东秦岭金堆城大型斑岩钼矿床同位素及元素地球化学研究

文章系统研究了金堆城钼矿床的含矿钾长斑岩、围岩、矿石、矿石中的黄铁矿及矿化围岩的地球化学特征,深入探讨了矿区成矿物质的来源.金堆城含矿斑岩的稀土元素分布和特征地球化学参数显示,金堆城含矿斑岩富集LREE(LaN/YbN=540～1684),轻、重稀土元素分馏较明显,Eu异常不明显或无Eu异常(δEu=070～096).矿石中黄铁矿富集LREE(LaN/YbN=315～2628),具有弱的Eu负异常,无Ce异常(δEu=064～081, δCe=088～103),并与金堆城含矿钾长斑岩和矿石具有一致的球粒陨石标准化配分曲线和特征的地球化学参数,显示金堆城钼矿床的成矿物质来源与钾长斑岩同源.矿床铅、硫、碳和氢-氧同位素地球化学综合研究表明,成矿物质来源于深部,与钾长斑岩同源.围岩在矿化和蚀变过程中元素的迁移计算结果表明,在热液成矿过程中Mo随成矿流体加入到围岩并使围岩发生蚀变和矿化.钼矿床的成矿物质主要来自钾长斑岩,围岩不提供成矿物质.金堆城含矿斑岩和钼矿化的发生处于秦岭造山带在中新生代的挤压-伸展转变期,受板片断离作用和壳幔边界附近发生的基性岩浆底侵作用影响,加厚的华北地块南缘下地壳物质发生熔融形成花岗质岩浆,并沿构造薄弱带上升到浅部侵位,形成金堆城等同熔型斑岩和斑岩型矿床.     

东秦岭金堆城钼矿床辉绿岩地球化学特征及其地质意义

对金堆城钼矿区辉绿岩脉的岩石学和地球化学的详细研究表明,该区辉绿岩均遭受到不同程度的蚀变,为拉斑系列岩石,其主量元素以中等w(TiO_2)(1.47%~2.16%)、中等w(MgO)(3.47%~6.58%)、Mg#为26.99~40.46,w(K_2O)变化较大(0.05%~3.16%)为特征,可能与蚀变有关,贫w(P_2O_5)(0.36%~0.58%)、MgO与主要组分的相关性表明,岩浆早期出现过轻微的橄榄石、斜方辉石及铬铁矿、钛铁矿结晶分异;稀土元素总量相对较高,轻重稀土元素分馏显著((La/Yb)N=7.5~12.4),δEu为0.7~1.0,出现Eu的弱负异常。金堆城钼矿区的辉绿岩脉属于大陆板内拉斑玄武岩,形成过程中受到地壳物质的混染。     

Fluid evolution of the Yuchiling porphyry Mo deposit,East Qinling,China

The Yuchiling Mo deposit, East Qinling, China, belongs to a typical porphyry Mo system associated with high-K calc-alkaline intrusions. The pure CO₂ (PC), CO₂-bearing (C), aqueous H₂O-NaCl (W), and daughter mineral-bearing (S) fluid inclusions were observed in the hydrothermal quartz. Based on field investigations, petrographic, microthermometric and LA-ICP-MS studies of fluid inclusions, we develop a five-stage fluid evolution model to understand the ore-forming processes of the Yuchiling deposit. The earliest barren quartz ± potassic feldspar veins, developed in intensively potassic alteration, were crystallized from carbonic-dominant fluids at high temperature (> 416 °C) and high pressure (> 133 MPa). Following the barren quartz ± potassic feldspar veins are quartz-pyrite veins occasionally containing minor K-feldspar and molybdenite, which were formed by immiscible fluids at pressures of 47–159 MPa and temperatures of 360–400 °C. The fluids were characterized by high CO₂ contents (approximately 8 mol%) and variable salinities, as well as the highest Mo contents that resulted in the development of quartz-molybdenite veins. The quartz-molybdenite veins, accounting for > 90% Mo in the orebody, were also formed by immiscible fluids with lower salinity and lower CO₂ content of 7 mol%, at temperatures of 340–380 °C and pressures of 39–137 MPa, as constrained by fluid inclusion assemblages. After the main Mo-mineralization, the uneconomic Cu-Pb-Zn mineralization occurred, as represented by quartz-polymetallic sulfides veins consisting of pyrite, molybdenite, chalcopyrite, digenite, galena, sphalerite and quartz. The quartz-polymetallic sulfide veins were formed by fluids containing 5 mol% CO₂, with minimum pressures of 32–110 MPa and temperatures of 260–300 °C. Finally, the fluids became dilute (5 wt.% NaCl equiv) and CO₂-poor, which caused the formation of late barren quartz ± carbonate ± fluorite veins at 140–180 °C and 18–82 MPa.It is clear that the fluids became more dilute, CO₂-poor, and less fertile, with decreasing temperature and pressure from quartz-pyrite to late barren veins. Molybdenite and other sulfides can only be observed in the middle three stages, i.e., quartz-pyrite, quartz-molybdenite and quartz-polymetallic sulfide veins. These three kinds of veins are generally hosted in potassic altered rocks with remarkable K-feldspathization, but always partly overprinted by phyllic alteration. The traditional porphyry-style potassic–phyllic–propylitic alteration zoning is not conspicuous at Yuchiling, which may be related to, and characteristic of, the CO₂-rich fluids derived from the magmas generated in intercontinental collision orogens.Among the fluid inclusions at Yuchiling, only the C-type contains maximum detectable Mo that gradationally decreases from 73 ppm in quartz-pyrite veins, through 19 ppm in quartz-molybdenite veins, and to 13 ppm in quartz-polymetallic sulfide veins, coinciding well with the decreasing CO₂ contents from 8 mol%, through 7 mol%, to 5 mol%, respectively. Hence it is suggested that decreasing CO₂ possibly results in decreasing Mo concentration in the fluids, as well as the precipitation of molybdenite from the fluids. This direct relationship might be a common characteristic for other porphyry Mo systems in the world.The Yuchiling Mo deposit represents a new type Mo mineralization, with features of collision-related setting, high-K calc-alkaline intrusion, CO₂-rich fluid, and unique wall-rock alterations characterized by strong K-feldspathization and fluoritization.     

Zircon U-Pb ages and geochemistry of the Wenquan Mo-bearing granitioids in West Qinling,China: Constraints on the geodynamic setting for the newly discovered Wenquan Mo deposit

East Qinling is the largest porphyry molybdenum province in the world; these Mo deposits have been well documented. In West Qinling, however, few Mo deposits have been discovered although granitic rocks are widespread. Recently, the Wenquan porphyry Mo deposit has been discovered in Gansu province, which provides an insight into Mo mineralization in West Qinling. In this paper we report Pb isotope compositions for K-feldspar and sulfides, S isotope ratios for sulfides, the results obtained from petrochemical study and from in situ LA-ICP-MS zircon U-Pb dating and Hf isotopes. The granitoids are enriched in LILE and LREE, with REE and trace element patterns similar to continental crust, suggesting a crustal origin. The Mg^# (40.05 to 56.34) and Cr and Ni contents are high, indicating a source of refractory mafic lower crust. The ε_Hf(t) values of zircon grains from porphyritic monzogranite range from ? 2.9 to 0.6, and from granitic porphyry vary from ? 3.3 to 1.9. The zircons have T_DM2 of 1014 to 1196 Ma for the porphyritic monzogranite and 954 to 1224 Ma for the granitic porphyry, implying that these granitoids were likely derived from partial melting of a Late Mesoproterozoic juvenile lower crust. The Pb isotope compositions of the granitoids are similar to granites in South China, showing that the magma was sourced from the middle–lower crust in the southern Qinling tectonic unit. The Pb isotopic contrast between the Mo-bearing granitoids and ores shows that the Pb in the ore-forming solution was derived from fractionation of a Triassic magmatic system. δ³⁴S values of sulfides are between 5.02 and 5.66‰, similar to those associated with magmatic-hydrothermal systems. LA-ICP-MS zircon U-Pb dating yields crystallization ages of 216.2 ± 1.7 and 217.2 ± 2.0 Ma for the granitoids, consistent with a previously reported molybdenite Re-Os isochron age of 214.4 ± 7.1 Ma. This suggests that the Mo mineralization is related to the late Triassic magmatism in the West Qinling orogenic belt. In view of these geochemical results and known regional geology, we propose that both granitoid emplacement and Mo mineralization in the Wenquan deposit resulted from the Triassic collision between the South Qinling and the South China Block, along the Mianlue suture. Since Triassic granitoid plutons commonly occur along the Qinling orogenic belt, the Triassic Wenquan Mo-bearing granitoids highlight the importance of the Triassic tectono-magmatic belt for Mo exploration. In order to apply this metallogenic model to the whole Qinling orogen, further study is needed to compare the Wenquan deposit with other deposits.     

西秦岭格娄昂金矿床赋矿斑岩岩石成因及其地质意义

西秦岭造山带广泛发育印支期花岗质岩石,已探明超过1200吨金资源量与这些花岗质岩石具有密切空间关系;揭示赋矿花岗质岩石成因对于进一步约束金成矿与岩浆作用是否具有成因关系具有重要意义。格娄昂矿床（金资源量27.7t,平均品位2.18g/t）是西秦岭造山带西段甘南地区的大型金矿床,花岗质岩石和变沉积岩是其主要赋矿围岩。格娄昂金矿床赋矿英安斑岩与黑云英安斑岩属于过铝质高钾钙碱性系列,轻重稀土分异较大,（La/Yb）_N比值为31.07~40.59,富集大离子亲石元素,亏损高场强元素Nb、Ta等,具有弱铕负异常（δEu=0.76~0.78）。英安斑岩和黑云英安斑岩被金矿脉切割,LA-ICP-MS锆石U-Pb年龄分别为250.8±2.5Ma和252.9±3.4Ma,磷灰石U-Pb年龄分别为248.9±7.3Ma和249.7±7.9Ma,为成矿前早三叠世岩浆作用的产物。锆石ε_Hf（t）=-13.88~-7.84,对应的二阶段Hf模式年龄（t_DM²）为2.15~1.78Ga。因此,格娄昂金矿床早三叠世赋矿英安斑岩和黑云英安斑岩为成矿前岩浆活动的产物,源于古元古代下地壳的部分熔融。可能与洋壳板片北向俯冲有关,形成于活动大陆边缘碰撞前构造环境,进一步支持阿尼玛卿-勉略洋在早三叠世尚未闭合。

     

西秦岭太阳山斑岩铜-钼矿床岩体氧逸度及成矿意义

甘肃天水三叠纪太阳山斑岩铜钼矿床位于西秦岭造山带东段。矿体主要赋存于石英闪长斑岩、二长斑岩、石英二长斑岩和泥盆系大草滩群。氧逸度是表征岩石物理化学性质的重要参数,对岩浆热液成矿具有明显的控制作用。在综合评述常用氧逸度计算方法及适用性的前提下,文中应用激光剥蚀等离子质谱分析方法对太阳山矿床含矿岩体锆石微量元素进行测定,选用含量较高的Sm、Nd进行Ce异常计算,查明含矿斑岩岩浆氧逸度,探讨其成矿意义。太阳山矿床岩浆氧逸度计算结果表明,太阳山成矿二长斑岩和石英二长斑岩相对氧逸度ΔFMQ分别为+3.04和+3.15,成矿前石英闪长斑岩相对氧逸度ΔFMQ为-1.83,成矿岩体氧逸度明显高于成矿前岩体。成矿岩体岩浆氧逸度高于成矿前岩体的原因可能与富集地幔有关。富集岩石圈地幔的加入,带来了大量的硫和金属铜,并提高了岩浆氧逸度。     

Geological features and genesis of the Jinduicheng porphyry molybdenum deposit,Shaanxi Province,China

Situated in the Henan-Shaanxi fault-uplift area on the southern margin of the Sino-Korean Paraplatform, the Jinduicheng porphyry molybdenum deposit is the most important molybdenum producer in China. During Yenshanian the Jinduicheng granite porphyry was emplaced in metaspilite of the Proterozoic Xionger Group, controlled by a NW-trending fault. Mineral compositions are mainly quartz (25–40%), microcline and microcline-perthite (27–40%) and plagioclase (An 8–14, 14–32%), associated with minor biotite and muscovite, and phenocrysts are made up of K-feldspar, quartz and plagioclase. Accessory minerals include magmatite, apatite and zircon. The porphyry contains SiO₂ 73.83% and K₂O + Na₂O 8.06% (with K₂O/Na₂O ratio being 1.82), beloning to the calc-alkaline series. Mineralization occurs in the porphyry body and biotitized and hornfelsized spilite within the exocontact zone. The maximum depth of mineralization reaches 1000 meters below the surface. According to mineral assemblage, ore veins are classified into five types: (1) pyrite-quartz; (2) pyrite-K-feldspar-quartz; (3) pyrite-molybdenite-quartz; (4) pyrite-molybdenite-K-feldspar-quartz; and (5) muscovitefluorite-pyrite-molybdenite-quartz. As the most important economic molybdenum mineral, molybdenite occurs in various forms. Wall-rock alterations show a gross zonation of K-feldspathization-greisenization → silicification → propylitization from the porphyry outwards, of which silicification is most intense and has close genetic relationship with Mo mineralization. Fluid inclusion studies yield homogeneous temperatures ranging from 250 to 240°C, with the main stage between 400 and 300°C. Gas inclusions frequently coexist with multiphase inclusions containing such daughter minerals as halite, sylvite, molybdenite and K-feldspar. Under moderate-high temperatures, lowerfo₂, highfs₂ and weak acidity conditions, boiling of ore-forming fluids is a prerequisite for the precipitation of molybdenite. Sulfur, oxygen and carbon isotopic compositions suggest that at the high temperature stage (450°C) magmatic water is dominant and at the main ore-forming stage a mixture of magmatic water and meteoric water is expected. At the late stage, the mixture is predominated by meteoric water. Sulfur and molybdenum are mostly of magmatic origin.     

东秦岭花岗伟晶岩中电气石地球化学特征及成矿指示意义

东秦岭地区是我国重要的花岗伟晶岩区及稀有金属成矿区。电气石在东秦岭各类花岗伟晶岩中广泛发育,通常在无矿化伟晶岩、铍矿化及锂矿化伟晶岩中呈黑色-深蓝色。本文旨在通过各类伟晶岩中电气石的对比研究揭示电气石地球化学特征对东秦岭伟晶岩矿化类型的指示作用。本文所研究电气石为作为东秦岭各类伟晶岩贯通矿物的黑电气石系列。在双峰村、碾盘及风原无矿化伟晶岩中,黑电气石生长环带发育,单偏光下呈蓝绿色-棕色,具有较高的Mg、Ti、Sc含量,较低Li、Mn、Zn含量,δ¹¹B值变化较大（约-19.00‰~-12.00‰）。街子沟富铍伟晶岩中黑电气石单偏光下呈蓝色-草绿色,Ti、V、Sc含量低于无矿化伟晶岩中黑电气石,δ¹¹B值约-16.00‰~-12.00‰。丰庄伟晶岩具弱铌钽矿化,黑电气石具有核-边结构,单偏光下呈蓝色-深蓝色,比无矿化和铍矿化伟晶岩中黑电气石含有更高Li、Zn含量,δ¹¹B值-21.92‰~-14.75‰。在蔡家沟Li矿化伟晶岩中,黑色-深蓝色电气石Li₂O含量达到约1.0%,成分上过渡至黑电气石-锂电气石系列,具有最高Li、Mn、Zn含量,而Mg、Ti、Sc、V含量极低,其δ¹¹B值-18.96‰~-16.89‰。硼同位素分析揭示碾盘、风原及丰庄伟晶岩中存在两类电气石,Ⅰ类电气石富重B同位素,可能为较早从伟晶岩熔体中结晶形成;而Ⅱ类电气石具有更负的δ¹¹B值,可能为伟晶岩流体出溶时由流体中晶出。流体出溶导致围岩中形成热液电气石,其δ¹¹B值与伟晶岩中Ⅱ类电气石相似,表明出溶流体与围岩的作用并未导致显著的B同位素分馏。但伟晶岩与围岩之间的作用,使得Mg、Ti、V进入伟晶岩,同时Li、B、Al进入围岩。在研究区内,从无矿化至锂矿化伟晶岩,随伟晶岩分异程度增加,岩浆成因的黑电气石中Li、Mn、Zn、F含量升高而δ¹¹B值降低,表明黑电气石的Li、Mn、Zn及F含量和B同位素组成可以有效指示伟晶岩矿化类型。

     

Geochronology of magmatism and mineralization of the Daheishan giant porphyry molybdenum deposit,Jilin Province,Northeast China: constraints on ore genesis and implications for geodynamic setting

Daheishan giant porphyry Mo deposit is located in the Lesser Xing’an–Zhangguangcai Ranges, Jilin Province, NE China. Mineralization is closely related to the Daheishan intrusive complex, which can be divided into Changganglin biotite granodiorite, Qiancuoluo biotite granodiorite, and Qiancuoluo granodioritic porphyry. Four stages of mineralization are distinguished, based on the cross-cutting relationships of mineralized veins. LA-ICPMS zircon U-Pb analysis yields ²⁰⁶Pb/²³⁸U ages of 177.9 ± 2.3 Ma for the Changganglin biotite granodiorite, 169.9 ± 2.3 Ma for the Qiancuoluo biotite granodiorite, and 166.6 ± 4.0 Ma for the Qiancuoluo granodioritic porphyry. Hydrothermal fluids responsible for mineralization evolved from different magmas. Six molybdenite samples yield Re-Os model ages of ~167 Ma. Muscovite from the last mineralization stage gives a ⁴⁰Ar/³⁹Ar plateau age of 163.6 ± 0.9 Ma. Geochronology data indicate that the entire magmatic system lasted for about 10 million years, and the total duration of hydrothermal activity was less than 4 million years. The ε_Hf(t) values of zircons obtained from the Changganglin biotite granodiorite, Qiancuoluo biotite granodiorite, and Qiancuoluo granodioritic porphyry range from 4.5 to 9.1, 5.7 to 10.9, and 4.4 to 7.1, respectively, indicating that they were mainly derived from the depleted mantle, although contaminated by crustal materials to a greater or lesser extent. The formation of the Daheishan porphyry Mo deposit was temporally and spatially related to the amalgamation of Jiamusi Massif and Songliao terrane in the Palaeo-Pacific Ocean regime. Regional Hf isotopic compositions of zircon suggest an episode of crustal growth in the Phanerozoic in the Lesser Xing’an–Zhangguangcai Ranges. Regional Mo mineralization ages suggest a peak of porphyry Mo mineralization in the Jurassic in the Lesser Xing’an-Zhangguangcai Ranges.     

西秦岭温泉钼矿区含钼花岗斑岩锆石U-Pb年龄、Hf同位素组成及岩浆物质来源讨论

温泉钼矿床位于西秦岭造山带北缘,是西秦岭地区唯一斑岩型钼矿床。矿体产于花岗斑岩体及其与围岩接触带内。对温泉钼矿含矿花岗斑岩开展锆石U-Pb年代学与原位Hf同位素研究,有助于精确约束含钼花岗斑岩时代,揭示岩浆演化信息,深化温泉钼矿床成因的认识。本文利用LA-ICPMS锆石U-Pb定年方法,对温泉钼矿区含钼岩体进行精确同位素定年。结果表明：花岗斑岩的锆石环带结构明显,Th/U比值较大（0.41~0.88）,为典型的岩浆锆石,含钼花岗斑岩侵位年龄为212.43~213.4 Ma,其侵入的似斑状二长花岗岩年龄（围岩）则为219.9 Ma,均属晚三叠世岩浆活动的产物。温泉矿区花岗斑岩锆石Hf同位素组成较为一致,ε_Hf（t）值均为负值,介于-1.89~-0.63,平均-1.59,在ε_Hf（t）-t图解中,样点集中分布于球粒陨石以及亏损地幔线之下,暗示其岩浆源区较单一,应为经改造过的地壳物质部分熔融的产物。二阶段模式年龄（T_DM2）主要集中在1291~1408 Ma,表明中元古代地壳物质可能为岩体主要来源。     

Late Mesozoic magmatism in the East Qinling Orogen,China and its tectonic implications

The Qinling Orogen in Central China records the history of a complex geological evolution and tectonic transition from compression to extension during the Late Mesozoic,with concomitant voluminous granitoids formation.In this study,we present results from petrological,geochemical,zircon U-Pb-Lu-Hf isotopic studies on the Lengshui felsic dykes from Luanchuan region in the East Qinling Orogen.We also compile published geochronological,geochemical,and Hf isotopic data from Luanchuan region and present zircon Hf isotopic contour maps.The newly obtained age data yield two group of ages at～145 Ma and 140 Ma for two granite porphyries from the Lengshui felsic dykes,with the ～145 Ma interpreted as response to the peak of magmatism in the region,and the ～140 Ma as the timing of formation of the felsic dykes.The corresponding Hf isotopic data of the granite porphyries display negativeeHit)values of-16.67 to-4.61,and Hf crustal model ages(T_(DM~C_)of 2255-1490 Ma,indicating magma sourced from the melting of Paleo-to Mesoproterozoic crustal materials.The compiled age data display two major magmatic pulses at 160-130 Ma and 111-108 Ma with magmatic quiescence in between,and the zircon Hf isotopic data display/ε_(Hf)(t)values ranging from-41.9 to 2.1 and T_(DM)~c values of3387-1033 Ma,suggesting mixed crustal and mantle-derived components in the magma source,and correspond to multiple tectonic events during the Late Mesozoic.The Luanchuan granitoids are identified as 1-type granites and most of these are highly fractionated granites,involving magma mixing and mingling and crystal fractionation.The tectonic setting in the region transformed from the Late Jurassic syn-collision setting to Early Cretaceous within-plate setting,with E-W extension in the Early Cretaceous.This extension is correlated with the N-S trending post-collisional extension between the North China Craton and Yangtze Craton as well as the E-W trending back-arc extension triggered by the westward Paleo-Pacific Plate subduction,eventually leading to lithospheric thinning,asthenospheric upwelling,mafic magma underplating,and crustal melting in the East Qinling Orogen.     

黑龙江洋灰洞子铜矿床花岗闪长斑岩地球化学、锆石U--Pb定年及地质意义

黑龙江洋灰洞子斑岩型铜矿床地处兴蒙造山带东段、吉黑褶皱带北部,矿体主要赋存在花岗闪长斑岩和构造角砾岩中。为厘定洋灰洞子铜矿床的成岩成矿时代和构造背景,笔者对洋灰洞子花岗闪长斑岩进行了元素地球化学和LA--ICP--MS锆石U--Pb年代学的相关研究。岩石地球化学特征显示,花岗闪长斑岩富硅贫镁,属于过铝质钙碱性系列,富集轻稀土元素(LREE),(La/Yb)N=10.49~19.79,Eu显示弱负异常或正异常,高Sr低Y和Yb,富集大离子亲石元素(LILE),相对亏损高场强元素(HFSE),具有埃达克岩或埃达克质岩的特征。LA--ICP--MS锆石U--Pb测年结果显示,花岗闪长斑岩锆石206Pb/238U加权平均年龄为204.4±2.8 Ma和201.2±1.7 Ma。综合研究认为,洋灰洞子斑岩型铜矿床的成岩成矿时代可能为晚三叠世—早侏罗世之交,该矿床形成于古亚洲洋闭合后的陆陆碰撞造山环境,是加厚下地壳部分熔融形成的岩浆流体作用的结果。     

东昆仑夏日哈木铜镍矿镁铁质超镁铁质岩体岩相学、锆石U-Pb年代学、地球化学及其构造意义

文章报道了东昆仑夏日哈木铜镍矿成矿岩体的岩相学、锆石U-Pb年代学、全岩地球化学以及锆石Hf同位素资料,以确定该岩体的形成时代、岩石成因及其形成的构造环境。夏日哈木Ⅰ号镁铁质超镁铁质岩体位于昆中基底隆起花岗岩带中段,北侧靠近昆北断裂。岩体走向NEE,剖面呈平缓的“岩盆状”,地表出露面积约0.7 km2。该杂岩体主要由辉长苏长岩、斜方辉石岩、橄榄辉石岩、斜长二辉橄榄岩和方辉橄榄岩组成,橄榄岩相和辉石岩相是主要的Cu、Ni赋矿岩相。镁铁质超镁铁质岩体主量元素具有低硅(w(SiO₂)=36.68%~52.58%)、低钛(w(TiO2)=0.13%~0.47%)、高镁(w(MgO)=10.91%~35.81%)、贫碱(w(K₂O+Na₂O)=0.26%~1.95%)的特征,属亚碱性系列岩石,m/f为3.88~6.29,属铁质超基性岩类(m/f=2~6.5)。岩石稀土元素球粒陨石标准化配分模式为轻稀土富集型,(La/Yb)N=1.44~2.98,Eu异常不明显,相似的稀土元素配分模式说明岩体的同源性。岩石富集大离子亲石元素(Rb、Th、U、K),相对亏损高场强元素(Nb、Ta)。岩体中存在新元古代花岗岩的捕虏体以及La/Yb、Ce/Yb、Th/Yb、Nb/La、La/Sm比值显示岩体经历了有限的地壳混染。辉长苏长岩锆石的LA-MC ICPMS、U-Pb年代学研究表明,岩体形成年龄为(423±1) Ma,MSWD=0.14,属晚志留世。锆石的176Hf/177Hf比值为0.282 628~0.282 833,相应的εHf(t)均为正值(4.0~10.9),Lu-Hf的单阶段模式年龄(tDM1)为610~875 Ma,平均值为788 Ma,大于锆石U-Pb年龄。研究认为,岩体的岩浆源区主要为亏损地幔,可能有早期流体交代的富集岩石圈地幔组分的加入和地壳物质的混染。结合区域构造演化,文章认为岩体形成于碰撞后伸展的构造环境,可能与俯冲板片的断离作用有关。岩浆演化过程中橄榄石和斜方辉石的分离结晶作用和地壳中硫的加入可能是促使岩浆体系达到硫饱和的主要机制。     

Sanukite（赞岐岩）的地球化学特征、成因及其地球动力学意义

赞岐岩 (サヌカイト ,sanukite)是指发现于日本四国北部的一种富Mg的火山岩 ,主要产于日本中新世 (11～14Ma)Setouchi火山岩带 ,是一种黑色玻璃质的火山岩。其化学成分以富Si质 (安山英安质 )、具很高的Mg# 值 (>0 .6 )、高的Cr、Ni丰度和K/Na值 (0 .33～ 0 .5 2 )为特征。赞岐岩的形成与菲律宾海板块年轻的热的岩石圈俯冲和四国盆地的张开有关 ,产于岛弧的弧前或弧后盆地环境。赞岐岩不只代表火山岩 ,也包括侵入岩。Shirey和Hanson(1984 )将该术语引入太古宙 ,将太古宙具上述赞岐岩特征 (Si过饱和、Mg# 高和Ni、Cr、LILE含量高 )的深成岩和火山岩称为sanukite岩套。赞岐岩与埃达克岩具有大体类似的地球化学特征 ,但前者更富Mg、Cr和Ni,表明赞岐岩可以直接由地幔岩部分熔融形成 ,而埃达克岩只能由玄武岩部分熔融形成。现代的赞岐岩很少见 ,而太古宙的赞岐岩比较常见 ,暗示太古宙导致板片熔融的消减的岩石圈本身或上地幔可能具有更高的温度。赞岐岩集中出现在晚太古代 (<3.0Ga) ,表明板块消减作用可能在 3.0Ga之后才成为一个重要的过程 ,晚太古代赞岐岩的出现可能标志着现代类型板块构造的开始     

南秦岭桂林沟斑岩型钼矿Re-Os同位素年代学及其构造意义研究

陕西省镇安县桂林沟斑岩型钼矿床位于南秦岭多金属成矿带内,其成矿围岩主要为细粒花岗岩、钾长花岗岩和蚀变的粗粒花岗岩。本文通过对桂林沟斑岩型钼矿床中辉钼矿Re-Os同位素定年以及围岩中锆石U-Pb年代学研究,旨在探讨成矿成岩的关系及其构造意义。结果表明,6件辉钼矿的Re-Os同位素年龄在195.9~198.5Ma之间,加权平均年龄为197.2±1.3Ma,表明桂林沟钼矿形成于早侏罗世。围岩细粒花岗岩、钾长花岗岩和粗粒花岗岩的锆石U-Pb年龄分别为199±1.4Ma、201±3.1Ma和198±11Ma,这说明其成岩和成矿年龄基本一致。值得注意的的是,桂林沟钼矿床的形成年龄不同于前人已报导的秦岭钼矿的三个主要成矿期,即238~213Ma、145~126Ma和116~110Ma,其稍晚于第一成矿期。200~190Ma可能代表了秦岭成矿带一期尚未认识的重要成矿事件,对于南秦岭找矿具有重要意义。该期钼矿形成于秦岭印支期碰撞之后,是在造山带垮塌引起的岩浆-热液事件过程中形成的。     

The porphyry molybdenum deposit of Compaccha,Peru, and its geologic setting

Compaccha, in Peru, is a zoned molybdenum, copper, zinc, lead, antimonyarsenic district which has historically been important because of tungsten production derived from all zones. Wolframite, the principal tungsten mineral, is zoned compatibly with the sulfides. Manganese tungstate occurs in the molybdenum zone, while iron replaces the manganese increasingly importantly as distance is gained away from this zone. The alteration zoning in and around the molybdenum zone is typical of that of a porphyry copper deposit, in that fluorite, topaz or other fluorine rich silicates are not common. The molybdenum zone does include a porphyry molybdenum deposit, however, and this is characterized by intense silicification and quartz veining (stockworks). Within the area of the deposit, east of the coastal batholith, no Mesozoic arc type or basic volcanics can be inferred. A cratonic setting is postulated for the deposit.     

东秦岭石窑沟斑岩钼矿床地质特征及辉钼矿Re-Os年龄

在东秦岭钼成矿带最近探明的石窑沟大型钼矿床位于近东西向马超营断裂带与北东向石窑沟-焦园断裂带的交汇部位,获得钼金属储量10余万吨,平均品位0.068%。钼矿化呈细脉-网脉状分布于花岗斑岩体及其围岩熊耳群火山岩中,与矿化有关的围岩蚀变有钾长石化、硅化、绢云母化、黄铁矿化等,具有斑岩型钼矿床的一些基本特点。在矿床中选取5件不同矿化类型的辉钼矿样品,采用ICP-MS法进行Re-Os同位素定年,获得模式年龄131.3±2.4～134.3±2.6Ma,等时线年龄135.2±1.8Ma(MSWD=0.18),形成于早白垩世,与豫西熊耳山地区雷门沟、鱼池岭等钼矿床形成时代相近。据辉钼矿Re含量(8.242×10-6～30.24×10-6)推测,矿床成矿物质主要来自于下地壳。矿床为东秦岭-大别山地区中生代第三期钼成矿作用产物,形成于早白垩世中国东部岩石圈伸展环境。     

陕西省华县金堆城斑岩型钼矿床流体包裹体研究

陕西省华县金堆城钼矿床位于东秦岭钼矿带西部,形成于燕山期大陆碰撞体制.矿体产出于金堆城花岗斑岩体内部及其内外接触带.流体成矿过程包括早、中、晚3个阶段,分别以石英-钾长石组合、石英-(钾长石)-多金属硫化物-(碳酸盐)组合和石英-碳酸盐组合为标志,矿石矿物主要沉淀于中阶段.早、中阶段石英中可见纯CO_2包裹体(PC型)、CO_2-H_2O型包裹体(C型)、水溶液包裹体(W型)和含子晶多相包裹体(S型),但晚阶段只发育水溶液包裹体(W型).早阶段C型和W型包裹体均一温度集中于280～370℃,盐度为5.68～11.05 wt%NaCl.eqv;中阶段C型和W型流体包裹体均一温度集中于170～270℃,盐度为5.14～12.63 wt%NaCl.eqv.早、中阶段石英中见S型包裹体,加热过程中子矿物不溶.晚阶段流体包裹体均一温度集中于110～1900C,盐度介于7.17%～11.22 wt%NaCl.eqv之间.估算的早、中阶段流体捕获压力分别为143～243MPa和22～115MPa,推测成矿深度约为2.2～8.1km.金堆城钼矿的成矿流体以富CO_2、贫Cl~-为特征.     

西秦岭甘南早子沟石英闪长玢岩岩石成因及其地质意义

西秦岭造山带位于华北板块和华南板块之间,是我国中央造山带的重要组成部分,记录了东亚古特提斯洋东北支的演化历史,对于探讨华北板块和华南板块的碰撞过程具有重要意义。西秦岭广泛发育的早-中三叠世火成岩与勉略洋壳向北俯冲有关,但勉略洋壳的闭合时限仍有争议。因此本文对采自早子沟地区的石英闪长玢岩进行锆石U-Pb年代学、Lu-Hf同位素和全岩主微量地球化学分析,查明早子沟石英闪长玢岩成因及其构造演化背景,并进一步约束勉略洋壳闭合时间。锆石LA-ICP-MS U-Pb定年结果表明,石英闪长玢岩侵位年龄为~232Ma,为中三叠世岩浆活动的产物。石英闪长玢岩含有较高的SiO₂(56.18%~68.26%),K₂O为1.82%~3.70%,A/CNK值为0.73~1.07,是准铝质-弱过铝质的钙碱性-高钾钙碱性岩石。其富钾的特征,与中高钾基性下地壳部分熔融产生的熔体成分一致。轻重稀土分异明显,(La/Yb)_N比值为8.10~61.2,富集大离子亲石元素(K、Sr、Ba、Cs),亏损高场强元素Nb、Ta,具有弱负铕异常(δEu=0.65~0.93),显示了典型的大陆地壳岩石特征。石英闪长玢岩较高的Mg^#值(47.57~70.35)意味着有一定幔源物质的加入。ε_Hf(t)在-12.9~-7.2之间,对应的二阶段Hf模式年龄(t_DM²)为1.70~2.10Ga,表明岩浆来自于古元古代下地壳的重熔。本文认为石英闪长玢岩形成于勉略洋壳向北俯冲背景下的活动大陆边缘环境,具有碰撞前花岗质岩石特征,即勉略洋壳在~232Ma仍处在俯冲阶段。

     

Geochemistry,zircon U–Pb and molybdenite Re–Os dating of the Taolaituo porphyry Mo deposit in the Central Great Hinggan Range: implications for the geodynamic evolution of northeastern China

The Taolaituo porphyry‐type molybdenum deposit is located in the eastern Inner Mongolia Autonomous Region in China. The mineralization occurs mainly as veins, lenses and layers within the host porphyry. To better understand the link between the mineralization and the host igneous rocks, we studied samples from the underground workings and report new SHRIMP II zircon U–Pb and Re–Os molybdenite ages, and geochemical data from both the molybdenites and the porphyry granites. Five molybdenite samples yield a Re–Os isochron weighted mean age of 133.0 ± 0.82 Ma, whereas the porphyry granitoids samples yield crystallization ages of 133 ± 1 Ma and 130.4 ± 1.3 Ma. The U–Pb and Re–Os ages are similar, suggesting that the mineralization is genetically related to the Early Cretaceous porphyry emplacement. Re contents of the molybdenites range from 21.74 to 42.45 ppm, with an average of 32.69 ppm, whereas δ³⁴S values vary between 3.7‰ and 4.2‰, which is typical of mantle sulphur. The ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/ ²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb vary in the ranges of 18.276–18.385, 15.566–15.580 and 38.321–38.382, respectively. The Taolaituo Early Cretaceous granitoids are A‐type granites. These observations indicate that the molybdenites and the porphyry granites were derived from a mixed source involving young accretionary materials and enriched subcontinental lithospheric mantle. A synthesis of geochronological and geological data reveals that porphyry emplacement and Mo mineralization in the Taolaituo deposit occurred contemporaneously with the Early Cretaceous tectonothermal events associated with lithospheric thinning, which was caused by delamination and subsequent upwelling of the asthenosphere associated with intra‐continental extension in northeast China. Copyright © 2015 John Wiley & Sons, Ltd.