Water losses from a reservoir built in karst: the example of the Boljunčica reservoir (Istria,Croatia)

The paper presents the case of the Boljunčica reservoir, which began operation in 1973. It is situated on the Istria peninsula (Croatia). This is a multipurpose reservoir which was built in order to protect the downstream area from flood, to store water for irrigation, and to control sediment transport. The reservoir is situated on the contact zone between water impermeable Eocene flysch and deep Eocene and Cretaceous limestone. The bottom of the reservoir is covered partly by both flysch and quaternary deposits. Water losses from the reservoir bottom are so large that the main service intended for the reservoir, the storage of water for irrigation, is impossible. After every intensive precipitation, which occurs often in this region, the reservoir fills very quickly. The problem is that its retention of water is very short, and lasts only a few days. The water volume of the reservoir at the spillway altitude of 93.00 m a. s. l. is about 6.5 × 10⁶ m³. Because of water losses from the reservoir bottom, the mean annual volume of water stored in it, during the period of 1977–2005 was only 0.5 × 10⁶ m³, which is less than 8% of the full reservoir volume. On the reservoir bottom, many new swallow holes opened through the sediment cover after each time it filled and emptied with water. Special attention is paid to the groundwater level analyses. Interdisciplinary analyses and investigations of hydrological and hydrogeological factors causing the formation of swallow holes and water losses from the Boljunčica reservoir are discussed. The example given in this paper explains one unsuccessful case of building a reservoir in Dinaric karst, caused mainly due to insufficient geological, hydrogeological and hydrological investigations. In order to prevent water losses from the Boljunčica reservoir, very complex and expensive work needs to be done, but its success regarding the reasonable reduction of water losses from the reservoir is in question.     

Geochemical characterization of a karst polje – an example from Sinjsko polje, Croatia

 The poljes of the Adriatic Coast are rather special features whose like is not found anywhere else in the world. The delineation of this unique landform feature by its geochemical characteristics has been attempted by using examples from Sinjsko polje, which represents a typical karst polje in the Adriatic Coast, or the area of the Dinaric Karst. Factor analysis was performed on 96 samples collected in a regular grid of 1×1 km which covered the entire area of the Sinjsko polje valley. Another factor analysis was performed in a regular grid of 5×5 km that comprised 41 samples in the karstic environment. In this manner two factor models were created and closely inspected for possible differences due to the peculiar properties arising from two geochemically different environments. Within the polje itself it was possible to evaluate three factors, while four factors were identified to be significant for the explanation of the geochemical structure of data assessed in the regular 5×5-km grid. This grid includes the area of Sinjsko polje and its wider neighborhood. The Ba/Sr index reveals striking differences in drainage patterns between the polje itself and the surrounding area. Received: 3 May 1996 · Accepted: 25 June 1997     

Contrasting tourmaline types from peraluminous granites: a case study from Moslava?ka Gora (Croatia)

Two texturally and chemically distinct types of tourmaline are found inside peraluminous granites of the Moslava?ka Gora, Croatia: nodular tourmaline in the two-mica granite and disseminated tourmaline in the cross-cutting leucogranite dykes. Both tourmaline types belong to alkali tourmaline group, nodular tourmaline being dravite to schorl and disseminated tourmaline corresponding to schorl. Comparison of characteristic parameters of nodular (Nt) and disseminated tourmaline (Dt) shows significant differences in #Fe (0.40?C0.65 for Nt vs. 0.74?C0.85 in Dt) along with variations in the calculated X-site vacancy (0.22?C0.37 pfu in Nt and 0.33?C0.44 in Dt) and ??/(??+Na) ratio (0.23?C0.40 in Nt and 0.34?C0.45 in Dt). Disseminated tourmaline from the MG leucogranites is regarded as an early crystallized magmatic phase, while the interstitial tourmaline from the cores of tourmaline nodules originated from more complex mineralogical and chemical interactions inside the two-mica granite melt. Major element gain (Mg) and loss (Fe, Ca, Na, K) for the ??idealized nodule?? (34 vol. % core + 66 vol. % halo) when compared to the host granite shows that the nodule??s volume is not a completely independent and closed system. Based on the observed characteristics, nodule??s halo can be considered as a ??transitional zone?? between the tourmaline-bearing core and the host granite, texturally and mineralogically related to the host two-mica granite, chemically being an integral part of the nodule??s volume at the same time.     

Karst rivers’ particularity: an example from Dinaric karst (Croatia/Bosnia and Herzegovina)

The very complex system of sinking, losing and underground transboundary Karst rivers, lakes and aquifers in the central part of the deep and bare Dinaric karst in Croatia and Bosnia and Herzegovina is analysed. The groundwater and surface water are hydraulically connected through numerous karst forms which facilitate the exchange of water between the surface and subsurface. A complex underground conduit system is an inherent characteristic karst system analysed. Groundwater and surface water exchange with both adjacent and distant aquifers through underground routes or inflows from surface streams and artificial reservoirs. Because of a complex surface and underground karst features, which strongly influenced its hydrological and hydrogeological regime, the main open stream flow, with a longitude of about 106 km, undergoes eight name changes. In this paper, it is noted as “the eight-name river”. In fact, it represents one river with losing, sinking and underground stream sections. Different surface and underground karst forms play crucial roles in the way the water flowing over the surface and on the underground sections of its catchment. The analysed area is full of varied and often spectacular surface landforms, including for example the Blue and Red Lakes and the Kravice Waterfall. The analyses made in the paper show the existence of a decreasing trend of mean annual discharges on the eight-name river, which can cause numerous problems in the regional water resource management of this transboundary river and catchment.     

Benkovac Stone (Eocene,Croatia): a deep-sea Plattenkalk?

In contrast to Solnhofen-type conservation Lagerstätten, the platy limestones of the Benkovac Stone of the Eocene of Croatia contains a variety of trace fossils. They belong to the Nereites ichnofacies, characterized by a suite of highly specialized ichnogenera, turbiditic preservation, and distinctive pre-event versus post-event communities. In siliciclastic rocks, this ichnofacies stands for turbiditic deep-sea sediments. Also unusual is the lack of body fossils. The only exceptions are occasional plant debris and Bencovacina concentrica. n. gen., n. sp., which is affiliated with xenophyophorian Foraminifera. These giant protozoans survive on present deep-sea bottoms, but they were also common on the shallow-marine biomats in Ediacaran times. These findings contradict the current shallow-marine interpretation, which is based on the regional geologic setting and sedimentary structures typical for tempestites. Thus, the Benkovac Stone would be an ideal place to test the reliability of ichnological versus sedimentological depth criteria in an entirely calcareous sequence.     

Geochemical background of potentially toxic trace elements in reclaimed soils of the abandoned pyrite–uranium mine (south-central Poland)

Spatial distribution patterns of As, Ba, Cd, Cr, Cu, Mn, Ni, Pb, U and Zn were determined in topsoil samples collected after 40 years of chemical remediation conducted in the inoperative “Staszic” pyrite–uranium mine in the Holy Cross Mountains, south-central Poland. Soil samples were taken from 58 sites using a systematic random sampling design. Selected samples were subjected to an X-ray diffractometry analysis on bulk soils and separated clay fractions. Hematite, goethite and gypsum are common mineral phases in soil samples. Technogenic soils developed on reclaimed mine spoils show uniform spatial element distribution patterns and additionally a distinct enrichment in As, Pb, Mn, U and Zn. Mineral and chemical composition of soils vs. rocks points to the lithogenic source of the determined elements. The results of chemical analysis have been used for evaluation of geochemical background of trace elements in the study area with the iterative 2σ-technique. This investigation shows that using mean crustal element concentrations (Clarke values) as proxies of threshold values in soils are not useful for determination of strongly positive geochemical anomalies. A modified enrichment factor, i.e. a local enrichment factor, is proposed for identification of sites where soils are contaminated.     

How does shear zone nucleate? An example from the Suretta nappe (Swiss Eastern Alps)

In order to address the question of the processes involved during shear zone nucleation, we present a petro-structural analysis of millimetre-scale shear zones within the Roffna rhyolite (Suretta nappe, Eastern central Alps). Field and microscopic evidences show that ductile deformation is localized along discrete fractures that represent the initial stage of shear zone nucleation. During incipient brittle deformation, a syn-kinematic metamorphic assemblage of white mica + biotite + epidote + quartz precipitated at ca. 8.5 ± 1 kbar and 480 ± 50 °C that represent the metamorphic peak conditions of the nappe stacking in the continental accretionary wedge during Tertiary Alpine subduction. The brittle to ductile transition is characterized by the formation of two types of small quartz grains. The Qtz-IIa type is produced by sub-grain rotation. The Qtz-IIb type has a distinct CPO such that the orientation of c-axis is perpendicular to the shear fracture and basal and rhombhoedric slip systems are activated. These Qtz-IIb grains can either be formed by recrystallization of Qtz-IIa or by precipitation from a fluid phase. The shear zone widening stage is characterized by a switch to diffusion creep and grain boundary sliding deformation mechanisms. During the progressive evolution from brittle nucleation to ductile widening of the shear zone, fluid–rock interactions play a critical role, through chemical mass-transfer, metasomatic reactions and switch in deformation mechanisms.     

The water on a small karst island: the island of Korčula (Croatia) as an example

The island of Korčula, which has an area of 271.47 km² is located along the north-eastern coast of the Adriatic Sea. Due to the Mediterranean climate, size and karst geology its water resources are very scarce. This paper describes the natural features of the island (air temperature, precipitation, geology, hydrogeology and groundwater) which are important for the water appearance and its distribution in time and space. The water supply of the island has been managed in the following ways: through a pipeline from the mainland, by drawing groundwater and by rain harvesting. Tourism causes high seasonal water needs which are barely met by the existing water supply system. Therefore, present water resource management on the island must be improved. The paper also presents mathematical programming scheme to get optimal costs and benefits of water exploitation on the island. Besides economic aspect, linear programming is applied to social and ecological objectives, as well. This study suggests that island’s water management should be primarily based on wisely using its proper water resources.     

Application of CSAMT in hydrogeology exploration in Shandong Province–An example from geothermal exploration in Changdao County(south four islands)

The geophysical exploration in Changdao County is conducted using controlled source audio-frequency magnetotelluric(CSAMT) method. The inversion results reveal obvious evidences of one existed fault and five new blind faults, including their location, size, occurrence and development degree. Another two low resistance anomaly zones are delineated. According to the results, a geothermal well drilling test is applied in the middle of South Changshan Island, discovering a large flow of salt hotspring with bromine and strontium. The outlet temperature is 36 ℃ and the yield of a single well is 1 830 m~3/d. This study on island hotspring exploration marks the first of its kind conducted in Shandong Province. It provides basic high-quality information for subsequent similar studies.     

Geochemical gradients in soil O-horizon samples from southern Norway: Natural or anthropogenic?

Forty soil O- and C-horizon samples were collected along a south-to-north transect extending inland for approximately 200 km from the southern tip of Norway. The elements As, Au, Bi, Cd, Cu, Ga, Ge, Hf, Hg, In, Mg, Mn, Mo, Na, Ni, Pb, Sb, Se, V, W, Zn and Zr all show a distinct decrease in concentration in soil O-horizons with increasing distance from the coast. The elements showing the strongest coastal enrichment, some by more than an order of magnitude compared to inland samples, are Au, Bi, As, Pb, Sb and Sn. Furthermore, the elements Cd (median O-/median C-horizon = 31), C, Sb, Ag, K, S, Ge (10), Hg, Pb, As, Bi, Sr (5), Se, Au, Ba, Na, Zn, P, Cu and Sn (2) are all strongly enriched in the O-horizon when compared to the underlying C-horizon. Lead isotope ratios, however, do not show any gradient with distance from the coast (declining Pb concentration). Along a 50 km topographically steep east–west transect in the centre of the survey area, far from the coast but crossing several vegetation zones, similar element enrichment patterns and concentration gradients can be observed in the O-horizon. Lead isotope ratios in the O-horizon correlate along both transects with pH and the C/N-ratio, both proxies for the quality of the organic material. Natural conditions in southern Norway, related to climate and vegetation, rather than long range atmospheric transport of air pollutants (LRT), cause the observed features.     

Tectonic control on third‐order sequences in a siliciclastic ramp‐style basin: An example from the Roper Superbasin (Mesoproterozoic), northern Australia

TThe Roper Group is a cyclic, predominantly marine, siliciclastic succession of Calymmian (Early Mesoproterozoic) age. It has a distribution of at least 145 000 km² and a maximum known thickness of ～5000 m. In the Roper River district the middle part of the Roper Group (～1300 m thick) is characterised by the cyclical alternation of mudstone and sandstone units, and can be divided into six third‐order depositional sequences. A typical sequence is broadly progradational in aspect, and comprises a lower, mudstone‐rich, storm‐dominated shelf succession (up to 330 m thick), and a sequence‐capping unit dominated by tidal‐platform cross‐bedded sandstone (up to 80 m thick); both are interpreted as highstand systems tracts. Transgressive strata are poorly represented but where present are characterised by paralic to fluvial redbed assemblages that include ooidal ironstone. Roper Group sequences lack a distinct condensed section and sequence boundaries are mostly conformable. Erosional contacts separate mud‐rich shelf facies from sequence‐capping sandstones. We infer that these erosion surfaces were generated by episodic flexural tectonism, which also generated the accommodation and sediment supply for Roper sequences.     

Microstructurally controlled trace element (Zr,U–Pb) concentrations in metamorphic rutile: An example from the amphibolites of the Bergen Arcs

As a common constituent of metamorphic assemblages, rutile provides constraints on the timing and conditions of rock transformation at high resolution. However, very little is known about the links between trace element mobility and rutile microstructures that result from synmetamorphic deformation. To address this issue, here we combine in situ LA-ICP-MS and sensitive high-resolution ion microprobe trace element data with electron back-scatter diffraction microstructural analyses to investigate the links between rutile lattice distortions and Zr and U–Pb systematics. Furthermore, we apply this integrated approach to constrain further the temperature and timing of amphibolite facies metamorphism and deformation in the Bergen Arcs of southwestern Norway. In outcrop, the formation of porphyroblastic rutile in dynamically hydrated leucocratic domains of otherwise rutile-poor statically hydrated amphibolite provides key contextual information on both the ambient conditions of hydration and deformation and the composition of the reactive fluid. Rutile in amphibolite recorded ambient metamorphic temperatures of ~590–730°C during static hydration of the granulitic precursor. By contrast, rutile from leucocratic domains in the directly adjacent shear zone indicates that deformation was accompanied by a localized increase in temperature. These higher temperatures are recorded in strain-free rutile (~600–860°C) and by Zr concentration measurements on low-angle boundaries and shear bands (620–820°C). In addition, we also observe slight depletions of Zr and U along rutile low-angle boundaries relative to strain-free areas in deformed grains from the shear zone. This indicates that crystal–plastic deformation facilitated the compositional re-equilibration of rutile upon cooling to slightly below the peak temperature of deformation. Cessation of deformation at mid-crustal conditions near ~600°C is recorded by late stage growth of small (<150 µm) rutile in the high-strain zones. U–Pb age data obtained from the strain-free and distorted rutile grains cluster in distinct populations of 437.4 ± 2.7 Ma and c. 405–410 Ma, respectively. These different ages are interpreted to reflect the difference in closure for thermally induced Pb diffusion between undeformed and deformed rutile during post-deformation exhumation and cooling. Thus, our results provide a reconstruction of the thermochronological history of the amphibolite facies rocks of the Lindås Nappe and highlight the importance of integration of microstructural data during application of thermometers and geochronometers.     

Rainfall in Central Sudan: An asset or a liability?

Sudan has been at the centre of the debate of drought and famine issues over the last 3 or 4 years. While the ideas of a simplistic casual link between these two phenomena has been partially slain, there still remains the desire in some circles to find a scapegoat for famine. Drought remains one of the readiest to hand. Rather than being seen as a basic characteristic of the rainfall resource which requires management, drought is seen as such an abnormality that it provides too convenient an excuse for the failure of agriculture, inadequacy of water supplies, exhaustion of soils and other environmental phenomena that have afflicted Sudan within the last 3–4 years (and longer). Such an attitude is in danger of converting rainfall in Sudan from an asset to a liability. This paper examines rainfall in Sudan as a resource and hence a potential asset. Drought is recognised as an inherent characteristic of that resource and its management discussed. It is suggested that the performance of indigenous traditional adaptive strategies has contrasted favourably with those of Governmental institutions. Reasons for this are given. Some broad options for future perspectives on the effective management of rainfall are outlined.     

Rječina River sediments (Croatia): from captured spring to polluted prodelta

Surface sediments (fraction <63 μm) from the source to the mouth of the Rječina, short (18.3 km) karst allogenic river in Croatia, which is an important source of drinking water, were studied to investigate their mineral (by XRD) and chemical (by ICP-MS) composition to check possible anthropogenic influence at the lower course due to paper industry and mills, and in the prodelta area from untreated municipal sewage and the large harbor of Rijeka town. In all analyzed sediment samples and in the sandstone source, rock quartz is a major mineral, while feldspar and mica group minerals are less abundant. Chlorite is a minor or trace mineral in all samples. Calcite and dolomite are abundant in the river prodelta, reflecting changes in bedrock lithology from flysch to carbonates. In river sediments, Fe is the most abundantly analyzed element, while Ca is the most abundant in prodelta sediments. Concentrations of Al, Mn, Ni, Cr, Co, La and Nd decrease downstream, while Mg, S, Na, B, Pb, Zn, As, Sn, U, Mo, Hg and Ag have relatively higher concentration in prodelta sediments. The results are compared with sediments of other rivers in the area: Raša, Rižana and Dragonja, as well as with those of the Rosandra Creek (Italy). Sediments in the Raša River showed similar behavior as those in the Rječina, as the highest concentration of metals was found in the restricted upper part of the estuary, characterized by rapid deposition of clay particles and terrestrial sedimentary organic matter. The comparison also showed that the most contaminated were the sediments from the Rižana, followed by those from the Rječina and Rosandra Creek, which had similar results. Among the studied elements, As was present in all sediment samples at concentrations >6 ppm that might have the lowest toxic effects. At the lower Rječina and in prodelta sediments, Pb was also present at slightly elevated concentrations (>31 ppm) that could cause such effects. Concentrations of Zn in the prodelta correspond to those occurring in moderately polluted sediments (90–200 ppm). In the prodelta sediments, Hg is slightly below toxicity threshold (1 ppm), while Ag is present at toxicity threshold (0.5 ppm) or close to it. Rječina River could act as a good illustrative example for behavior of toxic metals in allogenic karstic rivers, in which accumulation of anthropogenically introduced pollutants usually occurs in their estuaries, as a result of transport and deposition of fine particles.     

Weakening associated with the diaspore–corundum dehydration reaction in metabauxites: an example from Naxos (Greece)

Metabauxite lenses embedded in marble on Naxos consist of diasporites below the 420°C isograd, and dehydrate into corundum-rich rocks with increasing grades of metamorphism. While the diasporites are essentially undeformed, the corundum-rich rocks are strongly deformed, even though both diasporites and corundum-rich rocks are much stronger than the surrounding intensely deformed marbles. The observed structures can be explained as an effect of high fluid pressures during the prograde diaspore–corundum dehydration reaction, which causes dramatic temporary weakening of the metabauxites (to a strength comparable to that of the surrounding deforming marbles). Deformation of the metabauxite is thus largely restricted to the time span the phase transformation occurred, allowing the dehydrating bauxite mass to deform together with the surrounding marbles.     

Systematic changes in orientation of linear mylonitic fabrics: An example of strain partitioning during transpressional deformation in north Golpaygan,Sanandaj–Sirjan zone,Iran

Kilometer-scale, shallowly dipping, NW-striking top-to-the NE reverse and dextral strike-slip shear zones occur in metamorphic rocks of north Golpaygan. These metamorphic rocks are exposed at the NE margin of the central part of the Sanandaj–Sirjan zone in the hinterland of the Zagros orogen. NW-striking top-to-the NE normal shear zones were also found in a small part of the study area. Structural evidence of three deformation stages were found. Pre-mylonitization metamorphic mineral growth happened during D₁. The main mylonitization event was during the D₂ deformational event, following coaxial refolding, synchronous to retrograde metamorphism of amphibolite to greenschist facies in the Late Cretaceous–Paleocene, and before D₃ folding and related mylonitization. We documented the systematic changes in the orientations of D₂ linear fabrics especially stretching lineations and superimposition relations of structures. It is concluded that the dextral strike-slip and dip-slip shear zones were coeval kinematic domains of partitioned dextral transpression. The shallowly dipping reverse and strike-slip shear zones are compatible with partitioning in a very inclined transpressional model. Fabric relations reflect that the top-to-the NE normal shear zones were not produced during deformation partitioning of inclined dextral transpression. The Late Cretaceous–Paleocene strain partitioning was followed by later N–S shortening and NE-extension in the north Golpaygan area.     

Late Triassic aetosaur (Archosauria) from Krasiejów (SW Poland): new species or an example of individual variation?

An aetosaur discovery in Krasiejów (SW Poland), in Late Triassic deposits, was first described by Sulej in 2010 as a new species carrying the name Stagonolepis olenkae. However, new fossil material suggests that its taxonomical position is not as clear as was initially presumed. In the new material from the ‘Triassic’ site of Krasiejów, the typical features of Stagonolepis robertsoni, described by Walker in 1961 from the Elgin area of Scotland, were identified (i.e. frontal/prefrontal width ratio), as well as features of S. olenkae (i.e. angle between ventral edge of the maxilla and ventral edge of the antorbital fenestra). However, distinct features from both species, such as the shape of the canal at the dorsal surface of the frontal, are present. Some of the variation is similar to sexual dimorphism observed in recent amphibians and reptiles. These variations, as well as the fact that the postcranial skeleton was previously described as S. robertsoni by Lucas and co‐workers in 2007, suggest that the taxonomical affiliation of the Krasiejów aetosaur (and/or the number of aetosaur species) should be re‐considered. Copyright © 2015 John Wiley & Sons, Ltd.     

Middle-proterozoic anorthosite–rapakivi granite complexes: An example of within-plate magmatism in abnormally thick crust: Evidence from the East European Craton

Large, bimodal, and multistage anorthosite–rapakivi granite complexes (ARGCs) of Middle-Proterozoic age (1.8–1.5 Ga) are distinct magmatic assemblages in the western part of the present-day European Craton. ARGCs formation commenced after stabilization of the Svecofennian orogen and relics of its abnormally thick crust occur in many places. In the eastern part of the Kola-Karelian domain and the Volga-Urals domain, where crustal thickness is normal ∼40 km, ARGCs are practically absent. Geological data evidence that melting processes occurred both in the crust and in the mantle during formation of the complexes. Geochemical peculiarities of ARGC rocks include enrichment in alkalis (mainly in K), Ti, Zn, Pb, Zr, Be, Sn, In, Y, Nb, Rb, F, Cu, W, Mo, sometimes Li and U. The negative ?Nd values and relatively high Th and Zn concentrations that are most frequently observed in the rocks imply that parental magmas were considerably contaminated by crustal components.