnicwetlandsofthisregionarespecialnaturecomplex.Itisimportantfortheutilizationofwetlandresourcesandtheintegrateddevelopmentofsaline-alkalinesoiltostudychemicalcharacteristicsofwaterenvironmentinthisregion.1NATURALENVIRONMENTCHARACTERISTICSOFTHEWE…     

Antioxidative capacity and enzyme activity in Haematococcus pluvialis cells exposed to superoxide free radicals

The antioxidative capacity of astaxanthin and enzyme activity of reactive oxygen eliminating enzymes such as superoxide dismutase (SOD), peroxidase (POD), catalase (CAT) and ascorbate peroxidase (APX) were studied in three cell types of Haematococcus pluvialis exposed to high concentrations of a superoxide anion radical (O₂⁻). The results show that defensive enzymes and astaxanthin-related mechanisms were both active in H. pluvialis during exposure to reactive oxygen species (ROS) such as O₂⁻. Astaxanthin reacted with ROS much faster than did the protective enzymes, and had the strongest antioxidative capacity to protect against lipid peroxidation. The defensive mechanisms varied significantly between the three cell types and were related to the level of astaxanthin that had accumulated in those cells. Astaxanthin-enriched red cells had the strongest antioxidative capacity, followed by brown cells, and astaxanthin-deficient green cells. Although there was no significant increase in expression of protective enzymes, the malondialdehyde (MDA) content in red cells was sustained at a low level because of the antioxidative effect of astaxanthin, which quenched O₂⁻ before the protective enzymes could act. In green cells, astaxanthin is very low or absent; therefore, scavenging of ROS is inevitably reliant on antioxidative enzymes. Accordingly, in green cells, these enzymes play the leading role in scavenging ROS, and the expression of these enzymes is rapidly increased to reduce excessive ROS. However, because ROS were constantly increased in this study, the enhance enzyme activity in the green cells was not able to repair the ROS damage, leading to elevated MDA content. Of the four defensive enzymes measured in astaxanthin-deficient green cells, SOD eliminates O₂⁻, POD eliminates H₂O₂, which is a by-product of SOD activity, and APX and CAT are then initiated to scavenge excessive ROS.     

Cultural characteristics of chromium resistant unicellular cyanobacteria isolated from local environment in Pakistan

Many unicellular cyanobacteria were isolated from different places： fields, ponds, polluted water, and soils from Muredkey and Kasur tannery areas, near Lahore, Pakistan. Different media like BG 11 medium, Bold Basal medium, Chu＇s # 10 medium and Gotham＇s medium, in standard forms and with slight variations of ingredients, and different pH, temperature and light regimes were checked for the optimum growth of the isolates. The isolation pro- cedure was repeated with different concentrations of chromium to select the resistant strains. These selected strains grew on chromium of the range 100-200 μg/ml in BG 11 medium. Cyanobacteria were maintained in solid and liquid media with/without shaking. Cyanobacterial strains were collected from natural habitats that were accompanied by a diversified group of organisms including bacteria, protozoan, and rotifers etc. In order to eliminate these agents termed as contaminants, we used several methods including phenol treatment, use of antibiotic and careful manual picking of unicellular cyanobacteria. Resistance of these strains against different heavy metals （ZnSO4, MnSO4, NiSO4, COCl2, Pb（NO3）3, CuSO4, HgCl2, AgNO3 and CdCl2） and antibiotics （erythromycin, streptomycin, kanamycin, chloramphenicol, neomycin） was evaluated. Optimum temperature was 30℃ with variable pH for the reduction of Cr^6＋ in to Cr^3＋ in majority of strains.     

Collapse behavior and microstructural evolution of loess soils from the Loess Plateau of China

Loess soils are characterized by metastable microstructure, high porosity and water-sensitivity. These soils have always been problematic soils and attracted attention from researchers all over the world. In the present study, three loess soils extracted at various depths from the Loess Plateau of China, i.e. Malan (Q₃), upper Lishi (Q₂²) and lower Lishi (Q₂¹) loess soils, were studied. Single oedometer-collapse tests were performed on intact loess specimens to investigate the collapse behavior of three loess soils. The microstructure and chemical composition of each loess before and after collapse test were characterized using scanning electron microscopy (i.e. SEM) and energy dispersive spectroscopy (i.e. EDS) techniques. The microstructural evolution due to wetting collapse was interpreted qualitatively and quantitatively in terms of the pore morphology properties. The results suggest that: ① the collapse potential of each loess may rise again after a round of rise and drop, which could be failure of the new-developed stable structure under quite high vertical pressure. It implies that loess may collapse even if it has collapsed. ② Q₃, Q₂² and Q₂¹ loess have different types of microstructure, namely, granule, aggregate and matrix type of microstructure, respectively. ③ The microstructural evolution due to loading and wetting is observed from a granule type to an aggregate type and finally to a matrix type of structure. The variations in distributions of pore morphology properties indicate that collapse leads to a transformation of large-sized pores into small-sized pores, re-orientation and remolding of soil pores due to particle rearrangement. ④ A porous structure is essential for loess collapse; however, the non-water-stability of bonding agents promotes the occurrence of collapse under the coupling effect of loading and wetting.     

Effects of iron electrovalence and species on growth and astaxanthin production of Haematococcus pluvialis

To increase the cell concentration and the accumulation of astaxanthin in the cultivation of Haematococcus pluvialis, effects of different iron electrovalencies (Fe²⁺-EDTA and Fe³⁺-EDTA) and species (Fe-EDTA, Fe(OH)_x^32x and FeC₆H₅O₇) addition on cell growth and accumulation of astaxanthin were studied. Results show that different iron electrovalencies have various effects on cell growth and astaxanthin accumulation of H. pluvialis. Compared with Fe³⁺-EDTA, Fe²⁺-EDTA stimulate more effectively the formation of astaxanthin. The maximum astaxanthin content (30.70 mg/g biomass cell) was obtained under conditions of 18 μmol/L Fe²⁺-EDTA, despite the lower cell density (2.3×10⁵ cell/ml) in such condition. Fe³⁺-EDTA is more effective than Fe²⁺-EDTA in improving the cell growth. Especially, the maximal steady-state cell density, 2.9×10⁵ cell/ml was obtained at 18 μmol/L Fe³⁺-EDTA addition. On the other hand, all the various species of iron (EDTA-Fe, Fe(OH)_x^32x, FeC₆H₅O₇) are capable to improve the growth of the algae and astaxanthin production. Among the three iron species, FeC₆H₅O₇ performed the best. Under the condition of a higher concentration (36 μmol/L) of FeC₆H₅O₇, the cell density and astaxanthin production is 2 and 7 times higher than those of iron-limited group, respectively. The present study demonstrates that the effects of the stimulation with different iron species increased in the order of FeC₆H₅O₇, Fe(OH)_x^32x and EDTA-Fe. Supported by Xiamen Scientific and Technologic Projects (No. 3052Z20031086), Xiamen University Alumni Association Foundation in Singapore, and the First National College Students Innovative Experimental Project     

Effects of Anthropogenic Disturbance on Sediment Organic Carbon Mineralization Under Different Water Conditions in Coastal Wetland of a Subtropical Estuary

The changes in soil organic carbon(C) mineralization as affected by anthropogenic disturbance directly determine the role of soils as C source or sink in the global C budget. The objectives of this study were to investigate the effects of anthropogenic disturbance(aquaculture pond, pollutant discharge and agricultural activity) on soil organic C mineralization under different water conditions in the Minjiang River estuary wetland, Southeast China. The results showed that the organic C mineralization in the wetland soils was significantly affected by human disturbance and water conditions(P 0.001), and the interaction between human disturbance activities and water conditions was also significant(P 0.01). The C mineralization rate and the cumulative mineralized carbon dioxide-carbon(CO_2-C)(at the 49th day) ranked from highest to lowest as follows: Phragmites australis wetland soil aquaculture pond sediment soil near the discharge outlet rice paddy soil. This indicated that human disturbance inhibited the mineralization of C in soils of the Minjiang River estuary wetland, and the inhibition increased with the intensity of human disturbance. The data for cumulative mineralized CO_2-C showed a good fit(R~2 0.91) to the first-order kinetic model C_t = C_0(1 – exp(–kt)). The kinetic parameters C_0, k and C_0 k were significantly affected by human disturbance and water conditions. In addition, the total amount of mineralized C(in 49 d) was positively related to C_0, C_0 k and electrical conductivity of soils. These findings indicated that anthropogenic disturbance suppressed the organic C mineralization potential in subtropical coastal wetland soils, and changes of water pattern as affected by human activities in the future would have a strong influence on C cycling in the subtropical estuarine wetlands.     

ORIGIN OF CARBONATE MATERIALS IN THE NORTHERN BASIN OF LAKE BAIKAL AND ITS RELATIONSHIP TO HOLOCENE PALEOCLIMATE

Fine-grained disseminated carbonate was found in Holocene sediments in a core taken from the northern basin of Lake Baikal. The core had two distinct facies. a terrigenous blue-clay overlain by a diatomaceous silt. Oxygen and carbon stable isotope analyses, combined with SEM , X-ray diffraction and .palynology, show that the carbonate in the blue-clay layer is pedogenic in origin, rather than biogenic or authigenic . The S C values in the blue clay suggest that the carbonate is derived from a single source , while the carbonate in the diatom-rich layer might be transported by winds from different sources. On the assumption that the carbonate was formed during the post-glacial age and was transported primarily by river runoff, the 18O isotopic values suggest that the annual temperature in the northern Baikal drainage area was about 3℃ warmer during the middle Holocene (8500-7000 a, B. P.) than during the early Holocene (11 000-8 500a, B.P.) when the blue clay was being deposited . This interpretation is     

Distributions and Relationships of CO<Subscript>2</Subscript>, O<Subscript>2</Subscript>, and Dimethylsulfide in the Changjiang (Yangtze) Estuary and Its Adjacent Waters in Summer

The distributions and relationships of O₂, CO₂, and dimethylsulfide (DMS) in the Changjiang (Yangtze) Estuary and its adjacent waters were investigated in June 2014. In surface water, mean O₂ saturation level, partial pressure of CO₂ (pCO₂), and DMS concentrations (and ranges) were 110% (89%–167%), 374 μatm (91–640 μatm), and 8.53 nmol L^?1 (1.10–27.50 nmol L^?1), respectively. The sea-to-air fluxes (and ranges) of DMS and CO₂ were 8.24 μmol m^?2 d^?1 (0.26–62.77 μmol m^?2 d^?1), and ?4.7 mmol m^?2 d^?1 (?110.8-31.7 mmol m^?2 d^?1), respectively. Dissolved O₂ was oversaturated, DMS concentrations were relatively high, and this region served as a sink of atmospheric CO₂. The pCO₂ was significantly and negatively correlated with the O₂ saturation level, while the DMS concentration showed different positive relationships with the O₂ saturation level in different water masses. In vertical profiles, a hypoxic zone existed below 20 m at a longitude of 123°E. The stratification of temperature and salinity caused by the Taiwan Warm Current suppressed seawater exchange between upper and lower layers, resulting in the formation of a hypoxic zone. Oxidative decomposition of organic detritus carried by the Changjiang River Diluted Water (CRDW) consumed abundant O₂ and produced additional CO₂. The DMS concentrations decreased because of low phytoplankton biomass in the hypoxic zone. Strong correlations appeared between the O₂ saturation level, pCO₂ and DMS concentrations in vertical profiles. Our results strongly suggested that CRDW played an important role in the distributions and relationships of O₂, CO₂, and DMS.     

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Controlling mechanisms for the trace metals, (Cu,Zn, Cd,Fe, Co and Ni) in anoxic sea water in Saanich Inlet,British Columbia,Canada

A study was conducted on Cu, Zn, Cd, Fe, Co and Ni levels in Saanich Inlet anoxic seawater. Data on the concentration of these trace metals and H₂S, and other oceanographic parameters were obtained in four cruises. Equilibrium models are presented together with in situ data. The results strongly support the assumption that the solubilities of Cu, Zn, Cd, Fe, Co and Ni are controlled by bisulfide and/or polysulfide complexes. The species of Cu, Zn, Cd and Ni are shown to be Cu(S₄) ₂ ³⁻ and Cu(Sn₄S₅)³⁻, Zn(HS) ₂ ⁰ and ZnHS ₂ ⁻ , Cd(HS) ₂ ⁰ and Ni(HS) ₂ ⁰ , respectively. The solid species controlling Fe²⁺ and Co²⁺ are respectively the pyrohotites FeS and CoS. The data illustrates that thermodynamic equilibrium has been established in the H₂S-controlled seawater of Saanich Inlet, and that equilibrium has not been established in the H₂S−O₂-coexisted seawater of Saanich Inlet. The lack of equilibrium in the H₂S−O₂-coexisted seawater is a result of the flushing or mixing of oxygenated seawater with anoxic water. The new species of trace metals are still in the processes of reduction and precipitation. Contribution No. 1428 from Institute of Oceanology, Academia Sinica     

Soil organic carbon pools in particle-size fractions as affected by slope gradient and land use change in hilly regions, western Iran

This study was conducted to explore the effects of topography and land use changes on particulate organic carbon(POC),particulate total nitrogen(PTN),organic carbon(OC) and total nitrogen(TN) associated with different size primary particle fractions in hilly regions of western Iran.Three popular land uses in the selected site including natural forest(NF),disturbed forest(DF) and cultivated land(CL) and three slope gradients(0-10 %,S1,10-30 %,S2,and 30-50%,S3) were employed as the basis of soil sampling.A total of 99 soil samples were taken from the 0-10 cm surface layer in the whole studied hilly region studied.The results showed that the POC in the forest land use in all slope gradients was considerably more than the deforested and cultivated lands and the highest value was observed at NF-S1 treatment with 9.13%.The values of PTN were significantly higher in the forest land use and in the down slopes(0.5%) than in the deforested and cultivated counterparts and steep slopes(0.09%) except for the CL land use.The C:N ratios in POC fraction were around 17-18 in the forest land and around 23 in the cultivated land.In forest land,the silt-associated OC was highest among the primary particles.The enrichment factor of SOC,EC,was the highest for POC.For the primary particles,EC of both primary fractions of silt and clay showed following trend for selected land uses and slope gradients:CL> DF> NF and S3 > S2> S1.Slope gradient of landscape significantly affected the OC and TN contents associated with the silt and clay particles,whereas higher OC and TN contents were observed in lower positions and the lowest value was measured in the steep slopes.Overall,the results showed that native forest land improves soil organic carbon storage and can reduce the carbon emission and soil erosion especially in the mountainous regions with high rainfall in west of Iran.