The detection of single-domain greigite (Fe3S4) using rotational remanent magnetization (RRM) and the effective gyro field (Bg): mineral magnetic and palaeomagnetic applications

The intensity of rotational remanent magnetization (RRM) acquired by single-domain greigite at a rotation frequency of 5 rps was combined with measurements of anhysteretic remanent magnetization (ARM) to calculate the effective biasing field ( Bg ) that produced the RRM. Samples of single-domain greigite had Bg values between -137 and -84 μT, and a MDF_RRM of c. 80 mT. By contrast, a suite of natural and synthetic ferrimagnetic iron oxide samples, including single-domain magnetite and y Fe₃O₄ tape particles, acquired Bg values between -3 and -14 μT, and MDF_RRM ranged between 43 and 68 mT (when RRM was acquired). Multidomain magnetite did not acquire a RRM. Bg values at 5 rps were calculated from previously published data for magnetite particles of different grain sizes, which revealed a minimum Bg value of -24 μT and a MDF_RRM of 57 mT for the finest fraction (0.2-0.8 μm in diameter). In a geological example, measurements of Bg and MDF_RRM were used to detect the presence of greigite in a 4 m long Late Weichselian sediment core. Variations in inclination, declination and the intensity of the natural remanent magnetization (NRM) correlate with changes in magnetic mineralogy.     

New palaeomagnetic result from Vendian red sediments in Cisbaikalia and the problem of the relationship of Siberia and Laurentia in the Vendian

A palaeomagnetic study of Vendian red sediments from the Lena River section on the western margin of Lake Baikal in the region of Cisbaikalia (54°N, 108°E) has isolated a stable remanence with direction D = 296.3°, I = −27.7° (high-temperature component) and a corresponding pole of 2.7°S, 168.2°E. The primary nature of this remanence is confirmed from a positive fold test, dual polarities and the presence of detrital haematite. This result, together with all late Precambrian–Early Cambrian palaeomagnetic data from Siberia, indicates that Siberia occupied low latitudes during that time. It has been proposed on the basis of palaeomagnetic data that Laurentia occupied high latitudes during the Vendian, so it would appear that there cannot have been any Laurentia–Siberia connection at that time. A review of Vendian to Cambrian Laurentian palaeomagnetic data shows that such an interpretation is ambiguous. An alternative interpretation places Laurentia in low latitudes and confirms the Laurentia–Siberia fit of Hoffman (1991 ) and Pelechaty (1996 ). However, the lack of Late Vendian palaeomagnetic data for Siberia still allows the possibility that it could have occupied high latitudes during that time.     

A palaeomagnetic study of fracture fills in the Holy Cross Mountains of Central Poland and its application in dating tectonic processes

Calcite and sedimentary fills in fractures cutting the Upper Devonian carbonates in the Holy Cross Mountains (HCM) were dated palaeomagnetically by comparison with the apparent polar wander path (APWP). Haematite-bearing calcite possessed well-defined components of natural remanent magnetization (NRM), which were preserved under thermal demagnetization to temperatures of approximately 500 °C, when specimens disintegrated. Although not completely demagnetized, some specimens revealed a stable NRM component before destruction, thus making a component analysis possible. Five components were determined using density point distribution and cluster analysis. One has a mean that is similar to the present-day local geomagnetic vector. The remaining four components yielded palaeomagnetic poles located at: A (70.3°S, 5.5°E), B (71.3°S, 31.2°E), C (48.7°S, 351.0°E, virtual geomagnetic pole), and D (11.6°S, 312.3°E). Antipodal polarities found in the fracture fills, together with dissimilarities in magnetization found in calcite and hosting carbonates, indicate the lack of simultaneous remagnetization, and different times of remanence acquisition for the rocks under comparison. Taking both palaeomagnetically inferred palaeolatitudes and regional tectonics into consideration, a Mesozoic (Cretaceous?) age is estimated for palaeopoles A and B, a Permian age for pole C, and a Carboniferous age for pole D. These age determinations are in line with the calcite ages estimated from isotopic studies. A comparative palaeomagnetic study performed on a well-dated Upper Devonian neptunian dyke of limestone and a Lower Triassic clastic vein yielded virtual geomagnetic poles (VGPs) close to the APWP for Baltica. Generally, the remanence from fracture fills may be useful for dating related tectonics, karst phenomena and mineralization processes.     

Gyroremanent magnetization and the magnetic properties of greigite-bearing clays in southern Sweden

The acquisition of a gyroremanent magnetization (GRM) by single-domain (SD) greigite particles during alternating-field (AF) demagnetization is demonstrated. Previous palaeomagnetic studies failed to identify the presence of authigenic greigite in the glacio-marine clays studied. These clays formed the subject of an earlier debate about the validity of a Late Weichselian geomagnetic excursion (the Gothenburg Flip) in southern Sweden. The greigite carries a stable chemical remanent magnetization (CRM), which coexists with a detrital remanent magnetization (DRM) carried by magnetite. AF demagnetization could not isolate the primary remanence in the sediments where magnetite and greigite coexist, due to the overlapping coercivity spectra of the two minerals and the inability to determine the time lag between sediment deposition and CRM formation. Thermal demagnetization removed the CRM at temperatures below 400 C, but this method was hindered by the unconsolidated nature of the sediments and the formation of secondary magnetic minerals at higher temperatures. The results suggest that the low-coercivity DRM carried by magnetite was mistaken for a 'viscous' component in the earlier studies. Hence the former debate about the record of the Gothenburg Flip may have been based on erroneous palaeomagnetic interpretations or non-reproducible results. AF demagnetization procedures applied to samples suspected of bearing SD magnetic particles (such as greigite) should be carefully selected to recognize and account for GRM acquisition.     

New Early Cretaceous palaeomagnetic pole from Córdoba Province (Argentina): revision of previous studies and implications for the South American database

A continental sequence of red beds and interbedded basaltic layers crops out in the Sierra Chica of Córdoba Province, Argentina (31.5°S, 64.4°W). This succession was deposited in a half-graben basin during the Early Cretaceous. We have carried out a palaeomagnetic survey on outcrops of this basin (147 sites in seven localities). From an analysis of IRM acquisition curves and detailed demagnetization behaviour, three different magnetic components are identified in the volcanic rocks: components A, B and X are carried by single- or pseudo-single-domain (titano) magnetite, haematite and multidomain magnetite, respectively. Component A is interpreted as a primary component of magnetization because it passes conglomerate, contact, tilt and reversal tests. The carrier of the primary magnetization, fine-grained (titano)magnetite, is present in basalts with a high degree of deuteric oxidation. This kind of oxidation is interpreted to have occurred during cooling. Components B and X are discarded because they are interpreted as recent magnetizations. In the sedimentary rocks, haematite and magnetite are identified as the carriers of remanence. Both minerals carry the same component, which passes a reversal test. The calculated palaeomagnetic pole, based on 55 sites, is Lat. 86.0°S, Long. 75.9°E ( A ₉₅=3.3, K =35). This palaeomagnetic pole supersedes four with anomalous positions reported in previous papers.