Phlogopite-olivine rocks of the Taukha terrane in southeastern Sikhote Alin

The Paleocene ultraferrous Mn-rich phlogopite-olivine rocks of the Taukha terrane belong to the alkaline ultrabasic rocks of the potassic series. The olivine is represented by hortonolite, while the phlogopite is enriched in Cl. Other minerals are represented by Ti-magnetite, Mn-rich ilmenite, Zn-rich pleonaste, apatite, and zircon. There are also epigenetic serpentine, talc, carbonates, magnetite, breithauptite, nickeline, hedleyite, cobaltite, tsumoite, auricupride, cuproauride, and other minerals. The phlogopite-olivine rocks possibly represent a part of a magmatic complex previously unknown in Sikhote Alin, the rocks of which are associated with fluidolites of a large diatreme. There are grounds to suggest that they were formed by the injection of fluid-rich (mainly, H₂O, Cl, F, and S) deep magmas into the upper lithosphere. Based on these specific features, as well as the sharp K predominance over Na and the enrichment in some incompatible elements (Sn, Ta, Nb, and Zr), the phlogopite-olivine rocks are the most close to lamproites but differ in the high contents of Fe, Mn, Au, Pt, and Pd and in the olivine’s composition. The manifestation of such magmatism in the Taukha terrane records the transition from subduction to transform continental margin settings.     

Siliceous-clayey rocks of the Jurassic accretionary prism, Khekhtsir Range, Sikhote Alin: Stratigraphy and genesis

Lithologic-stratigraphic aspects of siliceous-clayey rocks forming the Khabarovsk terrane of the Jurassic accretionary prism were studied in western spurs of the Bol’shoi Khekhtsir Range on the left side of the Ussuri River (Ussuri-Khekhtsir section). Two defined types of the examined section differ in the composition, age, and origin of their constituting rocks. The northern segment of the section is composed of middle Bajocian red-brown siliceous-tuffaceous silty and olive-gray silty mudstones that accumulated in the hemipelagic domain under the influence of continental provenance. Its southern segment is represented by lower Bathonian olive-gray siliceous mudstones, mudstones barren of any admixtures, and yellowish brown tuffaceous mudstones deposited far away from the continent in waters with abundant radiolarians. It is shown that these rocks are elements of two tectono-stratigraphic complexes that reflect different stages in the accretionary prism formation.     

Structure,composition, and depositional environments of the lower cretaceous rocks of the Zhuravlevka terrane,Central Sikhote Alin

The structure, mineralogical-petrographic composition, and formation settings of the Berriasian-Albian terrigenous rocks of the Zhuravlevka terrane (Central Sikhote Alin) are considered. The rocks are interpreted as sediments accumulated in a virtually nonvolcanic basin along the transform plate boundary. Judging from the composition of terrigenous rocks, the main sources of clastic material were represented by the eroded granitic-metamorphic rocks of a mature continental crust, and, possibly, granitoid intrusions of ancient arc roots. Genetic features of the sediments suggest their accumulation on the shelf, underwater slope, foothill, and the adjacent basin plains of an oceanward-open marginal sea.     

Composition and provenances of mesozoic sandstones in Sikhote Alin

The composition of sandstones constituting different structural stages of the Jurassic accretionary wedge in the Samarka (upper and middle? structural levels in the Lyamfana Creek and Katen River basins, respectively) and Nadan’khada-Bikin (lower level in the Ulitka River basin) terranes of the Sikhote Alin region reflects changes in provenances and tectonic settings of the near-continental sedimentation basin in different periods of the wedge formation. In the terminal Middle Jurassic (Lyamfana Creek), the region was dominated by the subduction regime with sedimentary material transported from the eroded part of the continental-margin magmatic arc. During the Kimmeridgian-Tithonian (Katen River), erosion of granitoid batholiths of the arc exposed blocks of the crystalline basement along strike-slip faults. In the Tithonian-Berriasian period (Ulitka River), the role of these blocks increased, suggesting intensification of oblique subduction or development of transform faults during the accretion.     

Consedimentation tectonites in the Paleozoic of Sikhote Alin

Carboniferous and Permian terrigenous sediments in the basin of the Iman, Vaka and Ulakhe rivers show features known as tectonites — lens structures in conglomerate-type rocks, elongated pebbles and so on. These features and other considerations indicate that the central and eastern parts of the main Sikhote-Alin anticlinorium was experiencing contemporaneous differential movements. Competent beds of sandstones and flints form lenses, ovals and sometimes shapeless blocks embedded in incompetent siltstones and clay shales. Competent beds range greatly in thickness; fragments indicate most ranged from 1–5 cm with some beds 1–5 m. Most of the enclosing sequences are 100–300 m thick. Disposition of fragments indicates clearly the lines of the original beds. Direction of displacement is parallel to the plane of the layer. Elongation of fragments is in the direction of transport. Latest papers show a tendency to assign these tectonites a consedimentation origin; they are believed to be products of endogenous forces acting on consolidated sediments. The term hydrotectonite is used when morphologically similar products are formed under water through the joint action of forces both tectonic and otherwise. Two such structures are illustrated and their origin considered. Effects of dewatering are also discussed. Epochs favorable to hydrotectonites are rapid sinking a geosyncline when inclination of the floor increases and when earth tremors are common, in combination with rapid sedimentation. High tectonic activity in the Sikhote Alin syncline, based on hydrotectonites, may correlate with numerous magmatic effects in the adjacent Khanda central massif.—W.D. Lowry     

Ablation spherules in the Sikhote Alin meteorite and their genesis

Practically all of the examined spherules extracted in 1948?C1949 from soil at the crater field of the 1947 Sikhote Alin meteorite shower are ablation spherules produced during this meteorite fall. The spherules can classified into two textural types: (i) fine-grained, which consist of Ni-bearing magnetite (3?C6 wt % NiO) dendrites, sometimes with minor amounts of interstitial P- and Fe-rich material, and (ii) coarse-grained, which also consist of Ni-bearing magnetite dendrites or grains, sometimes with wuestite, an interstitial material, which resembles that in type (i) or has a silicate composition. The texture, mineralogy, and chemistry (presence of P and Si) of these spherules differ from those of iron cosmic spherules (type I) that occur in the background flux of micrometeorites. The spherules are thought to were produced by the ablation of meteoritic material at elevations of about 12 km (in the region where disintegration starts) and below, at maximum temperatures of 1600?C2180°C and oxygen fugacity of 10^?14 to 10^?1 atm. Conceivably, the ablated material was enriched in silicates compared to the fallen material.     

Geochemistry and metal potential of triassic carbonaceous silicites in Sikhote Alin

In the Triassic siliceous formation of Sikhote Alin, carbonaceous silicites occur in the late Olenekian-middle Anisian member (4–20 m) of alternating cherts and clayey cherts (“phtanite member”) near the section base. The silicites are represented by radiolarian and spicule-radiolarian cherts alternating with clayey cherts. They contain up to 8.5% C_org. In the majority of sections, the rocks underwent structural and mineral transformation at the mesocatagenetic stage. The slightly oxidized organic (primarily, marine sapropelic) matter contains quinones, methyl, methylene, and ether groups. The content of neutral bitumens in rocks shows a wide variation range. The carbon isotopic composition in phtanites and clayey phtanites (δ¹³C from ?27.3 to ?30.2‰) is identical to that in many Paleozoic-Mesozoic bitumens and oils. As compared with other Mesozoic sedimentary rocks of Sikhote Alin, the carbonaceous silicites are enriched in V, B, Mo, Ni, Cu, and Ag. Anomalously high concentrations of Ba are recorded in phtanite rock sections at the Gornaya and Khor rivers and in the vicinity of Khabarovsk. Modal value of the Au content in phtanites and clayey phtanites is three or four times higher than the clarke value in carbonaceous silicites and reaches anomalous values in some sections (e.g., Ogorodnaya River section). Carbonaceous silicites of this section are also enriched in Pt. Positive Au-C_org correlation is recorded in clayey phtanites of the Ogorodnaya River section containing more than 0.5% C_org. In organic fractions, Au and Ag are concentrated in alcohol and alcohol-benzene bitumens, asphalt acids, and asphaltenes. Migration of bitumens from high-carbonaceous clayey phtanites to the pore-fissure space of cherts and phtanites also fostered the concentration of these metals in some low-carbonaceous layers of the member.     

Clay Mineral Associations in Triassic–Lower Cretaceous Rocks of the Dal'negorsk Key Section, Southern Sikhote Alin

Investigation of the Triassic–Lower Cretaceous rocks of the Dal'negorsk key section (southern Sikhote Alin) revealed the following successive associations of authigenic clay minerals: (1) sericite–chlorite (Lower Triassic); (2) mica–chlorite (Anisian–Norian); (3) chlorite–mica (Rhaetian–Lower Jurassic); and (4) smectite–chlorite–mica (Upper Jurassic–Lower Cretaceous). These four associations reflect the primary composition of terrigenous admixture in the siliceous sediments and, hence, serve as important indicators of paleosedimentation conditions. The first association represents a product of the erosion of metamorphic rock complexes. The second one reflects the onset of volcanic activity within the sedimentation basin coinciding in time with a vigorous bloom of siliceous plankton (radiolarians) and short-term appearance of specific (anoxic) carbonaceous sediments in the sequence. The third association characterizes the epoch of minimal supply of the basin with volcanic and terrigenous clastic materials and the dominant accumulation of almost pure planktonogenic sediments. The fourth association marks the change of marginal-marine conditions for pelagic ones and is expressed in a significant input of pyroclastic and clastic materials and the formation of distal flysch deposits.     

Basalts of the Pantalassa ocean in the Samarka terrane, Central Sikhote Alin

Basalts developed on the right bank of the Matai River belong to the Samarka terrane (Central Sikhote Alin), which is a fragment of the Jurassic accretionary prism. They associate with Carboniferous-Permian reef limestones, Permian pelagic cherts, Jurassic hemipelagic cherty-clayey deposits, and terrigenous rocks of the near-continental sedimentation area. The petrogeochemical features of the basalts provide insight into the character of the volcanism in different settings of the ancient Pantalassa ocean. In terms of chemistry, the Carboniferous-Permian basalts are similar to the within-plate ocean-island basalts related to plume mantle sources. They were presumably formed in an oceanic area with numerous islands and seamounts. The Permian basalts associated with cherts are tholeiitic in composition and were formed from depleted mantle in a spreading center located in the pelagic area. The Jurassic basalts are of plume origin and, in terms of geochemistry, occupy an intermediate position between OIB and E-MORB. They were presumably formed in a convergent zone in a geodynamic setting of rapid oblique subduction.     

Mantle sources of the Cenozoic volcanic rocks of the Lake Kizi region in the eastern Sikhote Alin

The Middle Cenozoic lava sequence of the Lake Kizi region was studied. It characterizes the activity of sources in the Northern zone of the eastern Sikhote Alin: a Middle Eocene pulse of slab-related magmatism and prolonged injection of magmas from the sublithospheric convecting mantle in the Late Oligocene. Low contents of high field strength elements (Nb and Ta) with low Nb/Ta, Ce/Pb, and Nb/La and high K/Nb ratios and a low (⁸⁷Sr/⁸⁶Sr)₀ of 0.703399 were determined in a Middle Eocene dacite with an age of ∼43.5 Ma. Three phases of Late Oligocene volcanic eruptions were distinguished: (1) basaltic andesites (29–27 Ma), (2) basaltic trachyandesites and trachyandesites (27–24 Ma), and (3) andesites (∼23 Ma). The lavas of the first and third phases showed low Ce/Pb, Nb/La, and Ba/La and high K/Nb ratios, which are also characteristic of supraslab processes. The lavas of the second phase are shifted with respect to these ratios toward ocean island basalt compositions. The entire Late Oligocene volcanic sequence falls within a narrow range of the initial strontium isotope ratios, (⁸⁷Sr/⁸⁶Sr)₀, from 0.703661 to 0.703853. Such ratios are characteristic of volcanic and subvolcanic rocks with ages of ∼37, 31–23, and ∼16 Ma over the whole region of the Tatar Strait coast.     

Minerals in the Triassic carbonaceous silicites of Sikhote Alin

Over 60 minerals, including native elements, intermetallic compounds, haloids, sulfides, sulfates, arsenides, oxides and hydroxides, silicates, borosilicates, wolframates, phosphates and REE phosphates, were established in Triassic siliceous rocks of Sikhote Alin. Allothigenic and authigenic minerals in the carbonaceous silicites were formed over a long period through several stages. Judging from morphology, chemical composition, and structural position, K-feldspar (K-Fsp), illite, kaolinite, metahalloysite, monazite, xenotime, zircon, rutile, or its polymorphs are the disintegration products of sialic rocks of continental crust. Authigenic sulfides are dominated by diagenetic pyrite (fine-crystalline, microglobular, framboidal, as well as those developed after biogenic siliceous and carbonate fragments), which has been formed prior to precipitation of siliceous cement and lithification of siliceous rocks. Most of other sulfides (sphalerite, galena, chalcopyrite, pyrrhotite, argentite, pentlandite, antimonite, ulmanite, and bravoite), arsenides and sulfoarsenides (arsenopyrite, nickeline, skutterudite, cobaltite, glaucodot, and gersdorffite), wolframates (scheelite and wolframite), intermetallides (Cu₂Zn, Cu₃Zn₂, Cu₃Zn, Cu₄Zn, CuSn, Cu₄Sn, Cu₈Sn, Cu₄Zn₂Ni, Ni₂Cu₂Zn, Ni₄Cd), and native elements (Au, Pd, Ag, Cu, Fe, W, Ni, Se) were crystallized later (during catagenesis after the lithification and brecciation of siliceous beds) from metals involved in the easily mobile fractions of bitumens. Supergene mineral formation was mainly expressed in the sulfide oxidation and replacement of diagenetic pyrite by jarosite and iron hydroxides.     

Siliceous-volcanogenic complexes of western Sikhote Alin: Their stratigraphy and origin

New age and structural data are reported for the siliceous-volcanogenic complexes developed in the lower reaches of the Ussuri River. These complexes, which were previously treated as one stratigraphic unit, are subdivided into the Snarsky tectonostratigraphic complex (end of the Middle Jurassic-Middle Aptian) and the basaltic sequence (supposedly, Campanian-Maastrichtian). The Snarsky Complex is made up of basic volcanics, cherts, siliceous-clayey rocks, as well as subordinate limestones, sandstones, and conglomerates. Its distinctive features are the large amounts of genetically diverse basalts, the abundance of volcanomictic and pyroclastic material in siliceous-clayey rocks, the absence of fragmental rocks typical of the continental convergent zone, and the facies heterogeneity of the deposits. The complex is considered to be the southwestern continuation of the Kiselevka-Manoma terrane. Its origin is presumably related to the tectonic piling of genetically heterogeneous assemblages. The basaltic sequence includes basalts, basaltic andesites, their tuffs, and tuff conglomerates. The tuff conglomerates contain numerous fragments of granites and garnet-bearing felsic volcanics. The sequence was formed on the crystalline paleocontinental basement in the Late Cretaceous.     

Internal deformation of Sikhote Alin volcanic belt, far eastern Russia: Paleocene paleomagnetic results

We present paleomagnetic results of Paleocene welded tuffs of the 53–50 Ma Bogopol Group from the northern region (46°N, 137°E) of the Sikhote Alin volcanic belt. Characteristic paleomagnetic directions with high unblocking temperature components above 560 °C were isolated from all the sites. A tilt-corrected mean paleomagnetic direction from the northern region is D=345.8°, I=49.9°, α₉₅=14.6° (N=9). The reliability of the magnetization is ascertained through the presence of normal and reversed polarities. The mean paleomagnetic direction from the northern region of the Sikhote Alin volcanic belt reflects a counterclockwise rotation of 29° from the Paleocene mean paleomagnetic direction expected from its southern region. The counterclockwise rotation of 25° is suggested from the paleomagnetic data of the Kisin Group that underlies the Bogopol Group. These results establish that internal tectonic deformation occurred within the Sikhote Alin volcanic belt over the past 50 Ma. The northern region from 44.6° to 46.0°N in the Sikhote Alin volcanic belt was subjected to counterclockwise rotational motion through 29±17° with respect to the southern region. The tectonic rotation of the northern region is ascribable to relative motion between the Zhuravlevka terrane and the Olginsk–Taukhinsk terranes that compose the basements of the Sikhote Alin volcanic belt.