Isotopic geochronological evidence for the Paleoproterozoic age of gold mineralization in Archean greenstone belts of Karelia, the Baltic Shield

The Rb-Sr age of metasomatic rocks from four gold deposits and occurrences localized in Archean granite-greenstone belts of the western, central, and southern Karelian Craton of the Baltic Shield has been determined. At the Pedrolampi deposit in central Karelia, the dated Au-bearing beresite and quartz-carbonate veins are located in the shear zone and replace Mesoarchean (～2.9 Ga) mafic and felsic metavolcanic rocks of the Koikar-Kobozero greenstone belt. At the Taloveis ore occurrence in the Kostomuksha greenstone belt of western Karelia, the dated beresite replaces Neoarchean (～2.7 Ga) granitoids and is conjugated with quartz veins in the shear zone. At the Faddeinkelja occurrence of southern Karelia, Aubearing beresite in the large tectonic zone, which transects Archean granite and Paleoproterozoic mafic dikes, has been studied. At the Hatunoja occurrence in the Jalonvaara greenstone belt of southwestern Karelia, the studied quartz veins and related gold mineralization are localized in Archean granitoids. The Rb-Sr isochrons based on whole-rock samples and minerals from ore-bearing and metasomatic wall rocks and veins yielded ～1.7 Ga for all studied objects. This age is interpreted as the time of development of ore-bearing tectonic zones and ore-forming hydrothermal metasomatic alteration. New isotopic data in combination with the results obtained by our precursors allow us to recognize the Paleoproterozoic stage of gold mineralization in the Karelian Craton. This stage was unrelated to the Archean crust formation in the Karelian Block and is a repercussion of the Paleoproterozoic (2.0–1.7 Ga) crust-forming tectonic cycle, which gave rise to the formation of the Svecofennian and Lapland-Kola foldbelts in the framework of the Karelain Craton. The oreforming capability of Paleoproterozoic tectonics in the Archean complexes of the Karelian Craton was probably not great, and its main role consisted in reworking of the Archean gold mineralization of various genetic types, including the inferred orogenic mesothermal gold concentrations.     

BASIN-RANGE TRANSITION AND GENETIC TYPES OF SEQUENCE BOUNDARY OF THE QIANGTANG BASIN IN NORTHERN TIBET

BASIN-RANGE TRANSITION AND GENETIC TYPES OF SEQUENCE BOUNDARY OF THE QIANGTANG BASIN IN NORTHERN TIBET     

Banded iron formations of the calciphyre-metabasite-gneiss association in the East European Craton

The paper presents characteristics of the least studied iron formations of the East European Craton (Archean banded iron formations of the calciphyre-metabasite-gneiss association), a typical member of granulite complexes of the Ukrainian Shield, Belarussian-Baltic region, and Voronezh crystalline massif. They are mainly composed of diverse metasedimentary rocks: aluminous gneisses; silicate-magnetite, magnetite, and barren quartzites; eulysites; calciphyres; and marbles associated with metavolcanic rocks. Data on chemical compositions of the metasedimentary rocks are summarized for the first time and their possible primary mineral composition has been reconstructed using the MINLITH software. It is shown that they could be formed from a lithogenetic series of sediments linked by gradual transitions and geochemical commonness of sediments: from fine-grained terrigenous insufficiently mature sediments to chemogenic sediments depleted in terrigenous material (ferruginous-siliceous, ferruginous-siliceous-carbonate, siliceous-carbonate, and carbonate sediments). The inferred primary mineral assemblage indicates sedimentation in the central parts of large paleobasins in a reducing environment characterized by deficit of oxygen and excess of carbon dioxide. Lithological specifics of the banded iron formations in different regions presumably reflect different distances of sedimentation zones from submarine hydrothermal discharge sites and sources of terrigenous material. The banded iron formations at the present-day erosion section of basement represent metamorphosed fragments of the lateral-facies zoning of rocks of the Archean sedimentary basins (or a single basin) of the East European Craton. Unlike other Early Precambrian banded iron formations of the East European Craton, rocks of the calciphyre-metabasite-gneiss association are marked by a high Mn content.     

Trace elements in Upper Devonian rocks of the Andoma Hill zone of fold-and-fault dislocations (southeastern Onega region) as indicators of source areas

The paper reports the results of lithogeochemical studies of the Upper Devonian rocks from the Andoma Hill zone of fold-and-fault dislocations (SE Onega region). The rocks are characterized by the negative Eu anomaly (from 0.4 to 0.65) that maks them different from modern sediments of the White Sea. The latter can be regarded as the average composition of mainly Archean (Karelian–Kola) part of the Baltic Shield. In terms of the contents of some trace elements, they also differ from the Vendian rocks of the Zimnii Bereg area. Since the considered rocks are geochemically similar to the Svecofennian metamorphic rocks and Paleoproterozoic granite rapakivi, they could be formed by the erosion of these complexes. The clastic material was transported via a channel confined to the Baltic Shield and Russian Platform junction known as the Polkanov geoflexure.     

Sm-Nd data as a key to the origin of the Archean sanukitoids of Karelia,Baltic shield

New Sm-Nd isotopic data were obtained for the Late Archean sanukitoids of the Karelian granite-greenstone terrain of the Baltic shield. Regional variations in their Nd isotopic composition were detected. The Nd isotopic characteristics of sanukitoids from the youngest Central Karelian domain are similar to those of the depleted mantle, whereas the intrusions of the older western Karelian and Vodlozero domains show lower ?_Nd(t) values. This isotopic heterogeneity is explained by different time intervals between the enrichment and partial melting of the mantle sources of sanukitoids from particular domains. A two-stage model was proposed for the formation of sanukitoid magmas. The first stage included mantle metasomatism by slab-derived fluids and/or melts. During the second stage (2.74–2.70 Ga), a tectonothermal anomaly caused partial melting of the metasomatized mantle and generation of sanukitoid melts. Most of the sanukitoid intrusions are cut by calc-alkaline lamprophyre dikes, which are geochemically similar to the sanukitoids. The new Sm-Nd isotopic data suggest a genetic link between these rocks. A comparison of the geochemical features of the sanukitoids and Phanerozoic subduction-related magmas showed that the Archean sanukitoids have no modern analogues.     

中国南方海相生烃成藏研究的若干新进展(一) 南方四套区域性海相烃源岩的分布

通过对上、中、下扬子区121个地表及钻井剖面烃源岩的密集扫描取样和地化分析,系统研究了下寒武统、上奥陶统—下志留统、上二叠统、下二叠统四套区域性海相烃源岩的厚度及有机质丰度的纵横向分布,明确了海相烃源岩在纵向上以下寒武统和上二叠统为最好,横向上以上扬子区为最好,其次为下扬子区;确定了五个烃源岩发育区。明确了海相烃源岩以泥岩为主,碳酸盐岩烃源岩只出现在下二叠统栖霞组—茅口组,实测最大厚度为150m,从而表明中国南方不存在上千米厚的碳酸盐岩烃源岩。对四套海相烃源岩的厚度问题、层位问题、原始生烃潜量和碳酸盐岩烃源岩的鉴别问题等提出了认识。     

Problems of Siderite Formation and Iron Ore Epochs: Communication 1. Types of Siderite-Bearing Iron Ore Deposits

It is shown that siderite is unstable during sedimentation, diagenesis, and metamorphism of sedimentary and volcanosedimentary rocks. Regularities in the distribution of siderite in Precambrian jaspilites (iron formations), metasomatic ores of the Bakal type, continental–marine coaliferous formations, and oolitic iron ores are discussed. The genesis of the Precambrian iron formations and Riphean–Lower Paleozoic elisional–hydrothermal deposits is considered. The genetic relation of nodular siderites from coaliferous formations and oolitic iron ores with lowmoor coal-forming peat deposits is noted.     

Source Rocks for the Giant Puguang Gas Field, Sichuan Basin: Implication for Petroleum Exploration in Marine Sequences in South China

Detailed geochemistry studies were conducted to investigate the origin of solid bitumens and hydrocarbon gases in the giant Puguang gas field. Two types of solid bitumens were recognized: low sulfur content, low reflectance (LSLR) solid bitumens in sandstone reservoirs in the Xujiahe Formation and high sulfur content, high reflectance (HSHR) solid bitumens in the carbonate reservoirs in the Lower Triassic Feixianguan and Upper Permian Changxing formations. Solid bitumens in the Upper Triassic Xujiahe Formation correlate well with extracts from the Upper Triassic to Jurassic nonmarine source rocks in isotopic composition of the saturated and aromatic fractions and biomarker distribution. Solid bitumens in the Feixianguan and Changxing formations are distinctly different from extracts from the Cambrian and Silurian rocks but display reasonable correlation with extracts from the Upper Permian source rocks both in isotopic composition of the saturated and aromatic fractions and in biomarker distribution, suggesting that the Permian especially the Upper Permian Longtan Formation was the main source of solid bitumens in the carbonate reservoirs in the Feixianguan and Changxing formations in the Puguang gas field. Chemical and isotopic composition of natural gases indicates that the majority of hydrocarbon gases originated from sapropelic organic matter and was the products of thermal cracking of accumulated oils. This study indicates that source rock dominated by sapropelic organic matter existed in the Upper Permian and had made major contribution to the giant Puguang gas field, which has important implication for petroleum exploration in marine sequences in South China.     

New constraints for the source characteristics,deposition and age of the 2.1–1.9 Ga metasedimentary cover at the western margin of the Karelian Province

The Paleoproterozoic cover sequence at the 100–150 km wide western margin of the Archean Karelian Province is dominated by deep water Lower and Upper Kaleva metasediments. We present here an interpretation of Sm–Nd isotope and geochemical data on 36 samples, TIMS multi-grain U–Pb zircon analyses on nine samples, and ca. 100 SIMS analysis of detrital zircon grains from four Upper Kaleva and one Lower Kaleva samples.The Lower Kaleva is characterized by autochthonous–parautochthonous, lithologically heterogeneous metaturbidites showing common enrichment in quartz. All the analysed detrital zircons are of a local Neoarchean source but t_DM variation up to 2.4 Ga combined with geochemical data indicate abundant mixing of Paleoproterozoic mafic material, presumably from 2.1 Ga plateau lavas and dykes, in most of the Lower Kaleva samples.The Upper Kaleva is dominantly allochthonous with tectonically enclosed fragments of ophiolite bodies, and it is characterized by lithological and geochemical-isotopic homogeneity. Geochemical, isotopic and detrital zircon data favour material derived from an orogenic domain, comprising both Archean and Proterozoic units, followed by effective mixing during the transport. The Archean zircon grains (25%) are mostly Neoarchean. The Paleoproterozoic grains lack zircons at 2.5–2.2 Ga and plot dominantly (92%) between 1.92 and 2.05 Ga. The indicated maximum deposition ages vary from 1.95–1.94 Ga to 1.92 Ga. The main source area proposed is the Himalaya-type Lapland-Kola orogen (now) in the northeast, which experienced mountain building and erosion at 1.95–1.91 Ga.The western margin of the Karelian Province shows evidence of rifting and lithosphere thinning from 2.1 to 1.95 Ga but it is still under debate whether the craton breakup occurred at 2.06 Ga in a volcanic or later at 1.95 Ga in a non-volcanic margin setting. One hypothesis is that the onset of collision in the northeast changed plate motion and lead to a new spreading within the pre-existing passive margin at 1.97–1.95 Ga. Thus, both a volcanic margin at 2.06 Ga and a non-volcanic margin at ca. 1.95 Ga could have been operated at the western margin of the Karelian Province.     

Source Rocks for the Giant Puguang Gas Field,Sichuan Basin:Implication for Petroleum Exploration in Marine Sequences in South China

Detailed geochemistry studies were conducted to investigate the origin of solid bitumens and hydrocarbon gases in the giant Puguang gas field. Two types of solid bitumens were recognized： low sulfur content, low reflectance （LSLR） solid bitumens in sandstone reservoirs in the Xujiahe Formation and high sulfur content, high reflectance （HSHR） solid bitumens in the carbonate reservoirs in the Lower Triassic Feixianguan and Upper Permian Changxing formations. Solid bitumens in the Upper Triassic Xujiahe Formation correlate well with extracts from the Upper Triassic to Jurassic nonmarine source rocks in isotopic composition of the saturated and aromatic fractions and biomarker distribution. Solid bitumens in the Feixianguan and Changxing formations are distinctly different from extracts from the Cambrian and Silurian rocks but display reasonable correlation with extracts from the Upper Permian source rocks both in isotopic composition of the saturated and aromatic fractions and in biomarker distribution, suggesting that the Permian especially the Upper Permian Longtan Formation was the main source of solid bitumens in the carbonate reservoirs in the Feixianguan and Changxing formations in the Puguang gas field. Chemical and isotopic composition of natural gases indicates that the majority of hydrocarbon gases originated from sapropelic organic matter and was the products of thermal cracking of accumulated oils. This study indicates that source rock dominated by sapropelic organic matter existed in the Upper Permian and had made major contribution to the giant Puguang gas field, which has important implication for petroleum exploration in marine sequences in South China.     

Geochemical soil surveys over cambrian and lower devonian formations in the belgian ardennes as a tool for geological mapping

A geochemical soil survey was made over outcropping Cambrian and Lower Devonian formations in the Belgian Ardennes. About 300 soil samples were collected in an area of 2.5 × 1.1 km².Analysis of rock samples from scarce, but stratigraphically well-known outcrops show that the Cambrian rocks are richer in copper than those of the Lower and Upper Gedinnian (Lower Devonian). The Upper Gedinnian rocks are more nickeliferous than the other horizons.In the well-drained soils, copper and lead distributions permit precise location of the boundary between Cambrian and Lower Gedinnian formations. The nickel distribution seems to be a good stratigraphic indicator for distinguishing Upper from Lower Gedinnian. Zinc distribution seems unrelated to underlying bedrock geology.Regression analysis confirms that the content of Cu, Pb and Ni is essentially a function of lithostratigraphy. However, the distribution of these elements is more influenced by pedological factors in the poorly drained soils.     

A deep borehole in the East European platform margin: Petrologic and isotopic-geochronologic data

The petrologic and isotopic-geochronologic study of basement rocks that were penetrated by a deep borehole in the marginal part of the East European Platform revealed that its section overlain by the Vendian-Paleozoic sedimentary cover is Early Proterozoic in age and largely consists of aluminous migmatized biotite, biotite-cordierite, and biotite-cordierite-sillimanite gneisses, which are intruded by granites, plagiogranites, and metatonalites. The lower part of the section is dominated by amphibole schists and amphibolites with subordinate nonmetamorphosed dolerite dikes and pegmatite veins. By metamorphism parameters (T = 630–680°C, P = 2–4 kbar), the metamorphic complex may be considered as the shallowest one, compared with other Early Proterozoic complexes, developed at least in the southwestern part of Fennoscandia. The progressive decrease in the mineral-formation pressure observed in the Lower Proterozoic metamorphic rocks southward, away from the Karelian Craton is likely explained by the tectonic transport (thrusting) of the Svecofennides over the margin of the Karelian Craton and their subsequent deeper erosion near the craton. The magmatic crystallization of metamorphic palgiogranites, penetrated at depths of 925–928 and 1004 m, is estimated by the U-Pb ID-TIMS method on zircons to occur 1860 ± 9 Ma ago. It is shown that by their age, the REE composition, and isotopic-geochemical characteristics, these rocks are close to the plagiogranites formed in the southeastern extremity of the Svecofennnian belt in the present-day northern Ladoga region and the Karelian Isthmus. No rocks, which could be correlated by their lithology with the Archean rocks of the Karelian Craton, are found.     

SPACE-TIME TEXTURE AND TECTONIC EVOLUTION OF QAMDO BLOCK IN EAST TIBET

SPACE-TIME TEXTURE AND TECTONIC EVOLUTION OF QAMDO BLOCK IN EAST TIBET     

A new section of Lower Palaeozoic rocks in Kayin State (Southeast Myanmar)

Lower Palaeozoic rocks have been mapped in Kayin State in an area previously shown on published maps as either metamorphic or possibly Lower or Upper Palaeozoic rocks. Three new formations, with a total thickness of over 900?m, apparently overlain by an, at least, 100?m thick Upper Palaeozoic formation are mapped along the Salween River and along the road from Yinbaing, in Myanmar, to Tha Song Yang, in Thailand. The Lower Palaeozoic succession consists of the predominantly siliciclastic Kyaukpulu and Kushwe–e–we formations and an overlying, predominantly carbonate Meseik Ashe Formation which contains Middle Ordovician (Darriwilian) conodonts. The older two formations are probable correlates of the Ngwetaung and Lokeypin formations of the southern Shan State of Myanmar and the Lower Ordovician siliciclastics of western Thailand. The overlying, peritidal to shallow subtidal carbonates of the Meseik–Ashe Formation are correlates of the Wunbye and Sitha formations of Shan State, Myanmar. The thick–bedded, quartz arenites of the Nyaungwiang Formation are faulted against the Ordovician carbonates and are probable lithological correlates of the Carboniferous Taungnyo Formation. The folds in the Lower Palaeozoic rocks are overturned to the northeast and deformation was in one major phase between the Tournaisian and the Early Permian. The Lower Palaeozoic strata may probably be followed as a ridge for at least 100?km towards the NNW, close to the western border of the Sibuma Block which is separated by a postulated cryptic suture from the Irrawaddy Block to the west.     

Change of Conditions of the Formation of the Karelian Province of the Baltic Shield Continental Crust during Transition from Meso- to Neoarchean: Geochemical Study Results

The compositions of the tonalite–trondhjemite–granodiorite (TTG) assemblage and volcanic rocks of the Archaean greenstone belts from different domains of the Karelian province of the Baltic Shield are compared. Neoarchean medium felsic volcanic rocks and TTG of the Central Karelian domain drastically differ from analogous Mesoarchean rocks of the neighboring Vodlozero and West Karelian domains in higher Rb, Sr, P, La, and Ce contents and, correspondingly, values of Sr/Y, La/Yb, and La/Sm, and also in a different REE content distribution owing to different rock sources of these domains. This fact is confirmed by differences in the composition and the nature of the REE distribution in the basic and ultrabasic volcanic rocks making up the greenstone belts of these domains. It is established that the average compositions of Mesoarchean TTG rocks and volcanic rocks of the Karelian province differ markedly from those of plagiogranitoids and volcanic rocks of the recent geotectonic environments in high Mg (mg#) and Sr contents. Neoarchean volcanic rocks of Karelia differ from recent island-arc volcanic rocks, but are similar in composition to recent volcanic rocks of the continental arcs. On the basis of the cumulative evidence, the Karelian province of the Baltic Shield was subject to dramatic changes in the crust formation conditions at the beginning of the Neoarchean at the turn of about 2.75–2.78 Ga. These changes led to formation of volcano-sedimentary and plutonic rock complexes, different in composition from Mesoarchean rocks, and specific complexes of intrusive sanukitoids and granites. Changes and variations in the rock composition were related to the mixing of plume sources with continental crust and/or lithospheric mantle material, likely as a result of the combined effect of plumes and plate tectonics. This process resulted in formation of a younger large fragment of the Archean crust such as the Central Karelian domain which factually connected more ancient fragments of the crust and likely contributed to development of the Neoarchean Kenorland Supercontinent.     

Age and provenances of sandstones from the Riphean Priozersk and Salmi formations in the eastern Pasha-Ladoga basin (southern margin of the Baltic Shield)

The data on the age of sediments and their sources were first obtained by isotopic methods and lithological-petrographic observations for the Priozersk and Salmi formations in the northeastern Pasha-Ladoga basin. Wide development of coarse-grained terrigenous rocks and peculiar structures point to the proximity of provenances and dominant sedimentation in terrestrial settings. U-Pb dating of 168 detrital zircons revealed that approximately 87% of all grains are Early Riphean in age, while other grains are dated back to the Early Proterozoic. Archean age is documented for only two zircon grains. It is established that detrital material of sandstones from the Priozersk and Salmi formations largely originate from the Salmi Massif (1.55–1.53 Ga) and secondarily from the Svecofennian intrusions of the northern Ladoga region aged approximately 1.88 Ga, which is confirmed also by Sm-Nd data. The occurrence of detrital zircons dated at approximately 1480–1490 Ma indicates development of coeval magmatic bodies in the immediate proximity to the sedimentation basin, which remain undiscovered. The concordant age obtained for the youngest detrital zircon grain points to the onset of sedimentation in the basin after 1477 ± 8 Ma ago. Thus, Riphean sedimentation on the eastern slope of the trough commenced only 20 Ma prior to the emplacement of the Valaam Sill.     

扬子地块西南缘下震旦系火成岩系研究

研究区的天宝山组和苏雄组、开建桥组酸性、中酸性火山岩、火山碎屑岩同属下震旦系。它们及同期形成的花岗岩形成于后造山构造环境中,并非与裂谷活动有关。它们皆为S型,其源岩为太古界。     

四川西北部的岩关阶

<正> 四川西北部早石炭世地层,前人作过不少研究,侯德封、杨敬之(1939)在北川、绵竹、平武及江油一带进行地质调查,将下石炭统划分为杜内阶及维宪阶。朱森等人(1939)将下石炭统命为总长沟系,分上、下两部分,分别代表维宪阶及杜内阶。范影年(1980)依据珊瑚类化石,将原总长沟系的下部划分为两部分,下部称长滩子段,上部称马角坝段,并将     

塔里木盆地巴楚—麦盖提地区石炭系混合沉积研究*

通过岩心、薄片观察,从岩石学特征入手,结合测井资料,对塔里木盆地巴楚—麦盖提地区石炭系的陆源碎屑—碳酸盐混积岩和混积层系进行了研究。根据混积强度将混积岩划分为混积型碎屑岩、混积型碳酸盐岩和高度混积岩。巴楚组下泥岩段和中泥岩段发育混积型碎屑岩,巴楚组生屑灰岩段、中泥岩段和小海子组发育混积型碳酸盐岩,卡拉沙依组上泥岩段、巴楚组下泥岩段及巴什托局部地区的中泥岩段发育高度混积岩。高度混积岩出现在海退期沉积的碎屑岩段,代表了陆源碎屑—碳酸盐强烈混合的过渡性沉积环境。研究区石炭系可识别出4个三级层序,混积层系主要发育在海侵体系域早期和高位体系域晚期,以间断混合和相缘混合为主。研究认为混积强度是评价混合沉积环境性质的主要参数,并将其划分为4级。下泥岩段存在混积强度达3级以上的混积界面,能用于地层对比。最后,结合混合沉积特征讨论了构造运动和海平面变化对研究区石炭系层序组以上的混合沉积的控制作用。     

湖相深水细粒物质的混合沉积作用探讨*

沉积物的混合是自然界的普遍现象,湖盆中广泛发育的深水细粒沉积岩本身就是一类混积岩。以东营凹陷古近系沙河街组三段下亚段—沙河街组四段上亚段细粒沉积岩为研究对象,通过厘米级岩心观察描述、小型沉积构造解剖、岩石薄片观察、X射线衍射全岩矿物分析及微量元素测试等方法,研究细粒物质的产出状态和混合方式;分析湖盆流体、气候及水体性质对细粒物质迁移、混合、沉积的控制作用,尝试探讨细粒物质的混合沉积机制。结果表明,湖相深水细粒沉积岩既有物质成分上的混合,也有结构的混合,且在宏观与微观的不同尺度均存在混合;混合沉积作用有均匀混合、纹层叠置混合、不均匀团块状混合等类型。纹层叠置混合沉积是最主要的混合沉积方式,依据纹层接触关系、所占比例及矿物产出状态可分为泥砂—灰纹层叠置混合型、泥—灰纹层叠置混合型、泥砂粒序—灰纹层叠置混合型、灰—泥—云纹层叠置混合型等。湖相深水细粒物质的混合沉积作用类型多且往往受多个因素同时控制,气候及水动力条件是控制细粒混合沉积岩发育的最主要因素,不同流体(浊流和底流)作用下的细粒沉积物混合作用存在差异。气候引起湖水性质变化及水体分层,从而控制不同类型细粒物质的絮凝沉降及化学沉积。不同构造部位、不同水体深度的混合作用不同;相同构造部位在垂向上也存在混合沉积方式的差异。