Homogeneity of the Geochemical Reference Material BRP-1 (Paraná Basin Basalt) and Assessment of Minimum Mass

Reference materials (RM) are required for quantitative analyses and their successful use is associated with the degree of homogeneity, and the traceability and confidence limits of the values established by characterisation. During the production of a RM, the chemical characterisation can only commence after it has been demonstrated that the material has the required level of homogeneity. Here we describe the preparation of BRP-1, a proposed geochemical reference material, and the results of the tests to evaluate its degree of homogeneity between and within bottles. BRP-1 is the first of two geochemical RM being produced by Brazilian institutions in collaboration with the United States Geological Survey (USGS) and the International Association of Geoanalysts (IAG). Two test portions of twenty bottles of BRP-1 were analysed by wavelength dispersive-XRF spectrometry and major, minor and eighteen trace elements were determined. The results show that for most of the investigated elements, the units of BRP-1 were homogeneous at conditions approximately three times more rigorous than those strived for by the test of "sufficient homogeneity". Furthermore, the within bottle homogeneity of BRP-1 was evaluated using small beam (1 mm²) synchrotron radiation XRF spectrometry and, for comparison, the USGS reference materials BCR-2 and GSP-2 were also evaluated. From our data, it has been possible to assign representative minimum masses for some major constituents (1 mg) and for some trace elements (1-13 mg), except Zr in GSP-2, for which test portions of 74 mg are recommended.     

Determination of the REE in Geological Reference Materials DTS-1 (Dunite) and PCC-1 (Peridotite) by Ultrasonic and Microconcentric Desolvating Nebulisation ICP-MS

Inductively coupled plasma-mass spectrometry is well suited for the precise, accurate and rapid determination of rare earth elements in most geological samples. However, determination of rare earth elements in certain mantle-derived materials, without applying preconcentration techniques, remains problematical due to low natural concentrations (generally < 1 ng g⁻¹). Consequently, USGS reference materials DTS-1 (a dunite) and PCC-1 (a partially serpentinized harzburgite) have only suggested rather than recommended values for the rare earth elements in reference material compilations. We compared results obtained using two ICP-MS instruments: a U-5000AT ultrasonic nebuliser coupled to a PQ2+ quadrupole ICP-MS and an ELEMENT sector field ICP-MS equipped with a MCN-6000 microconcentric desolvating nebuliser, with the suggested literature values for these two reference materials. Precision and accuracy of analytical methods employed by both instruments were demonstrated by excellent relative standard deviations (< 2%) and inter-laboratory agreement (< 5%) for numerous analyses of BHVO-1 and BIR-1, which are well established with rare earth elements contents at the μg g⁻¹ level. Repeat analyses of DTS-1 and PCC-1 at each laboratory indicate that each method is generally precise to better than 5% at sub-g g⁻¹ levels. Furthermore, values from both instruments generally agree to within 10%. Our DTS-1 and PCC-1 values agree reasonably well with selected data reported in the literature (except for Ce and Sm in DTS-1) but exhibit poorer agreement with reported compilation values. With the demonstrated level of precision and accuracy, we contend that these new values for DTS-1 and PCC-1, generated by two different instruments, are the best estimates of the true whole-rock composition of these samples reported to date.     

Coupled (H, M) substitutions in forsterite

Coupled substitutions involving hydrogen plus trivalent elements (Al, Eu, Fe, Ga, Gd, Lu, Mn, Nd, Pu, Sc, Y and Yb) in forsterite (Mg₂SiO₄) are studied using atomistic simulation methods. Incorporation of hydrogen is energetically favourable when included in the forsterite lattice as hydroxyl groups (OH⁻) at O3 sites while the trivalent cations replace either magnesium or silicon. Our calculations show a strong dependence on the ionic radius of the impurity species and some variation with pressure. There are also significant structural distortions around the impurity defects. At low pressure (0 GPa), the smaller trivalent cations, (e.g. Al, Fe, Mn and Ga) substitute into forsterite by replacing Si as: . The larger trivalent cations (e.g. Eu, Gd, Lu, Nd, Pu, Y and Yb) however, replace Mg at the M2 site coupled with an Mg1 vacancy as described by . At 12 GPa, the large cations are more stable at Mg1 relative to Mg2, but both are predicted to be less stable than configurations associated with Si vacancies. The trivalent ionic radius has a significant effect on the H incorporation mechanism, however, the high formation energy of Si vacancies suggests that the presence of H in forsterite could inhibit incorporation of these elements, particularly at high pressure.     

攀西裂谷内陆盆地自由热对流应力分析及盆地沉降

康滇地区裂谷作用已得到证实,但形成这种地堑地垒的格局有多种解释,以传统的地质力学分析为主。笔者借以热力学的自由热对流原理来加以论述：攀西巨厚的火山岩体在下覆异常地幔热作用下,发生自由热对流,引起热量散失,使地壳沉降与隆起不均衡,生成地堑地垒的格局。自由对流单元的侧向迁移,使盆地形成非对称性。     

The Preparation and Preliminary Characterisation of Three Synthetic Andesite Reference Glass Materials (ARM‐1, ARM‐2, ARM‐3) for In Situ Microanalysis

Three synthetic reference glasses were prepared by directly fusing and stirring 3.8 kg of high‐purity oxide powders to provide reference materials for microanalytical work. These glasses have andesitic major compositions and are doped with fifty‐four trace elements in nearly identical abundance (500, 50, 5 µg g^?1) using oxide powders or element solutions, and are named ARM‐1, 2 and 3, respectively. We further document that sector‐field (SF) ICP‐MS (Element 2 or Element XR) is capable of sweeping seventy‐seven isotopes (from ⁷Li to ²³⁸U, a total of sixty‐eight elements) in 1 s and, thus, is able to quantify up to sixty‐eight elements by laser sampling. Micro‐ and bulk analyses indicate that the glasses are homogeneous with respect to major and trace elements. This paper provides preliminary data for the ARM glasses using a variety of analytical techniques (EPMA, XRF, ICP‐OES, ICP‐MS, LA‐Q‐ICP‐MS and LA‐SF‐ICP‐MS) performed in ten laboratories. Discrepancies in the data of V, Cr, Ni and Tl exist, mainly caused by analytical limitations. Preliminary reference and information values for fifty‐six elements were calculated with uncertainties [2 relative standard error (RSE)] estimated in the range of 1–20%.     

Diamondiferous peridotite xenoliths from the Argyle (AK1) lamproite pipe,Western Australia

This paper describes a suite of peridotite xenoliths. some carrying diamonds at high grades, from the richly diamondiferous early Proterozoic (1180 Ma) Argyle (AK1) lamproite pipe, in northwestern Australia. The peridotites are mostly coarse garnet lherzolites but also include garnet harzburgite, chromite — garnet peridotite, a garnet wehrlite, and an altered spinel peridotite with extremely Cr-rich chromite. In all cases the garnet has been replaced by a kelyphite-like, symplectic intergrowth of Alrich pyroxenes, Al-spinel and secondary silicates. The peridotites have refractory compositions characterized by high Mg/(Mg+Fe) and depletion in lithophile elements (Al₂O₃ and CaO < 1%, Na₂O0.03%) and high field strength cations such as Ti, Zr, Y, and Yb. Olivines have high Mg/(Mg+Fe) (Mg ^91–93 ) and, like olivine inclusions in diamonds from the Argyle pipe, contain detectable amounts of Cr₂O₃ (0.03%–0.07%) but have very low CaO contents (typically 0.04%–0.05%). Enstatites (Mg ^92–94 ) have comparatively high Cr₂O₃ (0.2%–0.45%) and Na₂O (up to 0.18%) but very low Al₂O₃ contents (0.5%–0.7%). Diopsides (Mg ^92–94 , Ca/(Ca+Mg+Fe)=0.37–0.43) are Cr-rich (0.7%–1.9% Cr₂O₃) and have low Al₂O₃ (0.7%–2.2%) and Na₂O (0.5%–1.6%) contents. Many have high K₂O contents, typically 0.1%–0.4% but up to 1.3% K₂O in one xenolith. The chromite coexisting with former garnet is Mg-and Cr-rich [Mg/(Mg+Fe²⁺)=0.68–0.72, Cr/(Cr+Al)=0.72–0.79] whereas chromite in the spinel peridotite is even more Cr-rich (65% Cr₂O₃, Cr/(Cr+Al)=0.85, resembling inclusions in diamond. One highly serpentinized former garnet peridotite contains a Cr-rich (up to 13% Cr₂O₃) titanate resembling armalcolite but containing significant K₂O (1%–2.5%), CaO (0.6%–2.2%), ZrO₂ (0.1%–0.8%), SrO (0.1%–0.3%), and BaO (up to 0.58%): this appears to have formed as an overprint of the primary mineralogy. Temperatures and pressures estimated from coexisting pyroxenes and reconstructed garnet compositions indicate that the garnet lherzolites equilibrated at 1140°–1290° C and 5.0–5.9 GPa (160–190 km depth), within the stability field of diamond. Oxygen fugacties within the diamond forming environment are estimated from spinel-bearing assemblages to be reducing, with f _O2 between MW and IW. The presence of significant K in the diopsides from the peridotite xenoliths and in diopsides from heavy mineral concentrate from the Argyle pipe implies metasomatic enrichment of the subcontinental lithosphere within the diamond stability field. The P-T conditions estimated for the Argyle peridotites demonstrate that diamondiferous lamproite magmas incorporate mantle xenoliths from similar depths to kimberlites in cratonic settings, and imply that Proterozoic cratonized orogenic belts can have lithospheric roots of comparable thickness to beneath Archaean cratons. These roots lie at the base of the lithosphere within the stability field of diamond. The xenoliths, the calcic nature of chrome pyropes from heavy mineral concentrate, and the diamond inclusion assemblage indicate that the lighosphere beneath the Western Australian lamproites is mostly depleted lherozolite rather than the harzburgite commonly found beneath Archaean cratons. Nevertheless, the dominance of eclogitic paragenesis inclusions in Argyle diamonds indicates a significant proportion of diamondiferous eclogite is also present. The form, mineral inclusion assemblage, and the C-isotopic composition of diamonds in the peridotite xenoliths suggest that disaggregated diamondiferous peridotites are the source of the planar octahedral diamonds which constitute a minor component of the Argyle production. These diamonds are believed to have formed from mantle carbon in reduced, refractory peridotite (Iherzolite-harzburgite) in contrast to the predominant strongly ¹³C-depleted eclogitic suite diamonds which contain a recycled crustal carbon component. The source region of the lamproites has undergone long-term (2 Ga) enrichment in incompatible elements.     

石家庄市大气PM1、PM2.5和PM10中重金属元素分布特征及来源的对比研究

为了解元素(尤其是重金属元素)在不同粒径大气颗粒物中的分布规律、污染特征及来源,于2016年在石家庄市采集PM1、PM2.5和PM10样品。利用等离子体质谱仪(ICP-MS)测定了Al、Ti、V、Cr、Mn、Fe、Cu、Zn、As、Sb、Hg、Pb和Cd共13种元素的质量浓度,采用富集因子(EF)法分析各种元素在PM1、PM2.5和PM10中的分布特征,并通过主成分分析法讨论了这些元素的主要来源。富集因子分析显示出Al、Fe、Ti、Mn受人为因素影响较少(EF<10),其他元素则出现显著至极强的人为影响,尤其是Cd元素(EF>103),并发现颗粒物粒径较小时,富集因子较大,即人为因素影响更重。主成分分析表明：PM1中元素有工业冶炼及燃煤活动、机动车燃油排放、生活燃煤3个来源,PM2.5中元素有地壳源、电厂及居民生活燃煤、金属冶炼等工业活动、机动车尾气4个来源,PM10中元素有化石燃料燃烧和地壳源、与机动车相关的道路扬尘及工业尘、垃圾焚烧及机动车排放与磨损、燃煤活动4个来源。     

CHARACTERIZATION OF MAJOR,MINOR AND TRACE ELEMENTS IN SIX CCRMP (TDB-1, WGB-1, UMT-1, WPR-1, WMG-1 AND WMS-1) AND ONE IWG (ZW-C) GEOCHEMICAL CANDIDATE REFERENCE MATERIALS*

Elemental compostions of six CCRMP (TDB-1, WGB-1, UMT-1, WPR-1, WMG-1 and WMS-1) and one IWG (ZW-C) geochemical candidate reference materials were determined by XRF, ICP-AES, ICP-MS, GFAAS and other modern instrumental techniques. Inter-method results compared favourably in the case of elements for which multiple data were available.     

The Distribution of Redox Sensitive Elements (U, As, Sb, V and Mo) along a River-Wetland-Lake System (Balaton Region, Hungary)

The distribution of redox sensitive elements (U, As,Sb, Mo and V) has been investigated in Lake Balatonand two man-made reservoirs (Lake Kis-Balaton-1 andKis-Balaton-2) built along the River Zala, the mainriver discharging into it. These elements underwentremoval in Lake Kis Balaton-2 (KB-2) during anoxicconditions (May and September).Similarities were found between the distributions ofdissolved As and Sb. Both elements had elevateddissolved concentrations in Lake Kis-Balaton-1 (KB-1)and in Lake Balaton in September. This increasedmobility could be due to a change of speciation (viareduction and the formation of methylated species).Such changes in speciation are well documented in theliterature and are generally enhanced during periodsof warmth and high primary productivity.Dissolved V and Mo distributions also showedsimilarities with higher concentrations in LakeBalaton than in other parts of the system.Although removal is not clearly detected from thedissolved concentrations, U, As, Sb and Mo aresignificantly enriched in the organic-rich sedimentsof Lake KB-1, while V is mainly associated with thealumino-silicate fraction. In Lake KB-1, theconcentrations of all elements in SPM (suspendedparticulate matter) are lower than in the depositedsediments (except for As) suggesting that enrichmentprocesses are occuring in the deposited sediments.Additionnally the cycling of As and Mo can be alsopartly controlled by uptake and scavenging processesin the water column, as suggested by the elevated Asand Mo concentrations observed in SPM seasonnally forAs in Lake KB-1 and at Z.mouth-1 station and for Mo atZ.mouth-1 station and Lake Balaton.     

Trace element evolution in the Phlegrean Fields (Central Italy): fractional crystallization and selective enrichment

Trace element analysis of Phlegrean Fields volcanic products shows that they belong to a homogeneous series whose evolution is due mainly to fractional crystallization. However quantitative modelling of crystal fractionation using measured mineral/groundmass and computed bulk distribution coefficients singles out K, Sb, Cl and F as elements which are selectively enriched in the differentiation process with respect to proven hygromagmaphile (HYG) elements. This anomalous enrichment involving elements that are easily transported in a magmatic fluid phase is thought to be due to percolation of such a fluid through a stored magma body. This enrichment is strongest in products resulting from protracted differentiation (trachybasalts-latites). Isotopic data from the literature are reinterpreted in terms of this model and show good agreement. Trace elements concentrations in clinopyroxenes provide evidence that complex differentiation paths were followed to produce latitic magmas. Their origin by mixing of magmas from different parentages is not indicated by the data. However, mixing of batches of the same parentage but of different degree of evolution seems likely. Because HYG elements ratios are not modified in the evolution of the magmas, they record these ratios in the partial melting zone. For example, the Th/Ta ratio in the source areas of the magmas has apparently been quite heterogeneous.     

A predictive model (ETLM) for As(III) adsorption and surface speciation on oxides consistent with spectroscopic data

Arsenic(III) adsorption reactions are thought to play a critical role in the mobility of arsenic in the environment. It is the nature of the As(III) surface species that must be known on a wide variety of minerals and over a range of pH, ionic strength and surface coverage in order to be able to predict adsorption behavior. EXAFS and XANES spectroscopic studies have identified bidentate, binuclear inner-sphere surface species and/or an outer-sphere species, but only a few oxides have been examined. These results need to be integrated with a predictive surface complexation model in order to ascertain the environmental conditions under which the different surface species may be important on a wide range of solids. In the present study, the surface species information from XAFS and XANES studies has been built into a recent extension of the triple-layer model (ETLM) for the formation of inner-sphere complexes of anions that takes into account the electrostatics of water dipole desorption during ligand exchange reactions. The ETLM has been applied to regress surface titration, proton coadsorption, and As(III) adsorption data over extensive ranges of pH, ionic strength, electrolyte type and surface coverage for magnetite, goethite, gibbsite, amorphous hydrous alumina, hydrous ferric oxide (HFO), ferrihydrite, and amorphous iron oxide. Two principal reactions forming inner- and outer-sphere As(III) surface species,

     

国外遥感卫星发展简介（1）

从美国发射其第一颗遥感卫星一陆地卫星－1算起的30余年里，世界范围内商业遥感卫星技术已经有了巨大的进步，越来越多的国家和国际团体拥有自己的遥感卫星。除了更多各类的遥感器得以使用外，卫星的图像分辨率和覆盖能力也有了很大的改进。未来的发展更加令人振奋。国外遥感卫星（包括已经发射和计划要发射的卫星）简介是根据从国内外出版物中获得的信息整编而成，旨在给遥感应用提供一个现在和未来图像信息源的总的概念。     

Platinum-Group Element Geochemical Certified Reference Materials (GPt1-7)

Unlike the situation for other elements, few reference materials certified for the platinum-group elements are currently available. Therefore, the GPt1-7 series of PGE geochemical CRMs, prepared by the IGGE, represent an important addition and comprise a range of matrix types, including a soil, stream sediment, Mg-rich ultramafic rock, Fe-rich ultramafic rock, platinoid ore depleted in Cu, Ni and Fe, and a chromitite. The concentration of PGE in these samples ranges over 4-5 orders of magnitude and the samples were shown to have good homogeneity as assessed by a variance test. Analytical methods based on different principles were used in sample certification, including several fire assay and wet chemical procedures used for decomposition and preconcentration. Certified values for the elements Pt, Pd, Os, Ru, Ir, Rh and Au were determined by AAS, catalytic colourimetry (COL), catalytic polarography (POL), atomic emission spectrometry (AES), ICP-MS and NAA. Recently, the GPt1-7 samples were approved as national primary CRMs by the State Bureau of Technical Supervision of China.     

Net earthquake hazard and elements at risk (NEaR) map creation for city of Istanbul via spatial multi-criteria decision analysis

The creation of earthquake hazard maps requires various datasets with selected attenuation relations. Based on the selected attenuation relation, the calculation time varies from half an hour to a couple of days. The length of time needed to create an earthquake hazard map also depends on the resolution of the resulting map. The time gets longer as the resolution of the resulting earthquake hazard map gets higher. The basic form of an attenuation relation requires complex calculation algorithms including geospatial information related to the region of interest. Nowadays, next-generation attenuation (NGA) models are introduced to generate more realistic earthquake hazard maps. However, the more complex the attenuation relation is, the longer time will be required to create a hazard map. This paper offers a new method to create high-resolution earthquake hazard maps, faster than using traditional attenuation relation methods, by using an analytic hierarchy process of spatial multi-criteria decision analysis and geographic information systems. This method has been generated and tested for the city of Istanbul. The resulting maps are compared with the earthquake hazard maps created for the city of Istanbul by using the NGA model of Boore and Atkinson (in Boore–Atkinson NGA ground motion relations for the geometric mean horizontal component of peak and spectral ground motion parameters (trans: Engineering Co, University of California B). Pacific Earthquake Engineering Research Center 2007). A second output of this paper is a map of the elements at risk (EaR) for the population and buildings of Istanbul, and the introduction of a new approach of net elements at risk (NEaR).     

Fitting matrix-valued variogram models by simultaneous diagonalization (Part I: Theory)

Suppose that ¯(x₁),...,¯Z(x_n). are observations of vector-valued random function ¯(x). In the isotropic situation, the sample variogram γ^*(h) for a given lag h is $$\bar \gamma ^ * (h) = \frac{1}{{2N(h)}}\mathop \sum \limits_{s(h)} (\overline Z (x_1 ) - \overline Z (x_1 )) \overline {(Z} (x_1 ) - \overline Z (x_1 ))^T $$ where s(h) is a set of paired points with distance h and N(h) is the number of pairs in s(h).. For a selection of lags h₁, h₂, .... h_k such that N (h₁) > O. we obtain a ktuple of (semi) positive definite matrices $\bar \gamma ^ * (h_{ 1} ),. . . ., \bar \gamma ^ * (h_{ k} )$ . We want to determine an orthonormal matrix B which simultaneously diagonalizes the $\bar \gamma ^ * (h_{ 1} ),. . . ., \bar \gamma ^ * (h_{ k} )$ or nearly diagonalizes them in the sense that the sum of squares of offdiagonal elements is small compared to the sum of squares of diagonal elements. If such a B exists, we linearly transform $\overline Z (x)$ by $\overline Y (x) = B\overline Z (x)$ . Then, the resulting vector function $\overline Y (x)$ has less spatial correlation among its components than $\overline Z (x)$ does. The components of $\overline Y (x)$ with little contribution to the variogram structure may be dropped, and small crossvariograms fitted by straightlines. Variogram models obtained by this scheme preserve the negative definiteness property of variograms (in the matrix-valued function sense). A simplified analysis and computation in cokriging can be carried out. The principles of this scheme arc presented in this paper.     

1:100万中华人民共和国数字地质图空间数据库

中华人民共和国1∶100万数字地质图数据库是根据统一标准和要求编制的专题数字地质图,以中华人民共和国1∶50万数字地质图数据库为数据源,在综合研究的基础上,充分吸收近年来地质调查1∶25万、1∶20万、1∶5万等区调工作新成果、新资料,应用地质编图新技术、新理论和新方法编制而成。以年代地层单位为主、辅以岩石地层的表示方法,侵入岩按“岩性加年代”表示方法,进一步提高了基础地质的研究程度。地质图数据库内容丰富,信息量大,数据量约为1.2 GB,标示了岩石地层单位5347个图例,侵入体“岩性加时代”单位1780个图例,跨省区重要断裂93条,各省（市、自治区）内重要断层558条,同位素年龄数据1545个（组）,有代表性的钻孔382个。所有地质体的面元及线元、同位素年龄和钻孔都建立了相应的属性,相邻图幅之间进行了接图处理,编写了编图说明书和元数据。数据库采用统一的线型库、符号库、色标库等,成图过程全部采用MapGIS6.5平台计算机辅助成图,成图精度高,质量好,符合设计要求,全国64幅图采用分4个片区的工作方法,最后统一编制而成。该数字地质图是目前中国资料最全、内容最新的1∶100万地质图,是中国第一份应用GIS技术的1∶100万数字地质图的最新成果,充分反映了中国地质构造特点和当前地质研究的新水平。