Physico-chemical parameters of Neoproterozoic and Early Cambrian plume magmatism in the Paleo-Asian ocean (data on melt inclusions)

The paper presents new data on physico-chemical parameters of the Neoproterozoic–Early Cambrian plume magmatism in the Paleo-Asian Ocean. The data on clinopyroxenes show the plume-related plateaubasalt magmatic systems of the Katun’ paleoseamounts, which interacted with mid-ocean ridge (MOR) magmas. The Kurai paleoseamount consists mainly of plateaubasalt systems, and the Agardag ophiolites represent products of OIB–type “hot-spot” within-plate magmatism. Our study of inclusions showed that the melts of the Katun’ and Kurai paleoseamounts crystallized at lower temperatures (1130–1190 °C) compared to the Agardag ophiolites (1210–1255 °C). The petrochemical analysis of the melt inclusions showed that the Katun’ and Kurai magmatic systems are different from the Mg- and Ti-richer melts of the Agardag ophiolites: the former are similar to the magmas of the Nauru Basin and Ontong Java Plateau (western Pacific), whereas the latter possess geochemical affinities to OIB-type magmatism. The rare-element compositions of the melts of the Katun’ and Kurai paleoseamounts correspond to those of the Ontong Java Plateau and Nauru Basin lavas. The numerically simulated parameters of the Katun’ paleoseamount primary magmas agree with the data on the magmatic systems of the Siberian Platform and Ontong Java Plateau. For the Kurai paleoseamount, the simulated results suggest interaction of deep-seated OIB-type magmatic systems with MOR ones. The Agardag ophiolites were formed in relation to mantle plume activity at the initial stages of paleo-oceanic complexes formation.     

Geology of the Gorny Altai subduction–accretion complex, southern Siberia: Tectonic evolution of an Ediacaran–Cambrian intra-oceanic arc-trench system

The Gorny Altai region in southern Siberia is one of the key areas in reconstructing the tectonic evolution of the western segment of the Central Asian Orogenic Belt (CAOB). This region features various orogenic elements of Late Neoproterozoic–Early Paleozoic age, such as an accretionary complex (AC), high-P/T metamorphic (HP) rocks, and ophiolite (OP), all formed by ancient subduction–accretion processes. This study investigated the detailed geology of the Upper Neoproterozoic to Lower Paleozoic rocks in a traverse between Gorno-Altaisk city and Lake Teletskoy in the northern part of the region, and in the Kurai to Chagan-Uzun area in the southern part. The tectonic units of the studied areas consist of (1) the Ediacaran (=Vendian)–Early Cambrian AC, (2) ca. 630 Ma HP complex, (3) the Ediacaran–Early Cambrian OP complex, (4) the Cryogenian–Cambrian island arc complex, and (5) the Middle Paleozoic fore-arc sedimentary rocks. The AC consists mostly of paleo-atoll limestone and underlying oceanic island basalt with minor amount of chert and serpentinite. The basaltic lavas show petrochemistry similar to modern oceanic plateau basalt. The 630 Ma HP complex records a maximum peak metamorphism at 660 °C and 2.0 GPa that corresponds to 60 km-deep burial in a subduction zone, and exhumation at ca. 570 Ma. The Cryogenian island arc complex includes boninitic rocks that suggest an incipient stage of arc development. The Upper Neoproterozoic–Lower Paleozoic complexes in the Gorno-Altaisk city to Lake Teletskoy and the Kurai to Chagan-Uzun areas are totally involved in a subhorizontal piled-nappe structure, and overprinted by Late Paleozoic strike-slip faulting. The HP complex occurs as a nappe tectonically sandwiched between the non- to weakly metamorphosed AC and the OP complex. These lithologic assemblages and geologic structure newly documented in the Gorny Altai region are essentially similar to those of the circum-Pacific (Miyashiro-type) orogenic belts, such as the Japan Islands in East Asia and the Cordillera in western North America. The Cryogenian boninite-bearing arc volcanism indicates that the initial stage of arc development occurred in a transient setting from a transform zone to an incipient subduction zone. The less abundant of terrigenous clastics from mature continental crust and thick deep-sea chert in the Ediacaran–Early Cambrian AC may suggest that the southern Gorny Altai region evolved in an intra-oceanic arc-trench setting like the modern Mariana arc, rather than along the continental arc of a major continental margin. Based on geological, petrochemical, and geochronological data, we synthesize the Late Neoproterozoic to Early Paleozoic tectonic history of the Gorny Altai region in the western CAOB.     

Pacific superplume-related oceanic basalts hosted by accretionary complexes of Central Asia,Russian Far East and Japan

Plume-related oceanic magmatism form oceanic islands, seamounts and plateaus (hereafter “seamounts” or “paleoseamounts”), which are important features in geological history. The accretion of oceanic seamounts to active continental margins significantly contributed to the formation of the continental crust. This paper reviews occurrences of Late Neoproterozoic–Mesozoic seamounts of the Paleo-Asian and Paleo-Pacific oceans, which are hosted by accretionary complexes (ACs) of Russian Altai, East Kazakhstan, Mongolia, Russian Far East and Japan. The paleoseamounts commonly consist of Ti–LREE–Nb-enriched plume-related basalts (OIB-type or intraplate basalts) capped with massive limestone and associated with other units of oceanic plate stratigraphy (OPS): oceanic floor basalts (MORB), pelagic chert, epiclastic slope facies, etc. The paper presents available geochemical data on the plume-related basalts including the first geochemical data on the Middle Paleozoic OIB-type basalts of the Paleo-Asian Ocean hosted by the Ulaanbaatar AC of Mongolia. An emphasis is made for the structural setting of OPS units, specific geochemical features of intraplate basalts, problems of their identification, and distinguishing from magmatic units of a different origin such as MORB, island-arc and back-arc basalts. Finally, we propose a continuous, though periodical, evolution of the Pacific superplume-related magmatism, which can be more reliably proved by studying Middle Paleozoic OPS units hosted by ACs of Mongolia and Tien Shan, and discuss prospects of future studies.     

Geochemistry of metamorphic rocks of the Kurai block (Gorny Altai)

We consider the primary nature and sources of the protoliths of metamorphic rocks of the Kurai block located in the large Teletskoe-Kurai system of deep faults separating the Gorny Altai and West Sayan structures. It has been established that the protoliths of the Kurai block metapelites were deposits of transitional crust: They lack typical rocks of mature continental crust (arkoses, litharenites) and have reduced (relative to the upper continental crust) contents of lithophile elements and elevated contents of transition elements. The average Nd model age of the protoliths of the metapelites of the Kurai complex corresponds to the Middle Riphean (1.4-1.6 Ga). The metabasites of the Kurai complex are similar in petrologic composition to metamorphic products of oceanic basalts. It is shown that the formation of metamorphic associations of the Kurai block was caused by tectonometamorphic transformations of a compositionally heterogeneous rock unit (basalts, aluminous and volcanomict sediments), which were, most likely, a fragment of Middle Cambrian-Early Ordovician turbidite basin with an oceanic basement.     

Fragments of oceanic islands in accretion–collision areas of Gorny Altai and Salair, southern Siberia, Russia: early stages of continental crustal growth of the Siberian continent in Vendian–Early Cambrian time

The Altai-Salair area in southern Siberia is a Caledonian folded area containing fragments of Vendian–Early Cambrian island arcs. In the Vendian–Early Cambrian, an extended system of island arcs existed near the Paleo-Asian Ocean/Siberian continent boundary and was located in an open ocean realm. In the present-day structural pattern of southern Siberia, the fragments of Vendian–Early Cambrian ophiolites, island arcs and paleo-oceanic islands occur in the accretion–collision zones. We recognized that the accretion–collision zones were mainly composed of the rock units, which were formed within an island-arc system or were incorporated in it during the subduction of the Paleo-Asian Ocean under the island arc or the Siberian continent. This system consists of accretionary wedge, fore-arc basin, primitive island arc and normal island arc. The accretionary wedges contain the oceanic island fragments which consist of OIB basalts and siliceous—carbonate cover including top and slope facies sediments. Oceanic islands submerged into the subduction zone and, later were incorporated into an accretionary wedge. Collision of oceanic islands and island arcs in subduction zones resulted in reverse currents in the accretionary wedge and exhumation of high-pressure rocks. Our studies of the Gorny Altai and Salair accretionary wedges showed that the remnants of oceanic crust are mainly oceanic islands and ophiolites. Therefore, it is important to recognize paleo-islands in folded areas. The study of paleo- islands is important for understanding the evolution of accretionary wedges and exhumation of subducted high-pressure rocks.     

Neoproterozoic to Early Ordovician Evolution of the Paleo-Asian Ocean: Implications to the Break-up of Rodinia

The paper reviews and integrates the recent geological and geochronological data, which allow us to recognize three stages of the evolution of the Paleo-Asian Ocean.The opening of the Paleo-Asian Ocean at 970-850 Ma is dated by the Nersin Complex in the Aldan shield, plagiogranites of the Sunuekit massif, enderbites of the Sludinsk Lake area, and passive margin sediments of the Patoma or Baikal series. The initial subduction (850-700 Ma) is marked by volcanic rocks, trondjemite and gabbro of the Sarkhoy island arc series. Collisions of microcontinents with Siberia at 660 to 620 Ma are evidenced by the exhumation of Muya eclogites (650 Ma), formation of migmatites and amphibolites of the Njurundukan belt (635 and 590 Ma), metamorphic units of the Near-Yenisei belt (640-600 Ma), and orogenic molasse (640-620 Ma). The Paleo-Asian Ocean maximally opened at 620-550 Ma, because at that time a long island arc composed of boninite volcanic rocks was formed. Primitive island arcs of that age have been reconstructed in Kazakhstan, Gorny Altai, West and East Sayan, and North Mongolia. HP and UHP rocks formed in two stages at 550-520 and 520-490 Ma. At 550-490 Ma oceanic islands and Gondwana-derived microcontinents (Kokchetav, Tuva-Mongolian, Central Mongolian and others) collided with the Cambrian-early Ordovician island arc of the Siberian continent. As a result, the island-arc system was extensively modified. Collision occurred twice at 550-520 and 520-490 Ma during which many HP and UHP rocks formed. At that time, the new oceans - the Junggar, Kazakhstan and Uralian - with an Ordovician island arc were formed.     

http://www.sciencedirect.com/science/article/pii/S1674987113001606

The paper reviews previous and recently obtained geological, stratigraphic and geochronological data on the Russian-Kazakh Altai orogen, which is located in the western Central Asian Orogenic Belt （CAOB）, between the Kazakhstan and Siberian continental blocks. The Russian-Kazakh Altai is a typical Pacific-type orogen, which represents a collage of oceanic, accretionary, fore-arc, island-arc and continental margin terranes of different ages separated by strike-slip faults and thrusts. Evidence for this comes from key indicative rock associations, such as boninite- and turbidite （graywacke）-bearing volcanogenic-sedimentary units, accreted pelagic chert, oceanic islands and plateaus, MORB-OIB-protolith blueschists. The three major tectonic domains of the Russian-Kazakh Altai are： （1） Altai-Mongolian terrane （AMT）; （2） subduction-accretionary （Rudny Altai, Gorny Altai） and collisional （Kalba-Narym） terranes; （3） Kurai, Charysh-Terekta, North-East, Irtysh and Char suture-shear zones （SSZ）. The evolution of this orogen proceeded in five major stages： （i） late Neoproterozoic-early Paleozoic subduction-accretion in the Paleo-Asian Ocean; （ii） Ordovician-Silurian passive margin; （iii） Devonian-Carboniferous active margin and collision of AMT with the Siberian conti- nent; （iv） late Paleozoic closure of the PAO and coeval collisional magmatism; （v） Mesozoic post-collisional deformation and anarogenic magmatism, which created the modern structural collage of the Russian- Kazakh Altai orogen. The major still unsolved problem of Altai geology is origin of the Altai-Mongolian terrane （continental versus active margin）, age of Altai basement, proportion of juvenile and recycled crust and origin of the middle Paleozoic units of the Gorny Altai and Rudny Altai terranes.     

Pacific superplume-related oceanic basalts hosted by accretionary complexes of Central Asia, Russian Far East and Japan

Plume-related oceanic magmatism form oceanic islands, seamounts and plateaus (hereafter “seamounts” or “paleoseamounts”), which are important features in geological history. The accretion of oceanic seamounts to active continental margins significantly contributed to the formation of the continental crust. This paper reviews occurrences of Late Neoproterozoic–Mesozoic seamounts of the Paleo-Asian and Paleo-Pacific oceans, which are hosted by accretionary complexes (ACs) of Russian Altai, East Kazakhstan, Mongolia, Russian Far East and Japan. The paleoseamounts commonly consist of Ti–LREE–Nb-enriched plume-related basalts (OIB-type or intraplate basalts) capped with massive limestone and associated with other units of oceanic plate stratigraphy (OPS): oceanic floor basalts (MORB), pelagic chert, epiclastic slope facies, etc. The paper presents available geochemical data on the plume-related basalts including the first geochemical data on the Middle Paleozoic OIB-type basalts of the Paleo-Asian Ocean hosted by the Ulaanbaatar AC of Mongolia. An emphasis is made for the structural setting of OPS units, specific geochemical features of intraplate basalts, problems of their identification, and distinguishing from magmatic units of a different origin such as MORB, island-arc and back-arc basalts. Finally, we propose a continuous, though periodical, evolution of the Pacific superplume-related magmatism, which can be more reliably proved by studying Middle Paleozoic OPS units hosted by ACs of Mongolia and Tien Shan, and discuss prospects of future studies.     

Tectonics and geodynamics of Gorny Altai and adjacent structures of the Altai–Sayan folded area

Packages of Late Paleozoic tectonic nappes and associated major NE-trending strike-slip faults are widely developed in the Altai–Sayan folded area. Fragments of early deformational phases are preserved within the Late Paleozoic allochthons and autochthons. Caledonian fold-nappe and strike-slip structures, as well as accompanying metamorphism and granitization in the region, are typical of the EW-trending suture-shear zone separating the composite Kazakhstan–Baikal continent and Siberia. In the Gorny Altai region, the Late Paleozoic nappes envelop the autochthon, which contains a fragment of the Vendian–Cambrian Kuznetsk–Altai island arc with accretionary wedges of the Biya–Katun’ and Kurai zones. The fold-nappe deformations within the latter zones occurred during the Late Cambrian (Salairian) and can thus be considered Salairian orogenic phases. The Salairian fold-nappe structure is stratigraphically overlain by a thick (up to 15 km) well-stratified rock unit of the Anyui–Chuya zone, which is composed of Middle Cambrian–Early Ordovician fore-arc basin rocks unconformably overlain by Ordovician–Early Devonian carbonate-terrigenous passive-margin sequences. These rocks are crosscut by intrusions and overlain by a volcanosedimentary unit of the Devonian active margin. The top of the section is marked by Famennian–Visean molasse deposits onlapping onto Devonian rocks. The molasse deposits accumulated above a major unconformity reflects a major Late Paleozoic phase of folding, which is most pronounced in deformations at the edges of the autochthon, nearby the Kaim, Charysh–Terekta, and Teletskoe–Kurai fault nappe zones. Upper Carboniferous coal-bearing molasse deposits are preserved as tectonic wedges within the Charysh–Terekta and Teletskoe–Kurai fault nappe zones.Detrital zircon ages from Middle Cambrian–Early Ordovician rocks of the Anyui–Chuya fore-arc zone indicate that they were primarily derived from Upper Neoproterozoic–Cambrian igneous rocks of the Kuznetsk–Altai island arc or, to a lesser extent, from an Ordovician–Early Devonian passive margin. A minor age population is represented by Paleoproterozoic grains, which was probably sourced from the Siberian craton. Zircons from the Late Carboniferous molasse deposits have much wider age spectra, ranging from Middle Devonian–Early Carboniferous to Late Ordovician–Early Silurian, Cambrian–Early Ordovician, Mesoproterozoic, Early–Middle Proterozoic, and early Paleoproterozoic. These ages are consistent with the ages of igneous and metamorphic rocks of the composite Kazakhstan–Baikal continent, which includes the Tuva-Mongolian island arc with accreted Gondwanan blocks, and a Caledonian suture-shear zone in the north. Our results suggest that the Altai–Sayan region is represented by a complex aggregate of units of different geodynamic affinity. On the one hand, these are continental margin rocks of western Siberia, containing only remnants of oceanic crust embedded in accretionary structures. On the other hand, they are represented by the Kazakhstan–Baikal continent composed of fragments of Gondwanan continental blocks. In the Early–Middle Paleozoic, they were separated by the Ob’–Zaisan oceanic basin, whose fragments are preserved in the Caledonian suture-shear zone. The movements during the Late Paleozoic occurred along older, reactivated structures and produced the large intracontinental Central Asian orogen, which is interpreted to be a far-field effect of the colliding East European, Siberian, and Kazakhstan–Baikal continents.     

Temporal evolution of the kerguelen plume: Geochemical evidence from 38 to 82 ma lavas forming the Ninetyeast ridge

Abstract Basaltic basement has been recovered by deep-sea drilling at seven sites on the linear Ninetyeast Ridge in the eastern Indian Ocean. Studies of the recovered lavas show that this ridge formed from ~ 82 to 38 Ma as a series of subaerial volcanoes that were created by the northward migration of the Indian Plate over a fixed magma source in the mantle. The Sr, Nd and Pb isotopic ratios of lavas from the Ninetyeast Ridge range widely, but they largely overlap with those of lavas from the Kerguelen Archipelago, thereby confirming previous inferences that the Kerguelen plume was an important magma source for the Ninetyeast Ridge. Particularly important are the ~ 81 Ma Ninetyeast Ridge lavas from DSDP Site 216 which has an anomalous subsidence history (Coffin 1992). These lavas are FeTi-rich tholeiitic basalts with isotopic ratios that overlap with those of highly alkalic, Upper Miocene lavas in the Kerguelen Archipelago. The isotopic characteristics of the latter which erupted in an intraplate setting have been proposed to be the purest expression of the Kerguelen plume (Weis et al. 1993a,b). Despite the overlap in isotopic ratios, there are important compositional differences between lavas erupted on the Ninetyeast Ridge and in the Kerguelen Archipelago. The Ninetyeast Ridge lavas are dominantly tholeiitic basalts with incompatible element abundance ratios, such as La/Yb and Zr/Nb, which are intermediate between those of Indian Ocean MORB (mid-ocean ridge basalt) and the transitional to alkalic basalts erupted in the Kerguelen Archipelago. These compositional differences reflect a much larger extent of melting for the Ninetyeast Ridge lavas, and the proximity of the plume to a spreading ridge axis. This tectonic setting contrasts with that of the recent alkalic lavas in the Kerguelen Archipelago which formed beneath the thick lithosphere of the Kerguelen Plateau. From ~ 82 to 38 Ma there was no simple, systematic temporal variation of Sr, Nd and Pb isotopic ratios in Ninetyeast Ridge lavas. Therefore all of the isotopic variability cannot be explained by aging of a compositionally uniform plume. Although Class et al. (1993) propose that some of the isotopic variations reflect such aging, we infer that most of the isotopic heterogeneity in lavas from the Ninetyeast Ridge and Kerguelen Archipelago can be explained by mixing of the Kerguelen plume with a depleted MORB-like mantle component. However, with this interpretation some of the youngest, 42–44 Ma, lavas from the southern Ninetyeast Ridge which have²⁰⁶pb/²⁰⁴Pb ratios exceeding those in Indian Ocean MORB and Kerguelen Archipelago lavas require a component with higher²⁰⁶Pb/²⁰⁴Pb, such as that expressed in lavas from St. Paul Island.     

Late Precambrian OIB magmatism in the Kuznetsk Alatau,Siberia: Geochemical features of the Kulbyurstyug Formation volcanics

Basaltoids of the Vendian–Cambrian Kulbyurstyug volcanic complex in the eastern part of Kuznetsk Alatau have a high content of titanium (TiO₂ 3–4 wt %). They are relatively enriched with LILE and HFSE (Ba 360–900, Zr 160–726, Nb 66–101, ΣREE up to 225–329 ppm), and demonstrate a fractionated spectrum of REEs (La/Yb ～ 13–17), high Nb/U (44–66), and low Th/Ta and Th/Nb. These features are comparable with derivatives of OIB (Ocean Island Basalts) magmatism. The rock geochemistry suggests the possible formation of an initial mafic melt in the garnet-bearing peridotite mantle with 2–4% degree of melting and the presence of a small amount of spinel. By the age and composition, the studied volcanics are correlated with the OIB magmatism products, occurring in the adjacent Gorny Altai and also considered to be derivatives of intraplate magmatism of Riphean–Early Cambrian age. This magmatism was caused by plume activity during formation of the Paleo-Asian Ocean.     

Geochemistry of Lavas from the Emperor Seamounts, and the Geochemical Evolution of Hawaiian Magmatism from 85 to 42 Ma

The Hawaiian–Emperor Seamount Chain (ESC), in the northernPacific Ocean, was produced during the passage of the PacificPlate over the Hawaiian hotspot. Major and trace element concentrationsand Sr–Nd–Pb isotopic compositions of shield andpost-shield lavas from nine of the Emperor Seamounts providea 43 Myr record of the chemistry of the oldest preserved Hawaiianmagmatism during the Late Mesozoic and Early Cenozoic (from85 to 42 Ma). These data demonstrate that there were large variationsin the composition of Hawaiian magmatism over this period. Tholeiiticbasalts from Meiji Seamount (85 Ma), at the northernmost endof the ESC, have low concentrations of incompatible trace elements,and unradiogenic Sr isotopic compositions, compared with youngerlavas from the volcanoes of the Hawaiian Chain (<43 Ma).Lavas from Detroit Seamount (81 Ma) have highly depleted incompatibletrace element and Sr–Nd isotopic compositions, which aresimilar to those of Pacific mid-ocean ridge basalts. Lavas fromthe younger Emperor Seamounts (62–42 Ma) have trace elementcompositions similar to those of lavas from the Hawaiian Islands,but initial ⁸⁷Sr/⁸⁶Sr ratios extend to lower values. From 81to 42 Ma there was a systematic increase in ⁸⁷Sr/⁸⁶Sr of boththoleiitic and alkalic lavas. The age of the oceanic lithosphereat the time of seamount formation decreases northwards alongthe Emperor Seamount Chain, and the oldest Emperor Seamountswere built upon young, thin lithosphere close to a former spreadingcentre. However, the inferred distance of the Hawaiian plumefrom a former spreading centre, and the isotopic compositionsof the oldest Emperor lavas appear to rule out plume–ridgeinteraction as an explanation for their depleted compositions.We suggest that the observed temporal chemical and isotopicvariations may instead be due to variations in the degree ofmelting of a heterogeneous mantle, resulting from differencesin the thickness of the oceanic lithosphere upon which the EmperorSeamounts were constructed. During the Cretaceous, when theHawaiian plume was situated beneath young, thin lithosphere,the degree of melting within the plume was greater, and incompatibletrace element depleted, refractory mantle components contributedmore to melting. KEY WORDS: Emperor Seamounts; Hawaiian plume; lava geochemistry; lithosphere thickness; mantle heterogeneity     

Features of magmatim-related metallogeny of Gorny Altai and Rudny Altai (Russia)

The Rudny Altai and Gorny Altai regions had different geologic histories and differ in metallogenic patterns. The Vendian-Early Cambrian to Permian-Triassic multistage evolution of Gorny Altai included subduction, accretion-collision, and rifting events accompanied by magmatism and related mineralization. Metallogeny evolved in discrete pulses, with especially abundant Late Paleozoic-earliest Mesozoic mineralization. The Devonian-Carboniferous pulse produced diverse mineral deposits (iron, mercury, gold, silver, molybdenum, tungsten, cobalt, polymetallic ores, and rare earths), some of considerable economic value. The territory of Gorny Altai includes several large ore districts that belong to different zones. They are the Beloretsk-Kholzun iron district in the west, the Kayancha-Sinyukha fluorine-gold district in the northeast, the Kurai gold-mercury and Yustyd rare-metal-silver districts in the southeast, and the Kalguty rare-metal-tungsten and Ulandryk U-REE-Cu districts in the south. The largest mineral deposits are Kholzun (Fe, P₂O₅), Karakul (Co, Bi), Sinyukha (Au), Aktash and Chagan-Uzun (Hg), Ozernoe and Pogranichnoe (Ag), Kalguty (Mo, W), Alakha (Li, Ta), Rudnyi Log (Y,Fe-specularite), and Urzarsai (W-scheelite). Mineralization in Rudny Altai is mainly pyritic: copper-pyrite, pyrite-polymelallic ore, and barite-polymelallic ore. It resides in suprasubduction basalts and rhyolites and in Emsian to Frasnian island-arc volcanics at different stratigraphic levels of Devonian volcanosedimentary sequences in six ore districts. The Kurchum high-grade metamorphic block hosts copper-pyrite and gold-quartz mineralization related to Hercynian volcanism.     

Origin of Tertiary to Recent EM- and subduction-like chemical and isotopic signatures in Auca Mahuida region (37°–38°S) and other Patagonian plateau lavas

The alkaline volcanic rocks of the 1.8–0.9 Ma Auca Mahuida and post-mid-Pliocene Rio Colorado backarc volcanic fields east of the Andean Southern Volcanic Zone at ~37°–38°S have pronounced intraplate-like chemical signatures with some striking similarities to oceanic DM-EM1-like lavas of the south Atlantic Tristan da Cunha type. These backarc lavas are considered to have formed as a series of mantle batches typified by 4–7 % melting, with decompression melting initiating in a garnet-bearing mantle above a steepening subduction zone, and final equilibration occurring near the base of a ~65- to 70-km-thick lithosphere at temperatures of ~1,350–1,380 °C. Evolved Auca Mahuida mugearite to trachytic samples are best explained by crystal fractionation with limited mixing of partial melts of recently underplated basalts, in line with isotopic signatures that preclude significant radiogenic contamination in a preexisting refractory crust. Higher Ba/La and subtly higher La/Ta ratios than in nearby ~24–20 Ma primitive basalts or oceanic (OIB) lavas are attributed to the residual effects of slab fluids introduced during a shallow subduction episode recorded in the arc-like chemistry of the adjacent 7–4 Ma Chachahuén volcanic complex. Positive Sr, K and Ba spikes on mantle-normalized patterns of both primitive Auca Mahuida and ~24–20 Ma basalts, like those in EM-like OIB basalts, are attributed to mixing of continental lithosphere into the asthenosphere. In Patagonia, this mixing is suggested to have peaked as the South America continent accommodated to major late Oligocene plate convergence changes, as similar Sr, K and Ba spikes and DM-EM1 signatures are absent in ~50–30 Ma backarc lavas north of 51°S, and all of those south of 51°S. Introduction of an EM1-like component associated with lateral mantle flow of a Tristan da Cunha source is largely precluded by its Cretaceous age and distance to Patagonia.     

扎河坝蛇绿混杂岩内富铌玄武(安山)岩的地球化学特征及其地质意义

在新疆北部东准噶尔的扎河坝蛇绿混杂岩中发现的富铌玄武（安山）岩,其SiO₂含量介于46.71%~57.65%,TiO₂含量为1.00%~1.76%,与太古代绿岩带内富铌玄武（安山）岩相似,Na₂O含量为3.86%~6.64%,P₂O₅为0.34%~0.82%,明显高于太古代绿岩带富铌玄武（安山）岩。扎河坝富铌玄武岩铌含量介于7.22×10^-6~21.91×10^-6之间,大于7×10^-6,与典型的富铌玄武岩相同。该岩石轻重稀土元素分馏较明显,其分布模式为无明显铕至弱负铕异常的右倾曲线。尽管铌的绝对含量较高,但由于钍和轻稀土元素更加富集,在微量元素蛛网图中扎河坝富铌玄武（安山）岩仍表现为铌的明显亏损,同时高场强元素Zr、Hf及Ti也表现出一定程度的亏损。微量元素地球化学特征显示,扎河坝蛇绿混杂岩内富铌玄武（安山）岩形成于古亚洲洋的洋内弧,它是被埃达克质岩浆交代的地幔楔橄榄岩部分熔融的产物,同时大洋沉积物及俯冲板块释放的流体对成岩作用也有一定的贡献。富铌玄武（安山）岩作为弧前增生楔定位在扎河坝蛇绿混杂岩体内,与早前报道的超高压变质岩共存表明,该蛇绿混杂岩体至少记录了两次性质不同的古亚洲洋洋壳俯冲,这更进一步证实新疆北部晚古生代新增陆壳是古亚洲洋多次俯冲作用的产物。     

Post-collisional transition from calc-alkaline to alkaline volcanism during the Neogene in Oranie (Algeria): magmatic expression of a slab breakoff

During the Neogene, a magmatic change from calc-alkaline to alkaline types occurred in all the regions surrounding the western Mediterranean. This change has been studied in Oranie (western Algeria). In this area, potassic to shoshonitic calc-alkaline andesites (with La/Nb ratios in the range 4–6) were mainly erupted between 12 and 9 Ma. They were followed (between 10 and 7 Ma) by basalts displaying geochemical features which are transitional between calc-alkaline and alkaline lavas (La/Nb=1–1.7). After a ca. 3-Ma quiescence period, volcanic activity resumed, with the eruption of OIB-type alkaline basalts (La/Nb=0.5–0.6), from 4 to 0.8 Ma. A combined geochemical approach, using incompatible elements and Sr, Nd and O isotopes, allows us to conclude that the transitional basalts derived from the melting of a heterogeneous mantle source, at the boundary between lithosphere and asthenosphere. We propose that melting of a previously subduction-modified lithospheric mantle occurred between 12 and 10 Ma, in response to the upwelling of hot asthenosphere flowing up into an opening gap above a detached sinking slab. As a result, calc-alkaline magmas were formed. From 10 to 7 Ma, the transitional basalts were generated through melting of the boundary mantle zone between the lithosphere and the upwelling asthenosphere. During that stage, the contribution of the lithospheric source was still predominant. Then, as sinking of the oceanic slab progressed, the increasing uprise of the asthenosphere led to the formation and emplacement (from 4 to 0.8 Ma) of typical within-plate alkaline basalts derived from a plume-modified asthenospheric mantle.     

西准噶尔玛依勒地区枕状玄武岩年代学、地球化学及岩石成因

通过对造山带内洋岛玄武岩的时代及地球化学性质研究,不仅可以进行古海山/大洋高原的识别,而且还可以进行古洋盆演化及古构造格局恢复。笔者等最新在西准噶尔玛依勒山北侧识别出一套枕状玄武岩,其与火山碎屑岩、硅质岩共生。枕状玄武岩斜长石微晶普遍发育中空骸晶结构,是在水下熔岩急剧萃冷条件下迅速结晶的产物。通过LA-ICP-MS锆石U-Pb测年,获得枕状玄武岩206Pb/238U加权平均年龄为437.2±2.2Ma,该年龄的获得填补了志留纪碱性玄武岩的空白。岩石地球化学分析结果显示,玛依勒枕状玄武岩为碱性玄武岩系列,岩石具有中等Si O2(44.89%~47.81%),高Ti O2(3.28%~4.12%)及P2O5(0.50%~0.70%),低Mg O(3.49%~6.79%),轻、重稀土元素分异较为明显((La/Yb)N=5.5~7.3),无明显Eu异常(Eu/Eu*=0.96~1.06),相对富集Rb、Th、U,亏损Ba、K、Sr,没有明显Nb、Ta负异常,这些地球化学特征与洋岛玄武岩(OIB)极其相似。微量元素含量及反映源区性质的比值表明,枕状玄武岩来源于富集地幔源区,主要组成为尖晶石和石榴石二辉橄榄岩,并发生了5%±的部分熔融,其形成于大洋板内与地幔柱有关的海山/大洋岛屿环境。结合前人研究,认为西准噶尔乃至古亚洲洋在中古生代洋内俯冲的同时,大洋板内可能存在地幔柱活动。     

Mantle dynamics and mantle melting beneath Niuafo’ou Island and the northern Lau back-arc basin

A suite of young volcanic basaltic lavas erupted on the intra-plate island of Niuafo’ou and at active rifts and spreading centres (the King’s Triple Junction and the Northeastern Lau Spreading Centre) in the northern Lau Basin is used to examine the pattern of mantle flow and the dynamics of melting beneath this complex back-arc system. All lavas contain variable amounts of a subduction related component inherited from the Tonga subduction zone to the east. All lavas have higher ⁸⁷Sr/⁸⁶Sr, lower ¹⁴³Nd/¹⁴⁴Nd and more radiogenic Pb isotope compositions than basalts erupted at the Central Lau Spreading Centre in the central Lau Basin, and are interpreted as variable mixtures of subduction-modified, depleted upper mantle, and mantle residues derived from melting beneath the Samoan Islands which has leaked through a tear in the subducting Pacific Plate beneath the Vitiaz Lineament at the northern edge of the Lau Basin. Our data can be used to map out the present-day distribution of Samoan mantle in this region, and show that it influences the compositions of lavas erupted as far as 400 km from the Samoan Islands. The distribution of Samoan-influenced lavas implies south- and southwest-wards mantle flow rates of >4 cm/year. U-series disequilibria in historic Niuafo’ou lavas have average (²³⁰Th/²³⁸U) = 1.13, (²³¹Pa/²³⁵U) = 2.17, (²²⁶Ra/²³⁰Th) = 2.11, and together with major and trace element data require ∼5% partial melting of mantle at between 2 and 3 GPa, with a residual porosity of 0.002 and an upwelling rate of 1 cm year⁻¹. We suggest that intraplate magmatism in the northern Lau Basin results from decompression melting during southward flow of mantle from beneath old (110–120 Ma), relatively thick Pacific oceanic lithosphere to beneath young (<5 Ma), thinner oceanic lithosphere beneath the northern Lau Basin.     

Architecture and composition of ocean floor subducted beneath northern Gondwana during Neoproterozoic to Cambrian: A palinspastic reconstruction based on Ocean Plate Stratigraphy (OPS)

The Blovice accretionary complex, Bohemian Massif, hosts well-preserved basaltic blocks derived from an oceanic plate subducted beneath the northern active margin of Gondwana during late Neoproterozoic to early Cambrian. The major and trace element and Hf–Nd isotope systematics revealed two different suites, tholeiitic and alkaline, whose composition reflects different sources of melts within a back-arc basin setting. The former suite has composition similar to mid-ocean ridge basalts (MORB), yet with striking enrichment in large-ion lithophile elements (LILE) and Pb paralleled by depletion in Nb, in agreement with its derivation from depleted mantle fluxed by subduction-related fluids. In contrast, the latter suite has composition similar to ocean island basalts (OIB) with variable contribution of ancient, recycled crustal material. We argue that both suites represent volcanic members of Ocean Plate Stratigraphy (OPS) and indicate that the oceanic realm consumed by the Cadomian subduction was a complex mosaic of intra-oceanic subduction zones, volcanic island arcs, and back-arc basins with mantle plume impinging the spreading centre. Hence, the basalt geochemistry implies that two distinct domains of oceanic lithosphere may have existed off the Gondwana’s continental edge: an outboard domain, made up of old and less buoyant oceanic lithosphere (remnants of the Mirovoi Ocean surrounding former Rodinia?) that was steeply subducted and generated the back-arcs, and young, hot, and more buoyant oceanic lithosphere generated in the back-arcs and later involved in accretionary complexes as dismembered OPS. Perhaps the best recent analogy of this setting is the Izu Bonin–Mariana arc–Philippine Sea in the western Pacific.     

The geochemistry and petrogenesis of the late-Cretaceous picrites and basalts of Curaçao,Netherlands Antilles: a remnant of an oceanic plateau

The island of Curaçao in the southern Caribbean Sea is composed mainly of a thick sequence (>5?km) of pillow lavas, grading upwards from picrites at the base of the exposed section, to basalts nearer the top. Modelling suggests that picrites are related to the basalts by fractional crystallisation. Initial radiogenic isotope ratios of the picrites have a restricted compositional range: ?_Nd=+6.1 to +6.6, ⁸⁷Sr/⁸⁶Sr=0.70296–0.70319; whereas the basalts display a wider range of compositions: ?_Nd=+6.6 to +7.6, ⁸⁷Sr/⁸⁶Sr=0.70321–0.70671. This variation in isotope ratios between basalts and picrites may be due to the assimilation of altered oceanic crust (or possibly partial melts of such crust) by a picritic magma along with fractional crystallisation. The relatively narrow range of Nd and Pb isotopic compositions in the Curaçao lavas suggests either that the source region was homogeneous, or that melts from a heterogeneous mantle source were well mixed before eruption. Chondritic to slightly light rare earth element enriched patterns, combined with long-term light rare earth element depletion (positive ?_Nd), suggest that the lavas were formed by polybaric melting of spinel lherzolite, with small a contribution from garnet lherzolite melts. High-MgO lavas, the absence of a subduction related chemistry, and the chemical similarity to other oceanic plateaux, suggest a mantle plume origin for the Curaçao lava succession. The Curaçao volcanic sequence is part of an oceanic plateau formed at about 88–90?Ma, fragments of which are dispersed around the Caribbean as well as being obducted onto the western margin of Colombia and Ecuador. The occurrence of high-Mg lavas throughout this Cretaceous Caribbean–Colombian igneous province requires anomalously hot mantle (>200^°?C hotter than ambient upper mantle) over a large part of a putative plume head, which is inconsistent with some mantle plume models.